JP2013079196A - Noxious organism control agent composition for agricultural and horticultural applications, and use thereof - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide new means and method to effectively control a noxious organism that cannot be controlled or is difficult to be controlled because there is a case that cannot perform effective control respectively alone by the reason of the kind of an object noxious organism or the like, the differential effect by living characteristics or the like, and a resistant development or the like.SOLUTION: The use of flubendiamide and thiosultap or a salt thereof in combination can produce a significant synergistic control effect, even when each of the components is used in an amount in which a satisfactory control effect cannot be achieved when used singly. The use of these components in combination can produce a significant control effect against noxious organisms that cannot be controlled when each of the components is used singly and noxious organism that have resistance to commercially available control agents.

Description

  The present invention is characterized by containing fulvendiamide (generic name, flubenamide) and one or more compounds selected from compounds having insecticidal activity and / or acaricidal activity, and has a synergistic effect, The present invention relates to an agricultural and horticultural pest control composition having an excellent effect on drug-resistant pests and a method for using the composition.

  Flubendiamide used as an active ingredient of the present invention is a known compound and is known to have insecticidal activity (see, for example, Patent Document 1). Moreover, the compound which has an insecticidal activity and / or acaricidal activity used as an active ingredient with a fulvendiamide is a well-known compound of literature description (for example, refer nonpatent literature 1).

Japanese Patent Laid-Open No. 11-240857

SHIBUYA INDEX 2009

  In the treatment of fulvendiamide, which is an active ingredient used in the present invention, and a compound having insecticidal activity and / or acaricidal activity alone, effect differences due to the type of target pests, habitat characteristics, development of resistance, etc. For these reasons, effective control may not be possible, and new means and methods for efficiently controlling pests that cannot or cannot be controlled are required.

  As a result of repeated studies to solve the above problems, the present inventors have used fulvendiamide in combination with one or more compounds selected from compounds having insecticidal activity and / or acaricidal activity. The present inventors have found that a plurality of pests can be efficiently controlled and completed the present invention.

That is, the present invention
[1] An agricultural and horticultural pest characterized by containing, as active ingredients, fulvendiamide and one or more compounds selected from compounds having insecticidal activity and / or acaricidal activity Control agent composition,
[2] Compounds having insecticidal activity and / or acaricidal activity are bistrifluron, acetoprole, flufenerim, noviflumuron, gamma-cyhalothrin, gamma-cyhalothrin, gamma-cyhalothrin (Flonicamid), pyridalyl (pyridalyl), thiosultap (methiofluthrin), prostruthrin (proflfluthrin), dimethlthrin (spirimrine), lepimetropro (le) etoram), chlorantraniliprole, pyrifluquinazone, cyantaniliprole, sulfantafluorid, alpha-endulphan, alpha-endosulfan The pesticide composition for agricultural and horticultural use according to claim 1, which is one or more compounds selected from (diflovidazin), cyflumetofen and cyenopyrafen.
[3] The agricultural and horticultural pest control composition according to claim 1, wherein the compound having insecticidal activity and / or acaricidal activity is thiosultap and / or a salt thereof.
[4] The pesticide composition for agricultural and horticultural use according to claim 3, wherein the salt of thiosultap is thiosultap-monosodium or thiosultap-monosodium.
[5] The harmfulness for agriculture and horticulture according to any one of claims 1 to 4, wherein thiosultap or a salt thereof is in a ratio of 0.05 to 2000 parts by mass with respect to 1 part by mass of fulvendiamide. Biocontrol agent composition,
[6] In order to protect useful plants from pests, an effective amount of the agricultural and horticultural pest control composition according to any one of claims 1 to 5 is applied to the target pests, target useful plants, and target useful plants. A method for using a pesticide composition for agricultural and horticultural use, characterized by being treated with seeds, soil, or a cultivation carrier,
About.

  The agricultural and horticultural pest control composition of the present invention exhibits a remarkable effect even at a dose that could not be obtained alone, and exhibits pests and drug resistance that could not be controlled alone. It also has a remarkable control effect against pests.

The fulvendiamide represented by the formula (I) of the present invention is a known compound described in JP-A No. 11-240857, and can be produced by the method described in the publication. Examples of the compound having insecticidal activity and / or acaricidal activity of the present invention include bistrifluron, acetoprole, flufenerimu, noviflumuron, flonicamid, pyridalyl ( pyridalyl, thiosultap, metofluthrin, profluthrin, spiromesifen, dimefluthrin, flubendiamide, lepimectin, pyrafluprole, pyrafluprole pyriprole, spirotetramat, spinetoram, chlorantraniliprole, pyrifluquinazon, cyantraniliprole, sulfoxafur (su Examples include lfoxaflor, alpha-endosulfan, fluacrypyrim, spirodiclofen, amidoflumet, diflovidazin, cyflumetofen, and cyenopyrafen. . These compounds are SHIBUYA
It is a known compound described in INDEX2009. Among these, thiosultap or a salt thereof can be produced by the method described in the publication (CN1685818). The monosodium salt of thiosultap is called monosultap, and the 2-sodium salt of thiosultap is called disultap. It is.

