CN102630695A - Ultra low volume concentrate containing lufenuron and nicotine insecticides - Google Patents
Ultra low volume concentrate containing lufenuron and nicotine insecticides Download PDFInfo
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- CN102630695A CN102630695A CN2012100941468A CN201210094146A CN102630695A CN 102630695 A CN102630695 A CN 102630695A CN 2012100941468 A CN2012100941468 A CN 2012100941468A CN 201210094146 A CN201210094146 A CN 201210094146A CN 102630695 A CN102630695 A CN 102630695A
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- 0 C*=C(N=CC*1C(N*)SCC1)Cl Chemical compound C*=C(N=CC*1C(N*)SCC1)Cl 0.000 description 1
- MRVDRBBQBVTEFF-UHFFFAOYSA-N CNC(NCc(cn1)ccc1Cl)=C[NH+]([O-])O Chemical compound CNC(NCc(cn1)ccc1Cl)=C[NH+]([O-])O MRVDRBBQBVTEFF-UHFFFAOYSA-N 0.000 description 1
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Abstract
The invention relates to an ultra low volume concentrate containing lufenuron and nicotine insecticides. The concentrate is characterized in that lufenuron and an active ingredient II are compounded to form a chemical ingredient; other ingredients are a surfactant and a solvent; and the active ingredient II is any one of imidacloprid, acetamiprid, nitenpyram, clothianidin, thiamethoxam, thiacloprid and dinotefuran. The concentrate has the following advantages: the concentrate is convenient to process, has long acting time and high work efficiency, ensures that the targets do not have drug resistance easily, is low in environmental pollution, saves pesticides and water, improves the utilization rate of the pesticides and can be used for controlling various pests of rice, wheat, corn, vegetables, tobaccos, tea trees, fruit trees and sugarcanes through ultra low volume spraying, low volume spraying or ultra low volume electrostatic spraying.
Description
Technical field
The present invention relates to pesticide field, is the ultra low volume liquids that contains Acarus tritici urea and nicotinic insecticide specifically, mainly realizes the effective control to crop pest through ultra low volume spraying, low-gallonage spraying or ultra low volume electrostatic spray.
Background technology
At present for the control of insect that is prone to produce resistance on the agricultural; Main way is that exploitation and existing kind do not have composite between new composition or the existing pesticide species of cross resistance; The former is because required development cost is high, the cycle is long, and at present development rate far away less than the speed of pest resistance to insecticide generation.Therefore, being mixed for the different existing pesticide species of the mechanism of action is a kind of selection of the best.If reasonable mixture ratio then can produce significant synergistic effect, make field control effect significantly be superior to the effect of each single agent.Usually there is certain defective in the insecticide that contains the single-activity composition on agricultural insect pests control; Continuous several times is used and is not only made insect be easy to generate pesticide resistance; And be prone to cause pollution, can overcome above shortcoming through rationally being mixed between the pesticide active ingredient to food and environment.The reasonably composite simultaneously synergistic effect that active ingredient is produced can improve preventive effect, reduces the effective ingredient consumption; Practice thrift cost; Delay the drug-fast generation of insect, closely can alleviate even avoid the pollution of agricultural chemicals food and environment, and the efficient novel pesticide of the low toxicity that the present invention researchs and develops out; Not only the target drug effect is significantly strengthened, and very low to the influence of people, crop, non-target and environment.
The Acarus tritici urea is a latest generation substituted urea class insecticide, and English name is Lufenuron, and chemical name is 1-[2,5-two chloro-4-(1,1,2,3,3,3-hexafluoro propoxyl group) phenyl]-3-(2, the 6-difluoro benzoyl) urea, and chemical structural formula does
This medicament is mainly used in larvas such as Lepidoptera such as control cotton, corn, vegetables, fruit tree through acting on insect larvae, stoping the decortication process to kill off the insect pests; Also can be used for preventing and treating the insect of animal such as ox etc.Medicament is through acting on insect larvae, stoping the decortication process to kill off the insect pests; Especially food leaf caterpillars such as fruit tree there is outstanding preventive effect; Thrips, rust mite, trialeurodes vaporariorum there are unique mechanism of killing, are suitable for control pyrethroid and organophosphorous pesticide are produced resistant insect.More safer relatively than organic phosphor, carbamate chemicals for agriculture, can be used as good mixed agent and use, lepidoptera pest there is good preventive effect.Can stop virus transmission, can effectively control the lepidoptera pest that chrysanthemum ester class and organic phosphor is had resistance.
