CN105994297A - Synergistic insecticide composition containing cyantraniliprole and pymetrozine and application thereof - Google Patents

Synergistic insecticide composition containing cyantraniliprole and pymetrozine and application thereof Download PDF

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Publication number
CN105994297A
CN105994297A CN201610454539.3A CN201610454539A CN105994297A CN 105994297 A CN105994297 A CN 105994297A CN 201610454539 A CN201610454539 A CN 201610454539A CN 105994297 A CN105994297 A CN 105994297A
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Prior art keywords
pymetrozine
insect amide
cyanogen insect
synergistic insecticidal
insecticidal compositions
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CN201610454539.3A
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Inventor
杨琴
郭崇友
万维肖
夏小云
石振龙
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Nanjing Huazhou Pharmaceutical Co Ltd
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Nanjing Huazhou Pharmaceutical Co Ltd
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/7071,2,3- or 1,2,4-triazines; Hydrogenated 1,2,3- or 1,2,4-triazines
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/561,2-Diazoles; Hydrogenated 1,2-diazoles

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a synergistic insecticide composition containing cyantraniliprole and pymetrozine and the application thereof. Cyantraniliprole and pymetrozine are the main effective constituents of the insecticide composition, and the weight ratio of cyantraniliprole to pymetrozine is (1-60):(1-60). The insecticide composition has control spectrum expanding and synergistic effects, can reduce pesticide cost, and can be made into missible oil, wettable powder, microemulsion, emulsion in water, suspending agent and water dispersible granules to control lepidoptera, hemiptera, hymenoptera and coleoptera pests.

Description

A kind of brominated cyanogen insect amide and the Synergistic insecticidal compositions of pymetrozine and application thereof
Technical field
The invention belongs to pesticide field, be specifically related to a kind of with bromine cyanogen insect amide and pymetrozine killing as principle active component Worm compositions and application thereof.
Background technology
Bromine cyanogen insect amide (cyantraniliprole), is E.I.Du Pont Company's second filial generation that success is developed after chlorantraniliprole Ryanodine receptor inhibitor insecticides, cyanogen insect amide is to be formed by the various polar groups on change phenyl ring, has higher Effect, applicable crops is more extensive, can effectively prevent and treat Lepidoptera, Semiptera and coleopteran pest.
Pymetrozine (Pymetrozine), chemical name: (E)-4,5-dihydro-6-methyl-4-(3-pyridine methylene ammonia Base)-1,2,4-triazine-3 (2H)-one;Chemical molecular formula: C10H11N5O;Structural formula:
Pymetrozine belongs to pyridines or Triazinone insecticide, is brand-new non-killing livestock property insecticide, the earliest by Switzerland's vapour Ba Jiaji company shows the prevention effect of excellence in exploitation in 1988, this product to the sucking pest of various crop. Pymetrozine has action of contace poison to insect, the most also systemic activity.Can also can be tough in xylem transporting in plant Skin zone's transporting;The most both can be used as foliar spray it can also be used to soil treatment.Due to the transporting characteristic that it is good, spray at stem and leaf The branch and leaf newly grown after mist can also be effectively protected.
Insecticide variety containing single component often existing defects in pesticide Pest control: use continuously easily produce anti- The property of medicine, insecticidal spectrum is narrow, it is impossible to providing comprehensively protection for crop, peasant's drug cost is high.
Summary of the invention
It is an object of the invention to provide a kind of brominated cyanogen insect amide and the Synergistic insecticidal compositions of pymetrozine, said composition can For preventing and treating various agricultural insect, such as preventing and treating vegetable diamondback moth, Pieris rapae, it is also possible to be used for preventing and treating cotton boll worm, sweet Dish noctuid and Brown Planthopper etc., can reach a drug and prevent and treat the effect of dissimilar insect.
It is a further object of the present invention to provide the Synergistic insecticidal compositions of brominated cyanogen insect amide and pymetrozine in preparation preventing and treating Application in the insecticidal materials of one or more insects in resistance Lepidoptera, Semiptera, Hymenoptera or coleoptera.
The present invention adopts the following technical scheme that
A kind of brominated cyanogen insect amide and the Synergistic insecticidal compositions of pymetrozine, it is main with bromine cyanogen insect amide and pymetrozine Effective ingredient, wherein, the weight ratio of bromine cyanogen insect amide and pymetrozine is 1~60:1~60.Preferably bromine cyanogen insect amide and pymetrozine Weight ratio be 1~40:1~40, the weight ratio of further preferred bromine cyanogen insect amide and pymetrozine is 1~30:1~30.One In a little preferably technical schemes: bromine cyanogen insect amide and pymetrozine can 1:30,1:29,1:28,1:27,1:26,1:25,1: 24、1:24、1:22、1:21、1:20、1:19、1:18、1:17、1:16、1:15、1:14、1:13、1:12、1:11、1:10、1:9、 1:8、1:7、1:6、1:5、1:4、1:3、1:2、1:1、2:1、3:1、4:1、5:1、6:1、7:1、8:1、9:1、10:1、11:1、12: 1、13:1、14:1、15:1、16:1、17:1、18:1、19:1、20:1、21:1、22:1、23:1、24:1、25:1、26:1、27:1、 These ratios of 28:1,29:1,30:1,2:3,3:2,2:5,5:2,3:4,4:3,5:2,2:5,5:3,3:5,5:4,4:5 select.
At brominated cyanogen insect amide and the Synergistic insecticidal compositions of pymetrozine of the present invention, bromine cyanogen insect amide and both pymetrozines Weight percentage in this Synergistic insecticidal compositions is 2%~80%, preferably 8%~60%, optimum be 20%~ 40%.
The Synergistic insecticidal compositions of above-mentioned brominated cyanogen insect amide and pymetrozine with bromine cyanogen insect amide with pymetrozine for mainly having Effect composition (active component) and insecticides adjuvant, excipient are configured on pesticide any one dosage form allowed.The preferred powder of dosage form, Wettable powder, suspending agent, cream and water dispersion granule.
Described auxiliary agent can use calcium dodecyl benzene sulfonate, alkylphenol polyoxyethylene, polyoxyethylene polyoxy propylene embedding Section compound is (such as agriculture breast 33#), NPE etc., excipient comprises Ketohexamethylene, dimethylbenzene, solvent naphtha, water, antifreeze Agent (such as propylene glycol), deionized water etc..Above auxiliary agent, excipient and other agriculturally known adjuvant can be alone or and use.
Above-mentioned brominated cyanogen insect amide and the Synergistic insecticidal compositions of pymetrozine are at preparation preventing and treating Lepidoptera, Semiptera, film Application in the insecticidal materials of one or more insects in wing mesh or coleoptera.Especially preparation preventing and treating planthopper or snout moths larva Application effect in insecticidal materials is notable.
The Synergistic insecticidal compositions antagonism lepidoptera pest of the present invention has significant preventive effect, particularly with cotton boll Worm, beet armyworm, diamondback moth etc. easily produce the various pests of resistance and have good preventive effect;And suppress insect to single The Drug resistance of preparation (bromine cyanogen insect amide or pymetrozine) produces and can prevent and treat Hemipteran pest such as Brown Planthopper etc. simultaneously.
The insecticidal materials prepared by the Synergistic insecticidal compositions of described brominated cyanogen insect amide and pymetrozine is preventing and treating resistance While Lepidoptera, Hymenoptera or coleopteran pest, Hemipteran pest can be prevented and treated again, especially to cotton boll worm, diamondback moth and Beet armyworm has good preventive effect, reaches the effect that a medicine is controlled more.
The Pesticidal combination of the present invention compared with prior art, produces following beneficial effect: (1) compared with single dose, this group Compound insect has notable synergistic, hence it is evident that improve prevention effect;(2) one medicines are controlled more, and a dispenser can prevent and treat various pests simultaneously, Reduce preventing and treating recruitment cost;(3) alternative high-toxic pesticide, and field dosage is greatly reduced, effectively reduce environmental pollution and Pesticide residues;(4) have concurrently quick-acting and long-acting;(5) compared with bromine cyanogen insect amide single dose, produce and use cost reduces;(6) suppression The resistance of pesticide is strengthened by insect.
Detailed description of the invention
Embodiments of the invention are the methods using indoor bioassay and field test to combine.First pass through indoor biological Measure, the co-toxicity coefficient after clear and definite two kinds of medicaments are compounding by a certain percentage;On this basis, then carry out field test.
Embodiment 1:
Weigh 80g bromine cyanogen insect amide, 2g pymetrozine, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, two Toluene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, forms principle active component weight Amount percentage composition is the bromine cyanogen insect amide pymetrozine cream of 82%.
Embodiment 2:
Weigh 2g bromine cyanogen insect amide, 80g pymetrozine, lignin 10g, Negel 2g, add to 100g with Kaolin, Above raw material is mixed in super micron mill, forms the bromine cyanogen insect amide that principle active component weight percentage is 82% Pymetrozine wettable powder.
Embodiment 3:
Weigh 60g bromine cyanogen insect amide, 2g pymetrozine, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 6g, two Toluene adds to 100g, and the method that above raw material is prepared cream routinely puts into mixing in mixing kettle, forms principle active component Weight percentage is the bromine cyanogen insect amide pymetrozine cream of 62%.
Embodiment 4:
Weigh 2g bromine cyanogen insect amide, 60g pymetrozine, nonyl phenol phosphate 5g, alkylphenol polyoxyethylene 4g, n-butyl alcohol The dimethylbenzene of 3g, 10g and the ketopyrrolidine of 10g, the xanthan gum of 0.1g, remaining supplies 100g, n-butyl alcohol and water dissolution shape with water Becoming aqueous phase, remaining component mix and blend forms oil phase, slowly aqueous phase is added in oil phase, and continue to cut under cutter effect Cut 10~30 minutes, form the bromine cyanogen insect amide pymetrozine water emulsion that principle active component weight percentage is 62%.
Embodiment 5:
Weigh 40g bromine cyanogen insect amide, 2g pymetrozine, calcium dodecyl benzene sulfonate 5g, alkylphenol polyoxyethylene 4g, 30g Solvent xylene and the ketopyrrolidine of 15g, remaining complements to 100g with water, and the mixing of former medicine, solvent, emulsifying agent, cosolvent is stirred Mix formation homogeneous phase transparent solution, be then slowly added into water and stir formation clear solution, being principle active component weight percent Content is the bromine cyanogen insect amide pymetrozine micron emulsion of 42%.
Embodiment 6:
Weigh 2g bromine cyanogen insect amide, 40g pymetrozine, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 3g, two Toluene is to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, forms principle active component weight Amount percentage composition is the bromine cyanogen insect amide pymetrozine cream of 42%.
Embodiment 7:
Weigh 20g bromine cyanogen insect amide, 2g pymetrozine, sodium lignin sulfonate 3g, polyoxyethylene poly-oxygen propylene aether and sulphuric acid thereof Salt 4g, xanthan gum 0.2g, ethylene glycol 10g, silica ethane 0.1g, aluminium-magnesium silicate 0.5g, supply 100g with water, at the work of sand mill With the bromine cyanogen insect amide pymetrozine suspension agent that lower formation principle active component weight percentage is 22%.
Embodiment 8:
Weigh 2g bromine cyanogen insect amide, 20g pymetrozine, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether 15g, Dimethylbenzene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, forms principle active component Weight percentage is the bromine cyanogen insect amide pymetrozine cream of 22%.
Embodiment 9:
Weigh 2g bromine cyanogen insect amide, 10g pymetrozine, sodium lignin sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g, Polyvinyl alcohol 5g, Borax 2g, Kaolin 28g, the method that above raw material is pressed water dispersion granule forms principle active component weight Amount percentage composition is the bromine cyanogen insect amide pymetrozine water dispersing granule of 12%.
Embodiment 10:
Weigh 5g bromine cyanogen insect amide, 10g pymetrozine, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether 15g, Dimethylbenzene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, forms principle active component Weight percentage is the bromine cyanogen insect amide pymetrozine cream of 15%.
Embodiment 11:
Weigh 10g bromine cyanogen insect amide, 10g pymetrozine, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, Dimethylbenzene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, forms principle active component Weight percentage is the bromine cyanogen insect amide pymetrozine cream of 20%.
Drug effect checking test
1, indoor virulence determination of activity
Weigh bromine cyanogen insect amide, pymetrozine uses conventional formulation method to be configured to principle active component weight by different proportion Percentage composition is the bromine cyanogen insect amide pymetrozine cream of 30%.Concrete ratio is shown in Table 1.
Use feedstuff to add poison method and measure bromine cyanogen insect amide and pymetrozine and the compounding sample virulence to cotton boll worm thereof, often Process is repeated 3 times, and every concentration processes 30, uses LC50It is worth and presses Sun Yun abundant method calculating co-toxicity coefficient:
Table 1 bromine cyanogen insect amide, pymetrozine and compounding sample thereof are to the toxicity test of cotton boll worm and co-toxicity coefficient
In table, data show, after bromine cyanogen insect amide and pymetrozine mixture, cotton boll worm are had potentiation, institute in table The proportioning co-toxicity coefficient of row is both greater than 120, and therefore bromine cyanogen insect amide and pymetrozine mixture have significant synergies.
Weigh bromine cyanogen insect amide, pymetrozine uses conventional formulation method to be configured to principle active component weight by different proportion Percentage composition is the bromine cyanogen insect amide pymetrozine cream of 30%.Concrete ratio is shown in Table 2.
Rice-stem dipping method is used to measure bromine cyanogen insect amide and pymetrozine and the compounding sample virulence to Brown Planthopper thereof, often Process is repeated 3 times, and uses LC50It is worth and presses Sun Yun abundant method calculating co-toxicity coefficient:
Table 2 bromine cyanogen insect amide, pymetrozine and compounding sample thereof are to the toxicity test of Brown Planthopper and co-toxicity coefficient
In table, data show, have potentiation, institute in table after bromine cyanogen insect amide and pymetrozine mixture to Brown Planthopper The proportioning co-toxicity coefficient of row is all much larger than 120, and therefore bromine cyanogen insect amide and pymetrozine mixture have significant synergies.
2, field control effectiveness test
Using embodiment institute sample product to carry out the field test of control in field cotton boll worm, comparison medicament is 5% bromine cyanogen Insect amide EC and 50% pymetrozine WDG, concrete consumption is shown in Table 3, and every mu of water consumption is 30kg, looks into 3 days, 7 days, within 14 days, tie after medicine Really, result of the test is shown in Table 3:
Table 3 sample field test results to cotton boll worm
Example has fabulous quick-acting to cotton boll worm as can be seen from Table 3, and the lasting period is long, at field table Now good, it is the outstanding medicament of preventing and treating cotton boll worm.
Measure through indoor synergism test and show: by bromine cyanogen insect amide with Pyraphione compound agent to cotton boll worm and Rice Brown Plant hopper has significant synergistic insecticidal action;Field control effectiveness test also indicates that all of built agent of the present invention is to cotton boll worm equally Insecticidal effect is all remarkably higher than the effect of corresponding single dose pesticide.

Claims (9)

1. brominated cyanogen insect amide and a Synergistic insecticidal compositions for pymetrozine, is characterized in that this Synergistic insecticidal compositions is with bromine cyanogen Insect amide and pymetrozine are principle active component, and wherein, the weight ratio of bromine cyanogen insect amide and pymetrozine is 1~60:1~60.
Brominated cyanogen insect amide the most according to claim 1 and the Synergistic insecticidal compositions of pymetrozine, is characterized in that this parasite killing The active ingredient bromine cyanogen insect amide of compositions and the weight ratio of pymetrozine are 1~40:1~40.
Brominated cyanogen insect amide the most according to claim 2 and the Synergistic insecticidal compositions of pymetrozine, is characterized in that this parasite killing The active ingredient bromine cyanogen insect amide of compositions and the weight ratio of pymetrozine are 1~30:1~30.
Brominated cyanogen insect amide the most according to claim 1 and the Synergistic insecticidal compositions of pymetrozine, is characterized in that bromine cyanogen worm Amide and both pymetrozines weight percentage in this Synergistic insecticidal compositions are 2%~80%.
Brominated cyanogen insect amide the most according to claim 4 and the Synergistic insecticidal compositions of pymetrozine, is characterized in that bromine cyanogen worm Amide and both pymetrozines weight percentage in this Synergistic insecticidal compositions are 8%~60%.
Brominated cyanogen insect amide the most according to claim 1 and the Synergistic insecticidal compositions of pymetrozine, is characterized in that this potentiation With bromine cyanogen insect amide, as principle active component and insecticides adjuvant is configured on pesticide any of permission to Pesticidal combination with pymetrozine A kind of dosage form.
Brominated cyanogen insect amide the most according to claim 6 and the Synergistic insecticidal compositions of pymetrozine, is characterized in that described dose Type is cream, wettable powder, microemulsion, aqueous emulsion, suspending agent or water dispersion granule.
8. the Synergistic insecticidal compositions of brominated cyanogen insect amide described in claim 1 and pymetrozine preparation preventing and treating Lepidoptera, half Application in the insecticidal materials of one or more insects in wing mesh, Hymenoptera or coleoptera.
Application the most according to claim 8, is characterized in that the Synergistic insecticidal compositions of brominated cyanogen insect amide and pymetrozine exists Application in the insecticidal materials of preparation preventing and treating cotton boll worm, beet armyworm and Brown Planthopper.
CN201610454539.3A 2016-06-21 2016-06-21 Synergistic insecticide composition containing cyantraniliprole and pymetrozine and application thereof Pending CN105994297A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102283205A (en) * 2004-07-26 2011-12-21 杜邦公司 Mixtures of anthranilamide invertebrate pest control agents
CN102428932A (en) * 2011-11-28 2012-05-02 北京燕化永乐农药有限公司 Insecticidal composition
CN103283744A (en) * 2012-03-01 2013-09-11 陕西韦尔奇作物保护有限公司 Cyantraniliprole-containing pesticidal composition
JP2015214554A (en) * 2015-06-11 2015-12-03 住友化学株式会社 Plant disease and harmful arthropod control composition and plant disease and harmful arthropod control method

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102283205A (en) * 2004-07-26 2011-12-21 杜邦公司 Mixtures of anthranilamide invertebrate pest control agents
CN102428932A (en) * 2011-11-28 2012-05-02 北京燕化永乐农药有限公司 Insecticidal composition
CN103283744A (en) * 2012-03-01 2013-09-11 陕西韦尔奇作物保护有限公司 Cyantraniliprole-containing pesticidal composition
JP2015214554A (en) * 2015-06-11 2015-12-03 住友化学株式会社 Plant disease and harmful arthropod control composition and plant disease and harmful arthropod control method

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Application publication date: 20161012