CN103283740A - Cyantraniliprole-containing pesticidal composition - Google Patents
Cyantraniliprole-containing pesticidal composition Download PDFInfo
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- CN103283740A CN103283740A CN2012100524883A CN201210052488A CN103283740A CN 103283740 A CN103283740 A CN 103283740A CN 2012100524883 A CN2012100524883 A CN 2012100524883A CN 201210052488 A CN201210052488 A CN 201210052488A CN 103283740 A CN103283740 A CN 103283740A
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- insect amide
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- mobucin
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Abstract
The invention discloses a cyantraniliprole-containing pesticidal composition which contains an active component A and an active component B, wherein the active component A is selected from spirotetramat; the active component B is selected from buprofezin, tsumacide or mobucin; and the weight ratio of the active component A to the active component B is 60:1-1:80. The composition disclosed by the invention can prevent and treat many soil pests, has an obvious synergistic action, widens the pesticidal spectrum, and has higher activity for flea beetle, aphid, thrips rice stem borer, yellow rice borer, rice leaf roller, rice fulgorid, leafhopper, coccid, phyllocnistis citrella stainton, orange arrowhead scale and smaller green leafhopper of tea; the invention reduces the consumption of the pesticide, lowers the residue level of the pesticide on crops, and reduces the environmental pollution; the composition is safe for both human and livestock, and has favorable environmental compatibility; and the pests can not easily generate drug resistance.
Description
Technical field
The invention belongs to technical field of pesticide, relate to a kind of Pesticidal combination that contains the bromine cyanogen insect amide.
Background technology
Bromine cyanogen insect amide (cyantraniliprole), chemical name: 4-chloro-3-ethyl-1-methyl-N-{[4-(4-methylphenoxy) phenyl]-methyl }-1H pyrazoles-5-carboxylic acid amides, the bromine cyanogen insect amide is to be E.I.Du Pont Company's second generation ryania acceptor inhibitor insecticides that success is developed after the chlorine insect amide, cyanogen insect amide is to form by the various polar groups that change on the phenyl ring, have more efficient, applicable crops is more extensive, can effectively prevent and treat Lepidoptera, Semiptera and coleopteran pest.
Yet in the real process of agricultural production, the problem that pest control is easy to generate most is the generation of pest resistance to insecticide.
The different cultivars composition carries out composite, is the very common method of control resistant insect.Heterogeneity is carried out composite, according to practical application effect, judge certain composite be synergy, add and or antagonism.In most cases, the composite effect of agricultural chemicals all is additive effect, and the seldom composite of synergistic effect really arranged, especially synergistic effect very obviously, co-toxicity coefficient very high composite just still less.Through inventor research, find can produce good synergistic effect after bromine cyanogen insect amide and Buprofezin, meta-tolyl-N-methylcarbamate (MTMC), Mobucin is composite, and still unexposed about the composite relevant report of bromine cyanogen insect amide and Buprofezin, meta-tolyl-N-methylcarbamate (MTMC), Mobucin.
Summary of the invention
Degradation problem under the resistance generation that the long-term use of bromine cyanogen insect amide list agent may bring, the drug effect, the Pesticidal combination that the present invention proposes contains two kinds of active components of A, B, and an amount of surfactant and carrier.
A kind of Pesticidal combination that contains the bromine cyanogen insect amide, comprise effective active component, auxiliary agent, it is characterized in that: active component A, B weight ratio are 60: 1～1: 80, and described active component A is selected from the bromine cyanogen insect amide, and active component B is selected from a kind of in Buprofezin, meta-tolyl-N-methylcarbamate (MTMC), the Mobucin.
Described Pesticidal combination is characterized in that: the weight ratio of A, two kinds of active components of B is 40: 1～1: 60.
Described Pesticidal combination is characterized in that: the weight ratio of bromine cyanogen insect amide and Buprofezin is 10: 1～1: 40, is preferably 1: 1～1: 8; The weight ratio of bromine cyanogen insect amide and meta-tolyl-N-methylcarbamate (MTMC) is 10: 1～1: 40, is preferably 1: 1～1: 20; The weight ratio of bromine cyanogen insect amide and Mobucin is 10: 1～1: 40, is preferably 1: 1～1: 20.
The weight ratio of A, two kinds of active components of B is 60: 1～1: 80.Usually active weight percentage is 0.5～90% of gross weight in the composition, and preferable is 5%～85%.According to different preparation types, the active component content scope is different.Usually, liquid preparation contains 1～70% active substance by weight, preferably is 5～50%; Solid pharmaceutical preparation contains 5～85% active substance by weight, preferably is 10～80%.
At least contain a kind of surfactant in the Pesticidal combination of the present invention, the dispersion of active component in water when being beneficial to use.Surface-active contents is 5～30% of total formulation weight amount, and surplus is solid or liquid diluent.
The selected surfactant of Pesticidal combination of the present invention is known in those skilled in the art: can be selected from dispersant, wetting agent, binding agent or the defoamer one or more.According to different dosage form, can also contain disintegrant known in those skilled in the art, antifreeze etc. in the preparation.
Described dispersant is selected from alkylnaphthalene sulfonate, two (alkyl) naphthalenesulfonate formaldehyde condensation compound, naphthalene sulfonic acid-formaldehyde condensation product, aryl phenol polyoxyethylene succinate sulfonate, octylphenol polyethylene oxyethylene group ether sulfate, polycarboxylate, lignosulfonates, the alkylaryl APEO, aliphatic alcohol polyethenoxy base ether, the phonetic formaldehyde condensation products sulphate of alkylphenol-polyethenoxy, alkyl benzene sulfonate calcium salt, the naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol-polyethenoxy is phonetic, aliphatic amine polyoxyethylene is phonetic, polyoxyethylene carboxylate, during the ester polyoxyethylene is phonetic one or more.
Described wetting agent is selected from: lauryl sodium sulfate, neopelex, Nekal BX, wetting and penetrating agent F, spaonin powder, sldium lauryl sulfate, tea are withered, in the silkworm excrement, soapberry powder one or more.
Described disintegrant is selected from: one or more in sodium bicarbonate, sodium carbonate, bentonite, urea, ammonium sulfate, glucose, the aluminium chloride.
Described thickener is selected from: one or more in CMC, hydroxyethylcellulose, Magnesiumaluminumsilicate, gelatin, melon glue, gum Arabic, xanthans, sodium phosphate trimer, phenolic resins, sodium alginate, white dextrin, methylcellulose, PAA, polyvinylpyrrolidone, crospolyvinylpyrrolidone, polyethylene glycol, the polyvinyl alcohol.
Described antifreeze is selected from: one or more in glycerine, ethylene glycol, propane diols, glycerine, diethylene glycol (DEG), triethylene glycol, the polyethylene glycol.
Described solvent is selected from: N, dinethylformamide, 3-methyl cyclohexanol ketenes, N-octylpyrrolidone, N-pyrrolidones, toluene, propyl alcohol, cyclohexanone, acetone, methyl alcohol, ethanol, butanols, ethylene glycol monomethyl ether, butyl ether, ethyl acetate, vegetable oil, acetonitrile one or more.
Described defoamer is selected from: silicone, C
8～10Aliphatic alcohols, C
10～20In saturated fat acids (as capric acid) and acid amides, silicone oil, the silicone compound one or more.
Described emulsifier is selected from: agricultural newborn 500# (alkyl benzene calcium sulfonate), OP series phosphate (polyoxyethylene nonylphenol ether phosphate), 600# phosphate (phenyl phenol polyoxy ethyl ether phosphate), styrene polyoxyethylene ether ammonium sulfate salt, alkyl biphenyl ether disulfonic acid magnesium salts, triethanolamine salt, farming newborn 400# (benzyl dimethyl phenol polyoxy ethyl ether), farming newborn 600# (phenyl phenol polyoxy ethyl ether), Nongru-700 # (alkylphenol-formaldehyde resin polyoxy ethyl ether), farming newborn 36# (phenethyl fluosite polyoxy ethyl ether), farming newborn 1600# (phenethyl phenol polyoxy ethyl polypropylene-base ether), ethylene oxide-propylene oxide block copolymer, OP series (polyoxyethylene nonylphenol ether), By series (castor oil polyoxyethylene ether), farming newborn 33# (alkylaryl polyoxyethylene polyoxypropylene ether), farming newborn 34# (alkylaryl polyoxyethylene poly-oxygen propylene aether), sapn series (sorbitan monostearate), tween series (sorbitan fatty acid ester APEO), in the AEO series (fatty alcohol-polyoxyethylene ether) one or more.
The macromolecule cyst material is selected from one or more in urea, formaldehyde, PIC, polyfunctional group acyl halide polyamines, polyfunctional group acyl halide dihydroxylic alcohols, sodium alginate, polyvinyl alcohol, gelatin, gum Arabic, sucrose, modified starch, maltose, distortion milk protein, glycerine, calcium chloride, carboxymethyl cellulose, the beta-schardinger dextrin-.
Described PH conditioning agent is selected from one or more in sodium hydroxide, hydrochloric acid, citric acid, the sorbic acid.
Described filler is selected from: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, the precipitated calcium carbonate.
Composition of the present invention can be by the user before use through dilution or directly use.Its preparation can be by the preparation of common processing method, is about to active substance and after liquid flux or solid carrier mix, and adds in surfactant such as dispersant, stabilizing agent, wetting agent, adhesive, the defoamer etc. one or more again.
Pesticidal combination of the present invention can be processed into acceptable forms on any agricultural chemicals on demand.Wherein preferred dosage form is wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspension-suspending agent.
When making wetting powder, composition comprises following constituent content: bromine cyanogen insect amide 0.1～60%, active component B 0.1～80%, dispersant 5～10%, wetting agent 2～10%, filler surplus.
Active component bromine cyanogen insect amide, active component B, dispersant, wetting agent, filler are mixed, in mixed cylinder, mix, after airslide disintegrating mill is pulverized, mix again, namely can be made into the wetting powder product of the present composition.
When making water dispersible granules, composition comprises following constituent content: active component bromine cyanogen insect amide 0.1～60%, active component B 0.1～80%, dispersant 3～12%, wetting agent 1～8%, disintegrant 1～10%, binding agent 1～8%, filler surplus.
Active component bromine cyanogen insect amide, active component B, dispersant, wetting agent, disintegrant, filler etc. are pulverized the particle diameter that obtains needs through air-flow together, add other auxiliary agents such as binding agent again, obtain the materials of granulating.It is interior through after granulation and the drying to expect that product are quantitatively sent the fluidized bed granulation dryer to, makes the water dispersible granules product of the present composition.
Comprise following constituent content when composition is made suspending agent: active component bromine cyanogen insect amide 0.1～40%, active component B 0.1～60%, dispersant 2～10%, wetting agent 2～10%, defoamer 0.1～1%, binding agent 0.1～2%, antifreeze 0.1～8%, deionized water add to 100%.
Dispersant, wetting agent, defoamer, thickener, antifreeze in the above-mentioned formulation material are mixed through high speed shear, add active component bromine cyanogen insect amide, active component B, ball milling is 2～3 hours in ball mill, make diameter of particle all below 5 μ m, make the suspending agent product of the present composition.
Comprise following constituent content when composition is made suspension emulsion: bromine cyanogen insect amide 0.1～40%, active component B 0.1～60%, emulsifier 2～12%, dispersant 2～10%, defoamer 0.1～2%, thickener 0.1～2%, antifreeze 0.1～8%, stabilizing agent 0.05～3%, water add to 100%.
Dispersant, defoamer, thickener, antifreeze, stabilizing agent in the above-mentioned formulation material are mixed through high speed shear, add the former medicine of bromine cyanogen insect amide, ball milling is 2～3 hours in ball mill, make diameter of particle all below 5 μ m, make bromine cyanogen insect amide suspending agent, then with the former medicine of active component B, emulsifier and various auxiliary agent with the direct emulsification of high speed agitator in suspending agent, make the suspension emulsion product of the present composition.
Comprise following constituent content when composition is made aqueous emulsion: active components A 0.1%～40%, active component B 0.1%～60%, solvent 0%～30%, emulsifier 1%～15%, co-emulsifier 0%～8%, antifreeze 0%～10%, thickener 0.1%～2%, defoamer 0.01%～2%, deionized water are supplied surplus.
Above-mentioned prescription is mixed, active ingredient, solvent, emulsifier, co-emulsifier are added together, make and be dissolved into even oil phase; Water, antifreeze, thickener, defoamer are mixed, become the homogeneous water.Under high-speed stirred, water is added oil phase, make aqueous emulsion product of the present invention.
Comprise following constituent content when composition is made microemulsion: active components A 0.1%～40%, active component B 0.1%～60%, solvent 0%～30%, emulsifier 3%～20%, co-emulsifier 0%～12%, antifreeze 0%～10%, thickener 0.1%～2%, defoamer 0.01%～2%, stabilizing agent 0%～4%, deionized water is supplied surplus.
Bromine cyanogen insect amide and the former medicine of active component B are dissolved in the homogenizer that solvent and cosolvent are housed; Mix strongly after joining emulsifier, stabilizing agent and antifreeze, water in the homogenizer that above-mentioned solution is housed and homogenize, obtain the as clear as crystal microemulsion product of the present invention of outward appearance at last.
Composition is made micro-capsule suspension and is comprised following constituent content: active components A 0.1%～40%, active ingredient B 0.1%～50%, macromolecule cyst material 1%～12%, surfactant 2%～10%, organic solvent 1%～15%, emulsifier 1%～8%, pH conditioning agent 0.1%～5%, deionized water adds to 100%.
The macromolecule cyst material is added the PH conditioning agent be heated to uniform temperature, obtain thick liquid, thin up forms stable prepolymer solution then, active ingredient B, active components A are dissolved in the organic solvent, be added to again in the prepolymer solution, add emulsifier, surfactant, and fully shear agitation is dispersed into superfine microgranular, add the PH conditioning agent again, and heat up, the catalysis polycondensation forms the microcapsules of firm difficult infiltration, makes micro-capsule suspension of the present invention.
When the formulation of composition was microcapsules suspension-suspending agent, the auxiliary agent of interpolation was that surfactant, emulsifier, solvent, PH conditioning agent, macromolecule cyst material, defoamer, thickener, water add to 100%.
Composition comprises following constituent content when making microcapsule suspension-suspending agent: active components A 0.1%～40%, active ingredient B0.1%～60%, macromolecule cyst material 2%～12%, surfactant 3%～15%, organic solvent 1%～5%, emulsifier 1%～6%, defoamer 0.2%～5%, thickener 0.2%～5%, pH conditioning agent 0.1%～5%, water add to 100%.
Adopt interfacial polymerization, to there be active ingredient B, macromolecule cyst material, organic solvent to mix in the above-mentioned prescription, make and be dissolved into even oil phase, oil phase is joined under shearing condition in the aqueous phase solution that contains emulsifier, pH conditioning agent, two kinds of materials react at oil-water interfaces, form the macromolecule cyst wall around the drop that contains chemical substance, make active ingredient B micro-capsule suspension.Surfactant, defoamer, thickener, antifreeze are mixed through high speed shear, add the former medicine of active components A, ball milling is 2～3 hours in ball mill, make diameter of particle all below 5 μ m, make the active components A suspending agent, to be dissolved in active components A suspending agent stable in the water then and join in the aqueous phase solution of active ingredient B micro-capsule suspension, make the finely disseminated microcapsule suspension of the present composition-suspending agent product.
The invention has the advantages that: after (1) bromine cyanogen insect amide and active component B are composite, have notable synergistic and lasting effect; (2) enlarged insecticidal spectrum, flea beetle, aphid, thrips, striped rice borer, paddy stem borer, rice leaf roller, rice fulgorid, leafhopper, scale insect, phyllocnistis citrella stainton, oranges and tangerines arrowhead scales, tea lesser leafhopper have been had greater activity; (3) reduce the dosage of agricultural chemicals, reduced the residual quantity of agricultural chemicals on crop, alleviated environmental pollution; (4), insect good to person poultry safety, Environmental compatibility is difficult for developing immunity to drugs.
Embodiment
Below in conjunction with the further instruction of the present invention of embodiment, the percentage among the embodiment all is weight percentage, but the present invention is not limited thereto.
Application Example one
Embodiment 1 50% bromine cyanogen insect amide Buprofezin wetting powder
Bromine cyanogen insect amide 10%, Buprofezin 40%, alkylphenol-polyethenoxy are phonetic 7%, wetting and penetrating agent F 5%, attapulgite add to 100%, and mixture carries out air-flow to be pulverized, and makes 50% bromine cyanogen insect amide Buprofezin wetting powder.
Embodiment 2 81% bromine cyanogen insect amide Buprofezin wetting powders
Bromine cyanogen insect amide 1%, Buprofezin 80%, ester polyoxyethylene are phonetic 5%, neopelex 4%, white carbon add to 100%, and mixture carries out air-flow to be pulverized, and makes 81% bromine cyanogen insect amide Buprofezin wetting powder.
Embodiment 3 45% bromine cyanogen insect amide Buprofezin water dispersible granules
Bromine cyanogen insect amide 5%, Buprofezin 40%, aryl phenol polyoxyethylene succinate sulfonate 8%, spaonin powder 6%, urea 2.8%, kaolin add to 100%, the mixed 45% bromine cyanogen insect amide Buprofezin water dispersible granules that gets.
Embodiment 4 75% bromine cyanogen insect amide Buprofezin water dispersible granules
Bromine cyanogen insect amide 15%, Buprofezin 60%, polycarboxylate 7%, soapberry powder 6%, ammonium sulfate 2%, starch add to 100%, the mixed 75% bromine cyanogen insect amide Buprofezin water dispersible granules that gets.
Embodiment 5 18% bromine cyanogen insect amide buprofezin suspension agents
Bromine cyanogen insect amide 8%, Buprofezin 10%, lignosulfonates 6%, silkworm excrement 5%, C
8～10Aliphatic alcohols 0.4%, Magnesiumaluminumsilicate 0.9%, triethylene glycol 2%, deionized water add to 100%, the mixed 18% bromine cyanogen insect amide buprofezin suspension agent that gets.
Embodiment 6 40% bromine cyanogen insect amide buprofezin suspension agents
Bromine cyanogen insect amide 10%, Buprofezin 30%, aliphatic amine polyoxyethylene are phonetic 8%, silicone compound 0.1%, PAA 0.7%, glycerine 1.8%, deionized water add to 100%, mixed 40% bromine cyanogen insect amide buprofezin suspension agent.
Embodiment 7 10% bromine cyanogen insect amide Buprofezin suspension emulsions
Bromine cyanogen insect amide 5%, Buprofezin 5%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6%, tea are withered 4%, hydroxyethylcellulose 1.3%, castor oil polyoxyethylene ether 7%, ethylene glycol 2%, silicone oil 0.3%, water add to 100%, through mixed 10% bromine cyanogen insect amide Buprofezin suspension emulsion.
