CN105638667B - A kind of Synergistic insecticidal compositions and its application containing propargite and ethyl spinosad - Google Patents
A kind of Synergistic insecticidal compositions and its application containing propargite and ethyl spinosad Download PDFInfo
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- CN105638667B CN105638667B CN201511019856.4A CN201511019856A CN105638667B CN 105638667 B CN105638667 B CN 105638667B CN 201511019856 A CN201511019856 A CN 201511019856A CN 105638667 B CN105638667 B CN 105638667B
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- Prior art keywords
- propargite
- ethyl spinosad
- ethyl
- insecticidal compositions
- spinosad
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- ZYHMJXZULPZUED-UHFFFAOYSA-N propargite Chemical compound C1=CC(C(C)(C)C)=CC=C1OC1C(OS(=O)OCC#C)CCCC1 ZYHMJXZULPZUED-UHFFFAOYSA-N 0.000 title claims abstract description 65
- 239000005930 Spinosad Substances 0.000 title claims abstract description 61
- 229940014213 spinosad Drugs 0.000 title claims abstract description 61
- -1 ethyl spinosad Chemical compound 0.000 title claims abstract description 53
- 239000000203 mixture Substances 0.000 title claims abstract description 39
- 230000000749 insecticidal effect Effects 0.000 title claims abstract description 24
- 230000002195 synergetic effect Effects 0.000 title claims abstract description 24
- 241000607479 Yersinia pestis Species 0.000 claims abstract description 18
- 239000000575 pesticide Substances 0.000 claims abstract description 9
- 241000500437 Plutella xylostella Species 0.000 claims abstract description 6
- 241001414989 Thysanoptera Species 0.000 claims abstract description 6
- 241000256247 Spodoptera exigua Species 0.000 claims abstract description 5
- 241000985245 Spodoptera litura Species 0.000 claims abstract description 4
- 241000594036 Liriomyza Species 0.000 claims abstract 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 28
- 239000003921 oil Substances 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 241001498622 Cixius wagneri Species 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 238000009472 formulation Methods 0.000 claims description 6
- 241000258937 Hemiptera Species 0.000 claims description 5
- 239000004615 ingredient Substances 0.000 claims description 5
- 239000000375 suspending agent Substances 0.000 claims description 5
- 240000007594 Oryza sativa Species 0.000 claims description 4
- 235000007164 Oryza sativa Nutrition 0.000 claims description 4
- 150000001345 alkine derivatives Chemical class 0.000 claims description 4
- 239000000839 emulsion Substances 0.000 claims description 4
- 239000000546 pharmaceutical excipient Substances 0.000 claims description 4
- 235000009566 rice Nutrition 0.000 claims description 4
- 229920000742 Cotton Polymers 0.000 claims description 3
- 241000219146 Gossypium Species 0.000 claims description 3
- 241000255777 Lepidoptera Species 0.000 claims description 3
- 241000488581 Panonychus citri Species 0.000 claims description 3
- 239000012752 auxiliary agent Substances 0.000 claims description 3
- 235000013399 edible fruits Nutrition 0.000 claims description 3
- 239000004530 micro-emulsion Substances 0.000 claims description 3
- 235000013311 vegetables Nutrition 0.000 claims description 3
- 239000004563 wettable powder Substances 0.000 claims description 3
- 235000009024 Ceanothus sanguineus Nutrition 0.000 claims description 2
- 240000003553 Leptospermum scoparium Species 0.000 claims description 2
- 235000015459 Lycium barbarum Nutrition 0.000 claims description 2
- 235000021307 Triticum Nutrition 0.000 claims description 2
- 239000006185 dispersion Substances 0.000 claims description 2
- 239000008187 granular material Substances 0.000 claims description 2
- 241000255925 Diptera Species 0.000 claims 2
- 244000046052 Phaseolus vulgaris Species 0.000 claims 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 claims 1
- 241000209140 Triticum Species 0.000 claims 1
- 210000004894 snout Anatomy 0.000 claims 1
- 239000003814 drug Substances 0.000 abstract description 18
- 241000488583 Panonychus ulmi Species 0.000 abstract description 12
- 230000000694 effects Effects 0.000 abstract description 10
- 230000000361 pesticidal effect Effects 0.000 abstract description 9
- 229940079593 drug Drugs 0.000 abstract description 7
- 238000001228 spectrum Methods 0.000 abstract description 4
- 241001232130 Maruca testulalis Species 0.000 abstract description 3
- 238000003912 environmental pollution Methods 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 abstract 1
- 244000144972 livestock Species 0.000 abstract 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 15
- 238000000034 method Methods 0.000 description 15
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 13
- JFLRKDZMHNBDQS-UCQUSYKYSA-N CC[C@H]1CCC[C@@H]([C@H](C(=O)C2=C[C@H]3[C@@H]4C[C@@H](C[C@H]4C(=C[C@H]3[C@@H]2CC(=O)O1)C)O[C@H]5[C@@H]([C@@H]([C@H]([C@@H](O5)C)OC)OC)OC)C)O[C@H]6CC[C@@H]([C@H](O6)C)N(C)C.CC[C@H]1CCC[C@@H]([C@H](C(=O)C2=C[C@H]3[C@@H]4C[C@@H](C[C@H]4C=C[C@H]3C2CC(=O)O1)O[C@H]5[C@@H]([C@@H]([C@H]([C@@H](O5)C)OC)OC)OC)C)O[C@H]6CC[C@@H]([C@H](O6)C)N(C)C Chemical compound CC[C@H]1CCC[C@@H]([C@H](C(=O)C2=C[C@H]3[C@@H]4C[C@@H](C[C@H]4C(=C[C@H]3[C@@H]2CC(=O)O1)C)O[C@H]5[C@@H]([C@@H]([C@H]([C@@H](O5)C)OC)OC)OC)C)O[C@H]6CC[C@@H]([C@H](O6)C)N(C)C.CC[C@H]1CCC[C@@H]([C@H](C(=O)C2=C[C@H]3[C@@H]4C[C@@H](C[C@H]4C=C[C@H]3C2CC(=O)O1)O[C@H]5[C@@H]([C@@H]([C@H]([C@@H](O5)C)OC)OC)OC)C)O[C@H]6CC[C@@H]([C@H](O6)C)N(C)C JFLRKDZMHNBDQS-UCQUSYKYSA-N 0.000 description 12
- 241000255967 Helicoverpa zea Species 0.000 description 8
- 230000002265 prevention Effects 0.000 description 7
- 239000002994 raw material Substances 0.000 description 7
- 238000013329 compounding Methods 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 description 5
- 229940051841 polyoxyethylene ether Drugs 0.000 description 5
- 229920000056 polyoxyethylene ether Polymers 0.000 description 5
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
- 239000004480 active ingredient Substances 0.000 description 4
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000002917 insecticide Substances 0.000 description 4
- 230000002045 lasting effect Effects 0.000 description 4
- 230000003449 preventive effect Effects 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 231100000820 toxicity test Toxicity 0.000 description 3
- 230000001018 virulence Effects 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 2
- 241000238631 Hexapoda Species 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 108010053950 Teicoplanin Proteins 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 150000004040 pyrrolidinones Chemical class 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- BJNLLBUOHPVGFT-QRZIFLFXSA-N teichomycin Chemical compound CCCCCCCCCC(=O)N[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1OC(C(=C1)OC=2C(=CC(=CC=2)[C@@H](O[C@H]2[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@H]2C(N[C@H](C3=CC(O)=CC(O[C@@H]4[C@H]([C@@H](O)[C@H](O)[C@@H](CO)O4)O)=C3C=3C(O)=CC=C(C=3)[C@@H](NC3=O)C(=O)N2)C(O)=O)=O)Cl)=C(OC=2C(=CC(C[C@H](C(N4)=O)NC(=O)[C@H](N)C=5C=C(O6)C(O)=CC=5)=CC=2)Cl)C=C1[C@H]3NC(=O)[C@@H]4C1=CC6=CC(O)=C1 BJNLLBUOHPVGFT-QRZIFLFXSA-N 0.000 description 2
- 239000004562 water dispersible granule Substances 0.000 description 2
- 229920001285 xanthan gum Polymers 0.000 description 2
- UUIPAJHTKDSSOK-UHFFFAOYSA-N (2-nonylphenyl) dihydrogen phosphate Chemical compound CCCCCCCCCC1=CC=CC=C1OP(O)(O)=O UUIPAJHTKDSSOK-UHFFFAOYSA-N 0.000 description 1
- 240000008067 Cucumis sativus Species 0.000 description 1
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 244000141359 Malus pumila Species 0.000 description 1
- 235000011430 Malus pumila Nutrition 0.000 description 1
- 235000015103 Malus silvestris Nutrition 0.000 description 1
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 1
- 241001674048 Phthiraptera Species 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 244000061458 Solanum melongena Species 0.000 description 1
- 235000002597 Solanum melongena Nutrition 0.000 description 1
- 239000005929 Spinetoram Substances 0.000 description 1
- GOENIMGKWNZVDA-OAMCMWGQSA-N Spinetoram Chemical compound CO[C@@H]1[C@H](OCC)[C@@H](OC)[C@H](C)O[C@H]1OC1C[C@H]2[C@@H]3C=C4C(=O)[C@H](C)[C@@H](O[C@@H]5O[C@H](C)[C@H](CC5)N(C)C)CCC[C@H](CC)OC(=O)CC4[C@@H]3CC[C@@H]2C1 GOENIMGKWNZVDA-OAMCMWGQSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 241001454293 Tetranychus urticae Species 0.000 description 1
- 244000098338 Triticum aestivum Species 0.000 description 1
- 235000009754 Vitis X bourquina Nutrition 0.000 description 1
- 235000012333 Vitis X labruscana Nutrition 0.000 description 1
- 240000006365 Vitis vinifera Species 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 230000000895 acaricidal effect Effects 0.000 description 1
- 239000000642 acaricide Substances 0.000 description 1
- 230000035508 accumulation Effects 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004166 bioassay Methods 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 210000000481 breast Anatomy 0.000 description 1
- SMLHHBQGIJMAIM-UHFFFAOYSA-N calcium;2-dodecylbenzenesulfonic acid Chemical compound [Ca].CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O SMLHHBQGIJMAIM-UHFFFAOYSA-N 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 239000006184 cosolvent Substances 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 230000009189 diving Effects 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 231100001231 less toxic Toxicity 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 210000000653 nervous system Anatomy 0.000 description 1
- 230000003151 ovacidal effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000000447 pesticide residue Substances 0.000 description 1
- 230000000144 pharmacologic effect Effects 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000007115 recruitment Effects 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
- YTZKOQUCBOVLHL-UHFFFAOYSA-N tert-butylbenzene Chemical compound CC(C)(C)C1=CC=CC=C1 YTZKOQUCBOVLHL-UHFFFAOYSA-N 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/22—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom rings with more than six members
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of Synergistic insecticidal compositions containing propargite and ethyl spinosad and application thereof, the Pesticidal combination using propargite and ethyl spinosad as principle active component, wherein, the weight ratio of propargite and ethyl spinosad is 1:60~60:1.The present composition can prevent various pests, and have obvious synergistic effect, and expand insecticidal spectrum, and greater activity is respectively provided with to pests such as diamondback moth, beet armyworm, Liriomyza, thrips, prodenia litura, bean-pod borer, red spider and mite class；And reduce pesticide usage amount, reduce residual quantity of the pesticide on crop, alleviate environmental pollution；To safety of human and livestock, Environmental compatibility is good, pest is not likely to produce the resistance to the action of a drug.
Description
Technical field
The invention belongs to pesticide field, and in particular to a kind of using propargite and ethyl spinosad as principle active component
Pesticidal combination and its application.
Background technology
Propargite (Propargite), molecular formula：C19H26O4S, chemical name：2- (4- tert-butyl benzene oxies) cyclohexyl third
Alkynes -2- base sulfites.Structural formula is：
Propargite is broad spectrum activity, efficiently, less toxic acaricide, have and tag and stomach poison function, no infiltration and systemic action.It is right
Children mite and good into mite effect, ovicidal effect is poor.Can effectively preventing and treating apple-tree, cotton, cucumber, grape, corn and soybean, kind
Tetranychid class pest on eggplant and vegetables.
Ethyl spinosad (Spinetoram), structural formula：
Ethyl spinosad is a kind of new multiple killing teichomycin insecticides produced by Dow AgroSciences, is killed by ethyl more
Two kinds of component compositions of mycin-J and ethyl spinosad-L, act on the nervous system of insect, to diamondback moth, beet armyworm, dive
The prevention effect that leaf fly, thrips, prodenia litura, bean-pod borer have had.It is with bioactivity higher, and insecticidal spectrum is wider, quick-acting
More preferably, the features such as lasting period is longer, resistance of rainwater washing against, low toxic and environment-friendly.
Insecticide variety containing single component often existing defects in pesticide control of insect：Continuous use easily produces anti-
Pharmacological property, insecticidal spectrum are narrow, it is impossible to provide comprehensive protection, peasant's drug cost height etc. for crop.It is various by two kinds or the coming year
The combination of active ingredient can overcome disadvantages mentioned above to a certain extent to a certain extent.Two kinds or two with synergistic effect
The combination mixture of kind above active ingredient, can improve preventive effect, and dosage, cost-effective with reducing active ingredient, slows down pest
Resistance, which occurs simultaneously can expand to prevent, composes, and plays that more worms are simultaneous to be controlled, reduces the use cost of peasant.
The content of the invention
It is an object of the invention to for above-mentioned various problems, in order to overcome and delay the resistance to the action of a drug to existing pesticide, expand
Big mite killing spectrum, enhancing drug effect, reduce drug cost, so as to provide a kind of prevention various crop Lepidoptera, homoptera pest and mite
The Pesticidal combination of class disease.
It is a still further object of the present invention to provide the purposes of the Pesticidal combination.
The measure of the present invention is realized by following measures.
A kind of Synergistic insecticidal compositions containing propargite and ethyl spinosad, the Synergistic insecticidal compositions with propargite with
Ethyl spinosad is principle active component, wherein, the weight ratio of propargite and ethyl spinosad is 1:60~60:1.
The more excellent weight ratio of the Pesticidal combination, wherein propargite and ethyl spinosad is 1:50~30:1.Into
The weight ratio of the preferred propargite of one step and ethyl spinosad is 1:20~20:1, still further preferably propargite kills more with ethyl
The weight ratio of mycin is 1:1~10, the most preferably weight ratio of propargite and ethyl spinosad is 1:5~10.Propargite and second
The weight ratio of Quito killing teichomycin can also be 1：10、1：5、1：10、1：2、1：3、1：1.
The weight of preparation shared by the two kinds of active principle accumulations of the Pesticidal combination, wherein propargite and ethyl spinosad
Amount is than being 0.5%~90%, preferably 1~60%.
The Pesticidal combination, using propargite and ethyl spinosad as principle active component (active ingredient) and auxiliary agent
And/or excipient is processed into any one formulation allowed on pesticide.The formulation that can be processed into be missible oil, suspending agent, aqueous emulsion,
Microemulsion, pulvis, wettable powder, dispersible oil-suspending agent and water dispersible granules etc..The auxiliary agent can use dodecyl
Benzene sulfonic acid calcium, alkylphenol polyoxyethylene ether, polyoxyethylene polyoxy propylene block compound (such as agriculture breast 33#), polyoxyethylene nonyl phenyl second
Alkene ether etc., excipient include cyclohexanone, dimethylbenzene, solvent naphtha, water, antifreezing agent (such as propane diols), deionized water.Help above
Agent, excipient and other agriculturally known auxiliary materials can be alone or be used in combination.
The Synergistic insecticidal compositions containing propargite and ethyl spinosad prepare be used for prevent rice, wheat,
Cotton, fruit tree, vegetables, apply on tea tree in the insecticide of more Lepidopterous, homoptera pest and mite class.
It is preferred that the above-mentioned Synergistic insecticidal compositions containing propargite and ethyl spinosad are being prepared for preventing diamondback moth, diving
Leaf fly, thrips, prodenia litura, bean-pod borer, beet armyworm, red spider, tetranychid, Panonychus citri, planthopper insecticide in apply.
The present invention Synergistic insecticidal compositions antagonism mite pest have significant preventive effect, particularly with tetranychid, red spider,
The various pests that Panonychus citri etc. easily produces resistance have good preventive effect；And suppress pest to unitary agent (propargite
Or ethyl spinosad) the resistance to the action of a drug produce and at the same time can prevent plant hopper, diamondback moth etc..
The Pesticidal combination of the present invention compared with prior art, produces following beneficial effect：(1) compared with single dose, the group
Prevention of the compound to pest has notable synergistic, and prevention effect significantly improves；(2) one medicines more control, a dispenser can at the same time anti-Zhiduo County
Kind pest, reduces prevention recruitment cost；Prepared by described containing propargite and the Synergistic insecticidal compositions of ethyl spinosad
Insecticidal materials at the same time, and can prevent Homoptera, lepidoptera pest in prevention red spider mite class, especially to diamondback moth, beet armyworm,
Planthopper has good preventive effect, reaches the effect that a medicine is controlled more.(3) alternative high-toxic pesticide, and field medication is greatly reduced
Amount, effectively reduces environmental pollution and pesticide residue；(4) have concurrently quick-acting and long-acting；(5) compared with propargite single dose, produce and make
Use cost reduction；(6) suppressing pest strengthens the resistance of pesticide.
Embodiment
The embodiment of the present invention is the method being combined using indoor bioassay and field trial.First pass through indoor biological
Measure, clear and definite two kinds of medicaments compound by a certain percentage after co-toxicity coefficient；On this basis, then field trial is carried out.
Embodiment 1：
Propargite and ethyl spinosad different ratio co-toxicity
Weigh propargite, ethyl spinosad is configured to principle active component weight using conventional formulation method by different proportion
Measure the propargite ethyl spinosad suspending agent that percentage composition is 30%.Specific ratio is shown in Table 1.
Using dipping slide measure propargite and ethyl spinosad and its compounding sample to the virulence of red spider, often handle
It is repeated 3 times, 30 is handled per concentration, uses LC50Value calculates co-toxicity coefficient by the abundant methods of Sun Yun：
:The toxicity test and co-toxicity coefficient of 1 propargite of table, ethyl spinosad and its compounding sample to red spider
There is synergistic effect after as shown by data in table, propargite and ethyl spinosad mixture to red spider, it is listed in table
Four proportioning co-toxicity coefficients be both greater than 120, therefore propargite and ethyl spinosad mixture have significant synergies.
Embodiment 2：
Weigh propargite, ethyl spinosad is configured to principle active component weight using conventional formulation method by different proportion
Measure the propargite ethyl spinosad missible oil that percentage composition is 30%.Specific ratio is shown in Table 2.
Test method first soak leaf connect again worm method measure propargite and ethyl spinosad and its compounding sample rice is flown
The virulence of lice, often processing are repeated 3 times, and use LC50Value calculates co-toxicity coefficient by the abundant methods of Sun Yun：
The toxicity test and co-toxicity coefficient of 2 propargite of table, ethyl spinosad and its compounding sample to planthopper
There is synergistic effect after as shown by data in table, propargite and ethyl spinosad mixture to planthopper, it is listed in table
Four proportioning co-toxicity coefficients be all much larger than 120, therefore propargite and ethyl spinosad mixture have significant synergies.
Embodiment 3：
Weigh 5g propargites, 20g ethyl spinosads, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g,
Above raw material is routinely prepared and is mixed in the method input mixing kettle of missible oil, form principle active component to 100g by dimethylbenzene
Weight percentage is 25% propargite ethyl spinosad missible oil.
Match somebody with somebody the field trial of sample progress control in field red spider using embodiment 3, comparison medicament is 57% propargite
EC and 6% ethyl spinosad SC, specific dosage are shown in Table 3, and water consumption is 30kg per acre, are looked into after medicine 3 days, 7 days, 14 days, 28 days
As a result, result of the test is shown in Table 3：
Field test results of 3 example of table, 3 sample to red spider
Example 3 has red spider fabulous quick-acting as can be seen from Table 3, and the lasting period is long, in variable rate technology
Well, it is the outstanding medicament of prevention red spider.
Embodiment 4：
Match somebody with somebody the field trial of sample progress control in field planthopper using embodiment 3, comparison medicament is 57% propargite
EC and 6% ethyl spinosad SC, specific dosage are shown in Table 4, are per acre 30kg with water, look into 3 days, 7 days, 14 days, tie within 28 days after medicine
Fruit, result of the test are shown in Table 4：
Field test results of 4 example of table, 3 sample to planthopper
3 sample of example has planthopper fabulous effect as can be seen from Table 4, and the lasting period is long, in field table
It is now good, it is the outstanding medicament for preventing planthopper.
Embodiment 5
Weigh propargite, ethyl spinosad is configured to principle active component weight using conventional formulation method by different proportion
Measure the propargite ethyl spinosad aqueous emulsion that percentage composition is 30%.Specific ratio is shown in Table 5.
Using feed plus malicious method measure propargite and ethyl pleocidin and its compounding sample to the virulence of bollworm, often locate
Reason is repeated 3 times, and 30 are handled per concentration, uses LC50Value calculates co-toxicity coefficient by the abundant methods of Sun Yun：
The toxicity test and co-toxicity coefficient of 5 propargite of table, ethyl pleocidin and its compounding sample to bollworm
Embodiment 6
Match somebody with somebody the field trial of sample progress control in field bollworm using embodiment 3, comparison medicament is 57% propargite
EC and 6% ethyl spinosad SC, specific dosage are shown in Table 6, and water consumption is 30kg per acre, are looked into after medicine 3 days, 7 days, 14 days, 28 days
As a result, result of the test is shown in Table 6：
Field test results of 6 example of table, 3 sample to bollworm
3 sample of example has bollworm fabulous effect as can be seen from Table 6, and the lasting period is long, in field table
It is now good, it is the outstanding medicament for preventing bollworm.
Show through indoor synergism test measure：By propargite and ethyl spinosad built agent to red spider and planthopper,
Bollworm has significant synergistic insecticidal action；Field control effectiveness test equally also indicates that all built agents of the present invention to red spider
Corresponding single dose pesticidal effects are all remarkably higher than with the insecticidal effect of planthopper, bollworm.
Embodiment 7：
Weigh 0.2g propargites, 20g ethyl spinosads, lignin 10g, Negel 2g, added to kaolin
100g, above raw material is mixed in micronizer, forms the alkynes mite that principle active component weight percentage is 20.2%
Special ethyl spinosad wettable powder.
Embodiment 8：
Weigh 78g propargites, 0.5g ethyl spinosads, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether
6g, dimethylbenzene add to 100g, and above raw material is routinely prepared and is mixed in the method input mixing kettle of missible oil, is formed main effective
Ingredients Weight percentage composition is 78.5% propargite ethyl spinosad missible oil.
Embodiment:9：
Weigh 2g propargites, 10g ethyl spinosads, nonyl phenol phosphate 5g, alkylphenol polyoxyethylene ether 4g, n-butanol
The dimethylbenzene of 3g, 30g and the pyrrolidones of 20g, the xanthans of 0.1g, remaining supplies 100g, n-butanol and water dissolving shape with water
Cheng Shuixiang, remaining component are mixed to form oil phase, slowly water are added in oil phase under cutter effect, and continue to cut
Cut 10~30 minutes, form the propargite ethyl spinosad aqueous emulsion that principle active component weight percentage is 12%.
Embodiment 10：
Weigh 10g propargites, 30g ethyl spinosads, calcium dodecyl benzene sulfonate 5g, alkylphenol polyoxyethylene ether 4g,
The solvent xylene of 30g and the pyrrolidones of 15g, remaining complements to 100g, active compound, solvent, emulsifying agent, cosolvent mixing with water
Stirring forms homogeneous phase transparent solution, is then slowly added into water and stirring forms clear solution, be principle active component weight hundred
Divide the propargite ethyl spinosad microemulsion that content is 40%.
Embodiment 11：
Weigh 4g propargites, 4g ethyl spinosads, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 3g,
Dimethylbenzene is to 100g.Above raw material is routinely prepared and is mixed in the method input mixing kettle of missible oil, forms principle active component
Weight percentage is 8% propargite ethyl spinosad missible oil.
Embodiment 12：
Weigh 3g propargites, 30g ethyl spinosads, sodium lignin sulfonate 3g, polyoxyethylene poly-oxygen propylene aether and its sulphur
Hydrochlorate 4g, xanthans 0.2g, ethylene glycol 10g, silica ethane 0.1g, aluminium-magnesium silicate 0.5g, supplies 100g, in sand mill with water
The propargite ethyl spinosad suspending agent that principle active component weight percentage is 33% is formed under effect.
Embodiment 13：
Weigh 5g propargites, 60g ethyl spinosads, alkylphenol polyoxyethylene ether 14g, phenethyl phenol polyethenoxy ether
15g, dimethylbenzene to 100g, above raw material is routinely prepared and is mixed in the method input mixing kettle of missible oil, is formed main effective
Ingredients Weight percentage composition is 65% propargite ethyl spinosad missible oil.
Embodiment 14：
Weigh 45g propargites, 5g ethyl spinosads, sodium lignin sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate
5g, polyvinyl alcohol 5g, borax 2g, kaolin 28g, principle active component is formed by above raw material by the method for water dispersion granule
Weight percentage is 50% propargite ethyl spinosad water dispersible granules.
Embodiment 15：
Weigh 25g propargites, 25g ethyl spinosads, alkylphenol polyoxyethylene ether 14g, phenethyl phenol polyethenoxy ether
15g, dimethylbenzene to 100g, above raw material is routinely prepared and is mixed in the method input mixing kettle of missible oil, is formed main effective
Ingredients Weight percentage composition is 50% propargite ethyl spinosad missible oil.
Claims (8)
- A kind of 1. Synergistic insecticidal compositions containing propargite and ethyl spinosad, it is characterized in that the Synergistic insecticidal compositions are with alkynes Mite is special and ethyl spinosad is principle active component, wherein, the weight ratio of propargite and ethyl spinosad is 1:1~1: 50。
- 2. the Synergistic insecticidal compositions according to claim 1 containing propargite and ethyl spinosad, it is characterized in that this is killed The effective ingredient propargite of worm composition and the weight ratio of ethyl spinosad are 1:1~10.
- 3. the Synergistic insecticidal compositions according to claim 2 containing propargite and ethyl spinosad, it is characterized in that this is killed The effective ingredient propargite of worm composition and the weight ratio of ethyl spinosad are 1:5~10.
- 4. the Synergistic insecticidal compositions according to claim 1 containing propargite and ethyl spinosad, its feature propargite It is 0.5%~90% with weight percentage of both ethyl spinosads in the Synergistic insecticidal compositions.
- 5. the Synergistic insecticidal compositions according to claim 1 containing propargite and ethyl spinosad, it is characterized in that with alkynes Mite is special and ethyl spinosad is processed into any one agent allowed on pesticide for principle active component and auxiliary agent and/or excipient Type.
- 6. the Synergistic insecticidal compositions according to claim 5 containing propargite and ethyl spinosad, it is characterized in that described Formulation is missible oil, wettable powder, microemulsion, aqueous emulsion, suspending agent, pulvis or water dispersion granule.
- 7. the Synergistic insecticidal compositions containing propargite and ethyl spinosad described in claim 1 are being prepared for preventing harnessing the river Rice, wheat, cotton, fruit tree, vegetables, more Lepidopterous on tea tree, Homoptera, Thysanoptera, the desinsection of Diptera pest and mite class Application in agent.
- 8. application according to claim 7, it is characterised in that the lepidoptera pest is diamondback moth, prodenia litura, beans Pod snout moth's larva, beet armyworm, Diptera pest are Liriomyza, and Thysanoptera is thrips, and mite class is Panonychus citri, and homoptera pest is rice Plant hopper.
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| CN1430890A (en) * | 2003-01-29 | 2003-07-23 | 徐建军 | Multiple preparation type pesticide for killing insects and acarids |
| CN102137593A (en) * | 2008-08-28 | 2011-07-27 | 巴斯夫欧洲公司 | Pesticidal mixtures comprising cyanosulfoximine compounds and spinetoram |
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| TW201031331A (en) * | 2009-02-19 | 2010-09-01 | Bayer Cropscience Ag | Pesticide composition comprising a tetrazolyloxime derivative and a fungicide or an insecticide active substance |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1430890A (en) * | 2003-01-29 | 2003-07-23 | 徐建军 | Multiple preparation type pesticide for killing insects and acarids |
| CN102137593A (en) * | 2008-08-28 | 2011-07-27 | 巴斯夫欧洲公司 | Pesticidal mixtures comprising cyanosulfoximine compounds and spinetoram |
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