CN104012551B - A kind of containing paichongding with the composition pesticide of cyflumetofen - Google Patents
A kind of containing paichongding with the composition pesticide of cyflumetofen Download PDFInfo
- Publication number
- CN104012551B CN104012551B CN201410240935.7A CN201410240935A CN104012551B CN 104012551 B CN104012551 B CN 104012551B CN 201410240935 A CN201410240935 A CN 201410240935A CN 104012551 B CN104012551 B CN 104012551B
- Authority
- CN
- China
- Prior art keywords
- cyflumetofen
- paichongding
- composition pesticide
- pesticide
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of containing paichongding with the composition pesticide of cyflumetofen, effective ingredient is paichongding and cyflumetofen, and wherein the weight ratio of paichongding and cyflumetofen is 20:1～1:20, preferably than for 5:1～1:5.Great number of indoor and outdoor experiments show that after being compounded, the present invention has obvious synergistic function, can be used for the insect prevented and treated agriculturally, is particularly adapted to the preventing and treating of red spider, tea lesser leafhopper, aleyrodid, aphid and scale insect；Simultaneously because decrease Pesticide use amount, reduce pesticide residual quantity on crops, alleviate the pollution to environment, delayed the generation of pest resistance to insecticide.
Description
Technical field
The present invention relates to composition pesticide and application thereof, specifically with paichongding with cyflumetofen for effectively becoming
The binary complex divided, is mainly used in the preventing and treating of agriculturally insect.
Background technology
Paichongding, belongs to novel nicotinamide insecticide, and the mechanism of action is to act on the axle synaptic receptor that insecticide is neural, blocks
Nerve conduction.This medicament has good Uptake and translocation function, and after dispenser, medicament can quickly be transmitted to each position of plant.It is to respectively
Plant sucking pest and have preferable prevention effect.
Cyflumetofen, belongs to novel acyl acetonitrile class acaricide, and the mechanism of action is suppression Mitochondrial electron conduction.Mainly should
On the crops such as fruit tree, vegetable, Camellia sinensis and flowers prevent and treat mite pest, simultaneously to diamondback moth, Prodenia litura, striped rice borer,
The diseases such as the insect such as planthopper, black peach aphid and rice blast, powdery mildew, downy mildew also have good preventive and therapeutic effect.
The resistance problems of agricultural pests is a global problem, the emphasis that always agricultural science and technology worker pays close attention to
Problem.Along with to the continuity year in year out of Chemical Control of Harmful Insects, the increase of Pesticide use amount and not scientifical use pesticide
Etc. the impact of factor, causing pest resistance day by day serious, the pest species producing resistance is on the increase.Simultaneously as high intensity
Use pesticide, result in Practice for Pesticide Residue in Agricultural Products and exceed standard, pollute the series of problems such as environment and peasant's drug cost increase, no
It is beneficial to the sustainable development of agricultural.
Therefore, develop efficiently, low toxicity, low-residual, the different mechanism of action, have again the compounding system of synergistic function simultaneously
Agent, not only facilitates the generation delaying pest resistance to insecticide, but also can extend the service life of pesticide species, reduces and uses agent
Amount, cost-effective, reduce the pollution to environment.
The compounded formula of paichongding and cyflumetofen is screened and conducts in-depth research by the present inventor, finds paichongding and fourth
Fluorine demodicid mite ester compounds, and has obvious synergistic function in the range of certain compound proportion, simultaneously in actually used mistake
Cheng Zhong, has outstanding preventing and treating to imitate insect agriculturally, especially red spider, tea lesser leafhopper, aleyrodid, aphid and scale insect
Really, after further study, the present invention is completed.
Summary of the invention
It is an object of the invention to provide a kind of containing paichongding with the composition pesticide of cyflumetofen, this complex composition
There is obvious synergistic function, can be used for the various pests prevented and treated agriculturally, be particularly adapted to red spider, the little greenery of tea
The preventing and treating of Cicadae, aleyrodid, aphid and scale insect.
Another object of the present invention is to the composition pesticide containing paichongding and cyflumetofen, in use can reduce
Dosage, reduce pesticide residual quantity on crops, delay the generation of pest resistance to insecticide, moreover it is possible to make it to various insects
Prevention effect is used alone to compare than single dose and significantly improves, laborsaving, economical, reduces farmer's burdens.
Technical solution of the present invention: a kind of containing paichongding with the composition pesticide of cyflumetofen, with paichongding and fourth fluorine demodicid mite
Ester be the weight ratio of effective ingredient, paichongding and cyflumetofen be 20:1～1:20, preferably than for 5:1～1:5, paichongding and fourth
Fluorine demodicid mite ester weight summation percentage by weight in composition pesticide is 1%～85%, remaining be in pesticide allow use and can
With the auxiliary element accepted.
Described auxiliary element is solvent, emulsifying agent, wetting agent, dispersant, stabilizer, antifreezing agent, thickening agent, disintegrate
One or more combination in agent, binding agent, defoamer, penetrating agent, synergist, fire retardant and filler, above material
It is in pesticidal preparations conventional known substance, is varied from according to being prepared as the different formulations of pesticide, but there is no limit especially
Fixed.
Composition pesticide of the present invention can be prepared as any one dosage form being suitable in agricultural production using by known method,
Reasonable dosage form has suspending agent, aqueous emulsion, microemulsion, water dispersible granules, wettable powder, ultra low volume liquids, microcapsule outstanding
Floating agent and thermal fog.
Frequency of administration and the amount of application of composition pesticide of the present invention have in a small amount with crops, insect, weather condition change
Change, can reach, by using suitable dosage, the purpose effectively prevented and treated.
Compared with prior art, it is an advantage of the current invention that:
1, paichongding and cyflumetofen compound and have synergistic function, are used alone than single dose and significantly improve evil
The prevention effect of worm, expands insecticidal spectrum simultaneously, solves the defect to some insect weak effect when single dose is used alone.
2, paichongding and two kinds of effective ingredient of cyflumetofen compound, and decrease Pesticide use amount, reduce use cost, subtract
The light pollution to environment, delay the generation of pest resistance to insecticide, added the service life of pesticide.
Detailed description of the invention
In order to be more fully understood that the essence of the present invention, below in conjunction with embodiment, present disclosure is described further,
But limitation of the present invention can not be considered as.
(1) Formulation Example.
In following examples, effective ingredient uses the 95% former medicine of paichongding and the former medicine of 97% cyflumetofen, each component percentage
Content is weight percentage.
Embodiment 1:25% paichongding cyflumetofen suspending agent.
Paichongding 15%, cyflumetofen 10%, to methoxyl group fatty acyl anilinesulfonic acid 10%, pull open powder 10%, xanthan
Glue 2%, glycerol 2%, silicone oil 0.1%, deionized water supplies 100%.By above-mentioned effective ingredient, dispersant, wetting agent, thickening
Agent, antifreezing agent, defoamer and deionized water mixing, sand milling in high speed shear dispersion, sand mill, formed in water-medium
High dispersive, stable suspension system, can be prepared by 25% paichongding cyflumetofen suspending agent.
Embodiment 2:30% paichongding cyflumetofen aqueous emulsion.
Paichongding 10%, cyflumetofen 20%, Ketohexamethylene 20%, alkyl phenol polyglycol ether 10%, polycarboxylate 5%,
Sodium sorbate 1%, glycerol 1%, deionized water supplies 100%.By above-mentioned effective ingredient, solvent, emulsifying agent, dispersant and steady
Determining agent and be mixed to form oil phase, antifreezing agent dissolves formation aqueous phase in water, slowly oil phase is added in aqueous phase under cutter effect,
And continue to shear about 30 minutes, can be prepared by the paichongding cyflumetofen aqueous emulsion of 30%.
Embodiment 3:35% paichongding cyflumetofen microemulsion.
