CN106070227A - A kind of compound pesticide compositions of brominated cyanogen insect amide and pleocidin and application thereof - Google Patents
A kind of compound pesticide compositions of brominated cyanogen insect amide and pleocidin and application thereof Download PDFInfo
- Publication number
- CN106070227A CN106070227A CN201610450188.9A CN201610450188A CN106070227A CN 106070227 A CN106070227 A CN 106070227A CN 201610450188 A CN201610450188 A CN 201610450188A CN 106070227 A CN106070227 A CN 106070227A
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- Prior art keywords
- pleocidin
- insect amide
- cyanogen insect
- pesticide compositions
- compound pesticide
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/22—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom rings with more than six members
Abstract
The invention discloses compound pesticide compositions of a kind of brominated cyanogen insect amide and pleocidin and application thereof, this Pesticidal combination is with bromine cyanogen insect amide and pleocidin as active insecticidal components, wherein, the weight ratio of bromine cyanogen insect amide and pleocidin is 0.1～80:0.5～80.This Pesticidal combination can produce higher synergistic function, overcomes and delayed pest resistance to insecticide, and parasite killing speed is fast, and the lasting period is long, reduces drug cost, and prevention effect uses apparently higher than its single dose.The present invention can prevent and treat the lepidoptera pest occurred on crops, is used especially for preventing and treating bollworm, snout moths larva, and its effect uses apparently higher than its single dose.
Description
Technical field
The invention belongs to the field of agricultural pesticide containing heterocyclic compound, concrete body relates to a kind of composite insecticidal combination
Thing.
Background technology
Bromine cyanogen insect amide (cyantraniliprole), is E.I.Du Pont Company's second filial generation that success is developed after chlorantraniliprole
Ryanodine receptor inhibitor insecticides, cyanogen insect amide is to be formed by the various polar groups on change phenyl ring, has higher
Effect, applicable crops is more extensive, can effectively prevent and treat Lepidoptera, Semiptera and coleopteran pest.
Pleocidin has another name called multiple killing teichomycin (Spinosad), molecular formula: C41H65NO10.It is to sting sugared many born of the same parents bacterium
A kind of Macrolide Nuisanceless high-efficient biological insecticides extracted in (Saccharopolyspora spinosa) fermentation liquid.
Structural formula:
Insect is had and quickly tags and stomach poison function, blade is had stronger osmosis, can kill subepidermal
Insect, the longevity of residure is longer, some insects is had certain ovicidal action, without systemic action.Can effectively preventing Lepidoptera, double
Wing mesh and Thysanoptera, also can well prevent and treat in coleoptera and Orthoptera some pest species taking food blade in a large number, right
The prevention effect of sucking pest and demodicid mite class is poor.Safer to predatory natural enemy insect, because insecticidal action mechanism is unique, mesh
Before not yet find with other insecticides there is mutual drug-fast report.It is suitable on vegetable, fruit tree, gardening, crops using,
Insecticidal effect is affected less by raining.
But the insect such as bollworm, snout moths larva is under conditions of current long-term prescription, and resistance is gradually increased, pesticide single dose is to evil
The effect of worm preventing and treating is gradually reduced.
Summary of the invention
It is an object of the invention to provide a kind of brominated cyanogen insect amide and the compound pesticide compositions of pleocidin, this parasite killing group
Compound is the multifunctional insecticide compositions of preventing and treating lepidoptera pest.
It is a further object of the present invention to provide this Pesticidal combination and prevent and treat the insecticidal materials of resistance lepidoptera pest in preparation
On application, particularly preparation preventing and treating bollworm or snout moths larva insecticidal materials on application.
