CN103283744A - Cyantraniliprole-containing pesticidal composition - Google Patents
Cyantraniliprole-containing pesticidal composition Download PDFInfo
- Publication number
- CN103283744A CN103283744A CN201210050946XA CN201210050946A CN103283744A CN 103283744 A CN103283744 A CN 103283744A CN 201210050946X A CN201210050946X A CN 201210050946XA CN 201210050946 A CN201210050946 A CN 201210050946A CN 103283744 A CN103283744 A CN 103283744A
- Authority
- CN
- China
- Prior art keywords
- insect amide
- cyanogen insect
- bromine cyanogen
- active component
- capillary
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/34—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a cyantraniliprole-containing pesticidal composition. The composition is mainly characterized by containing an active component A, an active component B and the balance of assistant, wherein the active component A is cyantraniliprole, and the active component B is pymetrozine, chlorfenapyr, ethiprole, pyriproxyfen or lufenuron; the weight ratio of the active component A to the active component B is 60:1-1:60; and the composition can be prepared into wettable powder, water-dispersible granules, a suspending agent, a suspended emulsion, an aqueous emulsion, a microemulsion, a microcapsule suspending agent and a microcapsule suspending-suspending agent. The composition can prevent and treat many pests, has an obvious synergistic action and a slow-release action, reduces the pesticide consumption, is safe for human and livestock, does not have chemical injury, and has favorable environmental compatibility; and the preparation has the advantages of higher adhesive force, rainfall erosion resistance, long lasting period and the like.
Description
Technical field
The invention belongs to technical field of pesticide, relate to a kind of Pesticidal combination of brominated cyanogen insect amide.
Background technology
Bromine cyanogen insect amide (cyantraniliprole), chemical name: 4-chloro-3-ethyl-1-methyl-N-{[4-(4-methylphenoxy) phenyl]-methyl }-1H pyrazoles-5-carboxylic acid amides, the bromine cyanogen insect amide is to be E.I.Du Pont Company's second generation ryania acceptor inhibitor insecticides that success is developed after the chlorine insect amide, cyanogen insect amide is to form by the various polar groups that change on the phenyl ring, have more efficient, applicable crops is more extensive, can effectively prevent and treat Lepidoptera, Semiptera and coleopteran pest.
Yet in the real process of agricultural production, the problem that pest control is easy to generate most is the generation of pest resistance to insecticide.The different cultivars composition carries out composite, is the very common method of control resistant insect.Heterogeneity is carried out composite, according to practical application effect, judge certain composite be synergy, add and or antagonism.In most cases, the composite effect of agricultural chemicals all is additive effect, and the seldom composite of synergistic effect really arranged, especially synergistic effect very obviously, co-toxicity coefficient very high composite just still less.Test discovery in a large number through the inventor, after bromine cyanogen insect amide and pyrrole aphid ketone, capillary, second worm nitrile, pyrrole propyl ether, Acarus tritici urea were composite, synergistic effect was remarkable, and Environmental compatibility is fabulous, has greatly reduced the agricultural chemicals dosage.
Summary of the invention
The Pesticidal combination that the present invention proposes contains in bromine cyanogen insect amide and pyrrole aphid ketone, capillary, second worm nitrile, pyrrole propyl ether, the Acarus tritici urea any one two kinds of active components, and an amount of surfactant and carrier.
A kind of Pesticidal combination of brominated cyanogen insect amide, comprise active components A, active component B, the auxiliary agent surplus, it is characterized in that: active components A is the bromine cyanogen insect amide, active component B is a kind of arbitrarily in pyrrole aphid ketone, capillary, second worm nitrile, pyrrole propyl ether, the Acarus tritici urea, and the weight ratio of active components A and active component B is 60: 1～1: 60.
Described Pesticidal combination is characterized in that: the weight ratio of active components A and active component B is 40: 1～1: 40.
Described Pesticidal combination is characterized in that: the weight ratio of active components A and active component B is 20: 1～1: 20, is preferably 6: 1～1: 6.
Described Pesticidal combination is characterized in that: composition is made wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, micro-capsule-microcapsule suspending agent.
Described Pesticidal combination is used for the application of insect on control paddy rice, wheat, brassicaceous vegetable, tea tree, cotton, fruit tree, the ornamental flower.
Described insect comprises: comprise rice fulgorid, brown planthopper, small brown rice planthopper, rice leaf roller, striped rice borer, paddy stem borer, aphid, Bemisia tabaci, beet armyworm, diamond-back moth, cabbage caterpillar, leaf miner, blister mite, olethreutid, scale insect, leafhopper, tea lesser leafhopper, cotton bollworm.
At least contain a kind of surfactant in the Pesticidal combination of the present invention, the dispersion of active component in water when being beneficial to use.Surface-active contents is 5%～30% of total formulation weight amount, and surplus is solid or liquid diluent.The selected surfactant of Pesticidal combination of the present invention is known in those skilled in the art: can be selected from dispersant, wetting agent, emulsifier or the defoamer one or more.
When making wetting powder, composition comprises following constituent content: active components A 0.1%～60%, active component B 0.1%～60%, dispersant 5%～10%, wetting agent 2%～10%, filler surplus.
Active components A, active component B, dispersant, wetting agent, filler are mixed, in mixed cylinder, mix, after airslide disintegrating mill is pulverized, mix again, namely can be made into wetting powder product of the present invention.
When making water dispersible granules, composition comprises following constituent content: active components A 0.1%～60%, active component B 0.1%～60%, dispersant 3%～12%, wetting agent 1%～8%, disintegrant 1%～10%, filler surplus.
Active components A, active component B, dispersant, wetting agent, disintegrant, filler etc. are pulverized the particle diameter that obtains needs through air-flow together, obtain the materials of granulating.It is interior through after granulation and the drying to expect that product are quantitatively sent the fluidized bed granulation dryer to, makes water dispersible granules product of the present invention.
Comprise following constituent content when composition is made suspending agent: active components A 0.1%～50%, active component B 0.1%～50%, dispersant 2～10%, wetting agent 2～10%, defoamer 0.1～1%, thickener 0.1～2%, antifreeze 0.1～8%, emulsifier 0.5%～5%, water adds to 100%.
Dispersant, wetting agent, defoamer, thickener, antifreeze, emulsifier in the above-mentioned formulation material are mixed through high speed shear, add bromine cyanogen insect amide, pyrrole aphid ketone ball milling 2～3 hours in ball mill, make diameter of particle all below 5 μ m, make suspending agent product of the present invention.
Comprise following constituent content when composition is made suspension emulsion: active components A 0.1%～50%, active component B0.1%～50%, emulsifier 2%～12%, dispersant 2%～10%, defoamer 0.1%～2%, thickener 0.1%～2%, antifreeze 0.1%～8%, stabilizing agent 0.05%～3%, deionized water add to 100%.
Dispersant, defoamer, thickener, antifreeze, stabilizing agent in the above-mentioned formulation material are mixed through high speed shear, add the former medicine of bromine cyanogen insect amide, ball milling is 2～3 hours in ball mill, make diameter of particle all below 5 μ m, make bromine cyanogen insect amide suspending agent, then with the former medicine of active component B, emulsifier and various auxiliary agent with the direct emulsification of high speed agitator in suspending agent, make suspension emulsion product of the present invention.
Comprise following constituent content when composition is made aqueous emulsion: active components A 0.1%～50%, active component B 0.1%～50%, solvent 0%～30%, emulsifier 1%～15%, co-emulsifier 0%～8%, antifreeze 0%～10%, thickener 0.1%～2%, defoamer 0.01%～2%, deionized water are supplied surplus.
Above-mentioned prescription is mixed, active ingredient, solvent, emulsifier, co-emulsifier are added together, make and be dissolved into even oil phase; Water, antifreeze, thickener, defoamer are mixed, become the homogeneous water.Under high-speed stirred, water is added oil phase, make aqueous emulsion product of the present invention.
Comprise following constituent content when composition is made microemulsion: active components A 0.1%～50%, active component B0.1%～50%, solvent 0%～30%, emulsifier 3%～20%, co-emulsifier 0%～12%, antifreeze 0%～10%, thickener 0.1%～2%, defoamer 0.01%～2%, stabilizing agent 0%～4%, deionized water is supplied surplus.
Bromine cyanogen insect amide and the former medicine of active component B are dissolved in the homogenizer that solvent and cosolvent are housed; Mix strongly after joining emulsifier, stabilizing agent and antifreeze, water in the homogenizer that above-mentioned solution is housed and homogenize, obtain the as clear as crystal microemulsion product of the present invention of outward appearance at last.
Composition is made micro-capsule suspension and is comprised following constituent content: active components A 0.1%～40%, active ingredient B0.1%～50%, macromolecule cyst material 1%～12%, surfactant 2%～10%, organic solvent 1%～15%, emulsifier 1%～8%, pH conditioning agent 0.1%～5%, deionized water adds to 100%.
The macromolecule cyst material is added the PH conditioning agent be heated to uniform temperature, obtain thick liquid, thin up forms stable prepolymer solution then, active ingredient B, active components A are dissolved in the organic solvent, be added to again in the prepolymer solution, add emulsifier, surfactant, and fully shear agitation is dispersed into superfine microgranular, add the PH conditioning agent again, and heat up, the catalysis polycondensation forms the microcapsules of firm difficult infiltration, makes micro-capsule suspension of the present invention.
When the formulation of composition was microcapsules suspension-suspending agent, the auxiliary agent of interpolation was that surfactant, emulsifier, solvent, PH conditioning agent, macromolecule cyst material, defoamer, thickener, water add to 100%.
Composition comprises following constituent content when making microcapsule suspension-suspending agent: active components A 0.1%～60%, active ingredient B0.1%～60%, macromolecule cyst material 2%～12%, surfactant 3%～15%, organic solvent 1%～5%, emulsifier 1%～6%, defoamer 0.2%～5%, thickener 0.2%～5%, pH conditioning agent 0.1%～5%, water add to 100%.
Adopt interfacial polymerization, to there be active ingredient B, macromolecule cyst material, organic solvent to mix in the above-mentioned prescription, make and be dissolved into even oil phase, oil phase is joined under shearing condition in the aqueous phase solution that contains emulsifier, pH conditioning agent, two kinds of materials react at oil-water interfaces, form the macromolecule cyst wall around the drop that contains chemical substance, make active ingredient B micro-capsule suspension.Surfactant, defoamer, thickener, antifreeze are mixed through high speed shear, add the former medicine of active components A, ball milling is 2～3 hours in ball mill, make diameter of particle all below 5 μ m, make the active components A suspending agent, to be dissolved in active components A suspending agent stable in the water then and join in the aqueous phase solution of active ingredient B micro-capsule suspension, make the finely disseminated microcapsule suspension of the present composition-suspending agent product.
Described dispersant is selected from alkylnaphthalene sulfonate, two (alkyl) naphthalenesulfonate formaldehyde condensation compound, naphthalene sulfonic acid-formaldehyde condensation product, aryl phenol polyoxyethylene succinate sulfonate, octylphenol polyethylene oxyethylene group ether sulfate, polycarboxylate, lignosulfonates, the alkylaryl APEO, aliphatic alcohol polyethenoxy base ether, the phonetic formaldehyde condensation products sulphate of alkylphenol-polyethenoxy, alkyl benzene sulfonate calcium salt, the naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol-polyethenoxy is phonetic, aliphatic amine polyoxyethylene is phonetic, polyoxyethylene carboxylate, during the ester polyoxyethylene is phonetic one or more.
Described wetting agent is selected from: lauryl sodium sulfate, neopelex, Nekal BX, wetting and penetrating agent F, spaonin powder, sldium lauryl sulfate, tea are withered, in the silkworm excrement, soapberry powder one or more.
Described disintegrant is selected from: one or more in sodium bicarbonate, sodium carbonate, bentonite, urea, ammonium sulfate, glucose, the aluminium chloride.
Described thickener is selected from: one or more in CMC, hydroxyethylcellulose, Magnesiumaluminumsilicate, gelatin, melon glue, gum Arabic, xanthans, sodium phosphate trimer, phenolic resins, sodium alginate, white dextrin, methylcellulose, PAA, polyvinylpyrrolidone, crospolyvinylpyrrolidone, polyethylene glycol, the polyvinyl alcohol.
Described antifreeze is selected from: one or more in glycerine, ethylene glycol, propane diols, glycerine, diethylene glycol (DEG), triethylene glycol, the polyethylene glycol.
Described solvent is selected from: N, dinethylformamide, 3-methyl cyclohexanol ketenes, N-octylpyrrolidone, N-pyrrolidones, toluene, propyl alcohol, cyclohexanone, acetone, methyl alcohol, ethanol, butanols, ethylene glycol monomethyl ether, butyl ether, ethyl acetate, vegetable oil, acetonitrile one or more.
Described defoamer is selected from: silicone, C
8～10Aliphatic alcohols, C
0～20In saturated fat acids (as capric acid) and acid amides, silicone oil, the silicone compound one or more.
