CN106070290A - A kind of containing sulfoxaflor and the Synergistic insecticidal compositions of methoxyfenozide and application - Google Patents
A kind of containing sulfoxaflor and the Synergistic insecticidal compositions of methoxyfenozide and application Download PDFInfo
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- CN106070290A CN106070290A CN201610454188.6A CN201610454188A CN106070290A CN 106070290 A CN106070290 A CN 106070290A CN 201610454188 A CN201610454188 A CN 201610454188A CN 106070290 A CN106070290 A CN 106070290A
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- Prior art keywords
- methoxyfenozide
- sulfoxaflor
- insecticidal compositions
- synergistic insecticidal
- synergistic
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
- A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
- A01N37/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system having at least one carboxylic group or a thio analogue, or a derivative thereof, and one oxygen or sulfur atom attached to the same aromatic ring system
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
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- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
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- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of Synergistic insecticidal compositions containing sulfoxaflor and methoxyfenozide and application thereof, this Pesticidal combination is with sulfoxaflor and methoxyfenozide as principle active component, wherein, the weight ratio of sulfoxaflor and methoxyfenozide is 1～60:1～60.This Pesticidal combination has expanding prevention spectrum and the effect of potentiation, and drug cost can be reduced, cream, wettable powder, microemulsion, aqueous emulsion, suspending agent, water dispersible granules can be configured to, be used for preventing and treating the various pests such as Lepidoptera, Semiptera, Hymenoptera, coleoptera.
Description
Technical field
The invention belongs to pesticide field, be specifically related to a kind of with sulfoxaflor and methoxyfenozide as principle active component
Pesticidal combination and application.
Background technology
Sulfoxaflor (Sulfoxaflor), chemical name: [1-6-(trifluoromethyl) pyridin-3-yl] ethyl]-λ 4-mercapto
Base cyanamide；Molecular formula: C10H10F3N3OS；Molecular weight: 277.27；CAS:[946578-00-3].
Sulfoxaflor is the sulfimide insecticide of Tao Shi agricultural sciences exploitation, and sulfimide acts on the nerve of insecticide
System, i.e. acts on binding site unique in cholinoceptor and plays insecticidal function.Can enter plant through leaf, stem, root absorption
In object, sulfoxaflor is applicable to prevent and treat Cotton Gossypii fleahopper, aphid, aleyrodid, plant hopper and coccid etc.；Efficiently, quick and residual
The effect phase is long, can effectively prevent and treat nicotinoids, chrysanthemum esters, and organophosphate and carbamate pesticide produces the suction juice class evil of resistance
Worm.
Methoxyfenozide, chemical name: the N-tert-butyl group-N'-(3-methoxyl group-2-methyl benzoyl)-3,5-dimethyl
Benzoyl hydrazine.Structural formula is:
Methoxyfenozide is that the normal growth of the one of insect growth regulator, IGR, mainly interference insect is grown, though elder brother
Larval moult skin and dead, and can suppress to ingest.This product is strong to controlling object selectivity, is mainly used in the preventing and treating of lepidoptera pest.
Insecticide variety containing single component often existing defects in pesticide Pest control: use continuously easily produce anti-
The property of medicine, insecticidal spectrum is narrow, it is impossible to providing comprehensively protection for crop, peasant's drug cost is high.
Summary of the invention
It is an object of the invention to provide a kind of containing sulfoxaflor with the Synergistic insecticidal compositions of methoxyfenozide, this combination
Thing can be used for preventing and treating various agricultural insect, such as preventing and treating vegetable diamondback moth, Pieris rapae, it is also possible to be used for preventing and treating cotton boll
Worm, beet armyworm and Brown Planthopper etc., can reach a drug and prevent and treat the effect of dissimilar insect.
It is a further object of the present invention to provide the Synergistic insecticidal compositions containing sulfoxaflor and methoxyfenozide in preparation
Prevent and treat the application in the insecticidal materials of one or more insects in resistance Lepidoptera, Semiptera, Hymenoptera or coleoptera.
The present invention adopts the following technical scheme that
A kind of containing sulfoxaflor with the Synergistic insecticidal compositions of methoxyfenozide, it is with sulfoxaflor and methoxy worm acyl
Hydrazine is principle active component, and wherein, the weight ratio of sulfoxaflor and methoxyfenozide is 1～60:1～60.Preferably fluorine pyridine worm
The weight ratio of amine nitrile and methoxyfenozide is 1～40:1～40, further preferred sulfoxaflor and the weight of methoxyfenozide
Ratio is 1～30:1～30.In some preferred technical schemes: sulfoxaflor and methoxyfenozide can 1:30,1:29,
1:28、1:27、1:26、1:25、1:24、1:24、1:22、1:21、1:20、1:19、1:18、1:17、1:16、1:15、1:14、1:
13、1:12、1:11、1:10、1:9、1:8、1:7、1:6、1:5、1:4、1:3、1:2、1:1、2:1、3:1、4:1、5:1、6:1、7:
1、8:1、9:1、10:1、11:1、12:1、13:1、14:1、15:1、16:1、17:1、18:1、19:1、20:1、21:1、22:1、
23:1、24:1、25:1、26:1、27:1、28:1、29:1、30:1、2:3、3:2、2:5、5:2、3:4、4:3、5:2、2:5、5:3、
These ratios of 3:5,5:4,4:5 select.
In the present invention containing sulfoxaflor and the Synergistic insecticidal compositions of methoxyfenozide, sulfoxaflor and methoxy worm
Both hydrazides weight percentage in this Synergistic insecticidal compositions is 2%～80%, preferably 8%～60%, and optimum is
20%～40%.
The above-mentioned Synergistic insecticidal compositions containing sulfoxaflor and methoxyfenozide is with sulfoxaflor and methoxyfenozide
Any one dosage form allowed it is configured on pesticide for principle active component (active component) and insecticides adjuvant, excipient.Dosage form
Preferably powder, wettable powder, suspending agent, cream and water dispersion granule.
Described auxiliary agent can use calcium dodecyl benzene sulfonate, alkylphenol polyoxyethylene, polyoxyethylene polyoxy propylene embedding
Section compound is (such as agriculture breast 33#), NPE etc., excipient comprises Ketohexamethylene, dimethylbenzene, solvent naphtha, water, antifreeze
Agent (such as propylene glycol), deionized water etc..Above auxiliary agent, excipient and other agriculturally known adjuvant can be alone or and use.
The above-mentioned Synergistic insecticidal compositions containing sulfoxaflor and methoxyfenozide is at preparation preventing and treating Lepidoptera, half wing
Application in the insecticidal materials of one or more insects in mesh, Hymenoptera or coleoptera.Especially preparation preventing and treating planthopper or
Application effect in the insecticidal materials of snout moths larva is notable.
The Synergistic insecticidal compositions antagonism lepidoptera pest of the present invention has significant preventive effect, particularly with cotton boll
Worm, beet armyworm, diamondback moth etc. easily produce the various pests of resistance and have good preventive effect；And suppress insect to single
The Drug resistance of preparation (sulfoxaflor or methoxyfenozide) produces and can prevent and treat Hemipteran pest such as Brown Planthopper simultaneously
Deng.
The insecticidal materials prepared by the described Synergistic insecticidal compositions containing sulfoxaflor and methoxyfenozide is in preventing and treating
While resistance Lepidoptera, Hymenoptera or coleopteran pest, Hemipteran pest can be prevented and treated again.Especially to cotton boll worm, pickles
Moth and beet armyworm have good preventive effect, reach the effect that a medicine is controlled more.
The Pesticidal combination of the present invention compared with prior art, produces following beneficial effect: (1) compared with single dose, this group
Compound insect has notable synergistic, hence it is evident that improve prevention effect；(2) one medicines are controlled more, and a dispenser can prevent and treat various pests simultaneously,
Reduce preventing and treating recruitment cost；(3) alternative high-toxic pesticide, and field dosage is greatly reduced, effectively reduce environmental pollution and
Pesticide residues；(4) have concurrently quick-acting and long-acting；(5) compared with sulfoxaflor single dose, produce and use cost reduces；(6) suppression
The resistance of pesticide is strengthened by insect.
Detailed description of the invention
Embodiments of the invention are the methods using indoor bioassay and field test to combine.First pass through indoor biological
Measure, the co-toxicity coefficient after clear and definite two kinds of medicaments are compounding by a certain percentage；On this basis, then carry out field test.
Embodiment 1:
Weigh 80g sulfoxaflor, 2g methoxyfenozide, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether
3g, dimethylbenzene put into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, are formed and the most effectively become
The sulfoxaflor methoxyfenozide cream dividing weight percentage to be 82%.
Embodiment 2:
Weigh 2g sulfoxaflor, 80g methoxyfenozide, lignin 10g, Negel 2g, add to Kaolin
100g, mixes above raw material in super micron mill, forms the fluorine pyridine worm that principle active component weight percentage is 82%
Amine nitrile methoxyfenozide wettable powder.
Embodiment 3:
Weigh 60g sulfoxaflor, 2g methoxyfenozide, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether
6g, dimethylbenzene add to 100g, and the method that above raw material is prepared cream routinely puts into mixing in mixing kettle, are formed main effective
Ingredients Weight percentage composition is the sulfoxaflor methoxyfenozide cream of 62%.
Embodiment 4:
Weigh 2g sulfoxaflor, 60g methoxyfenozide, nonyl phenol phosphate 5g, alkylphenol polyoxyethylene 4g, positive fourth
The dimethylbenzene of alcohol 3g, 10g and the ketopyrrolidine of 10g, the xanthan gum of 0.1g, remaining supplies 100g, n-butyl alcohol and water dissolution with water
Forming aqueous phase, remaining component mix and blend forms oil phase, slowly aqueous phase is added in oil phase, and continue under cutter effect
Shear 10～30 minutes, form the sulfoxaflor methoxyfenozide water and milk that principle active component weight percentage is 62%
Agent.
Embodiment 5:
Weigh 40g sulfoxaflor, 2g methoxyfenozide, calcium dodecyl benzene sulfonate 5g, alkylphenol polyoxyethylene 4g,
The solvent xylene of 30g and the ketopyrrolidine of 15g, remaining complements to 100g, the mixing of former medicine, solvent, emulsifying agent, cosolvent with water
Stirring forms homogeneous phase transparent solution, is then slowly added into water and stirs formation clear solution, being principle active component weight hundred
The sulfoxaflor methoxyfenozide microemulsion dividing content to be 42%.
Embodiment 6:
Weigh 2g sulfoxaflor, 40g methoxyfenozide, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether
3g, dimethylbenzene are to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, is formed and the most effectively becomes
The sulfoxaflor methoxyfenozide cream dividing weight percentage to be 42%.
Embodiment 7:
Weigh 20g sulfoxaflor, 2g methoxyfenozide, sodium lignin sulfonate 3g, polyoxyethylene poly-oxygen propylene aether and
Sulfate 4g, xanthan gum 0.2g, ethylene glycol 10g, silica ethane 0.1g, aluminium-magnesium silicate 0.5g, supply 100g with water, at sand mill
Effect lower form the sulfoxaflor methoxyfenozide suspending agent that principle active component weight percentage is 22%.
Embodiment 8:
Weigh 2g sulfoxaflor, 20g methoxyfenozide, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether
15g, dimethylbenzene put into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, are formed main effective
Ingredients Weight percentage composition is the sulfoxaflor methoxyfenozide cream of 22%.
Embodiment 9:
Weigh 2g sulfoxaflor, 10g methoxyfenozide, sodium lignin sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate
5g, polyvinyl alcohol 5g, Borax 2g, Kaolin 28g, the method that above raw material is pressed water dispersion granule forms principle active component
Weight percentage is the sulfoxaflor methoxyfenozide water dispersible granules of 12%.
Embodiment 10:
Weigh 5g sulfoxaflor, 10g methoxyfenozide, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether
15g, dimethylbenzene put into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, are formed main effective
Ingredients Weight percentage composition is the sulfoxaflor methoxyfenozide cream of 15%.
Embodiment 11:
Weigh 10g sulfoxaflor, 10g methoxyfenozide, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether
3g, dimethylbenzene put into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, are formed and the most effectively become
The sulfoxaflor methoxyfenozide cream dividing weight percentage to be 20%.
Drug effect checking test
1, indoor virulence determination of activity
Weigh sulfoxaflor, methoxyfenozide uses conventional formulation method to be configured to principle active component by different proportion
Weight percentage is the sulfoxaflor methoxyfenozide cream of 30%.Concrete ratio is shown in Table 1.
Use feedstuff to add poison method and measure sulfoxaflor and methoxyfenozide and the compounding sample poison to cotton boll worm thereof
Power, often processes and is repeated 3 times, and every concentration processes 30, uses LC50It is worth and presses Sun Yun abundant method calculating co-toxicity coefficient:
Table 1 sulfoxaflor, methoxyfenozide and compounding sample thereof are to the toxicity test of cotton boll worm and co-toxicity coefficient
In table, data show, after sulfoxaflor and methoxyfenozide mixture, cotton boll worm are had potentiation, table
Co-toxicity coefficient listed by is both greater than 120, and therefore sulfoxaflor and methoxyfenozide mixture have significant synergies.
Weigh sulfoxaflor, methoxyfenozide uses conventional formulation method to be configured to principle active component by different proportion
Weight percentage is the sulfoxaflor methoxyfenozide cream of 30%.Concrete ratio is shown in Table 2.
Rice-stem dipping method is used to measure sulfoxaflor and methoxyfenozide and the compounding sample poison to Brown Planthopper thereof
Power, often processes and is repeated 3 times, use LC50It is worth and presses Sun Yun abundant method calculating co-toxicity coefficient:
Table 2 sulfoxaflor, methoxyfenozide and compounding sample thereof are to the toxicity test of Brown Planthopper and co-toxicity coefficient
In table, data show, have potentiation, table after sulfoxaflor and methoxyfenozide mixture to Brown Planthopper
Co-toxicity coefficient listed by is all much larger than 120, and therefore sulfoxaflor and methoxyfenozide mixture have significant synergies.
2, field control effectiveness test
Using embodiment institute sample product to carry out the field test of control in field cotton boll worm, comparison medicament is 21.8% fluorine
Sulfoxaflor SC and 20% methoxyfenozide SC, concrete consumption is shown in Table 3, and every mu of water consumption is 30kg, looks into 3 days after medicine, 7 days, and 14
My god, 28 days results, result of the test is shown in Table 3:
Table 3 sample field test results to cotton boll worm
Example has fabulous quick-acting to cotton boll worm as can be seen from Table 3, and the lasting period is long, at field table
Now good, it is the outstanding medicament of preventing and treating cotton boll worm.
Measure through indoor synergism test and show: by sulfoxaflor with methoxyfenozide built agent to cotton boll worm and water
Brown plant-hopper has significant synergistic insecticidal action；Field control effectiveness test also indicates that all of built agent of the present invention is cotton to Cotton Gossypii equally
Earworm insecticidal effect is all remarkably higher than the effect of corresponding single dose pesticide.
Claims (9)
1. containing sulfoxaflor and a Synergistic insecticidal compositions for methoxyfenozide, it is characterized in that this Synergistic insecticidal compositions with
Sulfoxaflor and methoxyfenozide are principle active component, wherein, the weight ratio of sulfoxaflor and methoxyfenozide be 1～
60:1～60.
The most according to claim 1 containing sulfoxaflor with the Synergistic insecticidal compositions of methoxyfenozide, it is characterized in that this
The active ingredient sulfoxaflor of Pesticidal combination and the weight ratio of methoxyfenozide are 1～40:1～40.
The most according to claim 2 containing sulfoxaflor with the Synergistic insecticidal compositions of methoxyfenozide, it is characterized in that this
The active ingredient sulfoxaflor of Pesticidal combination and the weight ratio of methoxyfenozide are 1～30:1～30.
The most according to claim 1 containing sulfoxaflor with the Synergistic insecticidal compositions of methoxyfenozide, it is characterized in that fluorine
Sulfoxaflor and both methoxyfenozides weight percentage in this Synergistic insecticidal compositions are 2%～80%.
The most according to claim 4 containing sulfoxaflor with the Synergistic insecticidal compositions of methoxyfenozide, it is characterized in that fluorine
Sulfoxaflor and both methoxyfenozides weight percentage in this Synergistic insecticidal compositions are 8%～60%.
The most according to claim 1 containing sulfoxaflor with the Synergistic insecticidal compositions of methoxyfenozide, it is characterized in that this
With sulfoxaflor, as principle active component and insecticides adjuvant is configured on pesticide to permit Synergistic insecticidal compositions with methoxyfenozide
Any one dosage form permitted.
The most according to claim 6 containing sulfoxaflor with the Synergistic insecticidal compositions of methoxyfenozide, it is characterized in that institute
Stating dosage form is cream, wettable powder, microemulsion, aqueous emulsion, suspending agent or water dispersion granule.
8. the Synergistic insecticidal compositions containing sulfoxaflor and methoxyfenozide described in claim 1 is at preparation preventing and treating squama wing
Application in the insecticidal materials of one or more insects in mesh, Semiptera, Hymenoptera or coleoptera.
Application the most according to claim 8, is characterized in that the potentiating pesticidal combination containing sulfoxaflor and methoxyfenozide
Thing application in the insecticidal materials of preparation preventing and treating cotton boll worm, beet armyworm and Brown Planthopper.
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| JP2011126837A (en) * | 2009-12-21 | 2011-06-30 | Nippon Nohyaku Co Ltd | Agricultural and horticultural pest-controlling agent composition, and method for applying them |
| CN102308834A (en) * | 2011-03-17 | 2012-01-11 | 陕西汤普森生物科技有限公司 | Pesticidal composition containing flonicamid and hormone compounds |
| CN103704240A (en) * | 2013-12-13 | 2014-04-09 | 广西田园生化股份有限公司 | Ultralow volume liquid containing sulfoxaflor and insect growth regulating pesticide |
| CN104738079A (en) * | 2013-12-26 | 2015-07-01 | 中国中化股份有限公司 | Binary insecticide composition and application thereof |
-
2016
- 2016-06-21 CN CN201610454188.6A patent/CN106070290A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011126837A (en) * | 2009-12-21 | 2011-06-30 | Nippon Nohyaku Co Ltd | Agricultural and horticultural pest-controlling agent composition, and method for applying them |
| CN102308834A (en) * | 2011-03-17 | 2012-01-11 | 陕西汤普森生物科技有限公司 | Pesticidal composition containing flonicamid and hormone compounds |
| CN103704240A (en) * | 2013-12-13 | 2014-04-09 | 广西田园生化股份有限公司 | Ultralow volume liquid containing sulfoxaflor and insect growth regulating pesticide |
| CN104738079A (en) * | 2013-12-26 | 2015-07-01 | 中国中化股份有限公司 | Binary insecticide composition and application thereof |
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Application publication date: 20161109 |