It is an object of the invention to be achieved through the following technical solutions:
A kind of brominated cyanogen insect amide and the compound pesticide compositions of pleocidin, this compound pesticide compositions is with bromine cyanogen worm acyl
Amine and pleocidin are principle active component, wherein, the weight ratio of bromine cyanogen insect amide and pleocidin be 0.1～80:0.5～
80。
In this compound pesticide compositions, the weight ratio of bromine cyanogen insect amide (A) and pleocidin (B) be preferably 1～60:1～
60, more preferably 1～40:1～40, most preferably 1～30:1～30.In some preferred technical schemes: bromine cyanogen worm
Amide and pleocidin can 1:30,1:29,1:28,1:27,1:26,1:25,1:24,1:24,1:22,1:21,1:20,1:
19、1:18、1:17、1:16、1:15、1:14、1:13、1:12、1:11、1:10、1:9、1:8、1:7、1:6、1:5、1:4、1:3、
1:2、1:1、2:1、3:1、4:1、5:1、6:1、7:1、8:1、9:1、10:1、11:1、12:1、13:1、14:1、15:1、16:1、
17:1、18:1、19:1、20:1、21:1、22:1、23:1、24:1、25:1、26:1、27:1、28:1、29:1、30:1、2:3、3:
2, these ratios of 2:5,5:2,3:4,4:3,5:2,2:5,5:3,3:5,5:4,4:5 select.
This compound pesticide compositions can comprise only active component bromine cyanogen insect amide and pleocidin, it is possible to is using or preparation
Time in active component, add other components, the active ingredient in this Pesticidal combination can be present in combination with enhancing effective amount
In thing.
In compound pesticide compositions of the present invention, bromine cyanogen insect amide and both pleocidin are in this compound pesticide compositions
Weight percentage be 3%～80%.It is preferably 5%～55%, most preferably 10%～40%.
Compound pesticide compositions of the present invention with bromine cyanogen insect amide and pleocidin as active component or principle active component, and
Insecticides adjuvant and excipient become any one dosage form allowed on pesticide, the preferred cream of described dosage form, suspending agent, wettable
Property powder, aqueous emulsion, microemulsion or water dispersion granule.
The insecticides adjuvant of the aforementioned present invention of can be applicable to is not particularly limited, and includes, but are not limited to detergent alkylate
Sulfoacid calcium, 600#, polyoxyethylene polyoxy propylene block compound are (such as agriculture breast 33#), NPE etc., aforementioned should
Excipient for the present invention is also not particularly limited, include, but are not limited to solvent naphtha, water, antifreezing agent (such as propylene glycol),
Deionized water etc..Above auxiliary agent, excipient and other adjuvant can be alone or and use.
Compound pesticide compositions of the present invention easily produces multiple Semiptera and the Lepidoptera of resistance to planthopper and snout moths larva etc.
Insect has good preventive effect；And suppress the insect Drug resistance to unitary agent (bromine cyanogen insect amide or pleocidin are arbitrary)
Produce.
Above-mentioned compound pesticide compositions prevents and treats the application on resistance lepidoptera pest insecticidal materials in preparation, especially in system
Application effect on standby preventing and treating bollworm or snout moths larva insecticidal materials is notable.
Compared with prior art beneficial effects of the present invention: (1) compared with single dose, said composition antagonism lepidoptera pest
As bollworm, snout moths larva etc. have obvious synergistic function, overcoming and delayed pest resistance to insecticide, expanding prevention is composed, parasite killing speed
Hurry up, hence it is evident that improve prevention effect；(2) preventing and treating recruitment, drug cost are reduced；(3) alternative high-toxic pesticide；(4) have concurrently quick-acting
With long-acting；(5) with bromine cyanogen insect amide compared with pleocidin single dose, produce and use cost reduces；(6) suppression lepidoptera pest
Strengthening the resistance of pesticide, its effect uses apparently higher than its single dose.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described, but limits the present invention never in any form.
Embodiment 1:
Weigh 80g bromine cyanogen insect amide, 2g pleocidin, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g,
Dimethylbenzene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, forms principle active component
Weight percentage is the bromine cyanogen insect amide pleocidin cream of 82%.
