CN105941467A - Compound insecticide composition containing cyantraniliprole and chlorpyrifos and application thereof - Google Patents
Compound insecticide composition containing cyantraniliprole and chlorpyrifos and application thereof Download PDFInfo
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- CN105941467A CN105941467A CN201610454540.6A CN201610454540A CN105941467A CN 105941467 A CN105941467 A CN 105941467A CN 201610454540 A CN201610454540 A CN 201610454540A CN 105941467 A CN105941467 A CN 105941467A
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- chlopyrifos
- insect amide
- cyanogen insect
- pesticide compositions
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing heterocyclic radicals
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a compound insecticide composition containing cyantraniliprole and chlorpyrifos and application thereof. The insecticide composition takes cyantraniliprole and chlorpyrifos as active ingredients, wherein the weight ratio of cyantraniliprole to chlorpyrifos is (0.1-80):(0.5-80). The insecticide composition can produce relatively high synergistic effect, overcomes and delays pest resistance to insecticide and is high in insecticidal speed and long in lasting period, application cost is reduced, and control efficiency is obviously higher than those of single dosages. The compound insecticide composition disclosed by the invention can be used for preventing and controlling lepidoptera pests on crops, especially can be used for preventing and controlling helicoverpa armigera and stem borers and has obviously better effect compared with the single dosages.
Description
Technical field
The invention belongs to the field of agricultural pesticide containing heterocyclic compound, concrete body relates to a kind of compound pesticide compositions.
Background technology
Bromine cyanogen insect amide (cyantraniliprole), is that E.I.Du Pont Company's second filial generation ryania that success is developed after chlorantraniliprole is subject to
Body inhibitor insecticides, cyanogen insect amide is to be formed by the various polar groups on change phenyl ring, has more efficient, is suitable for
Crop is more extensive, can effectively prevent and treat Lepidoptera, Semiptera and coleopteran pest.
Chlopyrifos (chlorpyrifos) is a kind of broad spectrum insecticide of The Dow Agrosciences, LLC.'s exploitation, in China's registration
Trade name is Le Siben.Chemical name is: O, O-diethyl-O-(3,5,6-trichloro-2-pyridyl) thiophosphate；Structure
Formula is:
Former medicine is white or canescence granular crystals (or blocks of solid), fusing point 41.5～43.5 DEG C；Fish and Apis are had
Poison, sensitive to Nicotiana tabacum L..Chlopyrifos is one of insecticide variety of current produced worldwide and sales volume maximum, and the Ye Shi world defends
The organophosphor kind of the unique license of raw tissue, through in registration such as country such as 14, China, the U.S., Australia, Japan etc.
And registration.This kind have tag, stomach toxicity and stifling three kinds of model of action, its insecticidal spectrum is wide, toxicity is relatively low, Shangdi over the ground
Lower insect is efficient equally, is preventing and treating grain, fruit tree, vegetable and the preferable insecticide of other industrial crops insect pests, to underground evil
The prevention effect of worm is especially prominent, is particularly suitable for the production of pollution-free vegetable.
But the insect such as bollworm, snout moths larva is under conditions of current long-term prescription, and resistance is gradually increased, pesticide single dose is to insect
The effect of preventing and treating is gradually reduced.
Summary of the invention
It is an object of the invention to provide a kind of brominated cyanogen insect amide and the compound pesticide compositions of chlopyrifos, this Pesticidal combination is
The multifunctional insecticide compositions of preventing and treating lepidoptera pest.
It is a further object of the present invention to provide this Pesticidal combination to prevent and treat on the insecticidal materials of resistance lepidoptera pest in preparation
Application, the particularly application on the insecticidal materials of preparation preventing and treating bollworm or snout moths larva.
It is an object of the invention to be achieved through the following technical solutions:
A kind of brominated cyanogen insect amide and the compound pesticide compositions of chlopyrifos, this compound pesticide compositions is with bromine cyanogen insect amide and poison
Dead Ticks is principle active component, and wherein, the weight ratio of bromine cyanogen insect amide and chlopyrifos is 0.1～80:0.5～80.
In this compound pesticide compositions, the weight ratio of bromine cyanogen insect amide (A) and chlopyrifos (B) is preferably 1～60:1～60,
More preferably 1～40:1～40, most preferably 1～30:1～30.In some preferred technical schemes: bromine cyanogen worm acyl
Amine and chlopyrifos can 1:30,1:29,1:28,1:27,1:26,1:25,1:24,1:24,1:22,1:21,1:20,
1:19、1:18、1:17、1:16、1:15、1:14、1:13、1:12、1:11、1:10、1:9、1:8、1:7、1:6、1:5、
1:4、1:3、1:2、1:1、2:1、3:1、4:1、5:1、6:1、7:1、8:1、9:1、10:1、11:1、12:1、13:1、
14:1、15:1、16:1、17:1、18:1、19:1、20:1、21:1、22:1、23:1、24:1、25:1、26:1、27:1、
These ratios of 28:1,29:1,30:1,2:3,3:2,2:5,5:2,3:4,4:3,5:2,2:5,5:3,3:5,5:4,4:5
Middle selection.
This compound pesticide compositions can comprise only active component bromine cyanogen insect amide and chlopyrifos, it is possible to when using or prepare to work
Adding other components in property composition, the active ingredient in this Pesticidal combination can be present in compositions with enhancing effective amount.
In compound pesticide compositions of the present invention, bromine cyanogen insect amide and both chlopyrifos weight in this compound pesticide compositions
Percentage composition is 3%～80%.It is preferably 5%～55%, most preferably 10%～40%.
Compound pesticide compositions of the present invention is with bromine cyanogen insect amide and chlopyrifos as active component or principle active component, and pesticide helps
Agent and excipient become any one dosage form allowed on pesticide, the preferred cream of described dosage form, suspending agent, wettable powder
Agent, aqueous emulsion, microemulsion or water dispersion granule.
The insecticides adjuvant of the aforementioned present invention of can be applicable to is not particularly limited, and includes, but are not limited to DBSA
Calcium, 600#, polyoxyethylene polyoxy propylene block compound are (such as agriculture breast 33#), NPE etc., aforementioned can
The excipient being applied to the present invention is also not particularly limited, and includes, but are not limited to solvent naphtha, water, antifreezing agent (such as the third two
Alcohol), deionized water etc..Above auxiliary agent, excipient and other adjuvant can be alone or and use.
Compound pesticide compositions of the present invention easily produces multiple Semiptera and the lepidoptera pest of resistance to planthopper and snout moths larva etc.
There is good preventive effect；And suppress insect that the Drug resistance of unitary agent (bromine cyanogen insect amide or chlopyrifos are arbitrary) is produced.
Above-mentioned compound pesticide compositions prevents and treats the application on resistance lepidoptera pest insecticidal materials in preparation, especially anti-in preparation
Control the application effect on bollworm or snout moths larva insecticidal materials notable.
Compared with prior art beneficial effects of the present invention: (1), compared with single dose, said composition antagonism lepidoptera pest is such as
Bollworm, snout moths larva etc. have obvious synergistic function, overcome and delayed pest resistance to insecticide, and expanding prevention is composed, parasite killing speed
Hurry up, hence it is evident that improve prevention effect；(2) preventing and treating recruitment, drug cost are reduced；(3) alternative high-toxic pesticide；(4) hold concurrently
Have immediate effect and long-acting；(5) with bromine cyanogen insect amide compared with chlopyrifos single dose, produce and use cost reduces；(6) suppression squama
The resistance of pesticide is strengthened by wing mesh insect, and its effect uses apparently higher than its single dose.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described, but limits the present invention never in any form.
Embodiment 1:
Weigh 80g bromine cyanogen insect amide, 2g chlopyrifos, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g,
Dimethylbenzene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, is formed and the most effectively become
The bromine cyanogen insect amide chlorpyrifos ec dividing weight percentage to be 82%.
Embodiment 2:
Weigh 2g bromine cyanogen insect amide, 80g chlopyrifos, lignin 10g, Negel 2g, add to 100g with Kaolin,
Above raw material is mixed in super micron mill, forms the bromine cyanogen worm acyl that principle active component weight percentage is 82%
Amine chlopyrifos wettable powder.
Embodiment 3:
Weigh 60g bromine cyanogen insect amide, 2g chlopyrifos, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 6g,
Dimethylbenzene adds to 100g, and the method that above raw material is prepared cream routinely puts into mixing in mixing kettle, is formed main effective
Ingredients Weight percentage composition is the bromine cyanogen insect amide chlorpyrifos ec of 62%.
Embodiment 4:
Weigh 2g bromine cyanogen insect amide, 60g chlopyrifos, nonyl phenol phosphate 5g, alkylphenol polyoxyethylene 4g, n-butyl alcohol
The dimethylbenzene of 3g, 10g and the ketopyrrolidine of 10g, the xanthan gum of 0.1g, remaining supplies 100g, n-butyl alcohol and water with water
Dissolving and form aqueous phase, remaining component mix and blend forms oil phase, slowly aqueous phase is added in oil phase under cutter effect,
And continue to shear 10～30 minutes, form the bromine cyanogen insect amide chlopyrifos that principle active component weight percentage is 62%
Aqueous emulsion.
Embodiment 5:
Weigh 40g bromine cyanogen insect amide, 2g chlopyrifos, calcium dodecyl benzene sulfonate 5g, alkylphenol polyoxyethylene 4g, 30g
Solvent xylene and the ketopyrrolidine of 15g, remaining complements to 100g, former medicine, solvent, emulsifying agent, cosolvent with water
Mix and blend forms homogeneous phase transparent solution, is then slowly added into water and stirs formation clear solution, being principle active component weight
Amount percentage composition is the bromine cyanogen insect amide chlorpyrifos micro emulsion of 42%.
Embodiment 6:
Weigh 2g bromine cyanogen insect amide, 40g chlopyrifos, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 3g,
Dimethylbenzene is to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, is formed and the most effectively becomes
The bromine cyanogen insect amide chlorpyrifos ec dividing weight percentage to be 42%.
Embodiment 7:
Weigh 20g bromine cyanogen insect amide, 2g chlopyrifos, sodium lignin sulfonate 3g, polyoxyethylene poly-oxygen propylene aether and sulphuric acid thereof
Salt 4g, xanthan gum 0.2g, ethylene glycol 10g, silica ethane 0.1g, aluminium-magnesium silicate 0.5g, supply 100g with water, at sand
The effect of grinding machine is lower forms the bromine cyanogen insect amide chlopyrifos suspending agent that principle active component weight percentage is 22%.
Embodiment 8:
Weigh 2g bromine cyanogen insect amide, 20g chlopyrifos, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether 15g,
Dimethylbenzene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, is formed and the most effectively become
The bromine cyanogen insect amide chlorpyrifos ec dividing weight percentage to be 22%.
Embodiment 9:
Weigh 10g bromine cyanogen insect amide, 2g chlopyrifos, sodium lignin sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g,
Polyvinyl alcohol 5g, Borax 2g, Kaolin 28g, form main effectively one-tenth by above raw material by the method for water dispersion granule
The bromine cyanogen insect amide chlopyrifos water dispersible granules dividing weight percentage to be 12%.
Embodiment 10:
Weigh 15g bromine cyanogen insect amide, 5g chlopyrifos, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether 15g,
Dimethylbenzene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, is formed and the most effectively become
The bromine cyanogen insect amide chlorpyrifos ec dividing weight percentage to be 20%.
Embodiment 11:
Weigh 10g bromine cyanogen insect amide, 10g chlopyrifos, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g,
Dimethylbenzene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, is formed and the most effectively become
The bromine cyanogen insect amide chlorpyrifos ec dividing weight percentage to be 20%.
Drug effect checking test
1, indoor virulence determination of activity
Weigh bromine cyanogen insect amide and chlopyrifos 30g, calcium dodecyl benzene sulfonate 4g altogether, phenethyl phenol polyethenoxy ether 4g,
Vegetable oil is to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, is configured to main effective
Ingredients Weight percentage composition is the bromine cyanogen insect amide chlorpyrifos ec of 30%.Wherein bromine cyanogen insect amide and chlopyrifos specifically than
Example is shown in Table 1 and 2.
Using feedstuff to add poison method and carry out indoor potentiation bioassay, selection resistant bollworm is target pest, often processes repetition 3
Secondary, every concentration process 60, with probability value method calculate each medicament antagonism bollworm toxicity regression equation and lethal in dense
Degree LC50, use LC50Value press Sun Yun abundant method calculating co-toxicity coefficient, the results are shown in Table 1:
Table 1 bromine cyanogen insect amide, chlopyrifos and the toxicity test of compounding sample antagonism bollworm thereof and co-toxicity coefficient
In table, data show, after bromine cyanogen insect amide and chlopyrifos mixture, antagonism bollworm are had potentiation, listed in table
Proportioning co-toxicity coefficient be both greater than 120, therefore bromine cyanogen insect amide and chlopyrifos mixture have significant synergies.
Weigh bromine cyanogen insect amide, chlopyrifos uses conventional formulation method to be configured to principle active component weight percent by different proportion
Content is the bromine cyanogen insect amide chlorpyrifos ec of 30%.Concrete ratio is shown in Table 2.
Using feedstuff to add poison method and carry out indoor potentiation bioassay, selection rice-stem borer is target pest, often processes repetition
3 times, calculate toxicity regression equation and lethal concentration of 50 LC of each medicament antagonism striped rice borer by probability value method50, use LC50
Value press Sun Yun abundant method calculating co-toxicity coefficient, the results are shown in Table 2:
Table 2 bromine cyanogen insect amide, chlopyrifos and compounding sample thereof to striped rice borer toxicity test and co-toxicity coefficient
In table, data show, have potentiation after bromine cyanogen insect amide and chlopyrifos mixture to rice-stem borer, listed by table
Proportioning co-toxicity coefficient is all much larger than 120, and therefore bromine cyanogen insect amide and chlopyrifos mixture have significant synergies.
2, field control effectiveness test
Using embodiment institute sample product to carry out the field test of control in field bollworm, comparison medicament is 40% chlopyrifos WP
(wettable powder) and 20% bromine cyanogen insect amide WP (wettable powder), carry out dilute according to the extension rate in form 3
Release, after medicine, look into 3 days, 7 days, the result of 14 days, result is shown in Table 3:
The field test results of table 3 bromine cyanogen insect amide-chlorpyrifos mixture antagonism bollworm
Example has fabulous quick-acting to antagonism bollworm as can be seen from Table 3, and the lasting period is long, in field
Performance is good, is the outstanding medicament preventing and treating antagonism bollworm.
Measure through indoor synergism test and show: with chlorpyrifos mixture agent, bollworm and rice-stem borer are had aobvious by bromine cyanogen insect amide
The synergistic insecticidal action write；Field control effectiveness test also indicates that all of built agent of the present invention is the most aobvious to bollworm insecticidal effect equally
Write the effect higher than corresponding single dose pesticide.
Claims (10)
1. brominated cyanogen insect amide and a compound pesticide compositions for chlopyrifos, is characterized in that this compound pesticide compositions is with bromine
Cyanogen insect amide and chlopyrifos are active insecticidal components, and wherein, the weight ratio of bromine cyanogen insect amide and chlopyrifos is 0.1～80:
0.5～80.
Brominated cyanogen insect amide the most according to claim 1 and the compound pesticide compositions of chlopyrifos, is characterized in that described
Bromine cyanogen insect amide and the weight ratio of chlopyrifos be 1～60:1～60.
Brominated cyanogen insect amide the most according to claim 2 and the compound pesticide compositions of chlopyrifos, is characterized in that described
Bromine cyanogen insect amide and the weight ratio of chlopyrifos be 1～40:1～40.
Brominated cyanogen insect amide the most according to claim 3 and the compound pesticide compositions of chlopyrifos, is characterized in that described
Bromine cyanogen insect amide and the weight ratio of chlopyrifos be 1～30:1～30.
Brominated cyanogen insect amide the most according to claim 1 and the compound pesticide compositions of chlopyrifos, is characterized in that bromine cyanogen
Insect amide and both chlopyrifos weight percentage in this compound pesticide compositions are 3%～80%.
Brominated cyanogen insect amide the most according to claim 5 and the compound pesticide compositions of chlopyrifos, is characterized in that bromine cyanogen
Insect amide and both chlopyrifos weight percentage in this compound pesticide compositions are 5%～55%.
Brominated cyanogen insect amide the most according to claim 1 and the compound pesticide compositions of chlopyrifos, is characterized in that this is multiple
Close Pesticidal combination to be configured on pesticide with insecticides adjuvant and excipient with bromine cyanogen insect amide and chlopyrifos as active insecticidal components
The dosage form allowed.
Brominated cyanogen insect amide the most according to claim 7 and the compound pesticide compositions of chlopyrifos, is characterized in that described
Dosage form is cream, suspending agent, aqueous emulsion, wettable powder, microemulsion or water dispersion granule.
9. the compound pesticide compositions of brominated cyanogen insect amide described in claim 1 and chlopyrifos prevents and treats resistance squama wing in preparation
Application on the insecticidal materials of mesh insect.
The compound pesticide compositions of brominated cyanogen insect amide the most according to claim 9 and chlopyrifos is at preparation preventing and treating cotton boll
Application on the insecticidal materials of worm or snout moths larva.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106689189A (en) * | 2016-12-19 | 2017-05-24 | 浙江新农化工股份有限公司 | Composition containing chlorpyrifos-methyl and amide pesticide and preparation and application of composition |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1988803A (en) * | 2004-07-26 | 2007-06-27 | 杜邦公司 | Mixtures of anthranilamide invertebrate pest control agents |
| WO2009138523A2 (en) * | 2008-05-12 | 2009-11-19 | Syngenta Participations Ag | Pesticidal compositions |
| CN102626069A (en) * | 2012-03-29 | 2012-08-08 | 广西田园生化股份有限公司 | Ultra-low volume liquid containing cyantraniliprole and organophosphorus insecticides |
| CN103283776A (en) * | 2012-03-01 | 2013-09-11 | 陕西韦尔奇作物保护有限公司 | Cyantraniliprole-containing pesticidal composition |
-
2016
- 2016-06-21 CN CN201610454540.6A patent/CN105941467A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1988803A (en) * | 2004-07-26 | 2007-06-27 | 杜邦公司 | Mixtures of anthranilamide invertebrate pest control agents |
| WO2009138523A2 (en) * | 2008-05-12 | 2009-11-19 | Syngenta Participations Ag | Pesticidal compositions |
| CN103283776A (en) * | 2012-03-01 | 2013-09-11 | 陕西韦尔奇作物保护有限公司 | Cyantraniliprole-containing pesticidal composition |
| CN102626069A (en) * | 2012-03-29 | 2012-08-08 | 广西田园生化股份有限公司 | Ultra-low volume liquid containing cyantraniliprole and organophosphorus insecticides |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106689189A (en) * | 2016-12-19 | 2017-05-24 | 浙江新农化工股份有限公司 | Composition containing chlorpyrifos-methyl and amide pesticide and preparation and application of composition |
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Application publication date: 20160921 |