CN105557746B - A kind of Synergistic insecticidal compositions and its application containing etoxazole and silicon ethofenprox - Google Patents
A kind of Synergistic insecticidal compositions and its application containing etoxazole and silicon ethofenprox Download PDFInfo
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- CN105557746B CN105557746B CN201511017650.8A CN201511017650A CN105557746B CN 105557746 B CN105557746 B CN 105557746B CN 201511017650 A CN201511017650 A CN 201511017650A CN 105557746 B CN105557746 B CN 105557746B
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- ethofenprox
- silicon
- etoxazole
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N55/00—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/76—1,3-Oxazoles; Hydrogenated 1,3-oxazoles
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
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- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of Synergistic insecticidal compositions containing etoxazole and silicon ethofenprox and application thereof, the Pesticidal combination using etoxazole and silicon ethofenprox as principle active component, wherein, the weight ratio of etoxazole and silicon ethofenprox is 1:60~60:1.The present composition can prevent various pests, and there is obvious synergistic effect, and insecticidal spectrum is expanded, there is greater activity to the red spider on cereal crop, fruit tree, flowers, cotton, vegetables, tetranychid, Panonychus citri, bollworm, corn borer, beet armyworm, planthopper, prodenia litura etc.；And reduce pesticide usage amount, reduce residual quantity of the pesticide on crop, alleviate environmental pollution；To safety of human and livestock, Environmental compatibility is good, pest is not likely to produce the resistance to the action of a drug.
Description
Technical field
The invention belongs to pesticide field, and in particular to a kind of desinsection using etoxazole with silicon ethofenprox as principle active component
Composition and its application.
Background technology
Etoxazole (etoxazole), structural formula are：
Etoxazole is a kind of acaricide of brand-new tool special construction of SUMITOMO CHEMICAL Chemical Co., Ltd. research and development, belongs to 2,4-
Diphenyl-oxazole derivatives quasi-compound, is a kind of selective acaricide.Its mode of action be suppress mite ovum embry ogenesis with
And from young mite to the molting process into mite, it is effective to ovum and young mite, to invalid into mite.Therefore its optimal prevention time is evil mite
Harm initial stage.This medicament rain fastness is strong, and lasting period length, dosage is low, environmentally safe, to beneficial insect and beneficial mite non-hazardous
Or harm is minimum.
Silicon ethofenprox (Silafluofen), structural formula：
Silicon ethofenprox is siliceous pyrethroid insecticides, and effect is close to ethofenprox, available for rice, cotton-plant pest-insects
Prevention.Effect is rapid, and insecticidal spectrum is wide, and ichthyotoxin is very low, is expected to use in paddy field.It is right suitable for prevention rice, vegetables, on cotton
Homoptera Delphacidae special efficacy, while to various pests such as Lepidoptera, Semiptera, Orthoptera, coleoptera, Diptera and Isopteras
There is good effect.It is especially notable to the prevention effect of rice hoppers.
Insecticide variety containing single component often existing defects in pesticide control of insect：Continuous use easily produces anti-
Pharmacological property, insecticidal spectrum are narrow, it is impossible to provide comprehensive protection, peasant's drug cost height etc. for crop.It is various by two kinds or the coming year
The combination of active ingredient can overcome disadvantages mentioned above to a certain extent to a certain extent.Two kinds or two with synergistic effect
The combination mixture of kind above active ingredient, can improve preventive effect, and dosage, cost-effective with reducing active ingredient, slows down pest
Resistance, which occurs simultaneously can expand to prevent, composes, and plays that more worms are simultaneous to be controlled, reduces the use cost of peasant.
The content of the invention
It is an object of the invention to for above-mentioned various problems, in order to overcome and delay the resistance to the action of a drug to existing pesticide, expand
Big insecticidal spectrum, enhancing drug effect, reduce drug cost, so as to provide a kind of prevention various crop Homoptera, Lepidoptera, mite class disease pest
Harmful Pesticidal combination.
