CN105994353A - Composite insecticide composition containing Lepimectin and chlorpyrifos and application thereof - Google Patents
Composite insecticide composition containing Lepimectin and chlorpyrifos and application thereof Download PDFInfo
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- CN105994353A CN105994353A CN201610454033.2A CN201610454033A CN105994353A CN 105994353 A CN105994353 A CN 105994353A CN 201610454033 A CN201610454033 A CN 201610454033A CN 105994353 A CN105994353 A CN 105994353A
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- lepimectin
- chlopyrifos
- pesticide compositions
- compound pesticide
- chlorpyrifos
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing heterocyclic radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a composite insecticide composition containing Lepimectin and chlorpyrifos and the application thereof. The insecticidal active constituents of the insecticide composition are Lepimectin and chlorpyrifos, and the weight ratio of Lepimectin to chlorpyrifos is (0.1-80):(0.5-80). The insecticide composition can generate a good synergistic interaction effect, overcomes and delays pest resistance to insecticides, has a high insecticide speed and long lasting period, reduces pesticide cost and has a control effect obviously better than that of single application of Lepimectin or chlorpyrifos. The insecticide composition can control lepidoptera pests on crops, especially cotton bollworms and stem borers, and the effect is obviously better than that of single application of Lepimectin or chlorpyrifos.
Description
Technical field
The invention belongs to the field of agricultural pesticide containing heterocyclic compound, concrete body relates to a kind of compound pesticide compositions.
Background technology
Lepimectin, is the derivant being total to mibemycin (milbemycin) A3/A4 that company finds by Japan three, in
Within 2006, use in Japan's registration.As novel pesticide for the vegetable such as Caulis et Folium Brassicae capitatae, Fructus Lycopersici esculenti, Citrus, Fructus Fragariae Ananssae and Fructus Vitis viniferae and
Fruit, the main preventing and treating insect such as Lepidoptera and Semiptera.This medical instrument has insecticidal activity high, and dosage is few, to person poultry safety,
Free from environmental pollution, specificity is strong, does not injure natural enemy, is not easy to produce the features such as resistance, can take turns with avermectins
Change use, in case avilamycin produces resistance.Therefore it is referred to as the most promising wide spectrum, no interactions efficient, novel at present
One of insecticide of resistance.Its mechanism of action is the permeability that can increase polypide nerve synapse caudacoria to C1-, thus blocks god
Through the transmission of signal, insecticide neural paralysis is finally made to cause insect death.
Chlopyrifos (chlorpyrifos) is a kind of broad spectrum insecticide of The Dow Agrosciences, LLC.'s exploitation, in China's registration
Trade name is Le Siben.Chemical name is: O, O-diethyl-O-(3,5,6-trichloro-2-pyridyl) thiophosphate；Structure
Formula is:
Former medicine is white or canescence granular crystals (or blocks of solid), fusing point 41.5～43.5 DEG C；Fish and Apis are had
Poison, sensitive to Nicotiana tabacum L..Chlopyrifos is one of insecticide variety of current produced worldwide and sales volume maximum, and the Ye Shi world defends
The organophosphor kind of the unique license of raw tissue, through in registration such as country such as 14, China, the U.S., Australia, Japan etc.
And registration.This kind have tag, stomach toxicity and stifling three kinds of model of action, its insecticidal spectrum is wide, toxicity is relatively low, Shangdi over the ground
Lower insect is efficient equally, is preventing and treating grain, fruit tree, vegetable and the preferable insecticide of other industrial crops insect pests, to underground evil
The prevention effect of worm is especially prominent, is particularly suitable for the production of pollution-free vegetable.
Insecticide variety containing single component often existing defects in pesticide Pest control: use easily produces drug resistance continuously
Property, insecticidal spectrum is narrow, it is impossible to provide comprehensively protection for crop, and peasant's drug cost is high.
Summary of the invention
It is an object of the invention to provide a kind of containing Lepimectin with the compound pesticide compositions of chlopyrifos, this Pesticidal combination
It it is the multifunctional insecticide compositions of preventing and treating lepidoptera pest.
It is a further object of the present invention to provide this Pesticidal combination to prevent and treat on the insecticidal materials of resistance lepidoptera pest in preparation
Application, the particularly application on the insecticidal materials of preparation preventing and treating bollworm or snout moths larva.
It is an object of the invention to be achieved through the following technical solutions:
A kind of containing Lepimectin with the compound pesticide compositions of chlopyrifos, this compound pesticide compositions with Lepimectin and
Chlopyrifos is principle active component, and wherein, the weight ratio of Lepimectin and chlopyrifos is 0.1～80:0.5～80.
In this compound pesticide compositions, the weight ratio of Lepimectin (A) and chlopyrifos (B) is preferably 1～60:1～60,
More preferably 1～40:1～40, most preferably 1～30:1～30.
In some preferred technical schemes: Lepimectin and chlopyrifos can 1:30,1:29,1:28,1:27,1:26,
1:25、1:24、1:24、1:22、1:21、1:20、1:19、1:18、1:17、1:16、1:15、1:14、1:13、1:12、
1:11、1:10、1:9、1:8、1:7、1:6、1:5、1:4、1:3、1:2、1:1、2:1、3:1、4:1、5:1、6:1、7:1、
8:1、9:1、10:1、11:1、12:1、13:1、14:1、15:1、16:1、17:1、18:1、19:1、20:1、21:1、22:1、
23:1、24:1、25:1、26:1、27:1、28:1、29:1、30:1、2:3、3:2、2:5、5:2、3:4、4:3、5:2、2:5、
These ratios of 5:3,3:5,5:4,4:5 select.
This compound pesticide compositions can comprise only active component Lepimectin and chlopyrifos, it is possible to use or preparation time to
Adding other components in active component, the active ingredient in this Pesticidal combination can be present in compositions with enhancing effective amount
In.
In compound pesticide compositions of the present invention, Lepimectin and both chlopyrifos weight in this compound pesticide compositions
Percentage composition is 3%～80%.It is preferably 5%～55%, most preferably 10%～40%.
Compound pesticide compositions of the present invention is with Lepimectin and chlopyrifos as active component or principle active component, and pesticide
Auxiliary agent and excipient become any one dosage form allowed on pesticide, the preferred cream of described dosage form, suspending agent, wettability
Powder, aqueous emulsion, microemulsion or water dispersion granule.
The insecticides adjuvant of the aforementioned present invention of can be applicable to is not particularly limited, and includes, but are not limited to DBSA
Calcium, 600#, polyoxyethylene polyoxy propylene block compound are (such as agriculture breast 33#), NPE etc., aforementioned can
The excipient being applied to the present invention is also not particularly limited, and includes, but are not limited to solvent naphtha, water, antifreezing agent (such as the third two
Alcohol), deionized water etc..Above auxiliary agent, excipient and other adjuvant can be alone or and use.
Compound pesticide compositions of the present invention easily produces multiple Semiptera and the lepidoptera pest of resistance to planthopper and snout moths larva etc.
There is good preventive effect；And suppress insect that the Drug resistance of unitary agent (Lepimectin or chlopyrifos are arbitrary) is produced.
Above-mentioned compound pesticide compositions prevents and treats the application on resistance lepidoptera pest insecticidal materials in preparation, especially anti-in preparation
Control the application effect on bollworm or snout moths larva insecticidal materials notable.
Compared with prior art beneficial effects of the present invention: (1), compared with single dose, said composition antagonism lepidoptera pest is such as
Bollworm, snout moths larva etc. have obvious synergistic function, overcome and delayed pest resistance to insecticide, and expanding prevention is composed, parasite killing speed
Hurry up, hence it is evident that improve prevention effect；(2) preventing and treating recruitment, drug cost are reduced；(3) alternative high-toxic pesticide；(4) hold concurrently
Have immediate effect and long-acting；(5) with Lepimectin compared with chlopyrifos single dose, produce and use cost reduces；(6) suppression
The resistance of pesticide is strengthened by lepidoptera pest, and its effect uses apparently higher than its single dose.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described, but limits the present invention never in any form.
Embodiment 1:
Weigh 80gLepimectin, 2g chlopyrifos, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g,
Dimethylbenzene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, is formed and the most effectively become
The Lepimectin chlorpyrifos ec dividing weight percentage to be 82%.
Embodiment 2:
Weigh 2gLepimectin, 80g chlopyrifos, lignin 10g, Negel 2g, add to 100g with Kaolin,
Being mixed in super micron mill by above raw material, forming principle active component weight percentage is 82%
Lepimectin chlopyrifos wettable powder.
Embodiment 3:
Weigh 60gLepimectin, 2g chlopyrifos, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 6g,
Dimethylbenzene adds to 100g, and the method that above raw material is prepared cream routinely puts into mixing in mixing kettle, is formed main effective
Ingredients Weight percentage composition is the Lepimectin chlorpyrifos ec of 62%.
Embodiment 4:
Weigh 2gLepimectin, 60g chlopyrifos, nonyl phenol phosphate 5g, alkylphenol polyoxyethylene 4g, n-butyl alcohol
The dimethylbenzene of 3g, 10g and the ketopyrrolidine of 10g, the xanthan gum of 0.1g, remaining supplies 100g, n-butyl alcohol and water with water
Dissolving and form aqueous phase, remaining component mix and blend forms oil phase, slowly aqueous phase is added in oil phase under cutter effect,
And continue to shear 10～30 minutes, form the Lepimectin chlopyrifos water that principle active component weight percentage is 62%
Emulsion.
Embodiment 5:
Weigh 40gLepimectin, 2g chlopyrifos, calcium dodecyl benzene sulfonate 5g, alkylphenol polyoxyethylene 4g, 30g
Solvent xylene and the ketopyrrolidine of 15g, remaining complements to 100g, former medicine, solvent, emulsifying agent, cosolvent with water
Mix and blend forms homogeneous phase transparent solution, is then slowly added into water and stirs formation clear solution, being principle active component weight
Amount percentage composition is the Lepimectin chlorpyrifos micro emulsion of 42%.
Embodiment 6:
Weigh 2gLepimectin, 40g chlopyrifos, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 3g,
Dimethylbenzene is to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, is formed and the most effectively becomes
The Lepimectin chlorpyrifos ec dividing weight percentage to be 42%.
Embodiment 7:
Weigh 20gLepimectin, 2g chlopyrifos, sodium lignin sulfonate 3g, polyoxyethylene poly-oxygen propylene aether and sulfate thereof
4g, xanthan gum 0.2g, ethylene glycol 10g, silica ethane 0.1g, aluminium-magnesium silicate 0.5g, supply 100g with water, at sand mill
Effect lower form the Lepimectin chlopyrifos suspending agent that principle active component weight percentage is 22%.
Embodiment 8:
Weigh 2gLepimectin, 20g chlopyrifos, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether 15g,
Dimethylbenzene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, is formed and the most effectively become
The Lepimectin chlorpyrifos ec dividing weight percentage to be 22%.
Embodiment 9:
Weigh 10gLepimectin, 2g chlopyrifos, sodium lignin sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g,
Polyvinyl alcohol 5g, Borax 2g, Kaolin 28g, form main effectively one-tenth by above raw material by the method for water dispersion granule
The Lepimectin chlopyrifos water dispersible granules dividing weight percentage to be 12%.
Embodiment 10:
Weigh 10gLepimectin, 5g chlopyrifos, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether 15g,
Dimethylbenzene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, is formed and the most effectively become
The Lepimectin chlorpyrifos ec dividing weight percentage to be 15%.
Embodiment 11:
Weigh 10gLepimectin, 10g chlopyrifos, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g,
Dimethylbenzene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, is formed and the most effectively become
The Lepimectin chlorpyrifos ec dividing weight percentage to be 20%.
Drug effect checking test
1, indoor virulence determination of activity
Weigh Lepimectin and chlopyrifos 30g, calcium dodecyl benzene sulfonate 4g altogether, phenethyl phenol polyethenoxy ether 4g,
Vegetable oil is to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, is configured to main effective
Ingredients Weight percentage composition is the Lepimectin chlorpyrifos ec of 30%.Wherein Lepimectin and chlopyrifos specifically than
Example is shown in Table 1 and 2.
Using feedstuff to add poison method and carry out indoor potentiation bioassay, selection resistant bollworm is target pest, often processes repetition 3
Secondary, every concentration process 60, with probability value method calculate each medicament antagonism bollworm toxicity regression equation and lethal in dense
Degree LC50, use LC50Value press Sun Yun abundant method calculating co-toxicity coefficient, the results are shown in Table 1:
Table 1Lepimectin, chlopyrifos and the toxicity test of compounding sample antagonism bollworm thereof and co-toxicity coefficient
In table, data show, after Lepimectin and chlopyrifos mixture, antagonism bollworm are had potentiation, listed in table
Proportioning co-toxicity coefficient be both greater than 120, therefore Lepimectin and chlopyrifos mixture have significant synergies.
Weigh Lepimectin, chlopyrifos uses conventional formulation method to be configured to principle active component weight percent by different proportion
Content is the Lepimectin chlorpyrifos ec of 30%.Concrete ratio is shown in Table 2.
Using feedstuff to add poison method and carry out indoor potentiation bioassay, selection rice-stem borer is target pest, often processes repetition
3 times, calculate toxicity regression equation and lethal concentration of 50 LC of each medicament antagonism striped rice borer by probability value method50, use LC50
Value press Sun Yun abundant method calculating co-toxicity coefficient, the results are shown in Table 2:
Table 2Lepimectin, chlopyrifos and compounding sample thereof to striped rice borer toxicity test and co-toxicity coefficient
In table, data show, have potentiation after Lepimectin and chlopyrifos mixture to rice-stem borer, listed by table
Proportioning co-toxicity coefficient is all much larger than 120, and therefore Lepimectin and chlopyrifos mixture have significant synergies.
2, field control effectiveness test
Using embodiment institute sample product to carry out the field test of control in field bollworm, comparison medicament is 40% chlopyrifos EC
With 10%LepimectinEC (cream), it is diluted according to the extension rate in form 3, after medicine, looks into 3 days, 7 days,
The result of 14 days, result is shown in Table 3:
The field test results of table 3Lepimectin-chlorpyrifos mixture antagonism bollworm
Example has fabulous quick-acting to antagonism bollworm as can be seen from Table 3, and the lasting period is long, in field
Performance is good, is the outstanding medicament preventing and treating antagonism bollworm.
Measure through indoor synergism test and show: with chlorpyrifos mixture agent, bollworm and rice-stem borer are had aobvious by Lepimectin
The synergistic insecticidal action write；Field control effectiveness test also indicates that all of built agent of the present invention is the most aobvious to bollworm insecticidal effect equally
Write the effect higher than corresponding single dose pesticide.
Claims (10)
1. containing Lepimectin and a compound pesticide compositions for chlopyrifos, it is characterized in that this compound pesticide compositions with
Lepimectin and chlopyrifos are active insecticidal components, and wherein, the weight ratio of Lepimectin and chlopyrifos is 0.1～80:
0.5～80.
The most according to claim 1 containing Lepimectin with the compound pesticide compositions of chlopyrifos, it is characterized in that described
Lepimectin and the weight ratio of chlopyrifos be 1～60:1～60.
The most according to claim 2 containing Lepimectin with the compound pesticide compositions of chlopyrifos, it is characterized in that described
Lepimectin and the weight ratio of chlopyrifos be 1～40:1～40.
The most according to claim 3 containing Lepimectin with the compound pesticide compositions of chlopyrifos, it is characterized in that described
Lepimectin and the weight ratio of chlopyrifos be 1～30:1～30.
The most according to claim 1 containing Lepimectin with the compound pesticide compositions of chlopyrifos, it is characterized in that
Lepimectin and both chlopyrifos weight percentage in this compound pesticide compositions are 3%～80%.
The most according to claim 5 containing Lepimectin with the compound pesticide compositions of chlopyrifos, it is characterized in that
Lepimectin and both chlopyrifos weight percentage in this compound pesticide compositions are 5%～55%.
The most according to claim 1 containing Lepimectin with the compound pesticide compositions of chlopyrifos, it is characterized in that this is multiple
As active insecticidal components and insecticides adjuvant is configured on pesticide the agent of permission with chlopyrifos with Lepimectin to close Pesticidal combination
Type.
The most according to claim 7 containing Lepimectin with the compound pesticide compositions of chlopyrifos, it is characterized in that described
Dosage form is cream, suspending agent, aqueous emulsion, wettable powder, microemulsion or water dispersion granule.
9. the compound pesticide compositions containing Lepimectin and chlopyrifos described in claim 1 prevents and treats resistance squama wing in preparation
Application on the insecticidal materials of mesh insect.
Compound pesticide compositions containing Lepimectin and chlopyrifos the most according to claim 9 is in preparation preventing and treating cotton
Application on the insecticidal materials of earworm or snout moths larva.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610454033.2A CN105994353A (en) | 2016-06-21 | 2016-06-21 | Composite insecticide composition containing Lepimectin and chlorpyrifos and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201610454033.2A CN105994353A (en) | 2016-06-21 | 2016-06-21 | Composite insecticide composition containing Lepimectin and chlorpyrifos and application thereof |
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| CN105994353A true CN105994353A (en) | 2016-10-12 |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1299595A (en) * | 2001-01-05 | 2001-06-20 | 深圳市诺普信农化有限公司 | Abmectin-chlorpyrifos pesticide composition |
| US20100144888A1 (en) * | 2008-08-18 | 2010-06-10 | Ecosmart Technologies, Inc. | Pesticidal methods and compositions for modulating gaba receptors |
| CN105432657A (en) * | 2014-09-30 | 2016-03-30 | 青岛康和食品有限公司 | Efficient insecticide containing biopesticide lepimectin, chlorpyrifos and spirotetramat |
| CN105519568A (en) * | 2014-09-30 | 2016-04-27 | 青岛康和食品有限公司 | High-efficiency pesticide containing profenofos, flubendiamide, chlorpyrifos and biopesticide lepimectin |
-
2016
- 2016-06-21 CN CN201610454033.2A patent/CN105994353A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1299595A (en) * | 2001-01-05 | 2001-06-20 | 深圳市诺普信农化有限公司 | Abmectin-chlorpyrifos pesticide composition |
| US20100144888A1 (en) * | 2008-08-18 | 2010-06-10 | Ecosmart Technologies, Inc. | Pesticidal methods and compositions for modulating gaba receptors |
| CN105432657A (en) * | 2014-09-30 | 2016-03-30 | 青岛康和食品有限公司 | Efficient insecticide containing biopesticide lepimectin, chlorpyrifos and spirotetramat |
| CN105519568A (en) * | 2014-09-30 | 2016-04-27 | 青岛康和食品有限公司 | High-efficiency pesticide containing profenofos, flubendiamide, chlorpyrifos and biopesticide lepimectin |
Non-Patent Citations (1)
| Title |
|---|
| 胡萍 等: "生物杀虫剂—Lepimectin", 《世界农药》 * |
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Application publication date: 20161012 |