CN106070228A - A kind of brominated cyanogen insect amide and the Synergistic insecticidal compositions of Nitenpyram and application thereof - Google Patents

A kind of brominated cyanogen insect amide and the Synergistic insecticidal compositions of Nitenpyram and application thereof Download PDF

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Publication number
CN106070228A
CN106070228A CN201610454760.9A CN201610454760A CN106070228A CN 106070228 A CN106070228 A CN 106070228A CN 201610454760 A CN201610454760 A CN 201610454760A CN 106070228 A CN106070228 A CN 106070228A
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China
Prior art keywords
nitenpyram
insect amide
cyanogen insect
insecticidal compositions
synergistic insecticidal
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CN201610454760.9A
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Chinese (zh)
Inventor
邢刚
陈叶青
石振龙
万维肖
高瑞花
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Nanjing Huazhou Pharmaceutical Co Ltd
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Nanjing Huazhou Pharmaceutical Co Ltd
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Priority to CN201610454760.9A priority Critical patent/CN106070228A/en
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/561,2-Diazoles; Hydrogenated 1,2-diazoles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings

Abstract

The invention discloses Synergistic insecticidal compositions of a kind of brominated cyanogen insect amide and Nitenpyram and application thereof, this Pesticidal combination with bromine cyanogen insect amide with Nitenpyram as principle active component, wherein, the weight ratio of bromine cyanogen insect amide and Nitenpyram is 1~60:1~60.This Pesticidal combination has expanding prevention spectrum and the effect of potentiation, and drug cost can be reduced, cream, wettable powder, microemulsion, aqueous emulsion, suspending agent, water dispersible granules can be configured to, be used for preventing and treating the various pests such as Lepidoptera, Semiptera, Hymenoptera, coleoptera.

Description

A kind of brominated cyanogen insect amide and the Synergistic insecticidal compositions of Nitenpyram and application thereof
Technical field
The invention belongs to pesticide field, be specifically related to a kind of with bromine cyanogen insect amide and Nitenpyram as principle active component Pesticidal combination and application thereof.
Background technology
Bromine cyanogen insect amide (cyantraniliprole), is E.I.Du Pont Company's second filial generation that success is developed after chlorantraniliprole Ryanodine receptor inhibitor insecticides, cyanogen insect amide is to be formed by the various polar groups on change phenyl ring, has higher Effect, applicable crops is more extensive, can effectively prevent and treat Lepidoptera, Semiptera and coleopteran pest.
Nitenpyram (nitenpyram), is a kind of novel nicotinamide insecticide, chemical name: (E)-N-(6-chloro-3-pyrrole Pyridine methyl)-N '-methyl-2-nitro ethenylidene diamidogen, molecular formula: C11H15ClN4O2, structural formula:
The Nitenpyram mechanism of action is unique, mainly acts on insecticide neural, and the axle synaptic receptor of insecticide is had blocking-up work With, there is high-efficiency low-toxicity, interior suction, no interactions resistance feature, the insect that conventional pesticides has produced resistance has preferably preventing and treating Effect, is one of nicotinoids Agrochemicals last word so far.To sucking pest planthopper, trialeurodes vaporariorum, aphid, thrips, leaf The insects such as Cicadae have specially good effect.
Insecticide variety containing single component often existing defects in pesticide Pest control: use continuously easily produce anti- The property of medicine, insecticidal spectrum is narrow, it is impossible to providing comprehensively protection for crop, peasant's drug cost is high.
Summary of the invention
It is an object of the invention to provide a kind of brominated cyanogen insect amide and the Synergistic insecticidal compositions of Nitenpyram, said composition Can be used for preventing and treating various agricultural insect, such as preventing and treating vegetable diamondback moth, Pieris rapae, it is also possible to be used for preventing and treating cotton boll worm, Beet armyworm and Brown Planthopper etc., can reach a drug and prevent and treat the effect of dissimilar insect.
The Synergistic insecticidal compositions that it is a further object of the present invention to provide brominated cyanogen insect amide and Nitenpyram is anti-in preparation Control the application in the insecticidal materials of one or more insects in resistance Lepidoptera, Semiptera, Hymenoptera or coleoptera.
The present invention adopts the following technical scheme that
A kind of brominated cyanogen insect amide and the Synergistic insecticidal compositions of Nitenpyram, it with bromine cyanogen insect amide and Nitenpyram is Principle active component, wherein, the weight ratio of bromine cyanogen insect amide and Nitenpyram is 1~60:1~60.Preferably bromine cyanogen insect amide and The weight ratio of Nitenpyram is 1~40:1~40, and the weight ratio of further preferred bromine cyanogen insect amide and Nitenpyram is 1~30:1 ~30.
In some preferred technical schemes: bromine cyanogen insect amide and Nitenpyram can 1:30,1:29,1:28,1:27, 1:26、1:25、1:24、1:24、1:22、1:21、1:20、1:19、1:18、1:17、1:16、1:15、1:14、1:13、1:12、1: 11、1:10、1:9、1:8、1:7、1:6、1:5、1:4、1:3、1:2、1:1、2:1、3:1、4:1、5:1、6:1、7:1、8:1、9:1、 10:1、11:1、12:1、13:1、14:1、15:1、16:1、17:1、18:1、19:1、20:1、21:1、22:1、23:1、24:1、 25:1、26:1、27:1、28:1、29:1、30:1、2:3、3:2、2:5、5:2、3:4、4:3、5:2、2:5、5:3、3:5、5:4、4:5 These ratios select.
At brominated cyanogen insect amide and the Synergistic insecticidal compositions of Nitenpyram of the present invention, bromine cyanogen insect amide and Nitenpyram The two weight percentage in this Synergistic insecticidal compositions is 2%~80%, and preferably 8%~60%, optimum is 20% ~40%.
The Synergistic insecticidal compositions of above-mentioned brominated cyanogen insect amide and Nitenpyram is based on bromine cyanogen insect amide and Nitenpyram Effective ingredient (active component) and insecticides adjuvant, excipient is wanted to be configured on pesticide any one dosage form allowed.Dosage form is preferred Powder, wettable powder, suspending agent, cream and water dispersion granule.
Described auxiliary agent can use calcium dodecyl benzene sulfonate, alkylphenol polyoxyethylene, polyoxyethylene polyoxy propylene embedding Section compound is (such as agriculture breast 33#), NPE etc., excipient comprises Ketohexamethylene, dimethylbenzene, solvent naphtha, water, antifreeze Agent (such as propylene glycol), deionized water etc..Above auxiliary agent, excipient and other agriculturally known adjuvant can be alone or and use.
Above-mentioned brominated cyanogen insect amide and the Synergistic insecticidal compositions of Nitenpyram preparation preventing and treating Lepidoptera, Semiptera, Application in the insecticidal materials of one or more insects in Hymenoptera or coleoptera.Especially preparation preventing and treating planthopper or snout moths larva Insecticidal materials in application effect notable.
The Synergistic insecticidal compositions antagonism lepidoptera pest of the present invention has significant preventive effect, particularly with cotton boll Worm, beet armyworm, diamondback moth etc. easily produce the various pests of resistance and have good preventive effect;And suppress insect to single The Drug resistance of preparation (bromine cyanogen insect amide or Nitenpyram) produces and can prevent and treat Hemipteran pest such as Brown Planthopper etc. simultaneously.
The insecticidal materials prepared by the Synergistic insecticidal compositions of described brominated cyanogen insect amide and Nitenpyram is anti-in preventing and treating While property Lepidoptera, Hymenoptera or coleopteran pest, Hemipteran pest can be prevented and treated again, especially to cotton boll worm, diamondback moth There is good preventive effect with beet armyworm, reach the effect that a medicine is controlled more.
The Pesticidal combination of the present invention compared with prior art, produces following beneficial effect: (1) compared with single dose, this group Compound insect has notable synergistic, hence it is evident that improve prevention effect;(2) one medicines are controlled more, and a dispenser can prevent and treat various pests simultaneously, Reduce preventing and treating recruitment cost;(3) alternative high-toxic pesticide, and field dosage is greatly reduced, effectively reduce environmental pollution and Pesticide residues;(4) have concurrently quick-acting and long-acting;(5) compared with bromine cyanogen insect amide single dose, produce and use cost reduces;(6) suppression The resistance of pesticide is strengthened by insect.
Detailed description of the invention
Embodiments of the invention are the methods using indoor bioassay and field test to combine.First pass through indoor biological Measure, the co-toxicity coefficient after clear and definite two kinds of medicaments are compounding by a certain percentage;On this basis, then carry out field test.
Embodiment 1:
Weigh 80g bromine cyanogen insect amide, 2g Nitenpyram, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, Dimethylbenzene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, forms principle active component Weight percentage is the bromine cyanogen insect amide Nitenpyram cream of 82%.
Embodiment 2:
Weigh 2g bromine cyanogen insect amide, 80g Nitenpyram, lignin 10g, Negel 2g, add to Kaolin 100g, mixes above raw material in super micron mill, forms the bromine cyanogen worm that principle active component weight percentage is 82% Amide Nitenpyram wettable powder.
Embodiment 3:
Weigh 60g bromine cyanogen insect amide, 2g Nitenpyram, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 6g, Dimethylbenzene adds to 100g, and the method that above raw material is prepared cream routinely puts into mixing in mixing kettle, is formed and the most effectively becomes The bromine cyanogen insect amide Nitenpyram cream dividing weight percentage to be 62%.
Embodiment 4:
Weigh 2g bromine cyanogen insect amide, 60g Nitenpyram, nonyl phenol phosphate 5g, alkylphenol polyoxyethylene 4g, n-butyl alcohol The dimethylbenzene of 3g, 10g and the ketopyrrolidine of 10g, the xanthan gum of 0.1g, remaining supplies 100g, n-butyl alcohol and water dissolution shape with water Becoming aqueous phase, remaining component mix and blend forms oil phase, slowly aqueous phase is added in oil phase, and continue to cut under cutter effect Cut 10~30 minutes, form the bromine cyanogen insect amide Nitenpyram aqueous emulsion that principle active component weight percentage is 62%.
Embodiment 5:
Weigh 40g bromine cyanogen insect amide, 2g Nitenpyram, calcium dodecyl benzene sulfonate 5g, alkylphenol polyoxyethylene 4g, The solvent xylene of 30g and the ketopyrrolidine of 15g, remaining complements to 100g, the mixing of former medicine, solvent, emulsifying agent, cosolvent with water Stirring forms homogeneous phase transparent solution, is then slowly added into water and stirs formation clear solution, being principle active component weight hundred The bromine cyanogen insect amide Nitenpyram microemulsion dividing content to be 42%.
Embodiment 6:
Weigh 2g bromine cyanogen insect amide, 40g Nitenpyram, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 3g, Dimethylbenzene is to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, forms principle active component Weight percentage is the bromine cyanogen insect amide Nitenpyram cream of 42%.
Embodiment 7:
Weigh 20g bromine cyanogen insect amide, 2g Nitenpyram, sodium lignin sulfonate 3g, polyoxyethylene poly-oxygen propylene aether and sulfur thereof Hydrochlorate 4g, xanthan gum 0.2g, ethylene glycol 10g, silica ethane 0.1g, aluminium-magnesium silicate 0.5g, supply 100g with water, at sand mill Effect is lower forms the bromine cyanogen insect amide Nitenpyram suspending agent that principle active component weight percentage is 22%.
Embodiment 8:
Weigh 2g bromine cyanogen insect amide, 20g Nitenpyram, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether 15g, dimethylbenzene put into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, are formed main effective Ingredients Weight percentage composition is the bromine cyanogen insect amide Nitenpyram cream of 22%.
Embodiment 9:
Weigh 2g bromine cyanogen insect amide, 10g Nitenpyram, sodium lignin sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, Borax 2g, Kaolin 28g, the method that above raw material is pressed water dispersion granule forms principle active component Weight percentage is the bromine cyanogen insect amide Nitenpyram water dispersible granules of 12%.
Embodiment 10:
Weigh 5g bromine cyanogen insect amide, 10g Nitenpyram, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether 15g, dimethylbenzene put into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, are formed main effective Ingredients Weight percentage composition is the bromine cyanogen insect amide Nitenpyram cream of 15%.
Embodiment 11:
Weigh 10g bromine cyanogen insect amide, 10g Nitenpyram, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, dimethylbenzene put into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, are formed and the most effectively become The bromine cyanogen insect amide Nitenpyram cream dividing weight percentage to be 20%.
Drug effect checking test
1, indoor virulence determination of activity
Weigh bromine cyanogen insect amide, Nitenpyram uses conventional formulation method to be configured to principle active component weight by different proportion Amount percentage composition is the bromine cyanogen insect amide Nitenpyram cream of 30%.Concrete ratio is shown in Table 1.
Use feedstuff to add poison method and measure bromine cyanogen insect amide and Nitenpyram and the compounding sample virulence to cotton boll worm thereof, Often processing and be repeated 3 times, every concentration processes 30, uses LC50It is worth and presses Sun Yun abundant method calculating co-toxicity coefficient:
Table 1 bromine cyanogen insect amide, Nitenpyram and compounding sample thereof are to the toxicity test of cotton boll worm and co-toxicity coefficient
In table, data show, cotton boll worm are had potentiation, in table after bromine cyanogen insect amide and Nitenpyram mixture Listed proportioning co-toxicity coefficient is both greater than 120, and therefore bromine cyanogen insect amide and Nitenpyram mixture have significant synergies.
Weigh bromine cyanogen insect amide, Nitenpyram uses conventional formulation method to be configured to principle active component weight by different proportion Amount percentage composition is the bromine cyanogen insect amide Nitenpyram cream of 30%.Concrete ratio is shown in Table 2.
Rice-stem dipping method is used to measure bromine cyanogen insect amide and Nitenpyram and the compounding sample virulence to Brown Planthopper thereof, Often process and be repeated 3 times, use LC50It is worth and presses Sun Yun abundant method calculating co-toxicity coefficient:
Table 2 bromine cyanogen insect amide, Nitenpyram and compounding sample thereof are to the toxicity test of Brown Planthopper and co-toxicity coefficient
In table, data show, Brown Planthopper are had potentiation, in table after bromine cyanogen insect amide and Nitenpyram mixture Listed proportioning co-toxicity coefficient is all much larger than 120, and therefore bromine cyanogen insect amide and Nitenpyram mixture have significant synergies.
2, field control effectiveness test
Using embodiment institute sample product to carry out the field test of control in field cotton boll worm, comparison medicament is 5% bromine cyanogen Insect amide EC and 10% Nitenpyram WDG, concrete consumption is shown in Table 3, and every mu of water consumption is 30kg, looks into 3 days, 7 days, within 14 days, tie after medicine Really, result of the test is shown in Table 3:
Table 3 sample field test results to cotton boll worm
Example has fabulous quick-acting to cotton boll worm as can be seen from Table 3, and the lasting period is long, at field table Now good, it is the outstanding medicament of preventing and treating cotton boll worm.
Measure through indoor synergism test and show: by bromine cyanogen insect amide with Nitenpyram built agent to cotton boll worm and Oryza sativa L. Brown paddy plant hopper has significant synergistic insecticidal action;Field control effectiveness test also indicates that all of built agent of the present invention is to cotton boll equally Worm insecticidal effect is all remarkably higher than the effect of corresponding single dose pesticide.

Claims (9)

1. brominated cyanogen insect amide and a Synergistic insecticidal compositions for Nitenpyram, is characterized in that this Synergistic insecticidal compositions is with bromine Cyanogen insect amide and Nitenpyram are principle active component, wherein, the weight ratio of bromine cyanogen insect amide and Nitenpyram be 1~60:1~ 60。
Brominated cyanogen insect amide the most according to claim 1 and the Synergistic insecticidal compositions of Nitenpyram, is characterized in that this kills The active ingredient bromine cyanogen insect amide of worm compositions and the weight ratio of Nitenpyram are 1~40:1~40.
Brominated cyanogen insect amide the most according to claim 2 and the Synergistic insecticidal compositions of Nitenpyram, is characterized in that this kills The active ingredient bromine cyanogen insect amide of worm compositions and the weight ratio of Nitenpyram are 1~30:1~30.
Brominated cyanogen insect amide the most according to claim 1 and the Synergistic insecticidal compositions of Nitenpyram, is characterized in that bromine cyanogen Insect amide and both Nitenpyrams weight percentage in this Synergistic insecticidal compositions are 2%~80%.
Brominated cyanogen insect amide the most according to claim 4 and the Synergistic insecticidal compositions of Nitenpyram, is characterized in that bromine cyanogen Insect amide and both Nitenpyrams weight percentage in this Synergistic insecticidal compositions are 8%~60%.
Brominated cyanogen insect amide the most according to claim 1 and the Synergistic insecticidal compositions of Nitenpyram, is characterized in that this increasing Effect Pesticidal combination is configured on pesticide with insecticides adjuvant, excipient with bromine cyanogen insect amide and Nitenpyram as principle active component Any one dosage form allowed.
Brominated cyanogen insect amide the most according to claim 6 and the Synergistic insecticidal compositions of Nitenpyram, is characterized in that described Dosage form is cream, wettable powder, microemulsion, aqueous emulsion, suspending agent or water dispersion granule.
8. the Synergistic insecticidal compositions of brominated cyanogen insect amide described in claim 1 and Nitenpyram preparation preventing and treating Lepidoptera, Application in the insecticidal materials of one or more insects in Semiptera, Hymenoptera or coleoptera.
Application the most according to claim 8, is characterized in that the Synergistic insecticidal compositions of brominated cyanogen insect amide and Nitenpyram Application in the insecticidal materials of preparation preventing and treating cotton boll worm, beet armyworm and Brown Planthopper.
CN201610454760.9A 2016-06-21 2016-06-21 A kind of brominated cyanogen insect amide and the Synergistic insecticidal compositions of Nitenpyram and application thereof Pending CN106070228A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113907084A (en) * 2021-11-30 2022-01-11 江苏钟山新材料有限公司 Dithiopyrantel-nitenpyram oil suspending agent and preparation method and application thereof

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CN102657177A (en) * 2012-04-18 2012-09-12 联保作物科技有限公司 Insecticidal composition and preparation and application thereof
CN103283764A (en) * 2012-02-24 2013-09-11 陕西韦尔奇作物保护有限公司 Cyantraniliprole containing insecticidal composition

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Publication number Priority date Publication date Assignee Title
CN102283205A (en) * 2004-07-26 2011-12-21 杜邦公司 Mixtures of anthranilamide invertebrate pest control agents
CN103283764A (en) * 2012-02-24 2013-09-11 陕西韦尔奇作物保护有限公司 Cyantraniliprole containing insecticidal composition
CN102626071A (en) * 2012-03-29 2012-08-08 广西田园生化股份有限公司 Ultra-low volume liquid containing cyantraniliprole and neonicotinoid insecticides
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113907084A (en) * 2021-11-30 2022-01-11 江苏钟山新材料有限公司 Dithiopyrantel-nitenpyram oil suspending agent and preparation method and application thereof

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Application publication date: 20161109