It is a still further object of the present invention to provide the purposes of the Pesticidal combination.
The measure of the present invention is realized by following measures.
A kind of Synergistic insecticidal compositions containing etoxazole Yu silicon ethofenprox, the Synergistic insecticidal compositions are with etoxazole and silicon ether
Chrysanthemum ester is principle active component, wherein, the weight ratio of etoxazole and silicon ethofenprox is 1:60~60:1.
The more excellent weight ratio of the Pesticidal combination, wherein etoxazole and silicon ethofenprox is 1:50~30:1.Further
It is preferred that the weight ratio of etoxazole and silicon ethofenprox is 1:20~20:1, the still further preferably weight ratio of etoxazole and silicon ethofenprox
For 1:1~10, the weight ratio of most preferably etoxazole and silicon ethofenprox is 1:5~10.The weight ratio of etoxazole and silicon ethofenprox is also
Can be 1：10、1：5、1：10、1：2、1：3、1：1.
The weight ratio of preparation shared by the two kinds of active principle accumulations of the Pesticidal combination, wherein etoxazole and silicon ethofenprox
For 0.5%~90%, preferably 1~60%.
The Pesticidal combination, using etoxazole and silicon ethofenprox as principle active component (active ingredient) and auxiliary agent and/
Or excipient is processed into any one formulation allowed on pesticide.The formulation that can be processed into is missible oil, suspending agent, aqueous emulsion, micro-
Emulsion, pulvis, wettable powder, dispersible oil-suspending agent and water dispersible granules etc..The auxiliary agent can use detergent alkylate
Sulfoacid calcium, alkylphenol polyoxyethylene ether, polyoxyethylene polyoxy propylene block compound (such as agriculture breast 33#), Nonyl pheno
Ether etc., excipient include cyclohexanone, dimethylbenzene, solvent naphtha, water, antifreezing agent (such as propane diols), deionized water.Above auxiliary agent,
Excipient and other agriculturally known auxiliary materials can be alone or be used in combination.
The above-mentioned Synergistic insecticidal compositions containing etoxazole and silicon ethofenprox are preparing prevention cereal crop, fruit tree, flower
Grass, cotton, tea tree, the Homoptera on vegetables, Lepidoptera, mite pest insecticide in apply.The lepidoptera pest is excellent
Elect bollworm, leaf miner, beet armyworm as, homoptera pest is preferably plant hopper, and mite pest is preferably red spider, tetranychid, complete
Pawl mite.
The present invention Synergistic insecticidal compositions antagonism mite pest have significant preventive effect, particularly with tetranychid, red spider,
The various pests that Panonychus citri etc. easily produces resistance have good preventive effect；And suppress pest to unitary agent (etoxazole
Or silicon ethofenprox) the resistance to the action of a drug produce and at the same time can prevent the pests such as Homoptera, Lepidoptera.
The Pesticidal combination of the present invention compared with prior art, produces following beneficial effect：(1) compared with single dose, the group
Prevention of the compound to pest has notable synergistic, and prevention effect significantly improves；(2) one medicines more control, a dispenser can at the same time anti-Zhiduo County
Kind pest, reduces prevention recruitment cost；The desinsection prepared by the Synergistic insecticidal compositions containing etoxazole and silicon ethofenprox
Medicine is preventing mite class at the same time, and can prevent Lepidoptera, homoptera pest, especially to cotton boll worm, small brown rice planthopper and beet night
Moth has good preventive effect, reaches the effect that a medicine is controlled more.(3) alternative high-toxic pesticide, and field dosage is greatly reduced, have
Effect reduces environmental pollution and pesticide residue；(4) have concurrently quick-acting and long-acting；(5) compared with etoxazole single dose, production and application cost
Reduce；(6) suppressing pest strengthens the resistance of pesticide.
Embodiment
The embodiment of the present invention is the method being combined using indoor bioassay and field trial.First pass through indoor biological
Measure, clear and definite two kinds of medicaments compound by a certain percentage after co-toxicity coefficient；On this basis, then field trial is carried out.
