JP2011126837A - Agricultural and horticultural pest-controlling agent composition, and method for applying them - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a new means and method for efficiently controlling harmful organisms which are impossible or difficult to be controlled, since there are cases that by each singly, effective control can not be performed by reasons such as the kind of objective harmful organisms, effect differences caused by living characters, etc., the development of resistance, etc. <P>SOLUTION: By combining metaflumizone with 1 kind or ≥2 kinds of compounds having insecticidal activity and/or acaricidal activity and using, a marked effect is exhibited even by using a dosage not obtaining a sufficient controlling effect by the use of each singly, and the marked effect is shown even to the harmful organisms not controllable by singly, the harmful organisms showing drug resistance, etc. <P>COPYRIGHT: (C)2011,JPO&INPIT

Description

  The present invention is characterized by containing metaflumizone (generic name: metaflumizone) and one or more compounds selected from compounds having insecticidal activity and / or acaricidal activity, having a synergistic effect, and drug resistance The present invention relates to a pesticide composition for agricultural and horticultural use having an excellent effect on pests and a method for using the composition.

  Metaflumizone used as an active ingredient of the present invention is a known compound and is known to have insecticidal activity and nematicidal activity (see, for example, Patent Document 1). Moreover, the compound which has an insecticidal activity and / or acaricidal activity used as an active ingredient with metaflumizone is a well-known compound of literature description (for example, refer patent document 2, 3, nonpatent literature 1).

Japanese Patent Laid-Open No. 5-17428 International Publication No. 07/095229 Pamphlet International Publication No. 04/067528 Pamphlet

SHIBUYA INDEX2008

  In the treatment of metaflumizone, which is an active ingredient used in the present invention, and a compound having an insecticidal activity and / or acaricidal activity, the effects of differences in the types of target pests, habitat characteristics, development of resistance, etc. There is a case where effective control cannot be performed for a reason, and there is a need for new means and methods for efficiently controlling pests that cannot be controlled or difficult.

  As a result of intensive studies to solve the above-mentioned problems, the present inventors use metaflumizone in combination with one or more compounds selected from compounds having insecticidal activity and / or acaricidal activity. Thus, the present inventors have found that a plurality of pests can be efficiently controlled and completed the present invention.

That is, the present invention comprises [1] metaflumizone and one or more compounds selected from compounds having insecticidal activity and / or acaricidal activity as active ingredients. Horticultural pest control composition,
[2] Compounds having insecticidal activity and / or acaricidal activity are bistrifluron, acetoprole, flufenerim, noviflumuron, gamma-cyhalothrin (gamma-cyhalothrin (gammma-cyhalothramide) flonicamid, pyridalyl, thiosultap, methoflutrin, profluthrin, spiromesifen, dimefluthrin, dimefluthrin, dimefluthrin, dimefluthrin Roll, pyriprole, spirotetramat, spinetoram, chlorantraniprole, cyriflurane, pylfluquinonero , Alpha-endosulfan, fluacrylpyrim, spirodiclofen, amidoflumet, difluvidazin, cyflumetofen en), Shienopirafen (cyenopyrafen) 1 kind or agricultural and horticultural pesticidal composition is a two or more compounds selected from,
[3] One or more compounds selected from compounds having insecticidal activity and / or acaricidal activity with respect to 1 part by mass of metaflumizone are 0.05 to 2000 parts by mass. Item 1. The pesticide composition for agricultural and horticultural use according to any one of Items 1 or 2.
[4] In order to protect useful plants from pests, an effective amount of the agricultural and horticultural pest control composition according to any one of claims 1 to 3 is applied to target pests, target useful plants, and target useful plants. The present invention relates to a method for using an agricultural and horticultural pest control composition characterized by treating seeds, soil, or a cultivation carrier.

  The agricultural and horticultural pest control composition of the present invention exhibits a remarkable effect even at a dose that could not be obtained alone, and exhibits pests and drug resistance that could not be controlled alone. It also has a remarkable control effect against pests.

Metaflumizone represented by the formula (I) of the present invention is a known compound described in JP-A-5-17428 and can be produced by the method described in the publication. Further, the compound has geometric isomers based on a carbon-nitrogen double bond, that is, (E) isomer and (Z) isomer, and the present invention includes these geometric isomers alone and a mixture in any ratio.
Examples of the compound having insecticidal activity and / or acaricidal activity of the present invention include bistrifluron, acetoprole, flufenerimu, noviflumuron, gamma-cyhalothrin, Flonicamid (pyridalyl), thiosultap, methosfluthrin, profluthrin, spiromesifen, dimefluthrin, flubendiamide, pipictin, lepictin Roll (pyrafluprole), pyriprole (spiriprole), spirotetramat (spirotetramat), spinetoram (spinetoram), chlorantraniliprole (chlorantraniliprole), pyrifluquinazon (pyrifluquinazon), alpha-endosulfur Emissions (alpha-endosulfan), fluacrypyrim (fluacrypyrim), spirodiclofen (spirodiclofen), amide full Met (amidoflumet), Jifurobidajin (diflovidazin), cyflumetofen (cyflumetofen), can be exemplified Shienopirafen (cyenopyrafen) or the like. These compounds are SHIBUYA
It is a known compound described in INDEX2008. Cyantraniliprole is a compound of Compound No. 5 of WO 04/067528, and sulfoxaflor is a compound of Compound No. 2 of WO 07/095229. These compounds can be produced by the method described in the publication.