Embodiment 8 30.5% bromine cyanogen insect amide Buprofezin suspension emulsions
Bromine cyanogen insect amide 30%, Buprofezin 0.5%, alkyl benzene sulfonate calcium salt 5%, Nekal BX 5%, polyvinylpyrrolidone 1.4%, polyoxyethylene nonylphenol ether phosphate 8%, ethylene glycol 1.3%, silicone 0.2%, water add to 100%, through the mixed 30.5% bromine cyanogen insect amide Buprofezin suspension emulsion that gets.
Embodiment 9 25% bromine cyanogen insect amide Buprofezin microemulsions
Bromine cyanogen insect amide 10%, Buprofezin 15%, 3-methyl cyclohexanol ketenes 6%, toluene 5%, ethylene oxide-propylene oxide block copolymer 7%, propane diols 2.3%, C
8～10Aliphatic alcohols 0.2%, xanthans 1.5%, deionized water supplies 100%, the mixed 25% bromine cyanogen insect amide Buprofezin microemulsion that gets.
Embodiment 10 45% bromine cyanogen insect amide Buprofezin microemulsions
Bromine cyanogen insect amide 15%, Buprofezin 30%, N-pyrrolidones 5%, vegetable oil 4%, phenethyl phenol polyoxy ethyl polypropylene-base ether 6%, polyethylene glycol 1.2%, silicone compound 0.5%, sodium phosphate trimer 1.5%, deionized water supplies 100%, the mixed 45% bromine cyanogen insect amide Buprofezin microemulsion that gets.
Embodiment 11 40% bromine cyanogen insect amide Buprofezin aqueous emulsions
Bromine cyanogen insect amide 5%, Buprofezin 35%, cyclohexanone 6%, ethylene glycol monomethyl ether 8%, phenethyl fluosite polyoxy ethyl ether 5%, Magnesiumaluminumsilicate 1.4%, silicone oil 0.2%, deionized water adds to 100%, makes 40% bromine cyanogen insect amide Buprofezin aqueous emulsion.
Embodiment 12 60% bromine cyanogen insect amide Buprofezin aqueous emulsions
Bromine cyanogen insect amide 10%, Buprofezin 50%, toluene 8%, acetone 4%, ethylene oxide-propylene oxide block copolymer 6%, xanthans 1%, C
8～10Aliphatic alcohols 0.3%, deionized water supplies 100%, makes 60% bromine cyanogen insect amide Buprofezin aqueous emulsion.
Embodiment 13 30% bromine cyanogen insect amide meta-tolyl-N-methylcarbamate (MTMC) wetting powders
Bromine cyanogen insect amide 5%, meta-tolyl-N-methylcarbamate (MTMC) 25%, octylphenol polyethylene oxyethylene group ether sulfate 8%, Nekal BX 4%, attapulgite add to 100%, make 30% bromine cyanogen insect amide meta-tolyl-N-methylcarbamate (MTMC) wetting powder.
Embodiment 14 72% bromine cyanogen insect amide meta-tolyl-N-methylcarbamate (MTMC) wetting powders
Bromine cyanogen insect amide 8%, meta-tolyl-N-methylcarbamate (MTMC) 64%, lignosulfonates 9%, neopelex 6%, bentonite add to 100%, make 72% bromine cyanogen insect amide meta-tolyl-N-methylcarbamate (MTMC) wetting powder.
Embodiment 15 40.5% bromine cyanogen insect amide Tsumacide water dispersible granules
Bromine cyanogen insect amide 0.5%, meta-tolyl-N-methylcarbamate (MTMC) 40%, polycarboxylate 6%, sldium lauryl sulfate 5%, aluminium chloride 3%, diatomite add to 100%, make 40.5% bromine cyanogen insect amide Tsumacide water dispersible granule.
Embodiment 16 70% bromine cyanogen insect amide Tsumacide water dispersible granules
Bromine cyanogen insect amide 10%, meta-tolyl-N-methylcarbamate (MTMC) 60%, alkyl benzene sulfonate calcium salt 8%, wetting and penetrating agent F 5%, sodium bicarbonate 2.2%, kaolin add to 100%, make 70% bromine cyanogen insect amide Tsumacide water dispersible granule.
Embodiment 17 35% bromine cyanogen insect amide meta-tolyl-N-methylcarbamate (MTMC) suspending agents
Bromine cyanogen insect amide 5%, meta-tolyl-N-methylcarbamate (MTMC) 30%, ester polyoxyethylene are phonetic 7%, lauryl sodium sulfate 4%, polyvinyl alcohol 1.2%, C
8～10Aliphatic alcohols 0.5%, propane diols 1.9%, deionized water add to 100%, the mixed 35% bromine cyanogen insect amide meta-tolyl-N-methylcarbamate (MTMC) suspending agent that gets.
Embodiment 18 45% bromine cyanogen insect amide meta-tolyl-N-methylcarbamate (MTMC) suspending agents
Bromine cyanogen insect amide 5%, meta-tolyl-N-methylcarbamate (MTMC) 40%, polyoxyethylene carboxylate 8%, lauryl sodium sulfate 5%, silicone compound 0.3%, xanthans 1%, diethylene glycol (DEG) 2%, deionized water add to 100%, the mixed 45% bromine cyanogen insect amide meta-tolyl-N-methylcarbamate (MTMC) suspending agent that gets.
Embodiment 19 30.5% bromine cyanogen insect amide meta-tolyl-N-methylcarbamate (MTMC) suspension emulsions
Bromine cyanogen insect amide 30%, meta-tolyl-N-methylcarbamate (MTMC) 0.5%, the phonetic formaldehyde condensation products sulphate 7% of alkylphenol-polyethenoxy, Nekal BX 4%, phenolic resins 1.3%, phenyl phenol polyoxy ethyl ether phosphate 8%, propane diols 1.5%, silicone oil 0.6%, water add to 100%, through the mixed 30.5% bromine cyanogen insect amide meta-tolyl-N-methylcarbamate (MTMC) suspension emulsion that gets.
Embodiment 20 50% bromine cyanogen insect amide meta-tolyl-N-methylcarbamate (MTMC) suspension emulsions
Bromine cyanogen insect amide 10%, meta-tolyl-N-methylcarbamate (MTMC) 40%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6%, silkworm excrement 5%, Magnesiumaluminumsilicate 0.8%, alkylaryl polyoxyethylene poly-oxygen propylene aether 7%, glycerine 2%, C
8～10Aliphatic alcohols 0.2%, water add to 100%, through the mixed 50% bromine cyanogen insect amide meta-tolyl-N-methylcarbamate (MTMC) suspension emulsion that gets.
Embodiment 21 22% bromine cyanogen insect amide meta-tolyl-N-methylcarbamate (MTMC) microemulsions
Bromine cyanogen insect amide 2%, meta-tolyl-N-methylcarbamate (MTMC) 20%,, N-octylpyrrolidone 5%, toluene 7%, ethylene glycol 2.5%, methylcellulose 1%, silicone oil 0.5%, phenethyl fluosite polyoxy ethyl ether 6%, deionized water supplies 100%, the mixed 22% bromine cyanogen insect amide meta-tolyl-N-methylcarbamate (MTMC) microemulsion that gets.
Embodiment 22 45% bromine cyanogen insect amide meta-tolyl-N-methylcarbamate (MTMC) microemulsions
Bromine cyanogen insect amide 10%, meta-tolyl-N-methylcarbamate (MTMC) 35%, ethylene glycol monomethyl ether 6%, acetone 7%, ethylene oxide-propylene oxide block copolymer 8%, propane diols 2.1%, silicone oil 0.4%, polyvinylpyrrolidone 1.2%, deionized water supplies 100%, the mixed 45% bromine cyanogen insect amide meta-tolyl-N-methylcarbamate (MTMC) microemulsion that gets.
Embodiment 23 26% bromine cyanogen insect amide meta-tolyl-N-methylcarbamate (MTMC) aqueous emulsions
Bromine cyanogen insect amide 2%, meta-tolyl-N-methylcarbamate (MTMC) 24%, N, dinethylformamide 5%, cyclohexanone 5%, alkylaryl polyoxyethylene poly-oxygen propylene aether 6%, polyethylene glycol 1.8%, xanthans 1.2%, C
8～10Aliphatic alcohols 0.3%, deionized water supplies 100%, makes 26% bromine cyanogen insect amide meta-tolyl-N-methylcarbamate (MTMC) aqueous emulsion.
Embodiment 24 40% bromine cyanogen insect amide meta-tolyl-N-methylcarbamate (MTMC) aqueous emulsions
Bromine cyanogen insect amide 5%, meta-tolyl-N-methylcarbamate (MTMC) 35%, toluene 6%, 3-methyl cyclohexanol ketenes 4%, propane diols 1.5%, polyoxyethylene nonylphenol ether phosphate 5%, hydroxyethylcellulose 1.3%, silicone compound 0.1%, deionized water supplies 100%, makes 40% bromine cyanogen insect amide meta-tolyl-N-methylcarbamate (MTMC) aqueous emulsion.
Embodiment 25 55% bromine cyanogen insect amide Mobucin wetting powders
Bromine cyanogen insect amide 5%, Mobucin 50%, two (alkyl) naphthalenesulfonate formaldehyde condensation compound 10%, lauryl sodium sulfate 4%, bentonite add to 100%, make 55% bromine cyanogen insect amide Mobucin wetting powder.
Embodiment 26 81% bromine cyanogen insect amide Mobucin wetting powders
Bromine cyanogen insect amide 1%, Mobucin 80%, lignosulfonates 7%, soapberry powder 4%, white carbon add to 100%, make 81% bromine cyanogen insect amide Mobucin wetting powder.
Embodiment 27 45% bromine cyanogen insect amide Mobucin water dispersible granules
Bromine cyanogen insect amide 5%, Mobucin 40%, naphthalene sulfonic acid-formaldehyde condensation product 8%, Nekal BX 5%, urea 2%, diatomite add to 100%, make 45% bromine cyanogen insect amide Mobucin water dispersible granules.
Embodiment 28 80% bromine cyanogen insect amide Mobucin water dispersible granules
Bromine cyanogen insect amide 10%, Mobucin 70%, aliphatic amine polyoxyethylene are phonetic 5%, lauryl sodium sulfate 3%, sodium carbonate 3%, kaolin add to 100%, make 80% bromine cyanogen insect amide Mobucin water dispersible granules.
Embodiment 29 25% bromine cyanogen insect amide Mobucin suspending agents
Bromine cyanogen insect amide 5%, Mobucin 20%, alkyl benzene sulfonate calcium salt 9%, neopelex 5%, Magnesiumaluminumsilicate 1%, diethylene glycol (DEG) 1.6%, C
8～10Aliphatic alcohols 0.3%, deionized water add to 100%, the mixed 25% bromine cyanogen insect amide Mobucin suspending agent that gets.
Embodiment 30 42% bromine cyanogen insect amide Mobucin suspending agents
Bromine cyanogen insect amide 6%, Mobucin 36%, ester polyoxyethylene are phonetic 6%, wetting and penetrating agent F4%, silicone 0.4%, gum Arabic 1.3%, polyethylene glycol 2.5%, deionized water add to 100%, mixed 42% bromine cyanogen insect amide Mobucin suspending agent.
Embodiment 31 30% bromine cyanogen insect amide Mobucin suspension emulsions
Bromine cyanogen insect amide 5%, Mobucin 25%, polycarboxylate 8%, lauryl sodium sulfate 6%, silicone oil 0.2%, Magnesiumaluminumsilicate 1.1%, styrene polyoxyethylene ether ammonium sulfate salt 7%, propane diols 2.3%, water add to 100%, the aforementioned formula material is mixed, namely make 30% bromine cyanogen insect amide Mobucin suspension emulsion.
Embodiment 32 41% bromine cyanogen insect amide Mobucin suspension emulsions
Bromine cyanogen insect amide 40%, Mobucin 1%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6%, spaonin powder 4%, silicone compound 0.3%, PAA 0.9%, polyoxyethylene nonylphenol ether 8%, ethylene glycol 2%, water add to 100%, the aforementioned formula material is mixed, namely make 41% bromine cyanogen insect amide Mobucin suspension emulsion.
Embodiment 33 21% bromine cyanogen insect amide Mobucin microemulsions
Bromine cyanogen insect amide 1%, Mobucin 20%, acetone 6%, ethyl acetate 5%, sorbitan fatty acid ester APEO 6%, propane diols 2.1%, silicone 0.4%, deionized water supplies 100%, the mixed 21% bromine cyanogen insect amide Mobucin microemulsion that gets.
Embodiment 34 40% bromine cyanogen insect amide Mobucin microemulsions
Bromine cyanogen insect amide 10%, Mobucin 30%, 3-methyl cyclohexanol ketenes 7%, toluene 5%, castor oil polyoxyethylene ether 8%, triethylene glycol 2%, silicone compound 0.5%, polyvinyl alcohol 1.5%, deionized water supplies 100%, the mixed 40% bromine cyanogen insect amide Mobucin microemulsion that gets.
Embodiment 35 20% bromine cyanogen insect amide Mobucin aqueous emulsions
Bromine cyanogen insect amide 10%, Mobucin 10%, N-pyrrolidones 5%, butanols 6%, ethylene oxide-propylene oxide block copolymer 7%, hydroxyethylcellulose 1.1%, C
8～10Aliphatic alcohols 0.3%, deionized water adds to 100%, makes 20% bromine cyanogen insect amide Mobucin aqueous emulsion.
Embodiment 36 45% bromine cyanogen insect amide Mobucin aqueous emulsions
Bromine cyanogen insect amide 15%, Mobucin 30%, vegetable oil 6%, cyclohexanone 8%, ethylene glycol 1.4%, benzyl dimethyl phenol polyoxy ethyl ether 5%, xanthans 0.7%, silicone oil 0.2%, deionized water supplies 100%, makes 45% bromine cyanogen insect amide Mobucin aqueous emulsion.
Embodiment 37 61% bromine cyanogen insect amide active component B micro-capsule suspensions
Bromine cyanogen insect amide 60%, active component B 1%, polyfunctional group acyl halide dihydroxylic alcohols 3.5%, spaonin powder 4.6%, ester polyoxyethylene are phonetic 5%, carrene 3.2%, dimethylbenzene 2.8%, ethyl acetate 5%, alkylaryl polyoxyethylene poly-oxygen propylene aether 6%, sodium hydroxide 1.2%, sorbic acid 1.1%, deionized water add to 100% weight portion, mixed 61% bromine cyanogen insect amide active component B micro-capsule suspension.
Embodiment 38 40.5% bromine cyanogen insect amide active component B microcapsule suspension-suspending agents
Bromine cyanogen insect amide 0.5%, active component B 40%, PIC 3.5%, white dextrin 2.5%, modified starch 4%, silkworm excrement 8%, dodecylbenzene sodium sulfonate 1.5%, acetone 3.2%, vegetable oil 4%, castor oil polyoxyethylene ether 6%, tween series 4%, silicone defoaming agent 0.4%, methylcellulose 1.2%, pH conditioning agent sodium hydroxide and citric acid amount to 2%, deionized water adds to 100% weight portion, mixed 40.5% bromine cyanogen insect amide active component B microcapsule suspension-suspending agent.
Above-described embodiment 37, embodiment 38 described active component B are a kind of arbitrarily in Buprofezin, meta-tolyl-N-methylcarbamate (MTMC), the Mobucin, and the weight ratio of bromine cyanogen insect amide and active component B is any one ratio between 60: 1～1: 80.
The embodiment of the invention is the method that adopts Toxicity Determination and field trial to combine.Earlier by Toxicity Determination, the co-toxicity coefficient (CTC) after clear and definite two kinds of medicaments are composite by a certain percentage, CTC＜80 are antagonism, and 80≤CTC≤120 are summation action, and CTC＞120 are synergistic effect, on this basis, carry out field trial again.
Test method: respectively the mother liquor of each mixed agent of bromine cyanogen insect amide effective active composition B is diluted to five series concentration during test, places beaker standby respectively.Adopt and to soak the method that connects worm behind the leaf earlier, the blade of the same size that does not contact any medicament soaked in the soup that configures behind the 5s take out, dry naturally, put into insect box, connect then for examination 3 instar larvaes, under 25 ℃ of conditions, raise, every processing repeats for 3 times, every to repeat used examination borer population be 20, establishes blank simultaneously, checks dead borer population in 72h, calculate lethality and corrected mortality, try to achieve virulence regression equation and calculate LC
50Value.If the contrast lethality then is considered as invalid test greater than 10%.Computing formula is as follows:
The insect corrected mortality is converted into probit value (y), and concentration for the treatment of (μ g/ml) converts logarithm value (x) to, draws virulence regression equation with method of least squares, and calculates the value of every kind of medicament thus.Calculate co-toxicity coefficient CTC according to the abundant equation of Sun Yun.Computing formula following (be standard medicament with the bromine cyanogen insect amide, its toxicity index is 100):
TI * the P of theoretical toxicity index (TTI)=bromine cyanogen insect amide of M
The bromine cyanogen insect amideTI * P of+effective active composition B
Effective active composition B
In the formula: M is the mixture of different proportionings
P
Effective active composition BBe effective active composition B shared ratio in composition
P
The bromine cyanogen insect amideBe bromine cyanogen insect amide shared ratio in composition
A is selected from the bromine cyanogen insect amide;
B is selected from a kind of in Buprofezin, meta-tolyl-N-methylcarbamate (MTMC), the Mobucin.
Application Example two:
For trying insect: cabbage aphid.
Test medicine provides by Shaanxi Welch Crop Protection Co., Ltd..
Experimental scheme: effective lethal concentration scope of determining bromine cyanogen insect amide, Buprofezin and the two different proportioning mixture through preliminary experiment.
The different proportionings with Buprofezin of table 1 bromine cyanogen insect amide are to the toxicity test of cabbage aphid
As shown in Table 1, the proportioning of bromine cyanogen insect amide and buprofezin compound control cabbage aphid 60: 1 to 1: 80 o'clock, co-toxicity coefficient is all greater than 120, illustrating that both were mixed in the scope at 60: 1 to 1: 80 all shows synergistic effect, when saying that especially proportioning when bromine cyanogen insect amide and Buprofezin was at 1: 1 to 1: 8, synergistic effect is more obviously outstanding, co-toxicity coefficient maximum when bromine cyanogen insect amide and Buprofezin weight ratio are 1: 4 wherein, synergistic effect is the most obvious, find through the test people, bromine cyanogen insect amide and buprofezin compound 60: 1 to 1: 80 o'clock to the control flea beetle, aphid, thrips, striped rice borer, paddy stem borer, rice leaf roller, rice fulgorid, leafhopper, scale insect, phyllocnistis citrella stainton, the oranges and tangerines arrowhead scales, the tea lesser leafhopper insect also has synergistic effect preferably, particularly work as the proportioning of the two at 10: 1,9: 1,8: 1,7: 1,6: 1,5: 1,4: 1,3: 1,2: 1,1: 1,1: 2,1: 3,1: 4,1: 5,1: 6,1: 7,1: 8,1: 9,1: 10,1: 11,1: 12,1: 13,1: 14,1: 15,1: 16,1: 17,1: 18,1: 19,1: 20 o'clock co-toxicity coefficient is all greater than 150, and synergistic effect is obvious.
Application Example three:
For trying insect: rice hoppers.
Test medicine provides by Shaanxi Welch Crop Protection Co., Ltd..
Experimental scheme: effective lethal concentration scope of determining bromine cyanogen insect amide, meta-tolyl-N-methylcarbamate (MTMC) and the two different proportioning mixture through preliminary experiment.
The different proportionings with meta-tolyl-N-methylcarbamate (MTMC) of table 2 bromine cyanogen insect amide are to the toxicity test of rice hoppers
As shown in Table 2, bromine cyanogen insect amide and meta-tolyl-N-methylcarbamate (MTMC) be composite prevents and treats the proportioning 60: 1 to 1: 80 o'clock of rice hoppers, co-toxicity coefficient is all greater than 120, illustrating that both were mixed in the scope at 60: 1 to 1: 80 all shows synergistic effect, when saying that especially proportioning when bromine cyanogen insect amide and meta-tolyl-N-methylcarbamate (MTMC) was at 1: 1 to 1: 12, synergistic effect is more obviously outstanding, co-toxicity coefficient maximum when bromine cyanogen insect amide and meta-tolyl-N-methylcarbamate (MTMC) weight ratio are 1: 8 wherein, synergistic effect is the most obvious, find through the test people, bromine cyanogen insect amide and meta-tolyl-N-methylcarbamate (MTMC) composite 60: 1 to 1: 80 o'clock to the control flea beetle, aphid, thrips, striped rice borer, paddy stem borer, rice leaf roller, rice fulgorid, leafhopper, scale insect, phyllocnistis citrella stainton, the oranges and tangerines arrowhead scales, the tea lesser leafhopper insect also has synergistic effect preferably, particularly work as the proportioning of the two at 10: 1,9: 1,8: 1,7: 1,6: 1,5: 1,4: 1,3: 1,2: 1,1: 1,1: 2,1: 3,1: 4,1: 5,1: 6,1: 7,1: 8,1: 9,1: 10,1: 11,1: 12,1: 13,1: 14,1: 15,1: 16,1: 17,1: 18,1: 19,1: 20 o'clock co-toxicity coefficient is all greater than 150, and synergistic effect is obvious.
Application Example four:
For trying insect: leafhopper.
Test medicine provides by Shaanxi Welch Crop Protection Co., Ltd..
Experimental scheme: effective lethal concentration scope of determining bromine cyanogen insect amide, Mobucin and the two different proportioning mixture through preliminary experiment.
The different proportionings with Mobucin of table 3 bromine cyanogen insect amide are to the toxicity test of leafhopper
As shown in Table 3, the proportioning of the composite control of bromine cyanogen insect amide and Mobucin leafhopper 60: 1 to 1: 80 o'clock, co-toxicity coefficient is all greater than 120, illustrating that both were mixed in the scope at 60: 1 to 1: 80 all shows synergistic effect, when saying that especially proportioning when bromine cyanogen insect amide and Mobucin was at 1: 1 to 1: 12, synergistic effect is more obviously outstanding, co-toxicity coefficient maximum when bromine cyanogen insect amide and Mobucin weight ratio are 1: 8 wherein, synergistic effect is the most obvious, find through the test people, bromine cyanogen insect amide and Mobucin composite 60: 1 to 1: 80 o'clock to the control flea beetle, aphid, thrips, striped rice borer, paddy stem borer, rice leaf roller, rice fulgorid, leafhopper, scale insect, phyllocnistis citrella stainton, the oranges and tangerines arrowhead scales, the tea lesser leafhopper insect also has synergistic effect preferably, particularly work as the proportioning of the two at 10: 1,9: 1,8: 1,7: 1,6: 1,5: 1,4: 1,3: 1,2: 1,1: 1,1: 2,1: 3,1: 4,1: 5,1: 6,1: 7,1: 8,1: 9,1: 10,1: 11,1: 12,1: 13,1: 14,1: 15,1: 16,1: 17,1: 18,1: 19,1: 20 o'clock co-toxicity coefficient is all greater than 150, and synergistic effect is obvious.
Application Example pentabromo-cyanogen insect amide and Buprofezin and the composite control cabbage aphid test of pesticide effectiveness thereof
This experimental establishment is at the Xian City, Shanxi Province Changan District, and test medicine is researched and developed, provided by Shaanxi Welch Crop Protection Co., Ltd., contrast medicament 10% bromine cyanogen insect amide suspending agent (autogamy), 25% Buprofezin wetting powder (commercial).
Investigation cabbage aphid insect pest index before the medicine in the dispenser of insect pest initial stage of origination, was investigated the insect pest indexes in 3 days, 7 days, 14 days after the dispenser and is calculated preventive effect.Experimental result is as follows:
Table 4 bromine cyanogen insect amide, Buprofezin and the composite control cabbage aphid test of pesticide effectiveness thereof
As can be seen from Table 4, can effectively prevent and treat cabbage aphid behind bromine cyanogen insect amide and the buprofezin compound, control efficiency all is better than the preventive effect of single agent.In the test scope of medication, the target crop is had no adverse effects.
Application Example hexabromo cyanogen insect amide and meta-tolyl-N-methylcarbamate (MTMC) and the composite rice hoppers test of pesticide effectiveness of preventing and treating thereof
This experimental establishment is in Yingtan Yujiang County, Jiangxi Province, and test medicine is researched and developed, provided by Shaanxi Welch Crop Protection Co., Ltd., contrast medicament 10% bromine cyanogen insect amide suspending agent (autogamy), 25% meta-tolyl-N-methylcarbamate (MTMC) wetting powder (commercial).
Investigation rice hoppers insect pest index before the medicine in the dispenser of insect pest initial stage of origination, was investigated the insect pest indexes in 3 days, 7 days, 14 days after the dispenser and is calculated preventive effect.Experimental result is as follows:
Table 5 bromine cyanogen insect amide, meta-tolyl-N-methylcarbamate (MTMC) and the composite rice hoppers test of pesticide effectiveness of preventing and treating thereof
As can be seen from Table 5, can effectively prevent and treat rice hoppers after bromine cyanogen insect amide and meta-tolyl-N-methylcarbamate (MTMC) are composite, control efficiency all is better than the preventive effect of single agent.In the test scope of medication, the target crop is had no adverse effects.
Application Example seven bromine cyanogen insect amides and Mobucin and the composite control rice-leaf hopper test of pesticide effectiveness thereof
This experimental establishment is in Ankang City Ziyang County, Shaanxi Province, and test medicine is researched and developed, provided by Shaanxi Welch Crop Protection Co., Ltd., contrast medicament 10% bromine cyanogen insect amide suspending agent (autogamy), 20% Mobucin missible oil (commercial).
Investigation rice-leaf hopper insect pest index before the medicine in the dispenser of insect pest initial stage of origination, was investigated the insect pest indexes in 3 days, 7 days, 14 days after the dispenser and is calculated preventive effect.Experimental result is as follows:
Table 6 bromine cyanogen insect amide, Mobucin and the composite control rice-leaf hopper test of pesticide effectiveness thereof
As can be seen from Table 6, can effectively prevent and treat rice-leaf hopper after bromine cyanogen insect amide and Mobucin are composite, control efficiency all is better than the preventive effect of single agent.In the test scope of medication, the target crop is had no adverse effects.
After draw through different local throughout the country tests, the preventive effects of common insect dispenser after 30 days such as bromine cyanogen insect amide and Buprofezin, meta-tolyl-N-methylcarbamate (MTMC), the composite flea beetle to all kinds of crops of Mobucin, aphid, thrips, striped rice borer, paddy stem borer, rice leaf roller, rice fulgorid, leafhopper, scale insect, phyllocnistis citrella stainton, oranges and tangerines arrowhead scales, tea lesser leafhopper are all more than 95%, be better than single agent preventive effect, synergistic effect is obvious.
Claims (6)
1. Pesticidal combination that contains the bromine cyanogen insect amide, it is characterized in that: comprise active component A and active component B, described active component A is selected from the bromine cyanogen insect amide, active component B is selected from a kind of in Buprofezin, meta-tolyl-N-methylcarbamate (MTMC), the Mobucin, and wherein the weight ratio of active component A and active component B is 60: 1～1: 80.
2. Pesticidal combination according to claim 1, it is characterized in that: the weight ratio of A, two kinds of active components of B is 40: 1～1: 60.
3. Pesticidal combination according to claim 2, it is characterized in that: the weight ratio of bromine cyanogen insect amide and Buprofezin is 10: 1～1: 40;
The weight ratio of bromine cyanogen insect amide and meta-tolyl-N-methylcarbamate (MTMC) is 10: 1～1: 40;
The weight ratio of bromine cyanogen insect amide and Mobucin is 10: 1～1: 40.
4. Pesticidal combination according to claim 1, it is characterized in that: composition is made wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspension-suspending agent.
5. be used for the application of the insect on control cereal class, vegetables, fruit tree, the cotton according to each described Pesticidal combination in the claim 1～4.
6. application according to claim 5 is characterized in that: described insect comprises flea beetle, aphid, thrips, striped rice borer, paddy stem borer, rice leaf roller, rice fulgorid, leafhopper, scale insect, phyllocnistis citrella stainton, oranges and tangerines arrowhead scales, tea lesser leafhopper.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105613535A (en) * | 2014-10-30 | 2016-06-01 | 陕西美邦农药有限公司 | Insecticidal composition containing N-(2-(tert-butylaminoformyl)-4-chloro-6-methylphenyl)-1-(3-chloropyridin-2-yl)-3-fluoromethoxy-1H-pyrazolyl-5-formamide (ZJ3757) and carbamate |
| CN105638725A (en) * | 2016-01-25 | 2016-06-08 | 北京市农林科学院 | Pesticide mixture used for preventing and treating plant virus diseases and transmission media |
| CN106070247A (en) * | 2016-06-21 | 2016-11-09 | 南京华洲药业有限公司 | A kind of brominated cyanogen insect amide and the Synergistic insecticidal compositions of Buprofezin and application thereof |
| CN114521557A (en) * | 2021-12-21 | 2022-05-24 | 上海交通大学重庆研究院 | Bird-repelling slow-release agent and preparation method and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010025870A1 (en) * | 2008-09-03 | 2010-03-11 | Bayer Cropscience Ag | Synergistic combinations of thiadiazol carbonic acid derivatives |
| CN102283205A (en) * | 2004-07-26 | 2011-12-21 | 杜邦公司 | Mixtures of anthranilamide invertebrate pest control agents |
| CN102308805A (en) * | 2011-10-19 | 2012-01-11 | 北京燕化永乐农药有限公司 | Compound pesticide |
-
2012
- 2012-03-02 CN CN2012100524883A patent/CN103283740A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102283205A (en) * | 2004-07-26 | 2011-12-21 | 杜邦公司 | Mixtures of anthranilamide invertebrate pest control agents |
| WO2010025870A1 (en) * | 2008-09-03 | 2010-03-11 | Bayer Cropscience Ag | Synergistic combinations of thiadiazol carbonic acid derivatives |
| CN102308805A (en) * | 2011-10-19 | 2012-01-11 | 北京燕化永乐农药有限公司 | Compound pesticide |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105613535A (en) * | 2014-10-30 | 2016-06-01 | 陕西美邦农药有限公司 | Insecticidal composition containing N-(2-(tert-butylaminoformyl)-4-chloro-6-methylphenyl)-1-(3-chloropyridin-2-yl)-3-fluoromethoxy-1H-pyrazolyl-5-formamide (ZJ3757) and carbamate |
| CN105638725A (en) * | 2016-01-25 | 2016-06-08 | 北京市农林科学院 | Pesticide mixture used for preventing and treating plant virus diseases and transmission media |
| CN106070247A (en) * | 2016-06-21 | 2016-11-09 | 南京华洲药业有限公司 | A kind of brominated cyanogen insect amide and the Synergistic insecticidal compositions of Buprofezin and application thereof |
| CN114521557A (en) * | 2021-12-21 | 2022-05-24 | 上海交通大学重庆研究院 | Bird-repelling slow-release agent and preparation method and application thereof |
| CN114521557B (en) * | 2021-12-21 | 2023-11-24 | 上海交通大学重庆研究院 | Bird repellent sustained release agent and preparation method and application thereof |
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