Described emulsifier is selected from: agricultural newborn 500# (alkyl benzene calcium sulfonate), OP series phosphate (polyoxyethylene nonylphenol ether phosphate), 600# phosphate (phenyl phenol polyoxy ethyl ether phosphate), styrene polyoxyethylene ether ammonium sulfate salt, alkyl biphenyl ether disulfonic acid magnesium salts, triethanolamine salt, farming newborn 400# (benzyl dimethyl phenol polyoxy ethyl ether), farming newborn 600# (phenyl phenol polyoxy ethyl ether), Nongru-700 # (alkylphenol-formaldehyde resin polyoxy ethyl ether), farming newborn 36# (phenethyl fluosite polyoxy ethyl ether), farming newborn 1600# (phenethyl phenol polyoxy ethyl polypropylene-base ether), ethylene oxide-propylene oxide block copolymer, OP series (polyoxyethylene nonylphenol ether), By series (castor oil polyoxyethylene ether), farming newborn 33# (alkylaryl polyoxyethylene polyoxypropylene ether), farming newborn 34# (alkylaryl polyoxyethylene poly-oxygen propylene aether), sapn series (sorbitan monostearate), tween series (sorbitan fatty acid ester APEO), in the AEO series (fatty alcohol-polyoxyethylene ether) one or more.
The macromolecule cyst material is selected from one or more in urea, formaldehyde, PIC, polyfunctional group acyl halide polyamines, polyfunctional group acyl halide dihydroxylic alcohols, sodium alginate, polyvinyl alcohol, gelatin, gum Arabic, sucrose, modified starch, maltose, distortion milk protein, glycerine, calcium chloride, carboxymethyl cellulose, the beta-schardinger dextrin-.
Described PH conditioning agent is selected from one or more in sodium hydroxide, hydrochloric acid, citric acid, the sorbic acid.
Described filler is selected from: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, the precipitated calcium carbonate.
Wetting powder the key technical indexes of the present invention:
Water dispersible granules the key technical indexes of the present invention:
Suspending agent the key technical indexes of the present invention:
Suspension emulsion the key technical indexes of the present invention:
Aqueous emulsion the key technical indexes of the present invention:
Microemulsion the key technical indexes of the present invention:
Microcapsule suspending agent the key technical indexes of the present invention:
Microcapsule suspension of the present invention-suspending agent the key technical indexes:
The invention has the advantages that:
(1) bromine cyanogen insect amide and pyrrole aphid ketone, capillary, second worm nitrile, pyrrole propyl ether, Acarus tritici urea, fenpropathrin composite after, have notable synergistic and lasting effect;
(2) enlarged insecticidal spectrum, insects such as the rice fulgorid on paddy rice, wheat, brassicaceous vegetable, tea tree, cotton, fruit tree, the ornamental flower, brown planthopper, small brown rice planthopper, rice leaf roller, striped rice borer, paddy stem borer, aphid, Bemisia tabaci, beet armyworm, diamond-back moth, cabbage caterpillar, leaf miner, blister mite, olethreutid, scale insect, leafhopper, tea lesser leafhopper, cotton bollworm have all been had greater activity;
(3) reduce the dosage of agricultural chemicals, reduced the residual quantity of agricultural chemicals on crop, alleviated environmental pollution;
(4) to the person poultry safety, Environmental compatibility is good, and insect is difficult for developing immunity to drugs.
Embodiment
Below in conjunction with the further instruction of the present invention of embodiment, the percentage among the embodiment all is weight percentage, but the present invention is not limited thereto.
Application Example one
Embodiment 140% bromine cyanogen insect amide pyrrole aphid ketone wetting powder
Bromine cyanogen insect amide 10%, pyrrole aphid ketone 30%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 5%, tea are withered 4%, starch adds to 100%, and mixture carries out air-flow to be pulverized, and makes 40% bromine cyanogen insect amide pyrrole aphid ketone wetting powder.
Embodiment 250% bromine cyanogen insect amide pyrrole aphid ketone wetting powder
Bromine cyanogen insect amide 25%, pyrrole aphid ketone 25%, alkyl benzene sulfonate calcium salt 6%, Nekal BX 5%, bentonite add to 100%, and mixture carries out air-flow to be pulverized, and makes 50% bromine cyanogen insect amide pyrrole aphid ketone wetting powder.
Embodiment 361% bromine cyanogen insect amide pyrrole aphid ketone wetting powder
Bromine cyanogen insect amide 1%, pyrrole aphid ketone 60%, aliphatic amine polyoxyethylene are phonetic 7%, lauryl sodium sulfate 4%, white carbon add to 100%, and mixture carries out air-flow to be pulverized, and makes 61% bromine cyanogen insect amide pyrrole aphid ketone wetting powder.
Embodiment 430% bromine cyanogen insect amide capillary wetting powder
Bromine cyanogen insect amide 10%, capillary 20%, alkylnaphthalene sulfonate 8%, neopelex 5%, diatomite add to 100%, and mixture carries out air-flow to be pulverized, and makes 30% bromine cyanogen insect amide capillary wetting powder.
Embodiment 555% bromine cyanogen insect amide capillary wetting powder
Bromine cyanogen insect amide 5%, capillary 50%, lignosulfonates 5%, soapberry powder 4%, attapulgite add to 100%, and mixture carries out air-flow to be pulverized, and makes 55% bromine cyanogen insect amide capillary wetting powder.
Embodiment 661% bromine cyanogen insect amide capillary wetting powder
Bromine cyanogen insect amide 1%, capillary 60%, polycarboxylate 8%, sldium lauryl sulfate 6%, diatomite add to 100%, and mixture carries out air-flow to be pulverized, and makes 61% bromine cyanogen insect amide capillary wetting powder.
Embodiment 720% bromine cyanogen insect amide pymetrozine water dispersing granule
Bromine cyanogen insect amide 15%, pyrrole aphid ketone 5%, the phonetic formaldehyde condensation products sulphate 7% of alkylphenol-polyethenoxy, silkworm excrement 5%, sodium carbonate 2%, kaolin add to 100%, the mixed 20% bromine cyanogen insect amide pymetrozine water dispersing granule that gets.
Embodiment 860% bromine cyanogen insect amide pymetrozine water dispersing granule
Bromine cyanogen insect amide 20%, pyrrole aphid ketone 40%, polyoxyethylene carboxylate 7.2%, wetting and penetrating agent F 5.6%, ammonium sulfate 2.8%, bentonite add to 100%, the mixed 60% bromine cyanogen insect amide pymetrozine water dispersing granule that gets.
Embodiment 970% bromine cyanogen insect amide pymetrozine water dispersing granule
Bromine cyanogen insect amide 60%, pyrrole aphid ketone 10%, ester polyoxyethylene are phonetic 5%, Nekal BX 5%, sodium bicarbonate 3%, diatomite add to 100%, mixed 70% bromine cyanogen insect amide pymetrozine water dispersing granule.
Embodiment 1020% bromine cyanogen insect amide acarid nitrile water dispersion granula
Bromine cyanogen insect amide 10%, capillary 10%, naphthalene sulfonic acid-formaldehyde condensation product 7%, lauryl sodium sulfate 4%, aluminium chloride 2%, bentonite add to 100%, the mixed 20% bromine cyanogen insect amide acarid nitrile water dispersion granula that gets.
Embodiment 1145% bromine cyanogen insect amide acarid nitrile water dispersion granula
Bromine cyanogen insect amide 20%, capillary 25%, alkyl benzene sulfonate calcium salt 6%, wetting and penetrating agent F 5%, glucose 3%, kaolin add to 100%, the mixed 45% bromine cyanogen insect amide acarid nitrile water dispersion granula that gets.
Embodiment 1260% bromine cyanogen insect amide acarid nitrile water dispersion granula
Bromine cyanogen insect amide 40%, capillary 20%, two (alkyl) naphthalenesulfonate formaldehyde condensation compound 8%, spaonin powder 3%, urea 2.5%, attapulgite add to 100%, the mixed 60% bromine cyanogen insect amide acarid nitrile water dispersion granula that gets.
Embodiment 1315% bromine cyanogen insect amide pymetrozine suspension agent
Bromine cyanogen insect amide 7%, pyrrole aphid ketone 8%, polycarboxylate 7%, soapberry powder 5%, silicone compound 0.2%, hydroxyethylcellulose 1%, diethylene glycol (DEG) 1.6%, deionized water add to 100%, the mixed 15% bromine cyanogen insect amide pymetrozine suspension agent that gets.
Embodiment 1430% bromine cyanogen insect amide pymetrozine suspension agent
Withered 5%, the C of bromine cyanogen insect amide 10%, pyrrole aphid ketone 20%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6%, tea
8～10Aliphatic alcohols 0.3%, Magnesiumaluminumsilicate 1.4%, ethylene glycol 2.5%, deionized water add to 100%, the mixed 30% bromine cyanogen insect amide pymetrozine suspension agent that gets.
Embodiment 1535% bromine cyanogen insect amide pymetrozine suspension agent
Bromine cyanogen insect amide 5%, pyrrole aphid ketone 30%, alkyl benzene sulfonate calcium salt 8%, neopelex 5%, silicone oil 0.4%, xanthans 1.2%, propane diols 2.3%, deionized water add to 100%, the mixed 35% bromine cyanogen insect amide pymetrozine suspension agent that gets.
Embodiment 1620% bromine cyanogen insect amide capillary suspending agent
Bromine cyanogen insect amide 4%, capillary 16%, aliphatic amine polyoxyethylene are phonetic 6%, silicone compound 0.2%, polyvinylpyrrolidone 1%, triethylene glycol 2.5%, deionized water add to 100%, mixed 20% bromine cyanogen insect amide capillary suspending agent.
Embodiment 1735% bromine cyanogen insect amide capillary suspending agent
Bromine cyanogen insect amide 15%, capillary 20%, lignosulfonates 7%, silicone oil 0.3%, sodium phosphate trimer 1.5%, polyethylene glycol 2%, deionized water add to 100%, the mixed 35% bromine cyanogen insect amide capillary suspending agent that gets.
Embodiment 1845% bromine cyanogen insect amide capillary suspending agent
Bromine cyanogen insect amide 5%, capillary 40%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 8%, C
8～10Aliphatic alcohols 0.5%, white dextrin 0.9%, glycerine 2.8%, deionized water add to 100%, the mixed 45% bromine cyanogen insect amide capillary suspending agent that gets.
Embodiment 1910% bromine cyanogen insect amide pyrrole aphid ketone suspension emulsion
Bromine cyanogen insect amide 5%, pyrrole aphid ketone 5%, polyoxyethylene carboxylate 7%, lauryl sodium sulfate 4%, phenethyl phenol polyoxy ethyl polypropylene-base ether 6%, silicone compound 0.2%, xanthans 1%, ethylene glycol 1.8%, deionized water add to 100%, the mixed 10% bromine cyanogen insect amide pyrrole aphid ketone suspension emulsion that gets.
Embodiment 2030.5% bromine cyanogen insect amide pyrrole aphid ketone suspension emulsion
Bromine cyanogen insect amide 30%, pyrrole aphid ketone 0.5%, polycarboxylate 8%, wetting and penetrating agent F 3%, methylcellulose 1.1%, ethylene oxide-propylene oxide block copolymer 7%, triethylene glycol 2%, silicone oil 0.3%, deionized water add to 100%, through the mixed 30.5% bromine cyanogen insect amide pyrrole aphid ketone suspension emulsion that gets.
Embodiment 2140% bromine cyanogen insect amide pyrrole aphid ketone suspension emulsion
Bromine cyanogen insect amide 15%, pyrrole aphid ketone 25%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6%, phenethyl fluosite polyoxy ethyl ether 8%, silicone compound 0.3%, Magnesiumaluminumsilicate 1.5%, propane diols 2.2%, deionized water add to 100%, the mixed 40% bromine cyanogen insect amide pyrrole propyl ether suspension emulsion that gets.
Embodiment 2225% bromine cyanogen insect amide capillary suspension emulsion
Bromine cyanogen insect amide 10%, capillary 15%, alkylnaphthalene sulfonate 7%, neopelex 5%, polyoxyethylene nonylphenol ether phosphate 8%, xanthans 1%, polyethylene glycol 1.6%, silicone 0.4%, deionized water add to 100%, the mixed 25% bromine cyanogen insect amide capillary suspension emulsion that gets.
Embodiment 2335% bromine cyanogen insect amide capillary suspension emulsion
Bromine cyanogen insect amide 30%, capillary 5%, aryl phenol polyoxyethylene succinate sulfonate 8%, Nekal BX 5%, sorbitan monostearate 6%, methylcellulose 1.3%, glycerine 1.8%, silicone oil 0.1%, deionized water add to 100%, the mixed 35% bromine cyanogen insect amide capillary suspension emulsion that gets.
Embodiment 2441% bromine cyanogen insect amide capillary suspension emulsion
Bromine cyanogen insect amide 40%, capillary 1%, lignosulfonates 6%, sldium lauryl sulfate 5%, sodium phosphate trimer 1%, alkyl biphenyl ether disulfonic acid magnesium salts 8%, diethylene glycol (DEG) 2%, silicone oil 0.2%, deionized water add to 100%, through the mixed 41% bromine cyanogen insect amide capillary suspension emulsion that gets.
Embodiment 2511% bromine cyanogen insect amide pyrrole aphid ketone microemulsion
Bromine cyanogen insect amide 10%, pyrrole aphid ketone 1%, N, dinethylformamide 7%, vegetable oil 5%, castor oil polyoxyethylene ether 6%, propane diols 2.6%, silicone compound 0.4%, xanthans 1.2%, deionized water supplies 100%, the mixed 11% bromine cyanogen insect amide pyrrole aphid ketone microemulsion that gets.
Embodiment 2635% bromine cyanogen insect amide pyrrole aphid ketone microemulsion
Bromine cyanogen insect amide 15%, pyrrole aphid ketone 20%, propyl alcohol 8%, ethyl acetate 6%, phenyl phenol polyoxy ethyl ether phosphate 7%, triethylene glycol 2.1%, C
8～10Aliphatic alcohols 0.3%, PAA 1.1%, deionized water supplies 100%, the mixed 35% bromine cyanogen insect amide pyrrole aphid ketone microemulsion that gets.
Embodiment 2748% bromine cyanogen insect amide pyrrole aphid ketone microemulsion
Bromine cyanogen insect amide 40%, pyrrole aphid ketone 8%, N-pyrrolidones 5%, ethylene glycol monomethyl ether 3%, propane diols 1.6%, phenolic resins 0.7%, silicone oil 0.1%, polyoxyethylene nonylphenol ether 8%, deionized water supplies 100%, the mixed 48% bromine cyanogen insect amide pyrrole aphid ketone microemulsion that gets.
Embodiment 2816% bromine cyanogen insect amide capillary microemulsion
Bromine cyanogen insect amide 4%, capillary 12%, cyclohexanone 6%, acetonitrile 4%, styrene polyoxyethylene ether ammonium sulfate salt 5%, polyethylene glycol 1.1%, silicone 0.2%, methylcellulose 2.5%, deionized water supplies 100%, the mixed 16% bromine cyanogen insect amide capillary microemulsion that gets.
Embodiment 2930% bromine cyanogen insect amide capillary microemulsion
Bromine cyanogen insect amide 15%, capillary 15%, acetone 8%, butanols 3%, benzyl dimethyl phenol polyoxy ethyl ether 7%, propane diols 1.8%, C
8～10Aliphatic alcohols 0.5%, deionized water supplies 100%, the mixed 30% bromine cyanogen insect amide capillary microemulsion that gets.
Embodiment 3040% bromine cyanogen insect amide capillary microemulsion
Bromine cyanogen insect amide 30%, capillary 10%, toluene 6%, ethyl acetate 5%, sorbitan fatty acid ester APEO 6%, triethylene glycol 2%, silicone oil 0.4%, Magnesiumaluminumsilicate 1.5%, deionized water supplies 100%, the mixed 40% bromine cyanogen insect amide capillary microemulsion that gets.
Embodiment 3118% bromine cyanogen insect amide pyrrole aphid ketone aqueous emulsion
Bromine cyanogen insect amide 8%, pyrrole aphid ketone 10%, N-octylpyrrolidone 8%, methyl alcohol 4%, alkyl benzene calcium sulfonate 9%, hydroxyethylcellulose 1.3%, silicone compound 0.3%, deionized water adds to 100%, makes 18% bromine cyanogen insect amide pyrrole aphid ketone aqueous emulsion.
Embodiment 3224% bromine cyanogen insect amide pyrrole aphid ketone aqueous emulsion
Bromine cyanogen insect amide 20%, pyrrole aphid ketone 4%, cyclohexanone 5%, vegetable oil 6%, polyoxyethylene nonylphenol ether 8%, Magnesiumaluminumsilicate 1.3%, silicone oil 0.5%, deionized water supplies 100%, makes 24% bromine cyanogen insect amide pyrrole aphid ketone aqueous emulsion.
Embodiment 3350% bromine cyanogen insect amide pyrrole aphid ketone aqueous emulsion
Bromine cyanogen insect amide 10%, pyrrole aphid ketone 40%, toluene 5%, N-pyrrolidones 4%, benzyl dimethyl phenol polyoxy ethyl ether 5%, glycerine 2.2%, C
8～10Aliphatic alcohols 0.1%, deionized water supplies 100%, makes 50% bromine cyanogen insect amide pyrrole aphid ketone aqueous emulsion.
Embodiment 3425% bromine cyanogen insect amide capillary aqueous emulsion
Bromine cyanogen insect amide 20%, capillary 5%, N, N-% methylformamide 4%, acetone 5%, ethylene glycol 2%, phenethyl phenol polyoxy ethyl polypropylene-base ether 7%, hydroxyethylcellulose 1.4%, silicone oil 0.6%, deionized water supplies 100%, makes 25% bromine cyanogen insect amide capillary aqueous emulsion.
Embodiment 3542% bromine cyanogen insect amide capillary aqueous emulsion
Bromine cyanogen insect amide 20%, capillary 22%, 3-methyl cyclohexanol ketenes 6%, ethyl acetate 4%, sorbitan monostearate 8%, polyvinyl alcohol 0.7%, silicone compound 0.2%, deionized water adds to 100%, makes 42% bromine cyanogen insect amide capillary aqueous emulsion.
Embodiment 3645% bromine cyanogen insect amide capillary aqueous emulsion
Bromine cyanogen insect amide 30%, capillary 15%, methyl alcohol 7%, ethylene glycol monomethyl ether 5%, diethylene glycol (DEG) 1.1%, ethylene oxide-propylene oxide block copolymer 6%, silicone 0.5%, deionized water supplies 100%, makes 45% bromine cyanogen insect amide capillary aqueous emulsion.
Active component B pyrrole aphid ketone among the above embodiment 1～36, capillary replace with second worm nitrile, pyrrole propyl ether, Acarus tritici urea and form new embodiment.
Embodiment 3730.5% bromine cyanogen insect amide active component B microcapsule suspending agent
Bromine cyanogen insect amide 0.5%, active component B30%, PIC 4%, octylphenol polyethylene oxyethylene group ether sulfate 3.5%, cyclohexanone 2%, ethylene oxide-propylene oxide block copolymer 3%, deionized water adds to 100% weight portion, makes 30.5% bromine cyanogen insect amide active component B microcapsule suspending agent.
Embodiment 3830.5% bromine cyanogen insect amide active component B micro-capsule-microcapsule suspending agent
Bromine cyanogen insect amide 30%, active component B 0.5%, polyfunctional group acyl halide dihydroxylic alcohols 3%, the phonetic formaldehyde condensation products sulphate 5% of alkylphenol-polyethenoxy, cyclohexanone 3.2%; By series 6%; deionized water adds to 100% weight portion, makes 30.5% bromine cyanogen insect amide active component B micro-capsule-microcapsule suspending agent.
Above-described embodiment 37, embodiment 38 described active component B are a kind of arbitrarily in pyrrole aphid ketone, capillary, second worm nitrile, pyrrole propyl ether, the Acarus tritici urea, and the weight ratio of bromine cyanogen insect amide and active component B is any one ratio between 1: 60～60: 1.
The embodiment of the invention is the method that adopts Toxicity Determination and field trial to combine.Earlier by Toxicity Determination, the co-toxicity coefficient (CTC) after clear and definite two kinds of medicaments are composite by a certain percentage, CTC＜80 are antagonism, and 80≤CTC≤120 are summation action, and CTC＞120 are synergistic effect, on this basis, carry out field trial again.
Test method: respectively the mother liquor of each mixed agent is diluted to five series concentration during test, places beaker standby respectively.Adopt and to soak the method that connects worm behind the leaf earlier, the blade of the same size that does not contact any medicament soaked in the soup that configures behind the 5s take out, dry naturally, put into insect box, connect then for the examination larva, under 25 ℃ of conditions, raise, every processing repeats for 3 times, every to repeat used examination borer population be 50, establishes blank simultaneously, checks dead borer population in 72h, calculate lethality and corrected mortality, try to achieve virulence regression equation and calculate LC
50Value.If the contrast lethality then is considered as invalid test greater than 10%.Computing formula is as follows:
The insect corrected mortality is converted into probit value (y), and concentration for the treatment of (μ g/ml) converts logarithm value (x) to, draws virulence regression equation with method of least squares, and calculates the value of every kind of medicament thus.Calculate co-toxicity coefficient CTC according to the abundant equation of Sun Yun.Computing formula following (be standard medicament with the bromine cyanogen insect amide, its toxicity index is 100):
TI * the P of theoretical toxicity index (TTI)=bromine cyanogen insect amide of M
The bromine cyanogen insect amideTI * P of+active component B
Active component B
In the formula: M is the mixture of different proportionings;
P
Active component BBe active component B shared ratio in composition;
P
The bromine cyanogen insect amideBe bromine cyanogen insect amide shared ratio in composition.
Annotate: active component B is a kind of arbitrarily in pyrrole aphid ketone, capillary, second worm nitrile, pyrrole propyl ether, the Acarus tritici urea.
Application Example two:
For trying insect: aphid.
Experimental scheme: effective lethal concentration scope of determining bromine cyanogen insect amide, the former medicine of pyrrole aphid ketone and the two different proportioning mixture through preliminary experiment.
Table 1 bromine cyanogen insect amide and the toxicity test of the different proportionings of pyrrole aphid ketone to aphid
As shown in Table 1, the anti-proportioning that eliminates aphis of bromine cyanogen insect amide and Pyraphione compound was at 60: 1 to 1: 60 o'clock, co-toxicity coefficient is all greater than 120, illustrating that both were mixed in the scope at 60: 1 to 1: 60 all shows synergistic effect, especially when the proportioning of bromine cyanogen insect amide and pyrrole aphid ketone during at 6: 1 to 1: 6, synergistic effect is more obviously outstanding, co-toxicity coefficient maximum when bromine cyanogen insect amide and pyrrole aphid ketone weight ratio are 1: 1 wherein, synergistic effect is the most obvious, find through the test people, bromine cyanogen insect amide and Pyraphione compound 60: 1～1: 60 o'clock to the control flea beetle, striped rice borer, paddy stem borer, rice leaf roller, brown planthopper, small brown rice planthopper, Bemisia tabaci, the trialeurodes vaporariorum insect also has synergistic effect preferably, particularly work as the proportioning of the two at 10: 1,9: 1,8: 1,7: 1,6: 1,5: 1,4: 1,3: 1,2: 1,1: 1,1: 2,1: 3,1: 4,1: 5,1: 6,1: 7,1: 8,1: 9,1: 10 o'clock co-toxicity coefficient is all greater than 150, and synergistic effect is obvious.
Application Example three:
For trying insect: thrips.
Experimental scheme: effective lethal concentration scope of determining bromine cyanogen insect amide, the former medicine of capillary and the two different proportioning mixture through preliminary experiment.
The different proportionings with capillary of table 2 bromine cyanogen insect amide are to the toxicity test of thrips
As shown in Table 2, the proportioning of the composite control of bromine cyanogen insect amide and capillary thrips was at 60: 1 to 1: 60 o'clock, co-toxicity coefficient is all greater than 120, illustrating that both were mixed in the scope at 60: 1 to 1: 60 all shows synergistic effect, especially when the proportioning of bromine cyanogen insect amide and capillary during at 6: 1 to 1: 6, synergistic effect is more obviously outstanding, co-toxicity coefficient maximum when bromine cyanogen insect amide and capillary weight ratio are 1: 1 wherein, synergistic effect is the most obvious, find through the test people, bromine cyanogen insect amide and capillary composite 60: 1～1: 60 o'clock to the control diamond-back moth, cotton bollworm, beet armyworm, tea lesser leafhopper, apple leaf miner, rice fulgorid, striped rice borer, paddy stem borer, insects such as rice leaf roller also have synergistic effect preferably, particularly work as the proportioning of the two at 10: 1,9: 1,8: 1,7: 1,6: 1,5: 1,4: 1,3: 1,2: 1,1: 1,1: 2,1: 3,1: 4,1: 5,1: 6,1: 7,1: 8,1: 9,1: 10 o'clock co-toxicity coefficient is all greater than 150, and synergistic effect is obvious.
Application Example four:
For trying insect: rice fulgorid.
Experimental scheme: effective lethal concentration scope of determining bromine cyanogen insect amide, the former medicine of second worm nitrile and the two different proportioning mixture through preliminary experiment.
Table 3 bromine cyanogen insect amide and the toxicity test of the different proportionings of second worm nitrile to rice fulgorid
As shown in Table 3, the proportioning of the composite control of bromine cyanogen insect amide and second worm nitrile rice fulgorid was at 60: 1 to 1: 60 o'clock, co-toxicity coefficient is all greater than 120, illustrating that both were mixed in the scope at 60: 1 to 1: 60 all shows synergistic effect, especially when the proportioning of bromine cyanogen insect amide and second worm nitrile during at 6: 1 to 1: 6, synergistic effect is more obviously outstanding, co-toxicity coefficient maximum when bromine cyanogen insect amide and second worm nitrile weight ratio are 1: 1 wherein, synergistic effect is the most obvious, find through the test people, bromine cyanogen insect amide and second worm nitrile are composite to the control striped rice borer, paddy stem borer, insects such as rice leaf roller also have synergistic effect preferably, and co-toxicity coefficient is all greater than 150.
Application Example five:
For trying insect: Bemisia tabaci.
Experimental scheme: effective lethal concentration scope of determining bromine cyanogen insect amide, the former medicine of pyrrole propyl ether and the two different proportioning mixture through preliminary experiment.
The different proportionings with the pyrrole propyl ether of table 4 bromine cyanogen insect amide are to the toxicity test of Bemisia tabaci
As shown in Table 4, bromine cyanogen insect amide and pyriproxyfen compound were prevented and treated the proportioning of Bemisia tabaci at 60: 1 to 1: 60 o'clock, co-toxicity coefficient is all greater than 120, illustrating that both were mixed in the scope at 60: 1 to 1: 60 all shows synergistic effect, especially when the proportioning of bromine cyanogen insect amide and pyrrole propyl ether during at 6: 1 to 1: 6, synergistic effect is more obviously outstanding, co-toxicity coefficient maximum when bromine cyanogen insect amide and pyrrole propyl ether weight ratio are 1: 1 wherein, and synergistic effect is the most obvious.
Application Example six:
For trying insect: beet armyworm.
Experimental scheme: effective lethal concentration scope of determining bromine cyanogen insect amide, the former medicine of Acarus tritici urea and the two different proportioning mixture through preliminary experiment.
The different proportionings with the Acarus tritici urea of table 5 bromine cyanogen insect amide are to the toxicity test of beet armyworm
As shown in Table 5, the proportioning of the composite control of bromine cyanogen insect amide and Acarus tritici urea beet armyworm was at 60: 1 to 1: 60 o'clock, co-toxicity coefficient is all greater than 120, illustrating that both were mixed in the scope at 60: 1 to 1: 60 all shows synergistic effect, especially when the proportioning of bromine cyanogen insect amide and Acarus tritici urea during at 6: 1 to 1: 6, synergistic effect is more obviously outstanding, co-toxicity coefficient maximum when bromine cyanogen insect amide and Acarus tritici urea weight ratio are 1: 1 wherein, synergistic effect is the most obvious, find through the test people, bromine cyanogen insect amide and Acarus tritici urea are composite to the control small brown rice planthopper, insects such as brown planthopper also have synergistic effect preferably, and co-toxicity coefficient is all greater than 150.
Application Example seven bromine cyanogen insect amides and pyrrole aphid ketone and the composite control rice fulgorid test of pesticide effectiveness thereof
This test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd., contrast medicament 10% bromine cyanogen insect amide suspending agent (autogamy), 50% pymetrozine water dispersing granule (commercial).
Conventional spray-on process is adopted in test, and investigation rice fulgorid insect pest index before the medicine in the dispenser of insect pest initial stage of origination, was investigated the insect pest indexes in 3 days, 14 days, 30 days after the dispenser and calculated preventive effect.Experimental result is as follows:
Table 6 bromine cyanogen insect amide, pyrrole aphid ketone and the composite control rice fulgorid test of pesticide effectiveness thereof
As can be seen from Table 6, can effectively prevent and treat rice fulgorid behind bromine cyanogen insect amide and the Pyraphione compound, find through the test people, bromine cyanogen insect amide and Pyraphione compound all have favorable effect to control paddy rice brown planthopper, white-backed planthopper, small brown rice planthopper etc., 30 days preventive effects are up to more than 95% behind the medicine, control efficiency all is better than the preventive effect of single agent, and the preventive effect time is long.In the test scope of medication, the target crop is had no adverse effects.
Application Example eight bromine cyanogen insect amides and capillary and the composite control eggplant thrips test of pesticide effectiveness thereof
This test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd., contrast medicament 10% bromine cyanogen insect amide suspending agent (autogamy), 10% capillary suspending agent (commercial).
Conventional spray-on process is adopted in test, and investigation eggplant thrips insect pest index in the dispenser of insect pest initial stage of origination, was investigated the insect pest indexes in 3 days, 14 days, 30 days after the dispenser and calculated preventive effect before the medicine.Experimental result is as follows:
Table 7 bromine cyanogen insect amide, capillary and the composite eggplant thrips test of pesticide effectiveness thereof
As can be seen from Table 7, can effectively prevent and treat the eggplant thrips after bromine cyanogen insect amide and capillary are composite, find through the applicant, the composite back of bromine cyanogen insect amide and capillary is also better to preventive effects such as plant hopper, diamond-back moth, beet armyworms, 30 days preventive effects reach more than 95% behind the medicine, control efficiency all is better than the preventive effect of single agent, and the preventive effect time is long.In the test scope of medication, the target crop is had no adverse effects.
After draw through different local throughout the country tests, the preventive effects of common insect dispenser after 30 days such as bromine cyanogen insect amide and pyrrole aphid ketone, capillary, second worm nitrile, pyrrole propyl ether, the composite rice water weevil to all kinds of crops of Acarus tritici urea, rice fulgorid, brown planthopper, white-backed planthopper, small brown rice planthopper, rice leaf roller, aphid, Bemisia tabaci, beet armyworm, diamond-back moth, cabbage caterpillar, leaf miner, leafhopper, tetranychid, tea lesser leafhopper, tea geometrid, peach fruit borer, cotton bollworm, pink bollworm, trialeurodes vaporariorum, two spotted spider mite are all more than 95%, be better than single agent preventive effect, synergistic effect is obvious.
Claims (6)
1. the Pesticidal combination of a brominated cyanogen insect amide, comprise active components A, active component B, the auxiliary agent surplus, it is characterized in that: active components A is the bromine cyanogen insect amide, active component B is a kind of arbitrarily in pyrrole aphid ketone, capillary, second worm nitrile, pyrrole propyl ether, the Acarus tritici urea, and the weight ratio of active components A and active component B is 60: 1～1: 60.
2. Pesticidal combination according to claim 1, it is characterized in that: the weight ratio of active components A and active component B is 40: 1～1: 40.
3. Pesticidal combination according to claim 2, it is characterized in that: the weight ratio of active components A and active component B is 20: 1～1: 20.
4. according to any described Pesticidal combination in the claim 1～3, it is characterized in that: composition is made wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, micro-capsule-microcapsule suspending agent.
5. Pesticidal combination according to claim 4 is used for the application of insect on control paddy rice, wheat, brassicaceous vegetable, tea tree, cotton, fruit tree, the ornamental flower.
6. application according to claim 5 is characterized in that: described insect comprises rice fulgorid, brown planthopper, small brown rice planthopper, rice leaf roller, striped rice borer, paddy stem borer, aphid, Bemisia tabaci, beet armyworm, diamond-back moth, cabbage caterpillar, leaf miner, blister mite, olethreutid, scale insect, leafhopper, tea lesser leafhopper, cotton bollworm.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210050946XA CN103283744A (en) | 2012-03-01 | 2012-03-01 | Cyantraniliprole-containing pesticidal composition |
| CN201610367766.2A CN105994286A (en) | 2012-03-01 | 2012-03-01 | Cyantraniliprole-containing insecticidal composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210050946XA CN103283744A (en) | 2012-03-01 | 2012-03-01 | Cyantraniliprole-containing pesticidal composition |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610367766.2A Division CN105994286A (en) | 2012-03-01 | 2012-03-01 | Cyantraniliprole-containing insecticidal composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103283744A true CN103283744A (en) | 2013-09-11 |
Family
ID=49085726
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210050946XA Pending CN103283744A (en) | 2012-03-01 | 2012-03-01 | Cyantraniliprole-containing pesticidal composition |
| CN201610367766.2A Pending CN105994286A (en) | 2012-03-01 | 2012-03-01 | Cyantraniliprole-containing insecticidal composition |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610367766.2A Pending CN105994286A (en) | 2012-03-01 | 2012-03-01 | Cyantraniliprole-containing insecticidal composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (2) | CN103283744A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103168787A (en) * | 2013-03-25 | 2013-06-26 | 海利尔药业集团股份有限公司 | Insecticidal composition containing lufenuron and cyantraniliprole |
| CN103300037A (en) * | 2013-06-28 | 2013-09-18 | 京博农化科技股份有限公司 | Insecticidal composition containing lufenuron and cyantraniliprole |
| CN103651386A (en) * | 2013-12-19 | 2014-03-26 | 北京燕化永乐生物科技股份有限公司 | Insecticidal composition containing chlorfenapyr |
| CN103858888A (en) * | 2014-03-27 | 2014-06-18 | 中国水稻研究所 | Granular long-acting compound agent for preventing and controlling pests of machine transplanted rice seedlings |
| CN104839182A (en) * | 2015-05-04 | 2015-08-19 | 山东省烟台市农业科学研究院 | Pesticide composition and application thereof |
| CN105994297A (en) * | 2016-06-21 | 2016-10-12 | 南京华洲药业有限公司 | Synergistic insecticide composition containing cyantraniliprole and pymetrozine and application thereof |
| CN106472512A (en) * | 2016-10-11 | 2017-03-08 | 佛山市盈辉作物科学有限公司 | A kind of containing chlorine fluorine cyanogen insect amide and the Pesticidal combination of Nylar |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112970762A (en) * | 2019-01-19 | 2021-06-18 | 海利尔药业集团股份有限公司 | Composition containing flubendiamide and benzoylurea insecticides |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1988803A (en) * | 2004-07-26 | 2007-06-27 | 杜邦公司 | Mixtures of anthranilamide invertebrate pest control agents |
| CN101703054A (en) * | 2009-11-19 | 2010-05-12 | 湖南化工研究院 | Insecticidal composite of Cyantraniliprole and methylamino abamectin benzoate |
| US20110052555A1 (en) * | 2008-01-15 | 2011-03-03 | Pierre-Yves Coqueron | Pesticide composition comprising a tetrazolyloxime derivative and a fungicide or an insecticide active substance |
| CN102428932A (en) * | 2011-11-28 | 2012-05-02 | 北京燕化永乐农药有限公司 | Insecticidal composition |
-
2012
- 2012-03-01 CN CN201210050946XA patent/CN103283744A/en active Pending
- 2012-03-01 CN CN201610367766.2A patent/CN105994286A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1988803A (en) * | 2004-07-26 | 2007-06-27 | 杜邦公司 | Mixtures of anthranilamide invertebrate pest control agents |
| US20110052555A1 (en) * | 2008-01-15 | 2011-03-03 | Pierre-Yves Coqueron | Pesticide composition comprising a tetrazolyloxime derivative and a fungicide or an insecticide active substance |
| CN101703054A (en) * | 2009-11-19 | 2010-05-12 | 湖南化工研究院 | Insecticidal composite of Cyantraniliprole and methylamino abamectin benzoate |
| CN102428932A (en) * | 2011-11-28 | 2012-05-02 | 北京燕化永乐农药有限公司 | Insecticidal composition |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103168787A (en) * | 2013-03-25 | 2013-06-26 | 海利尔药业集团股份有限公司 | Insecticidal composition containing lufenuron and cyantraniliprole |
| CN103300037A (en) * | 2013-06-28 | 2013-09-18 | 京博农化科技股份有限公司 | Insecticidal composition containing lufenuron and cyantraniliprole |
| CN103651386A (en) * | 2013-12-19 | 2014-03-26 | 北京燕化永乐生物科技股份有限公司 | Insecticidal composition containing chlorfenapyr |
| CN103858888A (en) * | 2014-03-27 | 2014-06-18 | 中国水稻研究所 | Granular long-acting compound agent for preventing and controlling pests of machine transplanted rice seedlings |
| CN103858888B (en) * | 2014-03-27 | 2016-11-23 | 中国水稻研究所 | The long-acting preventing and treating Particles dispersed agent of rice machine seedlings plugging insect |
| CN104839182A (en) * | 2015-05-04 | 2015-08-19 | 山东省烟台市农业科学研究院 | Pesticide composition and application thereof |
| CN105994297A (en) * | 2016-06-21 | 2016-10-12 | 南京华洲药业有限公司 | Synergistic insecticide composition containing cyantraniliprole and pymetrozine and application thereof |
| CN106472512A (en) * | 2016-10-11 | 2017-03-08 | 佛山市盈辉作物科学有限公司 | A kind of containing chlorine fluorine cyanogen insect amide and the Pesticidal combination of Nylar |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105994286A (en) | 2016-10-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103283744A (en) | Cyantraniliprole-containing pesticidal composition | |
| CN103283764A (en) | Cyantraniliprole containing insecticidal composition | |
| CN103283734A (en) | Cyantraniliprole/biological-source-containing pesticidal composition | |
| CN102396508A (en) | Novel pesticide combination containing thiamethoxam | |
| CN103355300A (en) | High-efficiency insecticide composition | |
| CN103283776A (en) | Cyantraniliprole-containing pesticidal composition | |
| CN103238613A (en) | Insecticidal composition containing tolfenpyrad | |
| CN103250715A (en) | Insecticidal composition comprising spirotetramat and pyrethroid | |
| CN103283774B (en) | A kind of Pesticidal combination containing spiral shell worm ethyl ester | |
| CN102302035A (en) | Pesticide composition containing methoxyfenozide | |
| CN103283761B (en) | A kind of Pesticidal combination containing second worm nitrile | |
| CN103283740A (en) | Cyantraniliprole-containing pesticidal composition | |
| CN103283743A (en) | Metaflumizone-containing pesticidal composition | |
| CN102396471A (en) | Spinetoram-containing pesticide composition | |
| CN103250716A (en) | Insecticidal composition comprising spirotetramat and nereistoxin | |
| CN102228055A (en) | Pesticide composite containing fenazaquin | |
| CN103300034B (en) | A kind of Pesticidal combination containing second worm nitrile | |
| CN103238614A (en) | Insecticidal composition containing metaflumizone and cyantraniliprole | |
| CN103283738B (en) | A kind of Pesticidal combination containing spiral shell worm ethyl ester | |
| CN103300005B (en) | A kind of Pesticidal combination containing Tolfenpyrad and neires toxin | |
| CN102246762A (en) | Insecticidal composition containing furan tebufenozide and amide compounds | |
| CN103250706A (en) | Insecticidal composition containing tolfenpyrad | |
| CN103283771A (en) | Cyantraniliprole/pyrethroid-containing pesticidal composition | |
| CN103283741A (en) | Tolfenpyrad-containing pesticidal composition | |
| CN103300033B (en) | Pesticide composition containing flutenzine |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20130911 |