CN105475339A - Synergistic insecticidal composition containing propargite and cycloprothrin and application thereof - Google Patents

Synergistic insecticidal composition containing propargite and cycloprothrin and application thereof Download PDF

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Publication number
CN105475339A
CN105475339A CN201511016775.9A CN201511016775A CN105475339A CN 105475339 A CN105475339 A CN 105475339A CN 201511016775 A CN201511016775 A CN 201511016775A CN 105475339 A CN105475339 A CN 105475339A
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Prior art keywords
propargite
cycloprothrin
synergistic insecticidal
insecticidal compositions
synergistic
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CN201511016775.9A
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CN105475339B (en
Inventor
邢刚
孙会杰
高瑞花
程清云
郭崇友
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Nanjing Huazhou Pharmaceutical Co Ltd
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Nanjing Huazhou Pharmaceutical Co Ltd
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond

Abstract

The invention discloses a synergistic insecticidal composition containing propargite and cycloprothrin and application thereof. The insecticidal composition takes propargite and cycloprothrin as main effective components, wherein the weight ratio of propargite to cycloprothrin ranges from (1:60) to (60:1). The composition provided by the invention can be used for preventing and treating a plurality of types of injurious insects, has a remarkable synergistic effect and can be used for expanding the insecticidal spectrum; the synergistic insecticidal composition has relatively high activity on prodenia litura, cabbage caterpillars, aphids, red spiders, spider mites, panonychus ulmi, soybean pod borers, leaf miners and the like of cotton, rice, soybeans, vegetables, fruit trees and tea trees; the dosage of pesticides is reduced, the residual amount of the pesticides on crops is reduced and the environmental pollution is alleviated; and the synergistic insecticidal composition is safe to human and livestock and has good environment compatibility, and the injurious insects cannot easily have drug resistance.