When the fulvendiamide and one or more compounds selected from compounds having insecticidal activity and / or acaricidal activity are used in combination as a pesticide composition for agricultural and horticultural use, 100 masses of the composition The addition amount of the active compound in the part may be appropriately selected from the range of 0.1 to 50 parts by mass, and is preferably in the range of 1 to 20 parts by mass. Further, the addition ratio of fulvendiamide in the active compound and one or more compounds selected from compounds having insecticidal activity and / or acaricidal activity is such that fulvendiamide has an insecticidal activity and 1 part by mass. One or two or more compounds selected from compounds having acaricidal activity may be appropriately selected from the range of 0.05 parts by mass to 2000 parts by mass, preferably 0.1 parts by mass to The range is 20 parts by mass.
As the compound having insecticidal activity and / or acaricidal activity used in combination with fulvendiamide, thiosultap or a salt thereof is preferable.

When the agricultural and horticultural pest control composition of the present invention is used, it is generally used in a form convenient for use according to a conventional method for agricultural chemical preparations. That is, the active ingredient is mixed with an appropriate inert carrier or, if necessary, with an auxiliary agent in an appropriate ratio, dissolved, separated, suspended, mixed, impregnated, adsorbed or adhered, and an appropriate dosage form For example, it may be used after being formulated into a suspension, milk suspension, emulsion, solution, wettable powder, granule, powder, tablet, jumbo agent, pack agent or the like.
The inert carrier that can be used in the present invention may be either solid or liquid. Examples of materials that can be used as a solid carrier include vegetable powders (for example, soybean flour, cereal flour, wood flour, bark flour, Sawdust, tobacco stem powder, walnut shell powder, bran, fiber powder, residues after extraction of plant extracts, etc.), synthetic polymers such as pulverized synthetic resin, clays (eg kaolin, bentonite, acid clay), talc (For example, talc, pyrophyllite, etc.), silicas {for example, diatomaceous earth, silica sand, mica, white carbon (some synthetic high-dispersion silicic acid, also called hydrous finely divided silicon, hydrous silicic acid, and some products contain calcium silicate as a main component)} , Activated carbon, natural minerals (eg sulfur powder, pumice, attapulgite and zeolite), calcined diatomaceous earth, brick ground, fly ash, sand, plus Such as plastic carrier (eg polyethylene, polypropylene, polyvinylidene chloride), inorganic mineral powders such as potassium chloride, calcium carbonate, calcium phosphate, chemical fertilizers such as ammonium sulfate, phosphate, nitrate, urea, ammonium sulfate, compost, etc. These may be used alone or in the form of a mixture of two or more.

  The material that can be used as a liquid carrier is selected from those having solvent ability itself and those that can disperse the active ingredient compound with the aid of an auxiliary agent without having solvent ability, for example, water, alcohol (Eg, methanol, ethanol, isopropanol, butanol, ethylene glycol, etc.), ketones (eg, acetone, methyl ethyl ketone, methyl isobutyl ketone, diisobutyl ketone, cyclohexanone, etc.), ethers (eg, ethyl ether, dioxane, cellosolve, diester) Propyl ether, tetrahydrofuran, etc.), aliphatic hydrocarbons (eg kerosene, mineral oil, etc.), aromatic hydrocarbons (eg benzene, toluene, xylene, solvent naphtha, alkylnaphthalene, etc.), halogenated hydrocarbons (eg dichloroethane, The Roform, carbon tetrachloride, etc.), esters (eg, ethyl acetate, diisopropylpropyl phthalate, dibutyl phthalate, dioctyl phthalate, etc.), amides (eg, dimethylformamide, diethylformamide, dimethylacetamide, etc.), nitriles (eg, acetonitrile, etc.) And dimethyl sulfoxides, and the like. These may be used alone or in the form of a mixture of two or more.

  As other adjuvants, typical adjuvants exemplified below can be mentioned, and these adjuvants are used depending on the purpose, and used alone, in some cases, two or more kinds of adjuvants are used together. In some cases it is possible to use no adjuvants at all. Surfactants can be used for the purpose of emulsifying, dispersing, solubilizing and / or wetting of the active ingredient compound, such as polyoxyethylene alkyl ether, polyoxyethylene alkyl aryl ether, polyoxyethylene higher fatty acid ester, polyoxyethylene. Examples include surfactants such as resin acid esters, polyoxyethylene sorbitan monolaurate, polyoxyethylene sorbitan monooleate, alkylaryl sulfonates, naphthalene sulfonic acid condensates, lignin sulfonates, and higher alcohol sulfates. it can. For the purpose of stabilizing the dispersion, sticking and / or binding of the active ingredient compound, for example, casein, gelatin, starch, methylcellulose, carboxymethylcellulose, gum arabic, polyvinyl alcohol, pine oil, coconut oil, bentonite, lignin sulfonate, etc. Adjuvants can be used. In order to improve the fluidity of solid products, for example, auxiliary agents such as waxes, stearates and alkyl phosphates can be used. As a peptizer for a suspension product, for example, auxiliary agents such as naphthalenesulfonic acid condensate and condensed phosphate can be used. As the antifoaming agent, for example, an auxiliary agent such as silicone oil can be used.

The pesticide composition for agricultural and horticultural use of the present invention is suitable for various agricultural and forestry, horticultural, stored grain pests, sanitary pests, nematodes, and other pests that harm rice plants, vegetables, fruit trees, and other flowers. From the eyes (Hemiptera)
punctatissimum), sea turtle (Eurydema rugosum), Japanese horned stink bug (Eysarcoris lewisi), Japanese horned stink bug (Eysarcoris)
parvus), Southern beetle (Nezara viridula), Chabaen stink bug (Plautia stali), Halyomorpha mista, Coleus
punctiger), Leptocorisa chinensis, Riptortus clavatus, Tobanagaremushi (Togo)
hemipterus), Stephanitis nashi, Azalea, Stephanitis pyrioides, Apolygus
spinolai), red turtle (Stenotus rubrovittatus), red bearded turtle (Trigonotylus)
coelestialium), Platypleura kaempferi, Arboridia apicalis, Empoasca
onukii), leafhopper leaf (Nephotettix cincticeps), striped leafhopper (Nephotettix virescens), leafhopper (Laodelphax)
striatellus), brown planthopper (Nilaparvata lugens), white-tailed planthopper (Sogatella furcifera), Aobahagoromo (Geisha)
distinctissima), Psylla pyrisuga, Diaphorina citri, Aleurocanthus
spiniferus), silver leaf whiteflies (Bemisia argentifolii), tobacco whiteflies (Bemisia tabaci), citrus whiteflies (Dialeurodes)
citri), whitefly (Trialeurodes vaporariorum), grape aphid (Viteus vitifolii), apple rotifer (Eriosoma)
lanigerum),

Snowy aphid (Aphis citricola), bean aphid (Aphis craccivora), cotton aphid (Aphis gossypii), potato beetle aphid (Aulacorthum)
solani), Japanese aphid (Brevicoryne brassicae), Komikan aphid (Toxoptera aurantii), Citrus aphid (Toxoptera)
citricidus), Aulacorthum magnoliae, Schizaphis piricola, Nippolachnus
piri), phantom aphid (Lipaphis erysimi), peach beetle (Hyalopterus pruni), chrysanthemum aphid (Pleotrichophorus)
chrysanthemi), Macrosiphoniella sanborni, Broad bean aphid (Megoura)
crassicauda), Sitobion ibarae, Tulip mustard aphid (Macrosiphum euphorbiae), Mysterious aphid (Myzus)
varians), peach aphid (Myzus persicae), brown aphid (Rhopalosiphum rufiabdominalis), barley beetle (Rhopalosiphum)
padi), wheat beetle aphid (Sitobion akebiae), Icerya purchasi, stag beetle (Pseudococcus)
comstocki), horn beetle (Ceroplastes ceriferus), ruby weevil (Ceroplastes rubens), red beetle (Aonidiella)
aurantii), Nymphalidae (Comstockaspis perniciosa), Swordbug (Pseudaulacaspis)
pentagona), Aedes scale (Unaspis yanonensis), etc.

From Lepidoptera, Adoxophyes orana fasciata, Adoxophyes
honmai), Midchipakamonmonaki (Archips fuscocupreanus), Chamonaki (Homona magnanima), Chanohosoga (Caloptilia)
theivora), peach moth (Carposina niponensis), pear moth (Grapholita molesta), mugwort (Ascotis)
selenaria), grapeberry moss (Endopiza viteana), codling moth (Laspeyresia pomonella), kinmon hosoga (Phyllonorycter)
ringoniella), Ginmon leaflet (Lyonetia prunifoliella malinella), Citrus leaflet (Phyllocnistis)
citrella), peach leaf moth (Lyonetia clerkella), diamondback moth (Plutella xylostella), cotton beetle (Pectinophora)
gossypiella), green moth (Chilo suppressalis), sun moth (Scirpophaga incertulas), corn borer (Cnaphalocrocis)
medinalis), Hellulla undalis, Conogethes punctiferlis, Papilio
xuthus), white butterflies (Pieris rapae crucivora), damselfish (Parnara guttata), obikareha (Malacosoma)
neustria testacea), gypsy moth (Lymantria dispar), stag beetle (Spilosoma imparilis), American white star (Hyphantria)
cunea), Chadokuga (Euproctis pseudoconspersa), Bromeliad, Orygia recens approximans), Dokuga (Euproctis)
subflava), Hilohelia Oiraga (Parasa lepida), Himekuroiraga (Scopelodes contracus), Tenguiraga (Microleon)
longipalpis), Shibatatsuga (Parapediasia teterrella), Tobacco moth (Helicoverpa armigera), Heliothis species (Heliothis)
spp.), Abratis segetum, Autographa nigrisigna, Trichoplusia
ni), Mamestra brassicae, Spodoptera exigua, Spodoptera
litura), Mongolian killer whale (Phalera flavescens), Chaminoga (Eumeta minuscula),

From the order of the Coleoptera, Anomala cuprea, bean squirrel (Popillia japonica), core Ohameturi (Oxycetonia)
jucunda), Anomala geniculata, Agrilus auriventris, Epuraea
domina), Lyctus brunneus, Tribolium confusum, Epilachna
vigintioctopunctata), Anoplophora malasiaca, Matsunomukamikiri (Monochamus)
alternatus), weevil (Callosobruchus chinensis), leaf beetle (Aulacophora femoralis), root worm species (Diabrotica)
spp.), Phyllotreta striolata, Tortoise beetle (Cassida nebulosa), Radish beetle (Phaedon)
brassicae), peach weevil (Rhynchites heros), cotton weevil (Anthonomus gradis grandis), Mexican beetle (Epilachna)
varivestis), Colorado potato beetle (Leptinotarsa decemlineata), rice weevil (Lissorhoptrus)
oryzophilus), rice beetle (Oulema oryzae), sweet weevil (Sphenophrus venatus vestitus), etc.

From the order of Hymenoptera, Athalia rosae ruficornis, Arge pagana, Black ant (Formica)
japonica), Dryocsmus kuriphilus, etc., from Diptera, Agromyza
oryzae), waterflies (Hydrellia griseola), legumes (Liriomyza trifolii), silkworms (Chromatomyia)
horticola), eggplant fly (Liriomyza bryoniae), seed fly (Delia platura), onion fly (Delia)
antiqua), Rhacochlaena japonica, Musca domestica, Culex
From Pipiens molestus, Culex pipiens pallens, Thysanoptera, Scirtothrips
dorsalis), Thrips palmi, Thrips tabaci, Soybean thrips (Thrips)
setosus), Thrips thrips (Frankliniella intonsa), Citrus thrips (Frankliniella)
occidentalis), Croton thrips (Heliothrips haemorrhoidalis), Periwinkle thrips (Ponticulothrips)
diospyrosi), Termite (Isoptera), Termite (Coptotermes formosanus), Yamato termite (Reticulitermes)
speratus), scallop (Psocoptera), scallop (Liposcelis bostrychophilus), etc.

From the order of the Orthoptera, Oxya yezoensis, Gera (Gryllotalpa sp.), Cockroach (Periplaneta)
americana), German cockroach (Blattella germanica), etc., from the order of the Acarina, Pandanchus
citri), apple spider mite (Panonychus ulmi), spider mite (Tetranychus urticae), Kanzawa spider mite (Tetranychus)
kanzawai), Japanese spider mite (Tetranychus viennensis), Japanese spider mite (Oligonychus ununguis), Miyake spider mite (Eotetranychus)
kankitus), southern spider mite (Brevipalpus phoenicis), clover spider mite (Bryobia praetiosa), citrus red tick (Aculops)
pelekassi), red mite (Eriophyes chibaensis), tulip mite (Aceria tulipae), grape ticks (Colomerus)
vitis), pink mite (Aculus fockeui), green dust mite (Calacarus carinatus), green dust mite (Polyphagotarsonemus)
latus), Robin tick (Rhizoglyphus robini), Tyrophagus putrescentiae, etc., from the order of the Tylenchida (Pylylenchus)
coffeae), Kitanegusu nematode (Pratylenchus penetrans), potato cyst nematode (Globodera)
rostochiensis), Meloidogyne incognita, etc., from the order of Dorylaimida, Longirus
sp.) and other pests such as slugs (Incilaria bilineata) from the mollusc gastropoda.

  Although the useful plant which can use the agricultural and horticultural pest control composition of the present invention is not particularly limited, for example, cereals (eg, rice, barley, wheat, rye, oats, corn, etc.), beans (soybeans) , Red beans, broad beans, green beans, green beans, peanuts, etc.), fruit trees and fruits (apples, citrus fruits, pears, strawberries, peaches, plums, cherry peaches, walnuts, chestnuts, almonds, bananas, etc.), leaves and fruit vegetables (cabbage) , Tomatoes, spinach, broccoli, lettuce, onions, green onions, peppers, eggplants, strawberries, peppers, pork etc.), root vegetables (carrots, potatoes, sweet potatoes, sweet potatoes, sweet potatoes, turnips, lotus roots, burdocks, garlics, etc.), for processing Crops (salmon, hemp, beet, hop, sugar cane, sugar beet, olive, rubber, coffee, tobacco tea, etc.), cucumbers (pumpkin, cucumber, watermelon, (Wow, melon, etc.), pastures (orchard grass, sorghum, timothy, clover, alfalfa, etc.), turf (Korean turf, bentgrass, etc.), fragrances and other crops (lavender, rosemary, thyme, parsley, pepper Ginger, etc.), flowers (flowers, roses, carnations, orchids, etc.), garden trees (Ginkgo, Sakura, Aoki, etc.), forest trees (Todomatsu, Ezo pine, pine, hiba, cedar, firewood, etc.) Can be mentioned.

The pesticide composition for agricultural and horticultural use according to the present invention is capable of generating pests in an amount effective for pest control in the form as it is, or appropriately diluted with water or suspended to control various pests. It can be used for predicted plants. For example, for pests occurring in fruit trees, cereals, vegetables, etc., in addition to spraying on the foliage, seeds immersed in chemicals, seed dressing, seeds such as calper treatment Treatment, soil all layer mixing, crop application, floor soil mixing, cell seedling treatment, planting hole treatment, plant root treatment, top dress, rice box treatment, water surface application, etc. It can also be used. In addition, it can be used for nutrient solution in nutrient solution (hydroponics) cultivation, smoke, or trunk injection. Further, for example, in addition to spraying on stored grain pests, house pests, sanitary pests, forest pests, etc., they can also be used for application to house building materials, smoke, baits and the like.
Seed treatment methods include, for example, a method in which a liquid or solid preparation is diluted or undiluted and the seed is immersed in a liquid state to infiltrate the drug, a solid preparation or liquid preparation is mixed with the seed, Examples thereof include a method of treating and adhering to the surface of the seed, a method of coating the seed by mixing with an adhesive carrier such as resin and polymer, and a method of spraying around the seed simultaneously with planting.
The “seed” for performing the seed treatment means a plant body at an early stage of cultivation used for plant propagation, for example, a seed, a bulb, a tuber, a seed bud, a stock bud, a basket, a bulb or a nutrient for cultivation of cuttings. Mention may be made of plants for breeding.

The “soil” or “cultivation carrier” of the plant when carrying out the method of use of the present invention refers to a support for cultivating crops, particularly a support for growing roots, and the material is not particularly limited. However, any material that can grow plants may be used, and so-called soil, seedling mats, water, etc. may be used. Specific materials include, for example, sand, pumice, vermiculite, diatomaceous earth, agar, gel-like substances, high It may be a molecular substance, rock wool, glass wool, wood chip, bark or the like.
As spraying methods for crop foliage, stored grain pests, house pests, hygiene pests, forest pests, etc., dilute liquid preparations such as emulsions and flowables or solid preparations such as wettable powders or granular wettable powders with water. , A method of spraying, a method of spraying powder, smoke or the like.
Examples of application methods to soil include, for example, a method in which a liquid preparation is diluted or not diluted with water and applied to a plant stock or seedling nursery, etc. A method of spraying to a nursery, etc., a method of spraying powder, wettable powder, granule wettable powder, granule, etc. before sowing or transplanting, and mixing with the whole soil, a planting hole, cropping before sowing or planting a plant body Examples thereof include a method of spraying powder, wettable powder, wettable powder, granule, etc. on the strip.

As a method for applying paddy rice to a seedling box, the dosage form may vary depending on the application time such as application at seeding, greening period, application at transplanting, etc., for example, powder, granule wettable powder, granule etc. What is necessary is just to apply with a dosage form. It can also be applied by mixing with soil, and can be mixed with soil and powder, granulated wettable powder or granules, for example, mixed with ground soil, mixed with soil, mixed into the entire soil, etc. The soil and various preparations may be applied alternately in layers.
As a method of application to paddy fields, solid preparations such as jumbo agents, packs, granules, granule wettable powders, and liquid preparations such as flowables and emulsions are usually sprayed on flooded paddy fields. In addition, at the time of rice planting, an appropriate preparation can be sprayed and injected into the soil as it is or mixed with fertilizer. In addition, by using a chemical solution such as emulsion or flowable as a source of water flowing into a paddy field such as a water inlet or an irrigation device, it can be applied in a labor-saving manner along with the supply of water.
In field crops, it can be treated to seeds or a cultivation carrier close to the plant body from sowing to raising seedling. In plants that are sown directly in a field, in addition to direct treatment on seeds, treatment on the plant source of the plant being cultivated is suitable. It is possible to perform a irrigation treatment in a liquid state using a granule or a spraying treatment or a drug diluted or not diluted in water. It is also a preferable treatment to mix the granules with the cultivation carrier before sowing and then sow.

As the seeding of the cultivated plant to be transplanted and the treatment of the seedling raising period, in addition to the direct treatment to the seed, the irrigation treatment of the liquid drug or the granule spraying treatment to the seedling nursery is preferred. In addition, it is also preferable to treat a granule in a planting hole at the time of planting or to mix it with a cultivation carrier near the transplantation site.
The agricultural and horticultural pest control composition of the present invention is formulated into conventional dosage forms, for example, emulsions, wettable powders, granular wettable powders, flowables, liquids, granules, powders, smoke smokes and the like. The dosage varies depending on the proportion of active ingredient, weather conditions, formulation, application timing, application method, application location, pests to be controlled, target crops, etc. As long as it is appropriately selected from the range of 0.1 to 1000 g, and preferably in the range of 1 to 500 g. In the treatment of seeds, it can be used as an active ingredient in a range of 0.01% to 50%, preferably in a range of 0.1% to 20%, by comparison with the seed weight. When diluting and applying emulsions, wettable powders, etc. with water etc., the application concentration is 0.00001-0.1%, and liquids, etc. when treating granules, powders or seeds are usually diluted. It can be applied as it is.

Moreover, the compound which has other insecticidal activity, acaricidal activity, or nematocidal activity can also be added to the agricultural and horticultural pest control composition of this invention. Examples of the compound include insecticides such as chloronicotinyl compounds, carbamate compounds, pyrethroid compounds, macrolide compounds, and organic phosphorus compounds. Specifically, acetamiprid (acetamiprid)
Pymetrozine, fenitrothion, acephate, carbaryl, carbaryl, methomyl, cartap, cyhalothrine, etofenprox, teflubenzuron, flufenururon Flufenoxuron, tebufenozide, fenpyroximate, pyridaben, imidacloprid, buprofezin, BPMC (fenobucarb), malathion, methithione, methithione

Diazinon, oxydeprofos, vamidion, ethiophencarbe, pirimicarb, permethrin, cypermethrin, bifenthrin, halfenprox, halfenprox Silafluofen, nitenpyram, chlorfluazuron, methoxyfenozide, tebufenpyrad, pyrimidifen, kelofol, propargite, hexhiazox Gin (clofentezine), spinosad (spinosad), milbemectin (milbemectin), BT (bacillus
thuringiensis), indoxacarb, chlorfenapyr, fipronil, etoxazole, acequinocyl, pirimiphos-methyl, acrinathrin, quinomethionate, quinomethionate, quinomethionate )
, Abamectin, emamectin benzoate, fenbutatin oxide
oxide, terbufos, ethoprophos, cadusafos, fenamiphos, fensulfothion, DSP, dichlofenthion, fosthiazate, fosthiazate, oxamylisa ), Phosthietan, isazofos, thionazin, benfuracarb, ethiofencarb, azinphos-methyl, disulfoton, methiocarb, deoxytome methyloxy
n-methyl), parathions, cyfluthrin, beta-cyfluthrin, tebupirimfos, endosulfan, amitraz, tralomethrin,

Ethiprole, etion, trichlorfon, DEP, metamidophos, dichlorvos,
DDVP), mevinphos, monocrotophos, dimethoate, formothion, mecarbam, thiometon, disulfoton, nared,
BRP), methylparathion, cyanophos, diaphos, diamidafos, albendazole, oxibendazole, fenbendazole, oxfendazole, propaphos, Sulprofos, prothiofos, profenofos, isofenphos, temephos, phenthoate, dimethylvinphos, chlorfenvinphos, tetrachlorvinphos ( tetrachlorvinphos, phoxim, isoxathion, pyraclofos, chlorpyrifos-methyl, pyridafenthion, phosalone, phosmet, dioxabenzofos, quinalphos (quinalphos), pyrethrin (py rethrins), allethrin, prallethrin, resmethrin, permethrin, tefluthrin, fenpropathrin, alpha-cypermethrin, lambda cihalothrin (lambda) -cyhalothrin), deltamethrin, fenvalerate, esfenvalerate, flucythrinate, fluvalinate, cycloprothrin, thiodicarb, aldicarb ), Alanicarb, metolcarb, xylycarb, propoxur, phenoxycarb, fenoxycarb, fenothiocarb, bifenazate, carbofuran, carbofuran, carbosulfan, carbosulfan Furathiocarb, diaph Nchiuron (diafenthiuron), diflubenzuron (diflubenzuron), hexaflumuron (hexaflumuron), novaluron (novaluron), lufenuron (lufenuron), chlorfluazuron (chlorfluazuron),

Tricyclohexyltin hydroxide (cyhexatin), sodium oleate (Oleic acid sodium salt), potassium oleate (Potassium
oleate, metoprene, hydroprene, binapacryl, amitraz, chlorbenzilate, phenisobromolate, tetradifon, bensultap, benzomate (benzomate), chromafenozide, diofenolan, tolfenpyrad, triazamate, nicotine-sulfate, thiacloprid
, Thiamethoxam, clothianidin, dinotefuran, fluazinam
, Pyriproxyfen, hydramethylnon, cyromazine, TPIC (tripropylisocyanurate), thiocyclam, fenazaquin, polynactins, azadirachtin, rotenone (rotenone), hydroxypropyl starch (hydroxy
propyl starch, mesulfenfos, phosphocarb, isoamidofos, aldoxycarb, metam-sodium, morantel tartrate
tartrate), dazomet, levamisol hydrochloride, trichlamide.

Furthermore, in order to control diseases and / or weeds that occur at the same time of use of the agricultural and horticultural pest control composition of the present invention, it is controlled by mixing with a compound having bactericidal activity or herbicidal activity. Synergistic effects can also be expected in the expansion of target pests, reduction of dosage, and herbicides.
Examples of such a compound having bactericidal activity or herbicidal activity include compounds having bactericidal activity such as azoxystrobin, diclocymet, pyroquilon, kasugamycin, IBP (iprobenfos) Hymexazol, mepronil, tricyclazole, edifenphos, isoprothiolane, blasticidin, flutolanil, diclomezine, pencicuron, pencycuron, pencycuron, pencycuron, pencycuron, pencycuron, pencycuron Carbendazim, dodine, propamocarb, pyrimemethanil, fluquinconazole, fosetyl-aluminum, fosetyl-AL, bromuconazole, triticonazole , Flumetover, fenamidon (fen amidone, tolylfluanid, dichlofluanid, trifloxystrobin, triadimenol, spiroxamine, fenhexamid, iprovalicarb, fusalide (fthalide), iprodione, thiophanate, benomyl, triflumizole, fluazinam, zineb
Captan, manzeb, fenarimol, calcium polysulfide, triadimefon, vinclozolin, dithianon, bitertanol,

Polycarbamate, iminoctadine-DBS, pebulate, polyoxin-B, propineb, quinomethionate, dichlofluanid, chlorothalonil ), Difenoconazole, fluoroimide, triforine, oxadixyl, streptomycin, mancozeb, oxolinic
acid), metalaxyl, propiconazole, hexaconazole, sulfur, pyrifenox, basic copper sulfate (basic)
copper sulfate, pyrimethalanil, iprobenfos, tolclofos-methyl, maneb, thiophanate-methyl, thifluzamide, furametpyr, fursulfamide, flusulfamide -Methyl (kresoxim-methyl), carpropamid, hydroxyioxazole, echlomezole, procymidone, vinclozolin, ipconazole, furconazole, microbutanil , Tetraconazole, tebuconazole, imibenconazole, prochloraz, pefurazoate, cyproconazole, mepanipyrim, thiadiazin, probena Examples include bactericides such as probenazole, acibenzolar-S-methyl, validamycin (-A), phenoxanil, and thiadinil.

Next, as a compound having herbicidal activity, for example, bensulfuron-methyl, azimsulfuron, cinosulfuron, cyclosulfamuron, pyrazosulfuro-ethyl, imazosulfuron ( imazosulfuron, indanofan, cyhalofop-butyl, thenylchlor, esprocarb, etobenzanid, caffenstrole, clomeprop, dimethametryn, dimethametryn daimuron), bifenox
, Piributicarb, pyriminobac-methyl, pretilachlor, bromobutide, benzofenap, benthiocarb, bentoxazone, benfuresate, mefenacet, mefenacet Fenoxaprop-P-ethyl, phenmedipham, diclofop-methyl, desmedipham, etofumesate, isoproturon, amidosulfuron ( amidosulfuron, anilofos, benfuresate, ethoxysulfuron, iodosulfuron, isoxadifen, isoxadifen, foramsulfuron, pyraclonil, mesosulfuron, mesosulfuron (diuron), neburon ), Dinoterb, carbetamide, bromoxynil, oxadiazon, dimefuron, diflufenican, aclonifen, benzofenap, oxaziclomefone, oxaziclomefone Isoxaflutole, oxadiargyl, flurtamone, metribuzin, methabenzthiazuron, tribufos, metamitron, ethiozin, flufenaset flufenacet),

Sulcotrion, fentrazamide, propoxycarbazone, flucarbazone, metosulam, amicarbazone
, Glyphosate-isopropyl amine, glyphosate-trimesium, glufosinate-ammonium, bialaphos
, Butamifos, prosulfocarb, asuram, linuron, calcium peroxide
peroxide), alachlor, pendimethalin, acifluofen-sodium, lactofen, ioxynil-octanoate, alloxydim, sethoxydim, napropamide ), Pyrazolate, pyraflufen-ethyl, imazapyr, sulfentrazone, oxadiazon, paraquat, diquat, simazine, Mention may be made of herbicides of atrazine, fluthiacet-methyl, quizalofop-ethyl, bentazone, triaziflam, isouron. It can also be used by mixing with thidiazuron, mefenpyr, ethephon, cyclanilide and the like having a plant growth regulating action.

Furthermore, the present invention relates to nuclear polyhedrosis virus (NPV), granulosis virus (GV).
, Cytoplasmic polyhedrosis virus (CPV), virus preparations such as insect poxvirus (Entomopox virus, EPV), Monocrosporium fimatopagum (Monacrosporium)
phymatophagum), Steinernema carpocapsae, Steinernema carpocapsae
kushidai), Pasturia penetrans, Trichoderma lignorum, Agrobacterium radiobacter (Agrobacterium)
radiobactor), non-pathogenic Erwinia carotovora, Bacillus subtilis, Xanthomonas
campestris), microbial pesticides such as Beauveria brongniartii, Encarsia
formosa), Aphidius colemani, Aphidoletes aphidimyza, Diglyphus
isaea), Hyacinthus sibirica, Phytoseiulus persimilis, Amblyseius
cucumeris), natural enemy organisms such as Orius sauteri, (Z) -10-tetradecenyl acetate, (E, Z) -4,10-tetradecadinyl acetate, (Z) -8-dodecenyl = Acetate, (Z) -11-
It can also be used in combination with pheromone agents such as tetradecenyl acetate, (Z) -13-icosen-10-one, (Z) -13-icosen-10-one, 14-methyl-1-octadecene.

  Although the typical Example and test example of this invention are illustrated below, this invention is not limited to these. In the examples, “parts” means “mass parts”.

Example 1.
Flubendiamide 1 part Thiosultap monosodium salt 16 parts Hydrous silicic acid 30 parts Hytenol M08 (Daiichi Kogyo Seiyaku Co., Ltd.) 5 parts Lignin sulfonate 3 parts Wettable clay 45 parts After impregnating the active compound with hydrous silicic acid, etc. To obtain a wettable powder.

Example 2
Flubendiamide 1 part Thiosulfapto monosodium salt 16 parts Clay powder 68 parts Diatomaceous earth powder 15 parts The above is mixed and ground uniformly to form a powder.

Example 3
Flubendiamide 1 part Thiosultapto disodium salt
16 parts Bentonite / clay mixed powder 78 parts calcium lignin sulfonate 5 parts The above is uniformly mixed, kneaded with an appropriate amount of water, granulated and dried to give granules.

Test Example 1 Control effect against Nikameichu 2 egg masses (100 eggs) were inoculated into the rice leaf sheath. Three days after the inoculation, 400 L / ha equivalent of a chemical solution prepared by adjusting the chemical produced in Example 1 to a predetermined concentration was sprayed on the prototype. 17 days after spraying, the number of discolored stems was investigated, and the control value (%) was calculated according to Formula-1.
Formula 1
Control ratio (%) = untreated discolored stem ratio (%) − treated section discolored stem ratio (%) / untreated discolored stem ratio (%)

Table 1

  From the results in Table 1, it has been clarified that when fulvendiamide and thiosultap are used alone, an excellent effect is exhibited by the combined use.

Claims (6)

Agricultural and horticultural harm characterized by containing fulvendiamide and one or more compounds selected from compounds having insecticidal activity, acaricidal activity and / or nematocidal activity as active ingredients Biocontrol agent composition.   Compounds having insecticidal activity, acaricidal activity and / or nematicidal activity are bistrifluron, acetoprole, fluphenerim, noviflumuron, gamma-cyhalothrin Flonicamid, pyridalyl, thiosultap, methoflutrin, profluthrin, dimethrutrine, rapimetrol, lepimetrol, lepimetrol Spinetoram, chlorantraniprole, pyrifluquinazone, cyantraniliprole, sulfoxafluor, alpha-endsulfan, alpha-endulphane A pesticide composition for agricultural and horticultural use according to claim 1, which is one or more compounds selected from difluvidazine, cyflumetofen and cyenopyrafen, The agricultural and horticultural pest control composition according to claim 1, wherein the compound having insecticidal activity, acaricidal activity and / or nematocidal activity is thiosultap and / or a salt thereof.   The pesticide composition for agricultural and horticultural use according to claim 1, wherein the salt of thiosultap is thiosultap-monosodium or thiosultap-monosodium.   The pesticide for agricultural and horticultural use according to any one of claims 1 to 3, wherein thiosultap or a salt thereof is in a ratio of 0.05 to 2000 parts by mass with respect to 1 part by mass of fulbendamide. Composition.   In order to protect useful plants from pests, an effective amount of the agricultural and horticultural pest control composition according to any one of claims 1 to 5 is applied to target pests, target useful plants, seeds of target useful plants, A method of using a pest control composition for agricultural and horticultural use, characterized by being treated with soil or a cultivation carrier.