CN104855404A - Insecticidal combination containing tetrachloro worm amide and diafenthiuron - Google Patents
Insecticidal combination containing tetrachloro worm amide and diafenthiuron Download PDFInfo
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- CN104855404A CN104855404A CN201510224523.9A CN201510224523A CN104855404A CN 104855404 A CN104855404 A CN 104855404A CN 201510224523 A CN201510224523 A CN 201510224523A CN 104855404 A CN104855404 A CN 104855404A
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Abstract
The invention discloses insecticidal combination containing tetrachloro worm amide and diafenthiuron. The insecticidal combination containing tetrachloro worm amide and diafenthiuron comprises commonly used additive, tetrachloro worm amide and diafenthiuron, the weight part ratio of the tetrachloro worm amide and diafenthiuron is 1: 15 to 15: 1, and the weight percentage of the ratio of total weight of the butene-fipronil and fluorine benzene worm amide in the insecticidal combination is 1-80%; the insecticidal combination is used for preventing crop plutella xylostella, asparagus caterpillar and lepidoptera class pests; the insecticidal combination is superior to single dosage on quickly available performance and persistent effect performance, and the dosage of pesticide is reduced, the medicine use cost is reduced, and the insecticidal combination is good for environmental protection and comprehensive control of agricultural pests.
Description
Technical field
The present invention relates to agricultural insecticide composition and application thereof, specifically a kind of Pesticidal combination that is active ingredient with four chlorantraniliproles and diafenthiuron, is applied to the agriculture Lepidoptera class pest of control.
Background technology
Four chlorantraniliproles, the bromo-N-of chemical name: 3-(the chloro-6-of 2,4-bis-(methylformamide) phenyl)-1-(3,5-dichloro-2-pyridyl base)-1H-pyrazoles-5-formamide.Four chlorantraniliproles are benzamide insecticides of Shenyang Chemical Engineering Inst's independent research, be combined by ryanodine receptor in pest body, open calcium channel, make to be stored in intracellular calcium ion sustained release in sarcoplasm, calcium ion and sarcoplasm mesostroma protein combination, cause muscle contracts last, polypide poisoning symptom shows as tic, food refusal, final death, excellent to the preventive effect of paddy rice rice leaf roller, Laphygma exigua Hubner.
Diafenthiuron, English name: diafenthiuron, chemical name: 1-tertiary butyl-3-(2,6-diisopropyl-4-Phenoxyphenyl) thiocarbamide.Diafenthiuron belongs to Thiourea insecticidal/acaricidal agent, there is interior suction, tag, stomach toxicity and fumigation action, by the neural energy metabolism of interference insect, destroy neural basic function, suppress chitin synthesis, insect cannot be casted off a skin and extremely, to lepidoptera pest as diamond-back moth, beet armyworm, the pest such as mite class are efficient.
The resistance problem of pest is global problems, is the emphasis problem that agricultural science and technology worker pays close attention to always.Along with the continuity year in year out of Chemical Control of Harmful Insects, the increase of Pesticide use amount and not scientifical use agricultural chemicals, pest resistance is day by day serious, and the pest species producing resistance is on the increase.Particularly to insects such as the Lepidoptera classes that agricultural production is caused harm serious, resistance level is higher, and resistance development speed is relatively very fast.Meanwhile, the use agricultural chemicals of high strength, causes Practice for Pesticide Residue in Agricultural Products to exceed standard, environmental pollution and the increase of peasant's drug cost etc., is unfavorable for agricultural sustainable development.Therefore, the pesticide of efficient, the low toxicity of research and development, environmental protection has positive effect to agricultural sustainable development.
Diamond-back moth, beet armyworm are lepidoptera pests common above brassicaceous vegetable, and its larva gnaws harm dish leaf, often cause the damaged afoliate of vegetable leaf.The lepidoptera pest generation alternation of generations, fertility is strong, and under suitable temperature and humidity conditions, number of pest increases rapidly in the short period of time exponentially, thus easily develops immunity to drugs to insecticide, causes serious harm to crop simultaneously.
Different pesticide species composition carries out composite, is the common methods of preventing and treating agriculture resistant insect insect.The present inventor is on the basis of a large amount of indoor virulences and field medicine effect test, the compounded formula screening of four chlorantraniliproles and diafenthiuron is conducted in-depth research, find that four chlorantraniliproles and diafenthiuron carry out composite, in certain proportion, there is obvious synergistic function, and to wild cabbage diamond-back moth, beet armyworm, there is outstanding control efficiency, after further study, the present invention is completed.
Summary of the invention
The technical problem that the present invention solves be to provide a kind of efficient, low toxicity and the lasting period long, effectively can prevent and treat crops Lepidoptera class pest, be conducive to the Pesticidal combination containing four chlorantraniliproles and diafenthiuron of integrated pest management.
For solving the problem, the technical solution adopted in the present invention is: a kind of Pesticidal combination containing four chlorantraniliproles and diafenthiuron, comprise usual auxiliaries, four chlorantraniliproles and diafenthiuron, the ratio of weight and number of four chlorantraniliproles and diafenthiuron is 1:15-15:1, and four chlorantraniliproles and the percentage by weight of diafenthiuron weight summation in Pesticidal combination are 1%-80%.
Preferably, four chlorantraniliproles and the percentage by weight of diafenthiuron weight summation in Pesticidal combination are 10-60%.
Described Pesticidal combination according to well known to a person skilled in the art method, can be mixed with the application forms of the applicable agricultural uses such as suspending agent, water dispersible granules, aqueous emulsion, microemulsion, wetting powder.
Described Pesticidal combination is also containing the usual auxiliaries of preparation needed for pesticidal preparations, usual auxiliaries is the mixing of one or more in solvent, emulsifier, wetting agent, stabilizing agent, dispersant, thickener, pH adjusting agent, defoamer, antifreezing agent, packing agent etc., be known substance, various auxiliary agents conventional in pesticidal preparations, can change to some extent according to different situations, be not particularly limited.
The application of described Pesticidal combination, for preventing and treating crop pests, main control crops Lepidoptera class pest.
Pesticidal combination provided by the invention, usually adopts the method for spraying to use, also can adopt other operation techniques agriculturally applied as required.
Compared with prior art, the invention has the advantages that:
1, four chlorantraniliproles and diafenthiuron is composite has beyond thought synergistic function, are used alone the control efficiency that improve insect than single dose;
2, four chlorantraniliproles and the diafenthiuron mechanism of action different, the mixed generation that can delay pest resistance to insecticide;
3, four chlorantraniliproles and diafenthiuron two kinds of active ingredients composite, decrease Pesticide use amount, reduce use cost and alleviate pollution to environment.
Embodiment
In order to understand essence of the present invention better, below in conjunction with embodiment, content of the present invention is described further, but can not be considered as limitation of the present invention, content mentioned in embodiment is not limitation of the invention, material prescription is selected to suit measures to local conditions and on result without substantial impact.In these embodiments, unless otherwise indicated, all percentage is all weight percentage.
Example of formulations 1: described Pesticidal combination is suspending agent, and each component percentages is respectively:
Concrete operation step is: first mixed by other auxiliary agent, and in clipper, shear-mixed is even, then adds active ingredient, in ball crusher, grinds 2-3h, make a diameter all at below 5mm, can obtain Pesticidal combination aqueous suspension formulations of the present invention.
Example of formulations 2: described Pesticidal combination is aqueous emulsion, and each component percentages is respectively:
Concrete operation step is: first active ingredient, solvent, emulsifier are mixed, and dissolves and becomes uniform oil phase.Again part water and other auxiliary agents are mixed, dissolve and become uniform aqueous phase.Then oil phase is added aqueous phase while high-speed stirred in a kettle., slowly add water to and reach phase inversion point, carry out high speed shear afterwards, and add remaining water, shear about 30min, Pesticidal combination aqueous emulsion preparation of the present invention can be obtained.
Example of formulations 3: described Pesticidal combination is microemulsion, and each component percentages is respectively:
Concrete operation step is: active ingredient solvent and cosolvent are dissolved completely, and then adds other auxiliary agent, mixes, finally adds water, after fully stirring, can obtain Pesticidal combination microemulsion formulation of the present invention.
Example of formulations 4: described Pesticidal combination is wetting powder, and each component percentages is respectively:
Concrete operation step is: active ingredient, other auxiliary agent and filler are mixed, fully stir in stirred tank, mixes, can obtain Pesticidal combination wettable powder formulation of the present invention after airslide disintegrating mill is pulverized.
Example of formulations 5: described Pesticidal combination is water dispersible granules, and each component percentages is respectively:
Concrete operation step is: active ingredient, other auxiliary agent and filler are mixed, pulverize with micro jet, add after mediating after carrying out granulation, drying, screening in fluidized-bed granulation dryer, Pesticidal combination water-dispersible grain agent formulation of the present invention can be obtained.
In above formulation, auxiliary agent is selected from the following stated:
Solvent can be trimethylbenzene, durene, methyl naphthalene, methyl oleate, fatty acid methyl ester, loose base oil, soybean oil, biodiesel, 2-butyl acetate, dimethyl carbonate, diesel oil, white oil, machine oil, etc. in one or more.
Emulsifier can be calcium dodecyl benzene sulfonate, fatty alcohol-polyoxyethylene ether, triphenoethyl benzene phenol polyoxyethylene polyoxypropylene block polymer, dibenzyl xenyl APEO, phenethyl phenol polyethenoxy ether, castor oil polyoxyethylene ether, phenethyl fluosite APEO, phenethyl phenol polyoxyethylene polyoxypropylene ether, alkylaryl polyoxyethylene polyoxypropylene ether, phenethyl phenol formaldehyde resin APEO, Sorbitan fatty acid ester, sorbitan fatty acid ester APEO, natural fatty alcohol and ethylene oxide adduct, fatty acid and ethylene oxide condensate, one or more in polyoxyethylene fatty acid ester etc.
Wetting agent can be one or more in sodium butylnaphthalenesulfonate, lauryl sodium sulfate, aliphatic alcohol polyethenoxy (6-7) ether, aerosol-OT salt, Morwet EFW, alkylnaphthalene sulfonate etc.
Disintegrant can be one or more in sodium bicarbonate, magnesium chloride, aluminium chloride, sodium chloride, urea, ammonium sulfate, bentonite etc.
Dispersant can be the formaldehyde condensation products of methyl naphthalene sulfonic acid sodium, sodium lignin sulfonate, calcium lignosulfonate, to methoxyl group fatty acyl anilinesulfonic acid, desugar one or more in the sodium lignin sulfonate of classification, naphthalene sulfonic acid condensate sodium salt, alkyl naphthalene sulfonic acid condensation polymer sodium salt, alkylphenol polyoxyethylene formaldehyde condensation products sulfuric acid etc.
Thickener can be one or more in xanthans, aluminium-magnesium silicate, bentonite, white carbon etc.
PH adjusting agent can be one or more in ammonium hydroxide, potassium hydroxide, sodium hydroxide, hydrochloric acid, acetic acid, citric acid, phosphoric acid etc.
Stabilizing agent can be one or more in epoxidized soybean oil, epoxychloropropane, butylated hydroxy anisole, dibutyl hydroxy toluene, n-propyl gallate, ditert-butylhydro quinone etc.
Defoamer can be one or more in silicone compound, methyl alcohol, silicone oil etc.
Antifreezing agent can be one or more in glycerine, ethylene glycol, propane diols, sorbierite, polyethylene glycol etc.
Carrier can be one or more in kaolin, diatomite, bentonite, white carbon, precipitated calcium carbonate, attapulgite, clay, talcum powder, quartz sand, starch, APG etc.
Assays Example 1: four chlorantraniliprole and diafenthiuron are to the indoor joint toxicity measuring test of beet armyworm, diamond-back moth.
Test medicine adopts the former medicine of 95% 4 chlorantraniliprole and the former medicine of 97% diafenthiuron.
Examination worm is gather through the diamond-back moth in indoor feeding 3 generation, beet armyworm 3 instar larvae from wild cabbage.
The diamond-back moth gathered in field, beet exigua larvae put into off-the-shelf Chinese cabbage seedling, after larvae pupation, pupa is collected in the culture dish being lined with moisturizing filter paper, put into cage of laying eggs to sprout wings by it, then the Chinese cabbage seedling of whole dish being put into cage of laying eggs allows diamondback moth larvae lay eggs, often coil Chinese cabbage seedling and fall ovum amount when reaching about 500, take out Chinese cabbage seedling dish, be placed on climatic cabinate [temperature: 24 ~ 26 DEG C; Relative moisture 70% ~ 80%; Illumination: 14 (L): 10 (D)] in allow egg hatching, raise to 3 instar larvaes.
The malicious blade method of folder is adopted to measure: to beat with the card punch of diameter 1cm and get leaf butterfly, put into culture dish, moisturizing.With capillary dropper from low concentration, every leaf butterfly drop 1ul liquid, involutory the making of leaf butterfly scribbling gelatinized corn starch after solvent volatilization with another sheet presss from both sides malicious leaf butterfly, makes in the complete hole being put in 12 hole tissue culturing plates.Often process and repeat for 4 times, often repeat to be no less than 12 malicious leaf butterflies of folder, and establish not containing the corresponding organic solvent of medicament process in contrast.Connect 1 examination worm in each hole of tissue culturing plate, be placed in normal condition and cultivate.After meeting worm 2 ~ 4h, after examination worm has taken food pastille leaf butterfly, in cultivation plate hole, add clean feeds continue to raise to investigation, eliminated the examination worm not eaten a complete leaf butterfly.Each dosage process examination borer population 80.After process, 96h investigation examination worm death condition, records total borer population and dead borer population.
Statistical analysis is carried out, by calculating the LC of each medicament with DPS statistical analysis software
50evaluate the insecticidal activity of each medicament, and calculate the co-toxicity coefficient (CTC value) of mixture according to the abundant method of Sun Yun.
Actual measurement toxicity index (ATI)=(standard agent LC
50/ reagent agent LC
50) × 100
In theoretical toxicity index (TTI)=A medicament toxicity index × mixture A percentage composition+B medicament toxicity index × mixture in the percentage composition of B.
Co-toxicity coefficient (CTC)=[the theoretical toxicity index (TTI) of mixture actual measurement toxicity index (ATI)/mixture] × 100.
According to the NY/T11547.7-2006 insecticide combination effect criteria for classifying: co-toxicity coefficient (CTC) >=120 shows as synergistic effect; Co-toxicity coefficient (CTC)≤80 shows as antagonism; 80 < co-toxicity coefficient (CTC) < 120 show as summation action.
As can be seen from Table 1 and Table 2, four chlorantraniliproles and diafenthiuron composite in the scope of 1:15 ~ 15:1 time, co-toxicity coefficient (CTC) is all greater than 120, all shows synergistic function to wild cabbage diamond-back moth, beet armyworm.Visible four chlorantraniliproles and diafenthiuron is composite has reasonability and feasibility.
Table 1, four chlorantraniliproles and diafenthiuron are to the indoor joint toxicity measuring result of beet armyworm
| Medicament title and proportioning (weight ratio) | LC 50(mg/L) | ATI | TTI | CTC |
| Four chlorantraniliproles | 1.52 | 100.00 | - | - |
| Diafenthiuron | 11.25 | 13.51 | - | - |
| Four chlorantraniliproles: diafenthiuron (15:1) | 1.25 | 121.60 | 94.59 | 128.55 |
| Four chlorantraniliproles: diafenthiuron (10:1) | 1.32 | 115.15 | 92.14 | 124.98 |
| Four chlorantraniliproles: diafenthiuron (5:1) | 1.40 | 108.57 | 85.59 | 126.86 |
| Four chlorantraniliproles: diafenthiuron (1:1) | 2.03 | 74.88 | 56.76 | 131.93 |
| Four chlorantraniliproles: diafenthiuron (1:5) | 3.96 | 38.38 | 27.93 | 137.45 |
| Four chlorantraniliproles: diafenthiuron (1:10) | 4.88 | 31.15 | 21.37 | 145.73 |
| Four chlorantraniliproles: diafenthiuron (1:15) | 5.36 | 28.36 | 18.92 | 149.91 |
Table 2, four chlorantraniliproles and diafenthiuron are to the indoor joint toxicity measuring result of diamond-back moth
| Medicament title and proportioning (weight ratio) | LC 50(mg/L) | ATI | TTI | CTC |
| Four chlorantraniliproles | 1.49 | 100.00 | - | - |
| Diafenthiuron | 13.78 | 10.81 | - | - |
| Four chlorantraniliproles: diafenthiuron (15:1) | 1.25 | 119.20 | 94.43 | 126.24 |
| Four chlorantraniliproles: diafenthiuron (10:1) | 1.30 | 114.62 | 91.89 | 124.73 |
| Four chlorantraniliproles: diafenthiuron (5:1) | 1.33 | 112.03 | 85.14 | 131.59 |
| Four chlorantraniliproles: diafenthiuron (1:1) | 2.11 | 70.62 | 55.41 | 127.45 |
| Four chlorantraniliproles: diafenthiuron (1:5) | 4.46 | 33.41 | 25.68 | 130.11 |
| Four chlorantraniliproles: diafenthiuron (1:10) | 5.82 | 25.60 | 18.92 | 135.31 |
| Four chlorantraniliproles: diafenthiuron (1:15) | 6.29 | 23.69 | 16.39 | 144.56 |
Assays Example 2: four chlorantraniliprole and the composite field control effectiveness test to beet armyworm, diamond-back moth of diafenthiuron.
Beet armyworm test site is positioned at wild cabbage garden, Ma An town, Huizhou.In Laphygma exigua Hubner harm Sheng phase dispenser, adopt spray-on process.Adopt 10% 4 chlorantraniliprole suspending agent, 50% diafenthiuron suspension agent medicament in contrast, 7 chemicals treatment are established in test altogether, and each process repeats for 3 times.Cornerwise five somes investigation in district insect population radix is managed throughout, often some investigation 10 strain wild cabbages before dispenser.Within after dispenser 3 days, 7 days, 14 days, respectively investigate a control efficiency, record residual borer population, calculate control efficiency by Revision insect recluced rate, result of the test is as shown in table 3.
Table 3, four chlorantraniliproles and diafenthiuron mixture prevent and treat the result of the test of Laphygma exigua Hubner
All to use apparently higher than the chlorantraniliprole suspending agent single dose same period 10% 4 preventive effect of Laphygma exigua Hubner after four chlorantraniliproles and diafenthiuron composite 3d, 7d, 14d as can be seen from Table 3 and 50% diafenthiuron suspension agent single dose uses, the preventive effect to Laphygma exigua Hubner can be improved compared with illustrating that four chlorantraniliproles and diafenthiuron are composite and being used alone with two kinds of single doses, after medicine, 14d preventive effect still reaches more than 80% simultaneously, illustrate to have good lasting effect, duration of test does not find that this compound drug produces poisoning to wild cabbage.
Diamond-back moth test site is positioned at wild cabbage garden, Li Lin town, Huizhou.In diamond-back moth harm Sheng phase dispenser, adopt spray-on process.Adopt 10% 4 chlorantraniliprole suspending agent, 50% diafenthiuron suspension agent medicament in contrast, 7 chemicals treatment are established in test altogether, and each process repeats for 3 times.Cornerwise five somes investigation in district insect population radix is managed throughout, often some investigation 10 strain wild cabbages before dispenser.Within after dispenser 3 days, 7 days, 14 days, respectively investigate a control efficiency, record residual borer population, calculate control efficiency by Revision insect recluced rate, result of the test is as shown in table 4.
Table 4, four chlorantraniliproles and diafenthiuron mixture prevent and treat the result of the test of diamond-back moth
All to use apparently higher than the chlorantraniliprole suspending agent single dose same period 10% 4 preventive effect of diamond-back moth after four chlorantraniliproles and diafenthiuron composite 3d, 7d, 14d as can be seen from Table 4 and 50% diafenthiuron suspension agent single dose uses, the preventive effect to diamond-back moth can be improved compared with illustrating that four chlorantraniliproles and diafenthiuron are composite and being used alone with two kinds of single doses, after medicine, 14d preventive effect still reaches more than 80% simultaneously, illustrate to have good lasting effect, duration of test does not find that this compound drug produces poisoning to wild cabbage.
Assays Example 3: beet armyworm, the pesticide resistance indoor measurement of diamond-back moth to four chlorantraniliproles and diafenthiuron are tested.
Four chlorantraniliproles, the former medicine of diafenthiuron are mixed with the test medicine needed for test.Worm source gathers from Huizhou.Test adopts dip method, the concentration that test medicine adopts is the 50%-90% lethal dose of beet armyworm, diamond-back moth, impregnated in treatment fluid by examination worm, rejects dead examination worm after 96 hours, the examination worm stayed continues at indoor feeding, so repeatedly processes 20 generations examination worm.If the liquid only containing auxiliary agent is treated to blank.Measure each medicament tries worm half lethal concentration LC to 1st generation, the 5th generation, the 10th generation and the 20th generation
50, by contrast each treatment agent to 1st generation, the 5th generation, the 10th generation and the 20th generation examination worm LC
50evaluate examination worm to change the pesticide resistance of reagent agent.
Can find out according to table 5, table 6, in four chlorantraniliproles and diafenthiuron complex preparation process 20 generation, try the pesticide resistance that the pesticide resistance of worm population to this complex preparation is starkly lower than four chlorantraniliproles and the generation of diafenthiuron single dose process 20 generation examination worm after trying worm.This test shows, four chlorantraniliproles and diafenthiuron compositely can effectively delay wild cabbage diamond-back moth, beet armyworm develops immunity to drugs.
Table 5, four chlorantraniliproles and diafenthiuron are composite to the drug-fast determination test result of beet armyworm
Note: above table medium multiple represents that corresponding algebraically Laphygma exigua Hubner is to the pesticide resistance of each medicament.
Table 6, four chlorantraniliproles and diafenthiuron are composite to the drug-fast determination test result of diamond-back moth
Note: above table medium multiple represents that corresponding algebraically diamond-back moth is to the pesticide resistance of each medicament.
In sum, the present invention adopts two kinds of active components to be the complex composition of four chlorantraniliproles and diafenthiuron, compared with existing unitary agent, not only there is obvious synergistic effect, also have good insecticidal effect, the lasting period is long, to Crop securify, the generation of pest resistance to insecticide can be slowed down, be worth applying in agricultural production.
Claims (4)
1. one kind contains the Pesticidal combination of four chlorantraniliproles and diafenthiuron, comprise usual auxiliaries, four chlorantraniliproles and diafenthiuron, it is characterized in that: the ratio of weight and number of four chlorantraniliproles and diafenthiuron is 1:15-15:1, four chlorantraniliproles and the percentage by weight of diafenthiuron weight summation in Pesticidal combination are 1%-80%.
2. a kind of Pesticidal combination containing four chlorantraniliproles and diafenthiuron according to claim 1, is characterized in that: its formulation is the one in suspending agent, water dispersible granules, aqueous emulsion, microemulsion, wetting powder.
3. a kind of application of Pesticidal combination in control crop pests containing four chlorantraniliproles and diafenthiuron according to claim 1.
4. a kind of Pesticidal combination containing four chlorantraniliproles and diafenthiuron according to claim 3, is characterized in that: described insect is Lepidoptera class pest.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN115708510A (en) * | 2022-01-13 | 2023-02-24 | 青岛海利尔生物科技有限公司 | Insecticidal composition containing fluorine-containing chlorantraniliprole |
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|---|---|---|---|---|
| CN102113516A (en) * | 2010-01-05 | 2011-07-06 | 海南正业中农高科股份有限公司 | Insect killing compound containing chlorantraniliprole |
| CN103651433A (en) * | 2013-12-19 | 2014-03-26 | 北京燕化永乐生物科技股份有限公司 | Pesticide composite |
| CN103651434A (en) * | 2013-12-19 | 2014-03-26 | 北京燕化永乐生物科技股份有限公司 | Complex insecticide |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102113516A (en) * | 2010-01-05 | 2011-07-06 | 海南正业中农高科股份有限公司 | Insect killing compound containing chlorantraniliprole |
| CN103651433A (en) * | 2013-12-19 | 2014-03-26 | 北京燕化永乐生物科技股份有限公司 | Pesticide composite |
| CN103651434A (en) * | 2013-12-19 | 2014-03-26 | 北京燕化永乐生物科技股份有限公司 | Complex insecticide |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115708510A (en) * | 2022-01-13 | 2023-02-24 | 青岛海利尔生物科技有限公司 | Insecticidal composition containing fluorine-containing chlorantraniliprole |
| CN115708510B (en) * | 2022-01-13 | 2024-03-26 | 青岛海利尔生物科技有限公司 | Insecticidal composition containing flucloxapyroxad |
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