CN103053536A - Synergistic insecticidal composition containing tolfenpyrad and ethofenprox and application - Google Patents
Synergistic insecticidal composition containing tolfenpyrad and ethofenprox and application Download PDFInfo
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- CN103053536A CN103053536A CN2011103173278A CN201110317327A CN103053536A CN 103053536 A CN103053536 A CN 103053536A CN 2011103173278 A CN2011103173278 A CN 2011103173278A CN 201110317327 A CN201110317327 A CN 201110317327A CN 103053536 A CN103053536 A CN 103053536A
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- tolfenpyrad
- chrysanthemum ester
- ether chrysanthemum
- synergistic insecticidal
- insecticidal compositions
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Abstract
The invention discloses a synergistic insecticidal composition containing tolfenpyrad and ethofenprox and an application, the synergistic insecticidal composition takes tolfenpyrad and ethofenprox as main effective components, wherein the weight ratio of tolfenpyrad to ethofenprox is 0.1-80:0.5-80. The insecticidal composition has effects for enlarging the prevention and cure scope and synergia, and the medication cost is reduced, and the synergistic insecticidal composition can be prepared to a missible oil, a wettable powder, a microemulsion, an emulsion in water, a suspending agent and a water dispersible granule, and the synergistic insecticidal composition can be used for preventing and treating various pests such as Lepidoptera, Homoptera, Hymenoptera, thysanoptera and coleopteran.
Description
Technical field
The invention belongs to pesticide field, be specifically related to a kind of Synergistic insecticidal compositions and application thereof that contains Tolfenpyrad and ether chrysanthemum ester.
Background technology
Tolfenpyrad (Tolfenpyrad), chemical name: 4-chloro-3-ethyl-1-methyl-N-{[4-(4-methylphenoxy) phenyl]-methyl }-1H pyrazoles-5-carboxylic acid amides, be the off-white color pressed powder, density (25 ℃): 1.18g/cm, vapour pressure (25 ℃):＜5 * 10Pa.Solvability (25 ℃): water 0.037mg/L, n-hexane 7.41g/L, toluene 366g/L, methyl alcohol 59.6g/L.Distribution coefficient (n-octyl alcohol/water) (25 ℃): log Pow 5.61.Structural formula is:
The acute toxicity of Tolfenpyrad preparation is: rat oral LD50 102 (hero), 83 (female) mg/kg; Its mouse oral LD50104 (hero), 108 (female) mg/kg.Acute dermal toxicity is relatively low, to rat, mouse LD50 all＞2000mg/kg.Lagophthalmos eyeball and skin there is moderate spread effect.
Tolfenpyrad is the novel pyrazole heterocyclic insecticidal/acaricidal agent of former Mitsubishi chemical company (its agricultural chemicals partly now belong to Japanese agricultural chemicals company) exploitation, its main mechanism is the oxidative phosphorylation that stops insect, also has ovicidal, presses down food, oviposition deterrence and bactericidal action.
Ether chrysanthemum ester (etofenprox) has another name called trebon, chemical name: 2-(4-ethoxyl phenenyl)-2-methyl-propyl-3-benzyloxy phenoxy base ether, and structural formula is:
Without chrysanthemumic acid but because of space structure and pyrethroid similarity is arranged in the ether chrysanthemum ester structure, so still be called the insecticide of similar pyrethroid, have that insecticidal spectrum is wide, insecticidal activity is high, knock down that speed is fast, the lasting period is long, less to natural enemy lethality such as paddy field spiders, to advantages such as crop safeties.
Often there is defective in the insecticide variety that contains single component in the agricultural chemicals control of insect: use is developed immunity to drugs easily continuously, and insecticidal spectrum is narrow, can not provide comprehensive protection for crop, and peasant's drug cost is high.By two kinds or the coming year various active components be combined in to a certain extent the above-mentioned shortcoming of to a certain extent customer service.Have two kinds of synergistic effect or the combination of two or more active components and be mixed, can improve preventive effect, reduce active ingredient ground dosage, save cost, slow down pest resistance occur, and can the expanding prevention spectrum, play that many worms are double to be controlled, reduce peasant's use cost.