Description

A kind of Synergistic insecticidal compositions and application thereof containing propargite and cycloprothrin
Technical field
The invention belongs to pesticide field, be specifically related to a kind of be principle active component Pesticidal combination and the application thereof of propargite and cycloprothrin.
Background technology
Propargite (Propargite), molecular formula: C 19h 26o 4s, chemical name: 2-(4-tert-butyl benzene oxy) cyclohexyl propine-2-base sulfite.Structural formula is:
Propargite is broad spectrum activity, efficient, low toxicity miticide, has and tags and stomach poison function, without infiltration and systemic action.If to children mite with to become mite effective, ovicidal effect is poor.Can effectively preventing and treating apple-tree, cotton, cucumber, grape, corn, soybean, spider mite kind insect on tomato and vegetables.
Cycloprothrin (Cyclopropanecarboxylicacid), structural formula:
A kind of low toxicity pyrethroid insecticides of cycloprothrin, based on action of contace poison, has certain stomach poison function, without interior suction and fumigation action.This product insecticidal spectrum is wide, except the control being mainly used in rice grub, also can be used for the control of other insect such as dry crop, fruit and vegetables, has repellent and Antifeedant Effects, to plant safety.Be mainly used in water prevention Lissorhoptrus oryzophilus Kuschel, Lissorhoptrus oryzophilus Kuschel snout moth's larva, rice leafhopper, cabbage caterpillar, prodenia litura, aphid, soybean pod borer, tea olethreutid, Scirothrips dorsalis, fruit tree budworm, citrus leaf-miner, peach fruit borer, cotton bollworm etc.
Containing the insecticide variety of single component often existing defects in agricultural chemicals control of insect: use is easily developed immunity to drugs continuously, and insecticidal spectrum is narrow, and can not provide comprehensive protection for crop, peasant's drug cost is high.Being combined in and can overcoming above-mentioned shortcoming to a certain extent to a certain extent by two kinds or various active component in the coming year.There is two kinds of synergistic effect or the combination mixture of two or more active component, can preventive effect be improved, reduce active ingredient ground dosage, cost-saving, slow down pest resistance and to occur and can expanding prevention spectrum, play that many worms are double to be controlled, reduce the use cost of peasant.
Summary of the invention
The object of the invention is to for above-mentioned various problem, in order to overcome and delay pesticide resistance to existing agricultural chemicals, expand and kill mite spectrum, strengthen drug effect, reduce drug cost, thus provide a kind of Pesticidal combination preventing and treating various crop Acarina, Semiptera, lepidopterous insect pest.
A further object of the invention is to provide the purposes of this Pesticidal combination.
Measure of the present invention is realized by following measures.
Containing a Pesticidal combination for propargite and cycloprothrin, this Synergistic insecticidal compositions is with propargite and cycloprothrin for principle active component, and wherein, the weight ratio of propargite and cycloprothrin is 1:60 ~ 60:1.
Described Pesticidal combination, wherein the more excellent weight ratio of propargite and cycloprothrin is 1:50 ~ 30:1.Preferably the weight ratio of propargite and cycloprothrin is 1:20 ~ 20:1 further, then the weight ratio of further preferably propargite and cycloprothrin is 1:1 ~ 10, and most preferably the weight ratio of propargite and cycloprothrin is 1:5 ~ 10.The weight ratio of propargite and cycloprothrin can also be 1:10,1:5,1:10,1:2,1:3,1:1.
Described Pesticidal combination, wherein the weight ratio of propargite and the shared preparations of cycloprothrin two kinds of active principles accumulation is 0.5% ~ 90%, preferably 1 ~ 60%.
Described Pesticidal combination, with propargite and cycloprothrin for principle active component (active component) and auxiliary agent and/or excipient are processed into any one formulation that agricultural chemicals allows.The formulation that can be processed into is missible oil, suspending agent, aqueous emulsion, microemulsion, pulvis, wetting powder, dispersible oil-suspending agent and water dispersible granules etc.Described auxiliary agent can adopt calcium dodecyl benzene sulfonate, alkylphenol polyoxyethylene, the rare block compound of polyoxyethylene polyoxy third (as agriculture breast 33 #), polyoxyethylene nonylphenol ether etc., excipient comprises cyclohexanone, dimethylbenzene, solvent naphtha, water, antifreezing agent (as propane diols), deionized water etc.Above auxiliary agent, excipient and other agriculturally known auxiliary material can be alone or and use.
The above-mentioned Synergistic insecticidal compositions containing propargite and cycloprothrin is preparing the application of insecticide of the Acarina prevented and treated on paddy rice, fruit tree, soybean, tea tree, vegetables, cotton, Semiptera, lepidoptera pest.Described lepidoptera pest is cabbage caterpillar, cotton bollworm, leaf miner, beet armyworm, and Hemipteran pest is aphid, and mite pest is citrus red mite, tetranychid, Panonychus citri.
Synergistic insecticidal compositions antagonism mite pest of the present invention has significant preventive effect, especially has good preventive effect for the easy various pests producing resistance such as tetranychid, two spotted spider mite, Panonychus citri; And suppress insect produce the pesticide resistance of unitary agent (propargite or cycloprothrin) and can the lepidoptera pests such as soybean pod borer be prevented and treated simultaneously.
Pesticidal combination of the present invention compared with prior art, produces following beneficial effect: (1), compared with single dose, the control of said composition to insect has notable synergistic, and control efficiency significantly improves; (2) one medicines are controlled more, and a dispenser can prevent and treat various pests simultaneously, reduce control recruitment cost; By the described insecticidal materials prepared containing the Synergistic insecticidal compositions of propargite and cycloprothrin prevent and treat mite roughly the same time, lepidoptera pest can be prevented and treated again, there is good preventive effect to cotton cotton bollworm, paddy rice weevil, soybean pod borer, cabbage caterpillar and beet armyworm especially, reach the effect that a medicine is controlled more.(3) alternative high-toxic pesticide, and significantly reduce field dosage, effectively reduce environmental pollution and residue of pesticide; (4) have concurrently quick-acting and long-acting; (5) compared with propargite single dose, produce and use cost reduction; (6) insect is suppressed to strengthen the resistance of agricultural chemicals.
Embodiment
Embodiments of the invention are the methods adopting indoor bioassay and field trial to combine.First by indoor bioassay, the co-toxicity coefficient after clear and definite two kinds of medicaments are composite by a certain percentage; On this basis, then carry out field trial.
Embodiment 1:
Propargite and cycloprothrin different ratio co-toxicity
Take propargite, cycloprothrin employing conventional formulation method is mixed with by different proportion the propargite cycloprothrin suspending agent that principle active component weight percentage is 30%.Concrete ratio is in table 1.
Adopt dipping slide to measure propargite and cycloprothrin and composite sample thereof to the virulence of citrus red mite, often process repetition 3 times, every concentration process 30, uses LC 50value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient:
: table 1 propargite, cycloprothrin and composite sample thereof are to the toxicity test of citrus red mite and co-toxicity coefficient
In table, data show, have synergistic effect after propargite and cycloprothrin mixture to citrus red mite, and four proportioning co-toxicity coefficients listed in table are all greater than 120, and therefore propargite and cycloprothrin mixture have significant synergies.