Paichongding 25%, cyflumetofen 10%, Hexalin 10%, methanol 5%, castor oil polyoxyethylene ether 15%, Fructus Citri Limoniae
Acid sodium 2%, organosilicon 1.5%, azone 2%, deionized water supplies 100%.Effective ingredient solvent is completely dissolved, the most again
Add emulsifying agent, stabilizer, penetrating agent, synergist mix homogeneously, be eventually adding deionized water, after being sufficiently stirred for, can be prepared by
The paichongding cyflumetofen microemulsion of 35%.
Embodiment 4:40% paichongding cyflumetofen wettable powder.
Paichongding 25%, cyflumetofen 15%, alkylphenol polyoxyethylene 10%, calcium dodecyl benzene sulfonate 10%, silicon
Diatomaceous earth supplies 100%.Effective ingredient, dispersant, wetting agent and filler are mixed above-mentioned, again through air-flow powder after mechanical activation comminution
Broken, mix homogeneously, can be prepared by 40% paichongding cyflumetofen wettable powder.
Embodiment 5:50% paichongding cyflumetofen water dispersible granules.
Paichongding 20%, cyflumetofen 30%, naphthalenesulfonate formaldehyde condensation compound 10%, dodecylbenzene sodium sulfonate 10%,
Ammonium sulfate 3%, polyvinyl alcohol 2%, Kaolin supplies 100%.By above-mentioned effective ingredient, dispersant, wetting agent, disintegrating agent, glue
Knot agent and filler mix homogeneously, pulverize with micro jet, through mediating, is subsequently adding in fluidized-bed granulation dryer and carries out
Pelletize, dry, screening, can be prepared by 50% paichongding cyflumetofen water dispersible granules.
Embodiment 6:10% paichongding cyflumetofen ultra low volume liquids.
Paichongding 6%, cyflumetofen 4%, N-Methyl pyrrolidone 10%, DMF 5%, dibutyl naphthalene sulphur
Acid sodium 5%, castor oil polyoxyethylene ether 3%, double to kill 2.5%, Oleum Gossypii semen complements to 100%.By above-mentioned effective ingredient with molten
After agent stirring and dissolving, add other auxiliary agent, be thoroughly mixed uniformly, can be prepared by 10% paichongding cyflumetofen ultralow
Volume liquids.
Embodiment 7:15% paichongding cyflumetofen microcapsule suspending agent.
Paichongding 10%, cyflumetofen 5%, urea resin prepolymer aqueous solution 25%, Ketohexamethylene 15%, Oleum Ricini polyoxy
Vinyl Ether 5%, polyoxyethylene carboxylate 3%, sodium hydroxide 2%, deionized water complements to 100%.By above-mentioned effective ingredient,
Macromolecule cyst material, solvent mix, make to be dissolved into homogeneous oil phase, in a shear condition, oil phase is joined containing emulsifying agent,
PH adjusting agent, dispersant aqueous phase solution in, surplus deionized water is supplied, and bi-material reacts at oil-water interfaces, shape
Become macromolecule cyst wall, can be prepared by 15% paichongding cyflumetofen microcapsule suspending agent.
Embodiment 8:20% paichongding cyflumetofen thermal fog.
Paichongding 5%, cyflumetofen 15%, dimethylformamide 15%, polycarboxylate 10%, calcium dodecyl benzene sulfonate
5%, azone 2%, ammonium polyphosphate 2%, soybean oil complements to 100%.Above-mentioned effective ingredient and solvent are put into band stirring
In reaction vessel, after effective ingredient fully dissolves, add other auxiliary agent, be sufficiently stirred for about 60 minutes so that it is mix homogeneously,
Can be prepared by 20% paichongding cyflumetofen thermal fog.
(2) indoor biological determination of activity and the field efficacy of the present composition is verified.
1, paichongding and the cyflumetofen indoor joint toxicity measuring to tea lesser leafhopper.
For examination worm: select field to gather and raise tea lesser leafhopper 3 nymph in age of breeding in indoor.
Reagent agent: the 95% former medicine of paichongding and the former medicine of 97% cyflumetofen.
Test method: using infusion process to be measured, concrete grammar is as follows.
Choose the strain of the fresh tea tree germ tip 3, after impregnating 30 seconds in for reagent liquid, take out nature and dry, with the wet defat bale of cotton
Live root moisturizing, outsourcing preservative film, be placed in teat glass (200mm × 30mm), often process 4 times and repeat.Then connect with brush pen
Entering to use tea lesser leafhopper 3 nymph in age of ether light anesthesia, often pipe 20, the mouth of pipe is tightened with white gauze.It is disposed, is placed in sight
Examine indoor.
If the process of the corresponding organic solvent without medicament is as comparison.24h investigation examination worm death condition, note after process
Record total borer population and dead borer population.
Carry out statistical analysis with DPS statistical analysis software, calculate the LC of each medicament50, and calculate mixture according to the abundant method of Sun Yun
Co-toxicity coefficient (CTC value).
Actual measurement toxicity index (ATI)=(standard agent LC50/ reagent agent LC50)×100。
Percentage composition+B medicament the toxicity index of A in theoretical toxicity index (TTI)=A medicament toxicity index × mixture × mixed
The percentage composition of B in agent.
Co-toxicity coefficient (CTC)=[mixture actual measurement toxicity index (ATI)/mixture theory toxicity index (TTI)] × 100.
According to the NY/T11547.7-2006 insecticide combination effect criteria for classifying: co-toxicity coefficient (CTC) >=120 shows as
Potentiation；Co-toxicity coefficient (CTC)≤80 shows as antagonism；80 ＜ co-toxicity coefficient (CTC) ＜ 120 show as being added and make
With.
Table 1, paichongding and the cyflumetofen indoor joint toxicity measuring to tea lesser leafhopper.
| Medicament title and proportioning (weight ratio) | LC50(mg/L) | ATI | TTI | CTC |
| Paichongding | 4.27 | 100.00 | - | - |
| Cyflumetofen | 23.46 | 18.20 | - | - |
| Paichongding: cyflumetofen (20:1) | 3.36 | 127.08 | 96.10 | 132.24 |
| Paichongding: cyflumetofen (10:1) | 3.05 | 140.00 | 92.56 | 151.25 |
| Paichongding: cyflumetofen (5:1) | 2.67 | 159.93 | 86.37 | 185.17 |
| Paichongding: cyflumetofen (1:1) | 4.02 | 106.22 | 59.10 | 179.73 |
| Paichongding: cyflumetofen (1:5) | 7.87 | 54.26 | 31.83 | 170.47 |
| Paichongding: cyflumetofen (1:10) | 10.59 | 40.32 | 25.64 | 157.25 |
| Paichongding: cyflumetofen (1:20) | 14.84 | 28.77 | 22.10 | 130.18 |
During as it can be seen from table 1 paichongding and cyflumetofen are compounding in the range of 20:1～1:20 (by weight), poison altogether
Coefficient (CTC) is all higher than 120, and tea lesser leafhopper is shown synergistic function, especially 5:1's～1:5 (by weight)
In the range of compounding time, synergistic function becomes apparent from, and co-toxicity coefficient (CTC) is all higher than 160, it is seen that paichongding and cyflumetofen
Compounding have reasonability and feasibility.
2, paichongding and the cyflumetofen indoor joint toxicity measuring to citrus red mite.
For examination worm: select field to gather and raise the citrus red mite female one-tenth demodicid mite of breeding in indoor.
Reagent agent: the 95% former medicine of paichongding and the former medicine of 97% cyflumetofen.
Test method uses leaf butterfly nebulization, and concrete operation method is as follows:
Choose the Citrus leaf of healthy growth, make leaf butterfly with card punch, in culture dish, place a wet sponge block, on it
Putting filter paper, foliation butterfly on filter paper, every ware is put 2 pieces of leaf butterflies, is selected citrus red mite female one-tenth demodicid mite healthy, that age is consistent and be inoculated into
On leaf butterfly, every leaf butterfly inoculates 20.
Being placed under potter spray tower by the culture dish being connected to leaf butterfly, spray under 50PSI pressure, spray amount is 1ml, heavy
Take out culture dish after fall 1min, then the culture dish processed is put into 25 DEG C, cultivate in 12H/12H illumination box, after 48h
Check dead borer population, calculate mortality rate.Often process and set 4 repetitions, and set the process of clear water blank.
Carry out statistical analysis with DPS statistical analysis software, calculate the LC of each medicament50, and calculate mixture according to the abundant method of Sun Yun
Co-toxicity coefficient (CTC value).
Actual measurement toxicity index (ATI)=(standard agent LC50/ reagent agent LC50)×100。
Percentage composition+B medicament the toxicity index of A in theoretical toxicity index (TTI)=A medicament toxicity index × mixture × mixed
The percentage composition of B in agent.
Co-toxicity coefficient (CTC)=[mixture actual measurement toxicity index (ATI)/mixture theory toxicity index (TTI)] × 100.
According to the NY/T11547.7-2006 insecticide combination effect criteria for classifying: co-toxicity coefficient (CTC) >=120 shows as
Potentiation；Co-toxicity coefficient (CTC)≤80 shows as antagonism；80 ＜ co-toxicity coefficient (CTC) ＜ 120 show as being added and make
With.
Table 2, paichongding and the cyflumetofen indoor joint toxicity measuring to citrus red mite.
| Medicament title and proportioning (weight ratio) | LC50(mg/L) | ATI | TTI | CTC |
| Paichongding | 18.32 | 100.00 | - | - |
| Cyflumetofen | 4.61 | 397.40 | - | - |
| Paichongding: cyflumetofen (20:1) | 12.21 | 150.04 | 114.16 | 131.43 |
| Paichongding: cyflumetofen (10:1) | 9.83 | 186.37 | 127.04 | 146.70 |
| Paichongding: cyflumetofen (5:1) | 6.89 | 265.89 | 149.57 | 177.77 |
| Paichongding: cyflumetofen (1:1) | 3.86 | 474.61 | 248.70 | 190.84 |
| Paichongding: cyflumetofen (1:5) | 3.06 | 598.69 | 347.83 | 172.12 |
| Paichongding: cyflumetofen (1:10) | 3.27 | 560.24 | 370.36 | 151.27 |
| Paichongding: cyflumetofen (1:20) | 3.89 | 470.95 | 383.24 | 122.89 |
During from table 2 it can be seen that paichongding and cyflumetofen are compounding in the range of 20:1～1:20 (by weight), poison altogether
Coefficient (CTC) is all higher than 120, and citrus red mite is shown synergistic function, especially 5:1's～1:5 (by weight)
In the range of compounding time, synergistic function becomes apparent from, and co-toxicity coefficient (CTC) is all higher than 170, it is seen that paichongding and cyflumetofen
Compounding have reasonability and feasibility.
3, paichongding and the compounding field control effectiveness test to tea lesser leafhopper of cyflumetofen.
Use 25% paichongding cyflumetofen suspending agent embodiment for preventing and treating tea lesser leafhopper, use nebulization.Execute
Yao Qianmei presses community diagonal 5 sampling, chooses for every and has tea tree 2～3 strain of tea lesser leafhopper ovum and adult (depending on insect population
Depending on density), tea lesser leafhopper quantity in probability demarcation strain, in this, as the insect population radix before dispenser.After medicine, 3d, 7d, 14d divide
Tiao Cha not remain tea lesser leafhopper borer population alive, record borer population of living, calculate prevention effect.Prevention effect computational methods are as follows:
Preventive effect (%)=(1-CK1×Pt1/CK2×Pt2)×100。
Wherein: CK1Represent insect population number before the medicine of check plot；Pt1Represent insect population number after treatment region medicine；
CK2Represent insect population number after the medicine of check plot；Pt2Represent insect population number before treatment region medicine；
Table 3, each result of the test processing chemical control tea lesser leafhopper.