Summary of the invention
The purpose of this invention is to provide a kind of Synergistic insecticidal compositions that contains Tolfenpyrad and ether chrysanthemum ester.
Another object of the present invention provides the Synergistic insecticidal compositions that contains Tolfenpyrad and ether chrysanthemum ester and prevents and treats application in the insecticidal materials of one or more insects in resistance Lepidoptera, Homoptera, Hymenoptera, thrips or the coleoptera in preparation.
Said composition can be used for preventing and treating the various agricultural insect, and such as cotton cotton bollworm, beet armyworm, onion thrips, vegetables diamond-back moth, cabbage caterpillar etc. can reach the effect that a drug is prevented and treated dissimilar insects.
The present invention adopts following technical scheme:
A kind of Synergistic insecticidal compositions that contains Tolfenpyrad and ether chrysanthemum ester, it is take Tolfenpyrad and ether chrysanthemum ester as main active ingredient, and wherein, the weight ratio of Tolfenpyrad and ether chrysanthemum ester is 0.1～80: 0.5～80.Be preferably 1～60: 1～70, more preferably 1～30: 1～30.The effective ingredient of above-mentioned Insecticidal combinations is present in the composition with the synergy effective dose.
At the Synergistic insecticidal compositions that contains Tolfenpyrad and ether chrysanthemum ester of the present invention, Tolfenpyrad and the two weight percentage in this Synergistic insecticidal compositions of ether chrysanthemum ester are 2%～80%, are preferably 8%～60%, and optimum is 20%～40%.
The above-mentioned Synergistic insecticidal compositions that contains Tolfenpyrad and ether chrysanthemum ester take Tolfenpyrad and ether chrysanthemum ester as main active ingredient (active component) and insecticides adjuvant, excipients be mixed with any one formulation that allows on the agricultural chemicals.The preferred missible oil of formulation, wetting powder, microemulsion, aqueous emulsion, suspending agent or water dispersible granules.
Described auxiliary agent can adopt calcium dodecyl benzene sulfonate, alkylphenol polyoxyethylene, polyoxyethylene polyoxy third rare block compound (such as the newborn 33# of farming), polyoxyethylene nonylphenol ether etc., and excipient comprises cyclohexanone, dimethylbenzene, solvent naphtha, water, antifreezing agent (such as propane diols), deionized water etc.Above auxiliary agent, excipient and the upper known auxiliary material of other agricultural can alone or and usefulness.
Application in the insecticidal materials of the above-mentioned Synergistic insecticidal compositions that contains Tolfenpyrad and ether chrysanthemum ester one or more insects in preparation control Lepidoptera, Homoptera, Hymenoptera, thrips or coleoptera reaches the effect that a medicine is controlled more.Especially the effect in the insecticidal materials of the cotton cotton bollworm for preparing the easy generation of control resistance, beet armyworm, onion thrips, vegetables diamond-back moth, cabbage caterpillar etc. is remarkable, and suppresses insect to the pesticide resistance generation of unitary agent (Tolfenpyrad or ether chrysanthemum ester).
Pesticidal combination of the present invention compared with prior art, produce following beneficial effect: (1) is compared with single dose, the said composition insect has notable synergistic, has obviously improved control efficiency; (2) one medicines are controlled more, and a dispenser can prevent and treat various pests simultaneously, reduce control recruitment cost; (3) alternative high-toxic pesticide, and significantly reduce the field dosage, effective environmental contamination reduction and residue of pesticide; (4) have concurrently quick-acting and long-acting; (5) compare with the Tolfenpyrad single dose, produce and the use cost reduction; (6) suppress insect to the resistance enhancing of agricultural chemicals.
Embodiment
Embodiments of the invention are the methods that adopt indoor bioassay and field trial to combine.First by indoor bioassay, the co-toxicity coefficient after clear and definite two kinds of medicaments are composite by a certain percentage; On this basis, carry out again field trial.
Embodiment 1:
Taking by weighing Tolfenpyrad, ether chrysanthemum ester, to adopt the conventional formulation method to be mixed with main active ingredient weight percentage by different proportion be 30% Tolfenpyrad ether chrysanthemum emulsifiable concentrate.Concrete ratio sees Table 1.
Adopt feed to add malicious method and measure Tolfenpyrad and ether chrysanthemum ester and composite sample thereof to the virulence of cotton cotton bollworm, every processing repeats 3 times, and every concentration is processed 30, uses LC
50Value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient:
Table 1 Tolfenpyrad, ether chrysanthemum ester and composite sample thereof are to toxicity test and the co-toxicity coefficient of cotton cotton bollworm
Data show in the table, and Tolfenpyrad and ether chrysanthemum ester are mixed and rear the cotton cotton bollworm are had synergistic effect, and four listed in table proportioning co-toxicity coefficients are all greater than 100, so Tolfenpyrad and ether chrysanthemum ester are mixed and have significant synergies.The synergistic effect maximum that wherein is mixed when the ratio of ether chrysanthemum ester and Tolfenpyrad is 10: 1 and kills the cotton cotton bollworm, co-toxicity coefficient is 126.7.
Embodiment 2:
Taking by weighing Tolfenpyrad, ether chrysanthemum ester, to adopt the conventional formulation method to be mixed with main active ingredient weight percentage by different proportion be 30% Tolfenpyrad ether chrysanthemum emulsifiable concentrate.Concrete ratio sees Table 2.
Adopt rice stem infusion process to measure Tolfenpyrad and ether chrysanthemum ester and composite sample thereof to the virulence of onion thrips, every processing repeats 3 times, uses LC
50Value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient:
Table 2 Tolfenpyrad, ether chrysanthemum ester and composite sample thereof are to toxicity test and the co-toxicity coefficient of onion thrips
Data show in the table, and Tolfenpyrad and ether chrysanthemum ester are mixed and rear onion thrips are had synergistic effect, and four listed in table proportioning co-toxicity coefficients are all greater than 100, so Tolfenpyrad and ether chrysanthemum ester are mixed and have significant synergies.The synergistic effect maximum that wherein is mixed when the ratio of Tolfenpyrad and ether chrysanthemum ester is 1: 10 and kills onion thrips, co-toxicity coefficient is 139.4.
Embodiment 3:
Take by weighing 5g Tolfenpyrad, 20g ether chrysanthemum ester, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, add dimethylbenzene to 100g, the method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms main active ingredient weight percentage and be 25% Tolfenpyrad ether chrysanthemum emulsifiable concentrate.
Adopt 3 sample product of embodiment to carry out the field trial of control in field cotton cotton bollworm, the contrast medicament is 15% Tolfenpyrad EC (missible oil) and 10% ether chrysanthemum ester EW (aqueous emulsion), and concrete consumption sees Table 3, every mu of water consumption is 30kg, looks into 7 days behind the medicine 3 days, 14 days, 28 days results.Do blank with clear water, result of the test sees Table 3:
Table 3 example 3 samples are to the field test results of cotton cotton bollworm
3 pairs of cotton cotton bollworms of example have fabulous quick-acting as can be seen from Table 3, and the lasting period is more intense, in the field performance well, are the outstanding medicaments of control cotton cotton bollworm.
Embodiment 4:
Adopt 3 sample product of embodiment to carry out the field trial of control in field onion thrips, the contrast medicament is 15% Tolfenpyrad EC and 10% ether chrysanthemum ester EW, and concrete consumption sees Table 3, and every mu of water consumption is 30kg, looked into behind the medicine 3 days, and 7 days, 14 days, 28 days results.Do blank with clear water, result of the test sees Table 4:
Table 4 example 3 samples are to the field test results of onion thrips
Example 3 samples have fabulous effect to onion thrips as can be seen from Table 4, and the lasting period is long, in the field performance well, are the outstanding medicaments that prevents onion thrips.
Show through indoor synergism test mensuration: by Tolfenpyrad and ether chrysanthemum ester built agent cotton cotton bollworm and onion thrips are all had significant synergistic insecticidal action; Field control effectiveness test shows that equally also all built agents of the present invention all are significantly higher than the effect of corresponding single dose agricultural chemicals to the insecticidal effect of cotton cotton bollworm and onion thrips.
Embodiment 5:
Take by weighing 0.2g Tolfenpyrad, 19.8g ether chrysanthemum ester, lignin 10g, Negel 2g, add to 100g with kaolin, above raw material is mixed in micronizer, form main active ingredient weight percentage and be 20% Tolfenpyrad ether chrysanthemum ester wetting powder.
Embodiment 6:
Take by weighing 78g Tolfenpyrad, 0.5g ether chrysanthemum ester, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 6g, dimethylbenzene and add to 100g, the method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms main active ingredient weight percentage and be 78.5% Tolfenpyrad ether chrysanthemum emulsifiable concentrate.
Embodiment 7:
Take by weighing 2g Tolfenpyrad, 10g ether chrysanthemum ester, nonyl phenol phosphate 5g, alkylphenol polyoxyethylene 4g, n-butanol 3g, the dimethylbenzene of 30g and the pyrrolidones of 20g, the xanthans of 0.1g, all the other waters are supplied 100g, n-butanol and water-soluble solution form water, and all the other component mix and blends form oil phase, slowly water are added in the oil phase under the clipper effect and go, and continue to shear 10～30 minutes, form main active ingredient weight percentage and be 12% Tolfenpyrad ether chrysanthemum ester aqueous emulsion.
Embodiment 8:
Take by weighing 10g Tolfenpyrad, 30g ether chrysanthemum ester, calcium dodecyl benzene sulfonate 5g, alkylphenol polyoxyethylene 4g, the solvent xylene of 30g and the pyrrolidones of 15g, all the other waters complement to 100g, former medicine, solvent, emulsifier, cosolvent mix and blend form homogeneous phase transparent solution, then slowly add entry and stir to form clear solution, be main active ingredient weight percentage and be 40% Tolfenpyrad ether chrysanthemum ester microemulsion.
Embodiment 9:
Take by weighing 4g Tolfenpyrad, 4g ether chrysanthemum ester, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 3g, dimethylbenzene to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms main active ingredient weight percentage and be 8% Tolfenpyrad ether chrysanthemum emulsifiable concentrate.
Embodiment 10:
Take by weighing 3g Tolfenpyrad, 30g ether chrysanthemum ester, sodium lignin sulfonate 3g, polyoxyethylene poly-oxygen propylene aether and sulphate 4g thereof, xanthans 0.2g, ethylene glycol 10g, silica ethane 0.1g, aluminium-magnesium silicate 0.5g, water is supplied 100g, and the main active ingredient weight percentage of formation is 33% Tolfenpyrad ether chrysanthemum ester suspending agent under the effect of sand mill.
Embodiment 11:
Take by weighing 5g Tolfenpyrad, 55g ether chrysanthemum ester, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether 15g, dimethylbenzene to 100g, the method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms main active ingredient weight percentage and be 60% Tolfenpyrad ether chrysanthemum emulsifiable concentrate.
Embodiment 12:
Take by weighing 45g Tolfenpyrad, 5g ether chrysanthemum ester, sodium lignin sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, borax 2g, kaolin 28g, it is 50% Tolfenpyrad ether chrysanthemum ester water dispersible granules that above raw material is formed main active ingredient weight percentage by the method for water dispersion granule.
Embodiment 13:
Take by weighing 30g Tolfenpyrad, 1g ether chrysanthemum ester, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether 15g, dimethylbenzene to 100g, the method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms main active ingredient weight percentage and be 31% Tolfenpyrad ether chrysanthemum emulsifiable concentrate.
Embodiment 14:
Take by weighing 60g Tolfenpyrad, 1g ether chrysanthemum ester, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether 15g, dimethylbenzene to 100g, the method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms main active ingredient weight percentage and be 61% Tolfenpyrad ether chrysanthemum emulsifiable concentrate.
Embodiment 15:
Take by weighing 1g Tolfenpyrad, 70g ether chrysanthemum ester, alkylphenol polyoxyethylene 10g, phenethyl phenol polyethenoxy ether 10g, dimethylbenzene to 100g, the method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms main active ingredient weight percentage and be 71% Tolfenpyrad ether chrysanthemum emulsifiable concentrate.
Claims (10)
1. Synergistic insecticidal compositions that contains Tolfenpyrad and ether chrysanthemum ester is characterized in that this Synergistic insecticidal compositions take Tolfenpyrad and ether chrysanthemum ester as main active ingredient, and wherein, the weight ratio of Tolfenpyrad and ether chrysanthemum ester is 0.1～80: 0.5～80.
2. the Synergistic insecticidal compositions that contains Tolfenpyrad and ether chrysanthemum ester according to claim 1 is characterized in that the effective ingredient Tolfenpyrad of this Synergistic insecticidal compositions and the weight ratio of ether chrysanthemum ester are 1～60: 1～70.
3. the Synergistic insecticidal compositions that contains Tolfenpyrad and ether chrysanthemum ester according to claim 2 is characterized in that the effective ingredient Tolfenpyrad of this Synergistic insecticidal compositions and the weight ratio of ether chrysanthemum ester are 1～30: 1～30.
4. the Synergistic insecticidal compositions that contains Tolfenpyrad and ether chrysanthemum ester according to claim 1 is characterized in that Tolfenpyrad and the two weight percentage in this Synergistic insecticidal compositions of ether chrysanthemum ester are 2%～80%.
5. the Synergistic insecticidal compositions that contains Tolfenpyrad and ether chrysanthemum ester according to claim 4 is characterized in that Tolfenpyrad and the two weight percentage in this Synergistic insecticidal compositions of ether chrysanthemum ester are 8%～60%.
6. the Synergistic insecticidal compositions that contains Tolfenpyrad and ether chrysanthemum ester according to claim 5 is characterized in that Tolfenpyrad and the two weight percentage in this Synergistic insecticidal compositions of ether chrysanthemum ester are 20%～40%.
7. the Synergistic insecticidal compositions that contains Tolfenpyrad and ether chrysanthemum ester according to claim 1 is characterized in that this Synergistic insecticidal compositions take Tolfenpyrad and ether chrysanthemum ester as main active ingredient and insecticides adjuvant, excipients are mixed with any one formulation that allows on the agricultural chemicals.
8. the Synergistic insecticidal compositions that contains Tolfenpyrad and ether chrysanthemum ester according to claim 7 is characterized in that described formulation is missible oil, wetting powder, microemulsion, aqueous emulsion, suspending agent or water dispersible granules.
9. the application of Synergistic insecticidal compositions in preparing the insecticidal materials of preventing and treating one or more insects in Lepidoptera, Homoptera, Hymenoptera, thrips or the coleoptera that contains Tolfenpyrad and ether chrysanthemum ester claimed in claim 1.
10. application according to claim 9 is characterized in that containing the application of Synergistic insecticidal compositions in the insecticidal materials of preparation control cotton cotton bollworm, beet armyworm, cabbage caterpillar, vegetables diamond-back moth or onion thrips of Tolfenpyrad and ether chrysanthemum ester.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102428924A (en) * | 2011-11-15 | 2012-05-02 | 陕西美邦农药有限公司 | Pesticidal composition containing tolfenpyrad and ethofenprox |
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| JP2006131516A (en) * | 2004-11-04 | 2006-05-25 | Nippon Nohyaku Co Ltd | Pest control agent composition and method for use thereof |
| CN101658178A (en) * | 2009-07-22 | 2010-03-03 | 深圳诺普信农化股份有限公司 | Synergistic insecticidal composition |
| CN102017957A (en) * | 2009-09-14 | 2011-04-20 | 南京第一农药集团有限公司 | Synergistic insecticidal composition containing pymetrozine and ethofenprox and application thereof |
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- 2011-10-18 CN CN2011103173278A patent/CN103053536A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006131516A (en) * | 2004-11-04 | 2006-05-25 | Nippon Nohyaku Co Ltd | Pest control agent composition and method for use thereof |
| CN101658178A (en) * | 2009-07-22 | 2010-03-03 | 深圳诺普信农化股份有限公司 | Synergistic insecticidal composition |
| CN102017957A (en) * | 2009-09-14 | 2011-04-20 | 南京第一农药集团有限公司 | Synergistic insecticidal composition containing pymetrozine and ethofenprox and application thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102428924A (en) * | 2011-11-15 | 2012-05-02 | 陕西美邦农药有限公司 | Pesticidal composition containing tolfenpyrad and ethofenprox |
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Application publication date: 20130424 |