Embodiment 2:
Take propargite, cycloprothrin employing conventional formulation method is mixed with by different proportion the propargite cycloprothrin missible oil that principle active component weight percentage is 30%.Concrete ratio is in table 2.
Test method is first soaked method that leaf connects worm again and is measured propargite and cycloprothrin and composite sample thereof to the virulence of cabbage caterpillar, often processes repetition 3 times, uses LC 50value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient:
Table 2 propargite, cycloprothrin and composite sample thereof are to the toxicity test of cabbage caterpillar and co-toxicity coefficient
In table, data show, have synergistic effect after propargite and cycloprothrin mixture to cabbage caterpillar, and four proportioning co-toxicity coefficients listed in table are all much larger than 120, and therefore propargite and cycloprothrin mixture have significant synergies.
Embodiment 3:
Take 5g propargite, 20g cycloprothrin, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, dimethylbenzene to 100g, the method above raw material being prepared routinely missible oil drops in mixing kettle and mixes, and forms the propargite cycloprothrin missible oil that principle active component weight percentage is 25%.
Adopt embodiment 3 sample product to carry out the field trial of control in field citrus red mite, contrast medicament is 57% propargite EC and 2.0% cycloprothrin GR, and concrete consumption is in table 3, every mu of water consumption is 30kg, looks into 3 days after medicine, 7 days, 14 days, 28 days results, result of the test is in table 3:
Table 3 example 3 sample is to the field test results of citrus red mite
Example 3 pairs of citrus red mites have fabulous quick-acting as can be seen from Table 3, and the lasting period is long, good at variable rate technology, are the outstanding medicaments of control citrus red mite.
Embodiment 4:
Adopt embodiment 3 sample product to carry out the field trial of control in field cabbage caterpillar, contrast medicament is 57% propargite EC and 2.0% cycloprothrin GR, and concrete consumption is in table 4, every mu of use water is 30kg, looks into 3 days after medicine, 7 days, 14 days, 28 days results, result of the test is in table 4:
Table 4 example 3 sample is to the field test results of cabbage caterpillar
Example 3 sample has fabulous effect to cabbage caterpillar as can be seen from Table 4, and the lasting period is long, good at variable rate technology, is the outstanding medicament preventing cabbage caterpillar.
Measure through indoor synergism test and show: all have significant synergistic insecticidal action by propargite and cycloprothrin built agent to citrus red mite and cabbage caterpillar; Field control effectiveness test equally also shows that the insecticidal effect of all built agent of the present invention to citrus red mite and cabbage caterpillar is all significantly higher than the effect of corresponding single dose agricultural chemicals.
Embodiment 5
Take propargite, cycloprothrin employing conventional formulation method is mixed with by different proportion the propargite cycloprothrin suspending agent that principle active component weight percentage is 30%.Concrete ratio is in table 5.
Test method adopts feed to add malicious method and measures propargite and cycloprothrin and composite sample thereof to the virulence of wheat aphid, often processes repetition 3 times, uses LC 50value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient:
Table 5 propargite, cycloprothrin and composite sample thereof are to the toxicity test of wheat aphid and co-toxicity coefficient
Embodiment 6
Adopt embodiment 3 sample product to carry out the field trial of control in field wheat aphid, contrast medicament is 57% propargite EC and 2.0% cycloprothrin GR, and concrete consumption is in table 6, every mu of use water is 30kg, looks into 3 days after medicine, 7 days, 14 days, 28 days results, result of the test is in table 6:
Table 6 example 3 sample is to the field test results of wheat aphid
Example 3 sample has fabulous effect to wheat aphid as can be seen from Table 6, and the lasting period is long, good at variable rate technology, is the outstanding medicament preventing wheat aphid.
Measure through indoor synergism test and show: all have significant synergistic insecticidal action by propargite and cycloprothrin built agent to citrus red mite and cabbage caterpillar, wheat aphid; Field control effectiveness test equally also shows that the insecticidal effect of all built agent of the present invention to citrus red mite and cabbage caterpillar, wheat aphid is all significantly higher than the effect of corresponding single dose agricultural chemicals.
Embodiment 7:
Take 0.2g propargite, 20g cycloprothrin, lignin 10g, Negel 2g, add to 100g with kaolin, above raw material is mixed in micronizer, forms the propargite cycloprothrin wetting powder that principle active component weight percentage is 20.2%.
Embodiment 8:
Take 78g propargite, 0.5g cycloprothrin, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 6g, dimethylbenzene adds to 100g, the method above raw material being prepared routinely missible oil drops in mixing kettle and mixes, and forms the propargite cycloprothrin missible oil that principle active component weight percentage is 78.5%.
Embodiment 9:
Take 2g propargite, 10g cycloprothrin, nonyl phenol phosphate 5g, alkylphenol polyoxyethylene 4g, the dimethylbenzene of n-butanol 3g, 30g and the pyrrolidones of 20g, the xanthans of 0.1g, all the other supply 100g with water, n-butanol and water-soluble solution form aqueous phase, and all the other component mix and blends form oil phase, slowly aqueous phase is added in oil phase and go under clipper effect, and continue shearing 10 ~ 30 minutes, form the propargite cycloprothrin aqueous emulsion that principle active component weight percentage is 12%.
Embodiment 10:
Take 10g propargite, 30g cycloprothrin, calcium dodecyl benzene sulfonate 5g, alkylphenol polyoxyethylene 4g, the solvent xylene of 30g and the pyrrolidones of 15g, all the other complement to 100g with water, former medicine, solvent, emulsifier, cosolvent mix and blend form homogeneous phase transparent solution, then slowly add water and stir and form clear solution, be the propargite cycloprothrin microemulsion that principle active component weight percentage is 40%.
Embodiment 11:
Take 4g propargite, 4g cycloprothrin, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 3g, dimethylbenzene to 100g.The method above raw material being prepared routinely missible oil drops in mixing kettle and mixes, and forms the propargite cycloprothrin missible oil that principle active component weight percentage is 8%.
Embodiment 12:
Take 3g propargite, 30g cycloprothrin, sodium lignin sulfonate 3g, polyoxyethylene poly-oxygen propylene aether and sulphate 4g thereof, xanthans 0.2g, ethylene glycol 10g, silica ethane 0.1g, aluminium-magnesium silicate 0.5g, supplies 100g with water, forms the propargite cycloprothrin suspending agent that principle active component weight percentage is 33% under the effect of sand mill.
Embodiment 13:
Take 5g propargite, 60g cycloprothrin, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether 15g, dimethylbenzene to 100g, the method above raw material being prepared routinely missible oil drops in mixing kettle and mixes, and forms the propargite cycloprothrin missible oil that principle active component weight percentage is 65%.
Embodiment 14:
Take 45g propargite, 5g cycloprothrin, sodium lignin sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, borax 2g, kaolin 28g, forms by the method for water dispersion granule the propargite cycloprothrin water dispersible granules that principle active component weight percentage is 50% by above raw material.
Embodiment 15:
Take 25g propargite, 25g cycloprothrin, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether 15g, dimethylbenzene to 100g, the method above raw material being prepared routinely missible oil drops in mixing kettle and mixes, and forms the propargite cycloprothrin missible oil that principle active component weight percentage is 50%.

Claims (10)

1., containing a Synergistic insecticidal compositions for propargite and cycloprothrin, it is characterized in that this Synergistic insecticidal compositions with propargite and cycloprothrin for principle active component, wherein, the weight ratio of propargite and cycloprothrin is 1:60 ~ 60:1.
2. the Synergistic insecticidal compositions containing propargite and cycloprothrin according to claim 1, is characterized in that the effective ingredient propargite of this Pesticidal combination and the weight ratio of cycloprothrin are 1:50 ~ 30:1.
3. the Synergistic insecticidal compositions containing propargite and cycloprothrin according to claim 2, is characterized in that the effective ingredient propargite of this Pesticidal combination and the weight ratio of cycloprothrin are 1:20 ~ 20:1.
4. the Synergistic insecticidal compositions containing propargite and cycloprothrin according to claim 3, is characterized in that the effective ingredient propargite of this Pesticidal combination and the weight ratio of cycloprothrin are 1:1 ~ 10.
5. the Synergistic insecticidal compositions containing propargite and cycloprothrin according to claim 4, is characterized in that the effective ingredient propargite of this Pesticidal combination and the weight ratio of cycloprothrin are 1:5 ~ 10.
6. the Synergistic insecticidal compositions containing propargite and cycloprothrin according to claim 1, both its feature propargite and the cycloprothrin weight percentage in this Synergistic insecticidal compositions is 0.5% ~ 90%.
7. the Synergistic insecticidal compositions containing propargite and cycloprothrin according to claim 1, is characterized in that with propargite and cycloprothrin for principle active component and auxiliary agent and/or excipient are processed into any one formulation that agricultural chemicals allows.
8. the Synergistic insecticidal compositions containing propargite and cycloprothrin according to claim 7, is characterized in that described formulation is missible oil, wetting powder, microemulsion, aqueous emulsion, suspending agent, pulvis or water dispersion granule.
9. the application of Synergistic insecticidal compositions in the insecticide for the preparation of the Acarina prevented and treated on paddy rice, fruit tree, soybean, tea tree, vegetables, cotton, Semiptera, lepidoptera pest containing propargite and cycloprothrin according to claim 1.
10. application according to claim 9, it is characterized in that described lepidoptera pest is cabbage caterpillar, cotton bollworm, leaf miner, beet armyworm, Hemipteran pest is aphid, and mite pest is citrus red mite, tetranychid, Panonychus citri.
CN201511016775.9A 2015-12-29 2015-12-29 A kind of Synergistic insecticidal compositions and its application containing propargite and cycloprothrin Active CN105475339B (en)

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Cited By (1)

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CN106070298A (en) * 2016-05-31 2016-11-09 刘园 A kind of compositions preventing and treating corn smut and preparation method thereof

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