Embodiment 1：
Etoxazole and silicon ethofenprox different ratio co-toxicity
Weigh etoxazole, silicon ethofenprox is configured to principle active component weight hundred using conventional formulation method by different proportion
Divide the etoxazole silicon ethofenprox suspending agent that content is 30%.Specific ratio is shown in Table 1.
Using dipping slide measure etoxazole and silicon ethofenprox and its compounding sample to the virulence of citrus red mite, often handle
It is repeated 3 times, 30 is handled per concentration, uses LC50Value calculates co-toxicity coefficient by the abundant methods of Sun Yun：
The toxicity test and co-toxicity coefficient of 1 etoxazole of table, silicon ethofenprox and its compounding sample to citrus red mite
There is synergistic effect after as shown by data in table, etoxazole and silicon ethofenprox mixture to citrus red mite, it is listed in table
Four proportioning co-toxicity coefficients be both greater than 120, therefore etoxazole and silicon ethofenprox mixture have significant synergies.
Embodiment 2：
Weigh etoxazole, silicon ethofenprox is configured to principle active component weight hundred using conventional formulation method by different proportion
Divide the etoxazole silicon ethofenprox missible oil that content is 30%.Specific ratio is shown in Table 2.
Test method first soak leaf connect again worm method measure etoxazole and silicon ethofenprox and its compounding sample to small brown rice planthopper
Virulence, often processing are repeated 3 times, and use LC50Value calculates co-toxicity coefficient by the abundant methods of Sun Yun：
The toxicity test and co-toxicity coefficient of 2 etoxazole of table, silicon ethofenprox and its compounding sample to small brown rice planthopper
There is synergistic effect to small brown rice planthopper, listed four in table after as shown by data in table, etoxazole and silicon ethofenprox mixture
A proportioning co-toxicity coefficient is all much larger than 120, therefore etoxazole and silicon ethofenprox mixture have significant synergies.
Embodiment 3：
Weigh 5g etoxazoles, 20g silicon ethofenprox, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, diformazan
Above raw material is routinely prepared and is mixed in the method input mixing kettle of missible oil, form principle active component weight to 100g by benzene
Percentage composition is 25% etoxazole silicon ethofenprox missible oil.
Match somebody with somebody the field trial of sample progress control in field citrus red mite using embodiment 3, comparison medicament is 15% second
Mite azoles WP and 10% silicon ethofenprox EC, specific dosage are shown in Table 3, and water consumption is 30kg per acre, are looked into after medicine 3 days, 7 days, 14 days, 28 days
As a result, result of the test is shown in Table 3：
Field test results of 3 example of table, 3 sample to citrus red mite
Example 3 has citrus red mite fabulous quick-acting as can be seen from Table 3, and the lasting period is long, in field
Performance is good, is the outstanding medicament for preventing citrus red mite.
Embodiment 4：
Match somebody with somebody the field trial of sample progress control in field small brown rice planthopper using embodiment 3, comparison medicament is 15% etoxazole
WP and 10% silicon ethofenprox EC, specific dosage are shown in Table 4, are per acre 30kg with water, look into 3 days after medicine, 7 days, 14 days, 28 days as a result,
Result of the test is shown in Table 4：
Field test results of 4 example of table, 3 sample to small brown rice planthopper
3 sample of example has small brown rice planthopper fabulous effect as can be seen from Table 4, and the lasting period is long, in field table
It is now good, it is the outstanding medicament for preventing small brown rice planthopper.
Embodiment 5
Weigh etoxazole, silicon ethofenprox is configured to principle active component weight hundred using conventional formulation method by different proportion
Divide the etoxazole silicon ethofenprox missible oil that content is 30%.Specific ratio is shown in Table 5.
Using feed plus malicious method measure etoxazole and silicon ethofenprox and its compounding sample to the virulence of bollworm, often processing is heavy
It is 3 times multiple, 30 are handled per concentration, uses LC50Value calculates co-toxicity coefficient by the abundant methods of Sun Yun：
:The toxicity test and co-toxicity coefficient of 5 etoxazole of table, silicon ethofenprox and its compounding sample to bollworm
Embodiment 6
Match somebody with somebody the field trial of sample progress control in field bollworm using embodiment 3, comparison medicament is 15% etoxazole
WP and 10% silicon ethofenprox EC, specific dosage are shown in Table 6, are per acre 30kg with water, look into 3 days after medicine, 7 days, 14 days, 28 days as a result,
Result of the test is shown in Table 6：
Field test results of 6 example of table, 3 sample to bollworm
3 sample of example has bollworm fabulous effect as can be seen from Table 6, and the lasting period is long, in field table
It is now good, it is the outstanding medicament for preventing bollworm.
Show through indoor synergism test measure：By etoxazole and silicon ethofenprox built agent to citrus red mite and small brown rice planthopper,
Bollworm has significant synergistic insecticidal action；Field control effectiveness test equally also indicates that all built agents of the present invention are red to citrus
Spider and small brown rice planthopper, the insecticidal effect of bollworm are all remarkably higher than the effect of corresponding single dose pesticide.
Embodiment 7：
Weigh 0.2g etoxazoles, 20g silicon ethofenprox, lignin 10g, Negel 2g, with kaolin add to 100g,
Above raw material is mixed in micronizer, forms the etoxazole silicon that principle active component weight percentage is 20.2%
Ethofenprox wettable powder.
Embodiment 8：
Weigh 78g etoxazoles, 0.5g silicon ethofenprox, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 6g, two
Toluene adds to 100g, and above raw material is routinely prepared and is mixed in the method input mixing kettle of missible oil, forms principle active component
Weight percentage is 78.5% etoxazole silicon ethofenprox missible oil.
Embodiment 9：
Weigh 2g etoxazoles, 10g silicon ethofenprox, nonyl phenol phosphate 5g, alkylphenol polyoxyethylene ether 4g, n-butanol 3g,
The dimethylbenzene of 30g and the pyrrolidones of 20g, the xanthans of 0.1g, remaining supplies 100g with water, and n-butanol and water dissolve to form water
Phase, remaining component are mixed to form oil phase, slowly water are added in oil phase under cutter effect, and continue shearing 10
~30 minutes, form the etoxazole silicon ethofenprox aqueous emulsion that principle active component weight percentage is 12%.
Embodiment 10：
10g etoxazoles, 30g silicon ethofenprox, calcium dodecyl benzene sulfonate 5g, alkylphenol polyoxyethylene ether 4g are weighed, 30g's
The pyrrolidones of solvent xylene and 15g, remaining complements to 100g with water, and active compound, solvent, emulsifying agent, cosolvent are mixed
Homogeneous phase transparent solution is formed, water is then slowly added into and stirring forms clear solution, is that principle active component weight percent contains
Measure the etoxazole silicon ethofenprox microemulsion for 40%.
Embodiment 11：
Weigh 4g etoxazoles, 4g silicon ethofenprox, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 3g, diformazan
Benzene is to 100g.Above raw material is routinely prepared and is mixed in the method input mixing kettle of missible oil, forms principle active component weight
Percentage composition is 8% etoxazole silicon ethofenprox missible oil.
Embodiment 12：
Weigh 3g etoxazoles, 30g silicon ethofenprox, sodium lignin sulfonate 3g, polyoxyethylene poly-oxygen propylene aether and its sulfate
4g, xanthans 0.2g, ethylene glycol 10g, silica ethane 0.1g, aluminium-magnesium silicate 0.5g, 100g is supplied with water, in the effect of sand mill
It is lower to form the etoxazole silicon ethofenprox suspending agent that principle active component weight percentage is 33%.
Embodiment 13：
Weigh 5g etoxazoles, 60g silicon ethofenprox, alkylphenol polyoxyethylene ether 14g, phenethyl phenol polyethenoxy ether 15g, two
Above raw material is routinely prepared and is mixed in the method input mixing kettle of missible oil, form principle active component weight to 100g by toluene
Measure the etoxazole silicon ethofenprox missible oil that percentage composition is 65%.
Embodiment 14：
45g etoxazoles, 5g silicon ethofenprox, sodium lignin sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g are weighed, is gathered
Vinyl alcohol 5g, borax 2g, kaolin 28g, principle active component weight is formed by above raw material by the method for water dispersion granule
Percentage composition is 50% etoxazole silicon ethofenprox water dispersible granules.
Embodiment 15：
Weigh 25g etoxazoles, 25g silicon ethofenprox, alkylphenol polyoxyethylene ether 14g, phenethyl phenol polyethenoxy ether 15g,
Above raw material is routinely prepared and is mixed in the method input mixing kettle of missible oil, form principle active component to 100g by dimethylbenzene
Weight percentage is 50% etoxazole silicon ethofenprox missible oil.
Claims (7)
- A kind of 1. Synergistic insecticidal compositions containing etoxazole Yu silicon ethofenprox, it is characterized in that the Synergistic insecticidal compositions are with etoxazole It is principle active component with silicon ethofenprox, wherein, the weight ratio of etoxazole and silicon ethofenprox is 1:1~10.
- 2. the Synergistic insecticidal compositions according to claim 1 containing etoxazole Yu silicon ethofenprox, it is characterized in that the desinsection group The effective ingredient etoxazole of compound is 1 with the weight ratio of silicon ethofenprox:5~10.
- 3. the Synergistic insecticidal compositions according to claim 1 containing etoxazole Yu silicon ethofenprox, its feature etoxazole and silicon Weight percentage of both ethofenprox in the Synergistic insecticidal compositions is 0.5%~90%.
- 4. the Synergistic insecticidal compositions according to claim 1 containing etoxazole Yu silicon ethofenprox, it is characterized in that with etoxazole With silicon ethofenprox any one formulation allowed on pesticide is processed into for principle active component and auxiliary agent and/or excipient.
- 5. the Synergistic insecticidal compositions according to claim 4 containing etoxazole Yu silicon ethofenprox, it is characterized in that the formulation It is missible oil, wettable powder, microemulsion, aqueous emulsion, suspending agent, pulvis or water dispersion granule.
- Make 6. the Synergistic insecticidal compositions containing etoxazole and silicon ethofenprox described in claim 1 are used to prepare prevention Cereal Thing, fruit tree, flowers, cotton, tea tree, the Homoptera on vegetables, Lepidoptera, mite pest insecticide in application.
- 7. application according to claim 6, it is characterised in that the lepidoptera pest is bollworm, leaf miner, beet Noctuid, homoptera pest are plant hopper, and mite pest is red spider, tetranychid, Panonychus citri.
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| CN1169655A (en) * | 1994-11-30 | 1998-01-07 | 罗纳-普朗克农业化学公司 | Emulsifiable composition for control of insects |
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2015
- 2015-12-29 CN CN201511017650.8A patent/CN105557746B/en active Active
Patent Citations (3)
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|---|---|---|---|---|
| CN1077085A (en) * | 1991-08-27 | 1993-10-13 | 尤尼罗亚尔化学公司 | Coating mix and process for retaining moisture in meat, poultry, and seafood |
| CN1141580A (en) * | 1994-02-27 | 1997-01-29 | 罗纳-普朗克农业化学公司 | Synergistic termiticidal composition of pyerthroid and n-phenyl-pyrazole |
| CN1169655A (en) * | 1994-11-30 | 1998-01-07 | 罗纳-普朗克农业化学公司 | Emulsifiable composition for control of insects |
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| "乙螨唑对柑桔全爪螨的室内毒力测定";王志静等;《中国南方果树》;20120720;第75-76页 * |
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