CN102415396A - Compound insecticidal composition containing dinotefuran and carbosulfan and purpose thereof - Google Patents
Compound insecticidal composition containing dinotefuran and carbosulfan and purpose thereof Download PDFInfo
- Publication number
- CN102415396A CN102415396A CN2010102990811A CN201010299081A CN102415396A CN 102415396 A CN102415396 A CN 102415396A CN 2010102990811 A CN2010102990811 A CN 2010102990811A CN 201010299081 A CN201010299081 A CN 201010299081A CN 102415396 A CN102415396 A CN 102415396A
- Authority
- CN
- China
- Prior art keywords
- carbosulfan
- mti
- pesticide compositions
- compound pesticide
- dinotefuran
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
The invention discloses a compound insecticidal composition containing dinotefuran and carbosulfan and a purpose thereof. The insecticidal composition treats dinotefuran and carbosulfan as main effective components, wherein the weight ratio of dinotefuran to carbosulfan is 1-70:1-70. The insecticidal composition of the invention, which can control homoptera pests and lepidoptera pests on crops, and can especially control rice hoppers, aphids, rice stem borers and cotton bollworms, can generate high synergy effects, and allows the pest drug resistance to be overcome and delayed, the insecticidal speed to be fast, the persistent period to be long, the drug consumption cost to be reduced, and the control effect to be obviously higher than the control effect one of dinotefuran and carbosulfan.
Description
Technical field
The invention belongs to pesticide field, be specifically related to a kind of compound pesticide compositions that contains MTI-446 and carbosulfan and uses thereof.
Background technology
MTI-446 (dinotefuran), white crystal, 107.5 ℃ of fusing points., 94.5～101.5 ℃ of industrial goods. and, vapour pressure＜1.7 * 10-6pa (30 ℃ .), density 1.33 (25 ℃ .).Solvability is water 40g/L, is insoluble in cyclohexane, solvent wet goods organic solvent.
MTI-446 is fool proof to mammal, and its acute oral LD50 is male rat 2450mg/kg, female rats 2275mg/kg; Male mice 2840mg/kg, female mice 2000mg/kg.To rat acute through skin LD50＞2000mg/kg (female, hero).No teratogenesis, carcinogenic and mutagenicity.MTI-446 is also fool proof to aquatile.The ichthyotoxin test shows that MTI-446 is to carp nm (48h)＞1000mg/L, to water flea＞1000mg/L; Equally, MTI-446 is also very low to birds toxicity, and through the honeybee test is learnt, MTI-446 is to honeybee safety to quail acute oral LD50＞1000mg/kg., and do not influence honeybee producting honey.
This medicament insecticidal spectrum is wide, has remarkable interior suction osmosis, and has promptly shown very high insecticidal activity at very low dosage.This medicament is fool proof to mammal, birds and aquatile, and crop is not had poisoning, can be used for numerous crops such as paddy rice, fruit tree, vegetables.
Carbosulfan is a carbamate chemicals for agriculture, i.e. the low derivative that poisons of carbofuran agricultural chemicals belongs to highly effective and safe, interior absorption, killing insects by touching miticide easy to use, is one of comparatively ideal alternative kind of highly toxic pesticide carbofuran.The control that can be widely used in the ten kinds of insects such as blister mite, aphid, thrips, leafhopper and borer pest on fruit tree, cotton, vegetables, grain class and other diversified economy crops is used, and all kinds of aphids are had special efficacy; Instant effect, lasting period are long; These article or a plant growth regulators have the promotion plant growth simultaneously, and ripen in advance promotes effects such as young shoot growth.
But insect such as rice fulgorid, aphid is under the condition of present long-term prescription, and resistance increases gradually, and the agent of agricultural chemicals list descends to the effect of control of insect gradually.The inventor finds that after deliberation the synergistic complex of agricultural chemicals is expanding prevention spectrum and the effective measures that improve preventive effect, does not find the Pesticidal combination of relevant MTI-446 and carbosulfan up to now as yet.
Summary of the invention
The purpose of this invention is to provide a kind of high-efficiency low-toxicity compound pesticide compositions that contains MTI-446 and carbosulfan, this Pesticidal combination is the multifunctional insecticide composition of control homoptera pest.
Another object of the present invention provides this Pesticidal combination and prevents and treats the application on the insecticidal materials of resistance homoptera pest in preparation, particularly the application on the insecticidal materials of preparation control rice fulgorid, aphid, aleyrodid, cotton bollworm and the snout moth's larva of rice.
The objective of the invention is to realize through following technical scheme:
A kind of compound pesticide compositions that contains MTI-446 and carbosulfan, this Pesticidal combination is main active ingredient with MTI-446 and carbosulfan, wherein, the weight ratio of MTI-446 and carbosulfan is 1～70: 1～70.Effective ingredient is present in the composition with the synergy effective dose in this Pesticidal combination.
The weight ratio of MTI-446 and carbosulfan preferred 1～50 in this compound pesticide compositions: 1～40, further be preferably 1～10: 1～10.
In the present composition, the two percentage by weight that accounts for composition of MTI-446 and carbosulfan is 3～80%.Be preferably 5～55%, most preferably 10～40%.
Pesticidal combination of the present invention is that main active ingredient and insecticides adjuvant and excipient are mixed with any one formulation that allows on the agricultural chemicals, the preferred emulsion of described formulation, suspending agent, wetting powder, aqueous emulsion, microemulsion and water dispersion granule with MTI-446 and carbosulfan.
Auxiliary agent can adopt calcium dodecyl benzene sulfonate, APES, polyoxyethylene polyoxy third rare block compound (like farming breast 33
#), one or more combinations of conventional auxiliary agent such as NPE, excipient comprises cyclohexanone, solvent naphtha, solvent naphtha, water, antifreezing agent (like propane diols), deionized water etc.Above auxiliary agent, excipient and other auxiliary material can singly be used or mix and use.
Pesticidal combination of the present invention has good preventive effect to Homoptera and the lepidoptera pest that rice fulgorid and snout moth's larva etc. is easy to generate resistance; And the inhibition insect is to the pesticide resistance generation of single preparation (MTI-446 or carbosulfan are arbitrary).
Above-mentioned Pesticidal combination can be used for preparing the insecticidal materials of preventing and treating the resistance homoptera pest, in particular for the insecticidal materials of preparation control aleyrodid, rice fulgorid and aphid." % " of the present invention is mass percent.
Beneficial effect compared with prior art of the present invention: compare with single agent; Said composition antagonism Homoptera and lepidoptera pest such as rice fulgorid, aphid etc. have obvious synergistic function, overcome and have delayed pest resistance to insecticide, the expanding prevention spectrum; Desinsection speed is fast, has obviously improved control efficiency; Reduce control recruitment, drug cost; Alternative high-toxic pesticide; Have concurrently quick-acting and long-acting; Compare with the agent of carbosulfan list with MTI-446, produce and the use cost reduction; Suppress the resistance enhancing of homoptera pest to agricultural chemicals, its effect is used apparently higher than its single agent.
Embodiment
Below in conjunction with embodiment the present invention is described further:
Embodiment 1:
Taking by weighing MTI-446, carbosulfan, to adopt the conventional formulation method to be mixed with main effectively composition quality percentage composition by different proportion be 30% MTI-446 carbosulfan missible oil, and concrete ratio is seen table 1,2.The contrast medicament is respectively 30% MTI-446 missible oil and 30% carbosulfan missible oil.
Adopt rice stem infusion process to carry out indoor synergy biologicall test, selecting the resistant rice plant hopper is target pest, every processing repetition 3 times, and every concentration is handled 60, calculates toxicity regression equation and the lethal concentration of 50 LC of each medicament antagonism rice fulgorid with probability value method
50, use LC
50Value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient, and the result sees table 1:
The toxicity test of the composite and single agent antagonism of table 1 MTI-446 and carbosulfan rice fulgorid
Can be known that by table 1 MTI-446 and carbosulfan are composite, co-toxicity coefficient shows good synergistic effects all greater than 120.
Adopt feed to add malicious method and carry out indoor synergy biologicall test, selecting the resistance striped rice borer is target pest, and every processing repetition 3 times is with toxicity regression equation and the lethal concentration of 50 LC of each medicament antagonism rice fulgorid of probability value method calculating
50, use LC
50Value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient, and the result sees table 2:
The toxicity test of the composite and single agent antagonism of table 2 MTI-446 and carbosulfan striped rice borer
Can know that by table 2 MTI-446 and carbosulfan are composite, the co-toxicity coefficient of wheat aphid all greater than 120, is shown good synergistic effects.
Embodiment 2:
Take by weighing 5g MTI-446,50g carbosulfan, phenethyl phenol polyethenoxy ether phosphate 3g, farming breast 33
#2g, APES 1g, solvent naphtha 13g adds water to 100g.Above raw material is mixed by the method input mixing kettle high speed of routine preparation aqueous emulsion, and processing main active ingredient weight percentage is 55% MTI-446-carbosulfan aqueous emulsion.
Embodiment 3:
Take by weighing 10g MTI-446,10g carbosulfan, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate 3g, farming breast 33
#2g, APES 1g, cyclohexanone 10g adds water to 100g.With mixing in the method input mixing kettle of above raw material by routine preparation microemulsion, processing main active ingredient weight percentage is 20% MTI-446-carbosulfan microemulsion.
Embodiment 3 is prevented and treated the paddy rice brown planthopper test of pesticide effectiveness, and the contrast medicament is 20% carbosulfan WP and 20% MTI-446 WP, dilutes according to the extension rate of 3 li of forms; Every mu of ground, dilution back sprays 30 kilograms of soups; Looked into behind the medicine 3 days, 7 days result, result is seen table 3:
Table 3: the composite field test results of MTI-446-carbosulfan to the paddy rice brown planthopper
Field efficacy is the result show, MTI-446 carbosulfan composition antagonism brown planthopper has good control efficiency, and control efficiency all is better than single agent kind.
Embodiment 3 is prevented and treated the rice-stem borer field medicine effect test, and the contrast medicament is 20% carbosulfan WP and 20% MTI-446 WP, dilutes according to the extension rate of 3 li of forms; Every mu of ground, dilution back sprays 30 kilograms of soups; Looked into behind the medicine 3 days, 7 days result, result is seen table 4:
Table 4: the composite field test results of MTI-446-carbosulfan to rice-stem borer
Field efficacy is the result show, MTI-446 carbosulfan composition has good control efficiency to rice-stem borer, and control efficiency all is better than single agent kind.
Embodiment 4:
Take by weighing 5g MTI-446,1g carbosulfan, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, solvent naphtha to 100g.With mixing in the method input mixing kettle of above raw material by routine preparation missible oil, processing main active ingredient weight percentage is 6% MTI-446-carbosulfan missible oil.
Embodiment 5: take by weighing 50g MTI-446,20g carbosulfan, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g, solvent naphtha are to 100g.With mixing in the method input mixing kettle of above raw material by routine preparation missible oil, processing main active ingredient weight percentage is 70% MTI-446-carbosulfan missible oil.
Embodiment 6: take by weighing 2g MTI-446,40g carbosulfan, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, solvent naphtha are to 100g.With mixing in the method input mixing kettle of above raw material by routine preparation missible oil, processing main active ingredient weight percentage is 42% MTI-446-carbosulfan missible oil.
Embodiment 7: take by weighing 2g MTI-446,50g carbosulfan, calcium dodecyl benzene sulfonate 9g, phenethyl phenol polyethenoxy ether 8g, solvent naphtha are to 100g.With mixing in the method input mixing kettle of above raw material by routine preparation missible oil, processing main active ingredient weight percentage is 52% MTI-446-carbosulfan missible oil.
Embodiment 8: take by weighing 5g MTI-446,0.5g carbosulfan, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g, solvent naphtha are to 100g.With mixing in the method input mixing kettle of above raw material by routine preparation missible oil, processing main active ingredient weight percentage is 5.5% MTI-446-carbosulfan missible oil.
Embodiment 9: take by weighing 5g MTI-446,30g carbosulfan, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, solvent naphtha are to 100g.With mixing in the method input mixing kettle of above raw material by routine preparation missible oil, processing main active ingredient weight percentage is 35% MTI-446-carbosulfan missible oil.
Embodiment 10: take by weighing 20g MTI-446,5g carbosulfan, calcium dodecyl benzene sulfonate 7g, phenethyl phenol polyethenoxy ether 9g, solvent naphtha are to 100g.With mixing in the method input mixing kettle of above raw material by routine preparation missible oil, processing main active ingredient weight percentage is 25% MTI-446-carbosulfan missible oil.
Embodiment 11: take by weighing 30g MTI-446,12g carbosulfan, lignin 2g, polyoxyethylene poly-oxygen propylene aether and sulphate 4g thereof; Xanthans 0.15g; Ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g; Water complements to 100g, and under the effect of sand mill, processing main active ingredient weight percentage is 42% MTI-446 carbosulfan suspending agent.
Embodiment 12: take by weighing 2g MTI-446,5g carbosulfan, lignin 10g, Negel 2g, add to 100g with diatomite, processing main active ingredient weight percentage is 7% MTI-446 carbosulfan wetting powder.
Embodiment 13: take by weighing 50g MTI-446,3g carbosulfan, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, solvent naphtha are to 100g.With mixing in the method input mixing kettle of above raw material by routine preparation missible oil, processing main active ingredient weight percentage is 53% MTI-446-carbosulfan missible oil.
Embodiment 14: take by weighing 2g MTI-446,18g carbosulfan; Lignin 10g, Negel 2g, add to 100g with diatomite; Above raw material is mixed in micronizer, and processing main active ingredient weight percentage is 20% MTI-446 and carbosulfan wetting powder.
Embodiment 15: take by weighing 7g MTI-446,70g carbosulfan, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, solvent naphtha are to 100g.With mixing in the method input mixing kettle of above raw material by routine preparation missible oil, processing main active ingredient weight percentage is 77% MTI-446-carbosulfan missible oil.
Embodiment 16: take by weighing 60g MTI-446,5g carbosulfan, the 8g of wooden sodium sulfonate, lauryl sodium sulfate 2g, ammonium sulfate 5g; Polyvinyl alcohol 5g; Borax 2g; Kaolin complements to 100g, and it is 65% MTI-446-carbosulfan water dispersible granules that above raw material is processed main active ingredient weight percentage by the water dispersible granular agent method.
Embodiment 17:
Take by weighing 20g MTI-446,20g carbosulfan, nonyl phenol phosphate 5g, APES 4g, n-butanol 3g; 10g xylol and 20g pyrrolidones, the 0.1g xanthans, all the other waters complement to 100g; N-butanol and the water-soluble formation water of separating, all the other components mix stirring and form oil phase, under the clipper effect, slowly add water in the oil phase and go; And continue to shear 10～30 minutes, processing main active ingredient weight percentage is 40% MTI-446 carbosulfan aqueous emulsion.
Embodiment 18:
Take by weighing 60g MTI-446,1g carbosulfan, calcium dodecyl benzene sulfonate 5g; APES 4g; The xylol of 10g and the pyrrolidones of 15g, all the other waters complement to 100g, above-mentioned former medicine, solvent, emulsifier, cosolvent are mixed to stir forming homogeneous phase transparent solution; Slowly add entry at last and stir the formation clear solution, processing main active ingredient weight percentage is 61% MTI-446 carbosulfan microemulsion.
Claims (10)
1. a compound pesticide compositions that contains MTI-446 and carbosulfan is characterized in that this Pesticidal combination is main active ingredient with MTI-446 and carbosulfan, and wherein, the weight ratio of MTI-446 and carbosulfan is 1～70: 1～70.
2. Pesticidal combination according to claim 1, the weight ratio that it is characterized in that described MTI-446 and carbosulfan is 1～50: 1～40.
3. Pesticidal combination according to claim 2, the weight ratio that it is characterized in that described MTI-446 and carbosulfan is 1～10: 1～10.
4. the compound pesticide compositions that contains MTI-446 and carbosulfan according to claim 1 is characterized in that the two weight percentage that accounts for composition of MTI-446 and carbosulfan is 3～80%.
5. the compound pesticide compositions that contains MTI-446 and carbosulfan according to claim 4 is characterized in that the two weight percentage that accounts for composition of MTI-446 and carbosulfan is 5～55%.
6. the compound pesticide compositions that contains MTI-446 and carbosulfan according to claim 5 is characterized in that the two weight percentage that accounts for composition of MTI-446 and carbosulfan is 10～40%.
7. the compound pesticide compositions that contains MTI-446 and carbosulfan according to claim 1 is characterized in that it is that main active ingredient and insecticides adjuvant, excipients are mixed with any one formulation that allows on the agricultural chemicals with MTI-446 and carbosulfan.
8. the compound pesticide compositions that contains MTI-446 and carbosulfan according to claim 7 is characterized in that said formulation is missible oil, suspending agent, aqueous emulsion, wetting powder, microemulsion or water dispersion granule.
9. the described compound pesticide compositions that contains MTI-446 and carbosulfan of claim 1 is prevented and treated the application on the insecticidal materials of resistance Homoptera or lepidoptera pest in preparation.
10. the compound pesticide compositions that contains MTI-446 and carbosulfan according to claim 9 anti-ly eliminates aphis in preparation, the application on the insecticidal materials of aleyrodid, plant hopper, cotton bollworm and the snout moth's larva of rice.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010102990811A CN102415396A (en) | 2010-09-28 | 2010-09-28 | Compound insecticidal composition containing dinotefuran and carbosulfan and purpose thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010102990811A CN102415396A (en) | 2010-09-28 | 2010-09-28 | Compound insecticidal composition containing dinotefuran and carbosulfan and purpose thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102415396A true CN102415396A (en) | 2012-04-18 |
Family
ID=45940237
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010102990811A Pending CN102415396A (en) | 2010-09-28 | 2010-09-28 | Compound insecticidal composition containing dinotefuran and carbosulfan and purpose thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102415396A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103039498A (en) * | 2013-01-08 | 2013-04-17 | 广西汇丰生物科技有限公司 | Insecticidal composition containing dinotefuran and benfuracarb |
| CN103141505A (en) * | 2013-03-29 | 2013-06-12 | 广西田园生化股份有限公司 | Film diffusing oil agent combined reagent for preventing and treating rice planthopper |
| CN113024314A (en) * | 2020-12-31 | 2021-06-25 | 河南好年景生物发展有限公司 | Sustained and controlled release pesticide fertilizer granules containing carbosulfan and dinotefuran |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002226306A (en) * | 2001-02-01 | 2002-08-14 | Mitsui Chemicals Inc | Sustained release type fine particle and method for producing the same |
| JP2002363013A (en) * | 2001-06-07 | 2002-12-18 | Mitsui Chemicals Inc | Insecticidal and fungicidal composition |
| CN1646018A (en) * | 2002-02-21 | 2005-07-27 | 拜尔农作物科学股份公司 | Synergistic insecticide mixtures |
| CN101212904A (en) * | 2005-03-09 | 2008-07-02 | Fmc巴西化学有限公司 | Carbosulfane-based pesticidal compositions, process for preparing same, process for controlling insects/mites/nematodes, and use of said compositions |
-
2010
- 2010-09-28 CN CN2010102990811A patent/CN102415396A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002226306A (en) * | 2001-02-01 | 2002-08-14 | Mitsui Chemicals Inc | Sustained release type fine particle and method for producing the same |
| JP2002363013A (en) * | 2001-06-07 | 2002-12-18 | Mitsui Chemicals Inc | Insecticidal and fungicidal composition |
| CN1646018A (en) * | 2002-02-21 | 2005-07-27 | 拜尔农作物科学股份公司 | Synergistic insecticide mixtures |
| CN101212904A (en) * | 2005-03-09 | 2008-07-02 | Fmc巴西化学有限公司 | Carbosulfane-based pesticidal compositions, process for preparing same, process for controlling insects/mites/nematodes, and use of said compositions |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103039498A (en) * | 2013-01-08 | 2013-04-17 | 广西汇丰生物科技有限公司 | Insecticidal composition containing dinotefuran and benfuracarb |
| CN103141505A (en) * | 2013-03-29 | 2013-06-12 | 广西田园生化股份有限公司 | Film diffusing oil agent combined reagent for preventing and treating rice planthopper |
| CN103141505B (en) * | 2013-03-29 | 2015-04-22 | 广西田园生化股份有限公司 | Film diffusing oil agent combined reagent for preventing and treating rice planthopper |
| CN113024314A (en) * | 2020-12-31 | 2021-06-25 | 河南好年景生物发展有限公司 | Sustained and controlled release pesticide fertilizer granules containing carbosulfan and dinotefuran |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102415398A (en) | Composite insecticide composition containing dinotefuran and emamectin benzoate and purpose thereof | |
| CN102415396A (en) | Compound insecticidal composition containing dinotefuran and carbosulfan and purpose thereof | |
| CN102415404B (en) | Composite insecticidal composition containing dinotefuran and isoprocarb and purpose thereof | |
| CN102415408A (en) | Composite insecticidal composition containing dinotefuran and chlopyrifos and purpose thereof | |
| CN102415395A (en) | Composite pesticidal composition containing dinotefuran and imidacloprid and application of composite pesticidal composition | |
| CN103621539A (en) | Composite insecticidal composition containing clothianidin and chlorfenapyr and applications thereof | |
| CN102415402B (en) | Compound insecticidal composition containing dinotefuran and fenobucarb and application thereof | |
| CN103053594A (en) | Synergistic insecticidal composition containing tolfenpyrad and theta-cypermethrin and its application | |
| CN105475339B (en) | A kind of Synergistic insecticidal compositions and its application containing propargite and cycloprothrin | |
| CN102415407A (en) | Composite pesticidal composition containing dinotefuran and profenofos and application thereof | |
| CN102415399B (en) | Composite insecticide composition containing dinotefuran and methyl carbamate and purpose thereof | |
| CN102415403B (en) | Composite pesticidal composition containing dinotefuran and MTMC and application thereof | |
| CN103563900A (en) | Composite insecticidal composition containing methoxyfenozide and spinosad and application thereof | |
| CN106035369A (en) | Lepimectin and Profenofos contained compound insecticidal composition and use thereof | |
| CN104642378B (en) | A kind of containing Profenofos and the compound pesticide compositions of ethyl pleocidin and application | |
| CN105557760A (en) | Synergistic insecticidal composition containing propargite and tetranactin, and application thereof | |
| CN105685044B (en) | Pesticidal combination containing ethyl pleocidin and thiocyclam | |
| CN103621552B (en) | Compound pesticide compositions of a kind of clothianidin-containing and Profenofos and uses thereof | |
| CN104642362A (en) | A composite pesticidal composition comprising diafenthiuron and spinetoram and applications thereof | |
| CN103039508A (en) | Complex insecticidal composition containing tolfenpxrad and diazinon and application thereof | |
| CN103181398A (en) | Insecticidal composition containing tolfenpyradn and profenofos and application thereof | |
| CN104738058A (en) | Compound insecticidal composition containing pyridalyl and matrine, and application thereof | |
| CN103053607A (en) | Synergistic insecticidal composition containing lufenuron and profenofos and application | |
| CN106973935A (en) | Compound pesticide compositions of containing chromafenozide and acrinathrin and application thereof | |
| CN105475344A (en) | Synergistic insecticidal composition containing propargite and silafluofen and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20120418 |