CN102696619A - Ultra-low volume (ULV) liquid comprising fenpyroximate and triazoles bactericide - Google Patents
Ultra-low volume (ULV) liquid comprising fenpyroximate and triazoles bactericide Download PDFInfo
- Publication number
- CN102696619A CN102696619A CN2012101618271A CN201210161827A CN102696619A CN 102696619 A CN102696619 A CN 102696619A CN 2012101618271 A CN2012101618271 A CN 2012101618271A CN 201210161827 A CN201210161827 A CN 201210161827A CN 102696619 A CN102696619 A CN 102696619A
- Authority
- CN
- China
- Prior art keywords
- low volume
- ultra low
- mite ester
- azoles
- oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses an ultra-low volume (ULV) liquid comprising fenpyroximate and triazoles bactericide. The liquid comprises (by weight) 0.5-10% of fenpyroximate, 0.5-15% of triazoles bactericide, 1-15% of surfactant, and the balance of solvent. The triazoles bactericide is selected from any one of epoxiconazole, hexaconazole, propiconazole, flutriafol, metconazole and myclobutanil. The inventive ULV liquid combines fenpyroximate and above selected broad spectrum triazoles bactericide as effective ingredients, to realize rapid pest killing, good and lasting effects. The liquid provided by the invention is applicable to prevent and control Tetranychus cinnabarinns (Boisduval) and Panonychus on various plants; and also has good effects in preventing and controlling pests (such as Plutella xylostella, Prodenia litura, striped rice borer, rice planthopper and Myzus persicae) and diseases (such as rice blast, anthracnose, powdery mildew and downy mildew).
Description
Technical field
The present invention relates to technical field of pesticide, be specifically related to a kind of ultra low volume liquids that contains azoles mite ester and triazole bactericidal agent.
Background technology
Ultra low volume liquids is the pesticidal preparations that is applicable to that ultra low volume spraying is used; Ultra low volume spraying is to follow the appearance of ultra low volume sprayer tool and an advanced person's producing applications of pesticide new technology; Because of its droplet is the uniform oiliness droplet of fineness; Be prone to stick on the crops, the elegant loss of droplet is little, so the agricultural chemicals utilization ratio is high.
Mostly active component in the existing disclosed ultra low volume liquids is Fluoxastrobin, pyraclostrobin and kresoxim-methyl; Or they respectively with the combination of other bactericide; Like publication number is that the patent of invention of CN102273441A discloses a kind of ultra low volume liquids that contains Fluoxastrobin; Be to be active component with the Fluoxastrobin; Or with Fluoxastrobin and the composite composition active component of active component II; The ultra low volume liquids that adds auxiliary agent and solvent, described active component II are any one or any two kinds of compositions in Prochloraz, prothioconazoles, Difenoconazole, fluorine ring azoles, propiconazole, own azoles alcohol, Tebuconazole, tpn, Isoprothiolane, IBP, thifluzamide and the rice blast acid amides.Wherein, when ultra low volume liquids only was active component with the Fluoxastrobin, the percentage by weight of each component was: Fluoxastrobin is 0.1%～20%, and auxiliary agent is 1%～15%, and solvent complements to 100%; When ultra low volume liquids during with a kind of composite composition active component in Fluoxastrobin and the active component II, the percentage by weight of each component is: Fluoxastrobin is 0.5%～10%, and the active component II is 1%～25%, and auxiliary agent is 1%～15%, and solvent complements to 100%; When ultra low volume liquids during with any two kinds of composite composition active components of Fluoxastrobin and active component II; The percentage by weight of each component is: Fluoxastrobin is 0.5%～10%; Any one composition in the described active component II is 1%～15%, and auxiliary agent is 1%～15%, and solvent complements to 100%.This ultra low volume liquids is bactericide compounded with kresoxim-methyl and other, has drug effect preferably.But do not see at present the relevant report that the ultra low volume liquids that azoles mite ester and triazole bactericidal agent is composite is arranged as yet.
Summary of the invention
The technical problem that the present invention will solve provides a kind of ultra low volume liquids that contains azoles mite ester and triazole bactericidal agent.This ultra low volume liquids desinsection is rapid, drug effect better and hold imitate long.
The ultra low volume liquids that contains azoles mite ester and triazole bactericidal agent of the present invention, process by following weight percentages:
Azoles mite ester 0.5～10%;
Triazole bactericidal agent 0.5～15%;
Surfactant 1～15%;
The solvent surplus;
Wherein, triazole bactericidal agent is selected from any one in fluorine ring azoles, own azoles alcohol, propiconazole, Flutriafol, metconazole and the nitrile bacterium azoles.
The percentage by weight of above-mentioned each raw material is preferably:
Azoles mite ester 3～8%;
Triazole bactericidal agent 4～10%;
Surfactant 3～10%;
The solvent surplus.
In the technique scheme:
Described surfactant is selected among APES, AEO, castor oil polyoxyethylene ether, agricultural newborn 500# (calcium dodecyl benzene sulfonate), agricultural newborn 600# (phenethyl phenol polyethenoxy ether) and the Nongru-700 # (alkyl phenol formaldehyde resin polyoxyethylene ether) one or more combination.When surfactant selection was the combination of wherein two or more materials, the proportioning between them can be any proportioning.
Described solvent is selected from N, the combination of one or more in dinethylformamide (DMF), methyl-sulfoxide (DMSO), sulfolane, N-Methyl pyrrolidone, n-octyl alcohol, hexanol, tripropylene glycol butyl ether, methyl oleate, C10 aromatic hydrocarbons, terpineol, diesel oil and the vegetable oil; Vegetable oil wherein can be soybean oil, cottonseed oil, rapeseed oil, castor oil or turpentine wet goods, and described C10 aromatic hydrocarbons is two wires oil, heavy oil, butylbenzene, durene or 2-methyl naphthalene.When choice of Solvent was the combination of wherein two or more materials, the proportioning between them can be any proportioning.
Ultra low volume liquids according to the invention can prepare by existing common process, specifically can be: take by weighing raw material by proportioning, earlier solvent is dropped in the agitated reactor; Open the agitated reactor agitator; Under stirring condition, drop into azoles mite ester and triazole bactericidal agent, treat to dissolve fully back (about 10 minutes), input table surface-active agent again; Continue then to stir 15～60 minutes, the oily product that obtains homogeneous transparent is ultra low volume liquids of the present invention.
Azoles mite ester as one of active ingredient of the present invention; The spirit of trade name despot mite, chemical name is E-α-(1,3-dimethyl-5-phenoxy group pyrazoles-4-methylene-amino oxygen) p-methylbenzoic acid tert-butyl ester; It is a kind of efficient, wide spectrum phenoxy group pyrazoles miticide; Multiple harmful mite there is strong action of contace poison, the highest to young mite activity, and the lasting period is long; And other medicaments are not had cross resistance, be applicable to control tetranychus telarius and full pawl tetranychid on the various plants.Diseases such as insects such as diamond-back moth, prodenia litura, striped rice borer, rice fulgorid, black peach aphid and rice blast, powdery mildew, downy mildew also there is good preventive and therapeutic effect.
It is active ingredient that ultra low volume liquids of the present invention combines the triazole bactericidal agent of the wide above-mentioned selection of fungicidal spectrum with azoles mite ester; Make the products obtained therefrom desinsection rapid; Drug effect better and hold imitate long; Be applicable on the various plants control tetranychus telarius and full pawl tetranychid, and diseases such as insect such as diamond-back moth, prodenia litura, striped rice borer, rice fulgorid, black peach aphid and rice blast, anthracnose, powdery mildew, downy mildew are also had good preventive and therapeutic effect.
Embodiment
With embodiment the present invention is described further below, but the present invention is not limited to these embodiment.
Embodiment 1:10.5% azoles mite ester fluorine ring azoles ultra low volume liquids
The composition and the percentage by weight of each raw material are following:
Embodiment 2:13% azoles mite ester fluorine ring azoles ultra low volume liquids
The composition and the percentage by weight of each raw material are following:
Embodiment 3:8% azoles mite ester fluorine ring azoles ultra low volume liquids
The composition and the percentage by weight of each raw material are following:
The own azoles alcohol of embodiment 4:9.5% azoles mite ester ultra low volume liquids
The composition and the percentage by weight of each raw material are following:
The own azoles alcohol of embodiment 5:5% azoles mite ester ultra low volume liquids
The composition and the percentage by weight of each raw material are following:
The own azoles alcohol of embodiment 6:12% azoles mite ester ultra low volume liquids
The composition and the percentage by weight of each raw material are following:
Embodiment 7:8% azoles mite ester propiconazole ultra low volume liquids
The composition and the percentage by weight of each raw material are following:
Embodiment 8:16% azoles mite ester propiconazole ultra low volume liquids
The composition and the percentage by weight of each raw material are following:
Embodiment 9:12% azoles mite ester propiconazole ultra low volume liquids
The composition and the percentage by weight of each raw material are following:
Embodiment 10:9% azoles mite ester Flutriafol ultra low volume liquids
The composition and the percentage by weight of each raw material are following:
Embodiment 11:7% azoles mite ester Flutriafol ultra low volume liquids
The composition and the percentage by weight of each raw material are following:
Embodiment 12:9% azoles mite ester Flutriafol ultra low volume liquids
The composition and the percentage by weight of each raw material are following:
Embodiment 13:13% azoles mite ester metconazole ultra low volume liquids
The composition and the percentage by weight of each raw material are following:
Embodiment 14:7% azoles mite ester metconazole ultra low volume liquids
Press following weight proportion:
Embodiment 15:4% azoles mite ester nitrile bacterium azoles ultra low volume liquids
The composition and the percentage by weight of each raw material are following:
Embodiment 16:16% azoles mite ester nitrile bacterium azoles ultra low volume liquids
The composition and the percentage by weight of each raw material are following:
For further specifying the control efficiency of ultra low volume liquids according to the invention, the applicant has carried out field control effectiveness test.
Application implementation example 1: the field trial of ultra low volume liquids control apple anthracnose.
Experiment place: Luochuan County apple orchard, Shaanxi
Supply the reagent agent: the ultra low volume liquids that makes by the embodiment of the invention 2,4,8,10,13 and 15 prescriptions respectively, 5% azoles mite ester SC and triazole type conventional dose.
Method for using: the ultra low volume liquids by embodiment of the invention prescription makes is used ultra low volume spraying, and all the other medicament routines are sprayed with conventional after converting water.
Experimental technique: establish one-tenth apple tree in age 5 strains in 3 years of each cell selecting field planting, repeat 4 times; 14 days investigation preventive effects behind the medicine, the method for investigation drug effect is: 2 strains are investigated in each sub-district, and every strain is got a point by east, south, west, north, middle direction, and total strain number and diseased plant number at different levels are write down in every some investigation 2 strains, the occurrence degree of inspection anthracnose.Result of the test such as table 1:
The control efficiency of table 1 pair apple anthracnose
Field test results shows that the ultra low volume liquids of azoles mite ester and triazole type composition can effectively be prevented and treated apple anthracnose, and effect is superior to the control efficiency of list agent of azoles mite ester and the single agent of triazole type.
Application implementation example 2: the field trial of preventing and treating cucumber downy mildew with azoles mite ester and the own azoles alcohol ultra low volume liquids that is active ingredient
Experiment place: Nanning Wu Tang town herbary
Supply the reagent agent: the ultra low volume liquids that makes by the embodiment of the invention 4～6 prescriptions respectively, 5% azoles mite ester SC and 10% own azoles alcohol EC.
Method for using: the ultra low volume liquids by embodiment of the invention prescription makes is used ultra low volume spraying, and all the other medicament routines are sprayed with conventional after converting water.
Experimental technique: establish the cucumber ground 40m that each cell selecting was transplanted 2 months
2, repeat 4 times; 14 days investigation preventive effects behind the medicine, the method for investigation drug effect is: each sub-district diagonal is got at random at 5 and is taken a sample, and the total number of sheets and the sick number of sheets at different levels are write down in every some investigation 3 strains, the occurrence degree of inspection cucumber downy mildew.Result of the test such as table 2:
The control efficiency of table 2 pair cucumber downy mildew
Field test results shows that the ultra low volume liquids of azoles mite ester and own azoles alcohol composition can effectively be prevented and treated cucumber downy mildew, and effect is superior to the control efficiency of fluorine ring azoles or the agent of azoles mite ester list.
Claims (6)
1. contain the ultra low volume liquids of azoles mite ester and triazole bactericidal agent, process by following weight percentages:
Azoles mite ester 0.5～10%;
Triazole bactericidal agent 0.5～15%;
Surfactant 1～15%;
The solvent surplus;
Wherein, triazole bactericidal agent is selected from fluorine ring azoles, own azoles alcohol, propiconazole, Flutriafol, metconazole and the nitrile bacterium azoles any one.
2. the ultra low volume liquids that contains azoles mite ester and triazole bactericidal agent according to claim 1 is characterized in that: the percentage by weight of each raw material is:
Azoles mite ester 3～8%;
Triazole bactericidal agent 4～10%;
Surfactant 3～10%;
The solvent surplus.
3. the ultra low volume liquids that contains azoles mite ester and triazole bactericidal agent according to claim 1 and 2 is characterized in that: described surfactant is selected from one or more combination of APES, AEO, castor oil polyoxyethylene ether, agricultural newborn 500#, agricultural newborn 600# and Nongru-700 #.
4. the ultra low volume liquids that contains azoles mite ester and triazole bactericidal agent according to claim 1 and 2; It is characterized in that: described solvent is selected from N, the combination of one or more in dinethylformamide, methyl-sulfoxide, sulfolane, N-Methyl pyrrolidone, n-octyl alcohol, hexanol, tripropylene glycol butyl ether, methyl oleate, C10 aromatic hydrocarbons, terpineol, diesel oil and the vegetable oil.
5. the ultra low volume liquids that contains azoles mite ester and triazole bactericidal agent according to claim 4 is characterized in that: described vegetable oil is soybean oil, cottonseed oil, rapeseed oil, castor oil or turpentine oil.
6. the ultra low volume liquids that contains azoles mite ester and triazole bactericidal agent according to claim 4 is characterized in that: described C10 aromatic hydrocarbons is two wires oil, heavy oil, butylbenzene, durene or 2-methyl naphthalene.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012101618271A CN102696619A (en) | 2012-05-23 | 2012-05-23 | Ultra-low volume (ULV) liquid comprising fenpyroximate and triazoles bactericide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012101618271A CN102696619A (en) | 2012-05-23 | 2012-05-23 | Ultra-low volume (ULV) liquid comprising fenpyroximate and triazoles bactericide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102696619A true CN102696619A (en) | 2012-10-03 |
Family
ID=46889920
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012101618271A Pending CN102696619A (en) | 2012-05-23 | 2012-05-23 | Ultra-low volume (ULV) liquid comprising fenpyroximate and triazoles bactericide |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102696619A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102870768A (en) * | 2012-10-29 | 2013-01-16 | 南京扬子鸿利源化学品有限责任公司 | Ultralow-capacity imidacloprid spray and preparation method thereof |
| CN103636634A (en) * | 2013-11-19 | 2014-03-19 | 广西田园生化股份有限公司 | Ultra-low volume liquid containing fenpyroximate |