Imidacloprid anabasine insecticide, English name are Imidacloprid, and molecular formula is C9H10C1N502, and chemical name is 1-(6-chloro-3-pyridylmethyl)-N-Nitroimidazoline-2-base amine,
Chemical structural formula
Imidacloprid is a kind of efficient, interior suction, the long good agricultural insecticide new varieties of the longevity of residure that Bayer A.G and Japanese agricultural chemicals company succeed in developing jointly; Be widely used in crops such as cotton, vegetables, fruit tree, paddy rice, wheat, effectively anti-ly eliminate aphis, insects such as plant hopper, leafhopper, weevil.Be applicable to the various pests of crops such as control paddy rice, cotton, wheat, vegetables, fruit tree, sugarcane, corn, beans, tealeaves, tobacco,
Acetamiprid belongs to nicotinic insecticide, and English name is Acetamiprid, and molecular formula is C10H11C1N4, and chemical name is (E)-N1-[(6-chloro-3-pyridine) methyl]-N2-cyanic acid-N1-methyl ethanamidine,
Chemical structural formula
Acetamiprid and Imidacloprid belong to a series of, but its insecticidal spectrum is wider than Imidacloprid, mainly the aphid on cucumber, apple, citrus, the tobacco is had the better prevention effect.Because the Acetamiprid mechanism of action is unique, to organic phosphor, carbamate, and the insect that pesticide species such as pyrethroid develops immunity to drugs has better effects.
Nitenpyram belongs to novel nicotimine class super-high-efficient insecticide, and English name is nitenpyram, and molecular formula is C11H15C1N402, and chemical name is (E)-N-(6-chloro-3-picolyl)-N-ethyl-N '-methyl-2-nitro ethylene diamine, and chemical structural formula does
Nitenpyram is similar with other anabasine compound mechanism of action, mainly acts on the nervous system of insect.This medicament insecticidal spectrum is wide, can prevent and treat simultaneous numerous insect during use, has remarkable interior suction osmosis; And when very low dosage, show very high insecticidal activity, and crop there is not poisoning, be used for crops such as paddy rice, vegetables; Various aphids, aleyrodid, rice-leaf hopper and thrips have been shown remarkable activity; Have efficient, low toxicity, interior suction and do not have cross resistance four big advantages, and insecticidal spectrum is wider, residual life, is longer.
MTI-446 belongs to novel nicotinoyl class super-high-efficient insecticide, and English name is Dinotefuran, and molecular formula is C7H14N403, and chemical name is 1-methyl-2-nitro-3-(tetrahydrochysene-3-furfuryl) guanidine, and chemical structural formula does
MTI-446 is a third generation nicotinic insecticide.Since exist special furan structure in its structure, thus different at aspect of performance and nicotine, and people are referred to as " furans nicotine " at present.MTI-446 mainly acts on insect neurotransmission system, thereby makes insect paralysis performance insecticidal action.This medicament insecticidal spectrum is wide, can prevent and treat simultaneous numerous insect after the processing, has remarkable interior suction osmosis, and when very low dosage, shows very high insecticidal activity.This medicament is fool proof to mammal, birds and aquatile, and crop is not had poisoning, can be used for numerous crop pest controls such as paddy rice, fruit tree, vegetables.
Thiophene worm amine belongs to second generation nicotinic insecticide, and English name is Clothianidin, and molecular formula is C
6H
8ClN
5O
2S, chemical name are (E)-1-(2-chloro-1,3-thiazoles-5-ylmethyl)-3-methyl-2-nitroguanidine,
Chemical structural formula does
Thiophene worm amine carries out the world market exploitation jointly by Beyer Co., Ltd and Japanese Takeda Wu Tian company; Be used for crops such as paddy rice, vegetables, tealeaves, ornamental plants and fruit in Japan, thiophene worm amine be a kind of active high, have interior absorption, tag and the broad spectrum pesticide of stomach poison function.The mechanism of action is the nAChR that combines to be positioned at neural post-synapse.Be applicable to foliar spray, soil treatment.