  When metaflumizone is used as a pesticide composition for agricultural and horticultural use in combination with one or more compounds selected from compounds having insecticidal activity and / or acaricidal activity, 100 parts by mass of the composition The amount of the active compound added may be appropriately selected from the range of 0.1 to 50 parts by mass, and preferably 1 to 20 parts by mass. The addition ratio of metaflumizone in the active compound and one or more compounds selected from compounds having insecticidal activity and / or acaricidal activity is such that metaflumizone has insecticidal activity and / or One or more compounds selected from compounds having acaricidal activity may be appropriately selected from the range of 0.05 to 2000 parts by mass, preferably 0.1 to 10 parts by mass. Part range.

When the agricultural and horticultural pest control composition of the present invention is used, it is generally used in a form convenient for use according to a conventional method for agricultural chemical preparations. That is, the active ingredient is mixed with an appropriate inert carrier or, if necessary, with an auxiliary agent in an appropriate ratio, dissolved, separated, suspended, mixed, impregnated, adsorbed or adhered, and an appropriate dosage form. For example, it may be used after being formulated into a suspension, milk suspension, emulsion, solution, wettable powder, granule, powder, tablet, jumbo agent, pack agent or the like.
The inert carrier that can be used in the present invention may be either solid or liquid. Examples of materials that can be used as a solid carrier include vegetable powders (for example, soybean flour, cereal flour, wood flour, bark flour, Sawdust, tobacco stem powder, walnut shell powder, bran, fiber powder, residues after extraction of plant extracts, etc.), synthetic polymers such as pulverized synthetic resin, clays (eg kaolin, bentonite, acid clay), talc (For example, talc, pyrophyllite, etc.), silicas {for example, diatomaceous earth, silica sand, mica, white carbon (some synthetic high-dispersion silicic acid, also called hydrous finely divided silicon, hydrous silicic acid, and some products contain calcium silicate as a main component)} , Activated carbon, natural minerals (eg sulfur powder, pumice, attapulgite and zeolite), calcined diatomaceous earth, brick ground, fly ash, sand, plus Such as plastic carrier (eg polyethylene, polypropylene, polyvinylidene chloride), inorganic mineral powders such as potassium chloride, calcium carbonate, calcium phosphate, chemical fertilizers such as ammonium sulfate, phosphate, nitrate, urea, ammonium sulfate, compost, etc. These may be used alone or in the form of a mixture of two or more.

  The material that can be used as a liquid carrier is selected from those having solvent ability itself and those that can disperse the active ingredient compound with the aid of an auxiliary agent without having solvent ability, for example, water, alcohol (Eg, methanol, ethanol, isopropanol, butanol, ethylene glycol, etc.), ketones (eg, acetone, methyl ethyl ketone, methyl isobutyl ketone, diisobutyl ketone, cyclohexanone, etc.), ethers (eg, ethyl ether, dioxane, cellosolve, diester) Propyl ether, tetrahydrofuran, etc.), aliphatic hydrocarbons (eg kerosene, mineral oil, etc.), aromatic hydrocarbons (eg benzene, toluene, xylene, solvent naphtha, alkylnaphthalene, etc.), halogenated hydrocarbons (eg dichloroethane, The Roform, carbon tetrachloride, etc.), esters (eg, ethyl acetate, diisopropylpropyl phthalate, dibutyl phthalate, dioctyl phthalate, etc.), amides (eg, dimethylformamide, diethylformamide, dimethylacetamide, etc.), nitriles (eg, acetonitrile, etc.) And dimethyl sulfoxides, and the like. These can be used alone or in the form of a mixture of two or more.

  As other adjuvants, the following typical adjuvants can be mentioned, and these adjuvants are used depending on the purpose and are used alone, or in some cases, two or more kinds of adjuvants are used together. In some cases it is possible to use no adjuvants at all. Surfactants can be used for the purpose of emulsifying, dispersing, solubilizing and / or wetting the active ingredient compound, such as polyoxyethylene alkyl ether, polyoxyethylene alkyl aryl ether, polyoxyethylene higher fatty acid ester, polyoxyethylene. Examples include surfactants such as resin acid esters, polyoxyethylene sorbitan monolaurate, polyoxyethylene sorbitan monooleate, alkylaryl sulfonates, naphthalene sulfonic acid condensates, lignin sulfonates, and higher alcohol sulfates. it can. For the purpose of stabilizing the dispersion, sticking and / or binding of the active ingredient compound, for example, casein, gelatin, starch, methylcellulose, carboxymethylcellulose, gum arabic, polyvinyl alcohol, pine oil, coconut oil, bentonite, lignin sulfonate, etc. Adjuvants can be used. In order to improve the fluidity of the solid product, for example, auxiliary agents such as wax, stearate and alkyl phosphate ester can be used. As a peptizer for a suspension product, for example, auxiliary agents such as naphthalenesulfonic acid condensate and condensed phosphate can be used. As the antifoaming agent, for example, an auxiliary agent such as silicone oil can be used.

The pesticide composition for agricultural and horticultural use of the present invention is suitable for various agricultural and forestry, horticultural, stored grain pests, sanitary pests, nematodes, and other pests that harm rice plants, vegetables, fruit trees, and other flowers. From the eyes (Hemiptera)
punctatissimum), sea turtle (Eurydema rugosum), Japanese horned stink bug (Eysarcoris lewisi), Japanese horned stink bug (Eysarcoris)
parvus), Southern beetle (Nezara viridula), Chabaen stink bug (Plautia stali), Halymorpha mista, Hosoharikamemushi (Cletus)
punctiger), Leptocorisa chinensis, Riptortus clavatus, Tobanagaremushi (Togo)
hemipterus), Stephanitis nashi, Azalea, Stephanitis pyrioides, Apolygus turtle (Apolygus)
spinolai), red turtle (Stenotus rubrovittalus), red bearded turtle (Trigonotylus)
coelestialium), Platypleura kaempferi, Arboridia apicalis, Empoasca
onukii), leafhopper leaf (Nephotettix cincticeps), striped leafhopper (Nephotettix virescens), leafhopper (Laodelphax)
striatellus), brown planthopper (Nilaparvata lugens), white-tailed planthopper (Sogatella furcifera), Aobahagoromo (Geisha)
distinctissima), Psylla pyrisuga, Diaphorina citri, Aleurocanthus
spiniferus), silver leaf whiteflies (Bemisia argentifolii), tobacco whiteflies (Bemisia tabaci), citrus whiteflies (Dialeurodes)
citri), whitefly (Trialeurodes vaporariorum), grape aphid (Viteus vitifolii), apple rotifer (Eriosoma)
lanigerum),

Snowy aphid (Aphis citricola), bean aphid (Aphis craccivora), cotton aphid (Aphis gossypii), potato beetle aphid (Aulacorthum)
solani), Japanese aphid (Brevicoryne brassicae), Komikan aphid (Toxoptera aurantii), Citrus aphid (Toxoptera)
citricidus), Aulacorthum magnoliae, Schizaphis piricola, Nippolachnus
piri), phantom aphid (Lipaphis erysimi), peach beetle (Hyalopterus pruni), chrysanthemum aphid (Pleotrichophorus)
chrysanthemi), Macrosiphoniella sanborni, Broad bean aphid (Megoura)
crassicauda), Sitobion ibarae, Tulip beetle (Macrosiphum)
euphorbiae), mycots aphids (Myzus varians), peach aphids (Myzus persicae), red-footed aphids (Rhopalosiphum)
rufiabdominalis), Rhopalosiphum padi, wheat beetle aphid (Sitobion akebiae), Icerya scale insect (Icerya)
purchasi), stag beetle (Pseudococcus comstocki), horned beetle (Ceroplastes ceriferus), ruby weevil (Ceroplastes)
rubens), Aonidiella aurantii, Nymphalidae (Comstockaspis perniciosa), Pseudaulacaspis (Pseudaulacaspis)
pentagoa), the scale insect (Unaspis yanonensis), etc.

From Lepidoptera, Adoxophyes orana fasciata, Adoxophyes
honmai), Midchipakamonmonaki (Archips fuscocupreanus), Chamonaki (Homona magnanima), Chanohosoga (Caloptilia)
theivora), peach moth (Carposina niponensis), pear moth (Grapholita molesta), mugwort (Ascotis)
selenaria), grapeberry moss (Endopiza viteana), codling moth (Laspeyresia pomonella), kinmon hosoga (Phyllonorycter)
ringoniella), Ginmon leaflet (Lyonetia prunifoliella malinella), Citrus leaflet (Phyllocnistis)
citrella), peach leaf moth (Lyonetia clerkella), diamondback moth (Plutella xylostella), cotton beetle (Pectinophora)
gossypiella), green moth (Chilo suppressalis), sun moth (Scirpophaga incertulas), corn borer (Cnaphalocrocis)
medinalis), Hellulla undalis, Conogethes punctiferlis, Papilio
xuthus), white butterflies (Pieris rapae crucivora), damselfish (Parnara guttata), obikareha (Malacosoma)
neustria testacea), gypsy moth (Lymantria dispar), stag beetle (Spilosoma imparilis), American white star (Hyphantria)
cunea), Chadokuga (Euproctis pseudoconspersa), Bromeliad, Orygia recens approximans), Dokuga (Euproctis)
subflava), Hilohelia Oiraga (Parasa lepida), Himekuroiraga (Scopelodes contracus), Tenguiraga (Microleon)
longipalpis), Shibatatsuga (Parapediasia teterrella), Tobacco moth (Helicoverpa armigera), Heliothis species (Heliothis)
spp.), Abratis segetum, Autographa nigrisigna, Trichoplusia
ni), Mamestra brassicae, Spodoptera exigua, Spodoptera
litura), Mongolian killer whale (Phalera flavescens), Chaminoga (Eumeta minuscula),

