CN102726415A - Allicin-containing prevention and treatment pesticide for crop plant diseases - Google Patents
Allicin-containing prevention and treatment pesticide for crop plant diseases Download PDFInfo
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- CN102726415A CN102726415A CN2012102025659A CN201210202565A CN102726415A CN 102726415 A CN102726415 A CN 102726415A CN 2012102025659 A CN2012102025659 A CN 2012102025659A CN 201210202565 A CN201210202565 A CN 201210202565A CN 102726415 A CN102726415 A CN 102726415A
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Abstract
The present invention discloses an allicin-containing prevention and treatment pesticide for crop plant diseases. The pesticide can be prepared into powder, an emulsion, a microemulsion, an aqueous emulsion or a suspension by adopting allicin and a bactericidal agent as effective active ingredients, wherein a weight percentage of the allicin is 10-70% and a weight percentage of the bactericidal agent is 1-40%. The pesticide of the present invention has the following advantages that: the pesticide is prepared by compound combination of the allicin and the bactericidal agent, such that a significant synergy effect can be generated, bacterial killing and disease prevention capacity can be enhanced, bacterial killing spectrum can be enlarged, crop yields can be improved, and especially good prevention and treatment effects for gray mold, downy mildew, leaf mold, epidemic disease, and other diseases can be provided; the pesticide of the present invention provides strong affinity for crops, can be rapidly absorbed by crops, and has characteristics of pathogenic bacteria killing, plant disease inhibiting, and no residue, in addition, drug resistance is not easily generated; the use amount of the single component in the pesticide of the present invention is reduced, such that the safety on crops is improved, and the use cost is relatively low; and allicin is adopted for plant protection so as to increase selectivity of pesticide use and prompt development of plant protection technology.
Description
Technical field:
The present invention relates to a kind of agricultural chemicals, relate in particular to a kind of the pesticide for control of crop disease that contains allicin of better preventive and therapeutic effect is arranged because of difficult diseases such as the bacterial gray mold of fungi, downy mildew, leaf mold, eqpidemic diseases on the crop.
Background technology:
Fungi, bacterium are the main roots that causes corps diseases, cause crop fallen leaves, shedding easily, early ageing occurs, have a strong impact on the yield and quality of crop.The bactericide kind that is used to prevent and treat corps diseases at present is a lot; Some control efficiency pesticide species is preferably also arranged, but the bactericide specific aim is generally stronger, to the germ disease of difference; Control efficiency is widely different, is difficult to reach the purpose of integrated control multiple diseases.The inventor finds that through experimental study for many years the bactericide allicin has stronger killing action to part fungi, bacterium, but the lasting period is shorter, and it is not very desirable using integrated control effect separately, and usage amount is big, and poisoning is appearred in some crop easily.
Summary of the invention:
The purpose of this invention is to provide a kind ofly has stronger killing effect to the fungi bacterium, especially diseases such as the bacterial crop gray mold of fungi, downy mildew, leaf mold, eqpidemic disease is had the pesticide for control of crop disease that contains allicin of obvious preventive and therapeutic effect.This contains the pesticide for control of crop disease of allicin; Can be widely used in the control by the microbial corps diseases of several diseases, can stimulate plant growth again, it is sick that crop is reduced in growth and development process; Improve the output of crop; Reduce the one pack system consumption simultaneously, strengthened the safety of crop, reduced use cost.
Technical scheme of the present invention realizes in the following manner:
A kind of pesticide for control of crop disease that contains allicin, it is to be that effective active becomes pulvis, emulsion, microemulsion, aqueous emulsion, the suspending agent be distributed into allicin, bactericide, wherein the weight percentage of allicin is 10-70; The weight percentage of bactericide is 1-40.
Described allicin weight percentage is 15-25; Described bactericide weight percentage is 5-25.
Described allicin weight percentage is 25-30; Described bactericide weight percentage is 10-25.
Described allicin weight percentage is 30-40; Described bactericide weight percentage is 10.
Described bactericide is triazole bactericidal agent, pyridines bactericide, methoxy acrylic acid series bactericidal agent or other bactericide.
Described triazole bactericidal agent is: triazolone, Triadimenol, alkene azoles alcohol, Tebuconazole, own azoles alcohol, tricyclazole, propiconazole, fluorine ring azoles, Flusilazole, nitrile bacterium azoles or Difenoconazole.
Described pyridines bactericide is: Boscalid or fluorine Boscalid.
Described methoxy acrylic acid series bactericidal agent is: Fluoxastrobin, pyraclostrobin or kresoxim-methyl.
Described other bactericide are: Prochloraz, carbendazim, the mould spirit of evil, dichlord isocyanurice acid, sym-closene or chlorobromide isocyanuric acid.
Described triazole bactericidal agent is: propiconazole, triazolone, Difenoconazole, nitrile bacterium azoles or Tebuconazole; Described other bactericide are: dislike mould spirit, sym-closene or dichlord isocyanurice acid.
For the drug effect that improves this agricultural chemicals and the needs of preparation processing, also be added with surfactant or its mixture 0-30% in the prescription, agricultural chemicals synergist 0-10%; Described auxiliary agent be in auxiliary agent, organosilicon, azone or thiophene ketone.
In the prescription of the present invention, allicin is a main component of the present invention, can prevent and treat the multiple kinds of crops disease effectively, and the stimulating plant growth.The fungicidal activity composition plays synergistic effect, widens fungicidal spectrum, reduces usage amount, reduces cost.Surfactant is a preparation pesticidal preparations auxiliary agent commonly used, mainly plays emulsification, dispersion, is opening up, effect such as hydrotropy.It can make water-fast agricultural chemicals be scattered in the water with the form of fine droplet on the one hand; Can greatly improve wetability and the adhesion rate of agricultural chemicals on crop and target on the other hand, thereby improve drug effect greatly.Auxiliary agent plays the infiltration synergistic effect.
Good effect of the present invention is:
The present invention is allicin and the bactericide compounded combination as active component; Can produce obvious role in synergism, strengthen the sterilizing disease-preventing ability, enlarge fungicidal spectrum; Improve the output of crop, especially gray mold, downy mildew, leaf mold, eqpidemic disease etc. are had the better prevention effect;
The present invention and crop affinity are strong, can be absorbed by crop fast, and killing pathogenic bacteria suppresses disease, and noresidue, is difficult for developing immunity to drugs;
One pack system usage amount of the present invention reduces, and crop safety is improved, and use cost is relatively low;
The present invention is applied to allicin in the plant protection, has increased the selectivity that agricultural chemicals uses, and helps promoting the development of plant protection technology.
Embodiment:
Below in conjunction with embodiment the present invention is described further:
Amount among all embodiment is all by weight:
Embodiment one: allicin 15%, propiconazole 10%, solvent naphtha 10%, emulsifier 500#3%, phenethyl phenol polyethenoxy ether 5%, water surplus.
Allicin+propiconazole is dissolved in the solvent naphtha, adds surfactant successively, add entry after stirring, stir, be milky white liquid, i.e. aqueous emulsion.
With above-mentioned finished product with 1000 times of sprayings of water dilution, diseases such as control paddy rice aspergillus disease, banded sclerotial blight, rice blast, then disease stops to infect, paddy rice restore normal growth (seeing embodiment applicable cases one).
Embodiment two: allicin 20%, Difenoconazole 5%, emulsifier 500#5%, 600#10%, phenethyl phenol polyethenoxy phosphate 5%, cyclohexanone 10%, methyl alcohol 5%, water surplus.
With allicin+Difenoconazole stirring and dissolving in cyclohexanone, add surfactant and stabilizing agent methyl alcohol successively, supply water to 100%, continue to stir the back and be homogeneous phase transparent liquid, i.e. microemulsion.
Above-mentioned finished product is prevented and treated apple canker with 1000 times of sprayings of water dilution, and apple canker no longer spreads, scab inhibiting rate 90%, and not have the fruit tree of spraying, the apple canker scab continues expansion.
Embodiment three: allicin 15%, dislike mould clever 15%, emulsifier 500#5%, 603#6%, phenethyl phenol polyethenoxy phosphate 5%, ethylene glycol 10%, water surplus.
The mould clever stirring and dissolving of allicin+evil in ethylene glycol, is added each surfactant successively, stir, supply water to 100%, stir the back and be homogeneous phase transparent liquid, said preparation is a microemulsion.
With 2000 times of spraying controls of water dilution Da Jiang bacterial wilt of ginger, the state of an illness no longer spreads with above-mentioned finished product, and the general control effect obviously is superior to contrasting medicament more than 95%.
Embodiment four: allicin 20%, and sym-closene 20%, dispersant NNO 3% draws back powder 4%, lauryl sodium sulfate 2%, white carbon 10%, diatomite surplus.
Allicin is adsorbed with white carbon, fully mix in blender with materials such as sym-closene, surfactants, pulverize through airslide disintegrating mill, the abundant mixing of secondary is processed wetting powder again.
With above-mentioned finished product with 1500 times of sprayings of water dilution, diseases such as control graw mold of tomato, root-rot, spot, anthrax, after the dispenser 2 days, the state of an illness no longer spread, overall diseased plant rate reduces 90%.
Embodiment five: allicin 25%, dichlord isocyanurice acid 25%, dispersant NNO 3% draws back powder 4%, lauryl sodium sulfate 2%,, in auxiliary agent 3.5%, white carbon 5%, fine particle calcium carbonate surplus.
Allicin is adsorbed with white carbon, fully mix in blender with materials such as dichlord isocyanurice acid, surfactants, pulverize through airslide disintegrating mill, secondary mixes again, processes wetting powder.
With above-mentioned finished product with 2000 times of sprayings of water dilution, control green pepper root rot, after the dispenser 3 days, it is dark green that green pepper leaf look recovers, it is vigorous to grow, diseased plant is controlled.
Embodiment six: allicin 40%, triazolone 10%, emulsifier 500#3%, 600#6%, solvent naphtha 10%, organosilicon 3%, ethanol surplus.
Allicin+triazolone is joined in the solvent naphtha, and the back that stirs adds surfactant, organosilicon, supplies ethanol to 100%, stirs, and processes homogeneous phase transparent liquid, i.e. soluble concentrate.
With above-mentioned finished product with 2000 times of sprayings of water dilution, control wheat powdery mildew, rust, after the dispenser 2 days, the wheat mildew faded away, it is green that the leaf look changes, it is vigorous to grow, disease is effectively controlled.
Embodiment seven: allicin 40%, nitrile bacterium azoles 10%, emulsifier 500#5%, 600#5%, solvent naphtha 10%, azone 2%, methyl alcohol surplus.
Allicin+nitrile bacterium azoles is joined in the solvent naphtha, and the back that stirs adds surfactant, azone, supplies methyl alcohol to 100%, stirs, and processes homogeneous phase transparent liquid.
With 2500 times of sprayings of water dilution, control wheat powdery mildew, rust, banded sclerotial blight were observed after four days with above-mentioned finished product, and the disease symptom fades away, and observed after eight days, and it is dark green that crop leaf look recovers.And control group disease symptom still exists, and the leaf look light green, and color and luster is relatively poor.Explain that allicin+nitrile bacterium azoles when preventing and treating crop pest, also has the effect of stimulating growth to crop.
Embodiment eight: allicin 30%, and pyraclostrobin 10%, emulsifier 500#5%, phenethyl phenol polyethenoxy phosphate 5%,, organosilicon 3%, ethanol surplus.
The pyrazoles Fluoxastrobin is added in the allicin, and the back that stirs adds surfactant, organosilicon, supplies ethanol to 100%, stirs, and processes homogeneous phase transparent liquid.
Above-mentioned finished product with 3000 times of spraying controls of water dilution gray mold of cucumber, is observed after four days, and scab atrophy gradually is withered, and crop restore normal growth; Observe after eight days, it is dark green that the cucumber leaf look recovers, and mesophyll thickens, and the control group scab continues to spread, and the leaf look light green.Allicin+pyraclostrobin is described when preventing and treating crop pest, crop is also had the effect of stimulating growth.
Embodiment nine: allicin 25%, and Tebuconazole 10%, emulsifier 500#8%, 603#6%, phenethyl phenol polyethenoxy phosphate 6%,, cyclohexanone 10%, methyl alcohol 5%, water surplus.
Tebuconazole+allicin is joined in the cyclohexanone, and the dissolving back adds surfactant, fully mixes, and adds the first alcohol and water again, system homogeneous phase transparent liquid, i.e. microemulsion behind the mixing.
Above-mentioned finished product with 2000 times of spraying controls of water dilution pear scabs, is observed two days later, and scab is controlled, drying shrinkage gradually, and the control group scab enlarges.Explain that allicin+Tebuconazole has stronger control action to scab.
Embodiment ten: allicin 25%, and Boscalid 25%, dispersant NNO 3% draws back powder 4%, lauryl sodium sulfate 2%, white carbon 10%, kaolin (or diatomite) surplus.
Materials such as allicin, Boscalid, surfactant are fully mixed in blender, pulverize through airslide disintegrating mill, secondary fully mixes again, processes wetting powder.
Above-mentioned finished product with 2000 times of sprayings of water dilution, is prevented and treated graw mold of tomato, and dispenser was observed after three days, and fungal hyphae disappears, and scab is obviously suppressed fruit, is superior to contrasting the medicament allicin.
Embodiment 11: allicin 20%, and Prochloraz 20%, emulsifier 500#10%, 600#6%, phenethyl phenol polyethenoxy phosphate 4%,, cyclohexanone 10%, ethylene glycol 5%, water surplus.
Prochloraz+allicin is joined in the cyclohexanone, and the dissolving back adds surfactant, fully mixes, and adds ethylene glycol and water again, system homogeneous phase transparent liquid, i.e. microemulsion behind the mixing.
With 3000 times of sprayings of water dilution, control mandarin tree green mould was observed behind the medicine in 3 days with above-mentioned finished product, and green mold disappears, and the fruit face recovers normal, and contrast medicament carbendazim effect is relatively poor relatively.
Embodiment 12: allicin 20%, dislike mould clever 20%, emulsifier 500#5%, 603#8%, phenethyl phenol polyethenoxy phosphate 7%, ethylene glycol 10%, water surplus.
The mould clever stirring and dissolving of allicin+evil in ethylene glycol, is added each surfactant successively, stir, supply water to 100%, stir the back and be homogeneous phase transparent liquid, said preparation is a microemulsion.
The embodiment applicable cases is introduced:
One, the mould spirit control of allicin+evil eggplant fusarium wilt field efficacy
To the eggplant field of long-term morbidity, product of the present invention carries out under variable concentrations and other medicament comparative trials.Estimate the control efficiency of product of the present invention to the eggplant fusarium wilt.
1, supplies the reagent experimental scheme
1500 times of liquid of product of the present invention (embodiment 12)
2000 times of liquid of product of the present invention
2500 times of liquid of product of the present invention
2000 times of liquid of 40% allicin missible oil
30% dislikes 2000 times of liquid of mould Lingshui Spring agent
The clear water contrast
2, test method
2.1 arrange the sub-district: repetition is not established in this test, and each handles randomized arrangement, every sub-district area 100 ㎡.At the initial stage of a disease, spray in twice of mid-term medicine, dispenser for the first time July 4, dispenser for the second time July 11.Each is handled according to the mu consumption to supply the reagent agent, mu amount of water (30 kilograms), dilution back even spraying.
2.2 investigation method: each is handled and gets 5 points in every sub-district by the double diagonal line method, and every fixing 10 square metres (looking into 25 strains) inserted card mark, in observed result on July 21.
Eggplant fusarium wilt grade scale is following:
0 grade: anosis;
1 grade: the withered number of blade accounts for the 1-10% of total number of sheets;
3 grades: the withered number of blade accounts for the 11-30% of total number of sheets;
5 grades: the withered number of blade accounts for the 31-50% of total number of sheets;
7 grades: the withered number of blade accounts for the 51-70% of total number of sheets;
9 grades: the withered number of blade accounts for the 71-100% of total number of sheets.
2.3 computational methods
2.4 direct influence to crop
Three different extension rates of product of the present invention do not have influence to crop safety.
2.5 influence to other damage by disease and insect
Product of the present invention has certain prevention and therapeutic action to diseases such as the eqpidemic disease of eggplant, anthracnose.
3, result and analysis
Product control eggplant fusarium wilt result of the test of the present invention
| Chemicals treatment | Investigation strain number | Disease refers to | Relative control effect (%) |
| 2500 times of liquid of product of the present invention | 125 | 2.48 | 78.47 |
| 2000 times of liquid of product of the present invention | 125 | 2.08 | 81.94 |
| 1500 times of liquid of product of the present invention | 125 | 1.38 | 88.02 |
| 2000 times of liquid of 40% allicin missible oil | 125 | 2.64 | 77.08 |
| 30% dislikes 2000 times of liquid of mould Lingshui Spring agent | 125 | 3.04 | 73.61 |
| The clear water contrast | 125 | 11.52 | / |
Can know that by last table 1000 times of liquid controls of product of the present invention eggplant fusarium wilt preventive effect is the highest, reaches 88.02%; 2000 times of liquid preventive effects of product of the present invention are taken second place, and are 81.94%; 2500 times of liquid preventive effects of product of the present invention are 78.47%, all are superior to contrasting 2000 times of liquid of medicament 40% allicin missible oil, 30% and dislike 2000 times of liquid of mould Lingshui Spring agent.
4, Main Conclusions
Product two components of the present invention have obvious synergistic effect; Product of the present invention carries out foliage-spray to the eggplant fusarium wilt, can prevent and treat spreading and developing of disease effectively, and can restore normal growth optimum diluting multiple 1500-2000 times liquid rapidly.According to observing product of the present invention to eggplant and certain stimulating growth effect is arranged, eggplant is had no adverse effects, can on producing, apply.
Each handles control eggplant fusarium wilt initial data field record table subordinate list
Two, allicin+propiconazole control rice banded sclerotial blight, rice blast field efficacy
Product of the present invention carries out the comparative trial with other medicaments to the paddy field of long-term morbidity under variable concentrations, test drug is divided into 6 processing, and each Processing Test concentration is respectively:
1,1000 times of liquid of product of the present invention (embodiment one allicin 15%, propiconazole 10%)
2,1500 times of liquid of product of the present invention
3,2000 times of liquid of product of the present invention
4,1500 times of liquid of 30% allicin missible oil
5,2000 times of liquid of 25% propiconazole emulsifiable concentrate
6, clear water contrast
Each handles repetition 3 times, and 6 processing are totally 18 sub-districts, randomized arrangement.The cultivation management term harmonization of all sub-districts in the test, 35 square metres of each sub-districts.
Spraying times is for once, and the dispenser date and time is 16:30-18:30 on 17 afternoon of August.Paddy rice punishment tiller phase not during dispenser, the growing way viridescent is vigorous, rice sheath blight disease, rice blast place initial phase.According to experimental scheme dosage allotment soup, spray successively to high concentration by low concentration, evenly spray medicine on paddy rice.
16 days is to investigate once September 2 behind the medicine.10 samplings of the parallel great-jump-forward in every sub-district, 5 clumps every, every sub-district is investigated 50 Cong He altogether, the total strain number of record investigation, diseased plant number, and stripping is looked into rice sheath blight disease, rice blast diseased plant in the diseased plant, the calculating preventive effect.
Different chemical control rice sheath blight diseases, rice blast result of the test result
This test is shown by last table result: 1000 times of liquid of product of the present invention are the highest to the survival rate of seedlings and the preventive effect of rice sheath blight disease, rice blast, reach 91.91%, 99.18% and 95.91%, 99.10% respectively.1500 times of liquid of product of the present invention, 2000 times of liquid also have higher preventive effect to rice sheath blight disease, rice blast, and survival rate of seedlings is also more outstanding, obviously are superior to contrasting 1500 times of liquid of medicament 30% allicin missible oil.Particularly aspect control rice blast, the present invention has remedied the deficiency of propiconazole, and three concentration are handled and all are superior to contrasting medicament 25% propiconazole emulsifiable concentrate.Explain that the present invention has outstanding synergistic effect, enlarged fungicidal spectrum, and consumption is few, strengthened safety crop.
Claims (10)
1. pesticide for control of crop disease that contains allicin, it is to be pulvis, emulsion, microemulsion, aqueous emulsion, the suspending agent that effective active becomes to be distributed into allicin, bactericide, it is characterized in that: the weight percentage of allicin is 10-70; The weight percentage of bactericide is 1-40.
2. the pesticide for control of crop disease that contains allicin according to claim 1 is characterized in that: described allicin weight percentage is 15-25; Described bactericide weight percentage is 5-25.
3. the pesticide for control of crop disease that contains allicin according to claim 1 is characterized in that: described allicin weight percentage is 25-30; Described bactericide weight percentage is 10-25.
4. the pesticide for control of crop disease that contains allicin according to claim 1 is characterized in that: described allicin weight percentage is 30-40; Described bactericide weight percentage is 10.
5. according to claim 1,2, the 3 or 4 described pesticide for control of crop disease that contain allicin, it is characterized in that: described bactericide is triazole bactericidal agent, pyridines bactericide, methoxy acrylic acid series bactericidal agent or other bactericide.
6. the pesticide for control of crop disease that contains allicin according to claim 5 is characterized in that: described triazole bactericidal agent is: triazolone, Triadimenol, alkene azoles alcohol, Tebuconazole, own azoles alcohol, tricyclazole, propiconazole, fluorine ring azoles, Flusilazole, nitrile bacterium azoles or Difenoconazole.
7. the pesticide for control of crop disease that contains allicin according to claim 5 is characterized in that: described pyridines bactericide is: Boscalid or fluorine Boscalid.
8. the pesticide for control of crop disease that contains allicin according to claim 5 is characterized in that: described methoxy acrylic acid series bactericidal agent is: Fluoxastrobin, pyraclostrobin or kresoxim-methyl.
9. the pesticide for control of crop disease that contains allicin according to claim 5 is characterized in that: described other bactericide are: Prochloraz, carbendazim, the mould spirit of evil, dichlord isocyanurice acid, sym-closene or chlorobromide isocyanuric acid.
10. the pesticide for control of crop disease that contains allicin according to claim 5 is characterized in that: described triazole bactericidal agent is: propiconazole, triazolone, Difenoconazole, nitrile bacterium azoles or Tebuconazole; Described other bactericide are: dislike mould spirit, sym-closene or dichlord isocyanurice acid.
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| CN103907649A (en) * | 2014-04-14 | 2014-07-09 | 山东圣鹏科技股份有限公司 | Soil bactericide pesticide composite |
| CN103907649B (en) * | 2014-04-14 | 2016-05-04 | 山东圣鹏科技股份有限公司 | A kind of soil sterilization agricultural chemical compositions |
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| CN104222102B (en) * | 2014-09-23 | 2016-06-22 | 江苏丘陵地区镇江农业科学研究所 | Recompounded pesticide containing S-Ethyl ethylthio sulfonate and Tebuconazole and application thereof |
| CN104351199A (en) * | 2014-11-11 | 2015-02-18 | 济南新起点医药科技有限公司 | Tebuconazole-allicin water-dispersible granules |
| CN104351197A (en) * | 2014-11-11 | 2015-02-18 | 济南新起点医药科技有限公司 | Tebuconazole-allicin microcapsule suspending-suspension agent |
| CN104351205A (en) * | 2014-11-11 | 2015-02-18 | 济南新起点医药科技有限公司 | Water-dispersible granules for flos chrysanthemi |
| CN104351203A (en) * | 2014-11-11 | 2015-02-18 | 济南新起点医药科技有限公司 | Tebuconazole-allicin microemulsion |
| CN104351202A (en) * | 2014-11-11 | 2015-02-18 | 济南新起点医药科技有限公司 | Aqueous emulsion for flos chrysanthemi |
| CN104351196A (en) * | 2014-11-11 | 2015-02-18 | 济南新起点医药科技有限公司 | Microemulsion for flos chrysanthemi |
| CN104351201A (en) * | 2014-11-11 | 2015-02-18 | 济南新起点医药科技有限公司 | Fungicide for flos chrysanthemi |
| CN104430377A (en) * | 2014-11-11 | 2015-03-25 | 济南新起点医药科技有限公司 | Suspoemulsion for chrysanthemum |
| CN104351198A (en) * | 2014-11-11 | 2015-02-18 | 济南新起点医药科技有限公司 | Microcapsule suspension for flos chrysanthemi |
| CN104351206A (en) * | 2014-11-11 | 2015-02-18 | 济南新起点医药科技有限公司 | Tebuconazole-allicin wettable powder |
| CN104351200B (en) * | 2014-11-11 | 2016-06-08 | 江苏邦盛生物科技有限责任公司 | A kind of Tebuconazole and garlicin bactericidal composition |
| CN104351200A (en) * | 2014-11-11 | 2015-02-18 | 济南新起点医药科技有限公司 | Tebuconazole-allicin fungicidal composition |
| CN104351203B (en) * | 2014-11-11 | 2016-08-17 | 青岛青知企业管理咨询有限公司 | A kind of Tebuconazole and the microemulsion of garlicin |
| CN104351199B (en) * | 2014-11-11 | 2016-08-24 | 青岛青知企业管理咨询有限公司 | A kind of Tebuconazole and the water dispersible granules of allicin |
| CN104351201B (en) * | 2014-11-11 | 2016-08-24 | 青岛青知企业管理咨询有限公司 | A kind of chrysanthemum bactericide |
| CN104351202B (en) * | 2014-11-11 | 2016-08-24 | 青岛青知企业管理咨询有限公司 | A kind of aqueous emulsion for chrysanthemum |
| CN104351198B (en) * | 2014-11-11 | 2016-08-24 | 青岛青知企业管理咨询有限公司 | A kind of microcapsule suspending agent for chrysanthemum |
| CN104430377B (en) * | 2014-11-11 | 2016-08-24 | 青岛青知企业管理咨询有限公司 | A kind of suspension emulsion for chrysanthemum |
| CN105918362A (en) * | 2016-06-05 | 2016-09-07 | 河南科技学院 | Composition for preventing plant diseases |
| CN111053082A (en) * | 2019-10-08 | 2020-04-24 | 海南正业中农高科股份有限公司 | Composition containing ethylicin and difenoconazole and application thereof |
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