CN103300011A - Insecticidal composition containing flufenzine - Google Patents
Insecticidal composition containing flufenzine Download PDFInfo
- Publication number
- CN103300011A CN103300011A CN2012100615702A CN201210061570A CN103300011A CN 103300011 A CN103300011 A CN 103300011A CN 2012100615702 A CN2012100615702 A CN 2012100615702A CN 201210061570 A CN201210061570 A CN 201210061570A CN 103300011 A CN103300011 A CN 103300011A
- Authority
- CN
- China
- Prior art keywords
- pyridaben
- fluorine mite
- mite piperazine
- propargite
- piperazine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 86
- SWBHWUYHHJCADA-UHFFFAOYSA-N 3-(2-chlorophenyl)-6-(2,6-difluorophenyl)-1,2,4,5-tetrazine Chemical compound FC1=CC=CC(F)=C1C1=NN=C(C=2C(=CC=CC=2)Cl)N=N1 SWBHWUYHHJCADA-UHFFFAOYSA-N 0.000 title abstract description 4
- 230000000749 insecticidal effect Effects 0.000 title abstract 2
- DWFZBUWUXWZWKD-UHFFFAOYSA-N pyridaben Chemical compound C1=CC(C(C)(C)C)=CC=C1CSC1=C(Cl)C(=O)N(C(C)(C)C)N=C1 DWFZBUWUXWZWKD-UHFFFAOYSA-N 0.000 claims abstract description 125
- 239000005663 Pyridaben Substances 0.000 claims abstract description 124
- ZYHMJXZULPZUED-UHFFFAOYSA-N propargite Chemical compound C1=CC(C(C)(C)C)=CC=C1OC1C(OS(=O)OCC#C)CCCC1 ZYHMJXZULPZUED-UHFFFAOYSA-N 0.000 claims abstract description 77
- ZZYSLNWGKKDOML-UHFFFAOYSA-N tebufenpyrad Chemical compound CCC1=NN(C)C(C(=O)NCC=2C=CC(=CC=2)C(C)(C)C)=C1Cl ZZYSLNWGKKDOML-UHFFFAOYSA-N 0.000 claims abstract description 65
- 239000000375 suspending agent Substances 0.000 claims abstract description 42
- 239000005658 Tebufenpyrad Substances 0.000 claims abstract description 34
- 239000000839 emulsion Substances 0.000 claims abstract description 34
- 239000000725 suspension Substances 0.000 claims abstract description 28
- 241000238631 Hexapoda Species 0.000 claims abstract description 27
- 239000003094 microcapsule Substances 0.000 claims abstract description 26
- 239000004562 water dispersible granule Substances 0.000 claims abstract description 17
- 241000209140 Triticum Species 0.000 claims abstract description 15
- 239000004530 micro-emulsion Substances 0.000 claims abstract description 13
- 235000021307 Triticum Nutrition 0.000 claims abstract description 11
- 229920000742 Cotton Polymers 0.000 claims abstract description 9
- 235000013311 vegetables Nutrition 0.000 claims abstract description 5
- 235000009024 Ceanothus sanguineus Nutrition 0.000 claims abstract description 4
- 240000003553 Leptospermum scoparium Species 0.000 claims abstract description 4
- 235000015459 Lycium barbarum Nutrition 0.000 claims abstract description 4
- 235000013399 edible fruits Nutrition 0.000 claims abstract description 4
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 claims description 310
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 157
- 229910052731 fluorine Inorganic materials 0.000 claims description 157
- 239000011737 fluorine Substances 0.000 claims description 157
- 239000000843 powder Substances 0.000 claims description 32
- 238000009736 wetting Methods 0.000 claims description 22
- 230000000361 pesticidal effect Effects 0.000 claims description 21
- 241001454293 Tetranychus urticae Species 0.000 claims description 20
- 241000607479 Yersinia pestis Species 0.000 claims description 18
- 241000344246 Tetranychus cinnabarinus Species 0.000 claims description 11
- 241000239290 Araneae Species 0.000 claims description 7
- 241000952063 Polyphagotarsonemus latus Species 0.000 claims description 7
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 7
- 241001182720 Cacopsylla pyrisuga Species 0.000 claims description 5
- 241001414720 Cicadellidae Species 0.000 claims description 5
- 241000368289 Lepidosaphes ulmi Species 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 38
- 230000002195 synergetic effect Effects 0.000 abstract description 19
- 239000000470 constituent Substances 0.000 abstract description 14
- 239000000575 pesticide Substances 0.000 abstract description 10
- 230000007613 environmental effect Effects 0.000 abstract description 4
- 241000282414 Homo sapiens Species 0.000 abstract 1
- 231100000674 Phytotoxicity Toxicity 0.000 abstract 1
- 230000003628 erosive effect Effects 0.000 abstract 1
- 230000000266 injurious effect Effects 0.000 abstract 1
- 244000144972 livestock Species 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 239000004563 wettable powder Substances 0.000 abstract 1
- -1 2-methyl-phenyl propyl Chemical group 0.000 description 37
- 239000003814 drug Substances 0.000 description 34
- 239000002131 composite material Substances 0.000 description 31
- 238000012360 testing method Methods 0.000 description 26
- 239000008367 deionised water Substances 0.000 description 25
- 229910021641 deionized water Inorganic materials 0.000 description 25
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 18
- 239000003995 emulsifying agent Substances 0.000 description 14
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 12
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- 239000013530 defoamer Substances 0.000 description 12
- 230000003449 preventive effect Effects 0.000 description 12
- 239000007859 condensation product Substances 0.000 description 11
- 150000001298 alcohols Chemical class 0.000 description 10
- 230000002528 anti-freeze Effects 0.000 description 10
- 229910052799 carbon Inorganic materials 0.000 description 10
- 239000002270 dispersing agent Substances 0.000 description 10
- 230000000694 effects Effects 0.000 description 10
- 239000000463 material Substances 0.000 description 10
- 238000000034 method Methods 0.000 description 10
- 239000002562 thickening agent Substances 0.000 description 10
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 239000000080 wetting agent Substances 0.000 description 9
- 210000000481 breast Anatomy 0.000 description 8
- 238000009313 farming Methods 0.000 description 8
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 8
- 229920001296 polysiloxane Polymers 0.000 description 8
- 239000004094 surface-active agent Substances 0.000 description 8
- 239000005995 Aluminium silicate Substances 0.000 description 7
- 206010011732 Cyst Diseases 0.000 description 7
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 7
- 241001122767 Theaceae Species 0.000 description 7
- 235000012211 aluminium silicate Nutrition 0.000 description 7
- 230000010165 autogamy Effects 0.000 description 7
- 208000031513 cyst Diseases 0.000 description 7
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 7
- 229940043264 dodecyl sulfate Drugs 0.000 description 7
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 7
- 229920002521 macromolecule Polymers 0.000 description 7
- 239000003921 oil Substances 0.000 description 7
- 235000019198 oils Nutrition 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- 235000013616 tea Nutrition 0.000 description 7
- VIESAWGOYVNHLV-UHFFFAOYSA-N 1,3-dihydropyrrol-2-one Chemical class O=C1CC=CN1 VIESAWGOYVNHLV-UHFFFAOYSA-N 0.000 description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 229940079593 drug Drugs 0.000 description 6
- 235000011187 glycerol Nutrition 0.000 description 6
- 229940051841 polyoxyethylene ether Drugs 0.000 description 6
- 229920000056 polyoxyethylene ether Polymers 0.000 description 6
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 6
- 159000000000 sodium salts Chemical class 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 231100000820 toxicity test Toxicity 0.000 description 6
- 229920001732 Lignosulfonate Polymers 0.000 description 5
- 206010067482 No adverse event Diseases 0.000 description 5
- 229910019142 PO4 Inorganic materials 0.000 description 5
- 239000004372 Polyvinyl alcohol Substances 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 5
- 239000000945 filler Substances 0.000 description 5
- 238000011835 investigation Methods 0.000 description 5
- 239000012071 phase Substances 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 5
- 239000010452 phosphate Substances 0.000 description 5
- 229920002451 polyvinyl alcohol Polymers 0.000 description 5
- 229920002545 silicone oil Polymers 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 5
- 229920001285 xanthan gum Polymers 0.000 description 5
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 description 4
- 244000215068 Acacia senegal Species 0.000 description 4
- 241000675108 Citrus tangerina Species 0.000 description 4
- 102000002322 Egg Proteins Human genes 0.000 description 4
- 108010000912 Egg Proteins Proteins 0.000 description 4
- 229920000084 Gum arabic Polymers 0.000 description 4
- 241000488581 Panonychus citri Species 0.000 description 4
- 241000488583 Panonychus ulmi Species 0.000 description 4
- 239000002202 Polyethylene glycol Substances 0.000 description 4
- 235000010489 acacia gum Nutrition 0.000 description 4
- 239000000205 acacia gum Substances 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 4
- 239000003905 agrochemical Substances 0.000 description 4
- 125000002877 alkyl aryl group Chemical group 0.000 description 4
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 4
- 239000000440 bentonite Substances 0.000 description 4
- 229910000278 bentonite Inorganic materials 0.000 description 4
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 4
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 description 4
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 235000019197 fats Nutrition 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 210000004681 ovum Anatomy 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 229920001568 phenolic resin Polymers 0.000 description 4
- 239000005011 phenolic resin Substances 0.000 description 4
- 229920001223 polyethylene glycol Polymers 0.000 description 4
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 4
- 239000003381 stabilizer Substances 0.000 description 4
- 229910021653 sulphate ion Inorganic materials 0.000 description 4
- 231100000419 toxicity Toxicity 0.000 description 4
- 230000001988 toxicity Effects 0.000 description 4
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 4
- 235000015112 vegetable and seed oil Nutrition 0.000 description 4
- 239000008158 vegetable oil Substances 0.000 description 4
- JCUDAMKYTWVICI-UHFFFAOYSA-N 4-benzyl-2,3-dimethylphenol Chemical compound C1=C(O)C(C)=C(C)C(CC=2C=CC=CC=2)=C1 JCUDAMKYTWVICI-UHFFFAOYSA-N 0.000 description 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 3
- 240000003377 Shepherdia canadensis Species 0.000 description 3
- 235000018324 Shepherdia canadensis Nutrition 0.000 description 3
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 3
- 239000000642 acaricide Substances 0.000 description 3
- 150000001266 acyl halides Chemical class 0.000 description 3
- 238000000498 ball milling Methods 0.000 description 3
- 239000004202 carbamide Substances 0.000 description 3
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 3
- 150000007942 carboxylates Chemical class 0.000 description 3
- 230000003750 conditioning effect Effects 0.000 description 3
- 239000007884 disintegrant Substances 0.000 description 3
- 231100000636 lethal dose Toxicity 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229920000609 methyl cellulose Polymers 0.000 description 3
- 239000001923 methylcellulose Substances 0.000 description 3
- 235000010981 methylcellulose Nutrition 0.000 description 3
- 239000003002 pH adjusting agent Substances 0.000 description 3
- 150000004885 piperazines Chemical class 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 239000001587 sorbitan monostearate Substances 0.000 description 3
- 235000011076 sorbitan monostearate Nutrition 0.000 description 3
- 229940035048 sorbitan monostearate Drugs 0.000 description 3
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 2
- 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 2
- 241000255789 Bombyx mori Species 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- 229920005682 EO-PO block copolymer Polymers 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 2
- 102000014171 Milk Proteins Human genes 0.000 description 2
- 108010011756 Milk Proteins Proteins 0.000 description 2
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 150000004996 alkyl benzenes Chemical class 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 2
- 235000011130 ammonium sulphate Nutrition 0.000 description 2
- 230000008485 antagonism Effects 0.000 description 2
- 239000008346 aqueous phase Substances 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000001110 calcium chloride Substances 0.000 description 2
- 229910001628 calcium chloride Inorganic materials 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 239000007957 coemulsifier Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 2
- 230000008595 infiltration Effects 0.000 description 2
- 238000001764 infiltration Methods 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 231100000225 lethality Toxicity 0.000 description 2
- 235000021239 milk protein Nutrition 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 230000000149 penetrating effect Effects 0.000 description 2
- 229920005646 polycarboxylate Polymers 0.000 description 2
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- PYODKQIVQIVELM-UHFFFAOYSA-M sodium;2,3-bis(2-methylpropyl)naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S([O-])(=O)=O)=C(CC(C)C)C(CC(C)C)=CC2=C1 PYODKQIVQIVELM-UHFFFAOYSA-M 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 230000001018 virulence Effects 0.000 description 2
- FWVCSXWHVOOTFJ-UHFFFAOYSA-N 1-(2-chloroethylsulfanyl)-2-[2-(2-chloroethylsulfanyl)ethoxy]ethane Chemical compound ClCCSCCOCCSCCCl FWVCSXWHVOOTFJ-UHFFFAOYSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 1
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 description 1
- QGHDLJAZIIFENW-UHFFFAOYSA-N 4-[1,1,1,3,3,3-hexafluoro-2-(4-hydroxy-3-prop-2-enylphenyl)propan-2-yl]-2-prop-2-enylphenol Chemical group C1=C(CC=C)C(O)=CC=C1C(C(F)(F)F)(C(F)(F)F)C1=CC=C(O)C(CC=C)=C1 QGHDLJAZIIFENW-UHFFFAOYSA-N 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- 241000207199 Citrus Species 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 241000258937 Hemiptera Species 0.000 description 1
- 238000012695 Interfacial polymerization Methods 0.000 description 1
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 1
- 241000220225 Malus Species 0.000 description 1
- 235000011430 Malus pumila Nutrition 0.000 description 1
- 235000015103 Malus silvestris Nutrition 0.000 description 1
- 239000004368 Modified starch Substances 0.000 description 1
- 229920000881 Modified starch Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 241000382353 Pupa Species 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- ITTKZVYGKKKWIY-UHFFFAOYSA-N [F].N1CCNCC1 Chemical compound [F].N1CCNCC1 ITTKZVYGKKKWIY-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000000895 acaricidal effect Effects 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- ZCILODAAHLISPY-UHFFFAOYSA-N biphenyl ether Natural products C1=C(CC=C)C(O)=CC(OC=2C(=CC(CC=C)=CC=2)O)=C1 ZCILODAAHLISPY-UHFFFAOYSA-N 0.000 description 1
- 235000011148 calcium chloride Nutrition 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 229920006184 cellulose methylcellulose Polymers 0.000 description 1
- 235000020971 citrus fruits Nutrition 0.000 description 1
- 229940125904 compound 1 Drugs 0.000 description 1
- 230000002508 compound effect Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000006184 cosolvent Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 235000019441 ethanol Nutrition 0.000 description 1
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 231100000194 ovacidal Toxicity 0.000 description 1
- 230000003151 ovacidal effect Effects 0.000 description 1
- AICOOMRHRUFYCM-ZRRPKQBOSA-N oxazine, 1 Chemical compound C([C@@H]1[C@H](C(C[C@]2(C)[C@@H]([C@H](C)N(C)C)[C@H](O)C[C@]21C)=O)CC1=CC2)C[C@H]1[C@@]1(C)[C@H]2N=C(C(C)C)OC1 AICOOMRHRUFYCM-ZRRPKQBOSA-N 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 244000144977 poultry Species 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 235000021003 saturated fats Nutrition 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000004334 sorbic acid Substances 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
- 229940075582 sorbic acid Drugs 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 238000000967 suction filtration Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses an insecticidal composition containing flufenzine. The composition is mainly characterized in that the composition contains active constituent A and active constituent B, wherein the active constituent A is flufenzine, the active constituent B is any one selected from the group consisting of pyridaben, propargite and tebufenpyrad, a weight ratio of the active constituent A to the active constituent B is 1: 80 to 80: 1, and the composition can be prepared to form a wettable powder, a water-dispersible granule, a suspending agent, a suspension emulsion, a water emulsion, a microemulsion, a microcapsule suspension and a microcapsule suspension-suspending agent. The composition provided by the invention can be used for preventing and treating a variety of injurious insects on wheat, cotton, fruit trees, vegetables and tea trees, has an obvious synergistic effect, enables the dosage of a pesticide to be reduced, is safe to human beings and livestock and has no phytotoxicity and good environmental compatibility; a preparation of the composition has enhanced adhesion and resistance to rain erosion.
Description
Technical field
The invention belongs to technical field of pesticide, relate to a kind of Pesticidal combination that contains fluorine mite piperazine.
Background technology
Fluorine mite piperazine (diflovidazin), molecular formula: C
14H
7CLF
2N
4, fluorine mite piperazine contacts the ovum and active through skin that goes out, and attracts the mite adult to take food, and also prevents and treats the acarid in pupa stage.This compound effects mechanism is unique, not only ovum and one-tenth mite is had excellent activity, and makes female mite produce unsound ovum, causes destroying the evidence of mite, simultaneously pear sucker, oystershell scale, leafhopper etc. is also had good effect, and to natural enemy and Environmental security.
Pyridaben (pyridaben), chemical name: two [three 2-methyl-phenyl propyl) tin] oxide, chemical molecular formula: C
19H
25ClN
2OS.Pyridaben is wide spectrum, tagging property miticide, can be used for preventing and treating multiple food vegetalitas evil mite, if to ovum, young mite mite with becomes mite that good effect is arranged, has equally obvious speed to kill to the one-tenth mite of mobile phase and acts on.This medicine is not acted upon by temperature changes, and no matter uses in early spring or autumn, all can reach promising result.
Propargite (propargite), chemical name: 2-(4-tert-butyl benzene oxy) cyclohexyl Propargyl sulfite, chemical molecular formula: C
19H
26O
4S.Propargite is low toxicity broad spectrum activity organosulfur acaricide, have and tag and stomach poison function, without interior suction and infiltration conduction, if to becoming the mite mite effective, the weak effect of ovicidal, this medicine temperature more than 20 ℃ under the condition drug effect can improve, but falling progressively with low temperature below 20 ℃, can be used for preventing and treating the harmful mite of the various crop such as cotton, vegetables, apple, citrus, tea, flowers, safer to most natural enemies.
Tebufenpyrad (Tebufenpyrad), chemical molecular formula: C
18H
24CLN
3O, tebufenpyrad belong to the amide-type miticide.Various mite classes and Semiptera, homoptera pest are had remarkable effect, and the mite class is all had immediate effect with efficient each vegetative period, the lasting period is long, without interior absorption, but osmotically active is arranged, and target crop is had splendid selectivity.
In the real process of agricultural production, the problem that pest control, evil mite the most easily produce is drug-fast generation.The different cultivars composition carries out composite, is control resistant insect, the very common method of evil mite.Heterogeneity is carried out composite, according to practical application effect, judge certain composite be synergy, add and or antagonism.In most cases, the composite effect of agricultural chemicals all is additive effect, and the seldom composite of synergistic effect really arranged, especially synergistic effect very obviously, co-toxicity coefficient very high composite just still less.Find through inventor's lot of experiments, after fluorine mite piperazine and pyridaben, propargite, tebufenpyrad were composite, synergistic effect was remarkable, and Environmental compatibility is fabulous, has greatly reduced the agricultural chemicals dosage.
Summary of the invention
The Pesticidal combination that the present invention proposes any one two kinds of active components, also comprises an amount of surfactant and carrier in comprising fluorine mite piperazine and pyridaben, propargite, tebufenpyrad.
A kind of Pesticidal combination that contains fluorine mite piperazine, comprise active components A, active component B, it is characterized in that: active components A is fluorine mite piperazine, and active component B is a kind of arbitrarily in pyridaben, propargite, the tebufenpyrad, and the weight ratio of active components A and active component B is 1: 80～80: 1.
Described Pesticidal combination is characterized in that: the weight ratio of active components A and active component B is 1: 60～40: 1.
Described Pesticidal combination is characterized in that: the weight ratio of fluorine mite piperazine and pyridaben is 1: 40～20: 1, is preferably 1: 20～10: 1.
Described Pesticidal combination is characterized in that: the weight ratio of fluorine mite piperazine and propargite is 1: 30～10: 1, is preferably 1: 15～5: 1.
Described Pesticidal combination is characterized in that: the weight ratio of fluorine mite piperazine and tebufenpyrad is 1: 30～10: 1, is preferably 1: 15～5: 1.
Described Pesticidal combination is characterized in that: composition is made wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspension-suspending agent.
Described Pesticidal combination is used for the application of insect on control wheat, cotton, fruit tree, vegetables, the tea tree.
Described pest control comprises: two spotted spider mite, yellow spider, blister mite, rust mite, yellow tea mite, Tetranychus cinnabarinus, Tetranychus urticae, wheat leaf pawl mite, pear sucker, oystershell scale, leafhopper.
At least comprise a kind of surfactant in the Pesticidal combination of the present invention, the dispersion of active component in water when being beneficial to use.Surface-active contents is 5%～30% of total formulation weight amount, and surplus is solid or liquid diluent.The selected surfactant of Pesticidal combination of the present invention is known in those skilled in the art: can be selected from one or more in dispersant, wetting agent, emulsifier or the defoamer.
Comprise following constituent content when making wetting powder: active components A 1%～80%, active component B 1%～80%, dispersant 5%～10%, wetting agent 2%～10%, filler surplus.
Active components A, active component B, dispersant, wetting agent, filler are mixed, in mixed cylinder, mix, after airslide disintegrating mill is pulverized, mix again, namely can be made into wetting powder product of the present invention.
When making water dispersible granules, composition comprises following constituent content: active components A 1%～80%, active component B 1%～80%, dispersant 3%～12%, wetting agent 1%～8%, disintegrant 1%～10%, binding agent 0～8%, filler surplus.
Active components A, active component B, dispersant, wetting agent, disintegrant, filler etc. are obtained together the particle diameter of needs through air-flow crushing, obtain the materials of granulating.With item quantitatively send in the fluidized bed granulation dryer through granulation and drying after, make water dispersible granules product of the present invention.
Comprise following constituent content when composition is made suspending agent: active components A 1%～60%, active component B 1%～60%, dispersant 2～10%, wetting agent 2～10%, defoamer 0.1～2%, thickener 0.05～2%, antifreeze 0～8%, deionized water add to 100%.
Dispersant, wetting agent, defoamer, thickener, antifreeze, emulsifier in the above-mentioned formulation material are mixed through high speed shear, add active components A, active component B ball milling 2～3 hours in ball mill, make diameter of particle all below 5 μ m, make suspending agent product of the present invention.
Comprise following constituent content when composition is made suspension emulsion: active components A 1%～60%, active component B 1%～60%, emulsifier 2%～12%, dispersant 2%～10%, defoamer 0.1%～2%, thickener 0.05%～1%, antifreeze 0%～8%, stabilizing agent 0%～5%, deionized water add to 100%.
Dispersant, defoamer, thickener, antifreeze, stabilizing agent in the above-mentioned formulation material are mixed through high speed shear, add the former medicine of active components A, ball milling is 2～3 hours in ball mill, make diameter of particle all below 5 μ m, make the active components A suspending agent, then with the former medicine of active component B, emulsifier and various auxiliary agent with the direct emulsification of high speed agitator in suspending agent, make suspension emulsion product of the present invention.
Comprise following constituent content when composition is made aqueous emulsion: property composition A1%～60%, active component B 1%～60%, solvent 0%～30%, emulsifier 1%～15%, antifreeze 0%～10%, thickener 0%～2%, defoamer 0.01%～2%, deionized water are supplied surplus while still alive.
Above-mentioned prescription is mixed, active ingredient, solvent, emulsifier, co-emulsifier are added together, make to be dissolved into even oil phase; Water, antifreeze, thickener, defoamer are mixed, become the homogeneous water.Under high-speed stirred, water is added oil phase, make aqueous emulsion product of the present invention.
Comprise following constituent content active components A 1%～60%, active component B 1%～60%, solvent 0%～30%, emulsifier 3%～20%, co-emulsifier 0%～12%, antifreeze 0%～10%, defoamer 0.01%～2%, stabilizing agent 0%～4% when composition is made microemulsion, deionized water is supplied surplus.
Active components A and the former medicine of active component B are dissolved in the homogenizer that solvent and cosolvent are housed; Strongly mix after joining emulsifier, stabilizing agent and antifreeze, water in the homogenizer that mentioned solution is housed and homogenize, obtain at last the as clear as crystal microemulsion product of the present invention of outward appearance.
Composition is made micro-capsule suspension and is comprised following constituent content: active components A 1%～60%, active component B 1%～60%, macromolecule cyst material 1%～12%, surfactant 2%～10%, organic solvent 1%～15%, emulsifier 1%～8%, pH adjusting agent 0.1%～5%, deionized water adds to 100%.
The macromolecule cyst material is added the PH conditioning agent be heated to uniform temperature, obtain thick liquid, then thin up forms stable prepolymer solution, active component B, active components A are dissolved in the organic solvent, be added to again in the prepolymer solution, add emulsifier, surfactant, and fully shear agitation is dispersed into superfine microgranular, add again the PH conditioning agent, and heat up, the catalysis polycondensation forms the microcapsules of firm difficult infiltration, makes micro-capsule suspension of the present invention.
When the formulation of composition was microcapsules suspension-suspending agent, the auxiliary agent of interpolation was that surfactant, emulsifier, solvent, PH conditioning agent, macromolecule cyst material, defoamer, thickener, water add to 100%.
Composition comprises following constituent content when making microcapsule suspension-suspending agent: active components A 1%～60%, active component B 1%～60%, macromolecule cyst material 2%～12%, surfactant 3%～15%, organic solvent 1%～5%, emulsifier 1%～6%, defoamer 0.1%～5%, thickener 0.05%～2%, pH adjusting agent 0.1%～5%, water add to 100%.
Adopt interfacial polymerization, to there be active component B, macromolecule cyst material, organic solvent to mix in the above-mentioned prescription, make and be dissolved into even oil phase, under shearing condition, join oil phase in the aqueous phase solution that comprises emulsifier, pH adjusting agent, bi-material reacts at oil-water interfaces, form the macromolecule cyst wall around the drop that comprises chemical substance, make active component B micro-capsule suspension.Surfactant, defoamer, thickener, antifreeze are mixed through high speed shear, add the former medicine of active components A, ball milling is 2～3 hours in ball mill, make diameter of particle all below 5 μ m, make the active components A suspending agent, then will be dissolved in active components A suspending agent stable in the water and join in the aqueous phase solution of active component B micro-capsule suspension, make the finely disseminated microcapsule suspension of the present composition-suspending agent product.
Described dispersant is selected from: alkylnaphthalene sulfonate, two (alkyl) naphthalenesulfonate formaldehyde condensation compound, naphthalene sulfonic acid-formaldehyde condensation product, aryl phenol polyoxyethylene succinate sulfonate, octylphenol polyethylene oxyethylene group ether sulfate, polycarboxylate, lignosulfonates, the phonetic formaldehyde condensation products sulphate of alkylphenol-polyethenoxy, alkyl benzene sulfonate calcium salt, the naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol-polyethenoxy is phonetic, aliphatic amine polyoxyethylene is phonetic, polyoxyethylene carboxylate, during the ester polyoxyethylene is phonetic one or more.
Described wetting agent is selected from: lauryl sodium sulfate, neopelex, Nekal BX, washing powder, farming breast 2000
#Series, sldium lauryl sulfate, wetting and penetrating agent F, wetting agent T, spaonin powder, tea are withered, in the silkworm excrement, soapberry powder one or more.
Described disintegrant is selected from: one or more in bentonite, urea, ammonium sulfate, aluminium chloride, the glucose.
Described emulsifier is selected from: farming breast 500
#(alkyl benzene calcium sulfonate), OP series phosphate (polyoxyethylene nonylphenol ether phosphate), 600
#Phosphate (phenyl phenol polyoxy ethyl ether phosphate), styrene polyoxyethylene ether ammonium sulfate salt, alkyl biphenyl ether disulfonic acid magnesium salts, triethanolamine salt, farming breast 400
#(benzyl dimethyl phenol polyoxy ethyl ether), farming breast 600
#(phenyl phenol polyoxy ethyl ether), Nongru-700
#(alkylphenol-formaldehyde resin polyoxy ethyl ether), farming breast 36
#(phenethyl fluosite polyoxy ethyl ether), farming breast 1600
#(phenethyl phenol polyoxy ethyl polypropylene-base ether), ethylene oxide-propylene oxide block copolymer, OP series (polyoxyethylene nonylphenol ether), By series (castor oil polyoxyethylene ether), farming breast 33
#(alkylaryl polyoxyethylene polyoxypropylene ether), farming breast 34
#In (alkylaryl polyoxyethylene poly-oxygen propylene aether), sapn series (sorbitan monostearate), tween series (sorbitan fatty acid ester APEO), the EO series (the pure APEO of fat) one or more.
Described antifreeze is selected from: one or more in ethylene glycol, propane diols, glycerine, the polyethylene glycol.
Described defoamer is selected from: silicone, C
8～10Aliphatic alcohols, C
10～20In saturated fat acids (such as capric acid) and acid amides, silicone oil, the silicone compound one or more.
Described thickener is selected from: one or more in xanthans, CMC, hydroxyethylcellulose, methylcellulose, Magnesiumaluminumsilicate, the polyvinyl alcohol.
Macromolecule cyst material choosing: one or more in urea, formaldehyde, PIC, polyfunctional group acyl halide polyamines, polyfunctional group acyl halide dihydroxylic alcohols, sodium alginate, polyvinyl alcohol, gelatin, gum Arabic, sucrose, modified starch, maltose, distortion milk protein, glycerine, calcium chloride, carboxymethyl cellulose, beta-schardinger dextrin-.
Described filler is selected from: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, precipitated calcium carbonate, the vegetable oil.
Wetting powder the key technical indexes of the present invention:
Water dispersible granules the key technical indexes of the present invention:
Suspending agent the key technical indexes of the present invention:
Suspension emulsion the key technical indexes of the present invention:
Aqueous emulsion the key technical indexes of the present invention:
Microemulsion the key technical indexes of the present invention:
Microcapsule suspending agent the key technical indexes of the present invention:
Microcapsule suspension of the present invention-suspending agent the key technical indexes:
The invention has the advantages that:
(1) fluorine mite piperazine and pyridaben, propargite, tebufenpyrad composite after, have notable synergistic and lasting effect;
(2) enlarged control spectrum, the two spotted spider mite of wheat, cotton, fruit tree, vegetables, tea tree, yellow spider, blister mite, rust mite, yellow tea mite, Tetranychus cinnabarinus, Tetranychus urticae, wheat leaf pawl mite, pear sucker, oystershell scale, leafhopper etc. have all been had greater activity;
(3) reduce the dosage of agricultural chemicals, reduced the residual quantity of agricultural chemicals on crop, alleviated environmental pollution;
(4) to the person poultry safety, Environmental compatibility is good, is difficult for developing immunity to drugs.
Embodiment
To further instruction of the present invention, the percentage among the embodiment all is weight percentage below in conjunction with embodiment, but the present invention is not limited thereto.
Application Example one
Embodiment 181% fluorine mite piperazine pyridaben wetting powder
Fluorine mite piperazine 1%, pyridaben 80%, alkylnaphthalene sulfonate 5%, spaonin powder 3%, kaolin add to 100%, and mixture carries out air-flow crushing, make 81% fluorine mite piperazine pyridaben wetting powder.
With effective active composition pyridaben be changed to propargite, tebufenpyrad forms new embodiment.
Embodiment 260% fluorine mite piperazine pyridaben wetting powder
Fluorine mite piperazine 10%, pyridaben 50%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6%, lauryl sodium sulfate 4%, bentonite add to 100%, and mixture carries out air-flow crushing, make 60% fluorine mite piperazine pyridaben wetting powder.
With effective active composition pyridaben be changed to propargite, tebufenpyrad forms new embodiment.
Embodiment 345% fluorine mite piperazine pyridaben wetting powder
Fluorine mite piperazine 15%, pyridaben 30%, aliphatic alcohol polyethenoxy base ether 8%, sldium lauryl sulfate 3%, kaolin add to 100%, and mixture carries out air-flow crushing, make 45% fluorine mite piperazine pyridaben wetting powder.
With effective active composition pyridaben be changed to propargite, tebufenpyrad forms new embodiment.
Embodiment 461% fluorine mite piperazine pyridaben wetting powder
Fluorine mite piperazine 1%, pyridaben 60%, lignosulfonates 5%, Nekal BX 4%, kaolin add to 100%, and mixture carries out air-flow crushing, make 61% fluorine mite piperazine pyridaben wetting powder.
With effective active composition pyridaben be changed to propargite, tebufenpyrad forms new embodiment.
Embodiment 581% fluorine mite piperazine pyridaben water dispersible granules
Fluorine mite piperazine 80%, pyridaben 1%, alkylphenol-polyethenoxy are phonetic 6%, wetting and penetrating agent F5%, urea 2%, white carbon add to 100%, mix making 81% fluorine mite piperazine pyridaben water dispersible granules.
With effective active composition pyridaben be changed to propargite, tebufenpyrad forms new embodiment.
Embodiment 660% fluorine mite piperazine pyridaben water dispersible granules
Fluorine mite piperazine 20%, pyridaben 40%, sldium lauryl sulfate 4%, aryl phenol polyoxyethylene succinate sulfonate 7%, bentonite 2%, kaolin add to 100%, mix to make 60% fluorine mite piperazine pyridaben water dispersible granules.
With effective active composition pyridaben be changed to propargite, tebufenpyrad forms new embodiment.
Embodiment 740% fluorine mite piperazine pyridaben water dispersible granules
Fluorine mite piperazine 10%, pyridaben 30%, the phonetic formaldehyde condensation products sulphate 6% of alkylphenol-polyethenoxy, spaonin powder 5%, aluminium chloride 2%, diatomite add to 100%, mix to make 40% fluorine mite piperazine pyridaben water dispersible granules.
With effective active composition pyridaben be changed to propargite, tebufenpyrad forms new embodiment.
Embodiment 855% fluorine mite piperazine pyridaben water dispersible granules
Fluorine mite piperazine 5%, pyridaben 50%, tea are withered 4%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 7%, ammonium sulfate 2%, precipitated calcium carbonate add to 100%, mix making 55% fluorine mite piperazine pyridaben water dispersible granules.
With effective active composition pyridaben be changed to propargite, tebufenpyrad forms new embodiment.
Embodiment 945% fluorine mite piperazine Damanling suspension agent
Fluorine mite piperazine 15%, pyridaben 30%, polycarboxylate 5%, neopelex 4%, C
8～10Aliphatic alcohols 1.6%, phenolic resins 0.12%, ethylene glycol 1.2%, deionized water add to 100%, mix to make 45% fluorine mite piperazine Damanling suspension agent.
With effective active composition pyridaben be changed to propargite, tebufenpyrad forms new embodiment.
Embodiment 1030% fluorine mite piperazine Damanling suspension agent
Fluorine mite piperazine 10%, pyridaben 20%, polyoxyethylene carboxylate 6%, tea are withered 4%, silicone oil 1.2%, xanthans 0.14%, glycerine 0.8%, deionized water add to 100%, mix making 30% fluorine mite piperazine Damanling suspension agent.
With effective active composition pyridaben be changed to propargite, tebufenpyrad forms new embodiment.
Embodiment 1120% fluorine mite piperazine Damanling suspension agent
Fluorine mite piperazine 5%, pyridaben 15%, aliphatic alcohol polyethenoxy base ether 6%, soapberry powder 3%, C
10～20Saturated fat acids 2.5%, xanthans 0.09%, propane diols 1%, deionized water add to 100%, mix to make 20% fluorine mite piperazine Damanling suspension agent.
With effective active composition pyridaben be changed to propargite, tebufenpyrad forms new embodiment.
Embodiment 1211% fluorine mite piperazine Damanling suspension agent
Fluorine mite piperazine 10%, pyridaben 1%, the phonetic formaldehyde condensation products sulphate 6% of alkylphenol-polyethenoxy, spaonin powder 4%, silicone 1.4%, hydroxyethylcellulose 0.12%, deionized water add to 100%, mix to make 11% fluorine mite piperazine Damanling suspension agent.
With effective active composition pyridaben be changed to propargite, tebufenpyrad forms new embodiment.
Embodiment 1350% fluorine mite piperazine pyridaben suspension emulsion
Fluorine mite piperazine 20%, pyridaben 30%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 5%, silkworm excrement 5%, polyoxyethylene nonylphenol ether phosphate 6%, propyl alcohol 5%, C
8～10Aliphatic alcohols 1%, polyvinyl alcohol 0.08%, polyethylene glycol 1.8%, deionized water add to 100%, mix to make 50% fluorine mite piperazine pyridaben suspension emulsion.
With effective active composition pyridaben be changed to propargite, tebufenpyrad forms new embodiment.
Embodiment 1441% fluorine mite piperazine pyridaben suspension emulsion
Fluorine mite piperazine 1%, pyridaben 40%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 5%, tea are withered 4%, ethylene oxide-propylene oxide block copolymer 6%, butyl ether 5%, C
8～10Aliphatic alcohols 1.2%, methylcellulose 0.15%, propane diols 1.6%, deionized water add to 100%, mix to make 41% fluorine mite piperazine pyridaben suspension emulsion.
With effective active composition pyridaben be changed to propargite, tebufenpyrad forms new embodiment.
Embodiment 1525% fluorine mite piperazine pyridaben suspension emulsion
Fluorine mite piperazine 10%, pyridaben 15%, lignosulfonates 6.5%, sldium lauryl sulfate 4%, sorbitan fatty acid ester APEO 2%, N-pyrrolidones 5%, C
8～10Aliphatic alcohols 0.9%, propane diols 1.5%, polyvinyl alcohol 0.19%, deionized water add to 100%, mix to make 25% fluorine mite piperazine pyridaben suspension emulsion.
With effective active composition pyridaben be changed to propargite, tebufenpyrad forms new embodiment.
Embodiment 1625% fluorine mite piperazine pyridaben suspension emulsion
Fluorine mite piperazine 5%, pyridaben 20%, phenyl phenol polyoxy ethyl ether phosphate 4%, sldium lauryl sulfate 4%, alkylphenol-polyethenoxy are phonetic 6%, N-pyrrolidones 5%, silicone oil 0.8%, phenolic resins 0.17%, ethylene glycol 1.6%, deionized water add to 100%, mix making 25% fluorine mite piperazine pyridaben suspension emulsion.
With effective active composition pyridaben be changed to propargite, tebufenpyrad forms new embodiment.
Embodiment 1741% fluorine mite piperazine pyridaben micro-emulsion
Fluorine mite piperazine 40%, pyridaben 1%, alkylphenol-formaldehyde resin polyoxy ethyl ether 7%, toluene 4%, glycerine 1%, sodium phosphate trimer 0.18%, silicone oil 1.2%, BHT 2%, and deionized water supplies 100%, mixes to make 41% fluorine mite piperazine pyridaben micro-emulsion.
With effective active composition pyridaben be changed to propargite, tebufenpyrad forms new embodiment.
Embodiment 1830% fluorine mite piperazine pyridaben micro-emulsion
Fluorine mite piperazine 5%, pyridaben 30%, N-pyrrolidones 6%, gum Arabic 0.2%, styrene polyoxyethylene ether ammonium sulfate salt 7%, C
8～10Aliphatic alcohols 1.4%, triphenyl phosphite 1.5%, deionized water supplies 100%, makes 30% fluorine mite piperazine pyridaben micro-emulsion.
With effective active composition pyridaben be changed to propargite, tebufenpyrad forms new embodiment.
Embodiment 1942% fluorine mite piperazine pyridaben aqueous emulsion
Fluorine mite piperazine 2%, pyridaben 40%, cyclohexanone 3%, vegetable oil 4%, alkylphenol-formaldehyde resin polyoxy ethyl ether 6%, xanthans 0.18%, silicone 0.8%, deionized water adds to 100%, mixes to make 42% fluorine mite piperazine pyridaben aqueous emulsion.
With effective active composition pyridaben be changed to propargite, tebufenpyrad forms new embodiment.
Embodiment 2040% fluorine mite piperazine pyridaben aqueous emulsion
Fluorine mite piperazine 5%, pyridaben 35%, ethyl acetate 3.5%, N-pyrrolidones 5.5%, styrene polyoxyethylene ether ammonium sulfate salt 7%, polyethylene glycol 0.12%, silicone compound 1%, deionized water adds to 100%, makes 40% fluorine mite piperazine pyridaben aqueous emulsion through mixing.
With effective active composition pyridaben be changed to propargite, tebufenpyrad forms new embodiment.
Embodiment 2130% fluorine mite piperazine pyridaben aqueous emulsion
Fluorine mite piperazine 15%, pyridaben 15%, N-pyrrolidones 5%, cyclohexanone 5%, alkylaryl polyoxyethylene poly-oxygen propylene aether 6%, polyethylene glycol 2%, CMC 0.14%, C
8～10Aliphatic alcohols 0.6%, deionized water adds to 100%, mixes to make 30% fluorine mite piperazine pyridaben aqueous emulsion.
With effective active composition pyridaben be changed to propargite, tebufenpyrad forms new embodiment.
Embodiment 2225% fluorine mite piperazine pyridaben aqueous emulsion
Fluorine mite piperazine 15%, pyridaben 10%, toluene 7%, phenethyl fluosite polyoxy ethyl ether 8%, gum Arabic 0.22%, C
8～10Aliphatic alcohols 1.2%, deionized water adds to 100%, makes 25% fluorine mite piperazine pyridaben aqueous emulsion through mixing.
With effective active composition pyridaben be changed to propargite, tebufenpyrad forms new embodiment.
Embodiment 2331% fluorine mite piperazine pyridaben micro-capsule suspension
Fluorine mite piperazine 1%, pyridaben 30%, PIC 3%, polyvinyl alcohol 2%, spaonin powder 5%, lignosulfonates 2.4%, toluene 6%, water Span APEO 5%, citric acid 0.5%, sodium hydroxide 0.6%, deionized water add to 100% weight portion, make 31% fluorine mite piperazine pyridaben micro-capsule suspension.
With effective active composition pyridaben be changed to propargite, tebufenpyrad forms new embodiment.
Embodiment 2421% fluorine mite piperazine pyridaben microcapsule suspension-suspending agent
Fluorine mite piperazine 20%, pyridaben 1%, glycerine 5%, distortion milk protein 2%, spaonin powder 2.5%, ethyl acetate 7%, benzyl dimethyl phenol polyoxy ethyl ether 5%, sorbitan monostearate 3%, silicone 0.6%, gum Arabic 1.2%, sodium hydroxide 0.4%, citric acid 0.8%, water add to 100% weight portion, make 21% fluorine mite piperazine pyridaben microcapsule suspension-suspending agent.
With effective active composition pyridaben be changed to propargite, tebufenpyrad forms new embodiment.
Embodiment 2540% fluorine mite piperazine tebufenpyrad wetting powder
Fluorine mite piperazine 20%, tebufenpyrad 20%, lignosulfonates 6%, spaonin powder 5%, kaolin add to 100%, and mixture carries out air-flow crushing, make 40% fluorine mite piperazine tebufenpyrad wetting powder.
With effective active composition tebufenpyrad be changed to propargite, pyridaben forms new embodiment.
Embodiment 2650% fluorine mite piperazine tebufenpyrad water dispersible granules
Fluorine mite piperazine 10%, tebufenpyrad 40%, tea are withered 4%, polyoxyethylene carboxylate 7%, sodium bicarbonate 2%, white carbon add to 100%, mix making 50% fluorine mite piperazine tebufenpyrad water dispersible granules.
With effective active composition tebufenpyrad be changed to pyridaben, propargite forms new embodiment.
Embodiment 2740% fluorine mite piperazine propargite suspending agent
Fluorine mite piperazine 10%, propargite 30%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 7%, sldium lauryl sulfate 3%, C
10～20Saturated fat acids 1.6%, methylcellulose 0.16%, deionized water add to 100%, mix to make 40% fluorine mite piperazine propargite suspending agent.
With effective active composition propargite be changed to pyridaben, tebufenpyrad forms new embodiment.
Embodiment 2820% fluorine mite piperazine propargite suspension emulsion
Fluorine mite piperazine 5%, propargite 15%, alkylphenol-polyethenoxy are phonetic 6%, soapberry powder 4%, polyoxyethylene nonylphenol ether phosphate 6%, propyl alcohol 5%, C
10～20Saturated fat acids 1%, phenolic resins 0.12%, glycerine 1.5%, deionized water add to 100%, mix to make 20% fluorine mite piperazine propargite suspension emulsion.
With effective active composition propargite be changed to pyridaben, tebufenpyrad forms new embodiment.
Embodiment 2920% fluorine mite piperazine propargite microemulsion
Fluorine mite piperazine 10%, propargite 10%, N-pyrrolidones 6%, phenolic resins 0.2%, sorbitan monostearate 7%, silicone compound 1.4%, triphenyl phosphite 1.5%, deionized water supplies 100%, makes 20% fluorine mite piperazine propargite microemulsion.
With effective active composition propargite be changed to pyridaben, tebufenpyrad forms new embodiment.
Embodiment 3025% fluorine mite piperazine propargite aqueous emulsion
Fluorine mite piperazine 10%, propargite 15%, vegetable oil 5%, ethyl acetate 5%, benzyl dimethyl phenol polyoxy ethyl ether 6%, white dextrin 0.18%, silicone 0.8%, deionized water adds to 100%, mixes to make 25% fluorine mite piperazine propargite aqueous emulsion.
With effective active composition propargite be changed to pyridaben, tebufenpyrad forms new embodiment.
Embodiment 3145% fluorine mite piperazine propargite micro-capsule suspension
Fluorine mite piperazine 15%, propargite 30%, formaldehyde 3%, polyfunctional group acyl halide dihydroxylic alcohols %, spaonin powder 5%, alkylaryl APEO 2.4%, propyl alcohol 5%, fatty alcohol-polyoxyethylene ether 5%; sorbic acid 0.5%, sodium hydroxide 0.6%, deionized water add to 100% weight portion, make 45% fluorine mite piperazine propargite micro-capsule suspension.
With effective active composition propargite be changed to pyridaben, tebufenpyrad forms new embodiment.
Embodiment 3240% fluorine mite piperazine propargite microcapsule suspension-suspending agent
Fluorine mite piperazine 5%, propargite 35%, PIC 5%, calcium chloride 4%, sldium lauryl sulfate 2.6%, vegetable oil 6%, phenyl phenol polyoxy ethyl ether 4%, castor oil polyoxyethylene ether 4%, silicone oil 0.8%, xanthans 1.2%, sodium hydroxide 0.5%, hydrochloric acid 0.8%, water add to 100% weight portion, make 40% fluorine mite piperazine propargite microcapsule suspension-suspending agent.
With effective active composition propargite be changed to pyridaben, tebufenpyrad forms new embodiment.
Embodiment 3340% fluorine mite piperazine propargite wetting powder
Fluorine mite piperazine 10%, propargite 30%, the phonetic formaldehyde condensation products sulphate 6% of alkylphenol-polyethenoxy, tea are withered 5%, kaolin adds to 100%, and mixture carries out air-flow crushing, makes 40% fluorine mite piperazine propargite wetting powder.
With effective active composition propargite be changed to pyridaben, tebufenpyrad forms new embodiment.
The embodiment of the invention is the method that adopts Toxicity Determination and field trial to combine.First by Toxicity Determination, the co-toxicity coefficient (CTC) after clear and definite two kinds of medicaments are composite by a certain percentage, CTC＜80 are antagonism, and 80≤CTC≤120 are summation action, and CTC＞120 are synergistic effect, on this basis, carry out field trial again.
Test method: respectively the mother liquor of each mixed agent is diluted to five series concentration during test, places respectively beaker for subsequent use.Adopt and to soak first the method that connects worm behind the leaf, the blade of the same size that does not contact any medicament soaked in the liquid that configures behind the 5s take out, naturally dry, put into insect box, then connect for the examination larva, under 25 ℃ of conditions, raise, every processing repeats for 3 times, every to repeat used examination borer population be 50, establishes simultaneously blank, checks dead borer population in 72h, calculate lethality and corrected mortality, try to achieve virulence regression equation and calculate LC
50Value.If the contrast lethality then is considered as invalid test greater than 10%.Computing formula is as follows:
The insect corrected mortality is converted into probit value (y), and concentration for the treatment of (μ g/ml) converts logarithm value (x) to, draws virulence regression equation with method of least squares, and calculates thus the value of every kind of medicament.Calculate co-toxicity coefficient CTC according to the abundant equation of Sun Yun.Computing formula following (take fluorine mite piperazine as the standard medicament, its toxicity index is 100):
TI * the P of the theoretical toxicity index (TTI) of M=fluorine mite piperazine
Fluorine mite piperazineTI * P of+active component B
Active component B
In the formula: M is the mixture of different proportionings;
P
Active component BBe active component B shared ratio in composition;
P
Fluorine mite piperazineBe fluorine mite piperazine shared ratio in composition.
Annotate: active component B is propargite, pyridaben. a kind of arbitrarily in the tebufenpyrad.
Application Example two:
For trying insect: two spotted spider mite.
Experimental scheme: effective lethal concentration scope of determining fluorine mite piperazine, the former medicine of pyridaben and the two different proportioning mixture through preliminary experiment.
Toxicity test result one
Table 1 fluorine mite piperazine proportionings different from pyridaben are to the toxicity test of two spotted spider mite
As shown in Table 1, the composite control of fluorine mite piperazine and pyridaben two spotted spider mite fit at 80: 1 to 1: 80 o'clock, co-toxicity coefficient is all greater than 120, illustrating that both were mixed in the scope at 80: 1 to 1: 80 all shows synergistic effect, especially when fluorine mite piperazine and pyridaben get proportioning at 10: 1 to 1: 20, synergistic effect is more obviously outstanding, co-toxicity coefficient maximum when fluorine mite piperazine and pyridaben weight ratio are 1: 2 wherein, and synergistic effect is the most obvious.Find simultaneously, fluorine mite piperazine and pyridaben proportioning were at 10: 1,9: 1,8: 1,7: 1,6: 1,5: 1,4: 1,3: 1,2: 1,1: 1,1: 2,1: 3,1: 4,1: 5,1: 6,1: 7,1: 8,1: 9,1: 10,1: 11,1: 12,1: 13,1: 14,1: 15,1: 16,1: 17,1: 18,1: 19,1: 20 o'clock composite to two spotted spider mite, yellow spider, blister mite, rust mite, yellow tea mite, Tetranychus cinnabarinus, Tetranychus urticae, wheat leaf pawl mite, pear sucker, oystershell scale, the insects such as leafhopper also have preferably synergistic effect, and co-toxicity coefficient is all greater than 120.
Application Example three:
For trying insect: blister mite.
Experimental scheme: effective lethal concentration scope of determining fluorine mite piperazine, propargite medicine and the two different proportioning mixture through preliminary experiment.
Toxicity test result two
Table 2 fluorine mite piperazine proportionings different from propargite are to the toxicity test of blister mite
As shown in Table 2, the proportioning of the composite control blister mite of fluorine mite piperazine and propargite was at 80: 1 to 1: 80 o'clock, co-toxicity coefficient is all greater than 120, illustrating that both were mixed in the scope at 80: 1 to 1: 80 all shows synergistic effect, especially when the proportioning of fluorine mite piperazine and propargite during at 10: 1 to 1: 30, synergistic effect is more obviously outstanding, wherein co-toxicity coefficient is maximum when fluorine mite piperazine and propargite weight ratio are 1: 3, synergistic effect is the most obvious, find simultaneously, fluorine mite piperazine and propargite proportioning were at 10: 1,9: 1,8: 1,7: 1,6: 1,5: 1,4: 1,3: 1,2: 1,1: 1,1: 2,1: 3,1: 4,1: 5,1: 6,1: 7,1: 8,1: 9,1: 10,1: 11,1: 12,1: 13,1: 14,1: 15,1: 16,1: 17,1: 18,1: 19,1: 20,1: 21,1: 22,1: 23,1: 24,1: 25,1: 26,1: 27,1: 28,1: 29,1: 30 o'clock composite to two spotted spider mite, yellow spider, blister mite, rust mite, yellow tea mite, Tetranychus cinnabarinus, Tetranychus urticae, the insects such as wheat leaf pawl mite also have preferably synergistic effect, and co-toxicity coefficient is all greater than 120.
Application Example four:
For trying insect: Tetranychus urticae.
Experimental scheme: effective lethal concentration scope of determining fluorine mite piperazine, the former medicine of tebufenpyrad and the two different proportioning mixture through preliminary experiment.
Toxicity test result three
Table 3 fluorine mite piperazine proportionings different from tebufenpyrad are to the toxicity test of Tetranychus urticae
As shown in Table 3, the proportioning of the composite control Tetranychus urticae of fluorine mite piperazine and tebufenpyrad was at 80: 1 to 1: 80 o'clock, co-toxicity coefficient is all greater than 120, illustrating that both were mixed in the scope at 80: 1 to 1: 80 all shows synergistic effect, especially when the proportioning of fluorine mite piperazine and tebufenpyrad during at 10: 1 to 1: 30, synergistic effect is more obviously outstanding, wherein co-toxicity coefficient is maximum when fluorine mite piperazine and tebufenpyrad weight ratio are 1: 3, synergistic effect is the most obvious, find simultaneously, fluorine mite piperazine and tebufenpyrad proportioning were at 10: 1,9: 1,8: 1,7: 1,6: 1,5: 1,4: 1,3: 1,2: 1,1: 1,1: 2,1: 3,1: 4,1: 5,1: 6,1: 7,1: 8,1: 9,1: 10,1: 11,1: 12,1: 13,1: 14,1: 15,1: 16,1: 17,1: 18,1: 19,1: 20,1: 21,1: 22,1: 23,1: 24,1: 25,1: 26,1: 27,1: 28,1: 29,1: 30 o'clock composite to two spotted spider mite, yellow spider, blister mite, rust mite, yellow tea mite, Tetranychus cinnabarinus, Tetranychus urticae, the insects such as wheat leaf pawl mite also have preferably synergistic effect, and co-toxicity coefficient is all greater than 120.
Application Example five fluorine mite piperazines and pyridaben and the composite control cotton Tetranychus cinnabarinus test of pesticide effectiveness thereof
This experimental establishment is in Weinan City Dali County, Shaanxi Province, and test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd., contrast medicament 10% fluorine mite piperazine suspending agent (autogamy), 20% pyridaben missible oil (commercial).
Conventional spray-on process is adopted in test, and investigation cotton Tetranychus cinnabarinus insect pest index in the dispenser of insect pest initial stage of origination, was investigated the insect pest indexes in 10 days, 30 days, 45 days after the dispenser and calculated preventive effect before the medicine.Experimental result is as follows:
Table 4 fluorine mite piperazine, pyridaben and the composite control cotton Tetranychus cinnabarinus test of pesticide effectiveness thereof
As can be seen from Table 4, can effectively prevent and treat the cotton Tetranychus cinnabarinus after fluorine mite piperazine and pyridaben are composite, control efficiency all is better than the preventive effect of single dose, and efficiency time is long.In the test scope of medication, the target crop is had no adverse effects.
Application Example hexafluoro mite piperazine and propargite and the composite control wheat wheat leaf pawl mite test of pesticide effectiveness thereof
This experimental establishment is in Liquan County, Xianyang, Shanxi province city, and test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd., contrast medicament 10% fluorine mite piperazine suspending agent (autogamy), 20% propargite missible oil (commercial).
Test and adopt conventional spray-on process, investigation wheat wheat leaf pawl acarid evil index in the dispenser of insect pest initial stage of origination, was investigated the insect pest indexes in 10 days, 30 days, 45 days after the dispenser and is calculated preventive effect before the medicine.Experimental result is as follows:
Table 5 fluorine mite piperazine, pyridaben and the composite control wheat wheat leaf pawl mite test of pesticide effectiveness thereof
As can be seen from Table 5, can effectively prevent and treat wheat wheat leaf pawl mite after fluorine mite piperazine and propargite are composite, control efficiency all is better than the preventive effect of single dose, and efficiency time is long.In the test scope of medication, the target crop is had no adverse effects.
Application Example seven fluorine mite piperazines and pyridaben and composite control Pesticide Effect for Apple Red Spiders thereof
This experimental establishment is at Shaanxi Province's Weinan city Linwei district, and test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd., contrast medicament 10% fluorine mite piperazine suspending agent (autogamy), 20% pyridaben missible oil (commercial).
Conventional spray-on process is adopted in test, and investigation European red mite insect pest index before the medicine in the dispenser of insect pest initial stage of origination, was investigated the insect pest indexes in 10 days, 30 days, 45 days after the dispenser and calculated preventive effect.Experimental result is as follows:
Table 6 fluorine mite piperazine, pyridaben and composite control Pesticide Effect for Apple Red Spiders thereof
As can be seen from Table 6, can effectively prevent and treat European red mite after fluorine mite piperazine and pyridaben are composite, control efficiency all is better than the preventive effect of single dose, and efficiency time is long.In the test scope of medication, the target crop is had no adverse effects.
Application Example octafluoro mite piperazine and tebufenpyrad and the composite control oranges and tangerines blister mite test of pesticide effectiveness thereof
This experimental establishment is in the Haiyan County, Jiaxing City, Zhejiang Province, and test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd., contrast medicament 10% fluorine mite piperazine suspending agent (autogamy), 20% tebufenpyrad wetting powder (autogamy).
Conventional spray-on process is adopted in test, and investigation oranges and tangerines blister mite insect pest index in the dispenser of insect pest initial stage of origination, was investigated the insect pest indexes in 10 days, 30 days, 45 days after the dispenser and calculated preventive effect before the medicine.Experimental result is as follows:
Table 7 fluorine mite piperazine, tebufenpyrad and the composite control oranges and tangerines blister mite test of pesticide effectiveness thereof
As can be seen from Table 7, can effectively prevent and treat the oranges and tangerines blister mite after fluorine mite piperazine and tebufenpyrad are composite, control efficiency all is better than the preventive effect of single dose, and efficiency time is long.In the test scope of medication, the target crop is had no adverse effects.
Application Example nine fluorine mite piperazines and propargite and the composite control citrus red mite test of pesticide effectiveness thereof
This experimental establishment is in the Haiyan County, Jiaxing City, Zhejiang Province, and test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd., contrast medicament 10% fluorine mite piperazine suspending agent (autogamy), 20% tebufenpyrad wetting powder (autogamy).
Conventional spray-on process is adopted in test, and investigation citrus red mite insect pest index before the medicine in the dispenser of insect pest initial stage of origination, was investigated the insect pest indexes in 10 days, 30 days, 45 days after the dispenser and calculated preventive effect.Experimental result is as follows:
Table 8 fluorine mite piperazine, tebufenpyrad and the composite control citrus red mite test of pesticide effectiveness thereof
As can be seen from Table 8, can effectively prevent and treat citrus red mite after fluorine mite piperazine and tebufenpyrad are composite, control efficiency all is better than the preventive effect of single dose, and efficiency time is long.In the test scope of medication, the target crop is had no adverse effects.
After draw through different local throughout the country tests, fluorine mite piperazine and pyridaben, propargite, tebufenpyrad be composite makes behind wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, the microcapsule suspension-suspending agent preventive effect of the common insects such as two spotted spider mite to all kinds of crops, yellow spider, blister mite, rust mite, yellow tea mite, Tetranychus cinnabarinus, Tetranychus urticae, wheat leaf pawl mite all more than 95%, be better than the single dose preventive effect, synergistic effect is obvious.
Claims (8)
1. Pesticidal combination that contains fluorine mite piperazine, comprise active components A, active component B, it is characterized in that: active components A is fluorine mite piperazine, and active component B is a kind of arbitrarily in pyridaben, propargite, the tebufenpyrad, and the weight ratio of active components A and active component B is 1: 80～80: 1.
2. Pesticidal combination according to claim 1, it is characterized in that: the weight ratio of active components A and active component B is 1: 60～40: 1.
3. Pesticidal combination according to claim 2, it is characterized in that: the weight ratio of fluorine mite piperazine and pyridaben is 1: 40～20: 1.
4. Pesticidal combination according to claim 2, it is characterized in that: the weight ratio of fluorine mite piperazine and propargite is 1: 30～10: 1.
5. Pesticidal combination according to claim 2, it is characterized in that: the weight ratio of fluorine mite piperazine and tebufenpyrad is 1: 30～10: 1.
6. the described Pesticidal combination of any one according to claim 1～5, it is characterized in that: composition is made wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspension-suspending agent.
7. Pesticidal combination according to claim 6 is used for the application of insect on control wheat, cotton, fruit tree, vegetables, the tea tree.
8. application according to claim 7 is characterized in that institute's pest control comprises: two spotted spider mite, yellow spider, blister mite, rust mite, yellow tea mite, Tetranychus cinnabarinus, Tetranychus urticae, wheat leaf pawl mite, pear sucker, oystershell scale, leafhopper.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210061570.2A CN103300011B (en) | 2012-03-10 | 2012-03-10 | A kind of Pesticidal combination containing fluorine mite piperazine |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210061570.2A CN103300011B (en) | 2012-03-10 | 2012-03-10 | A kind of Pesticidal combination containing fluorine mite piperazine |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103300011A true CN103300011A (en) | 2013-09-18 |
| CN103300011B CN103300011B (en) | 2016-02-17 |
Family
ID=49126078
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210061570.2A Active CN103300011B (en) | 2012-03-10 | 2012-03-10 | A kind of Pesticidal combination containing fluorine mite piperazine |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103300011B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103461347A (en) * | 2013-09-06 | 2013-12-25 | 刘波 | Pesticide composition comprising flutenzine and tebufenpyrad |
| CN105123710A (en) * | 2015-09-28 | 2015-12-09 | 陕西先农生物科技有限公司 | Pesticide composition containing flufenzine and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02160705A (en) * | 1988-12-13 | 1990-06-20 | Shionogi & Co Ltd | Suspended fluid acaricide |
| CN1156536A (en) * | 1996-02-07 | 1997-08-13 | 河北省石油化学工业研究所 | Suspension of pyridaben clofentezine compound pesticide |
| CN101485325A (en) * | 2009-02-26 | 2009-07-22 | 陕西韦尔奇作物保护有限公司 | Miticide composition containing tebufenpyrad |
| CN102325445A (en) * | 2009-02-20 | 2012-01-18 | 迪帕克·普让嘉文达斯·沙 | A kind of novel water-dispersible particulate composition |
-
2012
- 2012-03-10 CN CN201210061570.2A patent/CN103300011B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02160705A (en) * | 1988-12-13 | 1990-06-20 | Shionogi & Co Ltd | Suspended fluid acaricide |
| CN1156536A (en) * | 1996-02-07 | 1997-08-13 | 河北省石油化学工业研究所 | Suspension of pyridaben clofentezine compound pesticide |
| CN102325445A (en) * | 2009-02-20 | 2012-01-18 | 迪帕克·普让嘉文达斯·沙 | A kind of novel water-dispersible particulate composition |
| CN101485325A (en) * | 2009-02-26 | 2009-07-22 | 陕西韦尔奇作物保护有限公司 | Miticide composition containing tebufenpyrad |
Non-Patent Citations (1)
| Title |
|---|
| 王宁 等: "杀螨剂的进展与展望", 《现代农药》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103461347A (en) * | 2013-09-06 | 2013-12-25 | 刘波 | Pesticide composition comprising flutenzine and tebufenpyrad |
| CN105123710A (en) * | 2015-09-28 | 2015-12-09 | 陕西先农生物科技有限公司 | Pesticide composition containing flufenzine and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103300011B (en) | 2016-02-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103283734A (en) | Cyantraniliprole/biological-source-containing pesticidal composition | |
| CN103283744A (en) | Cyantraniliprole-containing pesticidal composition | |
| CN102396508A (en) | Novel pesticide combination containing thiamethoxam | |
| CN103283776A (en) | Cyantraniliprole-containing pesticidal composition | |
| CN103238613A (en) | Insecticidal composition containing tolfenpyrad | |
| CN102302035A (en) | Pesticide composition containing methoxyfenozide | |
| CN103300020A (en) | Pesticidal composition | |
| CN103283761B (en) | A kind of Pesticidal combination containing second worm nitrile | |
| CN103238630A (en) | Bifenazate-bearing insecticidal composition | |
| CN103250716B (en) | A kind of Pesticidal combination containing spiral shell worm ethyl ester and neires toxin | |
| CN103283743A (en) | Metaflumizone-containing pesticidal composition | |
| CN103283740A (en) | Cyantraniliprole-containing pesticidal composition | |
| CN103300011B (en) | A kind of Pesticidal combination containing fluorine mite piperazine | |
| CN103300005B (en) | A kind of Pesticidal combination containing Tolfenpyrad and neires toxin | |
| CN103828832B (en) | Insecticidal composition containing spirotetramat and organic tin | |
| CN103283738B (en) | A kind of Pesticidal combination containing spiral shell worm ethyl ester | |
| CN103355299A (en) | Insecticide composition containing pyridalyl and nereistoxin | |
| CN103300050B (en) | A kind of Pesticidal combination containing fluorine mite piperazine and organic tin | |
| CN103300034B (en) | A kind of Pesticidal combination containing second worm nitrile | |
| CN103300040B (en) | A kind of Efficient insecticidal composition | |
| CN103300033B (en) | Pesticide composition containing flutenzine | |
| CN103283741A (en) | Tolfenpyrad-containing pesticidal composition | |
| CN103250706A (en) | Insecticidal composition containing tolfenpyrad | |
| CN103283771A (en) | Cyantraniliprole/pyrethroid-containing pesticidal composition | |
| CN103300012B (en) | A kind of Pesticidal combination containing fluorine mite piperazine |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CP01 | Change in the name or title of a patent holder | ||
| CP01 | Change in the name or title of a patent holder |
Address after: 715500 Pucheng Shaanxi chemical base industrial park, Shaanxi, Weinan Patentee after: Shaanxi yitianfeng crop Technology Co.,Ltd. Address before: 715500 Pucheng Shaanxi chemical base industrial park, Shaanxi, Weinan Patentee before: Shaanxi Welch Crop Protection Co.,Ltd. |
|
| OL01 | Intention to license declared | ||
| OL01 | Intention to license declared |