CN104855399B - A kind of Pesticidal combination containing butene-fipronil and fluorobenzene insect amide - Google Patents
A kind of Pesticidal combination containing butene-fipronil and fluorobenzene insect amide Download PDFInfo
- Publication number
- CN104855399B CN104855399B CN201510224522.4A CN201510224522A CN104855399B CN 104855399 B CN104855399 B CN 104855399B CN 201510224522 A CN201510224522 A CN 201510224522A CN 104855399 B CN104855399 B CN 104855399B
- Authority
- CN
- China
- Prior art keywords
- fipronil
- insect amide
- butene
- fluorobenzene insect
- pesticidal combination
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of Pesticidal combinations containing butene-fipronil and fluorobenzene insect amide, and including usual auxiliaries, butene-fipronil and fluorobenzene insect amide, the ratio of weight and number of butene-fipronil and fluorobenzene insect amide is 1：5‑5：1, the weight percent of butene-fipronil and fluorobenzene insect amide weight summation in Pesticidal combination is 1% 80%；The present invention is applied to prevention rice-stem borer, rice leaf roller, and the present invention is superior to single dose, and reduce the dosage of pesticide in terms of quick-acting and lasting effect, reduces drug cost, be conducive to environmental protection and the comprehensive treatment of agricultural pests.
Description
Technical field
The present invention relates to agricultural insecticide composition and its application fields, and specifically one kind is with butene-fipronil and fluorobenzene
Insect amide is the Pesticidal combination of active ingredient, applied to prevention rice-stem borer and rice leaf roller.
Background technology
Butene-fipronil, English name：Flufiprole, butene-fipronil are a kind of Phenylpyrazole insecticides, desinsection
Spectrum is wide, to pest based on stomach poison function, has concurrently and tags and certain systemic action, mechanism of action be to hinder insect γ-
The chloride metabolism of aminobutyric acid control, it is efficient to various pests such as the snout moth's larva of rice, snout moth's larva, vegetables lepidoptera pests.
Fluorobenzene insect amide, English name：Flubendiamide, fluorobenzene insect amide belong to novel phthalic diamides and kill
Worm agent by activating ryanodine receptor calcium release channel, leads to the runaway release of calcium ion of storage, pest twitch is dead
It dies, good activity is respectively provided with to almost all of Lepidoptera class pest, not only there is excellent activity to adult and larva, and
And work fast, lasting period are long.
The snout moth's larva of rice belongs to lepidoptera pest, mainly based on striped rice borer and rice leaf roller harm.Striped rice borer is in rice
Tillering stage harm causes the withered sheath of rice, withered heart seedling, and insect bite strain and dead ears are caused in rice earing stage harm.Rice leaf roller is with larva
Cause harm rice, sew leaf into vertical bud, hide wherein feeding epicuticle and mesophyll are only left white color lower epidermis.Seedling stage aggrieved influence rice
Normal growth or even withered；Tillering stage to the jointing stage is aggrieved, and tiller is reduced, and plant shortens, and breeding time postpones；After booting especially
It is that heading is killed to full heading time sword-like leave, influences to blossom and bear fruit, Empty grain rate improves, and mass of 1000 kernel declines.
Different pesticide species ingredients are compounded, and are the common methods of the agriculture resistant insect of prevention.The present inventor is a large amount of
Indoor virulence and field medicine effect test on the basis of, the screening of the compounded formula of butene-fipronil and fluorobenzene insect amide is carried out
Further investigation, it is found that butene-fipronil and fluorobenzene insect amide are compounded, and has apparent collaboration in a certain proportion
Synergistic effect, and there is outstanding control effect to the snout moth's larva of rice, after further study, complete the present invention.
Invention content
The technical problem to be solved by the present invention is to provide it is a kind of efficiently, low toxicity and the lasting period it is long, can effectively prevent crops squama
Wing mesh class pest is conducive to the Pesticidal combination containing butene-fipronil and fluorobenzene insect amide of integrated pest management.
To solve the above problems, the technical solution adopted in the present invention is：One kind contains butene-fipronil and fluorobenzene worm acyl
The Pesticidal combination of amine, including usual auxiliaries, butene-fipronil and fluorobenzene insect amide, the weight of butene-fipronil and fluorobenzene insect amide
It is 1 to measure portion rate：5-5：1, the weight percent of butene-fipronil and fluorobenzene insect amide weight summation in Pesticidal combination is
1%-80%.
Preferably, the weight percent of butene-fipronil and fluorobenzene insect amide weight summation in Pesticidal combination is 10-
60%.
The Pesticidal combination can be configured to suspending agent, water-dispersible grain according to well known to a person skilled in the art methods
The application forms of the suitable agricultural use such as agent, aqueous emulsion, microemulsion, wettable powder.
For the Pesticidal combination also containing the usual auxiliaries prepared needed for pesticidal preparations, usual auxiliaries are solvent, emulsification
One or more of agent, wetting agent, stabilizer, dispersant, thickener, pH adjusting agent, antifoaming agent, antifreezing agent, packing agent etc.
Mixing, be known substance, be common various auxiliary agents in pesticidal preparations, can be varied from, had no according to different situations
It is particularly limited to.
The application of the Pesticidal combination, it is main to prevent rice-stem borer and cnaphalocrocis for preventing crop pests
Snout moth's larva.
Pesticidal combination provided by the invention, is generally used by spray method, can also be as needed using agricultural
Other of upper application use technology.
Compared with prior art, the advantage of the invention is that：
1st, butene-fipronil and fluorobenzene insect amide compounding have unexpected synergistic function, are used alone than single dose
Improve the control effect to pest and germ；
2nd, butene-fipronil and the fluorobenzene insect amide mechanism of action are different, mixed pest and the germ drug resistance of can delaying
It generates；
3rd, two kinds of active ingredient compoundings of butene-fipronil and fluorobenzene insect amide, reduce Pesticide use amount, reduce use
Cost and alleviate the pollution to environment.
Specific embodiment
To better understand the essence of the present invention, present disclosure is described further with reference to embodiment,
But limitation of the present invention cannot be considered as, the content mentioned in embodiment is not limitation of the invention, and material prescription selects
Can adaptation to local conditions and to result without substantive influence.In these embodiments, unless otherwise stated, all percentages are attached most importance to
Measure percentage.
Example of formulations 1：The Pesticidal combination is suspending agent, and each component percentage composition is respectively：
Concrete operation step is：First other auxiliary agents are mixed, shear-mixed is uniform in cutter, then add in effectively into
Point, 2-3h is ground in ball crusher, makes a diameter in 5mm hereinafter, can be prepared by Pesticidal combination aqueous suspension formulations of the present invention.
Example of formulations 2：The Pesticidal combination is aqueous emulsion, and each component percentage composition is respectively：
Concrete operation step is：First active ingredient, solvent, emulsifier are mixed, dissolving becomes uniform oil phase.
Part water and other auxiliary agents are mixed again, dissolving becomes uniform water phase.Then high-speed stirred in a kettle is same
When oil phase added in into water phase, slowly add water to and reach phase inversion point, carry out high speed shear later, and add in remaining water, shearing is about
30min, you can Pesticidal combination water and milk agent formulation of the present invention is made.
Example of formulations 3：The Pesticidal combination is microemulsion, and each component percentage composition is respectively：
Concrete operation step is：Active ingredient with solvent and cosolvent is completely dissolved, then adds other auxiliary agents, is mixed
It closes uniformly, water is eventually adding, after being sufficiently stirred, you can Pesticidal combination microemulsion formulation of the present invention is made.
Example of formulations 4：The Pesticidal combination is wettable powder, and each component percentage composition is respectively：
Concrete operation step is：Active ingredient, other auxiliary agents and filler are mixed, are sufficiently stirred in stirred tank, is passed through
Airslide disintegrating mill is uniformly mixed after crushing, you can Pesticidal combination wettable powder formulation of the present invention is made.
Example of formulations 5：The Pesticidal combination is water dispersible granules, and each component percentage composition is respectively：
Concrete operation step is：Active ingredient, other auxiliary agents and filler are uniformly mixed, with micro jet powder
It is broken, it is added in fluidized-bed granulation dryer after kneading after being granulated, drying, sieve, you can obtained Insecticidal combinations of the present invention
Object water-dispersible grain agent formulation.
Auxiliary agent is selected from as described below in more than dosage form：
Solvent can be trimethylbenzene, durene, methyl naphthalene, methyl oleate, fatty acid methyl ester, loose base oil, soybean oil, biology
Diesel oil, sec-Butyl Acetate, dimethyl carbonate, diesel oil, white oil, machine oil, etc. one or more of.
Emulsifier can be that calcium dodecyl benzene sulfonate, fatty alcohol polyoxyethylene ether, triphenoethyl benzene phenol polyoxypropylene gather
Ethylene oxide block polymer, dibenzyl xenyl polyoxyethylene ether, phenethyl phenol polyethenoxy ether, castor oil polyoxyethylene ether,
Phenethyl phenol formaldehyde resin polyoxyethylene ether, phenethyl phenol polyoxyethylene polyoxypropylene ether, alkylaryl polyoxypropylene polyoxy
Vinethene, phenethyl phenol formaldehyde resin polyoxyethylene ether, Sorbitan aliphatic ester, sorbitan fatty acid ester polyoxy second
In alkene ether, natural fatty alcohol and ethylene oxide adduct, aliphatic acid and ethylene oxide condensate, polyoxyethylene fatty acid ester etc.
It is one or more of.
Wetting agent can be sodium butylnaphthalenesulfonate, lauryl sodium sulfate, aliphatic alcohol polyethenoxy (6-7) ether, sulfonation amber
One or more of amber dioctyl phthalate sodium salt, Morwet EFW, alkylnaphthalene sulfonate etc..
Disintegrant can be one in sodium bicarbonate, magnesium chloride, aluminium chloride, sodium chloride, urea, ammonium sulfate, bentonite etc.
Kind is several.
Dispersant can be the formaldehyde condensation products of methyl naphthalene sulfonic acid sodium, sodium lignin sulfonate, calcium lignosulfonate, to methoxy
Base fatty acyl anilinesulfonic acid, desugar and the sodium lignin sulfonate being classified, naphthalene sulfonic acid condensate sodium salt, alkyl naphthalene sulfonic acid condensation polymer
One or more of sodium salt, APES formaldehyde condensation product sulfuric acid etc..
Thickener can be one or more of xanthans, aluminium-magnesium silicate, bentonite, white carbon etc..
PH adjusting agent can be in ammonium hydroxide, potassium hydroxide, sodium hydroxide, hydrochloric acid, acetic acid, citric acid, phosphoric acid etc.
It is one or more of.
Stabilizer can be epoxidized soybean oil, epoxychloropropane, butylated hydroxy anisole, dibutyl hydroxy toluene, not eat
One or more of sub- propyl propionate, tert-butylhydroquinone etc..
Antifoaming agent can be one or more of silicone compound, methanol, silicone oil etc..
Antifreezing agent can be one or more of in glycerine, ethylene glycol, propylene glycol, sorbierite, polyethylene glycol etc..
Carrier can be kaolin, diatomite, bentonite, white carbon, precipitated calcium carbonate, attapulgite, clay, talcum
One or more of powder, quartz sand, starch, alkyl polyglycoside etc..
Assays Example 1：Butene-fipronil and fluorobenzene insect amide try the indoor joint toxicity measuring of the snout moth's larva of rice
It tests.
Test medicine uses 96% butene-fipronil active compound and 96% fluorobenzene insect amide active compound.
Snout moth's larva system picks up from Huizhou Zhong Kai areas Shi Zhen villages snout moth's larva and serious rice terrace occurs.
With reference to the rice-stem dipping method of the quasi- NY/T1154.11-2008 of raw mark, 15 plants of two leaves, one core rice seedling is chosen, for trying
After being impregnated 30 seconds in liquid, naturally dry is taken out, encasing root with wet absorbent cotton keeps the temperature, and outsourcing preservative film is placed in glass (Φ
200 × 30mm) in, per 4 repetitions of concentration.Then access snout moth's larva 3 age nymph with ether light anesthesia with writing brush, often pipe 20 ±
2, nozzle is tightened with white gauze.It is disposed, is placed in observation ward.Test worm death condition is checked after 72h, and is recorded,
Gently to be contacted with writing brush, test worm is reactionless to be calculated as death to test worm death criterion.
It is for statistical analysis with DPS statistical analysis softwares, by the LC for calculating each medicament50It lives to evaluate the desinsection of each medicament
Property, and according to the co-toxicity coefficient (CTC values) of the abundant method calculating mixtures of Sun Yun.
Survey toxicity index (ATI)=(standard agent LC50/ reagent agent LC50)×100。
Percentage composition+B the medicament toxicity index of A in theoretical toxicity index (TTI)=A medicament toxicity index × mixture × mixed
The percentage composition of B in agent.
Co-toxicity coefficient (CTC)=[mixture actual measurement toxicity index (ATI)/mixture theoretical toxicity index (TTI)] × 100.
The criteria for classifying is acted on according to NY/T11547.7-2006 insecticide combinations：Co-toxicity coefficient (CTC) >=120 is shown as
Synergistic effect；Co-toxicity coefficient (CTC)≤80 shows as antagonism；80 ＜ co-toxicity coefficients (CTC) ＜ 120, which show as being added, to be made
With.
As can be seen from Table 1 and Table 2, butene-fipronil and fluorobenzene insect amide are 1:5~5:When being compounded in the range of 1, altogether
Malicious coefficient (CTC) is all higher than 120, and synergistic function is shown to rice-stem borer and rice leaf roller.It can be seen that butylene fluorine
Worm nitrile and fluorobenzene insect amide compounding have reasonability and feasibility.
Table 1, butene-fipronil and fluorobenzene insect amide are to the indoor joint toxicity measuring result of striped rice borer
Table 2, butene-fipronil and fluorobenzene insect amide are to the indoor joint toxicity measuring result of rice leaf roller
Assays Example 2：Butene-fipronil and fluorobenzene insect amide compound the field control effectiveness test to the snout moth's larva of rice.
Striped rice borer test site is located at Huizhou rice terrace.Peak period dispenser is endangered in striped rice borer, using spraying
Method.Using 5% butene-fipronil missible oil, 10% fluorobenzene insect amide suspending agent as comparison medicament, experiment is set altogether at 7 medicaments
Reason each handles 3 repetitions.The cornerwise five points investigation rice withered heart rate in area is throughout managed before dispenser, investigate 30 plants at every
Rice.3 days after dispenser, respectively control effect of investigation, record withered heart rate calculate control effect, result of the test is such as within 7 days, 14 days
Shown in table 3.
The result of the test of table 3, butene-fipronil and fluorobenzene insect amide mixture prevention rice-stem borer
Butene-fipronil is intended to the preventive effect of striped rice borer after compounding 3d, 7d, 14d with fluorobenzene insect amide as can be seen from Table 3
It is apparently higher than 5% butene-fipronil missible oil single dose of the same period to use using with 10% fluorobenzene insect amide suspending agent single dose, illustrates butylene
Ethiprole and fluorobenzene insect amide compounding can improve the preventive effect to striped rice borer compared with two kinds of single doses are used alone, while after medicine
14d preventive effects still up to more than 80%, illustrate there is good lasting effect, do not find that the compound drug generates medicine to rice during experiment
Evil.
Rice leaf roller test site is located at Huizhou rice terrace.Peak period dispenser is endangered in rice leaf roller,
Using spray-on process.Using 5% butene-fipronil missible oil, 10% fluorobenzene insect amide suspending agent as comparison medicament, experiment sets 7 altogether
Chemicals treatment each handles 3 repetitions.The cornerwise five points investigation rice leaf roll rate in area, every tune are throughout managed before dispenser
Look into 30 plants of rice.3 days after dispenser, respectively control effect of investigation, record leaf roll rate calculate control effect, experiment within 7 days, 14 days
The results are shown in Table 4.
The result of the test of table 4, butene-fipronil and fluorobenzene insect amide mixture prevention paddy rice rice leaf roller
As can be seen from Table 4 to the preventive effect of rice leaf roller after butene-fipronil and fluorobenzene insect amide compounding 3d, 7d, 14d
It is intended to be apparently higher than that 5% butene-fipronil EC single doses of the same period use and 10% fluorobenzene insect amide SC single doses use, illustrates butylene fluorine
Worm nitrile and fluorobenzene insect amide compounding can improve the preventive effect to rice leaf roller compared with two kinds of single doses are used alone, while after medicine
14d preventive effects still up to more than 80%, illustrate there is good lasting effect, do not find that the compound drug generates medicine to rice during experiment
Evil.
Assays Example 3：Snout moth's larva tests the drug resistance indoor measurement of butene-fipronil fluorobenzene insect amide.
Worm sources are acquired from Huizhou.The 50%-90% lethal doses for a concentration of snout moth's larva of rice that test medicine uses,
Butene-fipronil, fluorobenzene insect amide active compound are configured to test required test medicine.Experiment is and above-mentioned using cane infusion process
The method of toxicity test is consistent.Dead test worm is rejected after 72 hours, the test worm continuation left is raised indoors, is so located repeatedly
Manage 20 generation test worms.If the liquid processing containing only auxiliary agent is blank control.Each medicament is measured to 1st generation, the 5th generation, the 10th generation and
The half lethal concentration LC of 20 generation test worms50, by comparing each treatment agent to 1st generation, the 5th generation, the 10th generation and the 20th generation test worm
LC50The drug resistance of reagent agent is changed to evaluate test worm.
According to table 5, table 6 as can be seen that after butene-fipronil and fluorobenzene insect amide complex preparation 20 generation test worms of processing, test worm
Population handles what 20 generation test worms generated to the drug resistance of the complex preparation significantly lower than butene-fipronil and fluorobenzene insect amide single dose
Drug resistance.This experiments have shown that, butene-fipronil and fluorobenzene insect amide compounding effectively the snout moth's larva of rice can be delayed to develop immunity to drugs.
Table 5, butene-fipronil and fluorobenzene insect amide compounding are to the measure result of the test of striped rice borer drug resistance
Note：Above table medium multiple represents drug resistance of the corresponding algebraically striped rice borer to each medicament.
Table 6, butene-fipronil and fluorobenzene insect amide compounding are to the measure result of the test of rice leaf roller drug resistance
Note：Above table medium multiple represents drug resistance of the corresponding algebraically rice leaf roller to each medicament.
In conclusion the present invention uses two kinds of active components as butene-fipronil and the complex composition of fluorobenzene insect amide,
Compared with existing single formulation, not only with apparent synergistic effect, also with good insecticidal effect, the lasting period is long, right
Crop securify can slow down the generation of pest resistance to insecticide, be worth promoting and applying in agricultural production.
Claims (4)
1. a kind of Pesticidal combination containing butene-fipronil and fluorobenzene insect amide, including usual auxiliaries, butene-fipronil and fluorine
Benzene insect amide, it is characterised in that：Butene-fipronil and the ratio of weight and number of fluorobenzene insect amide are 1：5-5：1, butene-fipronil and
Weight percent of the fluorobenzene insect amide weight summation in Pesticidal combination is 1%-80%.
2. a kind of Pesticidal combination containing butene-fipronil and fluorobenzene insect amide according to claim 1, feature exist
In：The dosage form of the Pesticidal combination is one kind in suspending agent, water dispersible granules, aqueous emulsion, microemulsion, wettable powder.
3. a kind of a kind of Pesticidal combination containing butene-fipronil and fluorobenzene insect amide according to claim 1 is being prevented
Application in crop pests.
4. a kind of Pesticidal combination containing butene-fipronil and fluorobenzene insect amide according to claim 3 is in prevention farming
Application in object pest, it is characterised in that：The crop pests are rice-stem borer, rice leaf roller.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510224522.4A CN104855399B (en) | 2015-05-02 | 2015-05-02 | A kind of Pesticidal combination containing butene-fipronil and fluorobenzene insect amide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510224522.4A CN104855399B (en) | 2015-05-02 | 2015-05-02 | A kind of Pesticidal combination containing butene-fipronil and fluorobenzene insect amide |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104855399A CN104855399A (en) | 2015-08-26 |
| CN104855399B true CN104855399B (en) | 2018-06-19 |
Family
ID=53901929
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510224522.4A Active CN104855399B (en) | 2015-05-02 | 2015-05-02 | A kind of Pesticidal combination containing butene-fipronil and fluorobenzene insect amide |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104855399B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107372546A (en) * | 2017-06-30 | 2017-11-24 | 江苏省绿盾植保农药实验有限公司 | A kind of rice seed treating agent containing bromine cyanogen insect amide and butene-fipronil and its application |
| CN113197208A (en) * | 2021-05-11 | 2021-08-03 | 安徽丰乐农化有限责任公司 | Insecticidal composition containing flubendiamide and acetoprole and application thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1006107A2 (en) * | 1998-11-30 | 2000-06-07 | Nihon Nohyaku Co., Ltd. | Phthalamide derivatives, or salt thereof agrohorticultural insecticide, and method for using the same |
| CN1398515A (en) * | 2002-07-30 | 2003-02-26 | 王正权 | N-phenyl pyrazole derivative pesticide |
| CN102302022A (en) * | 2011-07-19 | 2012-01-04 | 北京燕化永乐农药有限公司 | Insecticidal composition |
| CN102791128A (en) * | 2010-02-17 | 2012-11-21 | 日本农药株式会社 | Noxious organism control agent composition for agricultural and horticultural applications, and use thereof |
-
2015
- 2015-05-02 CN CN201510224522.4A patent/CN104855399B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1006107A2 (en) * | 1998-11-30 | 2000-06-07 | Nihon Nohyaku Co., Ltd. | Phthalamide derivatives, or salt thereof agrohorticultural insecticide, and method for using the same |
| CN1398515A (en) * | 2002-07-30 | 2003-02-26 | 王正权 | N-phenyl pyrazole derivative pesticide |
| CN102791128A (en) * | 2010-02-17 | 2012-11-21 | 日本农药株式会社 | Noxious organism control agent composition for agricultural and horticultural applications, and use thereof |
| CN102302022A (en) * | 2011-07-19 | 2012-01-04 | 北京燕化永乐农药有限公司 | Insecticidal composition |
Non-Patent Citations (1)
| Title |
|---|
| 新颖杀虫剂-丁烯氟虫腈;大连瑞泽农药股份有限公司;《世界农药》;20051231;第27卷(第5期);第49页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104855399A (en) | 2015-08-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104824017B (en) | A kind of composition pesticide containing fosthiazate and betacyfluthrin | |
| CN103141503A (en) | Dinotefuran/Spirotetramat compound insecticidal composition | |
| CN103283762B (en) | A kind of composition pesticide containing Prochloraz | |
| CN104855399B (en) | A kind of Pesticidal combination containing butene-fipronil and fluorobenzene insect amide | |
| CN102805102B (en) | Disinsection combination containing fosthiazate and ryanodine receptor inhibitor insecticide | |
| CN107494571A (en) | Efficient insecticidal composition containing capillary and lufenuron | |
| CN103651563A (en) | Sterilization insecticidal combination containing brassinolide | |
| CN104814031B (en) | A kind of Pesticidal combination containing butene-fipronil and clothianidin | |
| CN102428922A (en) | Diacylhydrazine pesticide compounded pesticidal composition | |
| CN109042715A (en) | One kind is containing double third ring worm esters and four chlorantraniliprole compositions | |
| CN104839171B (en) | Herbicidal combinations containing three azole amides and Oxyfluorfen | |
| CN110115268A (en) | A kind of composition pesticide containing Tolfenpyrad and fluopyram | |
| CN101690493A (en) | Pesticide composition of thiamethoxam and application thereof | |
| CN106376571B (en) | A kind of Pesticidal combination containing Celastrus angulatus and Rynaxypyr | |
| CN104472489A (en) | Insecticidal composition containing pyridalyl and cyhalodiamide | |
| CN104855404B (en) | A kind of Pesticidal combination containing four chlorantraniliproles and diafenthiuron | |
| CN104255735A (en) | Pyridalyl and tetra-chlorantraniliprole compounded insecticidal composition | |
| CN104351238A (en) | Pesticide composition containing picoxystrobin and pyrethroids, preparation and application thereof | |
| CN103704258B (en) | A kind of Fungicidal insecticidal composition containing abietic acid ketone | |
| CN109221154A (en) | A kind of Pesticidal combination containing Tolfenpyrad and d-phenothrin | |
| CN102771512B (en) | Insecticidal composition containing fosthiazate and pyridaben | |
| CN107372547A (en) | A kind of Pesticidal combination containing butene-fipronil | |
| CN109392928A (en) | A kind of Pesticidal combination containing emamectin benzoate Yu second azoles mite nitrile | |
| CN104814023B (en) | A kind of Pesticidal combination containing four chlorantraniliproles and flubenzuron | |
| CN105724424B (en) | A kind of composition pesticide containing Tolfenpyrad and phosmet |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |