CN105494414B - A kind of Synergistic insecticidal compositions and its application containing propargite and cyfluthrin - Google Patents
A kind of Synergistic insecticidal compositions and its application containing propargite and cyfluthrin Download PDFInfo
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- CN105494414B CN105494414B CN201511018241.XA CN201511018241A CN105494414B CN 105494414 B CN105494414 B CN 105494414B CN 201511018241 A CN201511018241 A CN 201511018241A CN 105494414 B CN105494414 B CN 105494414B
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- cyfluthrin
- propargite
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
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Abstract
The invention discloses a kind of Synergistic insecticidal compositions and application thereof containing propargite and cyfluthrin, the Pesticidal combination is using propargite and cyfluthrin as principle active component, wherein the weight ratio of propargite and cyfluthrin is 1:60~60:1.The present composition can prevent various pests, and there is apparent synergistic effect, and insecticidal spectrum is expanded, there is greater activity to the acarids such as cotton, fruit tree, vegetables, cereal crop Homoptera, Lepidoptera, acarina pest and red spider, tetranychid, Panonychus citri；And reduces pesticide usage amount, reduce residual quantity of the pesticide on crop, alleviate environmental pollution；To safety of human and livestock, Environmental compatibility is good, pest is not likely to produce drug resistance.
Description
Technical field
The invention belongs to pesticide fields, and in particular to a kind of using propargite and cyfluthrin as the desinsection of principle active component
Composition and its application.
Background technology
Propargite (Propargite), molecular formula：C19H26O4S, chemical name：2- (4- tert-butyl benzene oxies) cyclohexyl third
Alkynes -2- base sulfites.Structural formula is：
Propargite be broad spectrum activity, efficiently, less toxic acaricide, have and tag and stomach poison function, no infiltration and systemic action.It is right
Children mite and good at mite effect, ovicidal effect is poor.Can effectively preventing and treating apple-tree, cotton, cucumber, grape, corn and soybean, kind
Tetranychid class pest on eggplant and vegetables.
Cyfluthrin (beta-cyfluthrin), structural formula：
Cyfluthrin is non-internal-absorting insecticide, has and tags and stomach poison function.Nervous system is acted on, fast, length is knocked down
Residual effect.Can effectively prevent cotton, fruit tree, vegetables, cereal crop and Lepidoptera on other crops, coleoptera, Semiptera and
Homoptera pest can also prevent locust, and can be used as the use of animal health articles for use.
Insecticide variety containing single component often existing defects in pesticide control of insect：Continuous use easy tos produce anti-
Pharmacological property, insecticidal spectrum is narrow, and comprehensive protection, peasant's drug cost height etc. cannot be provided for crop.It is various by two kinds or the coming year
The combination of active constituent can overcome disadvantages mentioned above to a certain extent to a certain extent.Two kinds or two with synergistic effect
Kind or more active constituent combination mixture, preventive effect can be improved, dosage, cost-effective with reducing active ingredient, slows down pest
Resistance occurs that simultaneously prevention spectrum can be expanded, and plays that more worms are simultaneous to be controlled, reduces the use cost of peasant.
Invention content
It is an object of the invention to be directed to above-mentioned various problems, in order to overcome and delay the drug resistance to existing pesticide, expand
Big mite killing spectrum, reduces drug cost at enhancing drug effect, to provide a kind of prevention various crop Homoptera, Lepidoptera, Acarina worm
Harmful Pesticidal combination.
It is a still further object of the present invention to provide the purposes of the Pesticidal combination.
The measure of the present invention is realized by following measures.
A kind of Synergistic insecticidal compositions containing propargite and cyfluthrin, the Synergistic insecticidal compositions are with propargite and hundred trees
Pyrethroids is principle active component, wherein the weight ratio of propargite and cyfluthrin is 1:60~60:1.
The more excellent weight ratio of the Pesticidal combination, wherein propargite and cyfluthrin is 1:50~30:1.Further
It is preferred that the weight ratio of propargite and cyfluthrin is 1:20~20:1, the still further preferably weight ratio of propargite and cyfluthrin
It is 1:1~10, the most preferably weight ratio of propargite and cyfluthrin is 1:5~10.The weight ratio of propargite and cyfluthrin is also
Can be 1：10、1：5、1：10、1：2、1：3、1：1.
