CN103039500A - Synergistic insecticidal composition containing tolfenpxrad and cyfloxylate and application thereof - Google Patents

Synergistic insecticidal composition containing tolfenpxrad and cyfloxylate and application thereof Download PDF

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Publication number
CN103039500A
CN103039500A CN2011103158719A CN201110315871A CN103039500A CN 103039500 A CN103039500 A CN 103039500A CN 2011103158719 A CN2011103158719 A CN 2011103158719A CN 201110315871 A CN201110315871 A CN 201110315871A CN 103039500 A CN103039500 A CN 103039500A
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China
Prior art keywords
cyfloxylate
tolfenpyrad
synergistic insecticidal
insecticidal compositions
synergistic
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CN2011103158719A
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Chinese (zh)
Inventor
陈文明
刘奎涛
杨晓生
沈海峰
王静
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Nanjing Huazhou Pharmaceutical Co Ltd
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Nanjing Huazhou Pharmaceutical Co Ltd
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Priority to CN2011103158719A priority Critical patent/CN103039500A/en
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Abstract

The invention discloses a synergistic insecticidal composition containing tolfenpxrad and cyfloxylate and an application thereof. The insecticidal composition takes the tolfenpxrad and the cyfloxylate as main active ingredients, wherein the weight ratio of the tolfenpxrad to the cyfloxylate is (0.1-80):(0.5-80). The insecticidal composition has the effects of expanding a control spectrum and realizing synergy, can reduce the cost of medication, can be prepared into missible oil, wettable powder, micro-emulsion, aqueous emulsion, suspension and water dispersible granules, and can be used for controlling lepidoptera, homoptera, hymenoptera, coleoptera and other various pests.

Description

A kind of Synergistic insecticidal compositions and application thereof that contains Tolfenpyrad and cyfloxylate
Technical field
The invention belongs to pesticide field, be specifically related to a kind of Synergistic insecticidal compositions and application thereof that contains Tolfenpyrad and cyfloxylate.
Background technology
Tolfenpyrad (Tolfenpyrad), chemical name: 4-chloro-3-ethyl-1-methyl-N-{[4-(4-methylphenoxy) phenyl]-methyl }-1H pyrazoles-5-carboxylic acid amides, be the off-white color pressed powder, density (25 ℃): 1.18g/cm, vapour pressure (25 ℃):<5 * 10Pa.Solvability (25 ℃): water 0.037mg/L, n-hexane 7.41g/L, toluene 366g/L, methyl alcohol 59.6g/L.Distribution coefficient (n-octyl alcohol/water) (25 ℃): log Pow 5.61.Structural formula is:
The acute toxicity of Tolfenpyrad preparation is: rat oral LD50 102 (hero), 83 (female) mg/kg; Its mouse oral LD50104 (hero), 108 (female) mg/kg.Acute dermal toxicity is relatively low, to rat, mouse LD50 all>2000mg/kg.Lagophthalmos eyeball and skin there is moderate spread effect.
Tolfenpyrad is the novel pyrazole heterocyclic insecticidal/acaricidal agent of former Mitsubishi chemical company (its agricultural chemicals partly now belong to Japanese agricultural chemicals company) exploitation, its main mechanism is the oxidative phosphorylation that stops insect, also has ovicidal, presses down food, oviposition deterrence and bactericidal action.
Cyfloxylate (cyfluthrin) has another name called cyfluthrin, chemical name: alpha-cyano-3-phenoxy group-4-luorobenzyl (1R, 3R)-3-(2,2-dichloroethylene)-2, and 2-dimethyl cyclopropane carboxylic acid ester, structural formula is:
Cyfloxylate belongs to pyrethroid insecticides, acts on the nervous system of insect, can knock down fast, and the longevity of residure is long.Multiple lepidopterous larvae is had good result, also can effectively prevent and treat some soil insect, insecticidal spectrum is wide, and effect is rapid, and the lasting period is long, to the mammal low toxicity, to crop safety, is applicable to cotton, fruit tree, vegetables, tea tree, tobacco, soybean etc.
Often there is defective in the insecticide variety that contains single component in the agricultural chemicals control of insect: use is developed immunity to drugs easily continuously, and insecticidal spectrum is narrow, can not provide comprehensive protection for crop, and peasant's drug cost is high.Being combined in to a certain extent and can overcoming to a certain extent above-mentioned shortcoming by two kinds or various active components in the coming year.Have two kinds of synergistic effect or the combination of two or more active components and be mixed, can improve preventive effect, reduce active ingredient ground dosage, save cost, slow down pest resistance occur, and can the expanding prevention spectrum, play that many worms are double to be controlled, reduce peasant's use cost.
Summary of the invention
The purpose of this invention is to provide a kind of Synergistic insecticidal compositions that contains Tolfenpyrad and cyfloxylate, said composition can be used for preventing and treating the various agricultural insect, for example control vegetables diamond-back moth, cabbage caterpillar, control cotton cotton bollworm, beet armyworm etc. can also be used for, the effect that a drug is prevented and treated dissimilar insects can be reached.
Another object of the present invention provides the Synergistic insecticidal compositions that contains Tolfenpyrad and cyfloxylate and prevents and treats application in the insecticidal materials of one or more insects in resistance Lepidoptera, Homoptera, Hymenoptera or the coleoptera in preparation.
The present invention adopts following technical scheme:
A kind of Synergistic insecticidal compositions that contains Tolfenpyrad and cyfloxylate, it is take Tolfenpyrad and cyfloxylate as main active ingredient, wherein, the weight ratio of Tolfenpyrad and cyfloxylate is 0.1~80: 0.5~80, be preferably 1~60: 1~70, more preferably 1~30: 1~30, particularly preferably 1: 1~10.The effective ingredient of above-mentioned Insecticidal combinations is present in the composition with the synergy effective dose.
At the Synergistic insecticidal compositions that contains Tolfenpyrad and cyfloxylate of the present invention, the two weight percentage in this Synergistic insecticidal compositions of Tolfenpyrad and cyfloxylate is 2%~80%, is preferably 8%~60%, and optimum is 20%~40%.
The above-mentioned Synergistic insecticidal compositions that contains Tolfenpyrad and cyfloxylate take Tolfenpyrad and cyfloxylate as main active ingredient (active component) and insecticides adjuvant, excipients be mixed with any one formulation that allows on the agricultural chemicals.The preferred missible oil of formulation, wetting powder, microemulsion, aqueous emulsion, suspending agent or water dispersion granule.
Described auxiliary agent can adopt calcium dodecyl benzene sulfonate, alkylphenol polyoxyethylene, polyoxyethylene polyoxy third rare block compound (such as the newborn 33# of farming), polyoxyethylene nonylphenol ether, cyclohexanone, dimethylbenzene, solvent naphtha, water, antifreezing agent (such as propane diols), deionized water etc.Above auxiliary agent and the upper known auxiliary material of other agricultural can alone or and usefulness.
The application of Synergistic insecticidal compositions in preparing the insecticidal materials of preventing and treating one or more insects in Lepidoptera, Homoptera, Hymenoptera, thrips or the coleoptera that contains Tolfenpyrad and cyfloxylate of the present invention, the preferably application in the insecticidal materials of preparation control cotton cotton bollworm, beet armyworm or vegetables diamond-back moth.
Pesticidal combination of the present invention compared with prior art, produce following beneficial effect: (1) is compared with single dose, said composition has obvious synergistic function to the control of one or more insects in Lepidoptera, Homoptera, Hymenoptera, thrips or the coleoptera, has obviously improved control efficiency; (2) one medicines are controlled more, and a dispenser can prevent and treat various pests simultaneously, reduce control recruitment cost; (3) alternative high-toxic pesticide, and significantly reduce the field dosage, effective environmental contamination reduction and residue of pesticide; (4) have concurrently quick-acting and long-acting; (5) compare with the Tolfenpyrad single dose, produce and the use cost reduction; (6) suppress insect to the resistance enhancing of agricultural chemicals.
Embodiment
Embodiments of the invention are the methods that adopt indoor bioassay and field trial to combine.First by indoor bioassay, the co-toxicity coefficient after clear and definite two kinds of medicaments are composite by a certain percentage; On this basis, carry out again field trial.
Embodiment 1:
Taking by weighing Tolfenpyrad, cyfloxylate, to adopt the conventional formulation method to be mixed with main active ingredient weight percentage by different proportion be 30% Tolfenpyrad cyfluthrin.Concrete ratio sees Table 1.
Adopt feed to add malicious method and measure Tolfenpyrad and cyfloxylate and composite sample thereof to the virulence of cotton cotton bollworm, every processing repeats 3 times, and every concentration is processed 30, uses LC 50Value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient:
Table 1 Tolfenpyrad, cyfloxylate and composite sample thereof are to toxicity test and the co-toxicity coefficient of cotton cotton bollworm
Data show in the table, and Tolfenpyrad and cyfloxylate are mixed and rear the cotton cotton bollworm are had synergistic effect, and four listed in table proportioning co-toxicity coefficients are all much larger than 120, so Tolfenpyrad and cyfloxylate are mixed and have significant synergistic function.The synergistic function maximum that wherein is mixed when the ratio of cyfloxylate and Tolfenpyrad is 10: 1 and kills the cotton cotton bollworm, co-toxicity coefficient is 133.3.
Embodiment 2:
Taking by weighing Tolfenpyrad, cyfloxylate, to adopt the conventional formulation method to be mixed with main active ingredient weight percentage by different proportion be 30% Tolfenpyrad cyfluthrin.Concrete ratio sees Table 2.
Adopt rice stem infusion process to measure Tolfenpyrad and cyfloxylate and composite sample thereof to the virulence of diamond-back moth, every processing repeats 3 times, uses LC 50Value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient:
Table 2 Tolfenpyrad, cyfloxylate and composite sample thereof are to toxicity test and the co-toxicity coefficient of diamond-back moth
Data show in the table, and Tolfenpyrad and cyfloxylate are mixed and rear diamond-back moth are had synergistic effect, and four listed in table proportioning co-toxicity coefficients are all much larger than 120, so Tolfenpyrad and cyfloxylate are mixed and have significant synergistic function.The synergistic function maximum that wherein is mixed when the ratio of Tolfenpyrad and cyfloxylate is 1: 1 and kills diamond-back moth, co-toxicity coefficient is 189.7.
Embodiment 3:
Take by weighing 5g Tolfenpyrad, 20g cyfloxylate, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, dimethylbenzene to 100g, the method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms main active ingredient weight percentage and be 25% Tolfenpyrad cyfluthrin.
Adopt 3 sample product of embodiment to carry out the field trial of control in field cotton cotton bollworm, the contrast medicament is 15% Tolfenpyrad EC and 5.7% cyfloxylate EC, and with clear water as blank, concrete consumption sees Table 3, and every mu of water consumption is 30kg, looks into behind the medicine 3 days, 7 days, 14 days, 28 days results, result of the test sees Table 3:
Table 3 example 3 samples are to the field test results of cotton cotton bollworm
3 pairs of cotton cotton bollworms of example have fabulous quick-acting as can be seen from Table 3, and the lasting period is more intense, in the field performance well, are the outstanding medicaments of control cotton cotton bollworm.
Embodiment 4:
Adopt 3 sample product of embodiment to carry out the field trial of control in field vegetables diamond-back moth, the contrast medicament is 15% Tolfenpyrad EC and 5.7% cyfloxylate EC, and with clear water as blank, concrete consumption sees Table 4, and every mu of water consumption is 30kg, looks into behind the medicine 3 days, 7 days, 14 days, 28 days results, result of the test sees Table 4:
Table 4 example 3 samples are to the field test results of diamond-back moth
Example 3 samples have fabulous effect to diamond-back moth as can be seen from Table 4, and the lasting period is long, in the field performance well, are the outstanding medicaments that prevents diamond-back moth.
Show through indoor synergism test mensuration: by Tolfenpyrad and cyfloxylate built agent cotton cotton bollworm and diamond-back moth are all had significant synergistic insecticidal action; Field control effectiveness test shows that equally also all built agents of the present invention all are significantly higher than the effect of corresponding single dose agricultural chemicals to the insecticidal effect of cotton cotton bollworm and diamond-back moth.
Embodiment 5:
Take by weighing 0.2g Tolfenpyrad, 20g cyfloxylate, lignin 10g, Negel 2g, add to 100g with kaolin, above raw material is mixed in micronizer, form main active ingredient weight percentage and be 20.2% Tolfenpyrad cyfloxylate wetting powder.
Embodiment 6:
Take by weighing 78g Tolfenpyrad, 0.5g cyfloxylate, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 6g, dimethylbenzene and add to 100g, the method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms main active ingredient weight percentage and be 78.5% Tolfenpyrad cyfluthrin.
Embodiment 7:
Take by weighing 2g Tolfenpyrad, 10g cyfloxylate, nonyl phenol phosphate 5g, alkylphenol polyoxyethylene 4g, n-butanol 3g, the dimethylbenzene of 30g and the pyrrolidones of 20g, the xanthans of 0.1g, all the other waters are supplied 100g, n-butanol and water-soluble solution form water, and all the other component mix and blends form oil phase, slowly water are added in the oil phase under the clipper effect and go, and continue to shear 10~30 minutes, form main active ingredient weight percentage and be 12% Tolfenpyrad cyfloxylate aqueous emulsion.
Embodiment 8:
Take by weighing 10g Tolfenpyrad, 30g cyfloxylate, calcium dodecyl benzene sulfonate 5g, alkylphenol polyoxyethylene 4g, the solvent xylene of 30g and the pyrrolidones of 15g, all the other waters complement to 100g, former medicine, solvent, emulsifier, cosolvent mix and blend form homogeneous phase transparent solution, then slowly add entry and stir to form clear solution, be main active ingredient weight percentage and be 40% Tolfenpyrad cyfloxylate microemulsion.
Embodiment 9:
Take by weighing 4g Tolfenpyrad, 4g cyfloxylate, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 3g, dimethylbenzene to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms main active ingredient weight percentage and be 8% Tolfenpyrad cyfluthrin.
Embodiment 10:
Take by weighing 3g Tolfenpyrad, 30g cyfloxylate, sodium lignin sulfonate 3g, polyoxyethylene poly-oxygen propylene aether and sulphate 4g thereof, xanthans 0.2g, ethylene glycol 10g, silica ethane 0.1g, aluminium-magnesium silicate 0.5g, water is supplied 100g, and the main active ingredient weight percentage of formation is 33% Tolfenpyrad cyfloxylate suspending agent under the effect of sand mill.
Embodiment 11:
Take by weighing 5g Tolfenpyrad, 60g cyfloxylate, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether 15g, dimethylbenzene to 100g, the method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms main active ingredient weight percentage and be 65% Tolfenpyrad cyfluthrin.
Embodiment 12:
Take by weighing 45g Tolfenpyrad, 5g cyfloxylate, sodium lignin sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, borax 2g, kaolin 28g, it is 50% Tolfenpyrad cyfloxylate water dispersible granules that above raw material is formed main active ingredient weight percentage by the method for water dispersion granule.
Embodiment 13:
Take by weighing 25g Tolfenpyrad, 25g cyfloxylate, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether 15g, dimethylbenzene to 100g, the method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms main active ingredient weight percentage and be 50% Tolfenpyrad cyfluthrin.

Claims (10)

1. Synergistic insecticidal compositions that contains Tolfenpyrad and cyfloxylate is characterized in that this Synergistic insecticidal compositions take Tolfenpyrad and cyfloxylate as main active ingredient, and wherein, the weight ratio of Tolfenpyrad and cyfloxylate is 0.1~80: 0.5~80.
2. the Synergistic insecticidal compositions that contains Tolfenpyrad and cyfloxylate according to claim 1 is characterized in that the effective ingredient Tolfenpyrad of this Pesticidal combination and the weight ratio of cyfloxylate are 1~60: 1~70.
3. the Synergistic insecticidal compositions that contains Tolfenpyrad and cyfloxylate according to claim 2 is characterized in that the effective ingredient Tolfenpyrad of this Pesticidal combination and the weight ratio of cyfloxylate are 1~30: 1~30, preferred 1: 1~10.
4. the Synergistic insecticidal compositions that contains Tolfenpyrad and cyfloxylate according to claim 1 is characterized in that the two weight percentage in this Synergistic insecticidal compositions of Tolfenpyrad and cyfloxylate is 2%~80%.
5. the Synergistic insecticidal compositions that contains Tolfenpyrad and cyfloxylate according to claim 4 is characterized in that the two weight percentage in this Synergistic insecticidal compositions of Tolfenpyrad and cyfloxylate is 8%~60%.
6. the Synergistic insecticidal compositions that contains Tolfenpyrad and cyfloxylate according to claim 5 is characterized in that the two weight percentage in this Synergistic insecticidal compositions of Tolfenpyrad and cyfloxylate is 20%~40%.
7. the Synergistic insecticidal compositions that contains Tolfenpyrad and cyfloxylate according to claim 1 is characterized in that the auxiliary agent that allows on this Synergistic insecticidal compositions is take Tolfenpyrad and cyfloxylate as main active ingredient and agricultural chemicals is mixed with any one formulation.
8. the Synergistic insecticidal compositions that contains Tolfenpyrad and cyfloxylate according to claim 7 is characterized in that described formulation is missible oil, wetting powder, microemulsion, aqueous emulsion, suspending agent or water dispersion granule.
9. the application of Synergistic insecticidal compositions in preparing the insecticidal materials of preventing and treating one or more insects in Lepidoptera, Homoptera, Hymenoptera, thrips or the coleoptera that contains Tolfenpyrad and cyfloxylate claimed in claim 1.
10. application according to claim 9 is characterized in that containing the application of Synergistic insecticidal compositions in the insecticidal materials of preparation control cotton cotton bollworm, beet armyworm or vegetables diamond-back moth of Tolfenpyrad and cyfloxylate.
CN2011103158719A 2011-10-17 2011-10-17 Synergistic insecticidal composition containing tolfenpxrad and cyfloxylate and application thereof Pending CN103039500A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103190436A (en) * 2013-04-26 2013-07-10 柳州市惠农化工有限公司 Insecticidal composition
CN109984136A (en) * 2019-04-09 2019-07-09 江西正邦作物保护有限公司 A kind of Pesticidal combination containing Tolfenpyrad and ES- bioallethrin

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Publication number Priority date Publication date Assignee Title
US20040078843A1 (en) * 2001-02-03 2004-04-22 Manfred Kern Method for controlling harmful organisms in the culture of useful plants
CN101658178A (en) * 2009-07-22 2010-03-03 深圳诺普信农化股份有限公司 Synergistic insecticidal composition
CN101669478A (en) * 2009-10-13 2010-03-17 深圳诺普信农化股份有限公司 Pesticide combination
CN101690494A (en) * 2009-07-15 2010-04-07 深圳诺普信农化股份有限公司 Synergistic pesticide composition and use thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040078843A1 (en) * 2001-02-03 2004-04-22 Manfred Kern Method for controlling harmful organisms in the culture of useful plants
CN101690494A (en) * 2009-07-15 2010-04-07 深圳诺普信农化股份有限公司 Synergistic pesticide composition and use thereof
CN101658178A (en) * 2009-07-22 2010-03-03 深圳诺普信农化股份有限公司 Synergistic insecticidal composition
CN101669478A (en) * 2009-10-13 2010-03-17 深圳诺普信农化股份有限公司 Pesticide combination

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103190436A (en) * 2013-04-26 2013-07-10 柳州市惠农化工有限公司 Insecticidal composition
CN109984136A (en) * 2019-04-09 2019-07-09 江西正邦作物保护有限公司 A kind of Pesticidal combination containing Tolfenpyrad and ES- bioallethrin

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Application publication date: 20130417