CN106070278A - A kind of compound pesticide compositions of brominated cyanogen insect amide and Cascade and application thereof - Google Patents
A kind of compound pesticide compositions of brominated cyanogen insect amide and Cascade and application thereof Download PDFInfo
- Publication number
- CN106070278A CN106070278A CN201610456706.8A CN201610456706A CN106070278A CN 106070278 A CN106070278 A CN 106070278A CN 201610456706 A CN201610456706 A CN 201610456706A CN 106070278 A CN106070278 A CN 106070278A
- Authority
- CN
- China
- Prior art keywords
- cascade
- insect amide
- cyanogen insect
- pesticide compositions
- compound pesticide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- IPFPFMVBGNLQTC-UHFFFAOYSA-N Cc1c(C(C(C(NC(C(F)=C2)=CCC2Oc(ccc(C(F)(F)F)c2)c2Cl)O)=N)O)c(F)ccc1 Chemical compound Cc1c(C(C(C(NC(C(F)=C2)=CCC2Oc(ccc(C(F)(F)F)c2)c2Cl)O)=N)O)c(F)ccc1 IPFPFMVBGNLQTC-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/34—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
Abstract
The invention discloses compound pesticide compositions of a kind of brominated cyanogen insect amide and Cascade and application thereof, this Pesticidal combination is with bromine cyanogen insect amide and Cascade as active insecticidal components, and wherein, the weight ratio of bromine cyanogen insect amide and Cascade is 0.1～80:0.5～80.This Pesticidal combination can produce higher synergistic function, overcomes and delayed pest resistance to insecticide, and parasite killing speed is fast, and the lasting period is long, reduces drug cost, and prevention effect uses apparently higher than its single dose.The present invention can prevent and treat the lepidoptera pest occurred on crops, is used especially for preventing and treating bollworm, snout moths larva, and its effect uses apparently higher than its single dose.
Description
Technical field
The invention belongs to the field of agricultural pesticide containing heterocyclic compound, concrete body relates to a kind of composite insecticidal combination
Thing.
Background technology
Bromine cyanogen insect amide (cyantraniliprole), is E.I.Du Pont Company's second filial generation that success is developed after chlorantraniliprole
Ryanodine receptor inhibitor insecticides, cyanogen insect amide is to be formed by the various polar groups on change phenyl ring, has higher
Effect, applicable crops is more extensive, can effectively prevent and treat Lepidoptera, Semiptera and coleopteran pest.
Cascade (flufenoxuron), molecular formula: C21H11CLF6N2O3, chemical name: 1-[4-(2-chloro-Α, Α,
Α-trifluoro p-methoxyphenyl (-2-fluorophenyl]-3-(2,6-difluorobenzoyl) urea, structural formula is:
Cascade is to belong to process for preparation of benzoylurea compounds, is chitin synthesis inhibitor, its insecticidal activity, insecticidal spectrum and effect
Speed all has characteristic, and has good blade face anelasticity. and especially demodicid mite and insect to mezzanine level has high activity, extensively uses
On Citrus, Cotton Gossypii, Fructus Vitis viniferae, Semen sojae atricolor, fruit tree, king's rice and coffee, preventing and treating food planting property demodicid mite class (thorn wart demodicid mite, short hairs demodicid mite, Panonychus citri,
Rust mite, tetranychus telarius etc.) and other insects many, and have good lasting effect, to predatory mite and insecticide safety.
Insecticide variety containing single component often existing defects in pesticide Pest control: use continuously easily produce anti-
The property of medicine, insecticidal spectrum is narrow, it is impossible to providing comprehensively protection for crop, peasant's drug cost is high.
Summary of the invention
It is an object of the invention to provide a kind of brominated cyanogen insect amide and the compound pesticide compositions of Cascade, this Insecticidal combinations
Thing is the multifunctional insecticide compositions of preventing and treating lepidoptera pest.
It is a further object of the present invention to provide this Pesticidal combination and prevent and treat the insecticidal materials of resistance lepidoptera pest in preparation
On application, particularly preparation preventing and treating bollworm or snout moths larva insecticidal materials on application.
It is an object of the invention to be achieved through the following technical solutions:
A kind of brominated cyanogen insect amide and the compound pesticide compositions of Cascade, this compound pesticide compositions is with bromine cyanogen insect amide
Being principle active component with Cascade, wherein, the weight ratio of bromine cyanogen insect amide and Cascade is 0.1～80:0.5～80.
In this compound pesticide compositions, the weight ratio of bromine cyanogen insect amide (A) and Cascade (B) is preferably 1～60:1～60,
More preferably 1～40:1～40, most preferably 1～30:1～30.In some preferred technical schemes: bromine cyanogen insect amide
With Cascade can 1:30,1:29,1:28,1:27,1:26,1:25,1:24,1:24,1:22,1:21,1:20,1:19,1:
18、1:17、1:16、1:15、1:14、1:13、1:12、1:11、1:10、1:9、1:8、1:7、1:6、1:5、1:4、1:3、1:2、1:
1、2:1、3:1、4:1、5:1、6:1、7:1、8:1、9:1、10:1、11:1、12:1、13:1、14:1、15:1、16:1、17:1、18:
1、19:1、20:1、21:1、22:1、23:1、24:1、25:1、26:1、27:1、28:1、29:1、30:1、2:3、3:2、2:5、5:
2, these ratios of 3:4,4:3,5:2,2:5,5:3,3:5,5:4,4:5 select.
This compound pesticide compositions can comprise only active component bromine cyanogen insect amide and Cascade, it is possible to when using or prepare
Adding other components in active component, the active ingredient in this Pesticidal combination can be present in compositions with enhancing effective amount
In.
In compound pesticide compositions of the present invention, bromine cyanogen insect amide and both Cascades are in this compound pesticide compositions
Weight percentage is 3%～80%.It is preferably 5%～55%, most preferably 10%～40%.
Compound pesticide compositions of the present invention is with bromine cyanogen insect amide and Cascade as active component or principle active component, and agriculture
Medicine auxiliary agent and excipient become any one dosage form allowed on pesticide, the preferred cream of described dosage form, suspending agent, wettability
Powder, aqueous emulsion, microemulsion or water dispersion granule.
The insecticides adjuvant of the aforementioned present invention of can be applicable to is not particularly limited, and includes, but are not limited to detergent alkylate
Sulfoacid calcium, 600#, polyoxyethylene polyoxy propylene block compound are (such as agriculture breast 33#), NPE etc., aforementioned should
Excipient for the present invention is also not particularly limited, include, but are not limited to solvent naphtha, water, antifreezing agent (such as propylene glycol),
Deionized water etc..Above auxiliary agent, excipient and other adjuvant can be alone or and use.
Compound pesticide compositions of the present invention easily produces multiple Semiptera and the Lepidoptera of resistance to planthopper and snout moths larva etc.
Insect has good preventive effect；And suppress insect that the Drug resistance of unitary agent (bromine cyanogen insect amide or Cascade are arbitrary) is produced
Raw.
Above-mentioned compound pesticide compositions prevents and treats the application on resistance lepidoptera pest insecticidal materials in preparation, especially in system
Application effect on standby preventing and treating bollworm or snout moths larva insecticidal materials is notable.
Compared with prior art beneficial effects of the present invention: (1) compared with single dose, said composition antagonism lepidoptera pest
As bollworm, snout moths larva etc. have obvious synergistic function, overcoming and delayed pest resistance to insecticide, expanding prevention is composed, parasite killing speed
Hurry up, hence it is evident that improve prevention effect；(2) preventing and treating recruitment, drug cost are reduced；(3) alternative high-toxic pesticide；(4) have concurrently quick-acting
With long-acting；(5) with bromine cyanogen insect amide compared with Cascade single dose, produce and use cost reduces；(6) suppression lepidoptera pest
Strengthening the resistance of pesticide, its effect uses apparently higher than its single dose.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described, but limits the present invention never in any form.
Embodiment 1:
Weigh 80g bromine cyanogen insect amide, 2g Cascade, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, two
Toluene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, forms principle active component weight
Amount percentage composition is the bromine cyanogen insect amide Cascade cream of 82%.
Embodiment 2:
Weigh 2g bromine cyanogen insect amide, 80g Cascade, lignin 10g, Negel 2g, add to 100g with Kaolin,
Above raw material is mixed in super micron mill, forms the bromine cyanogen insect amide that principle active component weight percentage is 82%
Cascade wettable powder.
Embodiment 3:
Weigh 60g bromine cyanogen insect amide, 2g Cascade, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 6g, two
Toluene adds to 100g, and the method that above raw material is prepared cream routinely puts into mixing in mixing kettle, forms principle active component
Weight percentage is the bromine cyanogen insect amide Cascade cream of 62%.
Embodiment 4:
Weigh 2g bromine cyanogen insect amide, 60g Cascade, nonyl phenol phosphate 5g, alkylphenol polyoxyethylene 4g, n-butyl alcohol
The dimethylbenzene of 3g, 10g and the ketopyrrolidine of 10g, the xanthan gum of 0.1g, remaining supplies 100g, n-butyl alcohol and water dissolution shape with water
Becoming aqueous phase, remaining component mix and blend forms oil phase, slowly aqueous phase is added in oil phase, and continue to cut under cutter effect
Cut 10～30 minutes, form the bromine cyanogen insect amide Cascade aqueous emulsion that principle active component weight percentage is 62%.
Embodiment 5:
Weigh 40g bromine cyanogen insect amide, 2g Cascade, calcium dodecyl benzene sulfonate 5g, alkylphenol polyoxyethylene 4g, 30g
Solvent xylene and the ketopyrrolidine of 15g, remaining complements to 100g with water, and the mixing of former medicine, solvent, emulsifying agent, cosolvent is stirred
Mix formation homogeneous phase transparent solution, be then slowly added into water and stir formation clear solution, being principle active component weight percent
Content is the bromine cyanogen insect amide Cascade microemulsion of 42%.
Embodiment 6:
Weigh 2g bromine cyanogen insect amide, 40g Cascade, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 3g, two
Toluene is to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, forms principle active component weight
Amount percentage composition is the bromine cyanogen insect amide Cascade cream of 42%.
Embodiment 7:
Weigh 20g bromine cyanogen insect amide, 2g Cascade, sodium lignin sulfonate 3g, polyoxyethylene poly-oxygen propylene aether and sulphuric acid thereof
Salt 4g, xanthan gum 0.2g, ethylene glycol 10g, silica ethane 0.1g, aluminium-magnesium silicate 0.5g, supply 100g with water, at the work of sand mill
With the bromine cyanogen insect amide Cascade suspending agent that lower formation principle active component weight percentage is 22%.
Embodiment 8:
Weigh 2g bromine cyanogen insect amide, 20g Cascade, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether 15g,
Dimethylbenzene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, forms principle active component
Weight percentage is the bromine cyanogen insect amide Cascade cream of 22%.
Embodiment 9:
Weigh 10g bromine cyanogen insect amide, 2g Cascade, sodium lignin sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g,
Polyvinyl alcohol 5g, Borax 2g, Kaolin 28g, the method that above raw material is pressed water dispersion granule forms principle active component weight
Amount percentage composition is the bromine cyanogen insect amide Cascade water dispersible granules of 12%.
Embodiment 10:
Weigh 15g bromine cyanogen insect amide, 5g Cascade, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether 15g,
Dimethylbenzene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, forms principle active component
Weight percentage is the bromine cyanogen insect amide Cascade cream of 20%.
Embodiment 11:
Weigh 10g bromine cyanogen insect amide, 10g Cascade, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g,
Dimethylbenzene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, forms principle active component
Weight percentage is the bromine cyanogen insect amide Cascade cream of 20%.
Drug effect checking test
1, indoor virulence determination of activity
Weigh bromine cyanogen insect amide and Cascade 30g, calcium dodecyl benzene sulfonate 4g altogether, phenethyl phenol polyethenoxy ether 4g,
Vegetable oil is to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, is configured to main effectively one-tenth
The bromine cyanogen insect amide Cascade cream dividing weight percentage to be 30%.Wherein bromine cyanogen insect amide and the concrete ratio of Cascade
It is shown in Table 1 and 2.
Using feedstuff to add poison method and carry out indoor potentiation bioassay, selection resistant bollworm is target pest, often processes weight
Multiple 3 times, every concentration processes 60, with probability value method calculate each medicament antagonism bollworm toxicity regression equation and lethal in dense
Degree LC50, use LC50Value press Sun Yun abundant method calculating co-toxicity coefficient, the results are shown in Table 1:
Table 1 bromine cyanogen insect amide, Cascade and the toxicity test of compounding sample antagonism bollworm thereof and co-toxicity coefficient
In table, data show, antagonism bollworm are had potentiation, in table after bromine cyanogen insect amide and Cascade mixture
Listed proportioning co-toxicity coefficient is both greater than 120, and therefore bromine cyanogen insect amide and Cascade mixture have significant synergies.
Weigh bromine cyanogen insect amide, Cascade uses conventional formulation method to be configured to principle active component weight by different proportion
Percentage composition is the bromine cyanogen insect amide Cascade cream of 30%.Concrete ratio is shown in Table 2.
Using feedstuff to add poison method and carry out indoor potentiation bioassay, selection rice-stem borer is target pest, often processes weight
Multiple 3 times, calculate toxicity regression equation and lethal concentration of 50 LC of each medicament antagonism striped rice borer by probability value method50, use LC50Value
Calculate co-toxicity coefficient by the abundant method of Sun Yun, the results are shown in Table 2:
Table 2 bromine cyanogen insect amide, Cascade and compounding sample thereof to striped rice borer toxicity test and co-toxicity coefficient
In table, data show, have potentiation, institute in table after bromine cyanogen insect amide and Cascade mixture to rice-stem borer
The proportioning co-toxicity coefficient of row is all much larger than 120, and therefore bromine cyanogen insect amide and Cascade mixture have significant synergies.
2, field control effectiveness test
Using embodiment institute sample product to carry out the field test of control in field bollworm, comparison medicament is 5% Cascade EC
(cream) and 20% bromine cyanogen insect amide WP (wettable powder), be diluted according to the extension rate in form 3, look into 3 days after medicine,
7 days, the result of 14 days, result is shown in Table 3:
Table 3 bromine cyanogen insect amide-Cascade compounds the field test results of antagonism bollworm
Example has fabulous quick-acting to antagonism bollworm as can be seen from Table 3, and the lasting period is long, in field
Performance is good, is the outstanding medicament preventing and treating antagonism bollworm.
Measure through indoor synergism test and show: by bromine cyanogen insect amide with Cascade built agent to bollworm and rice-stem borer
There is significant synergistic insecticidal action；Field control effectiveness test also indicates that all of built agent of the present invention is to bollworm insecticidal effect equally
It is all remarkably higher than the effect of corresponding single dose pesticide.
Claims (10)
1. brominated cyanogen insect amide and a compound pesticide compositions for Cascade, is characterized in that this compound pesticide compositions is with bromine cyanogen
Insect amide and Cascade are active insecticidal components, wherein, the weight ratio of bromine cyanogen insect amide and Cascade be 0.1～80:0.5～
80。
Brominated cyanogen insect amide the most according to claim 1 and the compound pesticide compositions of Cascade, is characterized in that described
The weight ratio of bromine cyanogen insect amide and Cascade is 1～60:1～60.
Brominated cyanogen insect amide the most according to claim 2 and the compound pesticide compositions of Cascade, is characterized in that described
The weight ratio of bromine cyanogen insect amide and Cascade is 1～40:1～40.
Brominated cyanogen insect amide the most according to claim 3 and the compound pesticide compositions of Cascade, is characterized in that described
The weight ratio of bromine cyanogen insect amide and Cascade is 1～30:1～30.
Brominated cyanogen insect amide the most according to claim 1 and the compound pesticide compositions of Cascade, is characterized in that bromine cyanogen worm
Amide and both Cascades weight percentage in this compound pesticide compositions are 3%～80%.
Brominated cyanogen insect amide the most according to claim 5 and the compound pesticide compositions of Cascade, is characterized in that bromine cyanogen worm
Amide and both Cascades weight percentage in this compound pesticide compositions are 5%～55%.
Brominated cyanogen insect amide the most according to claim 1 and the compound pesticide compositions of Cascade, is characterized in that this is combined
Pesticidal combination is with bromine cyanogen insect amide and Cascade as active insecticidal components and insecticides adjuvant and excipient are configured on pesticide to permit
The dosage form permitted.
Brominated cyanogen insect amide the most according to claim 7 and the compound pesticide compositions of Cascade, is characterized in that described dose
Type is cream, suspending agent, aqueous emulsion, wettable powder, microemulsion or water dispersion granule.
9. the compound pesticide compositions of brominated cyanogen insect amide described in claim 1 and Cascade prevents and treats resistance Lepidoptera in preparation
Application on the insecticidal materials of insect.
The compound pesticide compositions of brominated cyanogen insect amide the most according to claim 9 and Cascade is at preparation preventing and treating cotton boll
Application on the insecticidal materials of worm or snout moths larva.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610456706.8A CN106070278A (en) | 2016-06-21 | 2016-06-21 | A kind of compound pesticide compositions of brominated cyanogen insect amide and Cascade and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610456706.8A CN106070278A (en) | 2016-06-21 | 2016-06-21 | A kind of compound pesticide compositions of brominated cyanogen insect amide and Cascade and application thereof |
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| CN106070278A true CN106070278A (en) | 2016-11-09 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108184884A (en) * | 2018-02-28 | 2018-06-22 | 佛山市海力盈生物科技有限公司 | A kind of composition pesticide containing bromine cyanogen insect amide and flubenzuron |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102283205A (en) * | 2004-07-26 | 2011-12-21 | 杜邦公司 | Mixtures of anthranilamide invertebrate pest control agents |
| CN102626070A (en) * | 2012-03-29 | 2012-08-08 | 广西田园生化股份有限公司 | Ultra-low volume liquid containing cyantraniliprole and organophosphorus insecticides |
| JP2015214554A (en) * | 2015-06-11 | 2015-12-03 | 住友化学株式会社 | Plant disease and harmful arthropod control composition and plant disease and harmful arthropod control method |
-
2016
- 2016-06-21 CN CN201610456706.8A patent/CN106070278A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102283205A (en) * | 2004-07-26 | 2011-12-21 | 杜邦公司 | Mixtures of anthranilamide invertebrate pest control agents |
| CN102626070A (en) * | 2012-03-29 | 2012-08-08 | 广西田园生化股份有限公司 | Ultra-low volume liquid containing cyantraniliprole and organophosphorus insecticides |
| JP2015214554A (en) * | 2015-06-11 | 2015-12-03 | 住友化学株式会社 | Plant disease and harmful arthropod control composition and plant disease and harmful arthropod control method |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108184884A (en) * | 2018-02-28 | 2018-06-22 | 佛山市海力盈生物科技有限公司 | A kind of composition pesticide containing bromine cyanogen insect amide and flubenzuron |
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