CN107996603A - A kind of Synergistic insecticidal compositions containing Flupyrazofos-containpesticide and Acetamiprid - Google Patents

A kind of Synergistic insecticidal compositions containing Flupyrazofos-containpesticide and Acetamiprid Download PDF

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Publication number
CN107996603A
CN107996603A CN201711440513.4A CN201711440513A CN107996603A CN 107996603 A CN107996603 A CN 107996603A CN 201711440513 A CN201711440513 A CN 201711440513A CN 107996603 A CN107996603 A CN 107996603A
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CN
China
Prior art keywords
flupyrazofos
containpesticide
acetamiprid
insecticidal compositions
synergistic insecticidal
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Withdrawn
Application number
CN201711440513.4A
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Chinese (zh)
Inventor
葛家成
杨志鹏
李建国
司国栋
孙海燕
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Hailir Pesticides and Chemicals Group Co Ltd
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Hailir Pesticides and Chemicals Group Co Ltd
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Priority to CN201711440513.4A priority Critical patent/CN107996603A/en
Publication of CN107996603A publication Critical patent/CN107996603A/en
Withdrawn legal-status Critical Current

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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/10Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
    • A01N57/16Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing heterocyclic radicals
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/40Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides

Abstract

The invention discloses a kind of Synergistic insecticidal compositions containing Flupyrazofos-containpesticide and Acetamiprid and application thereof, the Pesticidal combination using Flupyrazofos-containpesticide and Acetamiprid as principle active component, wherein, the weight ratio of Flupyrazofos-containpesticide and Acetamiprid is 1~60:1~60.The Pesticidal combination has the function that to expand prevention spectrum and synergy, and drug cost can be reduced, missible oil, wettable powder, microemulsion, aqueous emulsion, suspending agent, water dispersible granules can be configured to, for preventing the various pests such as Lepidoptera, Semiptera, Hymenoptera, coleoptera.

Description

A kind of Synergistic insecticidal compositions containing Flupyrazofos-containpesticide and Acetamiprid
Technical field
The invention belongs to pesticide field, and in particular to a kind of desinsection using Flupyrazofos-containpesticide and Acetamiprid as principle active component Composition and its application.
Background technology
Flupyrazofos-containpesticide English name flupyrazofos, is found by Korean Chemistry Inst (KRICT), and by Sungbo Chemicals Co.Ltd dominate the novel pyrazole organophosphorus insecticides of exploitation, belong to acetylcholinesteraseinhibitors inhibitors, mainly It is as follows for the prevention of the lepidoptera pests such as the crops such as Chinese cabbage prevention black peach aphid, brown paddy plant hopper, diamondback moth, structural formula:
Acetamiprid, is a kind of novel pesticide, mainly acts on the acetylcholine esterase of pest, destroys the movement god of pest Through system, make pest dead.As a kind of new insecticide, in addition to tagging with stomach poison function, also have stronger Osmosis, and show quick-acting insecticidal powers, the lasting period, length was up to 20 days or so.This product kills natural enemy people and animals' low toxicity Overstrain is small, relatively low to fish toxicity, small on honeybee influence, suitable for the Hemipteran pest in the various crops such as prevention fruit tree, vegetables; Make soil treatment with granule, subterranean pest-insect can be prevented.Acetamiprid have dosage it is few, it is quick-acting it is good, it is active it is high, the lasting period is long, kills The advantages that worm spectrum is wide, since its mechanism of action is different from common insecticides, so to organophosphor, carbamates and intending deinsectization The pest that chrysanthemum esters produce resistance has special effect.
Insecticide variety containing single component often existing defects in pesticide control of insect:Continuous use easily produces anti- Pharmacological property, insecticidal spectrum are narrow, it is impossible to provide comprehensive protection, peasant's drug cost height etc. for crop.
The content of the invention
The object of the present invention is to provide a kind of Synergistic insecticidal compositions containing Flupyrazofos-containpesticide and Acetamiprid, said composition can use In prevention various agricultural pest, such as vegetables diamondback moth is being prevented, cabbage caterpillar, can be also used for prevention cotton boll worm, beet Noctuid and Brown Planthopper etc., can reach the effect of a drug prevention different type pest.
It is anti-in preparation prevention it is a further object of the present invention to provide the Synergistic insecticidal compositions containing Flupyrazofos-containpesticide and Acetamiprid Property Lepidoptera, Semiptera, Hymenoptera or coleoptera in one or more pests insecticidal materials in application.The present invention is using such as Lower technical solution:
A kind of Synergistic insecticidal compositions containing Flupyrazofos-containpesticide and Acetamiprid, it is using Flupyrazofos-containpesticide and Acetamiprid to be main effective Component, wherein, the weight ratio of Flupyrazofos-containpesticide and Acetamiprid is 1~60:1~60.It is preferred that Flupyrazofos-containpesticide and the weight ratio of Acetamiprid For 1~40:1~40, the weight ratio of further preferred Flupyrazofos-containpesticide and Acetamiprid is 1~30:1~30.In some preferable skills In art scheme:Flupyrazofos-containpesticide and Acetamiprid can be 1:30、1:29、 1:28、1:27、1:26、1:25、1:24、1:24、1:22、 1:21、1:20、1:19、1:18、1:17、 1:16、1:15、1:14、1:13、1:12、1:11、1:10、1:9、1:8、1:7、1:6、 1:5、1:4、 1:3、1:2、1:1、2:1、3:1、4:1、5:1、6:1、7:1、8:1、9:1、10:1、11:1、12:1、 13:1、14: 1、15:1、16:1、17:1、18:1、19:1、20:1、21:1、22:1、23:1、24:1、 25:1、26:1、27:1、28:1、29: 1、30:1、2:3、3:2、2:5、5:2、3:4、4:3、5:2、 2:5、5:3、3:5、5:4、4:Selected in 5 these ratios.
In the Synergistic insecticidal compositions containing Flupyrazofos-containpesticide and Acetamiprid of the present invention, Flupyrazofos-containpesticide is with both Acetamiprids at this Weight percentage in Synergistic insecticidal compositions is 2%~80%, is preferably 8%~60%, optimal is 20%~40%.
The above-mentioned Synergistic insecticidal compositions containing Flupyrazofos-containpesticide and Acetamiprid using Flupyrazofos-containpesticide and Acetamiprid for mainly effectively into Point (active ingredient) and insecticides adjuvant, excipients are configured to any one formulation allowed on pesticide.It is the preferred pulvis of formulation, wettable Property pulvis, suspending agent, missible oil and water dispersion granule.
The auxiliary agent can use calcium dodecyl benzene sulfonate, alkylphenol polyoxyethylene ether, polyoxyethylene polyoxy propylene embedding Section compound (such as agriculture breast 33#), nonylphenol polyoxyethylene ether, excipient include cyclohexanone, dimethylbenzene, solvent naphtha, water, antifreeze Agent (such as propane diols), deionized water.Above auxiliary agent, excipient and other agriculturally known auxiliary materials can be alone or be used in combination.
The above-mentioned Synergistic insecticidal compositions containing Flupyrazofos-containpesticide and Acetamiprid are preparing prevention Lepidoptera, Semiptera, film wing Application in mesh or coleoptera in the insecticidal materials of one or more pests.Especially preparing prevention planthopper or snout moth's larva kills Application effect in worm medicine is notable.
The Synergistic insecticidal compositions antagonism lepidoptera pest of the present invention has significant preventive effect, particularly with cotton boll The various pests that worm, beet armyworm, diamondback moth etc. easily produce resistance have good preventive effect;And suppress pest to single The resistance to the action of a drug of preparation (Flupyrazofos-containpesticide or Acetamiprid) produces and can prevent Hemipteran pest such as Brown Planthopper etc. at the same time.
By described resistance squama is being prevented containing insecticidal materials prepared by the Synergistic insecticidal compositions of Flupyrazofos-containpesticide and Acetamiprid While wing mesh, Hymenoptera or coleopteran pest, and Hemipteran pest can be prevented, especially to cotton boll worm, diamondback moth and sweet tea Dish noctuid has good preventive effect, reaches the effect that a medicine is controlled more.
The Pesticidal combination of the present invention compared with prior art, produces following beneficial effect:(1) compared with single dose, the group Compound pest has notable synergistic, hence it is evident that improves prevention effect;(2) one medicines are controlled more, and a dispenser can prevent various pests at the same time, Reduce prevention recruitment cost;(3) alternative high-toxic pesticide, and field dosage is greatly reduced, effectively reduce environmental pollution and Pesticide residue;(4) have concurrently quick-acting and long-acting;(5) compared with Flupyrazofos-containpesticide single dose, production and application cost reduces;(6) evil is suppressed Worm strengthens the resistance of pesticide.
Embodiment
The embodiment of the present invention is the method being combined using indoor bioassay and field trial.First pass through indoor biological Measure, clear and definite two kinds of medicaments compound by a certain percentage after co-toxicity coefficient;On this basis, then field trial is carried out.
Embodiment 1:
Weigh 80g Flupyrazofos-containpesticides, 2g Acetamiprids, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, two Above raw material is routinely prepared and is mixed in the method input mixing kettle of missible oil, form principle active component weight to 100g by toluene Measure the Flupyrazofos-containpesticide acetamiprid EC that percentage composition is 82%.
Embodiment 2:
Weigh 2g Flupyrazofos-containpesticides, 80g Acetamiprids, lignin 10g, Negel 2g, with kaolin add to 100g, will Above raw material mixes in micronizer, forms the Flupyrazofos-containpesticide pyridine that principle active component weight percentage is 82% Worm amidine wettable powder.
Embodiment 3:
Weigh 60g Flupyrazofos-containpesticides, 2g Acetamiprids, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 6g, two Toluene adds to 100g, and above raw material is routinely prepared and is mixed in the method input mixing kettle of missible oil, forms principle active component Weight percentage is 62% Flupyrazofos-containpesticide acetamiprid EC.
Embodiment 4:
Weigh 2g Flupyrazofos-containpesticides, 60g Acetamiprids, nonyl phenol phosphate 5g, alkylphenol polyoxyethylene ether 4g, n-butanol 3g, The dimethylbenzene of 10g and the pyrrolidones of 10g, the xanthans of 0.1g, remaining supplies 100g with water, and n-butanol and water dissolve to form water Phase, remaining component are mixed to form oil phase, slowly water are added in oil phase under cutter effect, and continue shearing 10 ~30 minutes, form the Flupyrazofos-containpesticide Acetamiprid aqueous emulsion that principle active component weight percentage is 62%.
Embodiment 5:
Weigh 40g Flupyrazofos-containpesticides, 2g Acetamiprids, calcium dodecyl benzene sulfonate 5g, alkylphenol polyoxyethylene ether 4g, 30g's The pyrrolidones of solvent xylene and 15g, remaining complements to 100g with water, and active compound, solvent, emulsifying agent, cosolvent are mixed Homogeneous phase transparent solution is formed, water is then slowly added into and stirring forms clear solution, is that principle active component weight percent contains Measure the Flupyrazofos-containpesticide acetamiprid micro emulsion agent for 42%.
Embodiment 6:
Weigh 2g Flupyrazofos-containpesticides, 40g Acetamiprids, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 3g, two Toluene is to 100g.Above raw material is routinely prepared and is mixed in the method input mixing kettle of missible oil, forms principle active component weight Measure the Flupyrazofos-containpesticide acetamiprid EC that percentage composition is 42%.
Embodiment 7:
Weigh 20g Flupyrazofos-containpesticides, 2g Acetamiprids, sodium lignin sulfonate 3g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g, xanthans 0.2g, ethylene glycol 10g, silica ethane 0.1g, aluminium-magnesium silicate 0.5g, 100g is supplied with water, in the effect of sand mill It is lower to form the Flupyrazofos-containpesticide acetamiprid suspending agent that principle active component weight percentage is 22%.
Embodiment 8:
Weigh 2g Flupyrazofos-containpesticides, 20g Acetamiprids, alkylphenol polyoxyethylene ether 14g, phenethyl phenol polyethenoxy ether 15g, two Above raw material is routinely prepared and is mixed in the method input mixing kettle of missible oil, form principle active component weight to 100g by toluene Measure the Flupyrazofos-containpesticide acetamiprid EC that percentage composition is 22%.
Embodiment 9:
2g Flupyrazofos-containpesticides, 10g Acetamiprids, sodium lignin sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g are weighed, is gathered Vinyl alcohol 5g, borax 2g, kaolin 28g, principle active component weight is formed by above raw material by the method for water dispersion granule Percentage composition is 12% Flupyrazofos-containpesticide acetamiprid water dispersible granules.
Embodiment 10:
Weigh 5g Flupyrazofos-containpesticides, 10g Acetamiprids, alkylphenol polyoxyethylene ether 14g, phenethyl phenol polyethenoxy ether 15g, two Above raw material is routinely prepared and is mixed in the method input mixing kettle of missible oil, form principle active component weight to 100g by toluene Measure the Flupyrazofos-containpesticide acetamiprid EC that percentage composition is 15%.
Embodiment 11:
Weigh 10g Flupyrazofos-containpesticides, 10g Acetamiprids, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, two Above raw material is routinely prepared and is mixed in the method input mixing kettle of missible oil, form principle active component weight to 100g by toluene Measure the Flupyrazofos-containpesticide acetamiprid EC that percentage composition is 20%.
Drug effect checking test
1st, indoor virulence determination of activity
Weigh Flupyrazofos-containpesticide, Acetamiprid is configured to principle active component weight hundred using conventional formulation method by different proportion Divide the Flupyrazofos-containpesticide acetamiprid EC that content is 30%.Specific ratio is shown in Table 1.
Using feed plus malicious method measure Flupyrazofos-containpesticide and Acetamiprid and its compounding sample to the virulence of cotton boll worm, often locate Reason is repeated 3 times, and 30 are handled per concentration, and co-toxicity coefficient is calculated by the abundant methods of Sun Yun with LC50 values:
The toxicity test and co-toxicity coefficient of 1 Flupyrazofos-containpesticide of table, Acetamiprid and its compounding sample to cotton boll worm
There is synergistic effect after as shown by data in table, Flupyrazofos-containpesticide and Acetamiprid mixture to cotton boll worm, it is listed in table Proportioning co-toxicity coefficient be both greater than 120, therefore Flupyrazofos-containpesticide and Acetamiprid mixture have significant synergies.
Weigh Flupyrazofos-containpesticide, Acetamiprid is configured to principle active component weight hundred using conventional formulation method by different proportion Divide the Flupyrazofos-containpesticide acetamiprid EC that content is 30%.Specific ratio is shown in Table 2.
Flupyrazofos-containpesticide and Acetamiprid and its compounding sample are measured to the virulence of Brown Planthopper using rice-stem dipping method, often located Reason is repeated 3 times, and co-toxicity coefficient is calculated by the abundant methods of Sun Yun with LC50 values:
The toxicity test and co-toxicity coefficient of 2 Flupyrazofos-containpesticide of table, Acetamiprid and its compounding sample to Brown Planthopper
There is synergistic effect after as shown by data in table, Flupyrazofos-containpesticide and Acetamiprid mixture to Brown Planthopper, it is listed in table Proportioning co-toxicity coefficient be all much larger than 120, therefore Flupyrazofos-containpesticide and Acetamiprid mixture have significant synergies.
2nd, field control effectiveness test
Match somebody with somebody the field trial of sample progress control in field cotton boll worm using embodiment, comparison medicament is 5% pyrrole fluorine Sulphur phosphorus EC and 10% Acetamiprid WDG, specific dosage are shown in Table 3, and water consumption is 30kg per acre, look into 3 days after medicine, 7 days, 14 days as a result, Result of the test is shown in Table 3:
Field test results of 3 sample of table to cotton boll worm
Example has cotton boll worm fabulous quick-acting as can be seen from Table 3, and the lasting period is long, in field table It is now good, it is the outstanding medicament for preventing cotton boll worm.
Show through indoor synergism test measure:Cotton boll worm and Rice Brown are flown with Acetamiprid built agent by Flupyrazofos-containpesticide Lice has significant synergistic insecticidal action;Field control effectiveness test equally also indicates that all built agents of the present invention kill cotton boll worm Worm effect is all remarkably higher than the effect of corresponding single dose pesticide.

Claims (9)

  1. A kind of 1. Synergistic insecticidal compositions containing Flupyrazofos-containpesticide and Acetamiprid, it is characterized in that the Synergistic insecticidal compositions are with pyrrole fluorine sulphur Phosphorus and Acetamiprid are principle active component, wherein, the weight ratio of Flupyrazofos-containpesticide and Acetamiprid is 1~60:1~60.
  2. 2. the Synergistic insecticidal compositions according to claim 1 containing Flupyrazofos-containpesticide and Acetamiprid, it is characterized in that the desinsection group The effective ingredient Flupyrazofos-containpesticide of compound and the weight ratio of Acetamiprid are 1~40:1~40.
  3. 3. the Synergistic insecticidal compositions according to claim 2 containing Flupyrazofos-containpesticide and Acetamiprid, it is characterized in that the desinsection group The effective ingredient Flupyrazofos-containpesticide of compound and the weight ratio of Acetamiprid are 1~30:1~30.
  4. 4. the Synergistic insecticidal compositions according to claim 1 containing Flupyrazofos-containpesticide and Acetamiprid, it is characterized in that Flupyrazofos-containpesticide It is 2%~80% with weight percentage of both Acetamiprids in the Synergistic insecticidal compositions.
  5. 5. the Synergistic insecticidal compositions according to claim 4 containing Flupyrazofos-containpesticide and Acetamiprid, it is characterized in that Flupyrazofos-containpesticide It is 8%~60% with weight percentage of both Acetamiprids in the Synergistic insecticidal compositions.
  6. 6. the Synergistic insecticidal compositions according to claim 1 containing Flupyrazofos-containpesticide and Acetamiprid, it is characterized in that the synergy is killed Any one agent allowed on pesticide is made as principle active component and insecticides adjuvant using Flupyrazofos-containpesticide and Acetamiprid in worm composition Type.
  7. 7. the Synergistic insecticidal compositions according to claim 6 containing Flupyrazofos-containpesticide and Acetamiprid, it is characterized in that the formulation It is missible oil, wettable powder, microemulsion, aqueous emulsion, suspending agent or water dispersion granule.
  8. 8. the Synergistic insecticidal compositions containing Flupyrazofos-containpesticide and Acetamiprid described in claim 1 are preparing prevention Lepidoptera, half wing Application in mesh, Hymenoptera or coleoptera in the insecticidal materials of one or more pests.
  9. 9. application according to claim 8, it is characterized in that the Synergistic insecticidal compositions containing Flupyrazofos-containpesticide and Acetamiprid are being made Application in the insecticidal materials of standby prevention cotton boll worm, beet armyworm and Brown Planthopper.
CN201711440513.4A 2017-12-27 2017-12-27 A kind of Synergistic insecticidal compositions containing Flupyrazofos-containpesticide and Acetamiprid Withdrawn CN107996603A (en)

Priority Applications (1)

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Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711440513.4A CN107996603A (en) 2017-12-27 2017-12-27 A kind of Synergistic insecticidal compositions containing Flupyrazofos-containpesticide and Acetamiprid

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Application publication date: 20180508