CN102626071A - Ultra-low volume liquid containing cyantraniliprole and neonicotinoid insecticides - Google Patents

Ultra-low volume liquid containing cyantraniliprole and neonicotinoid insecticides Download PDF

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CN102626071A
CN102626071A CN2012100881109A CN201210088110A CN102626071A CN 102626071 A CN102626071 A CN 102626071A CN 2012100881109 A CN2012100881109 A CN 2012100881109A CN 201210088110 A CN201210088110 A CN 201210088110A CN 102626071 A CN102626071 A CN 102626071A
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low volume
ultra low
insect amide
cyanogen insect
volume liquids
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王群利
李现玲
李卫国
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Guangxi Tianyuan Biochemical Co Ltd
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Guangxi Tianyuan Biochemical Co Ltd
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/561,2-Diazoles; Hydrogenated 1,2-diazoles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A01N25/04Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
    • A01N25/06Aerosols

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  • General Health & Medical Sciences (AREA)
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  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
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Abstract

The invention relates to an ultra-low volume liquid containing cyantraniliprole and neonicotinoid insecticides. The liquid is compounded by cyantraniliprole and an active ingredient II into a chemical component, and other components are surfactants and solvents; and the active ingredient II is any one of imidacloprid, acetamiprid, nitenpyram, clothianidin, thiamethoxam, thiacloprid or dinotefuran. The ultra-low volume liquid has the advantages of convenience in processing, long duration, high work efficiency, low possibility of generating resistance to pesticides by a target, low environmental contamination, economy of drug and water, and improvement in pesticide utilization rate; and through ultra-low volume spraying, low volume spraying or ultra-low volume static spraying, various pests of rice, wheat, corn, vegetables, tobacco, tea trees, fruit trees and sugarcanes can be prevented and treated.

Description

The ultra low volume liquids that contains cyanogen insect amide and nicotinic insecticide
Technical field
The present invention relates to pesticide field, is the ultra low volume liquids that contains cyanogen insect amide and nicotinic insecticide specifically, mainly realizes the effective control to crop pest through ultra low volume spraying, low-gallonage spraying or ultra low volume electrostatic spray.
Background technology
At present for the control of insect that is prone to produce resistance on the agricultural; Main way is that exploitation and existing kind do not have composite between new composition or the existing pesticide species of cross resistance; The former is because required development cost is high, the cycle is long, and at present development rate far away less than the speed of pest resistance to insecticide generation.Therefore, being mixed for the different existing pesticide species of the mechanism of action is a kind of selection of the best.If reasonable mixture ratio then can produce significant synergistic effect, make field control effect significantly be superior to the effect of each single agent.Usually there is certain defective in the insecticide that contains the single-activity composition on agricultural insect pests control; Continuous several times is used and is not only made insect be easy to generate pesticide resistance; And be prone to cause pollution, can overcome above shortcoming through rationally being mixed between the pesticide active ingredient to food and environment.The reasonably composite simultaneously synergistic effect that active ingredient is produced can improve preventive effect, reduces the effective ingredient consumption; Practice thrift cost; Delay the drug-fast generation of insect, closely can alleviate even avoid the pollution of agricultural chemicals food and environment, and the efficient novel pesticide of the low toxicity that the present invention researchs and develops out; Not only the target drug effect is significantly strengthened, and very low to the influence of people, crop, non-target and environment.
The cyanogen insect amide English name is Cyantraniliprole; Trade name is CyazypyrTM; Test code number is DPX-HGW86; Chemical name is 3-bromo-N-(4-cyanic acid-2-methyl-6-(amino-carbonyl) phenyl)-1-(3-chloropyridine-2-yl)-1H-pyrazoles-5-carboxylic acid amides, is the novel O-formammidotiazol-benzamide insecticide that du pont company develops, and its chemical structural formula does
Figure BDA0000148497050000021
Cyanogen insect amide belongs to insect ryania acceptor inhibitor; Mainly calcium ion release shows and tags and stomach poison function in the striated muscle through inducing insect ryania receptor modulators and the smooth muscle cell; Can be used for the control of various crop insects such as paddy rice, vegetables, cotton, beet; Especially the control to various lepidoptera pests and sucking pest has special efficacy; Its control efficiency is remarkable in other commercialization insecticide varieties that use in the current production, and there is not cross resistance in other insecticides.Therefore, cyanogen insect amide is described as efficient pesticides of new generation in the world.
Imidacloprid anabasine insecticide, English name are Imidacloprid, and molecular formula is C 9H 10ClN 5O 2, chemical name is 1-(6-chloro-3-pyridylmethyl)-N-Nitroimidazoline-2-base amine, chemical structural formula
Figure BDA0000148497050000022
Imidacloprid is a kind of efficient, interior suction, the long good agricultural insecticide new varieties of the longevity of residure that Bayer A.G and Japanese agricultural chemicals company succeed in developing jointly; Be widely used in crops such as cotton, vegetables, fruit tree, paddy rice, wheat, effectively anti-ly eliminate aphis, insects such as plant hopper, leafhopper, weevil.Be applicable to the various pests of crops such as control paddy rice, cotton, wheat, vegetables, fruit tree, sugarcane, corn, beans, tealeaves, tobacco,
Acetamiprid belongs to nicotinic insecticide, and English name is Acetamiprid, and molecular formula is C 10H 11ClN 4, chemical name is (E)-N1-[(6-chloro-3-pyridine) methyl]-N2-cyanic acid-N1-methyl ethanamidine, chemical structural formula
Figure BDA0000148497050000023
Acetamiprid and Imidacloprid belong to a series of, but its insecticidal spectrum is wider than Imidacloprid, mainly the aphid on cucumber, apple, citrus, the tobacco is had the better prevention effect.Because the Acetamiprid mechanism of action is unique, to organic phosphor, carbamate, and the insect that pesticide species such as pyrethroid develops immunity to drugs has better effects.
Nitenpyram belongs to novel nicotimine class super-high-efficient insecticide, and English name is nitenpyram, and molecular formula is C 11H 15ClN 4O 2, chemical name is (E)-N-(6-chloro-3-picolyl)-N-ethyl-N '-methyl-2-nitro ethylene diamine, chemical structural formula does
Figure BDA0000148497050000031
Nitenpyram is similar with other anabasine compound mechanism of action, mainly acts on the nervous system of insect.This medicament insecticidal spectrum is wide, can prevent and treat simultaneous numerous insect during use, has remarkable interior suction osmosis; And when very low dosage, show very high insecticidal activity, and crop there is not poisoning, be used for crops such as paddy rice, vegetables; Various aphids, aleyrodid, rice-leaf hopper and thrips have been shown remarkable activity; Have efficient, low toxicity, interior suction and do not have cross resistance four big advantages, and insecticidal spectrum is wider, residual life, is longer.
MTI-446 belongs to novel nicotinoyl class super-high-efficient insecticide, and English name is Dinotefuran, and molecular formula is C 7H 14N 4O 3, chemical name is 1-methyl-2-nitro-3-(tetrahydrochysene-3-furfuryl) guanidine, chemical structural formula does
Figure BDA0000148497050000032
MTI-446 is a third generation nicotinic insecticide.Since exist special furan structure in its structure, thus different at aspect of performance and nicotine, and people are referred to as " furans nicotine " at present.MTI-446 mainly acts on insect neurotransmission system, thereby makes insect paralysis performance insecticidal action.This medicament insecticidal spectrum is wide, can prevent and treat simultaneous numerous insect after the processing, has remarkable interior suction osmosis, and when very low dosage, shows very high insecticidal activity.This medicament is fool proof to mammal, birds and aquatile, and crop is not had poisoning, can be used for numerous crop pest controls such as paddy rice, fruit tree, vegetables.
Thiophene worm amine belongs to second generation nicotinic insecticide, and English name is Clothianidin, and molecular formula is C 6H 8ClN 5O 2S, chemical name are (E)-1-(2-chloro-1,3-thiazoles-5-ylmethyl)-3-methyl-2-nitroguanidine, and chemical structural formula does
Figure BDA0000148497050000041
Thiophene worm amine carries out the world market exploitation jointly by Beyer Co., Ltd and Japanese Takeda Wu Tian company; Be used for crops such as paddy rice, vegetables, tealeaves, ornamental plants and fruit in Japan, thiophene worm amine be a kind of active high, have interior absorption, tag and the broad spectrum pesticide of stomach poison function.The mechanism of action is the nAChR that combines to be positioned at neural post-synapse.Be applicable to foliar spray, soil treatment.
The novel chloro nicotinic insecticide of thiophene worm quinoline, English name is thiacloprid, molecular formula is C 13H 5N 4SCl, chemical name are the inferior cyanamide of 3-(6-chloro-5-picoline)-1,3-thiazoles alkane-2-, and chemical structural formula does
Figure BDA0000148497050000042
The former medicine of thiophene worm quinoline is by Bayer farmingization company and the cooperative development of Japanese Bayer farmingization company, and its mechanism of action and other conventional pesticides are different.It mainly acts on the neural caudacoria that engages of insect, through combine interference insect nervous system normal conduction with nAChR; Cause the obstruction of neural channel; Cause a large amount of accumulation of acetylcholine, thereby make the insect exaltation, whole body spasm, paralysis and dead.Having stronger interior suction, tag and stomach poison function, do not have cross resistance with common insecticides such as pyrethroid, organic phosphates and carbamates, thereby can be used for resistance management, is the efficient medicament of control pierce-suck type and pests with chewing mouthparts.
Thiophene worm piperazine is novel chloro nicotinic insecticide, and English name is thiamethoxam, and molecular formula is C 8H 10ClN 5O 3S, chemical name are 3-(2-chloro-1,3-thiazoles-5-ylmethyl)-5-methyl isophthalic acid, 3, and 5-oxadiazines-4-base fork (nitro) amine, chemical structural formula does
Figure BDA0000148497050000051
Characteristics such as that thiophene worm piperazine has is active high, effect is fast, toxicity is low, the lasting period is long, insecticidal spectrum is wide, first generation anabasine insecticides such as the mechanism of action and Imidacloprid are similar, but have higher activity.To insect with stomach toxicity, tag and systemic action is main, be used for foliar spray and soil and irritate root and handle, rapidly by interior suction, and be transmitted to each position of plant after its dispenser, mainly be used for preventing and treating Lepidoptera, coleoptera, thrips insect.
Ultra low volume liquids is low through the screening volatility, flash-point is high, to former medicine dissolubility is good, low to chemical injury of crops, viscosity is low solvent; Do not convert water during dispenser, but directly use with ultra low volume sprayer tool, low-gallonage spraying apparatus or ultra low volume electrostatic spray apparatus.Ultra low volume spraying is not owing to contain the high volatile volatile composition in the droplet, and its size does not have significant change with quality from leave spraying apparatus arrival target process, reduced volatilization with elegant.Droplet is tiny and even, meets " biological best granula " requirement, has significantly improved deposition.Because need not to convert water uses, ultra low volume liquids is suitable for water scarcity, damage by disease and insect fulminant large tracts of land takes place and the occasion of dispenser on a large scale in the palpus short time, and ultra low volume spraying simultaneously reduces operator's labour intensity greatly.
The ultra low volume spraying technology has the following advantages:
1. spouting liquid is few, is merely hundreds of/one of conventional spraying.
2. droplet is little, and ultra low volume electrostatic spray fogdrop diameter is that 30~60 μ m, ultra low volume ground spraying droplet diameter are 30~80 μ m, aerial ultra low volume spraying fogdrop diameter 30~60 μ m, and conventional spraying droplet diameter is many more than 200~600 μ m.
3. spray pattern is the spraying of drift accumulation property, and conventional spraying is the specific aim spraying, promptly facing to the crop spraying.
What 4. ultra low volume sprayed is to be the finish of carrier with oil, and concentration is generally a few percent to percent tens; And the conventional water diluent agent concentration that sprays is very low, is generally some thousandths of to ten thousand/several.
5. work efficiency is high, and control in time.Hand-held ultra low volume spraying machine improves 20~30 times of work efficiency than manual compression sprayer, because of its work efficiency is high, can timely and effectively prevent and treat the fulminant insect, like plant hopper, mythimna separata, locust etc.
6. save agricultural chemicals.Save agricultural chemicals more than 30% with general than conventional spraying.
7. water not.Saved water intaking, made up a prescription and heavy physical labor such as negative water operation, the hilly and mountainous land of especially short of rain in arid, manpower shortage and water intaking difficulty is used, and is more convenient.
8. good drug efficacy is held and is imitated length.The oil agricultural chemicals is easy to penetrate ester dissolubility insect body surface and gets in the pest body, show as desinsection rapidly, good drug efficacy; The high boiling point auxiliary agent that occupies larger proportion in the finish can play protective effects such as anti-hydrolysis, anti-oxidant, anti-photodissociation to pesticide active ingredient, show as hold imitate long.
9. to crop safety.Ultra low volume spraying be difficult for to produce poisoning to crop safety, does not have obviously residually, can improve crop quality.
10. expenses for prevention and control is low.Since ultra low volume spraying have province's medicine, laborsaving, not water, good drug efficacy, hold and imitate advantages such as long, so expenses for prevention and control is lower than conventional spraying.
Summary of the invention
The purpose of this invention is to provide a kind of ultra low volume liquids preparation that contains cyanogen insect amide and nicotinic insecticide, and the preparation method of said ultra low volume liquids is provided.
The ultra low volume liquids formulation that the present invention processes, it be composite with cyanogen insect amide and active component II be active component, all the other supply 100% with surfactant and solvent; Active component II is any one of Imidacloprid, Acetamiprid, Nitenpyram, thiophene worm amine, thiophene worm piperazine, thiophene worm quinoline or MTI-446.
This ultra low volume liquids is composite with cyanogen insect amide and active component II to be active component; The weight content of its total amount is 0.2%~70%; The weight content of cyanogen insect amide is 0.1%~20%; The weight content of active component II is 0.1%~50%, and the weight content of auxiliary agent is 1%~10%, and solvent complements to 100%.
Suitable surfactant is selected from one or more the combination in OPEO, AEO, APES, phenethyl phenol polyethenoxy ether, alkylaryl polyoxyethylene polyoxypropylene ether, aliphatic alcohol polyoxyvinethene phosphate, APES phosphate, phenethyl phenol polyethenoxy ether phosphate, alkylaryl polyoxyethylene polyoxypropylene ether phosphate, castor oil polyoxyethylene ether or the calcium dodecyl benzene sulfonate, preferred fat alcohol APEO, APES, phenethyl phenol polyethenoxy ether, alkylaryl polyoxyethylene polyoxypropylene ether, castor oil polyoxyethylene ether or calcium dodecyl benzene sulfonate.
The solvent that is fit to is one or more combinations in aromatic hydrocarbon solvent, plant oil solvent and the polar solvent; Aromatic hydrocarbon solvent comprises trimethylbenzene, o-dichlorohenzene, durene, diethylbenzene, methyl-propyl benzene, butylbenzene, methyl naphthalene or two wires oil; The plant oil solvent comprises soybean oil, cottonseed oil, rapeseed oil, corn oil, castor oil, turpentine oil, methyl oleate or ethyl oleate; Polar solvent comprises acetophenone, phenmethylol, methyl-sulfoxide, N-Methyl pyrrolidone, N, dinethylformamide, DMAC N,N, n-hexyl alcohol, n-octyl alcohol or terpineol.
The preparation method of ultra low volume liquids of the present invention does; In the mixing kettle of belt stirrer; Earlier with partial solvent with the active component stirring and dissolving after; Add surfactant and remaining solvent again, fully mix, promptly get the ultra low volume liquids that contains cyanogen insect amide and nicotinic insecticide; Technological parameter is: mixing speed is controlled to be 60~150 rev/mins, and mixing time is 15~60 minutes, and temperature is a normal temperature, and pressure is normal pressure.
The target crop that is fit to is cereal crops such as paddy rice, wheat; Economic crops such as sugarcane, banana, rubber, cotton, tea tree, oranges and tangerines, apple, hawthorn, peach; Vegetable crops such as tomato, eggplant, capsicum, lettuce, celery, wild cabbage, Kidney bean, broad bean, cowpea, pea, ground family crops such as cucumber, pumpkin, watermelon.
Ultra low volume liquids of the present invention is fit to control rice fulgorid, rice leaf roller, brown planthopper, white-backed planthopper, small brown rice planthopper, striped rice borer, rice thrips, rice gall midge, rice leafhopper, rice leafhopper, rice spider rafter stinkbug, resembles the star stinkbug, green rice bug resembles, red must fleahopper, rice is negative mixes worm, rice tube water snout moth's larva, oryza chinensis, Phytophthira, aleyrodid class, a red-spotted lizard class, unaspis shield kuwana, the green stinkbug of Zhu, peach fruit borer, tangerine lyonetid, the thin moth of tea, striped flea-beetle, the beans fly of diving.The cured a red-spotted lizard in angle, diamond-back moth, two secret notes are chrysomelid, tea golden thistle horse, onion thrips, golden thistle horse, oranges and tangerines golden thistle horse, soybean pod gall-midge, tomato Liriomyza.
The method for optimizing of using ultra low volume liquids of the present invention is ultra low volume spraying, secondly is low-gallonage spraying and ultra low volume electrostatic spray, and a situation arises confirms suitable dosage according to controlling object, and formulation rate is 75~150g a.i./hm usually 2.
The inventor is through the research proof, and the ultra low volume liquids that the arbitrary pesticide active ingredient in cyanogen insect amide and Imidacloprid, Acetamiprid, Nitenpyram, thiophene worm amine, thiophene worm piperazine, thiophene worm quinoline, the MTI-446 is re-dubbed has extremely strong synergistic effect to target pest.
Ultra low volume liquids of the present invention is easy to process, with low cost, good drug efficacy, hold imitate long, coordinate synergy high, save water; Can reduce environmental pollution, improve the agricultural chemicals availability, reduce applications of pesticide amount.
Embodiment
Below in conjunction with embodiment the present invention is further specified, but do not limit the scope of the invention.
Embodiment 1
Prepare 4.0% cyanogen insect amide Imidacloprid ultra low volume liquids
Figure BDA0000148497050000081
Figure BDA0000148497050000091
Preparation technology: in the mixing kettle at belt stirrer in the reaction vessel that band stirs; Earlier with partial solvent with active component cyanogen insect amide and Imidacloprid stirring and dissolving after; Add surfactant and remaining solvent again; Fully mix, promptly get 4.0% cyanogen insect amide Imidacloprid ultra low volume liquids; Technological parameter is: mixing speed is controlled to be 60~150 rev/mins, and mixing time is 15~60 minutes, and temperature is a normal temperature, and pressure is normal pressure.
Step of preparation process according to identical with embodiment 1 can prepare following examples.
Embodiment 2
Prepare 20.1% cyanogen insect amide Imidacloprid ultra low volume liquids
Figure BDA0000148497050000092
Figure BDA0000148497050000101
Embodiment 3
Prepare 7% cyanogen insect amide Acetamiprid ultra low volume liquids
Figure BDA0000148497050000102
Embodiment 4
Prepare 30.1% cyanogen insect amide Acetamiprid ultra low volume liquids
Figure BDA0000148497050000103
Embodiment 5
Prepare 25% cyanogen insect amide Nitenpyram ultra low volume liquids
Figure BDA0000148497050000104
Figure BDA0000148497050000111
Embodiment 6
Prepare 40% cyanogen insect amide Nitenpyram ultra low volume liquids
Figure BDA0000148497050000112
Embodiment 7
Prepare 4% cyanogen insect amide thiophene worm amine ultra low volume liquids
Figure BDA0000148497050000113
Figure BDA0000148497050000121
Embodiment 8
Prepare 20.1% cyanogen insect amide thiophene worm amine ultra low volume liquids
Embodiment 9
Prepare 8% cyanogen insect amide thiophene worm piperazine ultra low volume liquids
Figure BDA0000148497050000123
Embodiment 10
Prepare 30.1% cyanogen insect amide thiophene worm piperazine ultra low volume liquids
Figure BDA0000148497050000124
Figure BDA0000148497050000131
Embodiment 11
Prepare 5% cyanogen insect amide thiophene worm quinoline ultra low volume liquids
Figure BDA0000148497050000132
Embodiment 12
Prepare 25% cyanogen insect amide thiophene worm quinoline ultra low volume liquids
Figure BDA0000148497050000133
Figure BDA0000148497050000141
Embodiment 13
Prepare 22% cyanogen insect amide MTI-446 ultra low volume liquids
Embodiment 14
Prepare 30.1% cyanogen insect amide MTI-446 ultra low volume liquids
Figure BDA0000148497050000143
The prepared ultra low volume liquids outward appearance that contains cyanogen insect amide and nicotinic insecticide is the homogeneous oily liquids; Low temperature compatibility is good, and under-5 ℃ of conditions, refrigeration 7d does not separate out crystallization and suspension; Volatility is low, and the filter paper suspension is sent out and measured the result, and volatility is lower than 30%; To plant safety, no poisoning; The employing method of remaining silent is measured, and flash-point is greater than 70 ℃; Viscosity is less than 30mPas; Conductance is 1 * 10 -6~1 * 10 -10In the s/cm scope.
The field efficacy that combines the application embodiment of the invention to carry out is again below measured the result beneficial effect of the present invention further is described.
Application implementation example of the present invention is the method that adopts Toxicity Determination and field control effectiveness test to combine.Pass through Toxicity Determination earlier, the co-toxicity coefficient (CTC) after clear and definite two kinds of medicaments are composite by a certain percentage, CTC<80 are antagonism, and 80<CTC<120 are summation action, and CTC>120 are synergistic effect, on this basis, carry out field control effectiveness test again.
Application implementation example 1
Controlling object: rice fulgorid
Experiment place: rice field, the Xin Xu of Nanning City town
Application method: ultra low volume spraying
Formulation rate: 120g a.i./hm 2
The contrast medicament: 25% pyrrole aphid ketone wp, preparation mu consumption 16g is diluted with water to the conventional spraying of 30L.
Table 1: control rice fulgorid field control effectiveness test result
Figure BDA0000148497050000151
From table 1, can find out: ultra low volume liquids employing ultra low volume spraying method control rice fulgorid of the present invention comparison is sprayed according to the medicament routine, and quick-acting is strong, control efficiency good, the lasting period is longer.
Application implementation example 2
Controlling object: cabbage caterpillar
Experiment place: brassicaceous vegetable vegetable plot, Xinjian County, Nanchang City
Application method: ultra low volume spraying
Formulation rate: 120g a.i./hm 2.
The contrast medicament: 1.8% AVM EC, preparation mu consumption 200ml is diluted with water to the conventional spraying of 30L.
Table 2: control cabbage caterpillar test of pesticide effectiveness result
Figure BDA0000148497050000162
From table 2, can find out: ultra low volume liquids employing ultra low volume spraying method control cabbage caterpillar of the present invention comparison is sprayed according to the medicament routine, and quick-acting is strong, control efficiency good, the lasting period is longer.

Claims (5)

1. ultra low volume liquids that contains cyanogen insect amide and nicotinic insecticide is characterized in that: it be composite with cyanogen insect amide and active component II be active component, all the other supply 100% ultra low volume liquids with surfactant and solvent; Active component II is any one of Imidacloprid, Acetamiprid, Nitenpyram, thiophene worm amine, thiophene worm piperazine, thiophene worm quinoline or MTI-446.
2. the ultra low volume liquids that contains cyanogen insect amide and nicotinic insecticide according to claim 1; It is characterized in that: cyanogen insect amide and active component II are composite to be active component; The weight content of its total amount is 0.2%~50%, and the weight content of cyanogen insect amide is 0.1%~20%, and the weight content of active component II is 0.1%~30%; The weight content of auxiliary agent is 1%~10%, and solvent complements to 100%.
3. the ultra low volume liquids that contains cyanogen insect amide and nicotinic insecticide according to claim 1 is characterized in that: described surfactant is one or more the combination in OPEO, AEO, APES, phenethyl phenol polyethenoxy ether, alkylaryl polyoxyethylene polyoxypropylene ether, aliphatic alcohol polyoxyvinethene phosphate, APES phosphate, phenethyl phenol polyethenoxy ether phosphate, alkylaryl polyoxyethylene polyoxypropylene ether phosphate, castor oil polyoxyethylene ether or the calcium dodecyl benzene sulfonate.
4. the ultra low volume liquids that contains cyanogen insect amide and nicotinic insecticide according to claim 1 is characterized in that: said solvent is one or more combinations in aromatic hydrocarbon solvent, plant oil solvent and the polar solvent; Aromatic hydrocarbon solvent comprises C10 aromatic hydrocarbons, methyl naphthalene or two wires oil; The plant oil solvent comprises soybean oil, cottonseed oil, corn oil, castor oil, turpentine oil or methyl oleate; Polar solvent comprises phenmethylol, N-Methyl pyrrolidone, N, dinethylformamide, DMAC N,N, n-hexyl alcohol or n-octyl alcohol.
5. the ultra low volume liquids that contains cyanogen insect amide and nicotinic insecticide according to claim 1; The preparation method who it is characterized in that said ultra low volume liquids is: in the mixing kettle of belt stirrer; Earlier with partial solvent with the active component stirring and dissolving after; Add surfactant and remaining solvent again, fully mix, promptly get the ultra low volume liquids that contains cyanogen insect amide and nicotinic insecticide; Technological parameter is: mixing speed is controlled to be 60~150 rev/mins, and mixing time is 15~60 minutes, and temperature is a normal temperature, and pressure is normal pressure.
CN2012100881109A 2012-03-29 2012-03-29 Ultra-low volume liquid containing cyantraniliprole and neonicotinoid insecticides Pending CN102626071A (en)

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CN102630696A (en) * 2012-04-05 2012-08-15 广西田园生化股份有限公司 Insecticidal composite containing Cyantraniliprole and anabasine compounds
CN102696656A (en) * 2012-06-11 2012-10-03 联保作物科技有限公司 Insecticidal composition and preparation thereof
CN102805099A (en) * 2012-08-23 2012-12-05 北京燕化永乐农药有限公司 Insect disinfestation composition
CN103229780A (en) * 2013-04-23 2013-08-07 中国农业科学院蔬菜花卉研究所 Cyantraniliprole-imidacloprid pesticide composition
CN103651510A (en) * 2013-12-13 2014-03-26 广西田园生化股份有限公司 Ultra-low volume liquid containing cycloxaprid and chloronicotinyl insecticide
CN105660679A (en) * 2016-02-25 2016-06-15 广西壮族自治区烟草公司百色市公司 Electrostatic oiling agent containing SYP-9080
CN105941459A (en) * 2016-06-21 2016-09-21 南京华洲药业有限公司 Synergistic insecticidal composition containing cyantraniliprole and clothianidin and application thereof
CN105941453A (en) * 2016-06-21 2016-09-21 南京华洲药业有限公司 Synergistic insecticidal composition containing cyantraniliprole and thiacloprid and application thereof
CN105941460A (en) * 2016-06-21 2016-09-21 南京华洲药业有限公司 Synergistic insecticidal composition containing cyantraniliprole and thiamethoxam and application thereof
CN106070295A (en) * 2016-06-21 2016-11-09 南京华洲药业有限公司 A kind of brominated cyanogen insect amide and the Synergistic insecticidal compositions of imidacloprid and application thereof
CN106070228A (en) * 2016-06-21 2016-11-09 南京华洲药业有限公司 A kind of brominated cyanogen insect amide and the Synergistic insecticidal compositions of Nitenpyram and application thereof
CN106417344A (en) * 2016-06-21 2017-02-22 南京华洲药业有限公司 Synergistic insecticidal composition containing cyantraniliprole and acetamiprid and application of synergistic insecticidal composition
EP3069610A4 (en) * 2013-11-13 2017-04-12 Nippon Soda Co., Ltd. Co-crystal and method for producing same

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CN102630696A (en) * 2012-04-05 2012-08-15 广西田园生化股份有限公司 Insecticidal composite containing Cyantraniliprole and anabasine compounds
CN102696656A (en) * 2012-06-11 2012-10-03 联保作物科技有限公司 Insecticidal composition and preparation thereof
CN102805099A (en) * 2012-08-23 2012-12-05 北京燕化永乐农药有限公司 Insect disinfestation composition
CN103229780A (en) * 2013-04-23 2013-08-07 中国农业科学院蔬菜花卉研究所 Cyantraniliprole-imidacloprid pesticide composition
CN103229780B (en) * 2013-04-23 2014-11-26 中国农业科学院蔬菜花卉研究所 Cyantraniliprole-imidacloprid pesticide composition
EP3069610A4 (en) * 2013-11-13 2017-04-12 Nippon Soda Co., Ltd. Co-crystal and method for producing same
US9648879B2 (en) 2013-11-13 2017-05-16 Nippon Soda Co., Ltd. Co-crystal and method for producing same
CN103651510A (en) * 2013-12-13 2014-03-26 广西田园生化股份有限公司 Ultra-low volume liquid containing cycloxaprid and chloronicotinyl insecticide
CN105660679A (en) * 2016-02-25 2016-06-15 广西壮族自治区烟草公司百色市公司 Electrostatic oiling agent containing SYP-9080
CN105941460A (en) * 2016-06-21 2016-09-21 南京华洲药业有限公司 Synergistic insecticidal composition containing cyantraniliprole and thiamethoxam and application thereof
CN106070295A (en) * 2016-06-21 2016-11-09 南京华洲药业有限公司 A kind of brominated cyanogen insect amide and the Synergistic insecticidal compositions of imidacloprid and application thereof
CN106070228A (en) * 2016-06-21 2016-11-09 南京华洲药业有限公司 A kind of brominated cyanogen insect amide and the Synergistic insecticidal compositions of Nitenpyram and application thereof
CN106417344A (en) * 2016-06-21 2017-02-22 南京华洲药业有限公司 Synergistic insecticidal composition containing cyantraniliprole and acetamiprid and application of synergistic insecticidal composition
CN105941453A (en) * 2016-06-21 2016-09-21 南京华洲药业有限公司 Synergistic insecticidal composition containing cyantraniliprole and thiacloprid and application thereof
CN105941459A (en) * 2016-06-21 2016-09-21 南京华洲药业有限公司 Synergistic insecticidal composition containing cyantraniliprole and clothianidin and application thereof

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