CN103719108A - Ultra-low volume liquid containing picoxystrobin and morpholine bactericide and application thereof - Google Patents
Ultra-low volume liquid containing picoxystrobin and morpholine bactericide and application thereof Download PDFInfo
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Abstract
The invention discloses an ultra-low volume liquid containing picoxystrobin and a morpholine bactericide and application thereof, and aims to provide a novel ultra-low volume liquid. The ultra-low volume liquid comprises the picoxystrobin, the morpholine bactericide, an auxiliary agent, a solvent and a cosolvent. The ultra-low volume liquid has the advantages that the effects are achieved quickly, the lasting period is long, the rain wash resistance is achieved, and water and labor are reduced; the ultra-low volume liquid is applicable to ultra-low volume spraying, low volume spraying and electrostatic spraying, can be used for preventing diseases of crops such as paddies, wheat, fruit trees and vegetables, and has better prevention effect on powdery mildew, banded sclerotial blight, rice blast, downy mildew, gray mold, rot, brown rot, root rot and anthracnose, the application range is wide, and the prevention effect is good.
Description
Technical field
The present invention relates to pesticide field, especially contain ultra low volume liquids and the application thereof of ZEN 90160 and morpholine series bactericidal agent.
Background technology
Ultra low volume liquids is to be applicable to the pesticidal preparations that ultra low volume spraying is used.Ultra low volume spraying follows the appearance of ultra low volume sprayer tool to produce, an advanced applications of pesticide new technology, and its droplet is the uniform oiliness droplet of fineness, easily stick on crops, thereby the elegant loss of its droplet is little, agricultural chemicals utilization ratio is high.Compared with the pesticidal preparations of conventional spray application, its tool has the following advantages: 1) ultra low volume liquids spray amount is 60～330mL/ mu, be conventional spraying consumption hundreds of/mono-, thereby it is low to have spray amount, the feature that work efficiency is high; 2) with respect to conventional fogdrop diameter 200～600 μ m, ultra low volume liquids mist droplet particle size scope is 20～100 μ m, and its droplet is thin, and the coverage rate of liquid is high, good penetrability, and drug effect is high; 3) ultra low volume liquids is Direct spraying dispenser, high tens of even hundreds of times of the conventional spraying of spray liquor concentration ratio; 4) conventional spray liquor is made carrier with water, and ultra low volume is made carrier in order to high boiling point oil solvent, more resistance of rainwater washing against, and the drug effect phase is long; 5) ultra low volume liquids, to crop, person poultry safety, has higher safety.
The solvent that ultra low volume liquids is low by screening volatility, flash-point is high, good to former medicine dissolubility, low to chemical injury of crops, viscosity is low, during dispenser, be not watered, but directly use with ultra low volume sprayer tool, low-gallonage spraying apparatus or ultra low volume electrostatic spray apparatus.Ultra low volume spraying is owing to not containing high volatile volatile composition in droplet, and its size does not have significant change with quality from leave spraying apparatus arrival target process, has reduced and has volatilized with elegant.Droplet is tiny and even, meets " biological best granula " requirement, has significantly improved deposition.Owing to using without being watered, ultra low volume liquids is suitable for the occasion of water scarcity, the generation of damage by disease and insect fulminant large area and dispenser on a large scale in the palpus short time, and ultra low volume spraying simultaneously reduces operator's labour intensity greatly.
Present inventor's earlier application Flusilazole and the composite ultra low volume liquids of ZEN 90160, application number is CN201110269638.1.In this patent application, under approximate consumption, this invention has than the better control efficiency of conventional dose.Because ultra low volume liquids requires to have, the property of sending out is low, flash-point is high, good to former medicine dissolubility, low to chemical injury of crops, viscosity is low, thereby conventional component is difficult to meet the requirement of corresponding ultra low volume solvent, therefore that ultra low volume liquids is come out at present is less.At present, there is not the report of the ultra low volume liquids composite about morpholine class yet.Therefore, develop new ultra low volume liquids and there is certain prospect.
Summary of the invention
Goal of the invention of the present invention is: for the problem of above-mentioned existence, provide ultra low volume liquids and application thereof containing ZEN 90160 and morpholine series bactericidal agent.The present invention is take ZEN 90160 and morpholine series bactericidal agent as active ingredient, and composite by with other components prepared the ultra low volume liquids containing ZEN 90160 and morpholine series bactericidal agent.The present invention is that applicant passes through long-term screening and great many of experiments, the ultra low volume liquids obtaining.Ultra low volume liquids of the present invention has instant effect, lasting period length, resistance of rainwater washing against, water-saving, saving of labor's advantage.The present invention is applicable to ultra low volume spraying, low-gallonage spraying and electrostatic spray, can be used in the control of the crop pests such as paddy rice, wheat, fruit tree, vegetables, powdery mildew, banded sclerotial blight, rice blast, downy mildew, gray mold, rot, brown rot, root rot and anthracnose are had to good control efficiency, applied widely, control efficiency is good.
To achieve these goals, the present invention adopts following technical scheme:
Containing the ultra low volume liquids of ZEN 90160 and morpholine series bactericidal agent, by the component of following percentage by weight, formed:
ZEN 90160 0.5～10%,
Morpholine series bactericidal agent 2～20%,
Auxiliary agent 1～15%,
Solvent and cosolvent surplus;
Described morpholine series bactericidal agent is the one in dimethomorph, fenpropidin, butadiene morpholine, volution bacterium amine, tridemorph.
Described auxiliary agent be in alkylphenol polyoxyethylene, fatty alcohol-polyoxyethylene ether, castor oil polyoxyethylene ether, alkyl benzene calcium sulfonate, phenethyl phenol polyethenoxy ether, alkyl phenol formaldehyde resin polyoxyethylene ether one or more.
Described solvent is one or more in DMF, methyl-sulfoxide, sulfolane, 1-METHYLPYRROLIDONE.
Described cosolvent is one or more in vegetable oil methyl oleate, soybean oil, cottonseed oil, palm oil, castor oil, turpentine oil, corn oil, trimethylbenzene, dimethylbenzene, two wires oil, butylbenzene, terpineol, tripropylene glycol butyl ether, n-octyl alcohol, 2-methyl naphthalene, diesel oil, repefral.
The preparation method of the aforementioned ultra low volume liquids containing ZEN 90160 and morpholine series bactericidal agent, comprise the steps: to take each component by proportioning, first solvent is dropped in reactor, and solvent is stirred, under stirring condition, in reactor, add Boscalid, morpholine series bactericidal agent simultaneously, after Boscalid, morpholine series bactericidal agent dissolve completely, in reactor, add cosolvent, auxiliary agent again, continue to stir 15-60 minute, obtain the oily product of homogeneous transparent.
The application of the aforementioned ultra low volume liquids containing ZEN 90160 and morpholine series bactericidal agent, the control by this ultra low volume liquids for crop pest.
The application of the aforementioned ultra low volume liquids containing ZEN 90160 and morpholine series bactericidal agent, the control by this ultra low volume liquids for paddy rice, wheat, fruit tree, vegetable disease.
The application of the aforementioned ultra low volume liquids containing ZEN 90160 and morpholine series bactericidal agent, the control by this ultra low volume liquids for powdery mildew, banded sclerotial blight, rice blast, downy mildew, gray mold, rot, brown rot, root rot, anthracnose.
ZEN 90160, its Chinese name is (E)-3-methoxyl group-2-{2-[6-(trifluoromethyl)-2-pyridine oxygen methyl] phenyl } methyl acrylate, molecular structural formula is as shown in Figure 1.It belongs to mitochondrial respiratory inhibitor, by electronics between cytochrome b and C1, is shifted and is suppressed mitochondrial breathing.The bacterial strain that ZEN 90160 produces resistance to 14-demethylation enzyme inhibitor, benzamides, three carboxyl acylamides and benzimidazole is effective.ZEN 90160, after blade absorbs, will move in xylem, with current, in transportation system, flows, and it also flows in the gas phase of blade surface, and in xylem, flows again along with gas phase absorbs to enter after blade.It is applicable to crop and safety wheat class, recommends under dosage breaking, to crop safety, without poisoning.ZEN 90160 can be used in the foliage disease of control wheat class as leaf blight, leaf rust, glume blight, brown spot, powdery mildew etc., compared with existing strobilurin series bactericidal agent, wheat leaf blessing disease, net blotch and moire disease is had to better result for the treatment of.
