CN105994287A - Composite insecticide composition containing cyantraniliprole and methoxyfenozide and application thereof - Google Patents
Composite insecticide composition containing cyantraniliprole and methoxyfenozide and application thereof Download PDFInfo
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- CN105994287A CN105994287A CN201610452935.2A CN201610452935A CN105994287A CN 105994287 A CN105994287 A CN 105994287A CN 201610452935 A CN201610452935 A CN 201610452935A CN 105994287 A CN105994287 A CN 105994287A
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- methoxyfenozide
- insect amide
- cyanogen insect
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- compound pesticide
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
- A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
- A01N37/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system having at least one carboxylic group or a thio analogue, or a derivative thereof, and one oxygen or sulfur atom attached to the same aromatic ring system
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a composite insecticide composition containing cyantraniliprole and methoxyfenozide and the application thereof. The insecticidal active constituents of the insecticide composition are cyantraniliprole and methoxyfenozide, and the weight ratio of cyantraniliprole to methoxyfenozide is (0.1-80):(0.5-80). The insecticide composition can generate a good synergistic interaction effect and overcome and delay pest resistance to insecticides, has a high insecticide speed and long lasting period, reduces pesticide cost and has a control effect obviously better than that of single application of cyantraniliprole or methoxyfenozide. The insecticide composition can control lepidoptera pests on crops, especially cotton bollworms and stem borers, and the effect is obviously better than that of single application of cyantraniliprole or methoxyfenozide.
Description
Technical field
The invention belongs to the field of agricultural pesticide containing heterocyclic compound, concrete body relates to a kind of compound pesticide compositions.
Background technology
Bromine cyanogen insect amide (cyantraniliprole), is that E.I.Du Pont Company's second filial generation ryania that success is developed after chlorantraniliprole is subject to
Body inhibitor insecticides, cyanogen insect amide is to be formed by the various polar groups on change phenyl ring, has more efficient, is suitable for
Crop is more extensive, can effectively prevent and treat Lepidoptera, Semiptera and coleopteran pest.
Methoxyfenozide, chemical name: the N-tert-butyl group-N'-(3-methoxyl group-2-methyl benzoyl)-3,5-dimethyl phenacyl
Hydrazine.Structural formula is:
Methoxyfenozide is that the normal growth of the one of insect growth regulator, IGR, mainly interference insect is grown, even if insecticide sloughs off
Skin and dead, and can suppress to ingest.This product is strong to controlling object selectivity, is mainly used in the preventing and treating of lepidoptera pest.
But the insect such as bollworm, snout moths larva is under conditions of current long-term prescription, and resistance is gradually increased, pesticide single dose is to insect
The effect of preventing and treating is gradually reduced.
Summary of the invention
It is an object of the invention to provide a kind of brominated cyanogen insect amide and the compound pesticide compositions of methoxyfenozide, this Insecticidal combinations
Thing is the multifunctional insecticide compositions of preventing and treating lepidoptera pest.
It is a further object of the present invention to provide this Pesticidal combination to prevent and treat on the insecticidal materials of resistance lepidoptera pest in preparation
Application, the particularly application on the insecticidal materials of preparation preventing and treating bollworm or snout moths larva.
It is an object of the invention to be achieved through the following technical solutions:
A kind of brominated cyanogen insect amide and the compound pesticide compositions of methoxyfenozide, this compound pesticide compositions is with bromine cyanogen insect amide
Being principle active component with methoxyfenozide, wherein, the weight ratio of bromine cyanogen insect amide and methoxyfenozide is 0.1～80:
0.5～80.
In this compound pesticide compositions, the weight ratio of bromine cyanogen insect amide (A) and methoxyfenozide (B) is preferably 1～60:
1～60, more preferably 1～40:1～40, most preferably 1～30:1～30.In some preferred technical schemes: bromine
Cyanogen insect amide and methoxyfenozide can 1:30,1:29,1:28,1:27,1:26,1:25,1:24,1:24,1:22,
1:21、1:20、1:19、1:18、1:17、1:16、1:15、1:14、1:13、1:12、1:11、1:10、1:9、1:8、1:7、
1:6、1:5、1:4、1:3、1:2、1:1、2:1、3:1、4:1、5:1、6:1、7:1、8:1、9:1、10:1、11:1、12:1、
13:1、14:1、15:1、16:1、17:1、18:1、19:1、20:1、21:1、22:1、23:1、24:1、25:1、26:1、
27:1,28:1,29:1,30:1,2:3,3:2,2:5,5:2,3:4,4:3,5:2,2:5,5:3,3:5,5:4,4:5 this
A little ratios select.
This compound pesticide compositions can comprise only active component bromine cyanogen insect amide and methoxyfenozide, it is possible to when using or prepare
Adding other components in active component, the active ingredient in this Pesticidal combination can be present in compositions with enhancing effective amount
In.
In compound pesticide compositions of the present invention, bromine cyanogen insect amide and both methoxyfenozides are in this compound pesticide compositions
Weight percentage is 3%～80%.It is preferably 5%～55%, most preferably 10%～40%.
Compound pesticide compositions of the present invention is with bromine cyanogen insect amide and methoxyfenozide as active component or principle active component, and agriculture
Medicine auxiliary agent and excipient become any one dosage form allowed on pesticide, the preferred cream of described dosage form, suspending agent, wettable
Property powder, aqueous emulsion, microemulsion or water dispersion granule.
The insecticides adjuvant of the aforementioned present invention of can be applicable to is not particularly limited, and includes, but are not limited to DBSA
Calcium, 600#, polyoxyethylene polyoxy propylene block compound are (such as agriculture breast 33#), NPE etc., aforementioned can
The excipient being applied to the present invention is also not particularly limited, and includes, but are not limited to solvent naphtha, water, antifreezing agent (such as the third two
Alcohol), deionized water etc..Above auxiliary agent, excipient and other adjuvant can be alone or and use.
Compound pesticide compositions of the present invention easily produces multiple Semiptera and the lepidoptera pest of resistance to planthopper and snout moths larva etc.
There is good preventive effect；And suppress the insect Drug resistance to unitary agent (bromine cyanogen insect amide or methoxyfenozide are arbitrary)
Produce.
Above-mentioned compound pesticide compositions prevents and treats the application on resistance lepidoptera pest insecticidal materials in preparation, especially anti-in preparation
Control the application effect on bollworm or snout moths larva insecticidal materials notable.
Compared with prior art beneficial effects of the present invention: (1), compared with single dose, said composition antagonism lepidoptera pest is such as
Bollworm, snout moths larva etc. have obvious synergistic function, overcome and delayed pest resistance to insecticide, and expanding prevention is composed, parasite killing speed
Hurry up, hence it is evident that improve prevention effect；(2) preventing and treating recruitment, drug cost are reduced；(3) alternative high-toxic pesticide；(4) hold concurrently
Have immediate effect and long-acting；(5) with bromine cyanogen insect amide compared with methoxyfenozide single dose, produce and use cost reduces；(6) press down
The resistance of pesticide is strengthened by lepidoptera pest processed, and its effect uses apparently higher than its single dose.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described, but limits the present invention never in any form.
Embodiment 1:
Weigh 80g bromine cyanogen insect amide, 2g methoxyfenozide, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether
3g, dimethylbenzene put into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, are formed and mainly have
Effect Ingredients Weight percentage composition is the bromine cyanogen insect amide methoxyfenozide cream of 82%.
Embodiment 2:
Weigh 2g bromine cyanogen insect amide, 80g methoxyfenozide, lignin 10g, Negel 2g, add with Kaolin
To 100g, above raw material is mixed in super micron mill, form the bromine that principle active component weight percentage is 82%
Cyanogen insect amide methoxyfenozide wettable powder.
Embodiment 3:
Weigh 60g bromine cyanogen insect amide, 2g methoxyfenozide, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether
6g, dimethylbenzene add to 100g, and the method that above raw material is prepared cream routinely puts into mixing in mixing kettle, is formed main
Effective ingredient weight percentage is the bromine cyanogen insect amide methoxyfenozide cream of 62%.
Embodiment 4:
Weigh 2g bromine cyanogen insect amide, 60g methoxyfenozide, nonyl phenol phosphate 5g, alkylphenol polyoxyethylene 4g, just
The dimethylbenzene of butanol 3g, 10g and the ketopyrrolidine of 10g, the xanthan gum of 0.1g, remaining supplies 100g, n-butyl alcohol with water
Forming aqueous phase with water dissolution, remaining component mix and blend forms oil phase, slowly aqueous phase is added in oil phase under cutter effect
Go, and continue to shear 10～30 minutes, form the bromine cyanogen insect amide first that principle active component weight percentage is 62%
Oxygen tebufenozide aqueous emulsion.
Embodiment 5:
Weigh 40g bromine cyanogen insect amide, 2g methoxyfenozide, calcium dodecyl benzene sulfonate 5g, alkylphenol polyoxyethylene 4g,
The solvent xylene of 30g and the ketopyrrolidine of 15g, remaining complements to 100g, former medicine, solvent, emulsifying agent, hydrotropy with water
Agent mix and blend forms homogeneous phase transparent solution, is then slowly added into water and stirs formation clear solution, being principle active component
Weight percentage is the bromine cyanogen insect amide methoxyfenozide microemulsion of 42%.
Embodiment 6:
Weigh 2g bromine cyanogen insect amide, 40g methoxyfenozide, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether
3g, dimethylbenzene are to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, is formed and mainly has
Effect Ingredients Weight percentage composition is the bromine cyanogen insect amide methoxyfenozide cream of 42%.
Embodiment 7:
Weigh 20g bromine cyanogen insect amide, 2g methoxyfenozide, sodium lignin sulfonate 3g, polyoxyethylene poly-oxygen propylene aether and
Sulfate 4g, xanthan gum 0.2g, ethylene glycol 10g, silica ethane 0.1g, aluminium-magnesium silicate 0.5g, supply 100g with water,
Under the effect of sand mill, form the bromine cyanogen insect amide methoxyfenozide that principle active component weight percentage is 22% hang
Floating agent.
Embodiment 8:
Weigh 2g bromine cyanogen insect amide, 20g methoxyfenozide, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether
15g, dimethylbenzene put into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, are formed and mainly have
Effect Ingredients Weight percentage composition is the bromine cyanogen insect amide methoxyfenozide cream of 22%.
Embodiment 9:
Weigh 10g bromine cyanogen insect amide, 2g methoxyfenozide, sodium lignin sulfonate 8g, sodium lauryl sulphate 2g, sulphuric acid
Ammonium 5g, polyvinyl alcohol 5g, Borax 2g, Kaolin 28g, formed above raw material mainly by the method for water dispersion granule
Effective ingredient weight percentage is the bromine cyanogen insect amide methoxyfenozide water dispersible granules of 12%.
Embodiment 10:
Weigh 15g bromine cyanogen insect amide, 5g methoxyfenozide, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether
15g, dimethylbenzene put into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, are formed and mainly have
Effect Ingredients Weight percentage composition is the bromine cyanogen insect amide methoxyfenozide cream of 15%.
Embodiment 11:
Weigh 10g bromine cyanogen insect amide, 10g methoxyfenozide, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether
3g, dimethylbenzene put into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, are formed and mainly have
Effect Ingredients Weight percentage composition is the bromine cyanogen insect amide methoxyfenozide cream of 20%.
Drug effect checking test
1, indoor virulence determination of activity
Weigh bromine cyanogen insect amide and methoxyfenozide 30g, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether altogether
4g, vegetable oil are to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, is configured to main
Effective ingredient weight percentage is the bromine cyanogen insect amide methoxyfenozide cream of 30%.Wherein bromine cyanogen insect amide and methoxy worm
The concrete ratio of hydrazides is shown in Table 1 and 2.
Using feedstuff to add poison method and carry out indoor potentiation bioassay, selection resistant bollworm is target pest, often processes repetition 3
Secondary, every concentration process 60, with probability value method calculate each medicament antagonism bollworm toxicity regression equation and lethal in dense
Degree LC50, use LC50Value press Sun Yun abundant method calculating co-toxicity coefficient, the results are shown in Table 1:
Table 1 bromine cyanogen insect amide, methoxyfenozide and the toxicity test of compounding sample antagonism bollworm thereof and co-toxicity coefficient
In table, data show, antagonism bollworm are had potentiation, in table after bromine cyanogen insect amide and methoxyfenozide mixture
Listed proportioning co-toxicity coefficient is both greater than 120, and therefore bromine cyanogen insect amide and methoxyfenozide mixture have significant synergies.
Weigh bromine cyanogen insect amide, methoxyfenozide uses conventional formulation method to be configured to principle active component weight by different proportion
Percentage composition is the bromine cyanogen insect amide methoxyfenozide cream of 30%.Concrete ratio is shown in Table 2.
Using feedstuff to add poison method and carry out indoor potentiation bioassay, selection rice-stem borer is target pest, often processes repetition
3 times, calculate toxicity regression equation and lethal concentration of 50 LC of each medicament antagonism striped rice borer by probability value method50, use LC50
Value press Sun Yun abundant method calculating co-toxicity coefficient, the results are shown in Table 2:
Table 2 bromine cyanogen insect amide, methoxyfenozide and compounding sample thereof to striped rice borer toxicity test and co-toxicity coefficient
In table, data show, have potentiation, institute in table after bromine cyanogen insect amide and methoxyfenozide mixture to rice-stem borer
The proportioning co-toxicity coefficient of row is all much larger than 120, and therefore bromine cyanogen insect amide and methoxyfenozide mixture have significant synergies.
2, field control effectiveness test
Using embodiment institute sample product to carry out the field test of control in field bollworm, comparison medicament is 24% methoxyfenozide
SC (suspending agent) and 20% bromine cyanogen insect amide WP (wettable powder), be diluted according to the extension rate in form 3,
3 days are looked into after medicine, 7 days, the result of 14 days, result is shown in Table 3:
Table 3 bromine cyanogen insect amide-methoxyfenozide compounds the field test results of antagonism bollworm
Example has fabulous quick-acting to antagonism bollworm as can be seen from Table 3, and the lasting period is long, in field
Performance is good, is the outstanding medicament preventing and treating antagonism bollworm.
Measure through indoor synergism test and show: by bromine cyanogen insect amide with methoxyfenozide built agent to bollworm and rice-stem borer
There is significant synergistic insecticidal action；Field control effectiveness test also indicates that all of built agent of the present invention is to bollworm insecticidal effect equally
It is all remarkably higher than the effect of corresponding single dose pesticide.
Claims (10)
1. brominated cyanogen insect amide and a compound pesticide compositions for methoxyfenozide, is characterized in that this compound pesticide compositions
With bromine cyanogen insect amide and methoxyfenozide as active insecticidal components, wherein, the weight ratio of bromine cyanogen insect amide and methoxyfenozide is
0.1～80:0.5～80.
Brominated cyanogen insect amide the most according to claim 1 and the compound pesticide compositions of methoxyfenozide, is characterized in that
Described bromine cyanogen insect amide and the weight ratio of methoxyfenozide are 1～60:1～60.
Brominated cyanogen insect amide the most according to claim 2 and the compound pesticide compositions of methoxyfenozide, is characterized in that
Described bromine cyanogen insect amide and the weight ratio of methoxyfenozide are 1～40:1～40.
Brominated cyanogen insect amide the most according to claim 3 and the compound pesticide compositions of methoxyfenozide, is characterized in that
Described bromine cyanogen insect amide and the weight ratio of methoxyfenozide are 1～30:1～30.
Brominated cyanogen insect amide the most according to claim 1 and the compound pesticide compositions of methoxyfenozide, is characterized in that
Bromine cyanogen insect amide and both methoxyfenozides weight percentage in this compound pesticide compositions are 3%～80%.
The compound pesticide compositions of brominated cyanogen insect amide sum the most according to claim 5, is characterized in that bromine cyanogen insect amide
It is 5%～55% with both methoxyfenozides weight percentage in this compound pesticide compositions.
Brominated cyanogen insect amide the most according to claim 1 and the compound pesticide compositions of methoxyfenozide, is characterized in that
This compound pesticide compositions is with bromine cyanogen insect amide and methoxyfenozide as active insecticidal components with insecticides adjuvant and excipient preparation
Become the dosage form allowed on pesticide.
Brominated cyanogen insect amide the most according to claim 7 and the compound pesticide compositions of methoxyfenozide, is characterized in that
Described dosage form is cream, suspending agent, aqueous emulsion, wettable powder, microemulsion or water dispersion granule.
9. the compound pesticide compositions of brominated cyanogen insect amide described in claim 1 and methoxyfenozide prevents and treats resistance in preparation
Application on the insecticidal materials of lepidoptera pest.
The compound pesticide compositions of brominated cyanogen insect amide the most according to claim 9 and methoxyfenozide is in preparation preventing and treating
Application on the insecticidal materials of bollworm or snout moths larva.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610452935.2A CN105994287A (en) | 2016-06-21 | 2016-06-21 | Composite insecticide composition containing cyantraniliprole and methoxyfenozide and application thereof |
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| CN201610452935.2A CN105994287A (en) | 2016-06-21 | 2016-06-21 | Composite insecticide composition containing cyantraniliprole and methoxyfenozide and application thereof |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20130085066A1 (en) * | 2010-05-31 | 2013-04-04 | Basf Se | Method for Increasing the Health of a Plant |
| CN103636610A (en) * | 2013-10-30 | 2014-03-19 | 广东中迅农科股份有限公司 | Methoxyfenozide-cyantraniliprole-containing insecticidal composition |
-
2016
- 2016-06-21 CN CN201610452935.2A patent/CN105994287A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20130085066A1 (en) * | 2010-05-31 | 2013-04-04 | Basf Se | Method for Increasing the Health of a Plant |
| CN103636610A (en) * | 2013-10-30 | 2014-03-19 | 广东中迅农科股份有限公司 | Methoxyfenozide-cyantraniliprole-containing insecticidal composition |
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