Embodiment 2:
Weigh 2g bromine cyanogen insect amide, 80g pleocidin, lignin 10g, Negel 2g, add to Kaolin
100g, mixes above raw material in super micron mill, forms the bromine cyanogen worm that principle active component weight percentage is 82%
Amide pleocidin wettable powder.
Embodiment 3:
Weigh 60g bromine cyanogen insect amide, 2g pleocidin, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 6g,
Dimethylbenzene adds to 100g, and the method that above raw material is prepared cream routinely puts into mixing in mixing kettle, is formed and the most effectively becomes
The bromine cyanogen insect amide pleocidin cream dividing weight percentage to be 62%.
Embodiment 4:
Weigh 2g bromine cyanogen insect amide, 60g pleocidin, nonyl phenol phosphate 5g, alkylphenol polyoxyethylene 4g, n-butyl alcohol
The dimethylbenzene of 3g, 10g and the ketopyrrolidine of 10g, the xanthan gum of 0.1g, remaining supplies 100g, n-butyl alcohol and water dissolution shape with water
Becoming aqueous phase, remaining component mix and blend forms oil phase, slowly aqueous phase is added in oil phase, and continue to cut under cutter effect
Cut 10～30 minutes, form the bromine cyanogen insect amide pleocidin aqueous emulsion that principle active component weight percentage is 62%.
Embodiment 5:
Weigh 40g bromine cyanogen insect amide, 2g pleocidin, calcium dodecyl benzene sulfonate 5g, alkylphenol polyoxyethylene 4g,
The solvent xylene of 30g and the ketopyrrolidine of 15g, remaining complements to 100g, the mixing of former medicine, solvent, emulsifying agent, cosolvent with water
Stirring forms homogeneous phase transparent solution, is then slowly added into water and stirs formation clear solution, being principle active component weight hundred
The bromine cyanogen insect amide pleocidin microemulsion dividing content to be 42%.
Embodiment 6:
Weigh 2g bromine cyanogen insect amide, 40g pleocidin, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 3g,
Dimethylbenzene is to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, forms principle active component
Weight percentage is the bromine cyanogen insect amide pleocidin cream of 42%.
Embodiment 7:
Weigh 20g bromine cyanogen insect amide, 2g pleocidin, sodium lignin sulfonate 3g, polyoxyethylene poly-oxygen propylene aether and sulfur thereof
Hydrochlorate 4g, xanthan gum 0.2g, ethylene glycol 10g, silica ethane 0.1g, aluminium-magnesium silicate 0.5g, supply 100g with water, at sand mill
Effect is lower forms the bromine cyanogen insect amide pleocidin suspension that principle active component weight percentage is 22%.
Embodiment 8:
Weigh 2g bromine cyanogen insect amide, 20g pleocidin, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether
15g, dimethylbenzene put into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, are formed main effective
Ingredients Weight percentage composition is the bromine cyanogen insect amide pleocidin cream of 22%.
Embodiment 9:
Weigh 10g bromine cyanogen insect amide, 2g pleocidin, sodium lignin sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate
5g, polyvinyl alcohol 5g, Borax 2g, Kaolin 28g, the method that above raw material is pressed water dispersion granule forms principle active component
Weight percentage is the bromine cyanogen insect amide pleocidin water dispersible granules of 12%.
Embodiment 10:
Weigh 15g bromine cyanogen insect amide, 5g pleocidin, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether
15g, dimethylbenzene put into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, are formed main effective
Ingredients Weight percentage composition is the bromine cyanogen insect amide pleocidin cream of 20%.
Embodiment 11:
Weigh 10g bromine cyanogen insect amide, 10g pleocidin, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether
3g, dimethylbenzene put into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, are formed and the most effectively become
The bromine cyanogen insect amide pleocidin cream dividing weight percentage to be 20%.
Drug effect checking test
1, indoor virulence determination of activity
Weigh bromine cyanogen insect amide and pleocidin 30g, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether altogether
4g, vegetable oil are to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, is configured to main effective
Ingredients Weight percentage composition is the bromine cyanogen insect amide pleocidin cream of 30%.Wherein bromine cyanogen insect amide and the tool of pleocidin
Body ratio is shown in Table 1 and 2.
Using feedstuff to add poison method and carry out indoor potentiation bioassay, selection resistant bollworm is target pest, often processes weight
Multiple 3 times, every concentration processes 60, with probability value method calculate each medicament antagonism bollworm toxicity regression equation and lethal in dense
Degree LC50, use LC50Value press Sun Yun abundant method calculating co-toxicity coefficient, the results are shown in Table 1:
Table 1 bromine cyanogen insect amide, pleocidin and the toxicity test of compounding sample antagonism bollworm thereof and co-toxicity coefficient
In table, data show, after bromine cyanogen insect amide and pleocidin mixture, antagonism bollworm are had potentiation, table
Proportioning co-toxicity coefficient listed by is both greater than 120, and therefore bromine cyanogen insect amide and pleocidin mixture have significant synergies.
Weigh bromine cyanogen insect amide, pleocidin uses conventional formulation method to be configured to principle active component weight by different proportion
Amount percentage composition is the bromine cyanogen insect amide pleocidin cream of 30%.Concrete ratio is shown in Table 2.
Using feedstuff to add poison method and carry out indoor potentiation bioassay, selection rice-stem borer is target pest, often processes weight
Multiple 3 times, calculate toxicity regression equation and lethal concentration of 50 LC of each medicament antagonism striped rice borer by probability value method50, use LC50Value
Calculate co-toxicity coefficient by the abundant method of Sun Yun, the results are shown in Table 2:
Table 2 bromine cyanogen insect amide, pleocidin and compounding sample thereof to striped rice borer toxicity test and co-toxicity coefficient
In table, data show, rice-stem borer are had potentiation, in table after bromine cyanogen insect amide and pleocidin mixture
Listed proportioning co-toxicity coefficient is all much larger than 120, and therefore bromine cyanogen insect amide and pleocidin mixture have significant synergies.
2, field control effectiveness test
Using embodiment institute sample product to carry out the field test of control in field bollworm, comparison medicament is 40% pleocidin
EC (cream) and 20% bromine cyanogen insect amide WP (wettable powder), be diluted according to the extension rate in form 3, look into 3 after medicine
My god, 7 days, the result of 14 days, result is shown in Table 3:
The field test results of table 3 bromine cyanogen insect amide-pleocidin compound antagonism bollworm
Example has fabulous quick-acting to antagonism bollworm as can be seen from Table 3, and the lasting period is long, in field
Performance is good, is the outstanding medicament preventing and treating antagonism bollworm.
Measure through indoor synergism test and show: with pleocidin compound agent, bollworm and Oryza sativa L. two are changed by bromine cyanogen insect amide
Snout moth's larva has significant synergistic insecticidal action；Field control effectiveness test also indicates that bollworm parasite killing is imitated by all of built agent of the present invention equally
Fruit is all remarkably higher than the effect of corresponding single dose pesticide.
Claims (10)
1. brominated cyanogen insect amide and a compound pesticide compositions for pleocidin, is characterized in that this compound pesticide compositions is with bromine
Cyanogen insect amide and pleocidin are active insecticidal components, and wherein, the weight ratio of bromine cyanogen insect amide and pleocidin is 0.1～80:
0.5～80.
Brominated cyanogen insect amide the most according to claim 1 and the compound pesticide compositions of pleocidin, is characterized in that described
Bromine cyanogen insect amide and the weight ratio of pleocidin be 1～60:1～60.
Brominated cyanogen insect amide the most according to claim 2 and the compound pesticide compositions of pleocidin, is characterized in that described
Bromine cyanogen insect amide and the weight ratio of pleocidin be 1～40:1～40.
Brominated cyanogen insect amide the most according to claim 3 and the compound pesticide compositions of pleocidin, is characterized in that described
Bromine cyanogen insect amide and the weight ratio of pleocidin be 1～30:1～30.
Brominated cyanogen insect amide the most according to claim 1 and the compound pesticide compositions of pleocidin, is characterized in that bromine cyanogen
Insect amide and both pleocidin weight percentage in this compound pesticide compositions are 3%～80%.
Brominated cyanogen insect amide the most according to claim 5 and the compound pesticide compositions of pleocidin, is characterized in that bromine cyanogen
Insect amide and both pleocidin weight percentage in this compound pesticide compositions are 5%～55%.
Brominated cyanogen insect amide the most according to claim 1 and the compound pesticide compositions of pleocidin, is characterized in that this is multiple
With bromine cyanogen insect amide and pleocidin as active insecticidal components and insecticides adjuvant and excipient are configured to pesticide to close Pesticidal combination
The dosage form of upper permission.
Brominated cyanogen insect amide the most according to claim 7 and the compound pesticide compositions of pleocidin, is characterized in that described
Dosage form is cream, suspending agent, aqueous emulsion, wettable powder, microemulsion or water dispersion granule.
9. the compound pesticide compositions of brominated cyanogen insect amide described in claim 1 and pleocidin prevents and treats resistance squama wing in preparation
Application on the insecticidal materials of mesh insect.
The compound pesticide compositions of brominated cyanogen insect amide the most according to claim 9 and pleocidin is in preparation preventing and treating cotton
Application on the insecticidal materials of earworm or snout moths larva.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610450188.9A CN106070227A (en) | 2016-06-21 | 2016-06-21 | A kind of compound pesticide compositions of brominated cyanogen insect amide and pleocidin and application thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610450188.9A CN106070227A (en) | 2016-06-21 | 2016-06-21 | A kind of compound pesticide compositions of brominated cyanogen insect amide and pleocidin and application thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114946891A (en) * | 2022-06-27 | 2022-08-30 | 河南农王实业有限公司 | Agricultural composition containing cyantraniliprole and spinosad |
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| CN102578101A (en) * | 2012-02-07 | 2012-07-18 | 上海沪联生物药业（夏邑）有限公司 | Application of pesticide composition containing spinosad and cyantraniliprole for preparing pesticide for preventing trialeurodes vaporariorum and thrips |
| CN103300003A (en) * | 2012-03-15 | 2013-09-18 | 浙江森得保生物制品有限公司 | Plane-prevention drug containing pleocidin and cyanoantraniliprole binary composition |
| JP2015214554A (en) * | 2015-06-11 | 2015-12-03 | 住友化学株式会社 | Plant disease and harmful arthropod control composition and plant disease and harmful arthropod control method |
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2016
- 2016-06-21 CN CN201610450188.9A patent/CN106070227A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102283205A (en) * | 2004-07-26 | 2011-12-21 | 杜邦公司 | Mixtures of anthranilamide invertebrate pest control agents |
| CN102308805A (en) * | 2011-10-19 | 2012-01-11 | 北京燕化永乐农药有限公司 | Compound pesticide |
| CN102578101A (en) * | 2012-02-07 | 2012-07-18 | 上海沪联生物药业（夏邑）有限公司 | Application of pesticide composition containing spinosad and cyantraniliprole for preparing pesticide for preventing trialeurodes vaporariorum and thrips |
| CN103300003A (en) * | 2012-03-15 | 2013-09-18 | 浙江森得保生物制品有限公司 | Plane-prevention drug containing pleocidin and cyanoantraniliprole binary composition |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114946891A (en) * | 2022-06-27 | 2022-08-30 | 河南农王实业有限公司 | Agricultural composition containing cyantraniliprole and spinosad |
| CN114946891B (en) * | 2022-06-27 | 2024-04-02 | 河南农王实业有限公司 | Agricultural composition containing cyantraniliprole and spinosad |
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Application publication date: 20161109 |