The novel chloro nicotinic insecticide of thiophene worm quinoline, English name is thiacloprid, molecular formula is C
13H
5N
4SCl, chemical name are the inferior cyanamide of 3-(6-chloro-5-picoline)-1,3-thiazoles alkane-2-, and chemical structural formula does
The former medicine of thiophene worm quinoline is by Bayer farmingization company and the cooperative development of Japanese Bayer farmingization company, and its mechanism of action and other conventional pesticides are different.It mainly acts on the neural caudacoria that engages of insect, through combine interference insect nervous system normal conduction with nAChR; Cause the obstruction of neural channel; Cause a large amount of accumulation of acetylcholine, thereby make the insect exaltation, whole body spasm, paralysis and dead.Having stronger interior suction, tag and stomach poison function, do not have cross resistance with common insecticides such as pyrethroid, organic phosphates and carbamates, thereby can be used for resistance management, is the efficient medicament of control pierce-suck type and pests with chewing mouthparts.
Thiophene worm piperazine is novel chloro nicotinic insecticide, and English name is thiamethoxam, and molecular formula is C8H10ClN5O3S, and chemical name is 3-(2-chloro-1,3-thiazoles-5-ylmethyl)-5-methyl isophthalic acid, 3, and 5-oxadiazines-4-base fork (nitro) amine, chemical structural formula does
Characteristics such as that thiophene worm piperazine has is active high, effect is fast, toxicity is low, the lasting period is long, insecticidal spectrum is wide, first generation anabasine insecticides such as the mechanism of action and Imidacloprid are similar, but have higher activity.To insect with stomach toxicity, tag and systemic action is main, be used for foliar spray and soil and irritate root and handle, rapidly by interior suction, and be transmitted to each position of plant after its dispenser, mainly be used for preventing and treating Lepidoptera, coleoptera, thrips insect.
Ultra low volume liquids is low through the screening volatility, flash-point is high, to former medicine dissolubility is good, low to chemical injury of crops, viscosity is low solvent; Do not convert water during dispenser, but directly use with ultra low volume sprayer tool, low-gallonage spraying apparatus or ultra low volume electrostatic spray apparatus.Ultra low volume spraying is not owing to contain the high volatile volatile composition in the droplet, and its size does not have significant change with quality from leave spraying apparatus arrival target process, reduced volatilization with elegant.Droplet is tiny and even, meets " biological best granula " requirement, has significantly improved deposition.Because need not to convert water uses, ultra low volume liquids is suitable for water scarcity, damage by disease and insect fulminant large tracts of land takes place and the occasion of dispenser on a large scale in the palpus short time, and ultra low volume spraying simultaneously reduces operator's labour intensity greatly.
The ultra low volume spraying technology has the following advantages:
1. spouting liquid is few, is merely hundreds of/one of conventional spraying.
2. droplet is little, and ultra low volume electrostatic spray fogdrop diameter is that 30～60 μ m, ultra low volume ground spraying droplet diameter are 30～80 μ m, aerial ultra low volume spraying fogdrop diameter 30～60 μ m, and conventional spraying droplet diameter is many more than 200～600 μ m.
3. spray pattern is the spraying of drift accumulation property, and conventional spraying is the specific aim spraying, promptly facing to the crop spraying.
What 4. ultra low volume sprayed is to be the finish of carrier with oil, and concentration is generally a few percent to percent tens; And the conventional water diluent agent concentration that sprays is very low, is generally some thousandths of to ten thousand/several.
5. work efficiency is high, and control in time.Hand-held ultra low volume spraying machine improves 20～30 times of work efficiency than manual compression sprayer, because of its work efficiency is high, can timely and effectively prevent and treat the fulminant insect, like plant hopper, mythimna separata, locust etc.
6. save agricultural chemicals.Save agricultural chemicals more than 30% with general than conventional spraying.
7. water not.Saved water intaking, made up a prescription and heavy physical labor such as negative water operation, the hilly and mountainous land of especially short of rain in arid, manpower shortage and water intaking difficulty is used, and is more convenient.
8. good drug efficacy is held and is imitated length.The oil agricultural chemicals is easy to penetrate ester dissolubility insect body surface and gets in the pest body, show as desinsection rapidly, good drug efficacy; The high boiling point auxiliary agent that occupies larger proportion in the finish can play protective effects such as anti-hydrolysis, anti-oxidant, anti-photodissociation to pesticide active ingredient, show as hold imitate long.
9. to crop safety.Ultra low volume spraying be difficult for to produce poisoning to crop safety, does not have obviously residually, can improve crop quality.
10. expenses for prevention and control is low.Since ultra low volume spraying have province's medicine, laborsaving, not water, good drug efficacy, hold and imitate advantages such as long, so expenses for prevention and control is lower than conventional spraying.
Summary of the invention
The purpose of this invention is to provide a kind of ultra low volume liquids preparation that contains Acarus tritici urea and nicotinic insecticide, and the preparation method of said ultra low volume liquids is provided.
The ultra low volume liquids formulation that the present invention processes, it be composite with Acarus tritici urea and active component II be active component, all the other supply 100% with surfactant and solvent; Active component II is any one of Imidacloprid, Acetamiprid, Nitenpyram, thiophene worm amine, thiophene worm piperazine, thiophene worm quinoline or MTI-446.
This ultra low volume liquids is composite with Acarus tritici urea and active component I I to be active component; The weight content of its total amount is 0.2%～70%; The weight content of Acarus tritici urea is 0.1%～20%; The weight content of active component II is 0.1%～50%, and the weight content of auxiliary agent is 1%～10%, and solvent complements to 100%.
Suitable surfactant is selected from one or more the combination in AEO, APES, phenethyl phenol polyethenoxy ether, alkylaryl polyoxyethylene polyoxypropylene ether, aliphatic alcohol polyoxyvinethene phosphate, APES phosphate, phenethyl phenol polyethenoxy ether phosphate, alkylaryl polyoxyethylene polyoxypropylene ether phosphate, castor oil polyoxyethylene ether or the calcium dodecyl benzene sulfonate, preferred fat alcohol APEO, APES, phenethyl phenol polyethenoxy ether, alkylaryl polyoxyethylene polyoxypropylene ether, castor oil polyoxyethylene ether or calcium dodecyl benzene sulfonate etc.
The solvent that is fit to is one or more combinations in aromatic hydrocarbon solvent, plant oil solvent and the polar solvent; Aromatic hydrocarbon solvent comprises C10 aromatic hydrocarbons, trimethylbenzene, o-dichlorohenzene, durene, diethylbenzene, methyl-propyl benzene, butylbenzene, methyl naphthalene or two wires oil; The plant oil solvent comprises soybean oil, cottonseed oil, rapeseed oil, corn oil, castor oil, turpentine oil, methyl oleate or ethyl oleate; Polar solvent comprises acetophenone, phenmethylol, methyl-sulfoxide, N-Methyl pyrrolidone, N, dinethylformamide, DMAC N,N, n-hexyl alcohol, n-octyl alcohol or terpineol.
The preparation method of ultra low volume liquids of the present invention does; In the mixing kettle of belt stirrer, earlier with partial solvent with the active component stirring and dissolving after, add surfactant and remaining solvent again; Fully mix, promptly get the ultra low volume liquids that contains Acarus tritici urea and nicotinic insecticide; Technological parameter is: mixing speed is controlled to be 60～150 rev/mins, and mixing time is 15～60 minutes, and temperature is a normal temperature, and pressure is normal pressure.
The target crop that is fit to is cereal crops such as paddy rice, wheat; Economic crops such as sugarcane, banana, rubber, cotton, tea tree, oranges and tangerines, apple, hawthorn, peach; Vegetable crops such as tomato, eggplant, capsicum, lettuce, celery, wild cabbage, Kidney bean, broad bean, cowpea, pea, ground family crops such as cucumber, pumpkin, watermelon.
Ultra low volume liquids of the present invention is fit to control rice fulgorid, rice leaf roller, brown planthopper, white-backed planthopper, small brown rice planthopper, striped rice borer, rice thrips, rice gall midge, rice leafhopper, rice leafhopper, rice spider rafter stinkbug, resembles the star stinkbug, green rice bug resembles, red must fleahopper, rice is negative mixes worm, rice tube water snout moth's larva, oryza chinensis, Phytophthira, aleyrodid class, a red-spotted lizard class, unaspis shield kuwana, the green stinkbug of Zhu, peach fruit borer, tangerine lyonetid, the thin moth of tea, striped flea-beetle, the beans fly of diving.The cured a red-spotted lizard in angle, diamond-back moth, two secret notes are chrysomelid, tea golden thistle horse, onion thrips, golden thistle horse, oranges and tangerines golden thistle horse, soybean pod gall-midge, tomato Liriomyza.
The method for optimizing of using ultra low volume liquids of the present invention is ultra low volume spraying, secondly is low-gallonage spraying and ultra low volume electrostatic spray, and a situation arises confirms suitable dosage according to controlling object, and formulation rate is 75～150g a.i./hm usually
2.
The inventor is through the research proof, and the ultra low volume liquids that the arbitrary pesticide active ingredient in Acarus tritici urea and Imidacloprid, Acetamiprid, Nitenpyram, thiophene worm amine, thiophene worm piperazine, thiophene worm quinoline, the MTI-446 is re-dubbed has extremely strong synergistic effect to target pest.
Ultra low volume liquids of the present invention is easy to process, with low cost, good drug efficacy, hold imitate long, coordinate synergy high, save water; Can reduce environmental pollution, improve the agricultural chemicals availability, reduce applications of pesticide amount.
Embodiment
Below in conjunction with embodiment the present invention is further specified, but do not limit the scope of the invention.
Embodiment 1
Prepare 4.0% Acarus tritici urea Imidacloprid ultra low volume liquids
Preparation technology: in the mixing kettle of belt stirrer, earlier with partial solvent with active component Acarus tritici urea and Imidacloprid stirring and dissolving after, add surfactant and remaining solvent again, fully mix, promptly get 4.0% Acarus tritici urea Imidacloprid ultra low volume liquids; Technological parameter is: mixing speed is controlled to be 60～150 rev/mins, and mixing time is 15～60 minutes, and temperature is a normal temperature, and pressure is normal pressure.
Step of preparation process according to identical with embodiment 1 can prepare following examples.
Embodiment 2
Prepare 20.1% Acarus tritici urea Imidacloprid ultra low volume liquids
Embodiment 3
Prepare 7% Acarus tritici urea Acetamiprid ultra low volume liquids
Embodiment 4
Prepare 30.1% Acarus tritici urea Acetamiprid ultra low volume liquids
Embodiment 5
Prepare 14% Acarus tritici urea Nitenpyram ultra low volume liquids
Embodiment 6
Prepare 20.1% Acarus tritici urea Nitenpyram ultra low volume liquids
Embodiment 7
Prepare 4% Acarus tritici urea thiophene worm amine ultra low volume liquids
Embodiment 8
Prepare 20.1% Acarus tritici urea thiophene worm amine ultra low volume liquids
Embodiment 9
Prepare 8% Acarus tritici urea thiophene worm piperazine ultra low volume liquids
Embodiment 10
Prepare 30.1% Acarus tritici urea thiophene worm piperazine ultra low volume liquids
Embodiment 11
Prepare 5% Acarus tritici urea thiophene worm quinoline ultra low volume liquids
Embodiment 12
Prepare 32% Acarus tritici urea thiophene worm quinoline ultra low volume liquids
Embodiment 13
Prepare 22% Acarus tritici urea MTI-446 ultra low volume liquids
Embodiment 14
Prepare 30.1% Acarus tritici urea MTI-446 ultra low volume liquids
The prepared ultra low volume liquids outward appearance that contains Acarus tritici urea and nicotinic insecticide is the homogeneous oily liquids; Low temperature compatibility is good, and under-5 ℃ of conditions, refrigeration 7d does not separate out crystallization and suspension; Volatility is low, and the filter paper suspension is sent out and measured the result, and volatility is lower than 30%; To plant safety, no poisoning; The employing method of remaining silent is measured, and flash-point is greater than 70 ℃; Viscosity is less than 30mPas; Conductance is 1 * 10
-6～1 * 10
-10In the s/cm scope.
The field efficacy that combines the application embodiment of the invention to carry out is again below measured the result beneficial effect of the present invention further is described.
Application implementation example of the present invention is the method that adopts Toxicity Determination and field control effectiveness test to combine.Pass through Toxicity Determination earlier, the co-toxicity coefficient (CTC) after clear and definite two kinds of medicaments are composite by a certain percentage, CTC＜80 are antagonism, and 80＜CTC＜120 are summation action, and CTC＞120 are synergistic effect, on this basis, carry out field control effectiveness test again.
Application implementation example 1
Controlling object: rice leaf roller
Experiment place: rice field, Ke Li village, the Xin Xu of Nanning City town
Application method: ultra low volume spraying
Formulation rate: 120g a.i./hm
2
Table 1: control rice leaf roller field control effectiveness test result
From table 1, can find out: ultra low volume liquids employing ultra low volume spraying method control rice leaf roller quick-acting of the present invention is strong, control efficiency good, the lasting period is longer.
Application implementation example 2
Controlling object: cabbage caterpillar
Experiment place: brassicaceous vegetable field, Xinjian County, Nanchang City
Application method: ultra low volume spraying
Formulation rate: 120g a.i./hm
2.
Table 2: control cabbage caterpillar test of pesticide effectiveness result
From table 2, can find out: ultra low volume liquids employing ultra low volume spraying method control of the present invention field brassicaceous vegetable cabbage caterpillar quick-acting is strong, control efficiency good, the lasting period is longer.
Claims (5)
1. ultra low volume liquids that contains Acarus tritici urea and nicotinic insecticide is characterized in that: it be composite with Acarus tritici urea and active component II be active component, all the other supply 100% ultra low volume liquids with surfactant and solvent; Active component II is any one of Imidacloprid, Acetamiprid, Nitenpyram, thiophene worm amine, thiophene worm piperazine, thiophene worm quinoline or MTI-446.
2. the ultra low volume liquids that contains Acarus tritici urea and nicotinic insecticide according to claim 1; It is characterized in that: Acarus tritici urea and active component II are composite to be active component; The weight content of its total amount is 0.2%～50%, and the weight content of Acarus tritici urea is 0.1%～20%, and the weight content of active component II is 0.1%～30%; The weight content of auxiliary agent is 1%～10%, and solvent complements to 100%.
3. the ultra low volume liquids that contains Acarus tritici urea and nicotinic insecticide according to claim 1 is characterized in that: described surfactant is one or more the combination in OPEO, AEO, APES, phenethyl phenol polyethenoxy ether, alkylaryl polyoxyethylene polyoxypropylene ether, aliphatic alcohol polyoxyvinethene phosphate, APES phosphate, phenethyl phenol polyethenoxy ether phosphate, castor oil polyoxyethylene ether or the calcium dodecyl benzene sulfonate.
4. the ultra low volume liquids that contains Acarus tritici urea and nicotinic insecticide according to claim 1 is characterized in that: said solvent is one or more combinations in aromatic hydrocarbon solvent, plant oil solvent and the polar solvent; Aromatic hydrocarbon solvent comprises C10 aromatic hydrocarbons, methyl naphthalene or two wires oil; The plant oil solvent comprises soybean oil, cottonseed oil, rapeseed oil, corn oil, castor oil or methyl oleate; Polar solvent comprises phenmethylol, N-Methyl pyrrolidone, N, dinethylformamide, n-hexyl alcohol, n-octyl alcohol or terpineol.
5. the ultra low volume liquids that contains Acarus tritici urea and nicotinic insecticide according to claim 1; The preparation method who it is characterized in that said ultra low volume liquids is: in the mixing kettle of belt stirrer; Earlier with partial solvent with the active component stirring and dissolving after; Add surfactant and remaining solvent again, fully mix, promptly get the ultra low volume liquids that contains Acarus tritici urea and nicotinic insecticide; Technological parameter is: mixing speed is controlled to be 60～150 rev/mins, and mixing time is 15～60 minutes, and temperature is a normal temperature, and pressure is normal pressure.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102823618A (en) * | 2012-09-13 | 2012-12-19 | 王学权 | Insecticide containing dinotefuran |
| CN103621540A (en) * | 2012-08-29 | 2014-03-12 | 南京华洲药业有限公司 | Synergistic insecticidal composition containing clothianidin and chlorfluazuron and applications thereof |
| CN103651510A (en) * | 2013-12-13 | 2014-03-26 | 广西田园生化股份有限公司 | Ultra-low volume liquid containing cycloxaprid and chloronicotinyl insecticide |
| CN106259408A (en) * | 2016-08-05 | 2017-01-04 | 江西正邦生物化工有限责任公司 | A kind of clothianidin-containing and the composition pesticide of lufenuron |
| CN114631535A (en) * | 2020-12-15 | 2022-06-17 | 江苏扬农化工股份有限公司 | Prevention and control composition for breeding ground fly larvae and prevention and control method |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006048868A2 (en) * | 2004-11-04 | 2006-05-11 | Makhteshim Chemical Works Ltd. | Pesticidal composition |
| CN1911022A (en) * | 2005-08-12 | 2007-02-14 | 南京第一农药有限公司 | Pesticide composition with lurfenuron and Dingchongmi as main active components, and its application |
| CN1911024A (en) * | 2005-08-12 | 2007-02-14 | 南京第一农药有限公司 | Synergistic compound pesticide contg. lurfenuron |
| CN101755788A (en) * | 2008-12-31 | 2010-06-30 | 浙江世佳科技有限公司 | Insecticidal composite containing lufenuron, nitenpyram and organosilicon synergist |
| CN102273440A (en) * | 2011-09-13 | 2011-12-14 | 广西田园生化股份有限公司 | Ultralow volume liquid containing clothianidin |
| CN102379282A (en) * | 2011-09-13 | 2012-03-21 | 广西田园生化股份有限公司 | Ultralow volume liquid containing benzoylurea insecticide |
-
2012
- 2012-04-01 CN CN2012100941468A patent/CN102630695A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006048868A2 (en) * | 2004-11-04 | 2006-05-11 | Makhteshim Chemical Works Ltd. | Pesticidal composition |
| CN1911022A (en) * | 2005-08-12 | 2007-02-14 | 南京第一农药有限公司 | Pesticide composition with lurfenuron and Dingchongmi as main active components, and its application |
| CN1911024A (en) * | 2005-08-12 | 2007-02-14 | 南京第一农药有限公司 | Synergistic compound pesticide contg. lurfenuron |
| CN101755788A (en) * | 2008-12-31 | 2010-06-30 | 浙江世佳科技有限公司 | Insecticidal composite containing lufenuron, nitenpyram and organosilicon synergist |
| CN102273440A (en) * | 2011-09-13 | 2011-12-14 | 广西田园生化股份有限公司 | Ultralow volume liquid containing clothianidin |
| CN102379282A (en) * | 2011-09-13 | 2012-03-21 | 广西田园生化股份有限公司 | Ultralow volume liquid containing benzoylurea insecticide |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103621540A (en) * | 2012-08-29 | 2014-03-12 | 南京华洲药业有限公司 | Synergistic insecticidal composition containing clothianidin and chlorfluazuron and applications thereof |
| CN103621540B (en) * | 2012-08-29 | 2015-06-03 | 南京华洲药业有限公司 | Synergistic insecticidal composition containing clothianidin and chlorfluazuron and applications thereof |
| CN102823618A (en) * | 2012-09-13 | 2012-12-19 | 王学权 | Insecticide containing dinotefuran |
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| CN106259408A (en) * | 2016-08-05 | 2017-01-04 | 江西正邦生物化工有限责任公司 | A kind of clothianidin-containing and the composition pesticide of lufenuron |
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