Dimethomorph, its chemical name is (E, Z)-4-[3-(4-chlorphenyl) 3-(3,4-Dimethoxyphenyl) acryloyl] morpholine, be a kind of efficient, interior absorption azoles fungicide.Its mechanism of action is demethylation sterol inhibitor, has the multiple actions such as prevention, protection and treatment.It is as single-minded ovicidal Gammaproteobacteria fungi bactericide, effect feature is to destroy the formation of cell envelope, there is effect in each stage to oomycetes history of life, particularly particularly responsive at the formation stages of sporangiophore and egg spore, under extremely low concentration, (<0.25 μ g/ml) is suppressed.It is widely used in vegetables downy mildew, epidemic disease, seedling stage damping off, black shank etc. by the fungus-caused disease control of Mastigomycotina Oomycete, tool systemic activity, and with phenylamide medicament without cross resistance.Do not considering under the drug-fast prerequisite of disease fungus, the drug effect of dimethomorph is better compared with metalaxyl, white urea cyanogen, aliette, Wakil etc.
Fenpropidin, its chemical name is (RS)-1-[3-(4-t-butyl-phenyl)-2-methyl-propyl] piperidines, belong to piperidines systemic fungicide.It is sterol decomposing inhibitor, effective especially to Erysiphaceae, especially standing grain powdery mildew, rye spore and handle rest fungus, cereal crop Application 750g/ha.As prevented and treated barley powdery mildew, rust with 500～700g (a.i.)/ha, it has therapeutic action, about 28d of lasting period.
Butadiene morpholine, its chemical name is (±) cis-4-3-(4-t-butyl-phenyl)-2-methyl-propyl)-2,6-thebaine, belongs to morpholines, is also sterol reduction inhibitor agent.It has protection and treatment double action, and can, to top conduction, to the protection of Newborn Leaves, reach 3～4 weeks.
Volution bacterium amine, its chemical name is the N-ethyl-N-propyl group-8-tert-butyl group-Isosorbide-5-Nitrae-dioxo spiro [4.5] decane-2-methylamine, belongs to sterol biosynthesis inhibitor, mainly suppresses the synthetic of C-14 demethylation enzyme.Volution bacterium amine, as a kind of blade face bactericide of novel, interior absorption, can be used in control wheat powdery mildew and various rust, barley leaf blotch and stripe disease, under recommended dose, to crop safety, without poisoning.Its speed of action is fast and the lasting period is long, has protection and treatment double action.It both can use separately, again can be with other fungicide compoundings to expand fungicidal spectrum, and using dosage is 375～750g (a.i.)/hm
2.
Tridemorph, its chemical name is 2,6-dimethyl-4-tridecyl morpholine, it is mainly used in preventing and treating powdery mildem of cereals and sigatoka, to other fungal disease (as white, red, the brown root rot of bamboo grows, powdery mildew, coffee eye spot; The cake disease that tealeaves is right; Melon powdery mildew and the powdery mildew of flowers and trees etc.) also there is good control efficiency.
Ultra low volume liquids of the present invention is comprised of ZEN 90160, morpholine series bactericidal agent, auxiliary agent, solvent and cosolvent, and morpholine series bactericidal agent is the one in dimethomorph, fenpropidin, butadiene morpholine, volution bacterium amine, tridemorph.The present invention is take ZEN 90160 and morpholine series bactericidal agent as active component, by the ultra low volume liquids of the two composite formation binary active ingredient.The present invention, by the cooperation between component, makes a kind of new ultra low volume liquids.In this ultra low volume liquids, have obvious synergistic function between component, its control efficiency is significantly better than each single dose.Ultra low volume liquids of the present invention can be applicable to ultra low volume spraying, low-gallonage spraying and electrostatic spray, the crop pests such as paddy rice, wheat, fruit tree, vegetables are had to good control efficiency, can be for the control of powdery mildew, banded sclerotial blight, rice blast, downy mildew, gray mold, rot, brown rot, root rot and anthracnose.
Accompanying drawing explanation
Examples of the present invention will be described by way of reference to the accompanying drawings, wherein:
Fig. 1 is the molecular structure of ZEN 90160.
Embodiment
Disclosed all features in this specification, or the step in disclosed all methods or process, except mutually exclusive feature and/or step, all can combine by any way.
Disclosed arbitrary feature in this specification, unless narration especially all can be replaced by other equivalences or the alternative features with similar object.That is,, unless narration especially, each feature is an example in a series of equivalences or similar characteristics.
Embodiment 1
Prepare 16% ZEN 90160 dimethomorph ultra low volume liquids
Take respectively 0.5kg ZEN 90160,15.0kg dimethomorph, 3.0kg fatty alcohol-polyoxyethylene ether, 6.0kg alkylphenol polyoxyethylene, 5.0kgN, dinethylformamide, 30.0kg methyl oleate, 40.5kg diesel oil, standby.
By N, dinethylformamide drops in reactor, and solvent is stirred, simultaneously under stirring condition, in reactor, add Boscalid, dimethomorph, after Boscalid, dimethomorph dissolve completely, then add cosolvent, auxiliary agent in reactor, continue to stir 15-60 minute, obtain the oily product of homogeneous transparent.
Embodiment 2
Prepare 12% ZEN 90160 dimethomorph ultra low volume liquids
Take respectively 10.0kg ZEN 90160,2.0kg dimethomorph, 3.0kg alkyl benzene calcium sulfonate, 4.0kg alkylphenol polyoxyethylene, 20.0kg sulfolane, 30.0kg two wires oil, 31kg cottonseed oil, standby.
Sulfolane is dropped in reactor, and solvent is stirred, simultaneously under stirring condition, in reactor, add Boscalid, dimethomorph, after Boscalid, dimethomorph dissolve completely, in reactor, add cosolvent, auxiliary agent again, continue to stir 15-60 minute, obtain the oily product of homogeneous transparent.
Embodiment 3
Prepare 8% ZEN 90160 dimethomorph ultra low volume liquids
Take respectively 5.0kg ZEN 90160,3.0kg dimethomorph, 0.5kg phenethyl phenol polyethenoxy ether, 0.5kg alkylphenol polyoxyethylene, 35.0kgN-methyl pyrrolidone, 30.0kg butylbenzene, 26kg palm oil, standby.
1-METHYLPYRROLIDONE is dropped in reactor, and solvent is stirred, simultaneously under stirring condition, in reactor, add Boscalid, dimethomorph, after Boscalid, dimethomorph dissolve completely, in reactor, add cosolvent, auxiliary agent again, continue to stir 15-60 minute, obtain the oily product of homogeneous transparent.
Embodiment 4
Prepare 15% ZEN 90160 fenpropidin ultra low volume liquids
Take respectively 10.0kg ZEN 90160,5.0kg fenpropidin, 4.0kg castor oil polyoxyethylene ether, 11kg phenethyl phenol polyethenoxy ether, 14.0kg methyl-sulfoxide, 5.0kg trimethylbenzene, 25.0kgN-methyl pyrrolidone, 12kg methyl oleate, 14kg terpineol, standby.
Methyl-sulfoxide is dropped in reactor, and solvent is stirred, simultaneously under stirring condition, in reactor, add Boscalid, fenpropidin, after Boscalid, fenpropidin dissolve completely, in reactor, add cosolvent, auxiliary agent again, continue to stir 15-60 minute, obtain the oily product of homogeneous transparent.
Embodiment 5
Prepare 23% ZEN 90160 fenpropidin ultra low volume liquids
Take respectively 3.0kg ZEN 90160,20.0kg fenpropidin, 5.0kg phenethyl phenol polyethenoxy ether, 3.5kg fatty alcohol-polyoxyethylene ether, 20.0kg methyl-sulfoxide, 12kg n-octyl alcohol, 36.5kg methyl oleate, standby.
Methyl-sulfoxide is dropped in reactor, and solvent is stirred, simultaneously under stirring condition, in reactor, add Boscalid, fenpropidin, after Boscalid, fenpropidin dissolve completely, in reactor, add cosolvent, auxiliary agent again, continue to stir 15-60 minute, obtain the oily product of homogeneous transparent.
Embodiment 6
Prepare 15% ZEN 90160 fenpropidin ultra low volume liquids
Take respectively 8.0kg ZEN 90160,7.0kg fenpropidin, 6.5kg alkyl phenol formaldehyde resin polyoxyethylene ether, 25.0kgN-methyl pyrrolidone, 12kg methyl oleate, 41.5kg repefral, standby.
1-METHYLPYRROLIDONE is dropped in reactor, and solvent is stirred, simultaneously under stirring condition, in reactor, add Boscalid, fenpropidin, after Boscalid, fenpropidin dissolve completely, in reactor, add cosolvent, auxiliary agent again, continue to stir 15-60 minute, obtain the oily product of homogeneous transparent.
Embodiment 7
Prepare 5% ZEN 90160 butadiene morpholine ultra low volume liquids
Take respectively 2.0kg ZEN 90160,3.0kg butadiene morpholine, 4.0kg fatty alcohol-polyoxyethylene ether, 25.0kgN-methyl pyrrolidone, 20.0kg methyl oleate, 46kg corn oil, standby.
1-METHYLPYRROLIDONE is dropped in reactor, and solvent is stirred, simultaneously under stirring condition, in reactor, add Boscalid, butadiene morpholine, after Boscalid, butadiene morpholine dissolve completely, in reactor, add cosolvent, auxiliary agent again, continue to stir 15-60 minute, obtain the oily product of homogeneous transparent.
Embodiment 8
Prepare 11% ZEN 90160 butadiene morpholine azoles ultra low volume liquids
Take respectively 9.0kg ZEN 90160,2.0kg butadiene morpholine, 4.5kg phenethyl phenol polyethenoxy ether, 30.0kgN, dinethylformamide, 5.0kg dimethylbenzene, 49.5kg terpineol, standby.
By N, dinethylformamide drops in reactor, and solvent is stirred, simultaneously under stirring condition, in reactor, add Boscalid, butadiene morpholine, after Boscalid, butadiene morpholine dissolve completely, then add cosolvent, auxiliary agent in reactor, continue to stir 15-60 minute, obtain the oily product of homogeneous transparent.
Embodiment 9
Prepare 18% ZEN 90160 butadiene morpholine ultra low volume liquids
Take respectively 3.0kg ZEN 90160,15.0kg butadiene morpholine, 8.0kg alkyl phenol formaldehyde resin polyoxyethylene ether, 6.5kg phenethyl phenol polyethenoxy ether, 25.0kg methyl-sulfoxide, 12kg n-octyl alcohol, 30.5kg castor oil, standby.
Methyl-sulfoxide is dropped in reactor, and solvent is stirred, simultaneously under stirring condition, in reactor, add Boscalid, butadiene morpholine, after Boscalid, butadiene morpholine dissolve completely, in reactor, add cosolvent, auxiliary agent again, continue to stir 15-60 minute, obtain the oily product of homogeneous transparent.
Embodiment 10
Prepare 10% ZEN 90160 volution bacterium amine ultra low volume liquids
Take respectively 5.0kg ZEN 90160,5.0kg volution bacterium amine, 4.0kg alkyl benzene calcium sulfonate, 25.0kgN-methyl pyrrolidone, 20.0kg tripropylene glycol butyl ether, 41kg repefral, standby.
1-METHYLPYRROLIDONE is dropped in reactor, and solvent is stirred, simultaneously under stirring condition, in reactor, add Boscalid, volution bacterium amine, until Boscalid, volution bacterium amine solvent completely after, in reactor, add cosolvent, auxiliary agent again, continue to stir 15-60 minute, obtain the oily product of homogeneous transparent.
Embodiment 11
Prepare 12% ZEN 90160 volution bacterium amine ultra low volume liquids
Take respectively 9.0kg ZEN 90160,3.0kg volution bacterium amine, 4.0kg alkyl phenol formaldehyde resin polyoxyethylene ether, 5.0kg phenethyl phenol polyethenoxy ether, 30.0kgN-methyl pyrrolidone, 5.0kg turpentine oil, 44kg cottonseed oil, standby.
1-METHYLPYRROLIDONE is dropped in reactor, and solvent is stirred, simultaneously under stirring condition, in reactor, add Boscalid, volution bacterium amine, until Boscalid, volution bacterium amine solvent completely after, in reactor, add cosolvent, auxiliary agent again, continue to stir 15-60 minute, obtain the oily product of homogeneous transparent.
Embodiment 12
Prepare 20% ZEN 90160 volution bacterium amine ultra low volume liquids
Take respectively 5.0kg ZEN 90160,15.0kg volution bacterium amine, 4.0kg alkylphenol polyoxyethylene, 4.0kg alkyl benzene calcium sulfonate, 30.0kgN-methyl pyrrolidone, 42kg two wires oil, standby.
1-METHYLPYRROLIDONE is dropped in reactor, and solvent is stirred, simultaneously under stirring condition, in reactor, add Boscalid, volution bacterium amine, until Boscalid, volution bacterium amine solvent completely after, in reactor, add cosolvent, auxiliary agent again, continue to stir 15-60 minute, obtain the oily product of homogeneous transparent.
Embodiment 13
Prepare 5% ZEN 90160 tridemorph ultra low volume liquids
Take respectively 2.0kg ZEN 90160,3.0kg tridemorph, 4.0kg fatty alcohol-polyoxyethylene ether, 4.0kg alkylaryl polyoxyethylene polyoxypropylene ether, 25.0kgN-methyl pyrrolidone, 20.0kg methyl oleate, 42kg soybean oil, standby.
1-METHYLPYRROLIDONE is dropped in reactor, and solvent is stirred, simultaneously under stirring condition, in reactor, add Boscalid, tridemorph, after Boscalid, tridemorph dissolve completely, in reactor, add cosolvent, auxiliary agent again, continue to stir 15-60 minute, obtain the oily product of homogeneous transparent.
Embodiment 14
Prepare 11% ZEN 90160 tridemorph azoles ultra low volume liquids
Take respectively 9.0kg ZEN 90160,2.0kg tridemorph, 4.5kg phenethyl phenol polyethenoxy ether, 30.0kg sulfolane, 54.5kg castor oil, standby.
Sulfolane is dropped in reactor, and solvent is stirred, simultaneously under stirring condition, in reactor, add Boscalid, tridemorph, after Boscalid, tridemorph dissolve completely, in reactor, add cosolvent, auxiliary agent again, continue to stir 15-60 minute, obtain the oily product of homogeneous transparent.
Embodiment 15
Prepare 23% ZEN 90160 tridemorph ultra low volume liquids
Take respectively 3.0kg ZEN 90160,20.0kg tridemorph, 8.0kg alkyl phenol formaldehyde resin polyoxyethylene ether, 6.5kg phenethyl phenol polyethenoxy ether, 25.0kg methyl-sulfoxide, 12kg n-octyl alcohol, 25.5kg2-methyl naphthalene, standby.
Methyl-sulfoxide is dropped in reactor, and solvent is stirred, simultaneously under stirring condition, in reactor, add Boscalid, tridemorph, after Boscalid, tridemorph dissolve completely, in reactor, add cosolvent, auxiliary agent again, continue to stir 15-60 minute, obtain the oily product of homogeneous transparent.
Contrast experiment
The field trial of ultra low volume liquids control apple anthracnose prepared by the employing embodiment of the present invention.
The mixture that the embodiment of the present invention 1～15 is obtained and 25% ZEN 90160 SC, 10% own azoles alcohol EC carry out field control effectiveness test, establish each community and select field planting one-tenth apple tree in age 5 strains of 3 years, repeat 4 times; 14 days investigation preventive effects after medicine, the method for investigation drug effect is: 2 strains are investigated in each community, and every strain is got a point by east, south, west, north, middle direction, every some investigation 2 strains, record total strain number and diseased plant number at different levels, check the occurrence degree of anthracnose.
Experimental result is as shown in table 1.
The control efficiency of table 1 embodiments of the invention to apple anthracnose
Field test results shows, the composite ultra low volume liquids of ZEN 90160 and morpholine class can effectively be prevented and treated apple anthracnose, and effect is better than the control efficiency of ZEN 90160 single dose and own azoles alcohol.
The present invention is not limited to aforesaid embodiment.The present invention expands to any new feature or any new combination disclosing in this manual, and the arbitrary new method disclosing or step or any new combination of process.
Claims (7)
1. containing the ultra low volume liquids of ZEN 90160 and morpholine series bactericidal agent, it is characterized in that, by the component of following percentage by weight, formed:
ZEN 90160 0.5～10%,
Morpholine series bactericidal agent 2～20%,
Auxiliary agent 1～15%,
Solvent and cosolvent surplus;
Described morpholine series bactericidal agent is the one in dimethomorph, fenpropidin, butadiene morpholine, volution bacterium amine, tridemorph.
2. contain according to claim 1 the ultra low volume liquids of ZEN 90160 and morpholine series bactericidal agent, it is characterized in that, described auxiliary agent be in alkylphenol polyoxyethylene, fatty alcohol-polyoxyethylene ether, castor oil polyoxyethylene ether, alkyl benzene calcium sulfonate, phenethyl phenol polyethenoxy ether, alkyl phenol formaldehyde resin polyoxyethylene ether one or more.
3. according to claim 1 containing the ultra low volume liquids of ZEN 90160 and morpholine series bactericidal agent, it is characterized in that, described solvent is one or more in DMF, methyl-sulfoxide, sulfolane, 1-METHYLPYRROLIDONE.
4. according to the ultra low volume liquids containing ZEN 90160 and morpholine series bactericidal agent described in claim 1-3 any one, it is characterized in that, described cosolvent is one or more in vegetable oil methyl oleate, soybean oil, cottonseed oil, palm oil, castor oil, turpentine oil, corn oil, trimethylbenzene, dimethylbenzene, two wires oil, butylbenzene, terpineol, tripropylene glycol butyl ether, n-octyl alcohol, 2-methyl naphthalene, diesel oil, repefral.
5. according to the application that contains the ultra low volume liquids of ZEN 90160 and morpholine series bactericidal agent described in claim 1-4 any one, it is characterized in that the control by this ultra low volume liquids for crop pest.
6. contain according to claim 5 the application of the ultra low volume liquids of ZEN 90160 and morpholine series bactericidal agent, it is characterized in that, the control by this ultra low volume liquids for paddy rice, wheat, fruit tree, vegetable disease.
7. contain according to claim 5 the application of the ultra low volume liquids of ZEN 90160 and morpholine series bactericidal agent, it is characterized in that the control by this ultra low volume liquids for powdery mildew, banded sclerotial blight, rice blast, downy mildew, gray mold, rot, brown rot, root rot, anthracnose.
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| CN110573016A (en) * | 2017-05-04 | 2019-12-13 | 江苏龙灯化学有限公司 | Fungicidal compositions and their use |
| CN110810401A (en) * | 2019-12-02 | 2020-02-21 | 贵州大学 | Dimethomorph and thiram bactericide, and preparation method and application thereof |
| CN112739210A (en) * | 2018-06-21 | 2021-04-30 | 阿达玛马克西姆有限公司 | Fungicidal compositions |
| WO2021197885A1 (en) * | 2020-04-01 | 2021-10-07 | Basf Se | Ternary mixtures containing fenpropimorph, azoles and strobilurins |
| WO2021197884A1 (en) * | 2020-04-01 | 2021-10-07 | Basf Se | Ternary mixtures containing fenpropimorph, succinate dehydrogenase inhibitors and strobilurins |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110573016A (en) * | 2017-05-04 | 2019-12-13 | 江苏龙灯化学有限公司 | Fungicidal compositions and their use |
| CN110573016B (en) * | 2017-05-04 | 2022-04-15 | 江苏龙灯化学有限公司 | Fungicidal compositions and their use |
| CN112739210A (en) * | 2018-06-21 | 2021-04-30 | 阿达玛马克西姆有限公司 | Fungicidal compositions |
| CN110810401A (en) * | 2019-12-02 | 2020-02-21 | 贵州大学 | Dimethomorph and thiram bactericide, and preparation method and application thereof |
| CN110810401B (en) * | 2019-12-02 | 2021-07-27 | 贵州大学 | Dimethomorph and thiram bactericide, and preparation method and application thereof |
| WO2021197885A1 (en) * | 2020-04-01 | 2021-10-07 | Basf Se | Ternary mixtures containing fenpropimorph, azoles and strobilurins |
| WO2021197884A1 (en) * | 2020-04-01 | 2021-10-07 | Basf Se | Ternary mixtures containing fenpropimorph, succinate dehydrogenase inhibitors and strobilurins |
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