From the order of the Coleoptera, Anomala cuprea, bean squirrel (Popillia japonica), core Ohameturi (Oxycetonia)
jucunda), Anomala geniculata, Agrilus auriventris, Epuraea
domina), Lyctus brunneus, Tribolium confusum, Epilachna
vigintioctopunctata), Anoplophora malasiaca, Matsunomukamikiri (Monochamus)
alternatus), weevil (Callosobruchus chinensis), leaf beetle (Aulacophora femoralis), root worm species (Diabrotica)
spp.), Phyllotreta striolata, Tortoise beetle (Cassida nebulosa), Radish beetle (Phaedon)
brassicae), peach weevil (Rhynchites heros), cotton weevil (Anthonomus gradis grandis), Mexican beetle (Epilachna)
varivestis), Colorado potato beetle (Leptinotarsa decemlineata), rice weevil (Lissorhoptrus)
oryzophilus), rice beetle (Oulema oryzae), sweet weevil (Sphenophrus venatus vestitus), etc.

From the order of Hymenoptera, Athalia rosae ruficornis, Arge pagana, Black ant (Formica)
japonica), Dryocsmus kuriphilus, etc., from Diptera, Agromyza
oryzae), waterflies (Hydrellia griseola), legumes (Liriomyza trifolii), silkworms (Chromatomyia)
horticola), eggplant fly (Liriomyza bryoniae), seed fly (Delia platura), onion fly (Delia)
antiqua), Rhacochlaena japonica, Musca domestica, Culex
From Pipiens molestus, Culex pipiens pallens, Thysanoptera, Scirtothrips
dorsalis), Thrips palmi, Thrips tabaci, Soybean thrips (Thrips)
setosus), Thrips thrips (Frankliniella intonsa), Citrus thrips (Frankliniella)
occidentalis), Croton thrips (Heliothrips haemorrhoidalis), Periwinkle thrips (Ponticulothrips)
diospyrosi), Termite (Isoptera), Termite (Coptotermes formosanus), Yamato termite (Reticulitermes)
speratus), scallop (Psocoptera), scallop (Liposcelis bostrychophilus), etc.

From the order of the Orthoptera, Oxya yezoensis, Gera (Gryllotalpa sp.), Cockroach (Periplaneta)
americana), German cockroach (Blattella germanica), etc., from the order of Acarina, mandarin mite (Panonychus citri), apple tick (Panonychus)
ulmi), spider mite (Tetranychus urticae), spider mite (Tetranychus kanzawai), spider mite (Tetranychus)
viennensis), Tokimatsu spider mite (Oligonychus ununguis), Miyake spider mite (Eotetranychus kankitus), Southern spider mite (Brevipalpus)
phoenicis), clover spider mite (Bryobia praetiosa), citrus red tick (Aculops pelekassi), black-headed tick (Eriophyes)
chibaensis), tulip rustic mites (Aceria tulipae), grape ticks (Colomerus vitis), moss mites (Aculus)
fockeui), green ticks (Calacarus carinatus), green dust mites (Polyphagotarsonemus latus), Robin tick (Rhizoglyphus)
robini), Tyrophagus putrescentiae, etc., from the order of the Tylenchida (Pylylenchus)
coffeae), red-footed nematode (Pratylenchus penetrans), potato cyst nematode (Globodera)
rostochiensis), Meloidogyne incognita, etc., from the order of Dorylaimida, Longirus
sp.) and other pests such as slugs (Incilaria bilineata) can be mentioned from the mollusc gastropoda (Gastropoda).

