CN102626068B - Ultra-low-volume liquid containing cyantraniliprole and carbamate pesticide - Google Patents
Ultra-low-volume liquid containing cyantraniliprole and carbamate pesticide Download PDFInfo
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- CN102626068B CN102626068B CN201210088065.7A CN201210088065A CN102626068B CN 102626068 B CN102626068 B CN 102626068B CN 201210088065 A CN201210088065 A CN 201210088065A CN 102626068 B CN102626068 B CN 102626068B
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Abstract
The invention relates to ultra-low-volume liquid containing cyantraniliprole and carbamate pesticide. Cyantraniliprole and an active ingredient II are compounded to form a chemical component of the ultra-low-volume liquid, and remaining components include a surfactant and a solvent. The active ingredient II is optionally one of carbosulfan, benfuracarb, nitrilacarb, fenobucarb, isoprocarb, triazamate, pirimicarb, metolcarb, dimethacarb, carbaryl, methiocarb, methomyl or thiodicarb. The ultra-low-volume liquid is convenient to process, long in lasting effect and high in work efficiency, targets cannot generate pesticide resistance easily, the environmental pollution is low, the pesticide and water are saved, the pesticide utilizing rate is improved, and various pests of rice, wheat, corns, vegetables, tobaccos, tea trees, fruit trees and sugarcane can be controlled by ultra-low-volume spraying, low-volume spraying or ultra-low-volume electrostatic spraying.
Description
Technical field
The present invention relates to pesticide field, is containing the ultra low volume liquids of cyanogen insect amide and carbamate insecticide specifically, mainly realizes the effective control to crop pest by ultra low volume spraying, low-gallonage spraying or ultra low volume electrostatic spray.
Background technology
At present for the control of insect that easily produces resistance in agricultural, what main way was exploitation and existing kind without between the new composition of cross resistance or existing pesticide species is composite, the former is because required development cost is high, the cycle is long, and the speed that development rate produces less than pest resistance to insecticide far away at present.Therefore, carry out for the different existing pesticide species of the mechanism of action selection that mixture is a kind of the best.If reasonable mixture ratio, can produce significant synergistic effect, make field control effect significantly be better than the effect of each single dose.On agricultural insect pests control, usually there is certain defect in the insecticide that contains single-activity composition, continuous several times is used and not only makes insect easily develop immunity to drugs, and easily cause the pollution to food and environment, can overcome above shortcoming by rational mixture between pesticide active ingredient.The reasonably composite synergistic effect that active ingredient is produced simultaneously, can improve preventive effect, reduce effective ingredient consumption, cost-saving, delay the drug-fast generation of insect, closely can alleviate and even avoid the pollution of agricultural chemicals to food and environment, and the efficient novel pesticide of the low toxicity that the present invention researchs and develops, not only target drug effect is significantly strengthened, and very low on the impact of people, crop, non-target and environment.
Cyanogen insect amide English name is Cyantraniliprole, trade name is CyazypyrTM, test code number is DPX-HGW86, chemical name is the bromo-N-of 3-(4-cyano group-2-methyl-6-(amino-carbonyl) phenyl)-1-(3-chloropyridine-2-yl)-1H-pyrazoles-5-carboxylic acid amides, be the novel O-formammidotiazol-benzamide insecticide that du pont company develops, its chemical structural formula is
Cyanogen insect amide belongs to insect ryanodine receptor inhibitor, in the striated muscle mainly regulating and controlling by induction insect ryanodine receptor and smooth muscle cell, calcium ion discharges to show and tags and stomach poison function, can be for the control of the various crop insects such as paddy rice, vegetables, cotton, beet, especially the control of each Species of Lepidopterous Insect Pests and sucking pest is had to special efficacy, its control efficiency is significantly due to other commercialization insecticide varieties that use in current production, and other insecticides are not existed to cross resistance.Therefore, cyanogen insect amide is described as efficient pesticides of new generation in the world.
Carbamate insecticide have effect rapidly, high, the majority of selectivity have interior absorption, low to warm blooded animal toxicity, there is no the advantages such as residual hazard, especially leafhopper and plant hopper are had to special efficacy.But some kind insecticidal spectrum is wideless, has limited the scope of application, and minority kind is very high to person poultry toxicity, use not too safe; Some insect can produce resistance to carbamate chemicals for agriculture, and rational mixture can overcome above shortcoming.In the present invention, the chemical name of the related carbamate insecticide of active component II is as follows:
The chemical name of carbosulfan is 2,3-dihydro-2,2-dimethyl benzofuran-7-base (dibutylamino sulphur) methyl carbamate;
The chemical name of Benfuracard micro is N-[2,3-dihydro-2,2-dimethyl benzofuran-7-base oxygen carbonyl (methyl) ammonia sulfenyl]-N-isopropyl-Beta-alanine ethyl ester;
The chemical name of nitrilacarb is 4,4-dimethyl-5-(methylamino formyloxy imino group) valeronitrile;
The chemical name of Bassa is 2-2-phenylbutane base-N-methyl carbamate;
The chemical name of Mobucin is 2-isopropyl phenyl-N-methyl carbamate;
The chemical name of triaguron is (3-tertiary butyl-1-dimethylamino formyl-1H-1,2,4-triazole-5-base sulphur) ethyl acetate;
The chemical name of Aphox is 5,6-dimethyl-2-dimethylamino-4-pyrimidine radicals-N, N-dimethylcarbamate;
The chemical name of meta-tolyl-N-methylcarbamate (MTMC) is m-tolyl-N-methyl carbamate;
The chemical name of dimethyl phenyl carbamate is Mixed XYLENE base-N-methyl carbamate;
The chemical name of carbaryl is 1 naphthyl N methyl carbamate;
The chemical name of mercaptodimethur is 3,5-dimethyl-4-(methyl mercapto) phenyl-N-methyl carbamate;
The chemical name of Methomyl is 1-(methyl mercapto) ethylidene ammonia-N-methyl carbamate;
The chemical name of UC-51762 is 3,7,9,13-tetramethyl-5,11-dioxa-2,8,14-, tri-thia-4,7,9,12-, tetra--azepine pentadecane-3,12-diene-6,10-diketone.
The solvent that ultra low volume liquids is low by screening volatility, flash-point is high, good to former medicine dissolubility, low to chemical injury of crops, viscosity is low, when dispenser, be not watered, but directly use with ultra low volume sprayer tool, low-gallonage spraying apparatus or ultra low volume electrostatic spray apparatus.Ultra low volume spraying is owing to not containing high volatile volatile composition in droplet, and its size does not have significant change with quality from leave spraying apparatus arrival target process, has reduced and has volatilized with elegant.Droplet is tiny and even, meets " biological best granula " requirement, has significantly improved deposition.Owing to using without being watered, ultra low volume liquids is suitable for the occasion of water scarcity, the generation of damage by disease and insect fulminant large area and dispenser on a large scale in the palpus short time, and ultra low volume spraying simultaneously reduces operator's labour intensity greatly.
Ultra low volume spraying technology has the following advantages:
1. spouting liquid is few, be only conventional spraying hundreds of/mono-.
2. droplet is little, and ultra low volume electrostatic spray fogdrop diameter is that 30～60 μ m, ultra low volume ground spraying droplet diameter are 30～80 μ m, aerial ultra low volume spraying fogdrop diameter 30～60 μ m, and conventional spraying droplet diameter is many more than 200～600 μ m.
3. spray pattern is the spraying of drift accumulation property, and conventional spraying is specific aim spraying, facing to crop spraying.
What 4. ultra low volume sprayed is the finish take oil as carrier, and concentration is generally a few percent to percent tens; And the conventional water diluent agent concentration spraying is very low, be generally some thousandths of to ten thousand/several.
5. work efficiency is high, and control in time.Hand-held ultra-low-volume sprayer improves 20～30 times of work efficiency than manual compression sprayer, because its work efficiency is high, can timely and effectively prevent and treat fulminant insect, as plant hopper, mythimna separata, locust etc.
6. save agricultural chemicals.Save agricultural chemicals more than 30% with general than conventional spraying.
7. water not.Save water intaking, made up a prescription and the heavy physical labor such as negative water operation, especially used at the hilly and mountainous land of drought, manpower shortage and water intaking difficulty, more convenient.
8. good drug efficacy, holding effect is long.Oil agricultural chemicals is easy to penetrate ester dissolubility insect body surface and enters in pest body, show as desinsection rapidly, good drug efficacy; In finish, occupy the high boiling point auxiliary agent of larger proportion, can play the protective effects such as resistant to hydrolysis, anti-oxidant, anti-photodissociation to pesticide active ingredient, show as holding effect long.
9. to crop safety.Ultra low volume spraying is difficult for producing poisoning to crop safety, without obviously residual, can improve crop quality.
10. expenses for prevention and control is low.Because ultra low volume spraying has the advantages such as province's medicine, laborsaving, water, good drug efficacy, holding effect be not long, therefore expenses for prevention and control is lower than conventional spraying.
Summary of the invention
The object of this invention is to provide a kind of ultra low volume liquids preparation containing cyanogen insect amide and carbamate insecticide, and the preparation method of described ultra low volume liquids is provided.
The ultra low volume liquids formulation that the present invention makes, it is composite as active component take cyanogen insect amide and active component II, all the other supply 100% ultra low volume liquids with surfactant and solvent; Active component II is any one of carbosulfan, Benfuracard micro, Bassa, Mobucin, triaguron, Aphox, meta-tolyl-N-methylcarbamate (MTMC), dimethyl phenyl carbamate, carbaryl, mercaptodimethur, Methomyl or UC-51762.
This ultra low volume liquids is composite as active component take cyanogen insect amide and active component II, the weight content of its total amount is 0.2%～70%, the weight content of cyanogen insect amide is 0.1%～20%, the weight content of active component II is 0.1%～50%, the weight content of auxiliary agent is 1%～10%, and solvent complements to 100%.
Applicable surfactant is selected from OPEO, fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, phenethyl phenol polyethenoxy ether, alkylaryl polyoxyethylene polyoxypropylene ether, aliphatic alcohol polyoxyvinethene phosphate, alkylphenol polyoxyethylene phosphate, phenethyl phenol polyethenoxy ether phosphate, alkylaryl polyoxyethylene polyoxypropylene ether phosphate, castor oil polyoxyethylene ether, the combination of one or more in calcium dodecyl benzene sulfonate, preferred fat alcohol APEO, alkylphenol polyoxyethylene, phenethyl phenol polyethenoxy ether, alkylaryl polyoxyethylene polyoxypropylene ether, castor oil polyoxyethylene ether, or calcium dodecyl benzene sulfonate etc.
Applicable solvent is one or more combinations in aromatic hydrocarbon solvent, plant oil solvent and polar solvent; Aromatic hydrocarbon solvent comprises trimethylbenzene, o-dichlorohenzene, durene, diethylbenzene, methyl-propyl benzene, butylbenzene, methyl naphthalene or two wires wet goods; Plant oil solvent comprises soybean oil, cottonseed oil, corn oil, rapeseed oil, castor oil, turpentine oil, methyl oleate or ethyl oleate etc.; Polar solvent comprises acetophenone, phenmethylol, methyl-sulfoxide, 1-METHYLPYRROLIDONE, DMF, DMA, n-hexyl alcohol, n-octyl alcohol or terpineol etc.
The preparation method of ultra low volume liquids of the present invention is: at the mixing kettle of belt stirrer first with partial solvent by after active component stirring and dissolving, add again surfactant and remaining solvent composition, fully be uniformly mixed,, obtain the ultra low volume liquids containing cyanogen insect amide and carbamate insecticide.
Technological parameter is: mixing speed control is 60～150 revs/min, and mixing time is 15～60 minutes, and temperature is normal temperature, and pressure is normal pressure.
Applicable target crop is the cereal crops such as paddy rice, wheat, the economic crops such as sugarcane, banana, rubber, cotton, tea tree, oranges and tangerines, apple, hawthorn, peach, the vegetable crops such as tomato, eggplant, capsicum, lettuce, celery, wild cabbage, Kidney bean, broad bean, cowpea, pea, the ground family crops such as cucumber, pumpkin, watermelon.
Ultra low volume liquids of the present invention is applicable to control rice fulgorid, rice leaf roller, brown planthopper, white-backed planthopper, small brown rice planthopper, striped rice borer, rice thrips, rice gall midge, rice leafhopper, rice leafhopper, rice spider rafter stinkbug, resemble star stinkbug, green rice bug resemble, red must fleahopper, the negative mixed worm of rice, rice cylinder water snout moth's larva, oryza chinensis, Phytophthira, aleyrodid class, a red-spotted lizard class, unaspis shield kuwana, the green stinkbug of Zhu, peach fruit borer, tangerine lyonetid, the thin moth of tea, striped flea-beetle, the beans fly of diving.The cured a red-spotted lizard in angle, diamond-back moth, two secret notes are chrysomelid, tea golden thistle horse, onion thrips, golden thistle horse, oranges and tangerines golden thistle horse, soybean pod gall-midge, tomato Liriomyza.
The method for optimizing of using ultra low volume liquids of the present invention is ultra low volume spraying, is secondly low-gallonage spraying and ultra low volume electrostatic spray, and according to controlling object, a situation arises determines suitable dosage, and conventionally formulation rate is 75～150g a.i./hm
2.
The inventor is by studies have shown that, the ultra low volume liquids that the arbitrary pesticide active ingredient in cyanogen insect amide and carbosulfan, Benfuracard micro, nitrilacarb, Bassa, Mobucin, triaguron, Aphox, meta-tolyl-N-methylcarbamate (MTMC), dimethyl phenyl carbamate, carbaryl, mercaptodimethur, Methomyl, UC-51762 is re-dubbed has extremely strong synergistic effect to target pest.
Ultra low volume liquids of the present invention is easy to process, with low cost, good drug efficacy, holding effect long, coordinate synergy high, save water; Can reduce environmental pollution, improve agricultural chemicals availability, reduce applications of pesticide amount.
Embodiment
Below in conjunction with embodiment, the present invention is further described, but do not limit the scope of the invention.
Embodiment 1
Prepare 20.1% cyanogen insect amide carbosulfan ultra low volume liquids
Preparation technology: at the mixing kettle of belt stirrer first with partial solvent by after active component cyanogen insect amide and carbosulfan stirring and dissolving, add again surfactant and remaining solvent composition, fully be uniformly mixed, obtain 20.1% cyanogen insect amide carbosulfan ultra low volume liquids; Technological parameter is: mixing speed control is 60～150 revs/min, and mixing time is 15～60 minutes, and temperature is normal temperature, and pressure is normal pressure.
According to the step of preparation process identical with embodiment 1, can prepare following examples.
Embodiment 2
Prepare 52% cyanogen insect amide carbosulfan ultra low volume liquids
Embodiment 3
Prepare 22% cyanogen insect amide Benfuracard micro ultra low volume liquids
Embodiment 4
Prepare 30% cyanogen insect amide Benfuracard micro ultra low volume liquids
Embodiment 5
Prepare 17% nitrilacarb cyanogen insect amide ultra low volume liquids
Embodiment 6
Prepare 20.1% nitrilacarb cyanogen insect amide ultra low volume liquids
Embodiment 7
Prepare 20.1% cyanogen insect amide Bassa ultra low volume liquids
Embodiment 8
Prepare 50.1% cyanogen insect amide Bassa ultra low volume liquids
Embodiment 9
Prepare 12% cyanogen insect amide Mobucin ultra low volume liquids
Embodiment 10
Prepare 20.1% cyanogen insect amide Mobucin ultra low volume liquids
Embodiment 11
Prepare 10% cyanogen insect amide triaguron ultra low volume liquids
Embodiment 12
Prepare 20.1% cyanogen insect amide triaguron ultra low volume liquids
Embodiment 13
Prepare 25% cyanogen insect amide Aphox ultra low volume liquids
Embodiment 14
Prepare 50.1% cyanogen insect amide Aphox ultra low volume liquids
Embodiment 15
Prepare 16% cyanogen insect amide meta-tolyl-N-methylcarbamate (MTMC) ultra low volume liquids
Embodiment 16
Prepare 20.1% cyanogen insect amide meta-tolyl-N-methylcarbamate (MTMC) ultra low volume liquids
Embodiment 17
Prepare 12% dimethyl phenyl carbamate cyanogen insect amide ultra low volume liquids
Embodiment 18
Prepare 35% dimethyl phenyl carbamate cyanogen insect amide ultra low volume liquids
Embodiment 19
Prepare 20% carbaryl cyanogen insect amide ultra low volume liquids
Embodiment 20
Prepare 35% carbaryl cyanogen insect amide ultra low volume liquids
Embodiment 21
Prepare 15% mercaptodimethur cyanogen insect amide ultra low volume liquids
Embodiment 22
Prepare 51% mercaptodimethur cyanogen insect amide ultra low volume liquids
Embodiment 23
Prepare 16% Methomyl cyanogen insect amide ultra low volume liquids
Embodiment 24
Prepare 50.1% Methomyl cyanogen insect amide ultra low volume liquids
Embodiment 25
Prepare 11% cyanogen insect amide UC-51762 ultra low volume liquids
Embodiment 26
Prepare 20.1% cyanogen insect amide UC-51762 ultra low volume liquids
The prepared ultra low volume liquids outward appearance containing cyanogen insect amide and carbamate insecticide is homogeneous oily liquids; Low-temperature phase capacitive is good, under-5 ℃ of conditions, and not crystallization and suspension of refrigeration 7d; Volatility is low, and filter paper hangs sends out measurement result, and volatility is lower than 30%; To plant safety, without poisoning; The employing method of remaining silent is measured, and flash-point is greater than 70 ℃; Viscosity is less than 30mPas; Conductance is 1 × 10
-6～1 × 10
-10within the scope of s/cm.
The furthermore bright beneficial effect of the present invention of field efficacy measurement result carrying out in conjunction with the application embodiment of the present invention more below.
Application Example of the present invention is the method that adopts Toxicity Determination and field control effectiveness test to combine.First pass through Toxicity Determination, co-toxicity coefficient (CTC) after clear and definite two kinds of medicaments are composite by a certain percentage, CTC < 80 is antagonism, 80 < CTC < 120 are summation action, CTC > 120 is synergistic effect, on this basis, then carry out field control effectiveness test.
Application Example 1
Controlling object: rice fulgorid
Experiment place: rice field, Yongxiu County, Nanchang City
Application method: ultra low volume spraying
Formulation rate: 120g a.i./hm
2
Contrast medicament: 25% pymetrozine wp, preparation mu consumption 16g, is diluted with water to the conventional spraying of 30L
Table 1: control rice fulgorid field control effectiveness test result
As can be seen from Table 1: ultra low volume liquids of the present invention adopts ultra low volume spraying method control rice fulgorid, and than contrasting, the conventional spraying of medicament quick-acting is strong, control efficiency good, the lasting period is longer.
Application Example 2
Controlling object: rice leaf roller
Experiment place: rice field, Ke Li village, Xixiangtang District, Nanning City
Application method: ultra low volume spraying
Formulation rate: 120g a.i./hm
2.
Contrast medicament: 1.8% Avermectin EC, preparation mu consumption 200ml, is diluted with water to the conventional spraying of 30L
Table 2: control rice leaf roller test of pesticide effectiveness result
As can be seen from Table 2: ultra low volume liquids of the present invention adopts ultra low volume spraying method control rice leaf roller, and than contrasting, the conventional spraying of medicament quick-acting is strong, control efficiency good, the lasting period is longer.
Claims (2)
1. containing a ultra low volume liquids for cyanogen insect amide and carbamate insecticide, it is characterized in that: it is composite as active component take cyanogen insect amide and active component II, and all the other supply 100% ultra low volume liquids with surfactant and solvent; Active component II is any one of carbosulfan, Bassa, Mobucin, meta-tolyl-N-methylcarbamate (MTMC), dimethyl phenyl carbamate, carbaryl, Methomyl;
Cyanogen insect amide and active component II are composite is active component, the weight content of its total amount is 0.2%～70%, and the weight content of cyanogen insect amide is 0.1%～20%, and the weight content of active component II is 0.1%～50%, the weight content of surfactant is 1%～10%, and solvent complements to 100%;
Described surfactant is one or more the combination in OPEO, fatty alcohol-polyoxyethylene ether, phenethyl phenol polyethenoxy ether phosphate, alkylaryl polyoxyethylene polyoxypropylene ether phosphate, castor oil polyoxyethylene ether or calcium dodecyl benzene sulfonate;
Described solvent is one or more combinations in aromatic hydrocarbon solvent, plant oil solvent and polar solvent; Aromatic hydrocarbon solvent comprises two wires oil; Plant oil solvent comprises soybean oil, cottonseed oil, rapeseed oil, turpentine oil or methyl oleate; Polar solvent comprises phenmethylol, 1-METHYLPYRROLIDONE, DMF, n-hexyl alcohol or n-octyl alcohol.
2. the preparation method of the ultra low volume liquids containing cyanogen insect amide and carbamate insecticide according to claim 1, it is characterized in that: at the mixing kettle of belt stirrer first with partial solvent by after active component stirring and dissolving, add again surfactant and remaining solvent composition, fully be uniformly mixed, obtain the ultra low volume liquids containing cyanogen insect amide and carbamate insecticide; Technological parameter is: mixing speed control is 60～150 revs/min, and mixing time is 15～60 minutes, and temperature is normal temperature, and pressure is normal pressure.
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| CN103766361B (en) * | 2014-02-23 | 2016-04-20 | 红河蔗保科技有限责任公司 | Insecticide of a kind of containing chlorantraniliprole and carbosulfan and preparation method thereof |
| CN106614675A (en) * | 2016-12-16 | 2017-05-10 | 张宗斌 | Pesticide composition for preventing and controlling thrips of mangoes |
| CN112998020A (en) * | 2019-12-20 | 2021-06-22 | 江苏功成生物科技有限公司 | Insecticidal composition containing second-generation ryanodine receptor inhibitor and application thereof |
| CN111194747B (en) * | 2020-01-21 | 2023-09-19 | 中国农业科学院植物保护研究所 | Insecticidal composition with systemic synergistic effect and application thereof |
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|---|---|---|---|---|
| CN1988803A (en) * | 2004-07-26 | 2007-06-27 | 杜邦公司 | Mixtures of anthranilamide invertebrate pest control agents |
| WO2011117272A2 (en) * | 2010-03-24 | 2011-09-29 | Syngenta Participations Ag | Pesticidal mixtures |
| GB2481118A (en) * | 2010-06-09 | 2011-12-14 | Syngenta Participations Ag | Pesticidal mixtures comprising enantiomerically enriched isoxazoline derivatives |
| CN102326577A (en) * | 2011-10-19 | 2012-01-25 | 北京燕化永乐农药有限公司 | Pesticide composition |
| CN102349504A (en) * | 2011-09-13 | 2012-02-15 | 广西田园生化股份有限公司 | Flonicamid-containing ultralow volume liquid agent |
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Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1988803A (en) * | 2004-07-26 | 2007-06-27 | 杜邦公司 | Mixtures of anthranilamide invertebrate pest control agents |
| WO2011117272A2 (en) * | 2010-03-24 | 2011-09-29 | Syngenta Participations Ag | Pesticidal mixtures |
| GB2481118A (en) * | 2010-06-09 | 2011-12-14 | Syngenta Participations Ag | Pesticidal mixtures comprising enantiomerically enriched isoxazoline derivatives |
| CN102349504A (en) * | 2011-09-13 | 2012-02-15 | 广西田园生化股份有限公司 | Flonicamid-containing ultralow volume liquid agent |
| CN102326577A (en) * | 2011-10-19 | 2012-01-25 | 北京燕化永乐农药有限公司 | Pesticide composition |
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