CN104381294A - Insect and mite killing composition containing xiaochongliulin and spirodiclofen - Google Patents
Insect and mite killing composition containing xiaochongliulin and spirodiclofen Download PDFInfo
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Abstract
The invention discloses an inset and mite killing composition containing xiaochongliulin and spirodiclofen. The inset and mite killing composition comprises xiaochongliulin, spirodiclofen and ordinary pesticide additives, wherein the weight ratio of xiaochongliuli to spirodiclofen is (40:1) to (1:40); the weight sum of xiaochongliulin and spirodiclofen accounts for 1-85% of the composition in percentage by weight. A great deal of indoor and outdoor experiment shows that the insect and mite killing composition has a remarkable synergistic interaction function, the insecticidal spectrum is widened, various insects such as red spiders and scale insects of the agriculture industry can be prevented and treated, the use amount of pesticide is reduced, the residual amount of pesticide on crops is reduced, the pollution to the environment is reduced, and the drug resistance of pests is delayed.
Description
Technical field
The present invention relates to composition pesticide and application thereof, specifically a kind of with sulfur-phosphor and spiral shell mite ester for active ingredient insecticide acaricide composition.
Background technology
Sulfur-phosphor: belong to organophosphorus insecticides, the mechanism of action is the inhibitor of acetylcholinesterase.Good control efficiency is had to insects such as citrus red mite, arrowhead scales, cotton cotton bollworm, vegetables oriental tobacco budworm, diamond-back moth and rice fulgorids.
Spiral shell mite ester: be a kind of spirocyclic tetronic acid class miticide, the mechanism of action is suppress the Fatty synthesis of mite, blocks the energy metabolism of mite, thus causes evil mite dead.Can be used for the control of evil mite on the solanaceous crops such as fruit tree and eggplant, capsicum, tomato.In addition, also have insects such as pear sucker, oystershell scale and leafhopper classes and well doublely control effect.
The resistance problems of pest is global problems, is the emphasis problem that agricultural science and technology worker pays close attention to always.Along with the impact on the continuity year in year out of Chemical Control of Harmful Insects, the increase of Pesticide use amount and the not factor such as scientifical use agricultural chemicals, cause pest resistance day by day serious, the pest species producing resistance is on the increase.Meanwhile, due to the use agricultural chemicals of high strength, result in that Practice for Pesticide Residue in Agricultural Products exceeds standard, the series of problems such as contaminated environment and the increase of peasant's drug cost, be unfavorable for the sustainable development of agricultural.
Therefore, development is efficient, low toxicity, low-residual, the different mechanism of action, have again the complex preparation of synergistic function simultaneously, not only contribute to the generation delaying pest resistance to insecticide, but also the service life of pesticide species can be extended, reduce using dosage, cost-saving, reduce the pollution to environment.
The compounded formula screening of the present inventor to sulfur-phosphor and spiral shell mite ester conducts in-depth research, find that sulfur-phosphor and spiral shell mite ester carry out composite, within the scope of certain compound proportion, there is obvious synergistic function, in actual use simultaneously, expand insecticidal spectrum, to insect agriculturally, as two spotted spider mite, scale insect etc. have outstanding control efficiency, after further study, the present invention is completed.
Summary of the invention
The object of the present invention is to provide a kind of insecticide acaricide composition containing sulfur-phosphor and spiral shell mite ester, this insecticide acaricide composition has obvious synergistic function, expands insecticidal spectrum, can be used for the various pests such as two spotted spider mite, scale insect of preventing and treating agriculturally.
Another object of the present invention is to the insecticide acaricide composition containing sulfur-phosphor and spiral shell mite ester, the generation that in use can reduce dosage, reduce the residual quantity of agricultural chemicals on crops, delay pest resistance to insecticide, it can also be made to be used alone to compare than single dose to the control efficiency of various insect and to significantly improve, laborsaving, economical, reduce farmer's burdens.
Technical solution of the present invention: a kind of insecticide acaricide composition containing sulfur-phosphor and spiral shell mite ester, active ingredient is sulfur-phosphor and spiral shell mite ester, the weight ratio of sulfur-phosphor and spiral shell mite ester is 40:1 ~ 1:40, sulfur-phosphor and spiral shell mite ester weight summation percentage by weight are in the composition 1 ~ 85%, and all the other are allow in agricultural chemicals to use and acceptable insecticides adjuvant.
Described insecticides adjuvant is one or more the combination in solvent, emulsifier, wetting agent, dispersant, stabilizing agent, antifreezing agent, thickener, disintegrant, binding agent, defoamer, bleeding agent, synergist, fire retardant, macromolecule cyst material, pH adjusting agent and filler, above material is known substance conventional in pesticidal preparations, change to some extent according to being prepared into the different formulations of pesticide, but be not particularly limited, describe no longer one by one at this.
Insecticide acaricide composition of the present invention can be prepared into any one formulation that applicable agricultural production uses by known method, reasonable formulation has suspending agent, aqueous emulsion, microemulsion, water dispersible granules, wetting powder, ultra low volume liquids, microcapsule suspending agent and thermal fog etc.
Insecticide acaricide composition of the present invention can be used for the various pests of preventing and treating agriculturally, as two spotted spider mite, scale insect etc.
The frequency of administration of insecticide acaricide composition of the present invention and amount of application change with crops, insect, weather condition and have small variations, can by the object using suitable dosage reach effectively control.
Compared with prior art, the invention has the advantages that:
1, sulfur-phosphor and spiral shell mite ester is composite has synergistic function, is used alone the control efficiency significantly improved insect, expands insecticidal spectrum simultaneously, solve the defect to some insect weak effect when single dose is used alone than single dose.
2, sulfur-phosphor and spiral shell mite ester two kinds of active ingredients composite, decrease Pesticide use amount, reduce use cost, alleviate pollution to environment, delayed the generation of pest resistance to insecticide, add the service life of agricultural chemicals.
Embodiment
In order to understand essence of the present invention better, below in conjunction with embodiment, content of the present invention is described further, but can not limitation of the present invention be considered as.
(1) Formulation Example
In following each embodiment, active ingredient adopts the former medicine of 90% sulfur-phosphor and the former medicine of 98% spiral shell mite ester, and each component percentages is weight percentage.
Embodiment 1:30% sulfur-phosphor spiral shell mite ester suspending agent
Sulfur-phosphor 25%, spiral shell mite ester 5%, lignosulfonates 15%, lauryl sodium sulfate 15%, CMC 2%, glycerine 2%, silicone oil 0.1%, deionized water supplies 100%.Above-mentioned active ingredient, dispersant, wetting agent, thickener, antifreezing agent, defoamer and deionized water are mixed, sand milling in high speed shear dispersion, sand mill, the high dispersive formed in water-medium, stable suspension system, can obtain 30% sulfur-phosphor spiral shell mite ester suspending agent.
Embodiment 2:40% sulfur-phosphor spirodiclofen water emulsion
Sulfur-phosphor 38%, spiral shell mite ester 2%, dimethylbenzene 10%, cyclohexanone 5%, styrenated phenol APEO 10%, polycarboxylate 10%, sodium sorbate 1%, glycerine 1%, deionized water supplies 100%.Above-mentioned active ingredient, solvent, emulsifier, dispersant and stabilizing agent are mixed to form oil phase, antifreezing agent dissolves and forms aqueous phase in water, slowly oil phase is added in aqueous phase under clipper effect, and continue to shear about 30 minutes, the sulfur-phosphor spirodiclofen water emulsion of 40% can be obtained.
Embodiment 3:35% sulfur-phosphor spirodiclofen microemulsion
Sulfur-phosphor 10%, spiral shell mite ester 25%, cyclohexanone 20%, diphenyl phenol polyethenoxy polyethenoxy ether 15%, sodium citrate 2%, organosilicon 1%, double to kill 2%, deionized water supplies 100%.Active ingredient solvent is dissolved completely, and then add emulsifier, stabilizing agent, bleeding agent, synergist mix, finally add deionized water, after fully stirring, the sulfur-phosphor spirodiclofen microemulsion of 35% can be obtained.
Embodiment 4:80% sulfur-phosphor spiral shell mite ester wetting powder
Sulfur-phosphor 70%, spiral shell mite ester 10%, alkylphenol polyoxyethylene 5%, calcium dodecyl benzene sulfonate 5%, diatomite supplies 100%.By above-mentioned, active ingredient, dispersant, wetting agent and filler are mixed, again through air-flow crushing after mechanical crushing, mix, 80% sulfur-phosphor spiral shell mite ester wetting powder can be obtained.
Embodiment 5:70% sulfur-phosphor spirodiclofen water dispersible granule
Sulfur-phosphor 30%, spiral shell mite ester 40%, lignosulfonates 5%, calcium dodecyl benzene sulfonate 5%, sodium sulphate 2%, polyethylene glycol 2%, kaolin supplies 100%.Above-mentioned active ingredient, dispersant, wetting agent, disintegrant, binding agent and filler are mixed, pulverize with micro jet, through mediating, then adding in fluidized-bed granulation dryer and carrying out granulation, drying, screening, 70% sulfur-phosphor spirodiclofen water dispersible granule can be obtained.
Embodiment 6:15% sulfur-phosphor spiral shell mite ester ultra low volume liquids
Sulfur-phosphor 5%, spiral shell mite ester 10%, DMF 20%, lauryl sodium sulfate 5%, castor oil polyoxyethylene ether 3%, azone 2%, ethyl oleate complements to 100%.After above-mentioned active ingredient stirring solvent being dissolved, then add other auxiliary agent, be fully uniformly mixed, 15% sulfur-phosphor spiral shell mite ester ultra low volume liquids can be obtained.
Embodiment 7:20% sulfur-phosphor spiral shell mite ester micro capsule suspending agent
Sulfur-phosphor 15%, spiral shell mite ester 5%, tolyl isocyanate 10%, cyclohexanone 20%, castor oil polyoxyethylene ether 5%, polyoxyethylene carboxylate 3%, sodium hydroxide 2%, deionized water complements to 100%.By above-mentioned active ingredient, macromolecule cyst material, solvent, make to be dissolved into homogeneous oil phase, in a shear condition, oil phase is joined in the aqueous phase solution containing emulsifier, pH adjusting agent, dispersant, surplus deionized water is supplied, bi-material reacts at oil-water interfaces, forms macromolecule cyst wall, can obtain 20% sulfur-phosphor spiral shell mite ester micro capsule suspending agent.
Embodiment 8:10% sulfur-phosphor spirodiclofen hot aerosol
Sulfur-phosphor 2%, spiral shell mite ester 8%, cyclohexanone 20%, fatty alcohol-polyoxyethylene ether 10%, calcium dodecyl benzene sulfonate 5%, thiophene ketone 2%, triphenyl phosphate 2%, soybean oil complements to 100%.Above-mentioned active ingredient and solvent are dropped in the reaction vessel of band stirring, after active ingredient is fully dissolved, then add other auxiliary agent, abundant stir about 60 minutes, makes it mix, and can obtain 10% sulfur-phosphor spirodiclofen hot aerosol.
(2) indoor biological determination of activity and field efficacy embodiment
Embodiment 9: sulfur-phosphor and spiral shell mite ester are to the indoor joint toxicity measuring of scale insect
For examination worm: select to be collected in citrus orchard and the scale insect nymph raising breeding in indoor.
Reagent agent: the former medicine of 90% sulfur-phosphor and the former medicine of 98% spiral shell mite ester.
Test method: adopt spray-on process to measure, concrete grammar is as follows.
Healthy, that the length of time is consistent scale insect nymph is selected in laboratory, put into the culture dish with Citrus leaf, every ware 40 cephalont, often 4 repetitions are established in process, spray under 50PSI pressure with potter spray tower, each spray ware, every ware spraying liquid 1ml, takes out culture dish after sedimentation 1min, then the culture dish processed is put into 25 DEG C, cultivate in the illumination box of 12H/12H, if not containing the corresponding organic solvent of medicament process in contrast.After process, 72h investigation examination worm death condition, records total borer population and dead borer population.
Carry out statistical analysis with DPS statistical analysis software, calculate the LC of each medicament
50, and the co-toxicity coefficient (CTC value) of mixture is calculated according to the abundant method of Sun Yun
Actual measurement toxicity index (ATI)=(standard agent LC
50/ reagent agent LC
50) × 100
In theoretical toxicity index (TTI)=A medicament toxicity index × mixture A percentage composition+B medicament toxicity index × mixture in the percentage composition of B
Co-toxicity coefficient (CTC)=[the theoretical toxicity index (TTI) of mixture actual measurement toxicity index (ATI)/mixture] × 100
According to the NY/T11547.7-2006 insecticide combination effect criteria for classifying: co-toxicity coefficient (CTC) >=120 shows as synergistic effect; Co-toxicity coefficient (CTC)≤80 shows as antagonism; 80 < co-toxicity coefficient (CTC) < 120 show as summation action.
Table 1, sulfur-phosphor and spiral shell mite ester are to the indoor joint toxicity measuring result of scale insect
| Medicament title and proportioning (weight ratio) | LC 50(mg/L) | ATI | TTI | CTC |
| Sulfur-phosphor | 6.72 | 100.00 | - | - |
| Spiral shell mite ester | 26.34 | 25.51 | - | - |
| Sulfur-phosphor: spiral shell mite ester (40:1) | 5.18 | 129.73 | 98.18 | 132.13 |
| Sulfur-phosphor: spiral shell mite ester (30:1) | 4.79 | 140.29 | 97.60 | 143.74 |
| Sulfur-phosphor: spiral shell mite ester (20:1) | 4.17 | 161.15 | 96.45 | 167.08 |
| Sulfur-phosphor: spiral shell mite ester (10:1) | 3.83 | 175.46 | 93.23 | 188.20 |
| Sulfur-phosphor: spiral shell mite ester (1:1) | 4.95 | 135.76 | 62.76 | 216.32 |
| Sulfur-phosphor: spiral shell mite ester (1:10) | 8.59 | 78.23 | 32.28 | 242.35 |
| Sulfur-phosphor: spiral shell mite ester (1:20) | 11.37 | 59.10 | 29.06 | 203.37 |
| Sulfur-phosphor: spiral shell mite ester (1:30) | 14.15 | 47.49 | 27.91 | 170.15 |
| Sulfur-phosphor: spiral shell mite ester (1:40) | 17.41 | 38.60 | 27.33 | 141.24 |
As can be seen from Table 1, sulfur-phosphor and spiral shell mite ester composite in the scope of 40:1 ~ 1:40 (by weight) time, co-toxicity coefficient (CTC) is all greater than 120, shows synergistic function to scale insect, visible sulfur-phosphor and spiral shell mite ester is composite has reasonability and feasibility.
Embodiment 10: sulfur-phosphor and spiral shell mite ester are to the indoor joint toxicity measuring of citrus red mite
For examination worm: select to be collected in citrus orchard and the female one-tenth mite of two spotted spider mite raising breeding in indoor.
Reagent agent: the former medicine of 90% sulfur-phosphor and the former medicine of 98% spiral shell mite ester.
Test method adopts leaf butterfly spray-on process, and concrete operation method is as follows:
Choose the Citrus leaf of healthy growth, leaf butterfly is made with card punch, a wet sponge block is placed in culture dish, it puts filter paper, foliation butterfly on filter paper, every ware puts 2 pieces of leaf butterflies, selects healthy, that the length of time the is consistent female one-tenth mite of citrus red mite and is inoculated on leaf butterfly, every leaf butterfly inoculates 20, and often 4 repetitions are established in process.Under the culture dish being connected to leaf butterfly is placed in potter spray tower, spray under 50PSI pressure, spray amount is 1ml, culture dish is taken out after sedimentation 1min, then the culture dish processed is put into 25 DEG C, cultivate in 12H/12H illumination box, if not containing the corresponding organic solvent of medicament process in contrast.After process, 48h investigation examination worm death condition, records total borer population and dead borer population.
Carry out statistical analysis with DPS statistical analysis software, calculate the LC of each medicament
50, and the co-toxicity coefficient (CTC value) of mixture is calculated according to the abundant method of Sun Yun
Actual measurement toxicity index (ATI)=(standard agent LC
50/ reagent agent LC
50) × 100
In theoretical toxicity index (TTI)=A medicament toxicity index × mixture A percentage composition+B medicament toxicity index × mixture in the percentage composition of B
Co-toxicity coefficient (CTC)=[the theoretical toxicity index (TTI) of mixture actual measurement toxicity index (ATI)/mixture] × 100
According to the NY/T11547.7-2006 insecticide combination effect criteria for classifying: co-toxicity coefficient (CTC) >=120 shows as synergistic effect; Co-toxicity coefficient (CTC)≤80 shows as antagonism; 80 < co-toxicity coefficient (CTC) < 120 show as summation action.
As can be seen from Table 2, sulfur-phosphor and spiral shell mite ester composite in the scope of 40:1 ~ 1:40 (by weight) time, co-toxicity coefficient (CTC) is all greater than 120, synergistic function is shown to citrus red mite, visible sulfur-phosphor and spiral shell mite ester is composite has reasonability and feasibility.
Table 2, sulfur-phosphor and spiral shell mite ester are to the indoor joint toxicity measuring result of citrus red mite
| Medicament title and proportioning (weight ratio) | LC 50(mg/L) | ATI | TTI | CTC |
| Sulfur-phosphor | 17.87 | 100.00 | - | - |
| Spiral shell mite ester | 4.71 | 379.41 | - | - |
| Sulfur-phosphor: spiral shell mite ester (40:1) | 11.67 | 153.13 | 106.81 | 143.37 |
| Sulfur-phosphor: spiral shell mite ester (30:1) | 9.83 | 181.79 | 109.01 | 166.76 |
| Sulfur-phosphor: spiral shell mite ester (20:1) | 8.76 | 204.00 | 113.31 | 180.04 |
| Sulfur-phosphor: spiral shell mite ester (10:1) | 7.14 | 250.28 | 125.40 | 199.59 |
| Sulfur-phosphor: spiral shell mite ester (1:1) | 3.67 | 486.92 | 239.71 | 203.13 |
| Sulfur-phosphor: spiral shell mite ester (1:10) | 2.78 | 642.81 | 354.01 | 181.58 |
| Sulfur-phosphor: spiral shell mite ester (1:20) | 3.01 | 593.69 | 366.10 | 162.17 |
| Sulfur-phosphor: spiral shell mite ester (1:30) | 3.34 | 535.03 | 370.40 | 144.45 |
| Sulfur-phosphor: spiral shell mite ester (1:40) | 3.83 | 466.58 | 372.60 | 125.22 |
Embodiment 11: sulfur-phosphor and the composite field control effectiveness test to scale insect of spiral shell mite ester
Adopt 40% sulfur-phosphor spirodiclofen water emulsion (embodiment 2) for preventing and treating oranges and tangerines scale insect, investigation insect population radix before dispenser, after medicine, 7d, 14d, 30d investigate residual borer population of living respectively, 2 strains are looked in investigation Shi Mei community, every strain looks into 5 blades respectively by orientation, 4, the four corners of the world, each community looks into 40 blades altogether, records borer population of living, and calculates control efficiency.Control efficiency computational methods are as follows:
Preventive effect (%)=(1-CK
1× Pt
1/ CK
2× Pt
2) × 100
Wherein: CK
1represent insect population number before the medicine of check plot; Pt
1represent insect population number after treatment region medicine;
CK
2represent insect population number after the medicine of check plot; Pt
2represent insect population number before treatment region medicine;
As can be seen from Table 3, during 40% sulfur-phosphor spirodiclofen water emulsion use 325-375mga.i./kg, after medicine, 7d, 14d, 30d are all better than each single dose to the preventive effect of scale insect and are used alone, and after medicine, 30d preventive effect all still reaches more than 80% simultaneously, illustrates that this compound drug has good lasting effect.In pilot survey process, do not find that this compound drug produces poisoning to mandarin tree.
The result of the test of table 3, each process chemical control scale insect
Embodiment 12: sulfur-phosphor and the composite field control effectiveness test to citrus red mite of spiral shell mite ester
Adopt 80% sulfur-phosphor spiral shell mite ester wetting powder (embodiment 8) for preventing and treating citrus red mite, investigation insect population radix before dispenser, after medicine, 7d, 14d, 30d investigate residual mite number of living respectively, 2 strains are looked in investigation Shi Mei community, every strain looks into 5 blades respectively by orientation, 4, the four corners of the world, each community looks into 40 blades altogether, records mite number of living, and calculates control efficiency.Control efficiency computational methods are as follows:
Control efficiency (%)=(1-CK
1× Pt
1/ CK
2× Pt
2) × 100
Wherein: CK
1represent insect population number before the medicine of check plot; Pt
1represent insect population number after treatment region medicine;
CK
2represent insect population number after the medicine of check plot; Pt
2represent insect population number before treatment region medicine;
The result of the test of table 4, each process chemical control citrus red mite
As can be seen from Table 4, during 80% sulfur-phosphor spiral shell mite ester wetting powder use 275-325mga.i./kg, after medicine, 7d, 14d, 30d are all better than each single dose to the preventive effect of citrus red mite and are used alone, after medicine, 30d preventive effect all still reaches more than 80% simultaneously, illustrates that this compound drug has good lasting effect.In pilot survey process, do not find that this compound drug produces poisoning to mandarin tree.
In sum, the present invention adopts two kinds of active components to be the compound insecticidal miticide composition of sulfur-phosphor and spiral shell mite ester, has synergistic function, compared with existing unitary agent, insecticidal effect significantly improves, and the lasting period is long, to crop safety, be worth applying in agricultural production.
Claims (5)
1. contain an insecticide acaricide composition for sulfur-phosphor and spiral shell mite ester, it is characterized in that: active ingredient is sulfur-phosphor and spiral shell mite ester, and the weight ratio of sulfur-phosphor and spiral shell mite ester is 40:1 ~ 1:40.
2. a kind of insecticide acaricide composition containing sulfur-phosphor and spiral shell mite ester according to claim 1, is characterized in that: sulfur-phosphor and spiral shell mite ester weight summation percentage by weight are in the composition 1 ~ 85%.
3. a kind of insecticide acaricide composition containing sulfur-phosphor and spiral shell mite ester according to claim 1, is characterized in that: be prepared into the formulation that suspending agent, aqueous emulsion, microemulsion, water dispersible granules, wetting powder, ultra low volume liquids, microcapsule suspending agent and thermal fog etc. are applicable to agriculturally using when reality uses.
4. a kind of insecticide acaricide composition containing sulfur-phosphor and spiral shell mite ester according to claim 1, is characterized in that: be applied to control various pests agriculturally.
5. a kind of insecticide acaricide composition containing sulfur-phosphor and spiral shell mite ester according to claim 4, is characterized in that: described insect is two spotted spider mite, scale insect.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107711876A (en) * | 2017-11-25 | 2018-02-23 | 惠州市无龄康态健康科技有限公司 | A kind of composition pesticide containing sulfur-phosphor and nitrile pyrrole mite ester |
| CN113826641A (en) * | 2021-09-16 | 2021-12-24 | 陕西上格之路生物科学有限公司 | Insecticide composition containing nitre sulfur and phosphorus |
| CN113925057A (en) * | 2021-09-24 | 2022-01-14 | 陕西上格之路生物科学有限公司 | Insecticide composition containing nitre sulfur and phosphorus |
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| JP2006131516A (en) * | 2004-11-04 | 2006-05-25 | Nippon Nohyaku Co Ltd | Pest control agent composition and method for use thereof |
| CN102125048A (en) * | 2010-12-21 | 2011-07-20 | 威海韩孚生化药业有限公司 | Water emulsion containing spirodiclofen and isocarbophos and preparation method thereof |
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Patent Citations (3)
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| JP2006131516A (en) * | 2004-11-04 | 2006-05-25 | Nippon Nohyaku Co Ltd | Pest control agent composition and method for use thereof |
| CN1742580A (en) * | 2005-09-23 | 2006-03-08 | 四川省化学工业研究设计院 | Sulfur-phosphor built insext-killing mite-killing agent |
| CN102125048A (en) * | 2010-12-21 | 2011-07-20 | 威海韩孚生化药业有限公司 | Water emulsion containing spirodiclofen and isocarbophos and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107711876A (en) * | 2017-11-25 | 2018-02-23 | 惠州市无龄康态健康科技有限公司 | A kind of composition pesticide containing sulfur-phosphor and nitrile pyrrole mite ester |
| CN113826641A (en) * | 2021-09-16 | 2021-12-24 | 陕西上格之路生物科学有限公司 | Insecticide composition containing nitre sulfur and phosphorus |
| CN113826641B (en) * | 2021-09-16 | 2022-09-16 | 陕西上格之路生物科学有限公司 | Insecticide composition containing nitre sulfur and phosphorus |
| CN113925057A (en) * | 2021-09-24 | 2022-01-14 | 陕西上格之路生物科学有限公司 | Insecticide composition containing nitre sulfur and phosphorus |
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| CN104381294B (en) | 2017-07-28 |
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