CN106070247A - A kind of brominated cyanogen insect amide and the Synergistic insecticidal compositions of Buprofezin and application thereof - Google Patents

A kind of brominated cyanogen insect amide and the Synergistic insecticidal compositions of Buprofezin and application thereof Download PDF

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Publication number
CN106070247A
CN106070247A CN201610454846.1A CN201610454846A CN106070247A CN 106070247 A CN106070247 A CN 106070247A CN 201610454846 A CN201610454846 A CN 201610454846A CN 106070247 A CN106070247 A CN 106070247A
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buprofezin
insect amide
cyanogen insect
insecticidal compositions
synergistic insecticidal
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CN201610454846.1A
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Inventor
郭崇友
万维肖
陈叶青
高瑞花
程清云
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Nanjing Huazhou Pharmaceutical Co Ltd
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Nanjing Huazhou Pharmaceutical Co Ltd
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/88Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with three ring hetero atoms
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/561,2-Diazoles; Hydrogenated 1,2-diazoles

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses Synergistic insecticidal compositions of a kind of brominated cyanogen insect amide and Buprofezin and application thereof, this Pesticidal combination with bromine cyanogen insect amide with Buprofezin as principle active component, wherein, the weight ratio of bromine cyanogen insect amide and Buprofezin is 1~60:1~60.This Pesticidal combination has expanding prevention spectrum and the effect of potentiation, and drug cost can be reduced, cream, wettable powder, microemulsion, aqueous emulsion, suspending agent, water dispersible granules can be configured to, be used for preventing and treating the various pests such as Lepidoptera, Semiptera, Hymenoptera, coleoptera.

Description

A kind of brominated cyanogen insect amide and the Synergistic insecticidal compositions of Buprofezin and application thereof
Technical field
The invention belongs to pesticide field, be specifically related to a kind of with bromine cyanogen insect amide and Buprofezin killing as principle active component Worm compositions and application thereof.
Background technology
Bromine cyanogen insect amide (cyantraniliprole), is E.I.Du Pont Company's second filial generation that success is developed after chlorantraniliprole Ryanodine receptor inhibitor insecticides, cyanogen insect amide is to be formed by the various polar groups on change phenyl ring, has higher Effect, applicable crops is more extensive, can effectively prevent and treat Lepidoptera, Semiptera and coleopteran pest.
Buprofezin (Buprofezin), chemical name: 2-tertiary butyl imino group-3-isopropyl-5-phenyl-1,3,5-thiophenes two Piperazine-4-ketone;Molecular formula: C16H23N3OS, chemical structural formula:
Buprofezin is diazthines insect growth regulator, IGR, belongs to insect molting inhibitor.By suppression chitin synthesis and Interference metabolism, makes insect normally not cast off a skin and abnormal and gradually dead.There is high activity, high selectivity, the long longevity of residure Feature.Plant hopper, leafhopper, aleyrodid there are is specially good effect, some scale insects such as arrowhead scales, long white a red-spotted lizard is also had better effects, mainly uses In preventing and treating rice-leaf hopper and plant hopper, potato leaf hopper, Citrus, Cotton Gossypii and vegetable aleyrodid, Citrus armored scale and mealybug.
Insecticide variety containing single component often existing defects in pesticide Pest control: use continuously easily produce anti- The property of medicine, insecticidal spectrum is narrow, it is impossible to providing comprehensively protection for crop, peasant's drug cost is high.
Summary of the invention
It is an object of the invention to provide a kind of brominated cyanogen insect amide and the Synergistic insecticidal compositions of Buprofezin, said composition can For preventing and treating various agricultural insect, such as preventing and treating vegetable diamondback moth, Pieris rapae, it is also possible to be used for preventing and treating cotton boll worm, sweet Dish noctuid and Brown Planthopper etc., can reach a drug and prevent and treat the effect of dissimilar insect.
It is a further object of the present invention to provide the Synergistic insecticidal compositions of brominated cyanogen insect amide and Buprofezin in preparation preventing and treating Application in the insecticidal materials of one or more insects in resistance Lepidoptera, Semiptera, Hymenoptera or coleoptera.
The present invention adopts the following technical scheme that
A kind of brominated cyanogen insect amide and the Synergistic insecticidal compositions of Buprofezin, it is main with bromine cyanogen insect amide and Buprofezin Effective ingredient, wherein, the weight ratio of bromine cyanogen insect amide and Buprofezin is 1~60:1~60.Preferably bromine cyanogen insect amide and Buprofezin Weight ratio be 1~40:1~40, the weight ratio of further preferred bromine cyanogen insect amide and Buprofezin is 1~30:1~30.One In a little preferably technical schemes: bromine cyanogen insect amide and Buprofezin can 1:30,1:29,1:28,1:27,1:26,1:25,1: 24、1:24、1:22、1:21、1:20、1:19、1:18、1:17、1:16、1:15、1:14、1:13、1:12、1:11、1:10、1:9、 1:8、1:7、1:6、1:5、1:4、1:3、1:2、1:1、2:1、3:1、4:1、5:1、6:1、7:1、8:1、9:1、10:1、11:1、12: 1、13:1、14:1、15:1、16:1、17:1、18:1、19:1、20:1、21:1、22:1、23:1、24:1、25:1、26:1、27:1、 These ratios of 28:1,29:1,30:1,2:3,3:2,2:5,5:2,3:4,4:3,5:2,2:5,5:3,3:5,5:4,4:5 select.
At brominated cyanogen insect amide and the Synergistic insecticidal compositions of Buprofezin of the present invention, bromine cyanogen insect amide and both Buprofezins Weight percentage in this Synergistic insecticidal compositions is 2%~80%, preferably 8%~60%, optimum be 20%~ 40%.
The Synergistic insecticidal compositions of above-mentioned brominated cyanogen insect amide and Buprofezin with bromine cyanogen insect amide with Buprofezin for mainly having Effect composition (active component) and insecticides adjuvant, excipient are configured on pesticide any one dosage form allowed.The preferred powder of dosage form, Wettable powder, suspending agent, cream and water dispersion granule.
Described auxiliary agent can use calcium dodecyl benzene sulfonate, alkylphenol polyoxyethylene, polyoxyethylene polyoxy propylene embedding Section compound is (such as agriculture breast 33#), NPE etc., excipient comprises Ketohexamethylene, dimethylbenzene, solvent naphtha, water, antifreeze Agent (such as propylene glycol), deionized water etc..Above auxiliary agent, excipient and other agriculturally known adjuvant can be alone or and use.
Above-mentioned brominated cyanogen insect amide and the Synergistic insecticidal compositions of Buprofezin are at preparation preventing and treating Lepidoptera, Semiptera, film Application in the insecticidal materials of one or more insects in wing mesh or coleoptera.Especially preparation preventing and treating planthopper or snout moths larva Application effect in insecticidal materials is notable.
The Synergistic insecticidal compositions antagonism lepidoptera pest of the present invention has significant preventive effect, particularly with cotton boll Worm, beet armyworm, diamondback moth etc. easily produce the various pests of resistance and have good preventive effect;And suppress insect to single The Drug resistance of preparation (bromine cyanogen insect amide or Buprofezin) produces and can prevent and treat Hemipteran pest such as Brown Planthopper etc. simultaneously.
The insecticidal materials prepared by the Synergistic insecticidal compositions of described brominated cyanogen insect amide and Buprofezin is preventing and treating resistance While Lepidoptera, Hymenoptera or coleopteran pest, Hemipteran pest can be prevented and treated again, especially to cotton boll worm, diamondback moth and Beet armyworm has good preventive effect, reaches the effect that a medicine is controlled more.
The Pesticidal combination of the present invention compared with prior art, produces following beneficial effect: (1) compared with single dose, this group Compound insect has notable synergistic, hence it is evident that improve prevention effect;(2) one medicines are controlled more, and a dispenser can prevent and treat various pests simultaneously, Reduce preventing and treating recruitment cost;(3) alternative high-toxic pesticide, and field dosage is greatly reduced, effectively reduce environmental pollution and Pesticide residues;(4) have concurrently quick-acting and long-acting;(5) compared with bromine cyanogen insect amide single dose, produce and use cost reduces;(6) suppression The resistance of pesticide is strengthened by insect.
Detailed description of the invention
Embodiments of the invention are the methods using indoor bioassay and field test to combine.First pass through indoor biological Measure, the co-toxicity coefficient after clear and definite two kinds of medicaments are compounding by a certain percentage;On this basis, then carry out field test.
Embodiment 1:
Weigh 80g bromine cyanogen insect amide, 2g Buprofezin, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, two Toluene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, forms principle active component weight Amount percentage composition is the bromine cyanogen insect amide Buprofezin cream of 82%.
Embodiment 2:
Weigh 2g bromine cyanogen insect amide, 80g Buprofezin, lignin 10g, Negel 2g, add to 100g with Kaolin, Above raw material is mixed in super micron mill, forms the bromine cyanogen insect amide that principle active component weight percentage is 82% Wettable powder with buprofezin.
Embodiment 3:
Weigh 60g bromine cyanogen insect amide, 2g Buprofezin, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 6g, two Toluene adds to 100g, and the method that above raw material is prepared cream routinely puts into mixing in mixing kettle, forms principle active component Weight percentage is the bromine cyanogen insect amide Buprofezin cream of 62%.
Embodiment 4:
Weigh 2g bromine cyanogen insect amide, 60g Buprofezin, nonyl phenol phosphate 5g, alkylphenol polyoxyethylene 4g, n-butyl alcohol The dimethylbenzene of 3g, 10g and the ketopyrrolidine of 10g, the xanthan gum of 0.1g, remaining supplies 100g, n-butyl alcohol and water dissolution shape with water Becoming aqueous phase, remaining component mix and blend forms oil phase, slowly aqueous phase is added in oil phase, and continue to cut under cutter effect Cut 10~30 minutes, form the bromine cyanogen insect amide Buprofezin aqueous emulsion that principle active component weight percentage is 62%.
Embodiment 5:
Weigh 40g bromine cyanogen insect amide, 2g Buprofezin, calcium dodecyl benzene sulfonate 5g, alkylphenol polyoxyethylene 4g, 30g Solvent xylene and the ketopyrrolidine of 15g, remaining complements to 100g with water, and the mixing of former medicine, solvent, emulsifying agent, cosolvent is stirred Mix formation homogeneous phase transparent solution, be then slowly added into water and stir formation clear solution, being principle active component weight percent Content is the bromine cyanogen insect amide Buprofezin microemulsion of 42%.
Embodiment 6:
Weigh 2g bromine cyanogen insect amide, 40g Buprofezin, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 3g, two Toluene is to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, forms principle active component weight Amount percentage composition is the bromine cyanogen insect amide Buprofezin cream of 42%.
Embodiment 7:
Weigh 20g bromine cyanogen insect amide, 2g Buprofezin, sodium lignin sulfonate 3g, polyoxyethylene poly-oxygen propylene aether and sulphuric acid thereof Salt 4g, xanthan gum 0.2g, ethylene glycol 10g, silica ethane 0.1g, aluminium-magnesium silicate 0.5g, supply 100g with water, at the work of sand mill With the bromine cyanogen insect amide buprofezin suspension agent that lower formation principle active component weight percentage is 22%.
Embodiment 8:
Weigh 2g bromine cyanogen insect amide, 20g Buprofezin, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether 15g, Dimethylbenzene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, forms principle active component Weight percentage is the bromine cyanogen insect amide Buprofezin cream of 22%.
Embodiment 9:
Weigh 2g bromine cyanogen insect amide, 10g Buprofezin, sodium lignin sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g, Polyvinyl alcohol 5g, Borax 2g, Kaolin 28g, the method that above raw material is pressed water dispersion granule forms principle active component weight Amount percentage composition is the bromine cyanogen insect amide Buprofezin water dispersible granules of 12%.
Embodiment 10:
Weigh 5g bromine cyanogen insect amide, 10g Buprofezin, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether 15g, Dimethylbenzene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, forms principle active component Weight percentage is the bromine cyanogen insect amide Buprofezin cream of 15%.
Embodiment 11:
Weigh 10g bromine cyanogen insect amide, 10g Buprofezin, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, Dimethylbenzene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, forms principle active component Weight percentage is the bromine cyanogen insect amide Buprofezin cream of 20%.
Drug effect checking test
1, indoor virulence determination of activity
Weigh bromine cyanogen insect amide, Buprofezin uses conventional formulation method to be configured to principle active component weight by different proportion Percentage composition is the bromine cyanogen insect amide Buprofezin cream of 30%.Concrete ratio is shown in Table 1.
Use feedstuff to add poison method and measure bromine cyanogen insect amide and Buprofezin and the compounding sample virulence to cotton boll worm thereof, often Process is repeated 3 times, and every concentration processes 30, uses LC50It is worth and presses Sun Yun abundant method calculating co-toxicity coefficient:
Table 1 bromine cyanogen insect amide, Buprofezin and compounding sample thereof are to the toxicity test of cotton boll worm and co-toxicity coefficient
In table, data show, after bromine cyanogen insect amide and Buprofezin mixture, cotton boll worm are had potentiation, institute in table The proportioning co-toxicity coefficient of row is both greater than 120, and therefore bromine cyanogen insect amide and Buprofezin mixture have significant synergies.
Weigh bromine cyanogen insect amide, Buprofezin uses conventional formulation method to be configured to principle active component weight by different proportion Percentage composition is the bromine cyanogen insect amide Buprofezin cream of 30%.Concrete ratio is shown in Table 2.
Rice-stem dipping method is used to measure bromine cyanogen insect amide and Buprofezin and the compounding sample virulence to Brown Planthopper thereof, often Process is repeated 3 times, and uses LC50It is worth and presses Sun Yun abundant method calculating co-toxicity coefficient:
Table 2 bromine cyanogen insect amide, Buprofezin and compounding sample thereof are to the toxicity test of Brown Planthopper and co-toxicity coefficient
In table, data show, have potentiation, institute in table after bromine cyanogen insect amide and Buprofezin mixture to Brown Planthopper The proportioning co-toxicity coefficient of row is all much larger than 120, and therefore bromine cyanogen insect amide and Buprofezin mixture have significant synergies.
2, field control effectiveness test
Using embodiment institute sample product to carry out the field test of control in field cotton boll worm, comparison medicament is 5% bromine cyanogen Insect amide EC and 25% Buprofezin WP, concrete consumption is shown in Table 3, and every mu of water consumption is 30kg, looks into 3 days after medicine, 7 days, 14 days results, Result of the test is shown in Table 3:
Table 3 sample field test results to cotton boll worm
Example has fabulous quick-acting to cotton boll worm as can be seen from Table 3, and the lasting period is long, at field table Now good, it is the outstanding medicament of preventing and treating cotton boll worm.
Measure through indoor synergism test and show: by bromine cyanogen insect amide with buprofezin compound agent to cotton boll worm and Rice Brown Plant hopper has significant synergistic insecticidal action;Field control effectiveness test also indicates that all of built agent of the present invention is to cotton boll worm equally Insecticidal effect is all remarkably higher than the effect of corresponding single dose pesticide.

Claims (9)

1. brominated cyanogen insect amide and a Synergistic insecticidal compositions for Buprofezin, is characterized in that this Synergistic insecticidal compositions is with bromine cyanogen Insect amide and Buprofezin are principle active component, and wherein, the weight ratio of bromine cyanogen insect amide and Buprofezin is 1~60:1~60.
Brominated cyanogen insect amide the most according to claim 1 and the Synergistic insecticidal compositions of Buprofezin, is characterized in that this parasite killing The active ingredient bromine cyanogen insect amide of compositions and the weight ratio of Buprofezin are 1~40:1~40.
Brominated cyanogen insect amide the most according to claim 2 and the Synergistic insecticidal compositions of Buprofezin, is characterized in that this parasite killing The active ingredient bromine cyanogen insect amide of compositions and the weight ratio of Buprofezin are 1~30:1~30.
Brominated cyanogen insect amide the most according to claim 1 and the Synergistic insecticidal compositions of Buprofezin, is characterized in that bromine cyanogen worm Amide and both Buprofezins weight percentage in this Synergistic insecticidal compositions are 2%~80%.
Brominated cyanogen insect amide the most according to claim 4 and the Synergistic insecticidal compositions of Buprofezin, is characterized in that bromine cyanogen worm Amide and both Buprofezins weight percentage in this Synergistic insecticidal compositions are 8%~60%.
Brominated cyanogen insect amide the most according to claim 1 and the Synergistic insecticidal compositions of Buprofezin, is characterized in that this potentiation With bromine cyanogen insect amide, as principle active component and insecticides adjuvant, excipient are configured on pesticide to allow Pesticidal combination with Buprofezin Any one dosage form.
Brominated cyanogen insect amide the most according to claim 6 and the Synergistic insecticidal compositions of Buprofezin, is characterized in that described dose Type is cream, wettable powder, microemulsion, aqueous emulsion, suspending agent or water dispersion granule.
8. the Synergistic insecticidal compositions of brominated cyanogen insect amide described in claim 1 and Buprofezin preparation preventing and treating Lepidoptera, half Application in the insecticidal materials of one or more insects in wing mesh, Hymenoptera or coleoptera.
Application the most according to claim 8, is characterized in that the Synergistic insecticidal compositions of brominated cyanogen insect amide and Buprofezin exists Application in the insecticidal materials of preparation preventing and treating cotton boll worm, beet armyworm and Brown Planthopper.
CN201610454846.1A 2016-06-21 2016-06-21 A kind of brominated cyanogen insect amide and the Synergistic insecticidal compositions of Buprofezin and application thereof Pending CN106070247A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102283205A (en) * 2004-07-26 2011-12-21 杜邦公司 Mixtures of anthranilamide invertebrate pest control agents
CN102626070B (en) * 2012-03-29 2013-07-31 广西田园生化股份有限公司 Ultra-low volume liquid containing cyantraniliprole and organophosphorus insecticides
CN103283740A (en) * 2012-03-02 2013-09-11 陕西韦尔奇作物保护有限公司 Cyantraniliprole-containing pesticidal composition
WO2015016251A1 (en) * 2013-07-31 2015-02-05 バイエルクロップサイエンス株式会社 Agrochemical composition for cultivation by direct seeding of paddy rice, and method for using same

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102283205A (en) * 2004-07-26 2011-12-21 杜邦公司 Mixtures of anthranilamide invertebrate pest control agents
CN103283740A (en) * 2012-03-02 2013-09-11 陕西韦尔奇作物保护有限公司 Cyantraniliprole-containing pesticidal composition
CN102626070B (en) * 2012-03-29 2013-07-31 广西田园生化股份有限公司 Ultra-low volume liquid containing cyantraniliprole and organophosphorus insecticides
WO2015016251A1 (en) * 2013-07-31 2015-02-05 バイエルクロップサイエンス株式会社 Agrochemical composition for cultivation by direct seeding of paddy rice, and method for using same

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Application publication date: 20161109