CN102349506A - Ultralow-volume solvent containing Flusilazole - Google Patents
Ultralow-volume solvent containing Flusilazole Download PDFInfo
- Publication number
- CN102349506A CN102349506A CN2011102696381A CN201110269638A CN102349506A CN 102349506 A CN102349506 A CN 102349506A CN 2011102696381 A CN2011102696381 A CN 2011102696381A CN 201110269638 A CN201110269638 A CN 201110269638A CN 102349506 A CN102349506 A CN 102349506A
- Authority
- CN
- China
- Prior art keywords
- low volume
- ultra low
- flusilazole
- volume liquids
- solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- FQKUGOMFVDPBIZ-UHFFFAOYSA-N flusilazole Chemical compound C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 FQKUGOMFVDPBIZ-UHFFFAOYSA-N 0.000 title claims abstract description 112
- 239000002904 solvent Substances 0.000 title claims abstract description 36
- 238000005507 spraying Methods 0.000 claims abstract description 13
- 239000007788 liquid Substances 0.000 claims description 106
- 238000002360 preparation method Methods 0.000 claims description 76
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 28
- -1 fluorine silicon azoles Chemical class 0.000 claims description 25
- 240000007594 Oryza sativa Species 0.000 claims description 18
- 235000007164 Oryza sativa Nutrition 0.000 claims description 17
- 235000009566 rice Nutrition 0.000 claims description 17
- 150000003851 azoles Chemical class 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 15
- 238000003756 stirring Methods 0.000 claims description 15
- 241000894006 Bacteria Species 0.000 claims description 12
- TWFZGCMQGLPBSX-UHFFFAOYSA-N Carbendazim Natural products C1=CC=C2NC(NC(=O)OC)=NC2=C1 TWFZGCMQGLPBSX-UHFFFAOYSA-N 0.000 claims description 12
- 239000006013 carbendazim Substances 0.000 claims description 12
- JNPZQRQPIHJYNM-UHFFFAOYSA-N carbendazim Chemical compound C1=C[CH]C2=NC(NC(=O)OC)=NC2=C1 JNPZQRQPIHJYNM-UHFFFAOYSA-N 0.000 claims description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 11
- 239000005780 Fluazinam Substances 0.000 claims description 9
- UZCGKGPEKUCDTF-UHFFFAOYSA-N fluazinam Chemical compound [O-][N+](=O)C1=CC(C(F)(F)F)=C(Cl)C([N+]([O-])=O)=C1NC1=NC=C(C(F)(F)F)C=C1Cl UZCGKGPEKUCDTF-UHFFFAOYSA-N 0.000 claims description 9
- 241000221785 Erysiphales Species 0.000 claims description 8
- 239000005807 Metalaxyl Substances 0.000 claims description 8
- 229910019142 PO4 Inorganic materials 0.000 claims description 8
- ZQEIXNIJLIKNTD-UHFFFAOYSA-N methyl N-(2,6-dimethylphenyl)-N-(methoxyacetyl)alaninate Chemical compound COCC(=O)N(C(C)C(=O)OC)C1=C(C)C=CC=C1C ZQEIXNIJLIKNTD-UHFFFAOYSA-N 0.000 claims description 8
- 239000003921 oil Substances 0.000 claims description 8
- 235000019198 oils Nutrition 0.000 claims description 8
- 239000010452 phosphate Substances 0.000 claims description 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 8
- 239000005760 Difenoconazole Substances 0.000 claims description 7
- 239000005868 Metconazole Substances 0.000 claims description 7
- 206010039509 Scab Diseases 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- BQYJATMQXGBDHF-UHFFFAOYSA-N difenoconazole Chemical compound O1C(C)COC1(C=1C(=CC(OC=2C=CC(Cl)=CC=2)=CC=1)Cl)CN1N=CN=C1 BQYJATMQXGBDHF-UHFFFAOYSA-N 0.000 claims description 7
- XWPZUHJBOLQNMN-UHFFFAOYSA-N metconazole Chemical compound C1=NC=NN1CC1(O)C(C)(C)CCC1CC1=CC=C(Cl)C=C1 XWPZUHJBOLQNMN-UHFFFAOYSA-N 0.000 claims description 7
- 239000007921 spray Substances 0.000 claims description 7
- QNBTYORWCCMPQP-JXAWBTAJSA-N (Z)-dimethomorph Chemical compound C1=C(OC)C(OC)=CC=C1C(\C=1C=CC(Cl)=CC=1)=C/C(=O)N1CCOCC1 QNBTYORWCCMPQP-JXAWBTAJSA-N 0.000 claims description 6
- JWUCHKBSVLQQCO-UHFFFAOYSA-N 1-(2-fluorophenyl)-1-(4-fluorophenyl)-2-(1H-1,2,4-triazol-1-yl)ethanol Chemical compound C=1C=C(F)C=CC=1C(C=1C(=CC=CC=1)F)(O)CN1C=NC=N1 JWUCHKBSVLQQCO-UHFFFAOYSA-N 0.000 claims description 6
- PXMNMQRDXWABCY-UHFFFAOYSA-N 1-(4-chlorophenyl)-4,4-dimethyl-3-(1H-1,2,4-triazol-1-ylmethyl)pentan-3-ol Chemical compound C1=NC=NN1CC(O)(C(C)(C)C)CCC1=CC=C(Cl)C=C1 PXMNMQRDXWABCY-UHFFFAOYSA-N 0.000 claims description 6
- LQDARGUHUSPFNL-UHFFFAOYSA-N 1-[2-(2,4-dichlorophenyl)-3-(1,1,2,2-tetrafluoroethoxy)propyl]1,2,4-triazole Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(COC(F)(F)C(F)F)CN1C=NC=N1 LQDARGUHUSPFNL-UHFFFAOYSA-N 0.000 claims description 6
- 239000005761 Dimethomorph Substances 0.000 claims description 6
- 239000005787 Flutriafol Substances 0.000 claims description 6
- 239000005821 Propamocarb Substances 0.000 claims description 6
- 239000005822 Propiconazole Substances 0.000 claims description 6
- 239000005869 Pyraclostrobin Substances 0.000 claims description 6
- 239000005839 Tebuconazole Substances 0.000 claims description 6
- 239000005840 Tetraconazole Substances 0.000 claims description 6
- 239000005842 Thiophanate-methyl Substances 0.000 claims description 6
- 150000001408 amides Chemical class 0.000 claims description 6
- 239000012752 auxiliary agent Substances 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 6
- UFHLMYOGRXOCSL-UHFFFAOYSA-N isoprothiolane Chemical compound CC(C)OC(=O)C(C(=O)OC(C)C)=C1SCCS1 UFHLMYOGRXOCSL-UHFFFAOYSA-N 0.000 claims description 6
- WZZLDXDUQPOXNW-UHFFFAOYSA-N propamocarb Chemical compound CCCOC(=O)NCCCN(C)C WZZLDXDUQPOXNW-UHFFFAOYSA-N 0.000 claims description 6
- STJLVHWMYQXCPB-UHFFFAOYSA-N propiconazole Chemical compound O1C(CCC)COC1(C=1C(=CC(Cl)=CC=1)Cl)CN1N=CN=C1 STJLVHWMYQXCPB-UHFFFAOYSA-N 0.000 claims description 6
- HZRSNVGNWUDEFX-UHFFFAOYSA-N pyraclostrobin Chemical compound COC(=O)N(OC)C1=CC=CC=C1COC1=NN(C=2C=CC(Cl)=CC=2)C=C1 HZRSNVGNWUDEFX-UHFFFAOYSA-N 0.000 claims description 6
- QGHREAKMXXNCOA-UHFFFAOYSA-N thiophanate-methyl Chemical compound COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC QGHREAKMXXNCOA-UHFFFAOYSA-N 0.000 claims description 6
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 claims description 5
- 241001272567 Hominoidea Species 0.000 claims description 5
- JHXVRRJXCDAINK-UHFFFAOYSA-N NC(=O)N.N#CC#N Chemical compound NC(=O)N.N#CC#N JHXVRRJXCDAINK-UHFFFAOYSA-N 0.000 claims description 5
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 5
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 5
- 235000019438 castor oil Nutrition 0.000 claims description 5
- 239000004359 castor oil Substances 0.000 claims description 5
- 235000013399 edible fruits Nutrition 0.000 claims description 5
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 5
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims description 5
- WOSNCVAPUOFXEH-UHFFFAOYSA-N thifluzamide Chemical compound S1C(C)=NC(C(F)(F)F)=C1C(=O)NC1=C(Br)C=C(OC(F)(F)F)C=C1Br WOSNCVAPUOFXEH-UHFFFAOYSA-N 0.000 claims description 5
- 235000013311 vegetables Nutrition 0.000 claims description 5
- FYGHSUNMUKGBRK-UHFFFAOYSA-N 1,2,3-trimethylbenzene Chemical compound CC1=CC=CC(C)=C1C FYGHSUNMUKGBRK-UHFFFAOYSA-N 0.000 claims description 4
- KVNYFPKFSJIPBJ-UHFFFAOYSA-N 1,2-diethylbenzene Chemical compound CCC1=CC=CC=C1CC KVNYFPKFSJIPBJ-UHFFFAOYSA-N 0.000 claims description 4
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 claims description 4
- QPUYECUOLPXSFR-UHFFFAOYSA-N 1-methylnaphthalene Chemical compound C1=CC=C2C(C)=CC=CC2=C1 QPUYECUOLPXSFR-UHFFFAOYSA-N 0.000 claims description 4
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 claims description 4
- 239000005740 Boscalid Substances 0.000 claims description 4
- 239000005784 Fluoxastrobin Substances 0.000 claims description 4
- 239000005867 Iprodione Substances 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 claims description 4
- 230000000740 bleeding effect Effects 0.000 claims description 4
- WYEMLYFITZORAB-UHFFFAOYSA-N boscalid Chemical compound C1=CC(Cl)=CC=C1C1=CC=CC=C1NC(=O)C1=CC=CN=C1Cl WYEMLYFITZORAB-UHFFFAOYSA-N 0.000 claims description 4
- 229940118790 boscalid Drugs 0.000 claims description 4
- OCKPCBLVNKHBMX-UHFFFAOYSA-N butylbenzene Chemical compound CCCCC1=CC=CC=C1 OCKPCBLVNKHBMX-UHFFFAOYSA-N 0.000 claims description 4
- 239000002131 composite material Substances 0.000 claims description 4
- SQNZJJAZBFDUTD-UHFFFAOYSA-N durene Chemical compound CC1=CC(C)=C(C)C=C1C SQNZJJAZBFDUTD-UHFFFAOYSA-N 0.000 claims description 4
- UFEODZBUAFNAEU-NLRVBDNBSA-N fluoxastrobin Chemical compound C=1C=CC=C(OC=2C(=C(OC=3C(=CC=CC=3)Cl)N=CN=2)F)C=1C(=N/OC)\C1=NOCCO1 UFEODZBUAFNAEU-NLRVBDNBSA-N 0.000 claims description 4
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 claims description 4
- ONUFESLQCSAYKA-UHFFFAOYSA-N iprodione Chemical compound O=C1N(C(=O)NC(C)C)CC(=O)N1C1=CC(Cl)=CC(Cl)=C1 ONUFESLQCSAYKA-UHFFFAOYSA-N 0.000 claims description 4
- 239000010773 plant oil Substances 0.000 claims description 4
- 239000002798 polar solvent Substances 0.000 claims description 4
- WHHIPMZEDGBUCC-UHFFFAOYSA-N probenazole Chemical compound C1=CC=C2C(OCC=C)=NS(=O)(=O)C2=C1 WHHIPMZEDGBUCC-UHFFFAOYSA-N 0.000 claims description 4
- 239000004094 surface-active agent Substances 0.000 claims description 4
- 241001530056 Athelia rolfsii Species 0.000 claims description 3
- 150000001298 alcohols Chemical class 0.000 claims description 3
- 238000009835 boiling Methods 0.000 claims description 3
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 claims description 3
- 150000002825 nitriles Chemical class 0.000 claims description 3
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 3
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 3
- 239000008158 vegetable oil Substances 0.000 claims description 3
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 2
- YQZBFMJOASEONC-UHFFFAOYSA-N 1-Methyl-2-propylbenzene Chemical compound CCCC1=CC=CC=C1C YQZBFMJOASEONC-UHFFFAOYSA-N 0.000 claims description 2
- AXTGDCSMTYGJND-UHFFFAOYSA-N 1-dodecylazepan-2-one Chemical group CCCCCCCCCCCCN1CCCCCC1=O AXTGDCSMTYGJND-UHFFFAOYSA-N 0.000 claims description 2
- FIPWRIJSWJWJAI-UHFFFAOYSA-N Butyl carbitol 6-propylpiperonyl ether Chemical compound C1=C(CCC)C(COCCOCCOCCCC)=CC2=C1OCO2 FIPWRIJSWJWJAI-UHFFFAOYSA-N 0.000 claims description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 2
- LVGKNOAMLMIIKO-UHFFFAOYSA-N Elaidinsaeure-aethylester Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC LVGKNOAMLMIIKO-UHFFFAOYSA-N 0.000 claims description 2
- 239000001293 FEMA 3089 Substances 0.000 claims description 2
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 2
- MHABMANUFPZXEB-UHFFFAOYSA-N O-demethyl-aloesaponarin I Natural products O=C1C2=CC=CC(O)=C2C(=O)C2=C1C=C(O)C(C(O)=O)=C2C MHABMANUFPZXEB-UHFFFAOYSA-N 0.000 claims description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 2
- 235000019484 Rapeseed oil Nutrition 0.000 claims description 2
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 claims description 2
- 235000012343 cottonseed oil Nutrition 0.000 claims description 2
- 239000002385 cottonseed oil Substances 0.000 claims description 2
- SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 claims description 2
- 229960001760 dimethyl sulfoxide Drugs 0.000 claims description 2
- QYDYPVFESGNLHU-UHFFFAOYSA-N elaidic acid methyl ester Natural products CCCCCCCCC=CCCCCCCCC(=O)OC QYDYPVFESGNLHU-UHFFFAOYSA-N 0.000 claims description 2
- LVGKNOAMLMIIKO-QXMHVHEDSA-N ethyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC LVGKNOAMLMIIKO-QXMHVHEDSA-N 0.000 claims description 2
- 229940093471 ethyl oleate Drugs 0.000 claims description 2
- QYDYPVFESGNLHU-KHPPLWFESA-N methyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC QYDYPVFESGNLHU-KHPPLWFESA-N 0.000 claims description 2
- 229940073769 methyl oleate Drugs 0.000 claims description 2
- 229910052698 phosphorus Inorganic materials 0.000 claims description 2
- 239000011574 phosphorus Substances 0.000 claims description 2
- 229960005235 piperonyl butoxide Drugs 0.000 claims description 2
- 235000012424 soybean oil Nutrition 0.000 claims description 2
- 239000003549 soybean oil Substances 0.000 claims description 2
- 150000003462 sulfoxides Chemical class 0.000 claims description 2
- 229940116411 terpineol Drugs 0.000 claims description 2
- GYICYQJEVCIYJY-UHFFFAOYSA-N thiophen-1-ylidenemethanone Chemical compound O=C=S1C=CC=C1 GYICYQJEVCIYJY-UHFFFAOYSA-N 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 16
- 230000000694 effects Effects 0.000 abstract description 15
- 238000005406 washing Methods 0.000 abstract description 3
- 239000004615 ingredient Substances 0.000 abstract 3
- 239000004480 active ingredient Substances 0.000 abstract 1
- 238000007590 electrostatic spraying Methods 0.000 abstract 1
- 230000002085 persistent effect Effects 0.000 abstract 1
- 238000009991 scouring Methods 0.000 abstract 1
- 239000003814 drug Substances 0.000 description 17
- 239000000203 mixture Substances 0.000 description 17
- 201000010099 disease Diseases 0.000 description 12
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 12
- 238000011835 investigation Methods 0.000 description 12
- 230000000857 drug effect Effects 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- 241000196324 Embryophyta Species 0.000 description 8
- 239000003899 bactericide agent Substances 0.000 description 8
- 230000003449 preventive effect Effects 0.000 description 8
- 241000233866 Fungi Species 0.000 description 7
- 230000000855 fungicidal effect Effects 0.000 description 7
- 239000000417 fungicide Substances 0.000 description 7
- 239000000575 pesticide Substances 0.000 description 7
- 230000009885 systemic effect Effects 0.000 description 7
- 240000008067 Cucumis sativus Species 0.000 description 6
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 6
- 241000233679 Peronosporaceae Species 0.000 description 6
- 240000001987 Pyrus communis Species 0.000 description 6
- 235000014443 Pyrus communis Nutrition 0.000 description 6
- 230000000844 anti-bacterial effect Effects 0.000 description 6
- 230000002045 lasting effect Effects 0.000 description 6
- 241000238631 Hexapoda Species 0.000 description 5
- 241000607479 Yersinia pestis Species 0.000 description 5
- 210000004027 cell Anatomy 0.000 description 5
- 230000002950 deficient Effects 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- 230000002265 prevention Effects 0.000 description 5
- 238000001228 spectrum Methods 0.000 description 5
- 239000000375 suspending agent Substances 0.000 description 5
- 241000233654 Oomycetes Species 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 239000002552 dosage form Substances 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- 238000007689 inspection Methods 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 235000014347 soups Nutrition 0.000 description 4
- 150000003852 triazoles Chemical class 0.000 description 4
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 description 3
- 241000235349 Ascomycota Species 0.000 description 3
- 241000221198 Basidiomycota Species 0.000 description 3
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 3
- 241000233614 Phytophthora Species 0.000 description 3
- 229930182558 Sterol Natural products 0.000 description 3
- 235000021307 Triticum Nutrition 0.000 description 3
- 244000098338 Triticum aestivum Species 0.000 description 3
- 230000006378 damage Effects 0.000 description 3
- 238000010790 dilution Methods 0.000 description 3
- 239000012895 dilution Substances 0.000 description 3
- 229940079593 drug Drugs 0.000 description 3
- 231100000053 low toxicity Toxicity 0.000 description 3
- 239000004530 micro-emulsion Substances 0.000 description 3
- 230000001681 protective effect Effects 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- 150000003432 sterols Chemical class 0.000 description 3
- 235000003702 sterols Nutrition 0.000 description 3
- 238000009736 wetting Methods 0.000 description 3
- 235000017060 Arachis glabrata Nutrition 0.000 description 2
- 244000105624 Arachis hypogaea Species 0.000 description 2
- 235000010777 Arachis hypogaea Nutrition 0.000 description 2
- 235000018262 Arachis monticola Nutrition 0.000 description 2
- 240000004160 Capsicum annuum Species 0.000 description 2
- 235000008534 Capsicum annuum var annuum Nutrition 0.000 description 2
- 239000005800 Kresoxim-methyl Substances 0.000 description 2
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 2
- 208000031888 Mycoses Diseases 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 241001533598 Septoria Species 0.000 description 2
- 240000003768 Solanum lycopersicum Species 0.000 description 2
- 244000061456 Solanum tuberosum Species 0.000 description 2
- 235000002595 Solanum tuberosum Nutrition 0.000 description 2
- 241000317942 Venturia <ichneumonid wasp> Species 0.000 description 2
- 235000009754 Vitis X bourquina Nutrition 0.000 description 2
- 235000012333 Vitis X labruscana Nutrition 0.000 description 2
- 240000006365 Vitis vinifera Species 0.000 description 2
- 235000014787 Vitis vinifera Nutrition 0.000 description 2
- 239000003905 agrochemical Substances 0.000 description 2
- 210000000170 cell membrane Anatomy 0.000 description 2
- 230000017858 demethylation Effects 0.000 description 2
- 238000010520 demethylation reaction Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 210000004602 germ cell Anatomy 0.000 description 2
- 230000001965 increasing effect Effects 0.000 description 2
- ZOTBXTZVPHCKPN-HTXNQAPBSA-N kresoxim-methyl Chemical compound CO\N=C(\C(=O)OC)C1=CC=CC=C1COC1=CC=CC=C1C ZOTBXTZVPHCKPN-HTXNQAPBSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 244000052769 pathogen Species 0.000 description 2
- 235000020232 peanut Nutrition 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 230000000361 pesticidal effect Effects 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 230000001225 therapeutic effect Effects 0.000 description 2
- 239000004562 water dispersible granule Substances 0.000 description 2
- WKBPZYKAUNRMKP-UHFFFAOYSA-N 1-[2-(2,4-dichlorophenyl)pentyl]1,2,4-triazole Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(CCC)CN1C=NC=N1 WKBPZYKAUNRMKP-UHFFFAOYSA-N 0.000 description 1
- PPOPIFLDDYPIDD-UHFFFAOYSA-N 1h-pyrrole;silicon Chemical class [Si].C=1C=CNC=1 PPOPIFLDDYPIDD-UHFFFAOYSA-N 0.000 description 1
- SNTWKPAKVQFCCF-UHFFFAOYSA-N 2,3-dihydro-1h-triazole Chemical compound N1NC=CN1 SNTWKPAKVQFCCF-UHFFFAOYSA-N 0.000 description 1
- UFNOUKDBUJZYDE-UHFFFAOYSA-N 2-(4-chlorophenyl)-3-cyclopropyl-1-(1H-1,2,4-triazol-1-yl)butan-2-ol Chemical compound C1=NC=NN1CC(O)(C=1C=CC(Cl)=CC=1)C(C)C1CC1 UFNOUKDBUJZYDE-UHFFFAOYSA-N 0.000 description 1
- ICSNLGPSRYBMBD-UHFFFAOYSA-N 2-aminopyridine Chemical class NC1=CC=CC=N1 ICSNLGPSRYBMBD-UHFFFAOYSA-N 0.000 description 1
- FRXSZNDVFUDTIR-UHFFFAOYSA-N 6-methoxy-1,2,3,4-tetrahydroquinoline Chemical compound N1CCCC2=CC(OC)=CC=C21 FRXSZNDVFUDTIR-UHFFFAOYSA-N 0.000 description 1
- 241000238876 Acari Species 0.000 description 1
- 241001163841 Albugo ipomoeae-panduratae Species 0.000 description 1
- 241000223600 Alternaria Species 0.000 description 1
- 241000222195 Ascochyta Species 0.000 description 1
- 235000016068 Berberis vulgaris Nutrition 0.000 description 1
- 241000335053 Beta vulgaris Species 0.000 description 1
- 241000123650 Botrytis cinerea Species 0.000 description 1
- 240000002791 Brassica napus Species 0.000 description 1
- 235000006008 Brassica napus var napus Nutrition 0.000 description 1
- 235000004936 Bromus mango Nutrition 0.000 description 1
- FERIUCNNQQJTOY-UHFFFAOYSA-M Butyrate Chemical compound CCCC([O-])=O FERIUCNNQQJTOY-UHFFFAOYSA-M 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
- 241000675108 Citrus tangerina Species 0.000 description 1
- 241000222199 Colletotrichum Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- 239000005757 Cyproconazole Substances 0.000 description 1
- 206010011732 Cyst Diseases 0.000 description 1
- 240000001008 Dimocarpus longan Species 0.000 description 1
- 241001480059 Erysiphaceae Species 0.000 description 1
- 235000000235 Euphoria longan Nutrition 0.000 description 1
- 239000005785 Fluquinconazole Substances 0.000 description 1
- 235000016623 Fragaria vesca Nutrition 0.000 description 1
- 240000009088 Fragaria x ananassa Species 0.000 description 1
- 235000011363 Fragaria x ananassa Nutrition 0.000 description 1
- 206010017533 Fungal infection Diseases 0.000 description 1
- 241000223218 Fusarium Species 0.000 description 1
- 241000192128 Gammaproteobacteria Species 0.000 description 1
- 241000219146 Gossypium Species 0.000 description 1
- 241000555709 Guignardia Species 0.000 description 1
- 240000005979 Hordeum vulgare Species 0.000 description 1
- 235000007340 Hordeum vulgare Nutrition 0.000 description 1
- 240000008415 Lactuca sativa Species 0.000 description 1
- 235000003228 Lactuca sativa Nutrition 0.000 description 1
- 241000220225 Malus Species 0.000 description 1
- 235000011430 Malus pumila Nutrition 0.000 description 1
- 235000015103 Malus silvestris Nutrition 0.000 description 1
- 240000007228 Mangifera indica Species 0.000 description 1
- 235000014826 Mangifera indica Nutrition 0.000 description 1
- 240000005561 Musa balbisiana Species 0.000 description 1
- 235000018290 Musa x paradisiaca Nutrition 0.000 description 1
- 101710167853 N-methyltransferase Proteins 0.000 description 1
- 244000061176 Nicotiana tabacum Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- 239000005813 Penconazole Substances 0.000 description 1
- 241001503951 Phoma Species 0.000 description 1
- 241000233622 Phytophthora infestans Species 0.000 description 1
- 241000233647 Phytophthora nicotianae var. parasitica Species 0.000 description 1
- 241000233629 Phytophthora parasitica Species 0.000 description 1
- 241000233626 Plasmopara Species 0.000 description 1
- 241000589516 Pseudomonas Species 0.000 description 1
- 241000221535 Pucciniales Species 0.000 description 1
- 241000173767 Ramularia Species 0.000 description 1
- 241000221662 Sclerotinia Species 0.000 description 1
- 241001558929 Sclerotium <basidiomycota> Species 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 235000009184 Spondias indica Nutrition 0.000 description 1
- 239000005846 Triadimenol Substances 0.000 description 1
- 241000228452 Venturia inaequalis Species 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 125000003647 acryloyl group Chemical group O=C([*])C([H])=C([H])[H] 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 210000002421 cell wall Anatomy 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- CRQQGFGUEAVUIL-UHFFFAOYSA-N chlorothalonil Chemical compound ClC1=C(Cl)C(C#N)=C(Cl)C(C#N)=C1Cl CRQQGFGUEAVUIL-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 239000006184 cosolvent Substances 0.000 description 1
- 208000031513 cyst Diseases 0.000 description 1
- XUJNEKJLAYXESH-UHFFFAOYSA-N cysteine Natural products SCC(N)C(O)=O XUJNEKJLAYXESH-UHFFFAOYSA-N 0.000 description 1
- 235000018417 cysteine Nutrition 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 150000008056 dicarboxyimides Chemical class 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000002612 dispersion medium Substances 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000008686 ergosterol biosynthesis Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 229960004979 fampridine Drugs 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- IJJVMEJXYNJXOJ-UHFFFAOYSA-N fluquinconazole Chemical compound C=1C=C(Cl)C=C(Cl)C=1N1C(=O)C2=CC(F)=CC=C2N=C1N1C=NC=N1 IJJVMEJXYNJXOJ-UHFFFAOYSA-N 0.000 description 1
- 230000002538 fungal effect Effects 0.000 description 1
- 230000002070 germicidal effect Effects 0.000 description 1
- 102000006602 glyceraldehyde-3-phosphate dehydrogenase Human genes 0.000 description 1
- 108020004445 glyceraldehyde-3-phosphate dehydrogenase Proteins 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 230000002147 killing effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 230000011278 mitosis Effects 0.000 description 1
- LZGUHMNOBNWABZ-UHFFFAOYSA-N n-nitro-n-phenylnitramide Chemical class [O-][N+](=O)N([N+]([O-])=O)C1=CC=CC=C1 LZGUHMNOBNWABZ-UHFFFAOYSA-N 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 238000006303 photolysis reaction Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 230000007115 recruitment Effects 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 230000001932 seasonal effect Effects 0.000 description 1
- 231100000004 severe toxicity Toxicity 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 230000004763 spore germination Effects 0.000 description 1
- 230000028070 sporulation Effects 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- BAZVSMNPJJMILC-UHFFFAOYSA-N triadimenol Chemical compound C1=NC=NN1C(C(O)C(C)(C)C)OC1=CC=C(Cl)C=C1 BAZVSMNPJJMILC-UHFFFAOYSA-N 0.000 description 1
- FFSJPOPLSWBGQY-UHFFFAOYSA-N triazol-4-one Chemical compound O=C1C=NN=N1 FFSJPOPLSWBGQY-UHFFFAOYSA-N 0.000 description 1
- DQJCHOQLCLEDLL-UHFFFAOYSA-N tricyclazole Chemical compound CC1=CC=CC2=C1N1C=NN=C1S2 DQJCHOQLCLEDLL-UHFFFAOYSA-N 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses an ultralow-volume solvent containing Flusilazole. Flusilazole or an active ingredient compounded by Flusilazole and an active component B, an accessory ingredient and a solvent are prepared into the ultralow-volume solvent. The ultralow-volume solvent containing Flusilazole comprises the following ingredients in percentage by weight: 1-10% of Flusilazole, 0-20% of active component B, 1-15% of accessory ingredient and the balance of solvent. The ultralow-volume solvent containing Flusilazole is suitable for ultralow-volume spraying, low-volume spraying and electrostatic spraying, has the advantages of high work efficiency, water conservation, good quick effect, long persistent period and rain scouring washing resistance.
Description
Technical field
The invention belongs to technical field of pesticide, specifically relate to the ultra low volume liquids of fluorine silicon azoles.
Background technology
Flusilazole, chemical name: two (4-fluorophenyl)-(1H-1,2; 4-triazol-1-yl methyl) monosilane belongs to the triazole type systemic fungicide, can suppress the sterol demethylation; Destroy and stop the biosynthesis of ergosterol, cause cell membrane not form, make germ dead.It is mainly used in and prevents and treats Ascomycetes, Basidiomycetes, Fungi Imperfecti fungi; Venturia inaequalis, white powder germ; The wheat class nuclear cavity bacteria of cereal class, Septoria bacterium, snag shell bacterium etc., the various pathogens on Guignardia and the sweet Lay, leaf spot of peanut; But invalid to oomycetes, pear scab there is special efficacy.
Difenoconazole, chemical name: 1-{2-[4-(4-chlorobenzene oxygen)-2-chlorphenyl]-4-methyl isophthalic acid, 3-dioxin-pentane-2-ylmethyl }-1H-1,2, the 4-triazole belongs to the triazole type systemic fungicide, has protection, treatment and systemic activity.It belongs to sterol demethylation inhibitor, can suppress the biosynthesis of cell wall sterol, stops fungi growth.Its fungicidal spectrum is wide, is used for output and guaranteed quality that foliar treatment or seed treatment can improve crop; To Ascomycetes, Basidiomycetes with comprise that half of Alternaria, Ascochyta, the mould genus of tail spore, Colletotrichum, ball Cuo Pseudomonas, Phoma, Ramularia, Septoria, Venturia know sickly, Erysiphaceae, Uredinales and some are planted and are passed pathogen lasting protection and therapeutic action are arranged; Also fine to bitter rot or anthracnose of grape, white rot effect.
Carbendazim, chemical name: 2-(methoxyl group carbamyl) benzimidazole, characteristic such as benzimidazole has efficiently, low toxicity, wide spectrum, systemic fungicide, and the lasting period is long, effective to many sac fungis, imperfect fungus and various basidiomycetes, invalid to phytocomycetes.It is used to prevent and treat gibberella zeaze petch of wheat and barley, rice sheath blight disease, rice blast, sclerotium oryzicola; Many fruit trees, vegetable disease, like powdery mildew, anthracnose, scab etc., carbendazim can be transferred to other positions by plant absorbing and through conduction; Disturb the mitosis of germ cell, suppress its growth.
Isoprothiolane, chemical name: 1,3-dithiolane-2-vinyl Diisopropyl malonate is the interior absorption organosulfureous fungicide of efficient, low toxicity, low-residual.Rice blast is had special efficacy, and rice plant can suppress the germ intrusion after absorbing, and has especially suppressed phosphide N-methyltransferase, thereby suppresses the germ growth, plays prevention and therapeutic action.
Tpn, chemical name: daconil M (or 2,4; 5,6-tetrachloro-1,3-benzene dicarbonitrile); Be a kind of wide-spectrum bactericide, can with the combined with protein of cysteine in the glyceraldehyde 3-phosphate dehydro-genase among the fungal cell, destroy metabolism and the loss of life power of cell.It mainly acts on is the prevention fungal infection, inhales conduction in not having, but at plant surface good adhesivity is arranged, and is not subject to rain drop erosion, and the long drug effect phase is arranged.Tpn is used for control like various crop fungal diseases such as paddy rice, wheat, cotton, potato, tomato, pimento, corn, peanut, mango, grape, apple, pear tree, oranges and tangerines, lichee, longans, particularly rust, anthracnose, powdery mildew, downy mildew on fruit tree, the vegetables is had outstanding control efficiency.
Metalaxyl, chemical name: N-(methoxy acetyl group)-N-(2, the 6-xylyl)-DL-methyl lactamine; Belong to the efficient systemic fungicide of amide-type, can interior inspiration go in the plant, the general bactericide of water-soluble ratio is much higher; Can penetrate the cell membrane of the little oomycetes of lipophilicity, play bactericidal action.Therefore, metalaxyl has the selectivity special efficacy to downy mildew in the Oomycete and phytophthora, for example potato late blight, downy mildew of garpe, hop downy mildew, beet eqpidemic disease, white rust of colza, black shank etc. is all had good control efficiency.
Dimethomorph; Chemical name: (E, Z)-4-[3-(4-chlorphenyl) 3-(3, the 4-Dimethoxyphenyl) acryloyl] morpholine; It is morpholine class broad-spectrum germicide; The Peronosporaceae of phycomycetes and the fungi of Phytophthora are had unique mode of action, mainly are the decomposition that causes the spore cyst wall, thereby make thalline dead.Except that zoospore form and the spore swarm stage, all there is effect in each stage of oomycetes history of life, especially more responsive in the formation stage of sporangiophore and egg spore, under extremely low concentration (＜0.25mg/L) promptly be suppressed.If medication before sporulation promptly can suppress spore fully and produce.The interior absorption of this medicine is extremely strong, and the root dispenser can get into each position of plant through root; Foliage spray, dimethomorph also can get into blade interior, and the germ that does in the object has been invaded in control in time, simultaneously newborn blade is also had desirable protective effect; Include two kinds of active components, can simultaneously form strong effectively diaphragm after using, thereby show the superior efficacy of internal therapentics and outer protection in crop surface.
Propamocarb; Chemical name: N-[3-(dimethylaminopropyl) amino] propyl formate belongs to carbamate fungicide, low toxicity, safety; Has local preferably systemic action; Can be absorbed by root system very soon and upwards be delivered to behind the processing soil and put in order the strain plant, after the cauline leaf spraying is handled, can be played a protective role by rapid absorption of blade; Its mechanism of action is to suppress the phosphoric acid of germ cell membrane component and synthesizing of fatty acid, suppresses mycelial growth and spreads and sporangial formation and spore germination.Propamocarb is a kind of wide-spectrum bactericide; Effective especially to algae Gammaproteobacteria fungi;, fungies such as dish stalk mould, downy mildew, epidemic disease mould, corruption mould mould to tow all have good killing action; Also can make impregnation process and seed protectant, be applicable to various crop such as vegetables such as cucumber, tomato, pimento, lettuce, potato and tobacco, strawberry, flowers, fruit tree.
Fluazinam, chemical name: N-[3-chloro-5-(trifluoromethyl)-2-pyridine radicals]-3-chloro-4-(trifluoromethyl)-2,6-dinitroaniline; The pyridine amine derivative; The dinitroaniline series bactericidal agent, no result of treatment and systemic activity are the protective fungicides of broad-spectrum high efficacy.Very effective to interlink spore genus, Phytophthora, Plasmopara, Sclerotinia and Venturia; Botrytis cinerea for resistance benzimidazole and dicarboximide series bactericidal agent also has good effect, to by the microbial paddy rice damping off of head mold good effect being arranged also.Fluazinam utmost point resistance of rainwater washing against, the longevity of residure is long, has the effect of control phytophagous mites in addition concurrently.Carry the unique effect of compound because β-trifluoromethyl Fampridine partly plays, can suppress sprouting, infiltration, the growth of mycelia and the formation of spore of pathogene spore in the course of infection to the active site of pathogenic bacteria.
Flusilazole has conventional formulations such as missible oil, suspending agent, microemulsion, wetting powder and water dispersible granules at present on the market, but the ultra low volume liquids of Flusilazole is not appeared in the newspapers both at home and abroad as yet; Ultra low volume liquids be a kind of be the pesticide activity component dispersion medium with high boiling oily solvent, add a kind of special finish that suitable cosolvent and auxiliary agent are mixed with.During use,, ultra low volume liquids is atomized into the droplet that particle diameter is 30～100 μ m by ultra low volume sprayer; And in the field diffusion and dispersion, after crop or pest contact, stick to rapidly crop or pest the surface; And, play quick-acting effects rapidly to internal penetration; Simultaneously, make it be difficult for being washed away from crop surface, help the performance of drug effect and prolong medicament action time by rainwater because the character of finish is strong to the adhesiveness of crop.Rice blast acid amides, pyraclostrobin, fluorine ring azoles, metalaxyl, tpn, carbendazim, thiophanate-methyl, fluazinam, white urea cyanogen have missible oil, suspending agent, microemulsion, wetting powder, a water dispersible granules common on the market; But there are long-term single a large amount of uses; Make germ produce very strong resistance, be unfavorable for the further raising of drug effect, increased the difficulty of bacteria-treating; Need to strengthen dosage and spray medicine number of times, not only improved labour intensity but also strengthened the control cost.In addition, a large amount of uses of medicament must cause the residual quantity of environment to increase, and pollute to environment, and do not appear in the newspapers as yet both at home and abroad with the composite ultra low volume liquids of Flusilazole.
Present domestic cultural control damage by disease and insect generally adopts the conventional spray-on process of regular dosage form, and it is that pesticidal preparations is carried out the extermination of disease and insect pest afterwards with big water gaging dilution, and there is many-sided defective in this method of preventing and treating:
1, conventional spray-on process work efficiency is low, and work efficiency is merely 2～5 mu/day per capita usually, is difficult to satisfy the needs of large-scale planting; Along with the enforcement of China's soil circulation policy, the soil presents the trend of intensive management, increasing agricultural planting rich and influential family occurs, and crop contiguous plant area increases; And along with China's aging population and the waste appearance of recruitment, the labour becomes rare resource just gradually, and human cost improves constantly, and agriculture production cost continues to increase; Agricultural production is obviously seasonal, and damage by disease and insect often needs a large amount of manpowers to prevent and treat at short notice.
2, conventional spray-on process prevention and elimination of disease and pests needs big water gaging, and water consumption reaches 450～900L/hm usually
2, and regional away from water source and drought and water shortage a lot, conventional spray-on process is difficult to carry out or can not reaches desirable control efficiency.
3, conventional spray-on process makes the with medicament lasting period short, because conventional spray-on process makes the formulation of with medicament be generally missible oil, aqua, wetting powder, suspending agent, aqueous emulsion etc., has certain defective in the use:
(1) owing to add big water gaging dilution, the concentration of soup is very low, and surface tension is often bigger, and is relatively poor in the crop that wax coat is arranged or the lip-deep adhesiveness of target, wetability, permeability, is difficult to effectively get in crop and the target body, causes preventive effect relatively poor;
(2) in the natural environment of illumination, high temperature, drying, the water in the soup is easy to evaporation, causes medicament only to remain in crop surface, comes off and loses efficacy from crop easily after photodissociation and the drying easily;
(3) mist droplet particle size of conventional spraying is bigger, reaches 200～600 μ m, causes being sprayed onto the lip-deep soup of crop or target and runs off easily.
(4) for a long time, the single and frequent use of pesticide species makes biological target grow with each passing day to the resistance of medicament itself, is unfavorable for the prevention and control to pest.
One Chinese patent application number: 201010253385.4; Name is called to disclose in the patent application document of " a kind of bactericidal composition " by in active component (A) fluazinam and (B) nitrile bacterium azoles, Difenoconazole, Tebuconazole, propiconazole, own azoles alcohol, Flutriafol, metconazole, fluorine ring azoles, Flusilazole, Fluquinconazole, tetraconazole, Triadimenol, triazolone, alkene azoles alcohol, penconazole, the Cyproconazole any one and forms; The mass ratio of A and B is 1: 100～100: 1, and the formulation of said composition is regular dosage forms such as missible oil, microemulsion, aqueous emulsion, suspending agent.Though the said composition preventive effect has improved, needs dilute with big water gaging in the use, and are inapplicable for the water-deficient area, and have the defective of conventional formulation.
One Chinese patent application number: CN201010614877.1; Name is called to disclose in the patent application document of " a kind of composition pesticide that contains metconazole " and the invention discloses a kind of composition pesticide that contains in metconazole and triazole bactericidal agent Flusilazole, fluorine ring azoles, tetraconazole, tricyclazole, the Flutriafol, and the ratio of weight and number of two kinds of active components is 80: 1～1: 80 in the composition pesticide.This invention is to a certain degree improving preventive effect, has delayed resistance speed, has lowered use cost, but is prepared into regular dosage form, has the defective of regular dosage form.
Summary of the invention
The objective of the invention is provides a kind of ultra low volume liquids of fluorine silicon azoles in order to solve deficiency of the prior art, and its water consumption is few, and work efficiency is strong, and is safe, can effectively save the labour, reduces labor intensity.
Technical scheme of the present invention: the ultra low volume liquids of fluorine silicon azoles is by with Flusilazole, or Flusilazole and active component B composite be active component, add auxiliary agent and solvent and be prepared into ultra low volume liquids; Active component B is any one in Difenoconazole, own azoles alcohol, propiconazole, Tebuconazole, Flutriafol, nitrile bacterium azoles, Isoprothiolane, thifluzamide, rice blast acid amides, pyraclostrobin, metalaxyl, tpn, carbendazim, thiophanate-methyl, fluazinam, white urea cyanogen, Boscalid, iprodione, prothioconazoles, probenazole, ZEN 90160, ether bacterium amine, fluoxastrobin, tetraconazole, metconazole, dimethomorph, the Propamocarb.
The percentage by weight of described each component of ultra low volume liquids is:
The preferred boiling point of said solvent is higher than 160 ℃, flash-point and is higher than 60 ℃ solvent, and solvent is one or more combinations in aromatic hydrocarbon solvent, plant oil solvent and the polar solvent;
(1) aromatic hydrocarbon solvent that is fit to comprises trimethylbenzene, o-dichlorohenzene, the above aromatic hydrocarbons of C10 such as durene, diethylbenzene, methyl-propyl benzene, butylbenzene, methyl naphthalene, two wires oil;
(2) the plant oil solvent that is fit to comprises soybean oil, cottonseed oil, rapeseed oil, castor oil, turpentine oil, esterified vegetable oil such as methyl oleate, ethyl oleate;
(3) the polar solvent solvent that is fit to comprises acetophenone, phenmethylol, methyl-sulfoxide, N-Methyl pyrrolidone, N, dinethylformamide, DMAC N,N, the above alcohols of C6 such as n-hexyl alcohol, n-octyl alcohol, terpineol.
Said auxiliary agent comprises surfactant, synergist, bleeding agent etc.; Mainly be used for improving adhesiveness, wetability and the permeability of preparation to crop and target; Enhancing crop and target reduce the volatility of solvent to the absorption of medicament, improve stability of formulation; Reduce the viscosity of preparation, thereby play the effect that improves drug effect.
Surfactant is selected from one or more the combination in AEO, APES, phenethyl phenol polyethenoxy ether, alkylaryl polyoxyethylene polyoxypropylene ether, aliphatic alcohol polyoxyvinethene phosphate, APES phosphate, phenethyl phenol polyethenoxy ether phosphate, alkylaryl polyoxyethylene polyoxypropylene ether phosphate, castor oil polyoxyethylene ether, the calcium dodecyl benzene sulfonate, preferred fat alcohol APEO, APES, phenethyl phenol polyethenoxy ether, alkylaryl polyoxyethylene polyoxypropylene ether, castor oil polyoxyethylene ether, calcium dodecyl benzene sulfonate.
Synergist is selected from one or more combination of synergy phosphorus, sulfoxide, piperonyl butoxide etc.
Bleeding agent is selected from azone, thiophene ketone, oozes one or more the combination of T soon, and the described T that oozes soon can directly buy on market, also is fast penetrant T or fast T.
The ultra low volume liquids preparation method of fluorine silicon azoles of the present invention is at normal temperatures and pressures; In the reaction vessel with active component and the stirring of solvent input band, low whipping speed is under 60～150 rev/mins, and solvent is with the active component stirring and dissolving; Add auxiliary component again; Fully stirred 15～60 minutes, it is mixed, obtain fluorine silicon azoles ultra low volume liquids.
The present invention is suitably in banded sclerotial blight, scab, powdery mildew and the anthracnose of crops such as control paddy rice, fruit tree, vegetables and uses.
Application process of the present invention is ultra low volume spraying, low-gallonage spraying or ultra low volume electrostatic spray; Usually spray with ultra low volume sprayer,, also can add the low amounts of water dilution and carry out low-gallonage spraying perhaps with the electrostatic atomiser spraying.
The invention has the beneficial effects as follows:
1. water-saving, the present invention blends with adding water in the process of spraying hardly, but directly medicament is sprayed onto on the blade and stem stalk of crop, and the damage by disease and insect target that goes directly makes things convenient for away from water source and the regional dispenser of drought and water shortage.
2. work efficiency is high, through using the ultra low volume sprayer dispenser, can increase substantially efficient, improve work efficiency several times to tens times, reduce cost of labor, effectively lower labour intensity, can prevent and treat explosive insect timely and effectively.
3. drug concentration is high, and the lasting period is long.The content of conventional dose own is high; It is low to blend the soup units activity component content that sprays after the water, and ultra low volume is directly with reagent spray, and the active component content of medicament own is low; But the units activity constituent concentration content of spraying liquor is high, helps improving drug effect; Secondly, ultra low volume adopts low-volatile oil to make solvent, and active component is penetrated into the blade deep layer, and resistance of rainwater washing against prolongs the lasting period, thereby reduces the medication number of times, reduces agricultural cost.
4. Synergistic: Flusilazole is a kind of triazole bactericidal agent, can play synergistic function with the bactericide compounded of other different effects mechanism, and expanding prevention target spectrum delays the pesticide resistance of germ, reduces the pollution of environment.
5. saving agricultural chemicals.Compare with the routine spraying, generally can save agricultural chemicals more than 30%.
6. safe, the ultra low volume finish is to crop safety, and its active component does not adopt severe toxicity and high-toxic pesticide, also is comparatively safe to the people.
Embodiment
For a better understanding of the present invention, specify technology contents of the present invention with instance below, but do not limit the scope of the invention.
Instance 1
1% Flusilazole ultra low volume liquids
Press following weight proportion:
Preparation method: in reaction vessel with electronic stirring; Normal temperature and pressure press down formula rate first with solvent with active component Flusilazole stirring and dissolving; Mixing speed is controlled to be 60 rev/mins, adds auxiliary component again, fully stirs 60 minutes; It is mixed, obtain 1% Flusilazole ultra low volume liquids.
Instance 2
3% Flusilazole ultra low volume liquids
Press following weight proportion:
The preparation method: in reaction vessel with electronic stirring, normal temperature press down formula rate first with solvent with active component Flusilazole stirring and dissolving, mixing speed is controlled to be 120 rev/mins; Add auxiliary component again; Fully stirred 30 minutes, it is mixed, obtain 3% Flusilazole ultra low volume liquids.
Instance 3
6% Flusilazole ultra low volume liquids
Press following weight proportion:
The preparation method: in reaction vessel with electronic stirring, normal temperature press down formula rate first with solvent with active component Flusilazole stirring and dissolving, mixing speed is controlled to be 100 rev/mins; Add auxiliary component again; Fully stirred 45 minutes, it is mixed, obtain 6% Flusilazole ultra low volume liquids.
Instance 4
10% Flusilazole ultra low volume liquids
Press following weight proportion:
Preparation method: in reaction vessel with electronic stirring; Normal temperature press down formula rate first with solvent with active component Flusilazole stirring and dissolving; Mixing speed is controlled to be 150 rev/mins, adds auxiliary component again, fully stirs 15 minutes; It is mixed, obtain 10% Flusilazole ultra low volume liquids.
Instance 5
8% Flusilazole Difenoconazole ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 2
Instance 6
15% Flusilazole Difenoconazole ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 3
Instance 7
25% Flusilazole Difenoconazole ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 4
Instance 8
The own azoles alcohol of 8% Flusilazole ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 2
Instance 9
The own azoles alcohol of 15% Flusilazole ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 3
Instance 10
The own azoles alcohol of 27% Flusilazole ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 4
Instance 11
8% Flusilazole propiconazole ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 2
Instance 12
13% Flusilazole propiconazole ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 3
Instance 13
22% Flusilazole propiconazole ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 4
Instance 14
6% Flusilazole Tebuconazole ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 2
Instance 15
12% Flusilazole Tebuconazole ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 3
Instance 16
24% Flusilazole Tebuconazole ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 4
Instance 17
7% Flusilazole Isoprothiolane ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 2
Instance 18
13% Flusilazole Isoprothiolane ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 3
Instance 19
20% Flusilazole Isoprothiolane ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 4
Instance 20
7% Flusilazole thifluzamide ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 2
Instance 21
13% Flusilazole thifluzamide low capacity liquor
Press following weight proportion:
The preparation method is with embodiment 3
Instance 22
25% Flusilazole thifluzamide low capacity liquor
Press following weight proportion:
The preparation method is with embodiment 4
Instance 23
6% Flusilazole rice blast acid amides ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 4
Instance 24
12% Flusilazole rice blast acid amides ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 3
Instance 25
19% Flusilazole rice blast acid amides ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 2
Instance 26
5% Flusilazole pyraclostrobin ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 2
Instance 27
11% Flusilazole pyraclostrobin ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 3
Instance 28
13% Flusilazole pyraclostrobin ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 4
Instance 29
9% Flusilazole metalaxyl ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 2
Instance 30
13% Flusilazole metalaxyl ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 3
Instance 31
19% Flusilazole metalaxyl ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 4
Instance 32
8% Flusilazole tpn ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 2
Instance 33
10% Flusilazole tpn ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 3
Instance 34
17% Flusilazole tpn ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 4
Instance 35
10% Flusilazole carbendazim ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 4
Instance 36
15% Flusilazole carbendazim ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 3
Instance 37
25% Flusilazole carbendazim ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 2
Instance 38
6% Flusilazole thiophanate-methyl ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 2
Instance 39
10% Flusilazole thiophanate-methyl ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 3
Instance 40
13% Flusilazole thiophanate-methyl ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 4
Instance 41
6% Flusilazole fluazinam ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 2
Instance 42
10% Flusilazole fluazinam ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 3
Instance 43
16% Flusilazole fluazinam ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 4
Instance 44
4% Flusilazole frost urea cyanogen ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 3
Instance 45
11% Flusilazole frost urea cyanogen ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 4
Instance 46
8% Flusilazole Boscalid ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 4
Instance 47
13% Flusilazole Boscalid ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 3
Instance 48
6% Flusilazole iprodione ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 3
Instance 49
12% Flusilazole iprodione ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 2
Instance 50
7% Flusilazole prothioconazoles ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 3
Instance 51
15% Flusilazole prothioconazoles low capacity liquor
Press following weight proportion:
The preparation method is with embodiment 3
Instance 52
7% Flusilazole probenazole ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 4
Instance 53
16% Flusilazole probenazole low capacity liquor
Press following weight proportion:
The preparation method is with embodiment 4
Instance 54
4% Flusilazole ZEN 90160 ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 2
Instance 55
10% Flusilazole ZEN 90160 ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 2
Instance 56
8% Flusilazole ether bacterium amine ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 3
Instance 57
11% Flusilazole ether bacterium amine ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 3
Instance 58
7% Flusilazole fluoxastrobin ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 4
Instance 59
14% Flusilazole fluoxastrobin ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 4
Instance 60
5.5% Flusilazole tetraconazole ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 3
Instance 61
15% Flusilazole tetraconazole ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 3
Instance 62
5% Flusilazole Flutriafol ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 2
Instance 63
13% Flusilazole Flutriafol ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 2
Instance 64
4% Flusilazole metconazole ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 3
Instance 65
12% Flusilazole metconazole ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 3
Instance 66
8% Flusilazole dimethomorph ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 4
Instance 67
11% Flusilazole dimethomorph ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 4
Instance 68
8% Flusilazole nitrile bacterium azoles ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 3
Instance 69
16% Flusilazole nitrile bacterium azoles ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 3
Instance 70
5.5% Flusilazole Propamocarb ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 3
Instance 71
10% Flusilazole Propamocarb ultra low volume liquids
Press following weight proportion:
The preparation method is with embodiment 3
More than each instance ultra low volume liquids be the oily liquids of outward appearance homogeneous transparent.
4 Flusilazole ultra low volume liquids that instance 1～4 of the present invention is obtained and 40% Flusilazole EC and 10% Flusilazole EW carry out field control effectiveness test, establish one-tenth pear tree in age 5 strains in 3 years of each cell selecting field planting, repeat 4 times; 7 days, 14 days investigation preventive effects behind the medicine, the method for investigation drug effect is: 5 strains are investigated in each sub-district, and every strain is got a point by east, south, west, north, middle direction, and total strain number and diseased plant number at different levels are write down in every some investigation 2 strains, the occurrence degree of inspection pear scab.Result of the test such as table 1:
The control efficiency of table 1 pair pear scab
Field test results shows that the ultra low volume liquids of Flusilazole is better than missible oil and aqueous emulsion to the preventive effect of pear scab, and lasting effect more is superior to missible oil and aqueous emulsion.
Test Example 2: the ultra low volume liquids of Flusilazole and carbendazim is prevented and treated the field trial of powdery mildew of cucumber.
Two kinds of ultra low volume liquids that instance 35,37 of the present invention is obtained and 40% Flusilazole EC and 40% silicon azoles carbendazim SC carry out field control effectiveness test, establish the cucumber ground 40m that each cell selecting was transplanted 2 months
2, repeat 4 times; 14 days investigation preventive effects behind the medicine, the method for investigation drug effect is: 5 samplings of each sub-district diagonal, the total number of sheets and the sick number of sheets at different levels are write down in every some investigation 3 strains, the occurrence degree of inspection powdery mildew of cucumber.Result of the test such as table 2:
The control efficiency of table 2 pair powdery mildew of cucumber
Field test results shows that the ultra low volume liquids of Flusilazole and carbendazim composition can effectively be prevented and treated powdery mildew of cucumber, and effect is superior to the control efficiency that Flusilazole is obeyed oily single agent and Flusilazole and the composite suspending agent of carbendazim.
Test Example 3: the ultra low volume liquids of Flusilazole and tpn is prevented and treated the field trial of sigatoka.
Two kinds of mixtures and 40% Flusilazole (EC), 40% tpn (SC) that instance 32,33 of the present invention is obtained carry out field control effectiveness test, establish high banana 5 strains of the 1m in 2 years of each cell selecting field planting, repeat 4 times; 14 days investigation preventive effects behind the medicine, the method for investigation drug effect is: two strains are investigated in each sub-district, and every strain is got a point by east, south, west, north, middle direction, and the total number of sheets and the sick number of sheets at different levels are write down in every some investigation 2 strains, the occurrence degree of inspection leaf spot.Result of the test such as table 3:
The control efficiency of table 3 pair sigatoka
Field test results shows that the ultra low volume liquids of Flusilazole and tpn composition can effectively be prevented and treated sigatoka, and effect is superior to the control efficiency of tpn or the agent of Flusilazole list.
Test Example 4: the ultra low volume liquids of Flusilazole and own azoles alcohol is prevented and treated the field trial of rice sheath blight disease.
Three kinds of mixtures and 30% kresoxim-methyl SC, 50% kresoxim-methyl WGD that instance 7～8 of the present invention is obtained carry out field control effectiveness test, and establishing each sub-district area is rice area 60m
2, repeat 3 times; 15 days investigation preventive effects, the method for investigation drug effect is: 5 pockets are investigated in each sub-district, and every pocket is got a point by east, south, west, north, middle direction, and total strain number and diseased plant number at different levels are write down in every some investigation 2 strains, the occurrence degree of inspection banded sclerotial blight.Result of the test such as table 4:
The control efficiency of table 4 pair rice sheath blight disease
Field test results shows that the ultra low volume liquids of Flusilazole and own azoles alcohol composition can effectively be prevented and treated rice sheath blight disease, and effect is superior to the control efficiency of own azoles alcohol or the agent of Flusilazole list.
Claims (8)
1. the ultra low volume liquids of a fluorine silicon azoles is characterized in that: it is with Flusilazole, or Flusilazole and active component B composite be active component, add auxiliary agent and solvent and be prepared into ultra low volume liquids; Active component B is any one in Difenoconazole, own azoles alcohol, propiconazole, Tebuconazole, Flutriafol, nitrile bacterium azoles, Isoprothiolane, thifluzamide, rice blast acid amides, pyraclostrobin, metalaxyl, tpn, carbendazim, thiophanate-methyl, fluazinam, white urea cyanogen, Boscalid, iprodione, prothioconazoles, probenazole, ZEN 90160, ether bacterium amine, fluoxastrobin, tetraconazole, metconazole, dimethomorph, the Propamocarb.
2. the ultra low volume liquids of fluorine silicon azoles according to claim 1 is characterized in that: the percentage by weight between each component of described ultra low volume liquids is:
Flusilazole 1%～10%
Active component B 0～20%
Auxiliary agent 1%～15%
The solvent surplus.
3. the ultra low volume liquids of fluorine silicon azoles according to claim 1; It is characterized in that: the preferred boiling point of said solvent is higher than 160 ℃, flash-point and is higher than 60 ℃ solvent, and solvent is one or more combinations in aromatic hydrocarbon solvent, plant oil solvent and the polar solvent; Aromatic hydrocarbon solvent comprises trimethylbenzene, o-dichlorohenzene, the above heavy aromatics of C10; The plant oil solvent comprises soybean oil, cottonseed oil, rapeseed oil, castor oil, turpentine oil, esterified vegetable oil; Polar solvent comprises acetophenone, phenmethylol, methyl-sulfoxide, N-Methyl pyrrolidone, N, dinethylformamide, DMAC N,N, the above alcohols of C6.
4. the ultra low volume liquids of fluorine silicon azoles according to claim 3 is characterized in that: the above heavy aromatics of said C10 comprises durene, diethylbenzene, methyl-propyl benzene, butylbenzene, methyl naphthalene, two wires oil; Said esterified vegetable oil comprises methyl oleate, ethyl oleate; The above alcohols of said C6 comprises n-hexyl alcohol, n-octyl alcohol, terpineol.
5. the ultra low volume liquids of fluorine silicon azoles according to claim 1 is characterized in that: said auxiliary agent comprises surfactant, synergist, bleeding agent; Surfactant is one or more the combination in AEO, APES, phenethyl phenol polyethenoxy ether, alkylaryl polyoxyethylene polyoxypropylene ether, aliphatic alcohol polyoxyvinethene phosphate, APES phosphate, phenethyl phenol polyethenoxy ether phosphate, alkylaryl polyoxyethylene polyoxypropylene ether phosphate, castor oil polyoxyethylene ether, the calcium dodecyl benzene sulfonate; Synergist is one or more the combination in synergy phosphorus, sulfoxide, the piperonyl butoxide; Bleeding agent is azone, thiophene ketone, oozes one or more combination among the T soon.
6. the ultra low volume liquids of fluorine silicon azoles according to claim 1 is characterized in that: the preparation method of said ultra low volume liquids is at normal temperatures and pressures, in the reaction vessel with active component and the stirring of solvent input band; Low whipping speed is under 60～150 rev/mins; Solvent adds auxiliary component again with the active component stirring and dissolving, fully stirs 15～60 minutes; It is mixed, obtain fluorine silicon azoles ultra low volume liquids.
7. the ultra low volume liquids of fluorine silicon azoles according to claim 1 is characterized in that: its application in banded sclerotial blight, scab, powdery mildew and the anthracnose of crops such as control paddy rice, fruit tree, vegetables.
8. the ultra low volume liquids of fluorine silicon azoles according to claim 1 is characterized in that: its application process is ultra low volume spraying, low-gallonage spraying or ultra low volume electrostatic spray.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110269638.1A CN102349506B (en) | 2011-09-13 | 2011-09-13 | Ultralow-volume solvent containing Flusilazole |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110269638.1A CN102349506B (en) | 2011-09-13 | 2011-09-13 | Ultralow-volume solvent containing Flusilazole |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102349506A true CN102349506A (en) | 2012-02-15 |
| CN102349506B CN102349506B (en) | 2014-07-09 |
Family
ID=45573234
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110269638.1A Expired - Fee Related CN102349506B (en) | 2011-09-13 | 2011-09-13 | Ultralow-volume solvent containing Flusilazole |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102349506B (en) |
Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102657183A (en) * | 2012-04-12 | 2012-09-12 | 广西田园生化股份有限公司 | Thifluzamide-containing ultra low volume liquid formulation |
| CN102669160A (en) * | 2012-04-28 | 2012-09-19 | 广东中迅农科股份有限公司 | Sterilization composite containing thifluzamide and flusilazole |
| CN102696619A (en) * | 2012-05-23 | 2012-10-03 | 钦州学院 | Ultra-low volume (ULV) liquid comprising fenpyroximate and triazoles bactericide |
| CN103636641A (en) * | 2013-11-19 | 2014-03-19 | 广西田园生化股份有限公司 | Ultra-low volume liquid containing cymoxanil |
| CN103651432A (en) * | 2013-12-13 | 2014-03-26 | 广西田园生化股份有限公司 | Ultra-low volume liquid containing ametoctradin and benzamide fungicide composition and preparation method of ultra-low volume liquid |
| CN103651431A (en) * | 2013-12-13 | 2014-03-26 | 广西田园生化股份有限公司 | Ultra-low volume liquid containing ametoctradin and strobilurin fungicide composition as well as preparation method and application of ultra-low volume liquid |
| CN103651393A (en) * | 2012-09-19 | 2014-03-26 | 陕西美邦农药有限公司 | Bactericidal composition containing dimoxystrobin and triazole |
| CN103688963A (en) * | 2013-12-13 | 2014-04-02 | 广西田园生化股份有限公司 | Ultra-low volume liquid containing ametoctradin composition and preparation method thereof |
| CN103704225A (en) * | 2013-12-13 | 2014-04-09 | 广西田园生化股份有限公司 | Ultralow-volume liquid of ametoctradin and phenyl and o-phthalimide-containing fungicide composition, and preparation method thereof |
| CN103719107A (en) * | 2013-12-13 | 2014-04-16 | 广西田园生化股份有限公司 | Ultra-low-volume liquor containing picoxystrobin and sterol synthesis inhibitor |
| CN103719108A (en) * | 2013-12-13 | 2014-04-16 | 广西田园生化股份有限公司 | Ultra-low volume liquid containing picoxystrobin and morpholine bactericide and application thereof |
| CN103798237A (en) * | 2013-11-19 | 2014-05-21 | 广西田园生化股份有限公司 | Ultra-low-volume liquid agent containing boscalid |
| CN103798242A (en) * | 2013-11-19 | 2014-05-21 | 广西田园生化股份有限公司 | Ultra-low volume liquid agent containing boscalid and triazole fungicide |
| CN103999874A (en) * | 2014-05-28 | 2014-08-27 | 甘肃省农业科学院植物保护研究所 | Grease ointment, preparation method and application of grease ointment |
| CN104872171A (en) * | 2015-04-07 | 2015-09-02 | 河南中天恒信生物化学科技有限公司 | Paddy field composite bactericide containing flutriafol, isoprothiolane and flusilazole, and application thereof |
| CN106135265A (en) * | 2015-04-13 | 2016-11-23 | 南京华洲药业有限公司 | A kind of containing Boscalid and the bactericidal composition of bis(4-fluorophenyl)methyl(1H-1,2,4-triazol-1-ylmethyl)silane and application |
| CN107027803A (en) * | 2017-06-19 | 2017-08-11 | 福建省农业科学院植物保护研究所 | Microbicide compositions and its application containing Flusilazole and olefin conversion |
| CN107593755A (en) * | 2017-09-01 | 2018-01-19 | 中国热带农业科学院环境与植物保护研究所 | A kind of preparation method of aqueous emulsion |
| CN107593694A (en) * | 2017-09-01 | 2018-01-19 | 中国热带农业科学院环境与植物保护研究所 | A kind of aqueous emulsion |
| CN107950561A (en) * | 2017-12-13 | 2018-04-24 | 仲恺农业工程学院 | 30% pyraclostrobin-flusilazole missible oil and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0280431A1 (en) * | 1987-02-07 | 1988-08-31 | Schering Agrochemicals Limited | Fungicidal mixtures with prochloraz |
| CN1810115A (en) * | 2006-01-11 | 2006-08-02 | 天津久日化学工业有限公司 | Flusilazole-and kresoxim methyl bactericide composition and its prepn process |
| CN101743974A (en) * | 2010-01-13 | 2010-06-23 | 海南大学 | Propiconazole ultra-low volume preparation and preparation method thereof |
| CN102067878A (en) * | 2011-02-23 | 2011-05-25 | 广西田园生化股份有限公司 | Ultra-low-volume liquid preparation containing carbosulfan |
-
2011
- 2011-09-13 CN CN201110269638.1A patent/CN102349506B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0280431A1 (en) * | 1987-02-07 | 1988-08-31 | Schering Agrochemicals Limited | Fungicidal mixtures with prochloraz |
| CN1810115A (en) * | 2006-01-11 | 2006-08-02 | 天津久日化学工业有限公司 | Flusilazole-and kresoxim methyl bactericide composition and its prepn process |
| CN101743974A (en) * | 2010-01-13 | 2010-06-23 | 海南大学 | Propiconazole ultra-low volume preparation and preparation method thereof |
| CN102067878A (en) * | 2011-02-23 | 2011-05-25 | 广西田园生化股份有限公司 | Ultra-low-volume liquid preparation containing carbosulfan |
Non-Patent Citations (1)
| Title |
|---|
| 周本新 等: "《农药新剂型》", 31 January 1997, 化学工业出版社 * |
Cited By (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102657183A (en) * | 2012-04-12 | 2012-09-12 | 广西田园生化股份有限公司 | Thifluzamide-containing ultra low volume liquid formulation |
| CN102669160A (en) * | 2012-04-28 | 2012-09-19 | 广东中迅农科股份有限公司 | Sterilization composite containing thifluzamide and flusilazole |
| CN102696619A (en) * | 2012-05-23 | 2012-10-03 | 钦州学院 | Ultra-low volume (ULV) liquid comprising fenpyroximate and triazoles bactericide |
| CN103651393A (en) * | 2012-09-19 | 2014-03-26 | 陕西美邦农药有限公司 | Bactericidal composition containing dimoxystrobin and triazole |
| CN103798242A (en) * | 2013-11-19 | 2014-05-21 | 广西田园生化股份有限公司 | Ultra-low volume liquid agent containing boscalid and triazole fungicide |
| CN103798237A (en) * | 2013-11-19 | 2014-05-21 | 广西田园生化股份有限公司 | Ultra-low-volume liquid agent containing boscalid |
| CN103636641A (en) * | 2013-11-19 | 2014-03-19 | 广西田园生化股份有限公司 | Ultra-low volume liquid containing cymoxanil |
| CN103798242B (en) * | 2013-11-19 | 2015-08-12 | 广西田园生化股份有限公司 | Containing the ultra low volume liquids of Boscalid and triazole bactericidal agent |
| CN103798237B (en) * | 2013-11-19 | 2015-09-09 | 广西田园生化股份有限公司 | A kind of ultra low volume liquids containing Boscalid |
| CN103651432A (en) * | 2013-12-13 | 2014-03-26 | 广西田园生化股份有限公司 | Ultra-low volume liquid containing ametoctradin and benzamide fungicide composition and preparation method of ultra-low volume liquid |
| CN103688963A (en) * | 2013-12-13 | 2014-04-02 | 广西田园生化股份有限公司 | Ultra-low volume liquid containing ametoctradin composition and preparation method thereof |
| CN103704225A (en) * | 2013-12-13 | 2014-04-09 | 广西田园生化股份有限公司 | Ultralow-volume liquid of ametoctradin and phenyl and o-phthalimide-containing fungicide composition, and preparation method thereof |
| CN103719107A (en) * | 2013-12-13 | 2014-04-16 | 广西田园生化股份有限公司 | Ultra-low-volume liquor containing picoxystrobin and sterol synthesis inhibitor |
| CN103719108A (en) * | 2013-12-13 | 2014-04-16 | 广西田园生化股份有限公司 | Ultra-low volume liquid containing picoxystrobin and morpholine bactericide and application thereof |
| CN103651431A (en) * | 2013-12-13 | 2014-03-26 | 广西田园生化股份有限公司 | Ultra-low volume liquid containing ametoctradin and strobilurin fungicide composition as well as preparation method and application of ultra-low volume liquid |
| CN103999874B (en) * | 2014-05-28 | 2018-06-19 | 甘肃省农业科学院植物保护研究所 | A kind of grease paste and its preparation method and application |
| CN103999874A (en) * | 2014-05-28 | 2014-08-27 | 甘肃省农业科学院植物保护研究所 | Grease ointment, preparation method and application of grease ointment |
| CN104872171A (en) * | 2015-04-07 | 2015-09-02 | 河南中天恒信生物化学科技有限公司 | Paddy field composite bactericide containing flutriafol, isoprothiolane and flusilazole, and application thereof |
| CN106135265A (en) * | 2015-04-13 | 2016-11-23 | 南京华洲药业有限公司 | A kind of containing Boscalid and the bactericidal composition of bis(4-fluorophenyl)methyl(1H-1,2,4-triazol-1-ylmethyl)silane and application |
| CN107027803A (en) * | 2017-06-19 | 2017-08-11 | 福建省农业科学院植物保护研究所 | Microbicide compositions and its application containing Flusilazole and olefin conversion |
| CN107593755A (en) * | 2017-09-01 | 2018-01-19 | 中国热带农业科学院环境与植物保护研究所 | A kind of preparation method of aqueous emulsion |
| CN107593694A (en) * | 2017-09-01 | 2018-01-19 | 中国热带农业科学院环境与植物保护研究所 | A kind of aqueous emulsion |
| CN107593755B (en) * | 2017-09-01 | 2020-05-19 | 中国热带农业科学院环境与植物保护研究所 | Preparation method of aqueous emulsion |
| CN107593694B (en) * | 2017-09-01 | 2020-07-24 | 中国热带农业科学院环境与植物保护研究所 | Aqueous emulsion |
| CN107950561A (en) * | 2017-12-13 | 2018-04-24 | 仲恺农业工程学院 | 30% pyraclostrobin-flusilazole missible oil and preparation method thereof |
| CN107950561B (en) * | 2017-12-13 | 2020-08-04 | 仲恺农业工程学院 | 30% pyraclostrobin-flusilazole missible oil and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102349506B (en) | 2014-07-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102349506B (en) | Ultralow-volume solvent containing Flusilazole | |
| CN102273441B (en) | Ultralow volume liquid containing azoxystronbin | |
| CN102379304B (en) | Pyraclostrobin-containing ultralow-volume liquid preparation | |
| CN102273443B (en) | Superlow-capacity liquid reagent containing ethofenprox | |
| CN102379292A (en) | Super low volume liquid formulation containing trifloxystrobin | |
| CN102273442A (en) | Ultralow volume liquid containing epoxiconazole | |
| CN102640748A (en) | Ultra-low-volume liquid containing prothioconazole | |
| CN102273445A (en) | Superlow-capacity liquid reagent containing prochloraz | |
| CN101548677B (en) | Sterilizing compound of ethirimol and triazole | |
| CN102177912A (en) | Pesticide composite containing pyraclostrobin | |
| CN102017961B (en) | Bactericidal composition containing tridemorph | |
| WO2018037361A1 (en) | Miticidal, insecticidal and nematocidal compositions containing plants extracts from bulnesia sp and humulus sp | |
| CN104322558A (en) | Sterilization composition and applications thereof | |
| CN102308825A (en) | Germicide composition in combination with bupirimate | |
| CN103348982B (en) | A kind of Fungicidal mixture | |
| CN103719123A (en) | Ultra-low volume liquid containing composite of pyraclostrobin and morpholine bactericide | |
| CN102626080A (en) | Ultralow-volume liquid containing cyprodinil | |
| CN103651368A (en) | Ultra-low-volume liquid containing picoxystrobin and preparation method of ultra-low-volume liquid | |
| CN103719108A (en) | Ultra-low volume liquid containing picoxystrobin and morpholine bactericide and application thereof | |
| CN106857511A (en) | A kind of microbicide compositions comprising emodin derivates Yu pyrazol acid amide compounds | |
| CN106070236A (en) | A kind of containing kind of bacterium azoles and the bactericidal composition of Tebuconazole and application | |
| CN102626081B (en) | Ultralow-volume liquid for preventing and treating oomycetes disease | |
| CN102204542A (en) | Bactericidal composition containing enostroburin and triazole compound | |
| CN102007929B (en) | Thifluzamide-containing bactericidal composition | |
| CN105494359B (en) | A kind of composite bactericide for preventing and treating wheat scab and its application |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20140709 |