| CN104886069A (en) * | 2015-06-12 | 2015-09-09 | 福建省德盛生物工程有限责任公司 | Low-volume spray containing fenpyroximate |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102225918A (en) * | 2010-06-12 | 2011-10-26 | 利尔化学股份有限公司 | 1,2,3-thiadiazole formyl urea compounds as well as preparation method and application thereof |
| CN102273442A (en) * | 2011-09-13 | 2011-12-14 | 广西田园生化股份有限公司 | Ultralow volume liquid containing epoxiconazole |
| CN102349506A (en) * | 2011-09-13 | 2012-02-15 | 广西田园生化股份有限公司 | Ultralow-volume solvent containing Flusilazole |
-
2012
- 2012-05-23 CN CN2012101618271A patent/CN102696619A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102225918A (en) * | 2010-06-12 | 2011-10-26 | 利尔化学股份有限公司 | 1,2,3-thiadiazole formyl urea compounds as well as preparation method and application thereof |
| CN102273442A (en) * | 2011-09-13 | 2011-12-14 | 广西田园生化股份有限公司 | Ultralow volume liquid containing epoxiconazole |
| CN102349506A (en) * | 2011-09-13 | 2012-02-15 | 广西田园生化股份有限公司 | Ultralow-volume solvent containing Flusilazole |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102870768A (en) * | 2012-10-29 | 2013-01-16 | 南京扬子鸿利源化学品有限责任公司 | Ultralow-capacity imidacloprid spray and preparation method thereof |
| CN103636634A (en) * | 2013-11-19 | 2014-03-19 | 广西田园生化股份有限公司 | Ultra-low volume liquid containing fenpyroximate |
| CN104886069A (en) * | 2015-06-12 | 2015-09-09 | 福建省德盛生物工程有限责任公司 | Low-volume spray containing fenpyroximate |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108935456A (en) | A kind of pesticide synergistic agent and its application in Herbicidal combinations, Pesticidal combination and bactericidal composition | |
| CN102726415A (en) | Allicin-containing prevention and treatment pesticide for crop plant diseases | |
| CN101999396B (en) | Bactericide composition containing propiconazole, flusilazole and levo-alpha-terpineol and production method thereof | |
| CN101444210B (en) | Desinsection composite with synergy and application thereof | |
| CN103385251A (en) | Insecticidal composition comprising pyriproxyfen | |
| CN101647463A (en) | Insecticidal and acaricidal composition containing spirodiclofen | |
| CN104115845A (en) | Efficient pesticide composition containing flubendiamide | |
| CN103081939A (en) | Methylamino abamectin benzoate/indoxacarb oil suspension and preparation method thereof | |
| CN101406192A (en) | Compositional acaricide and uses thereof | |
| CN102696619A (en) | Ultra-low volume (ULV) liquid comprising fenpyroximate and triazoles bactericide | |
| CN103798237A (en) | Ultra-low-volume liquid agent containing boscalid | |
| CN104430365A (en) | Efficient insecticidal composition containing trifluorobenzene pyrimidine | |
| CN104082300A (en) | Insecticide acaricide composition containing pyriproxyfen and spirodiclofen | |
| CN103960280A (en) | High-efficiency insecticidal composition containing tetrachlorantraniliprole | |
| CN103416426A (en) | Insecticide composition containing fosthiazate and pyrethroids | |
| CN104381294A (en) | Insect and mite killing composition containing xiaochongliulin and spirodiclofen | |
| CN102239874A (en) | Insecticidal composition containing chlorfenapyr and clothianidin | |
| CN102669161A (en) | Hot fogging concentrate containing pyraclostrobin and triazole fungicide | |
| CN103283775A (en) | Synergistic pesticide composition | |
| CN102669152B (en) | A kind of Pesticidal combination containing Tefluthrin | |
| CN105613542A (en) | Synergistic acaricidal composition containing etoxazole and bifenazate | |
| CN102027933B (en) | Disinfectant composition comprising tebuconazole and levorotatory alpha-terpilenol and production method thereof | |
| CN105340914A (en) | Sterilization composition containing benziothiazolinone and bromothalonil | |
| CN101926354A (en) | Bactericide composite containing flusilazole and levo alpha-terpineol and production method thereof | |
| CN105594724A (en) | High-efficient pesticide composition containing flumizone pentafluoride |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20121003 |