CN104642357B - A kind of containing ethyl pleocidin and the Synergistic insecticidal compositions of dimethyl phenyl carbamate and application - Google Patents
A kind of containing ethyl pleocidin and the Synergistic insecticidal compositions of dimethyl phenyl carbamate and application Download PDFInfo
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- CN104642357B CN104642357B CN201310581764.XA CN201310581764A CN104642357B CN 104642357 B CN104642357 B CN 104642357B CN 201310581764 A CN201310581764 A CN 201310581764A CN 104642357 B CN104642357 B CN 104642357B
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- phenyl carbamate
- dimethyl phenyl
- ethyl pleocidin
- insecticidal compositions
- synergistic insecticidal
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/22—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom rings with more than six members
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/22—O-Aryl or S-Aryl esters thereof
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
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- General Health & Medical Sciences (AREA)
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Abstract
The invention discloses a kind of Synergistic insecticidal compositions containing ethyl pleocidin and dimethyl phenyl carbamate and application thereof, this Pesticidal combination is with ethyl pleocidin and dimethyl phenyl carbamate as principle active component, wherein, the weight ratio of ethyl pleocidin and dimethyl phenyl carbamate is 0.1～80:0.5～80.This Pesticidal combination has expanding prevention spectrum and the effect of potentiation, and drug cost can be reduced, cream, wettable powder, microemulsion, aqueous emulsion, suspending agent, water dispersible granules can be configured to, be used for preventing and treating the various pests such as Lepidoptera, Semiptera, Hymenoptera, coleoptera.
Description
Technical field
The invention belongs to pesticide field, be specifically related to a kind of with ethyl pleocidin and dimethyl phenyl carbamate the parasite killing group as principle active component
Compound and application thereof.
Background technology
Ethyl pleocidin (Spinetoram), structural formula is:
XDE-175-J is the one produced by Dow AgroSciences novel pleocidin insecticides, and receives first whole world and step on
Note, it can effectively control the important insect pest on fruit tree and nut, the especially a kind of thorny primary pest Herba Marsileae Quadrifoliae on fruit tree
The most stupid moth.It is mainly used in preventing and treating lepidopterous larvae, thrips and Liriomyza etc., to diamondback moth, beet armyworm, Liriomyza, Ji
The prevention effect that horse, Prodenia litura, bean-pod borer have had.
Dimethyl phenyl carbamate, chemical name: 3,4,5-front three prestige；N-methyl carbamic acid Mixed XYLENE ester, molecular formula: C11H15NO2, knot
Structure formula:
Dimethyl phenyl carbamate have tag, stomach toxicity, fumigation action.Leafhopper, plant hopper there are is specially good effect, knocks down speed soon, major part after dispenser
Insect falls in water, but the longevity of residure only 2～3d.The most effective to Lepidoptera and homoptera pest.
Insecticide variety containing single component often existing defects in pesticide Pest control: use is easily developed immunity to drugs continuously,
Insecticidal spectrum is narrow, it is impossible to providing comprehensively protection for crop, peasant's drug cost is high.Become by the various activity of two kinds or the coming year
The combination divided can overcome disadvantages mentioned above to a certain extent to a certain extent.There is two kinds or two or more work of potentiation
Property composition combination mixture, can improve preventive effect, reduce effective ingredient ground dosage, cost-effective, slow down pest resistance and send out
Raw also can expanding prevention spectrum, play that many worms are double to be controlled, reduce the use cost of peasant.
Summary of the invention
It is an object of the invention to provide a kind of containing ethyl pleocidin with the Synergistic insecticidal compositions of dimethyl phenyl carbamate, said composition can be used for
Prevent and treat various agricultural insect, such as preventing and treating vegetable diamondback moth, Pieris rapae, it is also possible to be used for preventing and treating cotton boll worm, Radix Betae night
Moth and Brown Planthopper etc., can reach a drug and prevent and treat the effect of dissimilar insect.
It is a further object of the present invention to provide the Synergistic insecticidal compositions containing ethyl pleocidin and dimethyl phenyl carbamate and prevent and treat resistance squama in preparation
Application in the insecticidal materials of one or more insects in wing mesh, Semiptera, Hymenoptera or coleoptera.
The present invention adopts the following technical scheme that
A kind of containing ethyl pleocidin with the Synergistic insecticidal compositions of dimethyl phenyl carbamate, it is with ethyl pleocidin and dimethyl phenyl carbamate for mainly having
Effect composition, wherein, the weight ratio of ethyl pleocidin and dimethyl phenyl carbamate is 0.1～80:0.5～80.It is preferably 1～9:1～12, enters
One step is preferably 1:1～10.
Existing containing ethyl pleocidin and the Synergistic insecticidal compositions of dimethyl phenyl carbamate, ethyl pleocidin and both dimethyl phenyl carbamate in the present invention
Weight percentage in this Synergistic insecticidal compositions is 2%～80%, preferably 8%～60%, most preferably 20%～40%.
The above-mentioned Synergistic insecticidal compositions containing ethyl pleocidin and dimethyl phenyl carbamate with ethyl pleocidin with dimethyl phenyl carbamate for mainly effectively becoming
(active component) and insecticides adjuvant, excipient is divided to be configured on pesticide any one dosage form allowed.The preferred powder of dosage form, can
WP, suspending agent, cream and water dispersion granule.Described auxiliary agent can use calcium dodecyl benzene sulfonate, alkyl phenol poly-
Oxygen vinyl Ether, polyoxyethylene polyoxy propylene block copolymer (such as agriculture breast 33#), NPE etc., excipient bag
Containing Ketohexamethylene, dimethylbenzene, solvent naphtha, water, antifreezing agent (such as propylene glycol), deionized water etc..Above auxiliary agent, excipient and
Agriculturally known adjuvant can be alone or and use for other.
The above-mentioned Synergistic insecticidal compositions containing ethyl pleocidin and dimethyl phenyl carbamate is at preparation preventing and treating Lepidoptera, Semiptera, Hymenoptera
Or the application in the insecticidal materials of one or more insects in coleoptera.Especially at preparation preventing and treating planthopper or the parasite killing of snout moths larva
Application effect in thing is notable.
The Synergistic insecticidal compositions antagonism lepidoptera pest of the present invention has significant preventive effect, particularly with cotton boll worm, sweet
Dish noctuid, diamondback moth etc. easily produce the various pests of resistance and have good preventive effect；And suppress insect to unitary agent
The Drug resistance of (ethyl pleocidin or dimethyl phenyl carbamate) produces and can prevent and treat Hemipteran pest such as Brown Planthopper etc. simultaneously.
The insecticidal materials prepared by the described Synergistic insecticidal compositions containing ethyl pleocidin and dimethyl phenyl carbamate is preventing and treating resistance squama wing
While mesh, Hymenoptera or coleopteran pest, Hemipteran pest can be prevented and treated again, especially to cotton boll worm, diamondback moth and Radix Betae
Noctuid has good preventive effect, reaches the effect that a medicine is controlled more.
The Pesticidal combination of the present invention compared with prior art, produces following beneficial effect: (1) compared with single dose, this combination
Thing insect has notable synergistic, hence it is evident that improve prevention effect；(2) one medicines are controlled more, and a dispenser can prevent and treat various pests simultaneously,
Reduce preventing and treating recruitment cost；(3) alternative high-toxic pesticide, and field dosage is greatly reduced, effectively reduce environmental pollution and
Pesticide residues；(4) have concurrently quick-acting and long-acting；(5) compared with ethyl pleocidin single dose, produce and use cost reduces；
(6) resistance of pesticide is strengthened by suppression insect.
Detailed description of the invention
Embodiments of the invention are the methods using indoor bioassay and field test to combine.First pass through indoor bioassay,
Co-toxicity coefficient after clear and definite two kinds of medicaments are compounding by a certain percentage；On this basis, then carry out field test.
Embodiment 1:
Weigh ethyl pleocidin, dimethyl phenyl carbamate uses conventional formulation method to be configured to principle active component weight percent by different proportion
Content is the ethyl pleocidin dimethyl phenyl carbamate cream of 30%.Concrete ratio is shown in Table 1.
Use feedstuff to add poison method and measure ethyl pleocidin and dimethyl phenyl carbamate and the compounding sample virulence to cotton boll worm thereof, often process
Being repeated 3 times, every concentration processes 30, uses LC50It is worth and presses Sun Yun abundant method calculating co-toxicity coefficient:
Table 1 ethyl pleocidin, dimethyl phenyl carbamate and compounding sample thereof are to the toxicity test of cotton boll worm and co-toxicity coefficient
In table, data show, after ethyl pleocidin and dimethyl phenyl carbamate mixture, cotton boll worm are had potentiation, listed by table
Four proportioning co-toxicity coefficients are both greater than 120, and therefore ethyl pleocidin and dimethyl phenyl carbamate mixture have significant synergies.
Embodiment 2:
Weigh ethyl pleocidin, dimethyl phenyl carbamate uses conventional formulation method to be configured to principle active component weight percent by different proportion
Content is the ethyl pleocidin dimethyl phenyl carbamate cream of 30%.Concrete ratio is shown in Table 2.
Use rice-stem dipping method to measure ethyl pleocidin and dimethyl phenyl carbamate and the compounding sample virulence to Brown Planthopper thereof, often process
It is repeated 3 times, uses LC50It is worth and presses Sun Yun abundant method calculating co-toxicity coefficient:
Table 2 ethyl pleocidin, dimethyl phenyl carbamate and compounding sample thereof are to the toxicity test of Brown Planthopper and co-toxicity coefficient
In table, data show, have potentiation after ethyl pleocidin and dimethyl phenyl carbamate mixture to Brown Planthopper, listed by table
Four proportioning co-toxicity coefficients are all much larger than 120, and therefore ethyl pleocidin and dimethyl phenyl carbamate mixture have significant synergies.
Embodiment 3:
Weigh 5g ethyl pleocidin, 20g dimethyl phenyl carbamate, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g,
Dimethylbenzene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, forms principle active component
Weight percentage is the ethyl pleocidin dimethyl phenyl carbamate cream of 25%.
Using 3 sample product of embodiment to carry out the field test of control in field cotton boll worm, comparison medicament is 60 grams per liter ethyls
Pleocidin SC and 50% dimethyl phenyl carbamate EC, concrete consumption is shown in Table 3, and every mu of water consumption is 30kg, looks into 3 days after medicine, 7 days,
14 days, 28 days results, result of the test is shown in Table 3:
Table 3 example 3 sample field test results to cotton boll worm
Example 3 has fabulous quick-acting to cotton boll worm as can be seen from Table 3, and the lasting period is long, at field table
Now good, it is the outstanding medicament of preventing and treating cotton boll worm.
Embodiment 4:
Using 3 sample product of embodiment to carry out the field test of control in field Brown Planthopper, comparison medicament is 60 grams per liter ethyls
Pleocidin SC and 50% dimethyl phenyl carbamate EC, concrete consumption is shown in Table 3, and every mu of use water is 30kg, looks into 3 days after medicine, 7 days, and 14
My god, 28 days results, result of the test is shown in Table 4:
Table 4 example 3 sample field test results to Brown Planthopper
Example 3 sample has fabulous effect to Brown Planthopper as can be seen from Table 4, and the lasting period is long, at field table
Now good, it is the outstanding medicament preventing Brown Planthopper.
Measure through indoor synergism test and show: with dimethyl phenyl carbamate built agent, cotton boll worm and Rice Brown are flown by ethyl pleocidin
Louse all has significant synergistic insecticidal action；Field control effectiveness test also indicate that equally all of built agent of the present invention to cotton boll worm and
The insecticidal effect of Brown Planthopper is all remarkably higher than the effect of corresponding single dose pesticide.
Embodiment 5:
Weigh 0.2g ethyl pleocidin, 20g dimethyl phenyl carbamate, lignin 10g, Negel 2g, add to Kaolin
100g, mixes above raw material in super micron mill, forms the ethyl that principle active component weight percentage is 20.2% many
Bacteriocidin dimethyl phenyl carbamate wettable powder.
Embodiment 6:
Weigh 78g ethyl pleocidin, 0.5g dimethyl phenyl carbamate, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether
6g, dimethylbenzene add to 100g, and the method that above raw material is prepared cream routinely puts into mixing in mixing kettle, is formed and mainly has
Effect Ingredients Weight percentage composition is the ethyl pleocidin dimethyl phenyl carbamate cream of 78.5%.
Embodiment 7:
Weigh 2g ethyl pleocidin, 10g dimethyl phenyl carbamate, nonyl phenol ether phosphate 5g, alkylphenol polyoxyethylene 4g, positive fourth
The dimethylbenzene of alcohol 3g, 30g and the ketopyrrolidine of 20g, the xanthan gum of 0.1g, remaining supplies 100g, n-butyl alcohol and water with water
Dissolving and form aqueous phase, remaining component mix and blend forms oil phase, slowly aqueous phase is added in oil phase under cutter effect, and
Continue to shear 10～30 minutes, form the ethyl pleocidin dimethyl phenyl carbamate water and milk that principle active component weight percentage is 12%
Agent.
Embodiment 8:
Weigh 10g ethyl pleocidin, 30g dimethyl phenyl carbamate, calcium dodecyl benzene sulfonate 5g, alkylphenol polyoxyethylene 4g,
The solvent xylene of 30g and the ketopyrrolidine of 15g, remaining complements to 100g, former medicine, solvent, emulsifying agent, cosolvent with water
Mix and blend forms homogeneous phase transparent solution, is then slowly added into water stirring and forms homogeneous phase transparent solution, forms principle active component weight
Amount percentage composition is the ethyl pleocidin dimethyl phenyl carbamate microemulsion of 40%.
Embodiment 9:
Weigh 4g ethyl pleocidin, 4g dimethyl phenyl carbamate, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 3g,
Dimethylbenzene is to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, forms principle active component
Weight percentage is the ethyl pleocidin dimethyl phenyl carbamate cream of 8%.
Embodiment 10:
Weigh 3g ethyl pleocidin, 30g dimethyl phenyl carbamate, sodium lignin sulfonate 3g, agriculture breast 33#4g, xanthan gum 0.2g, second
Glycol 10g, silica ethane 0.1g, aluminium-magnesium silicate 0.5g, supply 100g with water, formed main effective under the effect of sand mill
Ingredients Weight percentage composition is the ethyl pleocidin dimethyl phenyl carbamate suspending agent of 33%.
Embodiment 11:
Weigh 5g ethyl pleocidin, 60g dimethyl phenyl carbamate, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether
15g, dimethylbenzene put into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, are formed main effective
Ingredients Weight percentage composition is the ethyl pleocidin dimethyl phenyl carbamate cream of 65%.
Embodiment 12:
Weigh 45g ethyl pleocidin, 5g dimethyl phenyl carbamate, sodium lignin sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate
5g, polyvinyl alcohol 5g, Borax 2g, Kaolin 28g, formed main effective by above raw material by the method for water dispersion granule
Ingredients Weight percentage composition is the ethyl pleocidin dimethyl phenyl carbamate water dispersible granules of 50%.
Embodiment 13:
Weigh 25g ethyl pleocidin, 25g dimethyl phenyl carbamate, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether
15g, dimethylbenzene put into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, are formed main effective
Ingredients Weight percentage composition is the ethyl pleocidin dimethyl phenyl carbamate cream of 50%.
Claims (7)
1. one kind contains ethyl pleocidin and the Synergistic insecticidal compositions of dimethyl phenyl carbamate, it is characterised in that this Synergistic insecticidal compositions is with ethyl pleocidin and dimethyl phenyl carbamate as principle active component, wherein, the weight ratio of ethyl pleocidin and dimethyl phenyl carbamate is 1:1 ~ 10, and described dimethyl phenyl carbamate is 3,4,5-front three prestige.
The most according to claim 1 containing ethyl pleocidin with the Synergistic insecticidal compositions of dimethyl phenyl carbamate, it is characterised in that described ethyl pleocidin and both dimethyl phenyl carbamate weight percentage in this Synergistic insecticidal compositions are 2% ~ 80%.
The most according to claim 2 containing ethyl pleocidin with the Synergistic insecticidal compositions of dimethyl phenyl carbamate, it is characterised in that described ethyl pleocidin and both dimethyl phenyl carbamate weight percentage in this Synergistic insecticidal compositions are 8% ~ 60%.
The most according to claim 1 containing ethyl pleocidin with the Synergistic insecticidal compositions of dimethyl phenyl carbamate, it is characterised in that this Synergistic insecticidal compositions is with ethyl pleocidin and dimethyl phenyl carbamate as principle active component and insecticides adjuvant, excipient are configured on pesticide any one dosage form of allowing.
The most according to claim 4 containing ethyl pleocidin with the Synergistic insecticidal compositions of dimethyl phenyl carbamate, it is characterised in that described dosage form is cream, wettable powder, microemulsion, aqueous emulsion, suspending agent or water dispersion granule.
6. the application in the insecticidal materials of one or more insects in preparation preventing and treating Lepidoptera, Semiptera, Hymenoptera or coleoptera of the Synergistic insecticidal compositions containing ethyl pleocidin and dimethyl phenyl carbamate described in claim 1.
7. the application in the insecticidal materials of preparation preventing and treating cotton boll worm, beet armyworm and Brown Planthopper of the Synergistic insecticidal compositions containing ethyl pleocidin and dimethyl phenyl carbamate described in claim 1.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310581764.XA CN104642357B (en) | 2013-11-19 | 2013-11-19 | A kind of containing ethyl pleocidin and the Synergistic insecticidal compositions of dimethyl phenyl carbamate and application |
| PCT/CN2014/076340 WO2015074381A1 (en) | 2013-11-19 | 2014-04-28 | Synergistic insecticidal composition containing spinetoram and dimethacarb and application thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310581764.XA CN104642357B (en) | 2013-11-19 | 2013-11-19 | A kind of containing ethyl pleocidin and the Synergistic insecticidal compositions of dimethyl phenyl carbamate and application |
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| Publication Number | Publication Date |
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| CN104642357A CN104642357A (en) | 2015-05-27 |
| CN104642357B true CN104642357B (en) | 2016-09-14 |
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| WO (1) | WO2015074381A1 (en) |
Citations (5)
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|---|---|---|---|---|
| CN101253870A (en) * | 2008-03-28 | 2008-09-03 | 中国农业大学 | Agricultural chemical composition containing multiple bactericidins and carbamate inecticides |
| CN102027958A (en) * | 2011-01-06 | 2011-04-27 | 北京燕化永乐农药有限公司 | Insecticidal composition consisting of spinosad and fenobucarb |
| CN102067863A (en) * | 2011-01-06 | 2011-05-25 | 北京燕化永乐农药有限公司 | Pesticide composition for preventing underground insects in peanut field |
| CN102986707A (en) * | 2012-12-18 | 2013-03-27 | 北京燕化永乐农药有限公司 | Complex insecticide |
| CN103098816A (en) * | 2013-01-27 | 2013-05-15 | 成都科利隆生化有限公司 | Indoxacarb and spinetoram insecticidal composition |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103053526A (en) * | 2011-10-20 | 2013-04-24 | 南京华洲药业有限公司 | Synergistic insecticidal composition containing spinosad and flonicamid, and application thereof |
| CN102934638A (en) * | 2012-11-21 | 2013-02-20 | 上海沪联生物药业（夏邑）股份有限公司 | Pesticide composition containing ethyl spinosad and clothianidin and application thereof |
-
2013
- 2013-11-19 CN CN201310581764.XA patent/CN104642357B/en active Active
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2014
- 2014-04-28 WO PCT/CN2014/076340 patent/WO2015074381A1/en active Application Filing
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101253870A (en) * | 2008-03-28 | 2008-09-03 | 中国农业大学 | Agricultural chemical composition containing multiple bactericidins and carbamate inecticides |
| CN102027958A (en) * | 2011-01-06 | 2011-04-27 | 北京燕化永乐农药有限公司 | Insecticidal composition consisting of spinosad and fenobucarb |
| CN102067863A (en) * | 2011-01-06 | 2011-05-25 | 北京燕化永乐农药有限公司 | Pesticide composition for preventing underground insects in peanut field |
| CN102986707A (en) * | 2012-12-18 | 2013-03-27 | 北京燕化永乐农药有限公司 | Complex insecticide |
| CN103098816A (en) * | 2013-01-27 | 2013-05-15 | 成都科利隆生化有限公司 | Indoxacarb and spinetoram insecticidal composition |
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| WO2015074381A1 (en) | 2015-05-28 |
| CN104642357A (en) | 2015-05-27 |
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