  Although the useful plant which can use the agricultural and horticultural pest control composition of the present invention is not particularly limited, for example, cereals (for example, rice, barley, wheat, rye, oats, corn, etc.), beans (soybeans) , Red beans, broad beans, green beans, green beans, peanuts, etc.), fruit trees (fruits, citrus fruits, pears, strawberries, peaches, plums, cherry peaches, walnuts, chestnuts, almonds, bananas, etc.), leaves, fruit vegetables (cabbage) , Tomatoes, spinach, broccoli, lettuce, onions, green onions, peppers, eggplants, strawberries, peppers, pork etc.), root vegetables (carrots, potatoes, sweet potatoes, sweet potatoes, sweet potatoes, turnips, lotus roots, burdocks, garlics, etc.), for processing Crops (salmon, hemp, beet, hop, sugar cane, sugar beet, olive, rubber, coffee, tobacco tea, etc.), cucumbers (pumpkin, cucumber, watermelon, (Wow, melon, etc.), pastures (orchard grass, sorghum, timothy, clover, alfalfa, etc.), turf (Korean turf, bentgrass, etc.), fragrances, etc. Plants such as ginger), flowering plants (kiku, rose, carnation, orchid, etc.), garden trees (ginkgo, sakura, aoki, etc.), forest trees (todomatsu, spruce, pine, hiba, cedar, bamboo, etc.) Can be mentioned.

The pesticide composition for agricultural and horticultural use according to the present invention is capable of generating pests in an amount effective for pest control in the form as it is, or appropriately diluted with water or suspended to control various pests. It can be used for predicted plants. For example, for pests occurring in fruit trees, cereals, vegetables, etc., in addition to spraying on the foliage, seeds immersed in chemicals, seed dressing, seeds such as calper treatment Treatment, soil all layer mixing, crop application, floor soil mixing, cell seedling treatment, planting hole treatment, plant root treatment, top dress, rice box treatment, water surface application, etc. It can also be used. In addition, it can be applied to nutrient solution in nutrient solution (hydroponics) cultivation, smoke, or trunk injection. Further, for example, in addition to spraying on stored grain pests, house pests, sanitary pests, forest pests, etc., they can also be used for application to house building materials, smoke, baits and the like.
Seed treatment methods include, for example, a method in which a liquid or solid preparation is diluted or undiluted and the seed is immersed in a liquid state to infiltrate the drug, a solid preparation or liquid preparation is mixed with the seed, Examples thereof include a method of treating and adhering to the surface of the seed, a method of coating the seed by mixing with an adhesive carrier such as resin and polymer, and a method of spraying around the seed simultaneously with planting.
The “seed” for performing the seed treatment means a plant body at an early stage of cultivation used for plant propagation, for example, a seed, a bulb, a tuber, a seed bud, a stock bud, a basket, a bulb or a nutrient for cultivation of cuttings. Mention may be made of plants for breeding.

The “soil” or “cultivation carrier” of the plant when carrying out the method of use of the present invention refers to a support for cultivating crops, particularly a support for growing roots, and the material is not particularly limited. However, any material that can grow plants may be used, and so-called soil, seedling mats, water, etc. may be used. Specific materials include, for example, sand, pumice, vermiculite, diatomaceous earth, agar, gel-like substances, high It may be a molecular substance, rock wool, glass wool, wood chip, bark or the like.
As spraying methods for crop foliage, stored grain pests, house pests, hygiene pests, forest pests, etc., dilute liquid preparations such as emulsions and flowables or solid preparations such as wettable powders or granular wettable powders with water. , A method of spraying, a method of spraying powder, smoke or the like.
Examples of application methods to soil include, for example, a method in which a liquid preparation is diluted or not diluted with water and applied to a plant stock or seedling nursery, etc. A method of spraying to a nursery, etc., a method of spraying powder, wettable powder, granule wettable powder, granule, etc. before sowing or transplanting, and mixing with the whole soil, a planting hole, cropping before sowing or planting plant Examples thereof include a method of spraying powder, wettable powder, wettable powder, granule, etc. on the strip.

As a method for applying paddy rice to a seedling box, the dosage form may vary depending on the application time such as application at seeding, greening period, application at transplanting, etc., for example, powder, granule wettable powder, granule etc. What is necessary is just to apply with a dosage form. It can also be applied by mixing with soil, and can be mixed with soil and powder, granulated wettable powder or granules, for example, mixed with ground soil, mixed with soil, mixed into the entire soil, etc. The soil and various preparations may be applied alternately in layers.
As an application method to paddy fields, solid preparations such as jumbo agents, pack agents, granules, granule wettable powders, and liquid preparations such as flowables and emulsions are usually sprayed on flooded paddy fields. In addition, at the time of rice planting, an appropriate preparation can be sprayed and injected into the soil as it is or mixed with fertilizer. In addition, by using a chemical solution such as emulsion or flowable as a source of water flowing into a paddy field such as a water inlet or an irrigation device, it can be applied in a labor-saving manner along with the supply of water.
In a field crop, it can be processed to a seed or a cultivation carrier close to a plant body from sowing to raising seedling. In plants that are sown directly in a field, in addition to direct treatment on seeds, treatment on a plant source of a plant being cultivated is suitable. It is possible to perform a irrigation treatment in a liquid state using a granule or a spraying treatment or a drug diluted or not diluted in water. It is also a preferable treatment to mix the granules with the cultivation carrier before sowing and then sow.

As the seeding of the cultivated plant to be transplanted and the treatment of the seedling raising period, in addition to the direct treatment to the seed, the irrigation treatment of the liquid drug or the spraying treatment of the granule to the seedling nursery is preferable. In addition, it is also preferable to treat a granule in a planting hole at the time of planting or to mix it with a cultivation carrier in the vicinity of the transplantation site.
The pest control composition of the present invention can be used by formulating it into usual dosage forms, for example, emulsions, wettable powders, granular wettable powders, flowables, liquids, granules, powders, smoke agents, and the like. The application amount may vary depending on the mixing ratio of the active ingredient, weather conditions, formulation form, application time, application method, application place, pest to be controlled, target crop, etc. What is necessary is just to select and apply from the range of 1g-1000g suitably, Preferably the range of 1g-500g is good. In the treatment of seeds, it can be used as an active ingredient in a range of 0.01% to 50%, preferably in a range of 0.1% to 10%, by comparison with the seed weight. When diluting and applying emulsions, wettable powders, etc. with water etc., the application concentration is 0.00001-0.1%, and liquids, etc. when treating granules, powders or seeds are usually diluted. It can be applied as it is.

In addition, in order to control diseases and / or weeds simultaneously occurring at the time of use of the agricultural and horticultural pest control composition of the present invention, the other active ingredient is a compound having insecticidal activity and / or acaricidal activity. In addition, when used in combination with a compound having bactericidal or herbicidal activity, synergistic effects can be expected in the expansion of pests to be controlled, reduction in dosage, herbicides and the like.
Examples of such a compound having bactericidal activity or herbicidal activity include compounds having bactericidal activity such as azoxystrobin, diclocymet, pyroquilon, kasugamycin, IBP (iprobenfos) Hymexazol, mepronil, tricyclazole, edifenphos, isoprothiolane, blasticidin, flutolanil, diclomezine, pencicuron, pencycuron, pencycuron, pencycuron, pencycuron, pencycuron, pencycuron Carbendazim, dodine, propamocarb, pyrimemethanil, fluquinconazole, fosetyl-aluminum, fosetyl-AL, bromuconazole, triticonazole , Flumetover, fenamidon (fen amidone, tolylfluanid, dichlofluanid, trifloxystrobin, triadimenol, spiroxamine, fenhexamid, iprovalicarb, fusalide (fthalide), iprodione, thiophanate, benomyl, triflumizole, fluazinam, zineb
Captan, manzeb, fenarimol, calcium polysulfide, triadimefon, vinclozolin, dithianon, bitertanol,

Polycarbamate, iminoctadine-arbesylate (iminoctadine-DBS), pebulate, polyoxin-B, propineb, propionb, chinomethionat, dichlofluanid, chlorothalonil ), Difenoconazole, fluoroimide, triforine, oxadixyl, streptomycin, mancozeb, oxolinic
acid), metalaxyl, propiconazole, hexaconazole, sulfur, pyrifenox, basic copper sulfate (basic)
copper sulfate, pyrimethalanil, iprobenfos, tolclofos-methyl, maneb, thiophanate-methyl, thifluzamide, furametpyr, fursulfamide, flusulfamide -Methyl (kresoxim-methyl), carpropamid, hydroxyioxazole, echlomezole, procymidone, vinclozolin, ipconazole, furconazole, microbutanil , Tetraconazole, tebuconazole, imibenconazole, prochloraz, pefurazoate, cyproconazole, mepanipyrim, thiadiazin, probena Examples include bactericides such as probenazole, acibenzolar-S-methyl, validamycin (-A), phenoxanil, and thiadinil.

Next, as a compound having herbicidal activity, for example, bensulfuron-methyl, azimsulfuron, cinosulfuron, cyclosulfamuron, pyrazosulfuro-ethyl, imazosulfuron ( imazosulfuron, indanofan, cyhalofop-butyl, thenylchlor, esprocarb, etobenzanid, caffenstrole, clomeprop, dimethametryn, dimethametryn daimuron), bifenox
, Piributicarb, pyriminobac-methyl, pretilachlor, bromobutide, benzofenap, benthiocarb, bentoxazone, benfuresate, mefenacet, mefenacet Fenoxaprop-P-ethyl, phenmedipham, diclofop-methyl, desmedipham, etofumesate, isoproturon, amidosulfuron ( amidosulfuron, anilofos, benfuresate, ethoxysulfuron, iodosulfuron, isoxadifen, isoxadifen, foramsulfuron, pyraclonil, mesosulfuron, mesosulfuron (diuron), neburon ), Dinoterb, carbetamide, bromoxynil, oxadiazon, dimefuron, diflufenican, aclonifen, benzofenap, oxaziclomefone, oxaziclomefone Isoxaflutole, oxadiargyl, flurtamone, metribuzin, methabenzthiazuron, tribufos, metamitron, ethiozin, fluphenaset flufenacet),

Sulcotrion, fentrazamide, propoxycarbazone, flucarbazone, metosulam, amicarbazone
, Glyphosate-isopropyl amine, glyphosate-trimesium, glufosinate-ammonium, bialaphos
, Butamifos, prosulfocarb, asuram, linuron, calcium peroxide
peroxide), alachlor, pendimethalin, acifluofen-sodium, lactofen, ioxynil-octanoate, alloxydim, sethoxydim, napropamide ), Pyrazolate, pyraflufen-ethyl, imazapyr, sulfentrazone, oxadiazon, paraquat, diquat, simazine, Mention may be made of herbicides of atrazine, fluthiacet-methyl, quizalofop-ethyl, bentazone, triaziflam, isouron. It can also be used by mixing with thidiazuron, mefenpyr, ethephon, cyclanilide and the like having a plant growth regulating action.

Furthermore, the present invention relates to nuclear polyhedrosis virus (NPV), granulosis virus (GV).
, Cytoplasmic polyhedrosis virus (CPV), virus preparations such as insect poxvirus (Entomopox virus, EPV), Monocrosporium fimatopagum (Monacrosporium)
phymatophagum), Steinernema carpocapsae, Steinernema carpocapsae
kushidai), Pasturia penetrans, Trichoderma lignorum, Agrobacterium radiobacter (Agrobacterium)
radiobactor), non-pathogenic Erwinia carotovora, Bacillus subtilis, Xanthomonas
campestris), microbial pesticides such as Beauveria brongniartii, Encarsia
formosa), Aphidius colemani, Aphidoletes aphidimyza, Diglyphus
isaea), Hyacinthus sibirica, Phytoseiulus persimilis, Amblyseius
cucumeris), natural enemy organisms such as Orius sauteri, (Z) -10-tetradecenyl acetate, (E, Z) -4,10-tetradecadinyl acetate, (Z) -8-dodecenyl = Acetate, (Z) -11-
Tetradecenyl acetate, (Z) -13-icosene-10-one, (Z) -8-dodecenyl acetate, (Z) -11-tetradecenyl acetate, (Z) -13
It can also be used in combination with pheromone agents such as icosen-10-one and 14-methyl-1-octadecene.

  Although the typical Example and test example of this invention are illustrated below, this invention is not limited to these. In the examples, “parts” means “mass parts”.

Example 1.
Metaflumizone 20 parts Flonicamid 5 parts Hydrous silicic acid 30 parts Hytenol M08 (Daiichi Kogyo Seiyaku Co., Ltd.) 5 parts Lignin sulfonate 3 parts Wettable clay 37 parts Hydrous silicic acid is impregnated with active compound and then homogeneous with other components To make a wettable powder.

Example 2
Metaflumizone 20 parts Spiromesifene 5 parts Solpol 3105 (manufactured by Toho Chemical Co., Ltd.) 5 parts Propylene glycol 5 parts Rhodopol 23 (manufactured by Rhône-Poulenc) 2 parts Water 63 parts Evenly mixed and dispersed in water And

Example 3
Metaflumizone 20 parts Sienopyrafen 5 parts Solpol 3105 5 parts Propylene glycol 2 parts Rhodopol 23 1 part Water 67 parts The above is uniformly mixed and dispersed in water to obtain a flowable agent.

Example 4
Metaflumizone 20 parts Spirodiclofen 5 parts Hydrous silicic acid 34 parts Hytenol M08 3 parts Demol T 2 parts Calcium carbonate powder 36 parts After impregnating the active compound in hydrous silicic acid, it is mixed uniformly with other ingredients and mixed with wettable powder To do.

Example 5 FIG.
Metaflumizone 20 parts Ciflumethofene 5 parts SP-3005X 15 parts Xylene 30 parts N-methylpyrrolidone 30 parts The above is mixed and melted uniformly to prepare an emulsion.

Example 6
Metaflumizone 20 parts Spirotetramat 5 parts Solpol 3105 5 parts Propylene glycol 2 parts Rhodopol 23 1 part Water 67 parts The above is uniformly mixed and dispersed in water to obtain a flowable agent.

Example 7
Metaflumizone 20 parts Pyriprole 5 parts Solpol 3105 5 parts Propylene glycol 3 parts Rhodopol 23 2 parts Water 65 parts The above is uniformly mixed and dispersed in water to obtain a flowable agent.

Example 8 FIG.
Metaflumizone 1 part Sulfoxaflor 1.5 parts Clay powder 82.5 parts Diatomaceous earth powder 15 parts The above is mixed and pulverized uniformly to obtain a powder.

Example 9
Metaflumizone 5 parts Cyantraniliprole 1 part Bentonite / clay mixed powder 89 parts Calcium lignin sulfonate 5 parts Mix evenly, knead with appropriate amount of water, granulate and dry to form granules .

Test Example 1 Control effect of cabbage on diamondback moth and peach aphid Kanran (variety: YR Harenori) was planted in the field, and after about one month of planting, the number of parasites per 30 strains was investigated, and the drug produced in the example was brought to an effective concentration. The diluted chemical solution was sufficiently sprayed. About 1 week after spraying, the number of parasites per 30 strains was investigated, and the control value was calculated by Formula-1. Tested in 2 replicates per section. The results are shown in Table 1.
[Formula-1]
Control value = 100 − {(Ta × Cb) / (Tb × Ca)} × 100
Ta: Number of parasites after spraying in the treated zone Tb: Number of parasites before spraying in the treated zone Ca: Number of parasites after spraying in the untreated zone Cb: Number of parasites before spraying in the untreated zone

Test Example 2 Control effect of eggplant on the tobacco moth, southern blue thrips and sand spider mite We investigated the number of adult larvae, adult thrips and female spider mites per 10 strains of eggplant (variety: Thousand No. 2) planted in the field. A drug solution prepared by diluting the manufactured drug to an effective concentration was sufficiently sprayed. One week after spraying, the number of adult tobacco larvae, the number of adult Thrips thrips per 10 strains, and the number of female spider mites after 1, 2, 3, and 4 weeks of spraying were investigated. The control efficiency (Namidani mite) was calculated using Formula-3. The results are shown in Table 1.
[Formula-2]
Control value = 100 − {(Ta × Cb) / (Tb × Ca)} × 100
Ta: Number of parasites after application / number of damaged leaves in treated area Tb: Number of parasites before application / number of damaged leaves in treated area Ca: Number of parasites after application / number of damaged leaves in untreated area Cb: Application in untreated area Number of preparasites / number of damaged leaves [Formula-3]

n
n
Control efficiency = {1- (Cb × ΣTai) / (Tb × ΣCai)} × 100

^{i = 1
i = 1}
n: Number of surveys after spraying Tai: Density of i-th survey after spraying in treated zone Tb: Density of survey before spraying in treated zone Cai: Density of i-th survey after spraying in untreated zone Cb: Before spraying in untreated zone Survey density

Test Example 3 Control effect of apples on apple coconut spruce and urticae mites. Number of damaged leaves (bamboo leaves) per 20 new shoots of apple trees (variety: Fuji, 8th grade) planted in the field, and urticae per 100 leaves The number of female adults was investigated, and a chemical solution diluted to an effective concentration was sufficiently sprayed. Two weeks after spraying, the number of damaged leaves (bamboo leaves) per 20 new shoots was investigated, and the number of female adult spider mites per 100 leaves after 1, 2, 3, and 4 weeks of spraying. In the same manner as in No. 2, the control value (apple coconut beetle) and the control efficiency (spider mite) were calculated. The results are shown in Table 2.

Test Example 4 Control effect of paddy rice on corn borer and brown planthopper Rice (variety: Koshihikari) was transplanted to Honda (mid-May). In early August, the number of leaf-damaged leaves and adult leafhopper larvae per treatment area was investigated. The diluted chemical solution was sufficiently sprayed. About 2 weeks after the spraying, 100 strains of Japanese corn borer-damaged leaves and the number of adult leafhoppers were examined, and the control value was calculated in the same manner as in Test Example 2. The results are shown in Table 2. In the table, “-” indicates untested.

  From the results in Tables 1 and 2, it was revealed that metaflumizone or each insecticide or acaricide is effective when used in combination as compared with the case where it is used alone.

Claims (4)

 A pesticide composition for agricultural and horticultural use comprising metaflumizone and one or more compounds selected from compounds having insecticidal activity and / or acaricidal activity as active ingredients . Compounds having insecticidal and / or acaricidal activity are bistrifluron, acetoprole, fluphenerim, noviflumuron, gamma-cyhalothrin, gamma-cyhalothrimid Pyridalyl, thiosultap, methoffluthrin, profluthrin, spiromesifen, dimethylfluthrin, flubendiamide (fludediamide) (Pyrafluprole), pyriprole, spirotetramat, spinetoram, chlorantraniprole, rifluriquinone, pylfluquinazone, i Alpha-endosulfan, fluacrylpyrim, spirodiclofen, amidoflumet, diflovidazin, cyflumethofen, cyflumetoffen A pest control composition for agricultural and horticultural use, which is one or more compounds selected from cynopyrafen.   1 or 2 or more types of compounds selected from the compound which has an insecticidal activity and / or acaricidal activity with respect to 1 mass part of metaflumizone (metaflumzone) are the ratio of 0.05-2000 mass parts, or 2. The agricultural or horticultural pest control composition according to any one of the above.   In order to protect useful plants from pests, an effective amount of the agricultural and horticultural pest control composition according to any one of claims 1 to 3 is applied to target pests, target useful plants, seeds of target useful plants, soil Alternatively, a method for using a pesticide composition for agricultural and horticultural use, characterized by being treated as a cultivation carrier.