During from table 3 it can be seen that 25% paichongding cyflumetofen suspending agent uses 1500-2000 times, 3d after medicine, 7d,
14d is superior to each single dose to the preventive effect of tea lesser leafhopper and is used alone, and after medicine, 14d preventive effect the most still reaches more than 85% simultaneously, explanation
This compound drug has good lasting effect.During test survey, do not find that this compound drug produces poisoning to Camellia sinensis.
4, paichongding and the compounding field control effectiveness test to citrus red mite of cyflumetofen.
Use 40% paichongding cyflumetofen wettable powder embodiment for preventing and treating citrus red mite, investigate before dispenser
Insect population radix, after medicine, 7d, 14d, 30d investigate residual demodicid mite number alive respectively, and 2 strains are looked in investigation Shi Mei community, and 4, the four corners of the world is pressed in every strain
5 blades are looked in orientation respectively, and each community looks into 40 blades altogether, record demodicid mite number of living, and calculate prevention effect.Prevention effect calculating side
Method is as follows:
Prevention effect (%)=(1-CK1×Pt1/CK2×Pt2)×100。
Wherein: CK1Represent insect population number before the medicine of check plot, Pt1Represent insect population number after treatment region medicine,
CK2Represent insect population number after the medicine of check plot, Pt2Represent insect population number before treatment region medicine.
Table 4, each result of the test processing chemical control citrus red mite.
During from table 4, it can be seen that 40% paichongding cyflumetofen wettable powder uses 2500-3000 times, 7d after medicine,
14d, 30d are superior to each single dose to the preventive effect of citrus red mite and are used alone, and after medicine, 30d preventive effect the most still reaches more than 80% simultaneously,
Illustrate that this compound drug has good lasting effect.During test survey, do not find that this compound drug produces medicine to Citrus
Evil.
In sum, the compound pesticide composition that the present invention uses two kinds of active component to be paichongding and cyflumetofen, tool
Having synergistic function, compared with existing unitary agent, insecticidal effect significantly improves, and the lasting period is long, to crop safety, value
Obtain popularization and application in agricultural production.
Claims (5)
1. one kind contains paichongding and the composition pesticide of cyflumetofen, it is characterised in that: effective ingredient is paichongding and fourth fluorine
The weight ratio of demodicid mite ester, paichongding and cyflumetofen is 20:1～1:20, paichongding and cyflumetofen gross weight in the composition
Percentage composition is 1～85%.
It is the most according to claim 1 a kind of containing paichongding with the composition pesticide of cyflumetofen, it is characterised in that: piperazine worm
The weight ratio of pyridine and cyflumetofen is 5:1～1:5.
It is the most according to claim 1 a kind of containing paichongding with the composition pesticide of cyflumetofen, it is characterised in that: described
The dosage form of composition pesticide is suspending agent, aqueous emulsion, microemulsion, water dispersible granules, wettable powder, ultra low volume liquids, micro-
One in capsule suspending agent and thermal fog.
4. the use of the insect agriculturally of a kind of composition pesticide preventing and treating containing paichongding and cyflumetofen described in claim 1
On the way.
Purposes the most according to claim 4, it is characterised in that: described insect is red spider, tea lesser leafhopper, aleyrodid, aphid
Worm and scale insect.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410240935.7A CN104012551B (en) | 2014-05-30 | 2014-05-30 | A kind of containing paichongding with the composition pesticide of cyflumetofen |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410240935.7A CN104012551B (en) | 2014-05-30 | 2014-05-30 | A kind of containing paichongding with the composition pesticide of cyflumetofen |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104012551A CN104012551A (en) | 2014-09-03 |
| CN104012551B true CN104012551B (en) | 2017-01-04 |
Family
ID=51429782
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410240935.7A Active CN104012551B (en) | 2014-05-30 | 2014-05-30 | A kind of containing paichongding with the composition pesticide of cyflumetofen |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104012551B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104304284B (en) * | 2014-10-27 | 2016-08-17 | 池州弘利农业科技开发有限公司 | A kind of containing paichongding with the insecticidal synergistic composition of capillary |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1446196A (en) * | 2000-08-11 | 2003-10-01 | 大塚化学控股株式会社 | Acylacetonitriles, process for preparation thereof and miticides containing the same |
| CN101045728A (en) * | 2006-03-28 | 2007-10-03 | 华东理工大学 | Preparation method and use of compound with high insecticidal activity |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009209124A (en) * | 2008-02-06 | 2009-09-17 | Nissan Chem Ind Ltd | Insect- or acarian-controlling composition |
-
2014
- 2014-05-30 CN CN201410240935.7A patent/CN104012551B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1446196A (en) * | 2000-08-11 | 2003-10-01 | 大塚化学控股株式会社 | Acylacetonitriles, process for preparation thereof and miticides containing the same |
| CN101045728A (en) * | 2006-03-28 | 2007-10-03 | 华东理工大学 | Preparation method and use of compound with high insecticidal activity |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104012551A (en) | 2014-09-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104115861B (en) | A kind of insecticide acaricide composition containing sulfur-phosphor and cyflumetofen | |
| CN104082300B (en) | Insecticide acaricide composition containing pyriproxyfen and spirodiclofen | |
| CN104542618A (en) | Synergetic acaricidal composition containing cyenopyrafen and etoxazole | |
| CN104106593B (en) | A kind of insecticide acaricide composition that contains sulfur-phosphor and second mite azoles | |
| CN104381294B (en) | A kind of insecticide acaricide composition containing sulfur-phosphor and Envidor | |
| CN104012551B (en) | A kind of containing paichongding with the composition pesticide of cyflumetofen | |
| CN104115850A (en) | Insect and mite killing composition containing etoxazole and spirotetramat | |
| CN103931621B (en) | A kind of containing Tolfenpyrad with the composition pesticide of cyflumetofen | |
| CN104738046A (en) | Insecticidal composition containing pyridine quinazoline and cyhalodiamide | |
| CN104286010B (en) | Composition pesticide containing sulfur-phosphor and Bifenazate | |
| CN104115833A (en) | Insect and mite killing composition containing pyriproxyfen and cyflumetofen | |
| CN103931617B (en) | A kind of containing flonicamid with the composition pesticide of cyflumetofen | |
| CN103931642B (en) | A kind of containing indoxacarb with the composition pesticide of cyflumetofen | |
| CN105941423B (en) | A kind of Pesticidal combination containing capillary and cyromazine | |
| CN104585179B (en) | A kind of Synergistic mite killing composition containing tebufenpyrad and spirodiclofen | |
| CN104026144A (en) | Pesticide composition containing thiamethoxam and cyflumetofen | |
| CN105794859A (en) | Insecticidal compound containing conidioblous thromboides and biological sources | |
| CN104012568A (en) | A pesticide composition comprising dinetofuran and cyflumetofen | |
| CN106973949B (en) | A kind of Pesticidal combination and application thereof comprising bitter pueraria root extract and matrine | |
| CN104115843A (en) | Insect and mite killing composition containing pyriproxyfen and etoxazole | |
| CN104082322A (en) | Insecticide acaricide composition containing pyriproxyfen and bifenazate | |
| CN104186500A (en) | Insecticidal and acaricidal composition containing buprofezin and spirodiclofen | |
| CN104542606A (en) | Synergetic acaricidal composition containing cyenopyrafen and cyflumetofen | |
| CN104012567A (en) | A pesticide composition comprising clothianidin and cyflumetofen | |
| CN105638719A (en) | Pesticide insecticidal composition containing Wufuchongzong |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| EXSB | Decision made by sipo to initiate substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |