CN103141505A - Film diffusing oil agent combined reagent for preventing and treating rice planthopper - Google Patents
Film diffusing oil agent combined reagent for preventing and treating rice planthopper Download PDFInfo
- Publication number
- CN103141505A CN103141505A CN201310105576XA CN201310105576A CN103141505A CN 103141505 A CN103141505 A CN 103141505A CN 201310105576X A CN201310105576X A CN 201310105576XA CN 201310105576 A CN201310105576 A CN 201310105576A CN 103141505 A CN103141505 A CN 103141505A
- Authority
- CN
- China
- Prior art keywords
- film
- oil solution
- spreading oil
- ether
- weight portions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention provides a film diffusing oil agent combined reagent for preventing and treating rice planthopper. The film diffusing oil agent combined reagent consists of an active ingredient, a film agent, a cosolvent and a solvent. When the reagent is used, a film diffusing oil agent is directly poured in a paddy field and dilution using water is not required. The film diffusing oil agent entering water is diffused in the form of oil films in the whole paddy field, and can climb along a rice rod, so that rice planthopper can be effectively prevented and treated, and rice borers can be prevented. The film diffusing oil agent combined reagent is a novel efficient pesticide formulation.
Description
Technical field
The present invention relates to a kind of film-spreading oil solution combination medicament of preventing and treating rice hoppers, belong to technical field of pesticide preparations.
Background technology
MTI-446, chemical name are 1-methyl-2-nitro-3-(tetrahydrochysene-3-furfuryl) guanidine, (EZ)-(RS)-1-methyl-2-nitro-3-(tetrahydrochysene-3-furfuryl) guanidine, N-methyl-N'-nitro-N''-[(tetrahydrochysene-3-furans) methyl] guanidine.Water solubility is 40g/L.This medicament have tag, strong, quick-acting height of absorption in stomach toxicity and root, the characteristics such as the lasting period is long, insecticidal spectrum is wide, and sucking insect is had excellent preventive effect, and has namely shown very high insecticidal activity at very low dosage.Be mainly used in preventing and treating aphid, leafhopper, plant hopper, thrips, aleyrodid and resistant strain thereof on the various crop such as wheat, paddy rice, cotton, vegetables, fruit tree, tobacco leaf.And carbamate chemicals for agriculture effect wide spectrum, can by tag, the stomach poison function kill pests.MTI-446 and carbamates medicament can effectively be prevented and treated for the rice fulgorid occurrence characteristic.
In recent years, the generation of China's rice hoppers is always in rising trend.Rice fulgorid adult and nymph are clustered on the stem stalk of rice clump bottom thorn and inhale juice, it is caused harm to paddy rice, inhale juice except directly stinging, make growth retardation, when serious, the rice clump is agglomerating withered, outside the dead stalk lodging in even full field, lays eggs and also can stab plant, destroy conducting tissue, hinder the nutriment viral disease of transporting and spread disease.Prevent and treat at present rice hoppers, usually adopt traditional conventional spray pattern to prevent and treat.But this conventional spray method not only takes a lot of work, time-consuming, and easily make the drift of medicine mist cause the environment around dispenser ground to be polluted.In addition because rice hoppers is mainly inhaled juice in thorn on the stem stalk of rice clump bottom, when paddy rice Feng Hanghou carries out conventional foliar spray control, not only make medicament be difficult to spray application to rice clump bottom stem stalk because the rice strain is too close, and because the drift of medicine mist, photodissociation are run off, the dosage that causes medicament to be delivered to the paddy rice base portion also reduces greatly.So with conventional spray method control rice fulgorid, the medicament availability is low, actual effect is also low.And along with the appearance of China's aging population and recruitment famine, the labour becomes rare resource just gradually, and human cost improves constantly, and agriculture production cost continues to increase; Agricultural production is obviously seasonal, and rice hoppers often needs a large amount of manpowers to prevent and treat at short notice.
