CN105941460A - Synergistic insecticidal composition containing cyantraniliprole and thiamethoxam and application thereof - Google Patents
Synergistic insecticidal composition containing cyantraniliprole and thiamethoxam and application thereof Download PDFInfo
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- CN105941460A CN105941460A CN201610454817.5A CN201610454817A CN105941460A CN 105941460 A CN105941460 A CN 105941460A CN 201610454817 A CN201610454817 A CN 201610454817A CN 105941460 A CN105941460 A CN 105941460A
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- diacloden
- insect amide
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
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Abstract
The invention discloses a synergistic insecticidal composition containing cyantraniliprole and thiamethoxam and application thereof. In the insecticidal composition, cyantraniliprole and thiamethoxam are main active ingredients, wherein the weight ratio of the cyantraniliprole to thiamethoxam is (1-60):(1-60). The insecticidal composition has the functions of expanding the control spectrum and improving effect and can reduce the application cost and can be prepared into missible oil, wettable powder, microemulsion, emulsion in water, suspending agent and water dispersible granules and is used for controlling multiple pests of lepidoptera, hemiptera, hymenoptera, coleoptera and the like.
Description
Technical field
The invention belongs to pesticide field, be specifically related to a kind of Pesticidal combination with bromine cyanogen insect amide and Diacloden as principle active component and application thereof.
Background technology
Bromine cyanogen insect amide (cyantraniliprole), it it is E.I.Du Pont Company's second filial generation ryanodine receptor inhibitor insecticides that success is developed after chlorantraniliprole, cyanogen insect amide is to be formed by the various polar groups on change phenyl ring, have more efficient, applicable crops is more extensive, can effectively prevent and treat Lepidoptera, Semiptera and coleopteran pest.
Diacloden (Thiamethoxam), chemical name: 3-(2-chloro-5-benzothiazolylmethyl)-5-methyl N-nitro-4H-1,3,5-tetrahydrochysene diazine-4-imines.Structural formula:
Anabasine insecticide, the Diacloden mechanism of action is similar to imidacloprid, alternative suppression insect CNS nicotinic acetylcholine esterase receptor, and then blocks the normal conduction of insect CNS, causes insect to occur during paralysis machine dead.
Diacloden not only have tag, stomach toxicity, systemic activity, and there is the features such as fast, the lasting period length of higher activity, more preferable safety, wider array of insecticidal spectrum and speed of action, it is to replace that those are high to mammalian toxicity, have residual and the organophosphor of environmental problem, carbamate, the preferable kind of organochlorine insecticides.
Diacloden is to coleoptera, Diptera, Lepidoptera, especially Hemipteran pest has high activity, can effectively prevent and treat the insects such as various aphid, leafhopper, plant hopper, aleyrodid, chafer larva, colorado potato bug, nematicide, ground beetle, leaf miner and the insect of knot polytype chemical pesticide generation resistance.With imidacloprid, Acetamiprid, Nitenpyram no interactions resistance.
Insecticide variety containing single component often existing defects in pesticide Pest control: use is easily developed immunity to drugs continuously, and insecticidal spectrum is narrow, it is impossible to providing comprehensively protection for crop, peasant's drug cost is high.
Summary of the invention
It is an object of the invention to provide a kind of brominated cyanogen insect amide and the Synergistic insecticidal compositions of Diacloden, said composition can be used for preventing and treating various agricultural insect, such as preventing and treating vegetable diamondback moth, Pieris rapae, can be also used for preventing and treating cotton boll worm, beet armyworm and Brown Planthopper etc., a drug can be reached and prevent and treat the effect of dissimilar insect.
It is a further object of the present invention to provide the application that the Synergistic insecticidal compositions of brominated cyanogen insect amide and Diacloden is prevented and treated in resistance Lepidoptera, Semiptera, Hymenoptera or coleoptera in the insecticidal materials of one or more insects in preparation.
The present invention adopts the following technical scheme that
A kind of brominated cyanogen insect amide and the Synergistic insecticidal compositions of Diacloden, it is with bromine cyanogen insect amide and Diacloden as principle active component, and wherein, the weight ratio of bromine cyanogen insect amide and Diacloden is 1～60:1～60.The preferably weight ratio of bromine cyanogen insect amide and Diacloden is 1～40:1～40, and the weight ratio of further preferred bromine cyanogen insect amide and Diacloden is 1～30:1～30.nullIn some preferred technical schemes: bromine cyanogen insect amide and Diacloden can be at 1:30、1:29、1:28、1:27、1:26、1:25、1:24、1:24、1:22、1:21、1:20、1:19、1:18、1:17、1:16、1:15、1:14、1:13、1:12、1:11、1:10、1:9、1:8、1:7、1:6、1:5、1:4、1:3、1:2、1:1、2:1、3:1、4:1、5:1、6:1、7:1、8:1、9:1、10:1、11:1、12:1、13:1、14:1、15:1、16:1、17:1、18:1、19:1、20:1、21:1、22:1、23:1、24:1、25:1、26:1、27:1、28:1、29:1、30:1、2:3、3:2、2:5、5:2、3:4、4:3、5:2、2:5、5:3、3:5、5:4、These ratios of 4:5 select.
At brominated cyanogen insect amide and the Synergistic insecticidal compositions of Diacloden of the present invention, bromine cyanogen insect amide and thiamethoxam's weight percentage in this Synergistic insecticidal compositions are 2%～80%, and preferably 8%～60%, optimum is 20%～40%.
With bromine cyanogen insect amide, as principle active component, (active component) and insecticides adjuvant, excipient are configured on pesticide any one dosage form allowed to the Synergistic insecticidal compositions of above-mentioned brominated cyanogen insect amide and Diacloden with Diacloden.The preferred powder of dosage form, wettable powder, suspending agent, cream and water dispersion granule.
Described auxiliary agent can use calcium dodecyl benzene sulfonate, alkylphenol polyoxyethylene, polyoxyethylene polyoxy propylene block compound (such as agriculture breast 33#), NPE etc., excipient comprises Ketohexamethylene, dimethylbenzene, solvent naphtha, water, antifreezing agent (such as propylene glycol), deionized water etc..Above auxiliary agent, excipient and other agriculturally known adjuvant can be alone or and use.
The application in the insecticidal materials of one or more insects in preparation preventing and treating Lepidoptera, Semiptera, Hymenoptera or coleoptera of above-mentioned brominated cyanogen insect amide and the Synergistic insecticidal compositions of Diacloden.The especially application effect in the insecticidal materials of preparation preventing and treating planthopper or snout moths larva is notable.
The Synergistic insecticidal compositions antagonism lepidoptera pest of the present invention has significant preventive effect, and the various pests easily producing resistance particularly with cotton boll worm, beet armyworm, diamondback moth etc. has good preventive effect；And suppress insect the Drug resistance of unitary agent (bromine cyanogen insect amide or Diacloden) is produced and Hemipteran pest such as Brown Planthopper etc. can be prevented and treated simultaneously.
The insecticidal materials prepared by the Synergistic insecticidal compositions of described brominated cyanogen insect amide and Diacloden is while preventing and treating resistance Lepidoptera, Hymenoptera or coleopteran pest, Hemipteran pest can be prevented and treated again, especially cotton boll worm, diamondback moth and beet armyworm there are is good preventive effect, reach the effect that a medicine is controlled more.
The Pesticidal combination of the present invention compared with prior art, produces following beneficial effect: (1), compared with single dose, said composition insect has notable synergistic, hence it is evident that improve prevention effect；(2) one medicines are controlled more, and a dispenser can prevent and treat various pests simultaneously, reduce preventing and treating recruitment cost；(3) alternative high-toxic pesticide, and field dosage is greatly reduced, effectively reduce environmental pollution and pesticide residues；(4) have concurrently quick-acting and long-acting；(5) compared with bromine cyanogen insect amide single dose, produce and use cost reduces；(6) resistance of pesticide is strengthened by suppression insect.
Detailed description of the invention
Embodiments of the invention are the methods using indoor bioassay and field test to combine.First pass through indoor bioassay, the co-toxicity coefficient after clear and definite two kinds of medicaments are compounding by a certain percentage；On this basis, then carry out field test.
Embodiment 1:
Weigh 80g bromine cyanogen insect amide, 2g Diacloden, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, dimethylbenzene to 100g, the method that above raw material is prepared cream routinely puts into mixing in mixing kettle, forms the bromine cyanogen insect amide Diacloden cream that principle active component weight percentage is 82%.
Embodiment 2:
Weigh 2g bromine cyanogen insect amide, 80g Diacloden, lignin 10g, Negel 2g, add to 100g with Kaolin, above raw material is mixed in super micron mill, forms the bromine cyanogen insect amide Diacloden wettable powder that principle active component weight percentage is 82%.
Embodiment 3:
Weigh 60g bromine cyanogen insect amide, 2g Diacloden, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 6g, dimethylbenzene add to 100g, the method that above raw material is prepared cream routinely puts into mixing in mixing kettle, forms the bromine cyanogen insect amide Diacloden cream that principle active component weight percentage is 62%.
Embodiment 4:
Weigh 2g bromine cyanogen insect amide, 60g Diacloden, nonyl phenol phosphate 5g, alkylphenol polyoxyethylene 4g, the dimethylbenzene of n-butyl alcohol 3g, 10g and the ketopyrrolidine of 10g, the xanthan gum of 0.1g, remaining supplies 100g with water, n-butyl alcohol and water dissolution form aqueous phase, and remaining component mix and blend forms oil phase, slowly aqueous phase are added in oil phase under cutter effect, and continue to shear 10～30 minutes, form the bromine cyanogen insect amide Diacloden aqueous emulsion that principle active component weight percentage is 62%.
Embodiment 5:
Weigh 40g bromine cyanogen insect amide, 2g Diacloden, calcium dodecyl benzene sulfonate 5g, alkylphenol polyoxyethylene 4g, the solvent xylene of 30g and the ketopyrrolidine of 15g, remaining complements to 100g with water, former medicine, solvent, emulsifying agent, cosolvent mix and blend form homogeneous phase transparent solution, then it is slowly added into water and stirs formation clear solution, being the bromine cyanogen insect amide thiamethoxam micro-emulsion that principle active component weight percentage is 42%.
Embodiment 6:
Weigh 2g bromine cyanogen insect amide, 40g Diacloden, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 3g, dimethylbenzene to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, forms the bromine cyanogen insect amide Diacloden cream that principle active component weight percentage is 42%.
Embodiment 7:
Weigh 20g bromine cyanogen insect amide, 2g Diacloden, sodium lignin sulfonate 3g, polyoxyethylene poly-oxygen propylene aether and sulfate 4g thereof, xanthan gum 0.2g, ethylene glycol 10g, silica ethane 0.1g, aluminium-magnesium silicate 0.5g, supplies 100g with water, forms the bromine cyanogen insect amide Diacloden suspending agent that principle active component weight percentage is 22% under the effect of sand mill.
Embodiment 8:
Weigh 2g bromine cyanogen insect amide, 20g Diacloden, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether 15g, dimethylbenzene to 100g, the method that above raw material is prepared cream routinely puts into mixing in mixing kettle, forms the bromine cyanogen insect amide Diacloden cream that principle active component weight percentage is 22%.
Embodiment 9:
Weigh 2g bromine cyanogen insect amide, 10g Diacloden, sodium lignin sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, Borax 2g, Kaolin 28g, forms, by the method for water dispersion granule, the bromine cyanogen insect amide Diacloden water dispersible granules that principle active component weight percentage is 12% by above raw material.
Embodiment 10:
Weigh 5g bromine cyanogen insect amide, 10g Diacloden, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether 15g, dimethylbenzene to 100g, the method that above raw material is prepared cream routinely puts into mixing in mixing kettle, forms the bromine cyanogen insect amide Diacloden cream that principle active component weight percentage is 15%.
Embodiment 11:
Weigh 10g bromine cyanogen insect amide, 10g Diacloden, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, dimethylbenzene to 100g, the method that above raw material is prepared cream routinely puts into mixing in mixing kettle, forms the bromine cyanogen insect amide Diacloden cream that principle active component weight percentage is 20%.
Drug effect checking test
1, indoor virulence determination of activity
Weigh bromine cyanogen insect amide, Diacloden uses conventional formulation method to be configured to, by different proportion, the bromine cyanogen insect amide Diacloden cream that principle active component weight percentage is 30%.Concrete ratio is shown in Table 1.
Using feedstuff to add poison method and measure bromine cyanogen insect amide and Diacloden and the compounding sample virulence to cotton boll worm thereof, often process and be repeated 3 times, every concentration processes 30, uses LC50It is worth and presses Sun Yun abundant method calculating co-toxicity coefficient:
Table 1 bromine cyanogen insect amide, Diacloden and compounding sample thereof are to the toxicity test of cotton boll worm and co-toxicity coefficient
In table, data show, after bromine cyanogen insect amide and Diacloden mixture, cotton boll worm are had potentiation, and proportioning co-toxicity coefficient listed in table is both greater than 120, and therefore bromine cyanogen insect amide and Diacloden mixture have significant synergies.
Weigh bromine cyanogen insect amide, Diacloden uses conventional formulation method to be configured to, by different proportion, the bromine cyanogen insect amide Diacloden cream that principle active component weight percentage is 30%.Concrete ratio is shown in Table 2.
Use rice-stem dipping method to measure bromine cyanogen insect amide and Diacloden and the compounding sample virulence to Brown Planthopper thereof, often process and be repeated 3 times, use LC50It is worth and presses Sun Yun abundant method calculating co-toxicity coefficient:
Table 2 bromine cyanogen insect amide, Diacloden and compounding sample thereof are to the toxicity test of Brown Planthopper and co-toxicity coefficient
In table, data show, have potentiation after bromine cyanogen insect amide and Diacloden mixture to Brown Planthopper, and proportioning co-toxicity coefficient listed in table is all much larger than 120, and therefore bromine cyanogen insect amide and Diacloden mixture have significant synergies.
2, field control effectiveness test
Using embodiment institute sample product to carry out the field test of control in field cotton boll worm, comparison medicament is 5% bromine cyanogen insect amide EC and 25% Diacloden WP, and concrete consumption is shown in Table 3, every mu of water consumption is 30kg, looks into 3 days after medicine, 7 days, 14 days results, result of the test is shown in Table 3:
Table 3 sample field test results to cotton boll worm
Example has fabulous quick-acting to cotton boll worm as can be seen from Table 3, and the lasting period is long, good at variable rate technology, is the outstanding medicament of preventing and treating cotton boll worm.
Measure through indoor synergism test and show: by bromine cyanogen insect amide and Thiamethoxam compound agent, cotton boll worm and Brown Planthopper are had significant synergistic insecticidal action；Field control effectiveness test also indicates that all of built agent of the present invention is all remarkably higher than the effect of corresponding single dose pesticide to cotton boll worm insecticidal effect equally.
Claims (9)
1. brominated cyanogen insect amide and a Synergistic insecticidal compositions for Diacloden, is characterized in that this Synergistic insecticidal compositions is with bromine cyanogen worm
Amide and Diacloden are principle active component, and wherein, the weight ratio of bromine cyanogen insect amide and Diacloden is 1～60:1～60.
Brominated cyanogen insect amide the most according to claim 1 and the Synergistic insecticidal compositions of Diacloden, is characterized in that this parasite killing group
The active ingredient bromine cyanogen insect amide of compound and the weight ratio of Diacloden are 1～40:1～40.
Brominated cyanogen insect amide the most according to claim 2 and the Synergistic insecticidal compositions of Diacloden, is characterized in that this parasite killing group
The active ingredient bromine cyanogen insect amide of compound and the weight ratio of Diacloden are 1～30:1～30.
Brominated cyanogen insect amide the most according to claim 1 and the Synergistic insecticidal compositions of Diacloden, is characterized in that bromine cyanogen worm acyl
Amine and thiamethoxam's weight percentage in this Synergistic insecticidal compositions are 2%～80%.
Brominated cyanogen insect amide the most according to claim 4 and the Synergistic insecticidal compositions of Diacloden, is characterized in that bromine cyanogen worm acyl
Amine and thiamethoxam's weight percentage in this Synergistic insecticidal compositions are 8%～60%.
Brominated cyanogen insect amide the most according to claim 1 and the Synergistic insecticidal compositions of Diacloden, is characterized in that this potentiation is killed
With bromine cyanogen insect amide, as principle active component and insecticides adjuvant, excipient are configured on pesticide appointing of permission to worm compositions with Diacloden
A kind of dosage form of meaning.
Brominated cyanogen insect amide the most according to claim 6 and the Synergistic insecticidal compositions of Diacloden, is characterized in that described dosage form
It is cream, wettable powder, microemulsion, aqueous emulsion, suspending agent or water dispersion granule.
8. the Synergistic insecticidal compositions of brominated cyanogen insect amide described in claim 1 and Diacloden is at preparation preventing and treating Lepidoptera, half wing
Application in the insecticidal materials of one or more insects in mesh, Hymenoptera or coleoptera.
Application the most according to claim 8, is characterized in that the Synergistic insecticidal compositions of brominated cyanogen insect amide and Diacloden is in system
Application in the insecticidal materials of standby preventing and treating cotton boll worm, beet armyworm and Brown Planthopper.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2021064731A1 (en) * | 2019-10-03 | 2021-04-08 | Adama Makhteshim Ltd. | Pesticidal mixtures |
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