The weight ratio of two kinds of shared preparations of active principle accumulation of the Pesticidal combination, wherein propargite and cyfluthrin
It is 0.5%~90%, preferably 1~60%.
The Pesticidal combination, using propargite and cyfluthrin as principle active component (active constituent) and auxiliary agent and/
Or excipient is processed into any one dosage form allowed on pesticide.The dosage form that can be processed into is missible oil, suspending agent, aqueous emulsion, micro-
Emulsion, pulvis, wettable powder, dispersible oil-suspending agent and water dispersible granules etc..Detergent alkylate may be used in the auxiliary agent
Sulfoacid calcium, alkyl phenol polyoxyethylene ether, polyoxyethylene polyoxy propylene block compound (such as agriculture breast 33#), Nonyl pheno
Ether etc., excipient include cyclohexanone, dimethylbenzene, solvent naphtha, water, antifreezing agent (such as propylene glycol), deionized water.The above auxiliary agent,
Excipient and other agriculturally known auxiliary materials can be applied alone or be used in combination.
The above-mentioned Synergistic insecticidal compositions containing propargite and cyfluthrin are preparing prevention Lepidoptera, Homoptera, acarian
The application of the insecticide of mesh pest.The homoptera pest includes planthopper, and lepidoptera pest includes bollworm, cotten aphid, tiltedly
Autographa spp, diamondback moth, Acarina include red spider, tetranychid, Panonychus citri.
The present invention Synergistic insecticidal compositions antagonism mite pest have significant preventive effect, particularly with tetranychid, red spider,
The various pests that Panonychus citri etc. easy tos produce resistance have good preventive effect；And inhibit pest to single formulation (propargite
Or cyfluthrin) drug resistance generate and simultaneously can prevent the pests such as Lepidoptera and homoptera pest.
The Pesticidal combination of the present invention compared with prior art, generates following advantageous effect：(1) compared with single dose, the group
Closing object has notable synergistic, control effect to significantly improve the prevention of pest；(2) one medicines more control, a dispenser can simultaneously anti-Zhiduo County
Kind pest reduces prevention recruitment cost；By the desinsection prepared containing the Synergistic insecticidal compositions of propargite and cyfluthrin
Drug is preventing mite class simultaneously, and can prevent Lepidoptera and homoptera pest, especially has very well to prodenia litura, rice hoppers
Preventive effect, achieve the effect that a medicine more control.(3) alternative high-toxic pesticide, and field dosage is greatly reduced, effectively reduce ring
Border is polluted and pesticide residue；(4) it has concurrently quick-acting and long-acting；(5) compared with propargite single dose, production and application cost reduces；(6)
Pest is inhibited to enhance the resistance of pesticide.
Specific implementation mode
The embodiment of the present invention is to use methods for combining laboratory biometrics with field trials.First pass through indoor biological
It measures, defines the co-toxicity coefficient after two kinds of medicaments compound by a certain percentage；On this basis, then field trial is carried out.
Embodiment 1：
Weigh propargite, cyfluthrin is configured to principle active component weight hundred using conventional formulation method by different proportion
It is 30% propargite cyfluthrin suspending agent to divide content.Specific ratio is shown in Table 1.
Propargite and cyfluthrin and its compounding sample are measured to the virulence of citrus red mite using dip-slide method, often located
Reason is repeated 3 times, and 30 are handled per concentration, uses LC50Value calculates co-toxicity coefficient by Sun Yunpei's Method：
:The toxicity test and co-toxicity coefficient of 1 propargite of table, cyfluthrin and its compounding sample to citrus red mite
Statistics indicate that, there is synergistic effect to citrus red mite after propargite and cyfluthrin mixture in table, it is listed in table
Four proportioning co-toxicity coefficients be both greater than 120, therefore propargite and cyfluthrin mixture have significant synergies.
Embodiment 2：
Weigh propargite, cyfluthrin is configured to principle active component weight hundred using conventional formulation method by different proportion
It is 30% propargite cyfluthrin missible oil to divide content.Specific ratio is shown in Table 2.
Experiment measures the virulence of propargite and cyfluthrin and its compounding sample to rice hoppers using rice-stem dipping method,
Often processing is repeated 3 times, and uses LC50Value calculates co-toxicity coefficient by Sun Yunpei's Method：
The toxicity test and co-toxicity coefficient of 2 propargite of table, cyfluthrin and its compounding sample to rice hoppers
Statistics indicate that, there is synergistic effect to rice hoppers after propargite and cyfluthrin mixture in table, it is listed in table
Four proportioning co-toxicity coefficients be all much larger than 120, therefore propargite and cyfluthrin mixture have significant synergies.
Embodiment 3：
Weigh 5g propargites, 20g cyfluthrins, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, diformazan
The above raw material is routinely prepared and is mixed in the method input mixing kettle of missible oil, form principle active component weight to 100g by benzene
The propargite cyfluthrin missible oil that percentage composition is 25%.
The field trial of control in field citrus red mite is carried out using 3 matched sample of embodiment, comparison medicament is 57% alkynes
Mite spy EC and 5.7% cyfluthrin EC, specific dosage are shown in Table 3, and water consumption is 30kg per acre, look into 3 days after medicine, 7 days, 14 days, and 28
It is as a result, test result is shown in Table 3：
Field test results of 3 example of table, 3 sample to citrus red mite
Example 3 has citrus red mite fabulous quick-acting as can be seen from Table 3, and the lasting period is long, in field
Performance is good, is the outstanding medicament for preventing citrus red mite.
Embodiment 4：
The field trial of control in field rice hoppers is carried out using 3 matched sample of embodiment, comparison medicament is 57% alkynes
Mite spy EC and 5.7% cyfluthrin EC, specific dosage are shown in Table 4, are per acre 30kg with water, are looked into after medicine 3 days, 7 days, 14 days, 28 days
As a result, test result is shown in Table 4：
Field test results of 4 example of table, 3 sample to rice hoppers
3 sample of example has rice hoppers fabulous effect as can be seen from Table 4, and the lasting period is long, in field
Between show good, be the outstanding medicament for preventing rice hoppers.
Embodiment 5：
Weigh propargite, cyfluthrin is configured to principle active component weight hundred using conventional formulation method by different proportion
It is 30% propargite cyfluthrin missible oil to divide content.Specific ratio is shown in Table 5.
Experiment connects worm method using first immersion liquid and measures propargite and cyfluthrin and its compounding sample to prodenia litura again
Virulence, often processing are repeated 3 times, and use LC50Value calculates co-toxicity coefficient by Sun Yunpei's Method：
The toxicity test and co-toxicity coefficient of 5 propargite of table, cyfluthrin and its compounding sample to prodenia litura
Embodiment 6
The field trial of control in field prodenia litura is carried out using 3 matched sample of embodiment, comparison medicament is 57% alkynes mite
Special EC and 5.7% cyfluthrin EC, specific dosage are shown in Table 6, are per acre 30kg with water, look into 3 days, 7 days, 14 days, tie within 28 days after medicine
Fruit, test result are shown in Table 6：
Field test results of 6 example of table, 3 sample to prodenia litura
3 sample of example has cabbage caterpillar fabulous effect as can be seen from Table 6, and the lasting period is long, in field table
It is now good, it is the outstanding medicament for preventing prodenia litura.
Show through indoor synergism test measurement：Citrus red mite and rice rice are flown with cyfluthrin compounding agent by propargite
Lice, prodenia litura have significant synergistic insecticidal action；Field control effectiveness test equally also indicates that all compounding agents pair of the present invention
The insecticidal effect of citrus red mite and rice hoppers, prodenia litura is all remarkably higher than the effect of corresponding single dose pesticide.
Embodiment 7：
It weighs 0.2g propargites, 20g cyfluthrins, lignin 10g, Negel 2g, with kaolin add to 100g,
The above raw material is mixed in micronizer, forms the propargite hundred that principle active component weight percentage is 20.2%
Set pyrethroids wettable powder.
Embodiment 8：
Weigh 78g propargites, 0.5g cyfluthrins, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 6g, two
Toluene adds to 100g, and the above raw material is routinely prepared and is mixed in the method input mixing kettle of missible oil, principle active component is formed
The propargite cyfluthrin missible oil that weight percentage is 78.5%.
Embodiment 9：
Weigh 2g propargites, 10g cyfluthrins, nonyl phenol phosphate 5g, alkyl phenol polyoxyethylene ether 4g, n-butanol 3g,
The dimethylbenzene of 30g and the pyrrolidones of 20g, the xanthans of 0.1g, remaining supplies 100g with water, and n-butanol and water dissolution form water
Phase, remaining component are mixed to form oil phase, slowly water phase are added in oil phase under cutter effect, and continue shearing 10
~30 minutes, form the propargite cyfluthrin aqueous emulsion that principle active component weight percentage is 12%.
Embodiment 10：
Weigh 10g propargites, 30g cyfluthrins, calcium dodecyl benzene sulfonate 5g, alkyl phenol polyoxyethylene ether 4g, 30g's
The pyrrolidones of solvent xylene and 15g, remaining complements to 100g with water, and active compound, solvent, emulsifier, cosolvent are mixed
Homogeneous phase transparent solution is formed, water is then slowly added into and stirring forms clear solution, as principle active component weight percent contains
The propargite cyfluthrin microemulsion that amount is 40%.
Embodiment 11：
Weigh 4g propargites, 4g cyfluthrins, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 3g, diformazan
Benzene is to 100g.The above raw material is routinely prepared and is mixed in the method input mixing kettle of missible oil, principle active component weight is formed
The propargite cyfluthrin missible oil that percentage composition is 8%.
Embodiment 12：
Weigh 3g propargites, 30g cyfluthrins, sodium lignin sulfonate 3g, polyoxyethylene poly-oxygen propylene aether and its sulfate
4g, xanthans 0.2g, ethylene glycol 10g, silica ethane 0.1g, aluminium-magnesium silicate 0.5g supply 100g with water, in the effect of sand mill
The lower propargite cyfluthrin suspending agent for forming principle active component weight percentage and being 33%.
Embodiment 13：
Weigh 5g propargites, 60g cyfluthrins, alkyl phenol polyoxyethylene ether 14g, phenethyl phenol polyethenoxy ether 15g, two
The above raw material is routinely prepared and is mixed in the method input mixing kettle of missible oil, form principle active component weight to 100g by toluene
Measure the propargite cyfluthrin missible oil that percentage composition is 65%.
Embodiment 14：
45g propargites, 5g cyfluthrins, sodium lignin sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g are weighed, is gathered
The above raw material is formed principle active component weight by vinyl alcohol 5g, borax 2g, kaolin 28g by the method for water dispersion granule
The propargite cyfluthrin water dispersible granules that percentage composition is 50%.
Embodiment 15：
Weigh 25g propargites, 25g cyfluthrins, alkyl phenol polyoxyethylene ether 14g, phenethyl phenol polyethenoxy ether 15g,
The above raw material is routinely prepared and is mixed in the method input mixing kettle of missible oil, form principle active component to 100g by dimethylbenzene
The propargite cyfluthrin missible oil that weight percentage is 50%.
Claims (5)
1. a kind of Synergistic insecticidal compositions containing propargite and cyfluthrin prepare prevention rice hoppers, prodenia litura kills
Application in worm agent, it is characterized in that the Synergistic insecticidal compositions are using propargite and cyfluthrin as active ingredient, wherein propargite
Weight ratio with cyfluthrin is 1:1~10.
2. application according to claim 1, it is characterized in that the effective ingredient propargite and cyfluthrin of the Pesticidal combination
Weight ratio be 1:5~10.
3. application according to claim 1, both feature propargite and cyfluthrin are in the Synergistic insecticidal compositions
Weight percentage be 0.5%~90%.
4. application according to claim 1, it is characterized in that using propargite and cyfluthrin as active ingredient and auxiliary agent and/or
Excipient is processed into any one dosage form allowed on pesticide.
5. application according to claim 4, it is characterized in that the dosage form is missible oil, wettable powder, microemulsion, water and milk
Agent, suspending agent, dispersible oil-suspending agent, pulvis, water dispersion granule or micro-capsule suspension.
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| CN201511018241.XA CN105494414B (en) | 2015-12-29 | 2015-12-29 | A kind of Synergistic insecticidal compositions and its application containing propargite and cyfluthrin |
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| CN201511018241.XA CN105494414B (en) | 2015-12-29 | 2015-12-29 | A kind of Synergistic insecticidal compositions and its application containing propargite and cyfluthrin |
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| CN105494414A CN105494414A (en) | 2016-04-20 |
| CN105494414B true CN105494414B (en) | 2018-09-07 |
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| JPH05112411A (en) * | 1991-08-27 | 1993-05-07 | Nippon Soda Co Ltd | Insecticide composition for agriculture and horticulture |
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