At present, 201210125077.2), " 5% preparation of ether chrysanthemum ester film-spreading oil solution and operation technique research ", " 5% ether chrysanthemum ester film-spreading oil solution prepare and to the control efficiency of rice fulgorid ", " 8% Buprofezin film-spreading oil solution is prevented and treated the rice hoppers Probe into effect " patent and related article report about control rice fulgorid film-spreading oil solution has " preparation of ether chrysanthemum ester film-spreading oil solution and the application on the control rice fulgorid thereof " (application number:, ether chrysanthemum ester itself there is no internal absorption characteristic, and Buprofezin is slower action time.And ether chrysanthemum ester and Buprofezin water-soluble are relatively poor, are respectively 1ug/L and 0.9mg/L, thus medicament to make after film-spreading oil solution the valid density in water less, crystallization in Yi Zaishui and lose effect.When medicament after the rice stem base portion is assembled on kill rice fulgorid after conducting; protect without medicament but make in the paddy rice body because active ingredient concentration is low; rice fulgorid is migratory pest, causes rice fulgorid can not effectively prevent and treat the insect that the later stage migrates after the death of tagging.The conventional pesticides such as Buprofezin, ether chrysanthemum ester, Imidacloprid, use separately for a long time at present, and rice fulgorid has been produced certain pesticide resistance, causes drug effect to descend.
Summary of the invention
For take a lot of work in present rice fulgorid preventing and controlling, time-consuming, consumption is seriously polluted greatly, the agricultural chemicals availability is low, actual control efficiency is low, reduce the consumption of single dose MTI-446, delay the problem of drug-fast generation or development, a kind of saving of labor who the object of the present invention is to provide, laborsaving, environmental contamination reduction, raising agricultural chemicals availability, the actual control efficiency that improves, and the film-spreading oil solution combination medicament of the anti-paddy rice borer of holding concurrently when realizing the control rice fulgorid.
The present invention realizes that the technical scheme that above-mentioned purpose is taked is: a kind of film-spreading oil solution combination medicament of preventing and treating rice hoppers comprises the component of following weight proportion:
As preferably, the carbamates medicament in the present invention is any one of following insecticide: carbosulfan, Benfuracard micro, UC-51762, Mobucin, Bassa, carbaryl, fenoxycarb.
Described film forming agent is selected one or more in Lauryl Alcohol ester, methyl laurate, 18 alcohol, propane diols phenylate and monobutyl ether acetate.
As preferably, in film forming agent, methyl laurate can be 0,3,4,5 or 8 weight portions; 18 alcohol can be 0,0.5,2,3,4,5,6,7 or 8 weight portions; The propane diols phenylate can be 0,2,3 or 5 weight portions; Monobutyl ether acetate can be 0,1,2,3,4,5 or 13 weight portions.
Described diffusant is selected one or more in polyoxyethylene nonylphenol ether, fatty alcohol-polyoxyethylene ether, fatty alcohol-polyoxyethylene ether yuban, castor oil polyoxyethylene ether, styryl phenol polyethenoxy ether.
As preferably, the polyoxyethylene nonylphenol ether in diffusant can be 0,0.5,1.5,2,3,4,5,6,7 or 10 weight portions; Fatty alcohol-polyoxyethylene ether can be 0,0.5,3,6,8 or 12 weight portions; The fatty alcohol-polyoxyethylene ether yuban can be 0,1.5 or 5 weight portions; Castor oil polyoxyethylene ether can be 0 or 3 weight portions; Styryl phenol polyethenoxy ether 0 or 5 weight portions.
Described solvent is selected one or more in trimethylbenzene, dimethylbenzene, isopropyl alcohol, dimethyl formamide, n-formyl sarcolysine base pyrrolidones, n-butanol, fatty acid distribution of coconut oil methyl esters, methyl oleate, methylated vegetable oil, ethyl acetate, repefral, dibutyl phthalate, and solvent is preferably dimethyl formamide, isopropyl alcohol, trimethylbenzene, methyl oleate.
In the present invention, a typical example of above-mentioned film-spreading oil solution combination medicament is:
[0011] preferred, the film-spreading oil solution combination medicament of preventing and treating rice hoppers of the present invention, MTI-446 and carbamates medicament account for 0.1%～60% of composition total weight.
Film-spreading oil solution combination medicament of the present invention can prepare by following method: in the container with agitator, first with solvent with the MTI-446 stirring and dissolving after, then add diffusant, add at last film forming agent, fully mix to transparent and get final product.
The described film-spreading oil solution combination medicament of preventing and treating rice hoppers is mainly used in the control of rice hoppers, the anti-paddy rice borer of can holding concurrently simultaneously.
Film-spreading oil solution combination medicament of the present invention is used conveniently, saving of work and time, use cost is low, long to human body, environmental friendliness, lasting period, be difficult for producing resistance, improve again the effective ingredient availability simultaneously.The present invention is indoor and field medicine effect test screening by agricultural chemicals, find a kind of can delaying drug resistance, enlarge the film-spreading oil solution combination medicament of action spectrum, the remarkable synergistic effect of tool, final discovery MTI-446 and the composite use of carbamate insecticide have significant synergy, the medicament of selecting the strong MTI-446 of interior absorption should have better effects in conjunction with contact killing type medicament carbamate to the rice fulgorid control, and both are composite has complementarity.Except according to above-mentioned feature, the film-spreading oil solution that complex composition is processed is present, still finds no relevant report.
Beneficial effect of the present invention is:
1) laborsaving, saving of labor.Compare with the routine spraying, product of the present invention in use, easy and simple to handle, need not use any spraying equipment, need not add water during dispenser or mix soil, every mu only needs this medicine 100-150ml, only need directly medicament to be poured into water, every mu got final product in artificial spraying time 3-5 minute, and conventional the spraying artificial spraying time 30-40 minute used every mu of product of the present invention can save human cost and dropped into more than 80%, improves work efficiency 8-10 doubly than conventional dispenser, greatly alleviating dispenser labour intensity, is to change existing significant improvement of traditional heavy insecticide-applying way and breakthrough.
2) improve the availability of pesticide active ingredient, reduce the usage amount of agricultural chemicals, improve actual control efficiency.Under same formulation rate, the pesticide active ingredient dosage that the film-spreading oil solution dispenser arrives the paddy rice base portion reaches the dosage (table 1) of paddy rice base portion far above routine spraying pesticide active ingredient, so use film-spreading oil solution can effectively improve the availability of pesticide active ingredient, reduce simultaneously the usage amount of agricultural chemicals, improve actual control efficiency.
3) environmental contamination reduction.Film-spreading oil solution of the present invention can not produce the phenomenon of liquid drift in the dispenser process, reduced the pollution of applying pesticides to surrounding environment.
4) be conducive to delay pesticide resistance and produce, enlarge the control spectrum of medicament.Film-spreading oil solution combination medicament of the present invention can be held concurrently in the control rice fulgorid and be prevented the paddy rice borer.
5) this medicine weatherproof.No matter rain or all directly dispensers of cloudy day preventing and treating optimum period, only a need paddy field water either is not overflowed ridge and is got final product; The droplet that has caused because of the impact of wind-force factor when having avoided simultaneously conventional spraying to use is elegant, has reduced the harm to people, animal and other beneficial organism.
Embodiment
The present invention describes with the following example, but does not limit the scope of the invention.
Following examples active component content adds after all calculating by folding hundred.
Embodiment 1:6% MTI-446 film-spreading oil solution
Formula: MTI-446 6kg, dimethylbenzene 3kg, ethyl acetate 4kg, dimethyl formamide 3kg, nonyl phenol oxygen vinethene 5kg, fatty alcohol-polyoxyethylene ether 3kg, methyl laurate 4kg, propane diols phenylate 3kg, monobutyl ether acetate 5kg, dimethylbenzene complements to 100kg.
Preparation technology: in the container with agitator, after first using solvent ethyl acetate, dimethyl formamide and dimethylbenzene with the MTI-446 stirring and dissolving, add again diffusant polyoxyethylene nonylphenol ether and fatty alcohol-polyoxyethylene ether, add at last film forming agent methyl laurate, propane diols phenylate, monobutyl ether acetate and citric acid, fully mix to transparent, namely get 5% MTI-446 film-spreading oil solution.
According to the preparation technology identical with embodiment 1, preparation following examples.
Embodiment 2:8% MTI-446 film-spreading oil solution
Formula: MTI-446 8kg, dimethyl formamide 6kg, polyoxyethylene nonylphenol ether 5kg, fatty alcohol-polyoxyethylene ether 3kg, 18 pure 4kg, propane diols phenylate 2kg, monobutyl ether acetate 5kg, dimethylbenzene complements to 100kg.
Embodiment 3:30% MTI-446 carbosulfan film-spreading oil solution
Formula: MTI-446 2kg, carbosulfan 28kg, dimethyl formamide 10kg, fatty alcohol-polyoxyethylene ether yuban 5kg, polyoxyethylene nonylphenol ether 10kg, methyl laurate 8kg, 18 pure 5kg, propane diols phenylate 5kg, monobutyl ether acetate 2kg, dimethylbenzene complements to 100kg.
Embodiment 4:60% MTI-446 Benfuracard micro film-spreading oil solution
Formula: MTI-446 10kg, Benfuracard micro 50kg, dimethylbenzene 12kg, dimethyl formamide 3kg, styryl phenol polyethenoxy ether 5kg, polyoxyethylene nonylphenol ether 5kg, methyl laurate 4kg, 18 pure 2kg, propane diols phenylate 5kg, monobutyl ether acetate 4kg, trimethylbenzene complements to 100kg.
Embodiment 5:50% MTI-446 carbaryl film-spreading oil solution
Formula: MTI-446 10kg, carbaryl 40kg, n-formyl sarcolysine base pyrrolidones 5kg, fatty alcohol-polyoxyethylene ether yuban 1.5kg, polyoxyethylene nonylphenol ether 1.5kg, 18 pure 8kg, methyl laurate 5kg, ethyl acetate complement to 100kg.
Embodiment 6:40% MTI-446 UC-51762 film-spreading oil solution
Formula: MTI-446 5kg, UC-51762 35kg, fatty alcohol-polyoxyethylene ether yuban 5kg, castor oil polyoxyethylene ether 3kg, 18 pure 2kg, methyl laurate 3kg, monobutyl ether acetate 5kg, methyl oleate complements to 100kg.
Embodiment 7:15% MTI-446 Bassa film-spreading oil solution
Formula: MTI-446 5kg, Bassa 10kg, trimethylbenzene 8kg, dimethyl formamide 3kg, fatty alcohol-polyoxyethylene ether yuban 5kg, polyoxyethylene nonylphenol ether 2kg, 18 pure 2kg, methyl laurate 5kg, monobutyl ether acetate 2kg, dimethylbenzene complements to 100kg.
Embodiment 8:0.1% MTI-446 film-spreading oil solution
Formula: MTI-446 0.1kg, dibutyl phthalate 1kg, dimethyl formamide 2kg, fatty alcohol-polyoxyethylene ether 0.5kg, polyoxyethylene nonylphenol ether 0.5kg, 18 pure 0.5kg, monobutyl ether acetate 1kg, dimethylbenzene complements to 100kg.
Embodiment 9:5% MTI-446 fenoxycarb film-spreading oil solution
Formula: MTI-446 0.5kg, fenoxycarb 4.5kg, dimethyl formamide 4kg, fatty alcohol-polyoxyethylene ether 2kg, polyoxyethylene nonylphenol ether 3kg, 18 pure 3kg, monobutyl ether acetate 2kg, trimethylbenzene complements to 100kg.
Embodiment 10:2% MTI-446 film-spreading oil solution
Formula: MTI-446 2kg, dimethyl formamide 4kg, polyoxyethylene nonylphenol ether 3kg, 18 pure 5kg, monobutyl ether acetate 3kg, methyl oleate complements to 100kg.
Embodiment 11:10% MTI-446 Benfuracard micro film-spreading oil solution
Formula: MTI-446 2kg, Benfuracard micro 8kg, dimethylbenzene 10kg, fatty alcohol-polyoxyethylene ether 3kg, 18 pure 5kg, methyl laurate 5kg, ethyl acetate complements to 100kg.
Embodiment 12:25% MTI-446 carbosulfan film-spreading oil solution
Formula: MTI-446 5kg, carbosulfan 20kg, isopropyl alcohol 20kg, fatty alcohol-polyoxyethylene ether 3kg, polyoxyethylene nonylphenol ether 7kg, 18 pure 5kg, monobutyl ether acetate 13kg, dimethylbenzene complements to 100kg.
Embodiment 13:20% MTI-446 Mobucin film-spreading oil solution
Formula: MTI-446 10kg, Mobucin 10kg, n-butanol 15kg, fatty alcohol-polyoxyethylene ether 12kg, polyoxyethylene nonylphenol ether 3kg, 18 pure 3kg, monobutyl ether acetate 3kg, dimethylbenzene complements to 100kg.
Embodiment 14:12% MTI-446 carbaryl film-spreading oil solution
Formula: MTI-446 7kg, carbaryl 5kg, dibutyl phthalate 10kg, fatty alcohol-polyoxyethylene ether 6kg, polyoxyethylene nonylphenol ether 3kg, methyl laurate 5kg, monobutyl ether acetate 3kg, ethyl acetate complements to 100kg.
Embodiment 15:18% MTI-446 fenoxycarb film-spreading oil solution
Formula: MTI-446 12kg, fenoxycarb 6kg, repefral 20kg, fatty alcohol-polyoxyethylene ether 8kg, polyoxyethylene nonylphenol ether 6kg, 18 pure 7kg, monobutyl ether acetate 5kg, dimethylbenzene complements to 100kg.
Embodiment 16:7% MTI-446 UC-51762 film-spreading oil solution
Formula: MTI-446 5kg, UC-51762 2kg, isopropyl alcohol 6kg, dimethyl formamide 4kg, polyoxyethylene nonylphenol ether 4kg, fatty alcohol-polyoxyethylene ether 3kg, 18 pure 6kg, monobutyl ether acetate 4kg, dimethylbenzene complements to 100kg.
Embodiment 17:35% MTI-446 Benfuracard micro film-spreading oil solution
Formula: MTI-446 5kg, Benfuracard micro 30kg, fatty alcohol-polyoxyethylene ether 6kg, castor oil ethylene oxide adduct and derivative 3kg thereof, propane diols phenylate 3kg, monobutyl ether acetate 5kg, dimethylbenzene complements to 100kg.
The film-spreading oil solution combination medicament that a kind of in the present invention prevents and treats rice hoppers is verified by following field control effectiveness test example the control efficiency of rice hoppers, but does not limit the scope of application of the present invention.
After 18 pairs of middle and later periods Fertilizer in Rice medicines of embodiment, the contrast of basal part of stem active ingredient dosage, the results are shown in Table 1
Wherein, spraying medicament is MTI-446, and mu is 10g with the active ingredient amount, and measuring numerical value is that the rice stem base portion is apart from the active ingredient dosage of water surface 3-10 centimeters.
Give birth to and survey embodiment 1: film-spreading oil solution is prevented and treated comparison of test results with conventional spraying to rice hoppers
Controlling object: rice hoppers
Place: Jiangxi Province's Ji'an City
Test period: on July 11st, 2011
Rice stem base portion pesticide active ingredient method for detecting dose:
3d, 7d, 14d after medicine, every residential quarter gathers the rice straw sample 1kg of dried up 3-10cm with five point samplings, it is cut into the 2cm segment, then with quartering, the field sample splitting is become the laboratory sample of actual needs, and-20 ℃ of preservations are to be measured.
[0041] accurately take rice straw sample 20.0g, with sample extract with purified treatment after, with liquid chromatography for measuring rice stem base portion pesticide active ingredient dosage.
Investigation method to the rice fulgorid preventive effect:
Investigate the insect population radix before medicine, after medicine, 3d, 7d, 14d investigation rice fulgorid control efficiency, adopt parallel great-jump-forward sampling, every residential quarter investigation 10 points, and 2 clumps every, record borer population alive calculates insect population decline rate and preventive effect.
Computing formula
In formula: PT-chemicals treatment district insect population decline rate;
CK-blank district insect population decline rate.
Table 2 film-spreading oil solution is prevented and treated the comparison of test results of rice hoppers with conventional the spraying
As can be seen from Table 2, film-spreading oil solution is better than conventional spray method to the preventive effect of rice fulgorid.The film-spreading oil solution dispenser after 14 days the preventive effect to rice fulgorid can reach more than 80%.
Give birth to and survey embodiment 2: film-spreading oil solution is prevented and treated comparison of test results with conventional spraying to rice hoppers
Controlling object: rice hoppers
Place: Huainan City, Anhui Province
Test period: on June 21st, 2012
Rice stem base portion pesticide active ingredient method for detecting dose:
3d, 7d, 14d after medicine, every residential quarter gathers the rice straw sample 1kg of dried up 3-10cm with five point samplings, it is cut into the 2cm segment, then with quartering, the field sample splitting is become the laboratory sample of actual needs, and-20 ℃ of preservations are to be measured.
[0048] accurately take rice straw sample 20.0g, with sample extract with purified treatment after, with liquid chromatography for measuring rice stem base portion pesticide active ingredient dosage.
Investigation method to the rice fulgorid preventive effect:
Investigate the insect population radix before medicine, after medicine, 3d, 7d, 14d investigation rice fulgorid control efficiency, adopt parallel great-jump-forward sampling, every residential quarter investigation 10 points, and 2 clumps every, record borer population alive calculates insect population decline rate and preventive effect.
Computing formula
Table 3 film-spreading oil solution is prevented and treated the comparison of test results of rice hoppers with conventional the spraying
As can be seen from Table 3, film-spreading oil solution is better than conventional spray method to the preventive effect of rice fulgorid.The film-spreading oil solution dispenser after 14 days the preventive effect to rice fulgorid can reach more than 80%.
Claims (10)
1. film-spreading oil solution combination medicament of preventing and treating rice hoppers comprises the component of following weight proportion:
MTI-446 and carbamates medicament account for 0.1%～60% of composition total weight.
2. film-spreading oil solution combination medicament as claimed in claim 1, wherein said carbamates medicament is any one of following insecticide: carbosulfan, Benfuracard micro, UC-51762, Mobucin, Bassa, carbaryl, fenoxycarb.
3. film-spreading oil solution combination medicament as claimed in claim 1 or 2, wherein film forming agent is selected one or more in Lauryl Alcohol ester, methyl laurate, 18 alcohol, propane diols phenylate and monobutyl ether acetate.
4. film-spreading oil solution combination medicament as described in claim 1-3 any one, wherein in film forming agent, methyl laurate is 0,3,4,5 or 8 weight portions; 18 alcohol are 0,0.5,2,3,4,5,6,7 or 8 weight portions; The propane diols phenylate is 0,2,3 or 5 weight portions; Monobutyl ether acetate is 0,1,2,3,4,5 or 13 weight portions.
5. film-spreading oil solution combination medicament as described in claim 1-4 any one, wherein said diffusant is selected one or more in polyoxyethylene nonylphenol ether, fatty alcohol-polyoxyethylene ether, fatty alcohol-polyoxyethylene ether yuban, castor oil polyoxyethylene ether, styryl phenol polyethenoxy ether.
6. film-spreading oil solution combination medicament as described in claim 1-5 any one, wherein the polyoxyethylene nonylphenol ether in diffusant is 0,0.5,1.5,2,3,4,5,6,7 or 10 weight portions; Fatty alcohol-polyoxyethylene ether is 0,0.5,3,6,8 or 12 weight portions; The fatty alcohol-polyoxyethylene ether yuban is 0,1.5 or 5 weight portions; Castor oil polyoxyethylene ether is 0 or 3 weight portions; The styryl phenol polyethenoxy ether is 0 or 5 weight portions.
7. film-spreading oil solution combination medicament as described in claim 1-6 any one, wherein said solvent is selected one or more in trimethylbenzene, dimethylbenzene, isopropyl alcohol, dimethyl formamide, n-formyl sarcolysine base pyrrolidones, n-butanol, fatty acid distribution of coconut oil methyl esters, methyl oleate, methylated vegetable oil, ethyl acetate, repefral, dibutyl phthalate, and solvent is preferably dimethyl formamide, isopropyl alcohol, trimethylbenzene, methyl oleate.
8. film-spreading oil solution combination medicament as described in claim 1-7 any one, wherein
9. as the preparation method of the described film-spreading oil solution combination medicament of claim 1-8 any one, comprising: first with solvent with the MTI-446 stirring and dissolving after, then add diffusant, add at last film forming agent, fully mix to transparent and get final product.
10. the application of film-spreading oil solution combination medicament as described in claim 1-8 any one in the control of the control of rice hoppers and paddy rice borer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310105576.XA CN103141505B (en) | 2013-03-29 | 2013-03-29 | Film diffusing oil agent combined reagent for preventing and treating rice planthopper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310105576.XA CN103141505B (en) | 2013-03-29 | 2013-03-29 | Film diffusing oil agent combined reagent for preventing and treating rice planthopper |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103141505A true CN103141505A (en) | 2013-06-12 |
| CN103141505B CN103141505B (en) | 2015-04-22 |
Family
ID=48540066
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310105576.XA Active CN103141505B (en) | 2013-03-29 | 2013-03-29 | Film diffusing oil agent combined reagent for preventing and treating rice planthopper |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103141505B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103355287A (en) * | 2013-07-30 | 2013-10-23 | 河北博嘉农业有限公司 | Spreading oil for controlling Lissorhoptrus oryzophilus Kuschel |
| CN106489928A (en) * | 2016-08-31 | 2017-03-15 | 江西天人生态股份有限公司 | A kind of exhibition film oil-suspending agent and its preparation method and application |
| CN109459538A (en) * | 2018-12-29 | 2019-03-12 | 华中农业大学 | The quickly kit and its method of screening prevention and treatment brown paddy plant hopper insecticide |
| CN109511670A (en) * | 2018-10-15 | 2019-03-26 | 深圳诺普信农化股份有限公司 | A kind of dinotefuran film-spreading oil solution and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0069269A2 (en) * | 1981-07-01 | 1983-01-12 | Bayer Ag | Ectoparasiticidal spray formulation |
| CN1889841A (en) * | 2003-12-12 | 2007-01-03 | 拜尔农作物科学股份公司 | Synergistic insecticidal mixtures |
| CN102415396A (en) * | 2010-09-28 | 2012-04-18 | 南京华洲药业有限公司 | Compound insecticidal composition containing dinotefuran and carbosulfan and purpose thereof |
| CN102415404A (en) * | 2010-09-28 | 2012-04-18 | 南京华洲药业有限公司 | Composite insecticidal composition containing dinotefuran and isoprocarb and purpose thereof |
| CN102415402A (en) * | 2010-09-28 | 2012-04-18 | 南京华洲药业有限公司 | Compound insecticidal composition containing dinotefuran and fenobucarb and application thereof |
| CN102657163A (en) * | 2012-04-26 | 2012-09-12 | 上海沪联生物药业（夏邑）有限公司 | Preparation of ethofenprox film-spreading oil solution and application of ethofenprox film-spreading oil solution on control of rice plant hopper |
-
2013
- 2013-03-29 CN CN201310105576.XA patent/CN103141505B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0069269A2 (en) * | 1981-07-01 | 1983-01-12 | Bayer Ag | Ectoparasiticidal spray formulation |
| CN1889841A (en) * | 2003-12-12 | 2007-01-03 | 拜尔农作物科学股份公司 | Synergistic insecticidal mixtures |
| CN102415396A (en) * | 2010-09-28 | 2012-04-18 | 南京华洲药业有限公司 | Compound insecticidal composition containing dinotefuran and carbosulfan and purpose thereof |
| CN102415404A (en) * | 2010-09-28 | 2012-04-18 | 南京华洲药业有限公司 | Composite insecticidal composition containing dinotefuran and isoprocarb and purpose thereof |
| CN102415402A (en) * | 2010-09-28 | 2012-04-18 | 南京华洲药业有限公司 | Compound insecticidal composition containing dinotefuran and fenobucarb and application thereof |
| CN102657163A (en) * | 2012-04-26 | 2012-09-12 | 上海沪联生物药业（夏邑）有限公司 | Preparation of ethofenprox film-spreading oil solution and application of ethofenprox film-spreading oil solution on control of rice plant hopper |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103355287A (en) * | 2013-07-30 | 2013-10-23 | 河北博嘉农业有限公司 | Spreading oil for controlling Lissorhoptrus oryzophilus Kuschel |
| CN106489928A (en) * | 2016-08-31 | 2017-03-15 | 江西天人生态股份有限公司 | A kind of exhibition film oil-suspending agent and its preparation method and application |
| CN109511670A (en) * | 2018-10-15 | 2019-03-26 | 深圳诺普信农化股份有限公司 | A kind of dinotefuran film-spreading oil solution and preparation method thereof |
| CN109511670B (en) * | 2018-10-15 | 2021-03-12 | 深圳诺普信农化股份有限公司 | Dinotefuran film-spreading oil agent and preparation method thereof |
| CN109459538A (en) * | 2018-12-29 | 2019-03-12 | 华中农业大学 | The quickly kit and its method of screening prevention and treatment brown paddy plant hopper insecticide |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103141505B (en) | 2015-04-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103155914B (en) | Film spreading oiling agent used for preventing and controlling plant diseases and insect pests at basal part of rice stem and application | |
| CN103689017B (en) | A kind of composite plant source pesticide and preparation method thereof | |
| CN102349507B (en) | Pymetrozine-containing ultralow volume liquid agent | |
| CN101589716B (en) | Compound insecticide of osthole and matrine and application thereof | |
| CN104430568A (en) | Botanical pesticide for preventing and treating wolfberry thrips | |
| CN103141505B (en) | Film diffusing oil agent combined reagent for preventing and treating rice planthopper | |
| CN103814964B (en) | A kind of emulsion for killing aphid and two spotted spider mite and preparation method thereof | |
| CN104488998A (en) | Synergistic compound hicide caphidicide containing sophocarpidine and preparation method of synergistic compound hicide caphidicide | |
| CN104522054A (en) | Biological source synergistic compound insecticide, preparation method and application thereof | |
| CN103891754B (en) | A kind of composition pesticide of clothianidin-containing and fluazinam and its production and use | |
| CN103355322B (en) | Compound biological insecticide and application thereof | |
| CN101642108A (en) | Pesticidal composition with synergistic effect | |
| CN108812707B (en) | Thrips killing plant essential oil composition, preparation and application thereof | |
| CN110959616A (en) | Plant source mixed pesticide and application thereof | |
| CN103918659B (en) | A kind of composition pesticide containing Tolfenpyrad and fluazinam and its production and use | |
| CN105532682A (en) | Botanical pesticide composition containing veratrine and preparing method thereof | |
| CN104255773A (en) | Pesticide composition containing dinotefuran and fluazinam | |
| CN102246800A (en) | Insecticidal composition containing indoxacarb and dinotefuran | |
| CN102246779A (en) | Pesticide composition containing spirotetramat and spinosad | |
| CN104222125A (en) | Pesticide composition containing lufenuron and fluazinam | |
| CN102228039A (en) | Pesticide composition containing spirotetramat and chlorfenapyr | |
| CN102273481B (en) | Dinotefuran-containing pesticidal composition | |
| CN103548833A (en) | Acaricidal composition containing pyriminostrobin and propargite | |
| CN103609307B (en) | Processing method for promoting accumulation and disease-resistance of lignans in schisandra chinensis | |
| CN113712049B (en) | Application of saponin extract in preventing and treating red imported fire ants |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |