CN104255735A - Pyridalyl and tetra-chlorantraniliprole compounded insecticidal composition - Google Patents
Pyridalyl and tetra-chlorantraniliprole compounded insecticidal composition Download PDFInfo
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- CN104255735A CN104255735A CN201410482297.XA CN201410482297A CN104255735A CN 104255735 A CN104255735 A CN 104255735A CN 201410482297 A CN201410482297 A CN 201410482297A CN 104255735 A CN104255735 A CN 104255735A
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- pyridalyl
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Abstract
The invention discloses a pyridalyl and tetra-chlorantraniliprole compounded insecticidal composition which belongs to the technical field of combination of pesticides and is used for solving the problem that insect resistance is easily resulted from chemical insecticides. Effective components of the insecticidal composition comprise pyridalyl and tetra-chlorantraniliprole with the weight ratio of 3:1 to 1:4. The compounded insecticidal composition disclosed by the invention has an obvious synergetic effect, a long drug effect lasting period and a small dosage of the effective components in a field, is safe for human and live stocks and good in environmental compatibility, is good for delaying generation of pest resistance to insecticides due to addition of functional points, and is particularly suitable for preventing and treating lepidoptera pests on vegetables and fruits, such as plutella xylostella and beet armyworm, rice-stem borer and other injurious insects, the product and use costs are lowered, and the insecticidal spectrum is enlarged.
Description
Technical field
The invention belongs to technical field of pesticide combination, specifically, relate to a kind of pyridalyl and four chlorantraniliprole complex insecticidal compositions.
Background technology
Four chlorantraniliproles take Rynaxypyr as the novel anthranilamides that lead compound is developed, belong to ryanodine receptor activator insecticides, be combined by ryanodine receptor in pest body, open calcium channel, make to be stored in intracellular calcium ion sustained release in sarcoplasm, calcium ion and sarcoplasm mesostroma protein combination, cause muscle contracts last.Insect bodies Symptoms is tic, food refusal, finally dead.Four chlorantraniliproles are low toxicity broad spectrum pesticide, all have good activity to lepidoptera pest, as rice leaf roller, and beet armyworm etc.
Pyridalyl (pyridalyl) fluoroform pyrrole ether is the novel dichloropropylene ethers insecticide containing pyridine groups developed by SUMITOMO CHEMICAL KCC.Be mainly used in the lepidoptera pest larva preventing and treating damage to crops, to thrips thrips, diptera leaf miner, also there is good preventive effect in addition.Remarkable insecticidal activity is had to the many lepidoptera pests on vegetables, cotton and fruit tree.Pyridalyl belongs to propylene halide insecticides, is different from the insecticide of other any types existing, has remarkable active to the lepidoptera pest that vegetables and cotton extensively exist.Meanwhile, it is less on many useful arthropods impacts.This compound also shows high insecticidal activity to the sensitive strain of diamond-back moth and resistant strain.
In the real process of agricultural production, using chemical agent is the most effective means of control plant pest, but is the generation of pest resistance to insecticide by the problem that chemical control insect the most easily produces.And use single chemical insecticide continuously for a long time high dose, composite or the mixture of the rational chemical insecticides of series of problems such as residual, the environmental pollution of medicament is easily caused to have expansion insecticidal spectrum, improve control efficiency, extend the optimum period for applying fertilizer, reduce dosage, reduce poisoning, reduce and remain, delay positive feature such as pest resistance and drug-fast generation and development etc., the composite or mixture of insecticidal/acaricidal agent is one of the effective method the most solved the problem.Develop new product insecticide price constantly rises, and by contrast, exploitation is efficient with research, low toxicity, low-residual composite and mixture has small investment, the lead time is short and be subject to domestic and international attention, numerous and confused increasing develops dynamics.
Summary of the invention
For solving the problem, the invention provides a kind of complex insecticidal composition containing pyridalyl and four chlorantraniliproles of efficient, low toxicity.
Pyridalyl of the present invention and four chlorantraniliprole complex insecticidal compositions, active ingredient comprises pyridalyl and four chlorantraniliproles, and its weight ratio is pyridalyl: four chlorantraniliproles=3:1 ~ 1:4.
Preferably, the weight ratio of pyridalyl and four chlorantraniliproles is 1:1.
Further, the weight percentage of active ingredient in complex insecticidal composition is 1 ~ 80%, preferably 5 ~ 60%.
Further, described complex insecticidal composition also comprises pesticidal preparations auxiliary element, and described preparation auxiliary element comprises carrier and auxiliary agent.Carrier comprises the one, two or three in water, solvent or filler, the preferred deionized water of water; Auxiliary agent comprises surfactant, antifreezing agent, thickener, stabilizing agent, disintegrant or defoamer.
The formulation of described complex insecticidal composition is aqueous suspension agent, oil-suspending agent, aqueous emulsion, wetting powder or water dispersible granules.
Described solvent is selected from the mixture of one or more compositions in DMF, cyclohexanone, toluene, dimethylbenzene, dimethyl sulfoxide (DMSO), methyl alcohol, ethanol, trimethylcyclohexanone, NOP, monoethanolamine, triethanolamine, isopropylamine, 1-METHYLPYRROLIDONE, propyl alcohol, butanols, ethylene glycol, diethylene glycol, ethylene glycol monomethyl ether, butyl ether, monoethanolamine, isopropylamine, ethyl acetate or acetonitrile.
Described filler is selected from the mixture of one or more compositions in kaolin, diatomite, bentonite, attapulgite, white carbon, starch or precipitated calcium carbonate.
Described auxiliary agent at least comprises a kind of surfactant, according to different use occasions and demand, also can add other functional aids such as antifreezing agent, thickener, stabilizing agent, disintegrant, defoamer.
Described surfactant be selected from emulsifier, dispersant, wetting agent or bleeding agent one or more.Above-mentioned surfactant is single dose or the complex preparation of common non-ionic surface active agent or anion surfactant.
Other functional aids described to be selected from antifreezing agent, thickener, stabilizing agent, disintegrant or defoamer one or more.
Described emulsifier is selected from OP series phosphate (thermally coupled distillation columns), 600# phosphate (phenyl phenol polyoxyethylene ether phosphate), styrene polyoxyethylene ether ammonium sulfate salt, alkyl biphenyl ether disulfonic acid magnesium salts, triethanolamine salt, agriculture breast 400# (benzyl dimethyl phenol polyoxyethyl ether), Nongru-700 # (alkylphenol-formaldehyde resin polyoxyethyl ether), peaceful newborn 36# (phenethyl fluosite polyoxyethyl ether), agriculture breast 1600# (phenethyl phenol polyoxyethanyl polypropylene-base ether), ethylene oxide-propylene oxide block copolymer, OP series (polyoxyethylene nonylphenol ether), BY series (castor oil polyoxyethylene ether), agriculture breast 33# (alkylaryl polyoxyethylene poly-oxygen propylene aether), Span series (sorbitol anhydride monostearate), mixtures of one or more compositions in TWEEN Series (anhydrous sorbitol fat acid ester polyoxyethylene ether) or AEO series (fatty alcohol-polyoxyethylene ether).
Described dispersant is selected from the mixture of one or more compositions in polycarboxylate, lignosulfonates, alkylphenol polyoxyethylene formaldehyde condensation products sulphate, alkyl benzene calcium sulfonate, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol polyoxyethylene, aliphatic amine polyoxyethylene ether, aliphatic acid polyethenoxy ether or fatty acid glyceride APEO.
Described wetting agent is selected from the mixture of one or more compositions in lauryl sodium sulfate, neopelex, Nekal BX, wetting and penetrating agent F, spaonin powder, silkworm excrement or soapberry powder.
Described bleeding agent is selected from the mixture of one or more compositions in penetrating agent JFC (fatty alcohol-polyoxyethylene ether), penetrant t (Maleic Acid Diisooctyl sulfonate), azone or organosilicon.
Described thickener is selected from the mixture of one or more compositions in gelatin, sodium carboxymethylcellulose, hydroxyethylcellulose, Sodium Polyacrylate, modified starch, xanthans, bentonite, silica or Magnesiumaluminumsilicate.。
Described antifreezing agent is selected from the mixture of one or more compositions in ethylene glycol, propane diols, glycerine or urea.
Described defoamer is selected from the mixture of one or more compositions in silicone oil, silicone compound, C10 ~ C20 saturated fat acid compounds or C8 ~ C10 aliphatic alcohols compound.
Described disintegrant is selected from the mixture of one or more compositions in bentonite, urea, ammonium sulfate, aluminium chloride, low-substituted hydroxypropyl cellulose, lactose, citric acid, succinic acid or sodium bicarbonate.
Described stabilizing agent is selected from epoxidized soybean oil, the mixture of one or more compositions in epoxychloropropane, BHT, ethyl acetate or triphenyl phosphate.
Material described above is all buied by various commercial channel.
Compared with prior art, the invention has the beneficial effects as follows: complex insecticidal composition of the present invention has obvious synergistic effect, and the lasting period is long, active ingredient field rate is low, and produce and use cost reduction, to person poultry safety, Environmental compatibility is good; Action site increases, and is conducive to the generation delaying pest resistance to insecticide; Expand insecticidal spectrum, be especially applicable to control vegetables and fruit lepidoptera pest diamond-back moth, beet moth and sleep to insects such as striped rice borer.
Embodiment
Be further explained the present invention below in conjunction with embodiment, in following examples, percentage is all weight percentage, and field efficacy treatment dosage is effective ingredient consumption.
Embodiment 1
A kind of pyridalyl and four chlorantraniliprole complex insecticidal compositions, for wetting powder, its component and percentage by weight are: pyridalyl 25%, four chlorantraniliprole 25%, wetting agent lauryl sodium sulfate 5%, dispersant calcium lignosulfonate 8%, filler white carbon 18%, surplus is filler kaolin.
Preparation method: by embodiment 1 formula rate, adds active ingredient pyridalyl and four chlorantraniliproles in carrier, and adds surfactant and other functional aids wherein, mixing, and after air-flow crushing, mixing obtains wetting powder again.Capital equipment has mixer, airslide disintegrating mill.
Embodiment 2
A kind of pyridalyl and four chlorantraniliprole complex insecticidal compositions, for water dispersible granules, its component and percentage by weight are: pyridalyl 30%, four chlorantraniliprole 30%, wetting agent dodecylbenzene sodium sulfonate 3%, dispersant alkylnaphthalene sulfonate formaldehyde condensation products 8%, surplus is filler attapulgite.
Embodiment 3
A kind of pyridalyl and four chlorantraniliprole complex insecticidal compositions, for water dispersible granules, its component and percentage by weight are: pyridalyl 40%, four chlorantraniliprole 20%, wetting agent dodecylbenzene sodium sulfonate 3%, dispersant alkylnaphthalene sulfonate formaldehyde condensation products 8%, surplus is filler attapulgite.
Embodiment 2,3 preparation method: by each component ratio, active ingredient pyridalyl and four chlorantraniliproles are added in carrier, and add surfactant and other functional aids wherein, mixing, after air-flow crushing, add the water of 10 ~ 25%, then obtain water dispersible granules product through kneading, granulation, drying, screening; Maybe the powder pulverized is sprayed water in boiling granulator, granulation, drying, the afterwards obtained product of screening.Capital equipment has mixer, airslide disintegrating mill, kneader, Squeezinggranulator, drying room or fluid-bed drying, or boiling granulator, screening machine.
Embodiment 4
A kind of pyridalyl and four chlorantraniliprole complex insecticidal compositions, for aqueous suspension agent, its component and percentage by weight are: emulsifier agriculture breast NP-10, the dispersant polycarboxylate 8% of pyridalyl 25%, four chlorantraniliprole 15%, 2%, antifreeze glycol 5%, defoamer silicone compound 0.2%; Thickener selects xanthans and aluminium-magnesium silicate, and consumption is respectively 0.1% and 1%; Surplus is water.
Embodiment 5
A kind of pyridalyl and four chlorantraniliprole complex insecticidal compositions, be aqueous suspension agent, its component and percentage by weight are: emulsifier agriculture breast NP-10, the dispersant polycarboxylate 6% of pyridalyl 10%, four chlorantraniliprole 10%, 2%; Thickener selects xanthans and aluminium-magnesium silicate, and consumption is respectively 0.15% and 1.5%; Antifreeze glycol 5%; Defoamer silicone compound, 0.1%; Surplus is water.
Embodiment 4,5 preparation method: by formula rate, active ingredient pyridalyl and four chlorantraniliproles, surfactant and other functional aids are placed in reactor successively, add water and mix, through high speed shear, wet method sand milling, namely last homogeneous filtration obtains product.Capital equipment is batching kettle, colloid mill or homogeneous mixer, sand mill.
Embodiment 6
A kind of pyridalyl and four chlorantraniliprole complex insecticidal compositions, for aqueous emulsion, its component and percentage by weight are: emulsifier agriculture breast NP-10, castor oil polyoxyethylene ether 2%, phenyl phenol polyoxyethylene ether phosphate 2%, solvent xylene 20%, cosolvent cyclohexanone 10%, the xanthans 0.1% of pyridalyl 5%, four chlorantraniliprole 2.5%, 2%; Antifreeze glycol 5%, defoamer silicone compound 0.2%, surplus is water.
Embodiment 6 preparation method: according to formula rate, active ingredient, emulsifier, solvent, cosolvent dissolving are become oil phase, other compositions such as water, antifreeze, preservative, thickener are mixed as aqueous phase; While high speed shear, oil phase is added dropwise to aqueous phase in a kettle., shears a period of time, form stable oil-in-water type aqueous emulsion.
Embodiment 7
Whether both have synergistic effect after composite to adopt indoor associating independent biochemical determination test to verify below.
One, test method
1.1 reagent agent
The former medicine of 90% 4 chlorantraniliprole, the former medicine of 95% pyridalyl.
1.2 for examination target: rice leaf roller
1.3 experimental procedure
1.3.1 medicament preparation
First use the former medicine of acetone solution, on the basis of prerun, respectively two kinds of former medicines are dissolved, then be diluted to 5 concentration gradient liquids with the 0.1% Tween 80 aqueous solution, be placed in beaker for subsequent use.
1.3.2 chemicals treatment
Leaf dipping method is adopted to measure.Appropriate rice leaf is soaked into the liquid 15s, and take out, naturally dry in ventilation, be positioned in diameter 9cm culture dish, connect rice leaf roller 3 instar larvae 15/ware, upper lid layer filter paper, adds a cover mark.Arrange clear water control treatment, each process repeats 4 times.Be positioned over 27 DEG C, in 14h illumination box, check result after 72h.Touch polypide with writing brush, be reactionlessly considered as death.
Two, data survey and statistical analysis
Adopt the co-toxicity coefficient method representation that Sun Yun is abundant: data according to investigations, examination worm average correction lethality is converted into probit value (Y), concentration for the treatment of (mg/L) converts logarithm value (x) to, draws virulence regression equation Y=a+bx with method of least squares, calculates LC
50standard error is equivalent.Calculate the corrected mortality of each process, and press abundant method calculating mixture preparation co-toxicity coefficient (CTC value) of Sun Yun with reference to NY/T1154.7-2006, computing formula is as follows
Mixture preparation theoretical toxicity index (TTI)=∑ (percentage composition of this active ingredient of the toxicity index ATI of certain active ingredient × in mixture)
Be synergistic effect when CTC is greater than 120, being antagonism when being less than 80, is summation action when 80 ~ 120.
Table 1 active ingredient different ratio is to the toxicity test result of rice leaf roller
As can be seen from the table, four chlorantraniliproles and pyridalyl are when 1:1 ~ 1:2, and its co-toxicity coefficient is all greater than 120, shows as synergistic effect, wherein pyridalyl: four chlorantraniliproles be 1: 1 synergistic effect the most obvious, co-toxicity coefficient is 131.
Embodiment 8
Adopt field control effectiveness test method below, prove that four chlorantraniliproles and composite the use in land for growing field crops of pyridalyl have synergistic effect to pest control further.
One, experimental condition
1, subjects and trial crops
Subjects: rice leaf roller
Trial crops: paddy rice
2, environmental condition
Experimental establishment is carried out at Hubei Province's Xiaogan City.Carry out on June 10th, 2013 to July 15, test plot physical features is smooth, and it is good that water waters condition, and crop growing state is consistent.
Two, experimental scheme
1, medicament
1.1 test medicine
Select following examples 1 ~ 6 to make medicament.
1.2 contrast medicaments
Comparative example 1:10% tetra-chlorantraniliprole aqueous suspension agent
Comparative example 2:10.5% pyridalyl missible oil
1.3 blank
The blank (CK) not using any medicament is set, sprays the clear water of same volume.
2, community arranges
Plot area 25m
2, test medicine, contrast medicament and the arrangement of random district, blank community group, each process repeats for 4 times.
3, control time and number of times
Radix is investigated: before dispenser process;
Second time investigation: after dispenser 3d;
Third time investigation: after dispenser 7d;
4th investigation: after dispenser process 14d.
4, data statistics and result
4.1 drug effects calculate
Insect population lethality and correction insect population lethality are according to following formulae discovery:
Data processing adopts DPS software, and DMRT (Duncan duncan's new multiple range method) carries out significance test, evaluates preventive effect.
Table 2 treatment agent control rice leaf roller field control effectiveness test result
Note: after column data, does not have identical lowercase to show data significant difference.
As can be seen from the above data, different formulations carry out composite after, mixture preparation (embodiment 1 ~ 6) is obviously better than contrast medicament 1 (10% 4 chlorantraniliprole SC) and contrast agents 2 (10.5% pyridalyl EC) for the control efficiency of rice leaf roller, there is significant difference with contrasting between medicament 1 and 2 in embodiment 1 ~ 6, four chlorantraniliproles and the obvious synergistic effect of composite rear existence according to a certain percentage of pyridalyl two kinds of active ingredients are described.Respective consumption can be reduced after the two is composite, delay the generation of pest resistance to insecticide, safety and environmental protection, to crop safety under test dose, do not affect growth.Pyridalyl and four chlorantraniliproles are combinations of more satisfactory compound drug.Compared with single dose, it is few that Pesticidal combination of the present invention has dosage, instant effect, delay pest resistance to insecticide produce advantage, research and development of the present invention and promote significant for the protection of farmer richness and local environment.
Claims (9)
1. pyridalyl and four chlorantraniliprole complex insecticidal compositions, is characterized in that, its active ingredient comprises pyridalyl and four chlorantraniliproles, and its weight ratio is pyridalyl: four chlorantraniliproles=3:1 ~ 1:4.
2. pyridalyl according to claim 1 and four chlorantraniliprole complex insecticidal compositions, is characterized in that, the weight ratio of pyridalyl and four chlorantraniliproles is 1:1.
3. pyridalyl according to claim 1 and four chlorantraniliprole complex insecticidal compositions, it is characterized in that, described complex insecticidal composition also comprises pesticidal preparations auxiliary element.
4. pyridalyl according to claim 3 and four chlorantraniliprole complex insecticidal compositions, is characterized in that, described preparation auxiliary element comprises carrier and auxiliary agent.
5. pyridalyl according to claim 4 and four chlorantraniliprole complex insecticidal compositions, is characterized in that, described carrier comprises the one, two or three in water, solvent or filler.
6. pyridalyl according to claim 4 and four chlorantraniliprole complex insecticidal compositions, it is characterized in that, described auxiliary agent comprises surfactant, antifreezing agent, thickener, stabilizing agent, disintegrant or defoamer.
7. pyridalyl according to claim 3 and four chlorantraniliprole complex insecticidal compositions, is characterized in that, the weight percentage of active ingredient in complex insecticidal composition is 1 ~ 80%.
8. pyridalyl according to claim 7 and four chlorantraniliprole complex insecticidal compositions, is characterized in that, the weight percentage of active ingredient in complex insecticidal composition is 5 ~ 60%.
9. the pyridalyl according to the arbitrary claim of claim 1 ~ 8 and four chlorantraniliprole complex insecticidal compositions, it is characterized in that, the formulation of described complex insecticidal composition is aqueous suspension agent, oil-suspending agent, aqueous emulsion, wetting powder or water dispersible granules.
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Cited By (2)
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| CN104719302A (en) * | 2015-03-23 | 2015-06-24 | 广东中迅农科股份有限公司 | Insecticidal composition containing chlorantraniliprole and pyridalyl |
| CN112715554A (en) * | 2019-10-14 | 2021-04-30 | 江苏功成生物科技有限公司 | Pesticide composition containing pyridalyl and application thereof |
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Cited By (2)
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| CN112715554A (en) * | 2019-10-14 | 2021-04-30 | 江苏功成生物科技有限公司 | Pesticide composition containing pyridalyl and application thereof |
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