CN104824017B - A kind of composition pesticide containing fosthiazate and betacyfluthrin - Google Patents
A kind of composition pesticide containing fosthiazate and betacyfluthrin Download PDFInfo
- Publication number
- CN104824017B CN104824017B CN201510214658.7A CN201510214658A CN104824017B CN 104824017 B CN104824017 B CN 104824017B CN 201510214658 A CN201510214658 A CN 201510214658A CN 104824017 B CN104824017 B CN 104824017B
- Authority
- CN
- China
- Prior art keywords
- betacyfluthrin
- fosthiazate
- agent
- composition pesticide
- root
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a kind of composition pesticide containing fosthiazate and betacyfluthrin, active ingredient are fosthiazate and betacyfluthrin, and the weight ratio of fosthiazate and betacyfluthrin is 1:25~25:1, the weight percent of fosthiazate and betacyfluthrin weight summation in composition pesticide is 5%~98%；One kind in suspending agent, water dispersible granules, aqueous emulsion, microemulsion, wettable powder can be made in composition pesticide of the present invention in actual use, suitable for prevention root-knot nematode, pratylenchus etc., not only have obvious synergistic function, Pesticide use amount is also reduced, the generation of pest resistance to insecticide is slowed down.
Description
Technical field
The present invention relates to composition pesticide and its application fields, and specifically one kind is with fosthiazate and efficient cyfluthrin chrysanthemum
Ester is the binary complex of active ingredient, is applied to prevention crops nematode, such as：Root-knot nematode, pratylenchus.
Background technology
Fosthiazate, English name：Fosthiazate, chemical name：- 1,3 thiazole of O- ethyl-S- sec-butyl -2- oxos
Alkane -3- base Thiophosphonates.Fosthiazate is organic phosphates nematicide, and main effect model is to inhibit root-knot nematode acetylcholine
The synthesis of esterase has excellent contact and uptake and translocation, and toxicity is relatively low and the lasting period is long, to root-knot nematode, root-rot line
Worm has preferable control effect；
Betacyfluthrin, English name：Beta-cyfluthrin, chemical name：Cyano-(the fluoro- 3- benzyloxy phenoxies of 4-
Base)-methyl-(2,2- dichloroethylene) -2,2- dimethyl cyclopropane carboxylic acid's esters.Betacyfluthrin acts on the god of insect
Through system, pest can be quickly knocked down, the longevity of residure is long.Have good result to a variety of lepidopterous larvaes, can effectively prevent subterranean pest-insect,
Nematode, insecticidal spectrum is wide, and effect is rapid, and the lasting period is long, is suitable for melon crop, fruit to crop safety to mammal low toxicity
Tree, vegetables, tea tree, tobacco, soybean etc..
Nematode is a kind of common agricultural disease, and host range is extensive, often cause harm melon, solanaceous vegetables, beans and radish, calabash
30 various vegetables such as radish, lettuce, Chinese cabbage, moreover it is possible to propagate some fungies and bacterial disease.
Different pesticide species ingredients are compounded, and are the common methods of prevention agriculture resistant insect and germ.The present inventor
On the basis of a large amount of indoor virulence and field medicine effect test, the compounded formula of fosthiazate and betacyfluthrin is screened
It has made intensive studies, it is found that fosthiazate and betacyfluthrin are compounded, have in a certain proportion apparent
Synergistic function, and have outstanding control effect, after further study, complete this root-knot nematode, pratylenchus
Invention.
Invention content
The purpose of the present invention is to provide a kind of compound synergic composition containing fosthiazate and betacyfluthrin, is answered
For preventing root-knot nematode, pratylenchus.
Technical solution：To achieve the above object, it is effective that the present invention, which provides one kind with fosthiazate and betacyfluthrin,
The composition pesticide of ingredient, the weight percent of fosthiazate and betacyfluthrin weight summation in composition pesticide are
5%~98%, remaining is to allow to use and acceptable auxiliary element in pesticide.
The composition pesticide can be configured to suspending agent, water-dispersible grain according to well known to a person skilled in the art methods
The application forms of the suitable agricultural use such as agent, aqueous emulsion, microemulsion, wettable powder.
The composition pesticide also contains the agriculturally acceptable insecticides adjuvant prepared needed for pesticidal preparations, selected from molten
Agent, emulsifier, wetting agent, stabilizer, dispersant, bleeding agent, thickener, antifoaming agent, antifreezing agent, disintegrant, binder, filling
One or more of agent, carrier, medium, surfactant are known substance, are commonly various in pesticidal preparations help
Agent can be varied from according to different situations, be not particularly limited.
The production technology of the various application forms of the composition pesticide belongs to existing known technology, and details are not described herein.
Composition pesticide provided by the invention is applied to prevention crops nematode, such as：Root-knot nematode, pratylenchus etc..
Compared with the prior art, the advantages of the present invention are as follows：
1, fosthiazate and betacyfluthrin compounding have unexpected synergistic function, are used alone than single dose
Improve the control effect to pest and germ；
2, fosthiazate and the betacyfluthrin mechanism of action are different, mixed pest and the germ drug resistance of can delaying
It generates；
3, two kinds of active ingredient compoundings of fosthiazate and betacyfluthrin, reduce Pesticide use amount, reduce use
Cost and alleviate the pollution to environment.
Specific implementation mode
To better understand the essence of the present invention, present disclosure is described further with reference to embodiment,
But limitation of the present invention cannot be considered as.
(1), preparation method embodiment
Embodiment 1：The nematicidal composition is suspending agent, and each component percentage composition is respectively：
Concrete operation step is：First other auxiliary agents are mixed, shear-mixed is uniform in cutter, be then added effectively at
Point, 2-3h is ground in ball crusher, a diameter is made to be below 5mm, you can nematicidal composition aqueous suspension formulations of the present invention are made.
Embodiment 2：The nematicidal composition is aqueous emulsion, and each component percentage composition is respectively：
Concrete operation step is：First effective constituents A, solvent, emulsifier are mixed, dissolving becomes uniform oil
Phase.Part water and other auxiliary agents are mixed again, dissolving becomes uniform water phase.Then high-speed stirred in a kettle
The oil phase is added to the aqueous phase simultaneously, slowly adds water to and reaches phase inversion point, carry out high speed shear later, and remaining water is added, and shears
About 30min, you can nematicidal composition water and milk agent formulation of the present invention is made.
Embodiment 3：The nematicidal composition is microemulsion, and each component percentage composition is respectively：
Concrete operation step is：Active ingredient is completely dissolved with solvent and cosolvent, then adds other auxiliary agents, is mixed
It closes uniformly, water is eventually adding, after being sufficiently stirred, you can nematicidal composition microemulsion formulation of the present invention is made.
Embodiment 4：The nematicidal composition is wettable powder, and each component percentage composition is respectively：
Concrete operation step is：Active ingredient, other auxiliary agents and filler are mixed, are sufficiently stirred in a stirring kettle, is passed through
Airslide disintegrating mill is uniformly mixed after crushing, you can nematicidal composition wettable powder formulation of the present invention is made.
Embodiment 5：The nematicidal composition is water dispersible granules, and each component percentage composition is respectively：
Concrete operation step is：Active ingredient, other auxiliary agents and filler are uniformly mixed, with micro jet powder
It is broken, it is added in fluidized-bed granulation dryer after kneading after being granulated, drying, sieve, you can obtained nematicidal group of the present invention
Close object water-dispersible grain agent formulation.
Auxiliary agent is selected from as described below in the above dosage form：
Solvent can be trimethylbenzene, durene, methyl naphthalene, methyl oleate, fatty acid methyl ester, loose base oil, soybean oil, biology
Diesel oil, sec-Butyl Acetate, dimethyl carbonate, diesel oil, white oil, machine oil, etc. one or more of.
Emulsifier can be that calcium dodecyl benzene sulfonate, fatty alcohol polyoxyethylene ether, triphenoethyl benzene phenol polyoxypropylene are poly-
Ethylene oxide block polymer, dibenzyl xenyl polyoxyethylene ether, phenethyl phenol polyethenoxy ether, castor oil polyoxyethylene ether,
Phenethyl phenol formaldehyde resin polyoxyethylene ether, phenethyl phenol polyoxyethylene polyoxypropylene ether, alkylaryl polyoxypropylene polyoxy
Vinethene, phenethyl phenol formaldehyde resin polyoxyethylene ether, Sorbitan aliphatic ester, sorbitan fatty acid ester polyoxy second
In alkene ether, natural fatty alcohol and ethylene oxide adduct, aliphatic acid and ethylene oxide condensate, polyoxyethylene fatty acid ester etc.
It is one or more of.
Wetting agent can be sodium butylnaphthalenesulfonate, lauryl sodium sulfate, aliphatic alcohol polyethenoxy (6-7) ether, sulfonation amber
One or more of amber dioctyl phthalate sodium salt, Morwet EFW, alkylnaphthalene sulfonate etc..
Disintegrant can be one in sodium bicarbonate, magnesium chloride, aluminium chloride, sodium chloride, urea, ammonium sulfate, bentonite etc.
Kind is several.
Dispersant can be formaldehyde condensate of sodium methylnaphthalene sulfonate, sodium lignin sulfonate, calcium lignosulfonate, to methoxy
Base fatty acyl anilinesulfonic acid, desugar and the sodium lignin sulfonate of classification, naphthalene sulfonic acid condensate sodium salt, alkyl naphthalene sulfonic acid condensation polymer
One or more of sodium salt, APES formaldehyde condensation product sulfuric acid etc..
Thickener can be one or more of xanthans, aluminium-magnesium silicate, bentonite, white carbon etc..
PH adjusting agent can be in ammonium hydroxide, potassium hydroxide, sodium hydroxide, hydrochloric acid, acetic acid, citric acid, phosphoric acid etc.
It is one or more of.
Stabilizer can be epoxidized soybean oil, epoxychloropropane, butylated hydroxy anisole, dibutyl hydroxy toluene, not eat
One or more of sub- propyl propionate, tert-butylhydroquinone etc..
Antifoaming agent can be one or more of silicone compound, methanol, silicone oil etc..
Antifreezing agent can be one or more of in glycerine, ethylene glycol, propylene glycol, sorbierite, polyethylene glycol etc..
Carrier can be kaolin, diatomite, bentonite, white carbon, precipitated calcium carbonate, attapulgite, clay, talcum
One or more of powder, quartz sand, starch, alkyl polyglycoside etc..
(2) indoor biological determination of activity and Field efficacy embodiment
Embodiment 6：The indoor joint toxicity measuring of fosthiazate and betacyfluthrin to root-knot nematode, pratylenchus.
Test medicine uses 96% fosthiazate active compound and 95% betacyfluthrin active compound.
Root-knot nematode, pratylenchus system pick up from the towns the Li Lin villages Tang Jiao of the Huizhou areas Zhong Kai, and root-knot nematode sends out for many years
Raw serious watermelon field, it is spare to take back laboratory by the watermelon old complaint of morbidity.
With reference to biometric standard method NY/T1833.1-2009, using dip method.Nematode suspension preparation：From the west of morbidity
The pieces of an egg of picking root-knot nematode on melon root, with sterile water wash, at 20-25 DEG C hatching obtain consistent second instar larvae, use is sterile
Nematode suspension concentration is adjusted to 300 every milliliter or so by water, spare.Medicine is drawn successively from low concentration to high concentration with pipettor
Liquid 3mL is separately added into test tube, is then drawn the equivalent nematode suspension 3mL prepared and is added in test tube, makes liquid and nematode
Suspension mixed in equal amounts is uniform.The above-mentioned mixed liquor for pipetting 2mL with pipettor is capped in the Xiao Sun of more grandson's biochemical test plates,
For 24 hours in 25 DEG C of constant temperature incubations.4 repetitions are often handled, and set the processing without liquid as a contrast.
It is for statistical analysis with DPS statistical analysis softwares, by the LC for calculating each medicament50To evaluate the nematicidal of each medicament
Activity, and according to the co-toxicity coefficient (CTC values) of Sun Yunpei's Method calculating mixture.
Survey toxicity index (ATI)=(standard agent LC50/ reagent agent LC50)×100。
Percentage composition+B the medicament toxicity index of A in theoretical toxicity index (TTI)=A medicament toxicity index × mixture × mixed
The percentage composition of B in agent.
Co-toxicity coefficient (CTC)=[mixture surveys toxicity index (ATI)/mixtures theoretical toxicity index (TTI)] × 100.
According to the NY/T11547.7-2006 nematicide synergy criteria for classifying：Co-toxicity coefficient (CTC) >=120 shows
For synergistic effect；Co-toxicity coefficient (CTC)≤80 shows as antagonism；80 ＜ co-toxicity coefficients (CTC) ＜ 120, which show as being added, to be made
With.
As can be seen from Table 1 and Table 2, fosthiazate and betacyfluthrin are 1:25~25:When being compounded in the range of 1,
Co-toxicity coefficient (CTC) is all higher than 120, and synergistic function is shown to root-knot nematode, pratylenchus.It can be seen that fosthiazate and height
Imitating cyfloxylate compounding has reasonability and feasibility.
The indoor joint toxicity measuring result of table 1, fosthiazate and betacyfluthrin to root-knot nematode
The indoor joint toxicity measuring result of table 2, fosthiazate and betacyfluthrin to pratylenchus
Embodiment 7：Fosthiazate and betacyfluthrin compound the field control effectiveness test to root-knot nematode, pratylenchus
Root-knot nematode test site is located at Compounds in Dongfang City of Hainan Province watermelon garden.Peak period dispenser is endangered in root-knot nematode, is used
Pouring method.Using 20% Fosthiazate aqueous emulsion, 5% betacyfluthrin aqueous emulsion, medicament, experiment set 7 medicines altogether as a contrast
Agent is handled, and each handles 3 repetitions.Cornerwise five of area is throughout managed before dispenser selects investigation watermelon seedling illness radix, every point
Investigate 10 plants of watermelons.It 7 days after dispenser, respectively investigates a control effect within 30 days, 100 days, records diseased plant number, calculate control effect,
Test result is as shown in table 3.
The test result of table 3, fosthiazate and betacyfluthrin mixture prevention root-knot nematode
As can be seen from Table 3 to the preventive effect of root-knot nematode after fosthiazate and betacyfluthrin compounding 7d, 30d, 100d
It is intended to be apparently higher than that 20% Fosthiazate aqueous emulsion single dose of the same period uses and 5% betacyfluthrin aqueous emulsion single dose uses, says
Bright fosthiazate and betacyfluthrin compounding can improve the preventive effect to root-knot nematode compared with two kinds of single doses are used alone, together
When medicine after 100d preventive effects still up to 90% or more, illustrate have good lasting effect, do not find the compound drug to west during experiment
Melon generates poisoning.
Pratylenchus test site is located at the Huizhou towns Li Lin cucumber garden.Peak period is endangered in pratylenchus to apply
Medicine, using the method for pouring.Using 20% Fosthiazate aqueous emulsion, 5% betacyfluthrin aqueous emulsion, medicament, experiment are total as a contrast
If 7 chemicals treatments, 3 repetitions are each handled.The cornerwise five points investigation cucumber illness radix in area is throughout managed before dispenser,
10 plants of cucumber of every investigation.7 days after dispenser, respectively control effect of investigation, record diseased plant number calculate prevention effect within 30 days, 100 days
Fruit, test result are as shown in table 4.
The test result of table 4, fosthiazate and betacyfluthrin mixture prevention pratylenchus
As can be seen from Table 4 to the preventive effect of pratylenchus after fosthiazate and betacyfluthrin compounding 7d, 30d, 100d
It is intended to be apparently higher than that 20% fosthiazate EW single doses of the same period use and 5% betacyfluthrin EW single doses use, illustrates fosthiazate
The preventive effect that can be improved compared with two kinds of single doses are used alone to pratylenchus is compounded with betacyfluthrin, while after medicine
100d preventive effects illustrate there is good lasting effect still up to 90% or more, do not find that the compound drug generates cucumber during experiment
Poisoning.
Embodiment 8：Root-knot nematode, pratylenchus test the drug resistance indoor measurement of fosthiazate betacyfluthrin
It is configured to fosthiazate, betacyfluthrin active compound to test required test medicine.Worm sources are acquired from Guangdong Province
Huizhou City and Compounds in Dongfang City of Hainan Province.Experiment uses dip method, a concentration of root-knot nematode that test medicine uses, pratylenchus
50%-90% lethal doses, test worm is impregnated in treatment fluid, and dead test worm is rejected after 24 hours, and the test worm left continues
Indoor raising handles 20 generation test worms repeatedly.If the liquid processing containing only auxiliary agent is blank control.Measure each medicament pair the 1st
The half lethal concentration LC in generation, the 5th generation, the 10th generation and the 20th generation test worm50, by comparing each treatment agent to 1st generation, the 5th generation, the
The LC in 10 generations and the 20th generation test worm50The drug resistance of reagent agent is changed to evaluate test worm.
According to table 5, table 6 as can be seen that after fosthiazate and betacyfluthrin complex preparation 20 generation test worms of processing, test worm
Population handles what 20 generation test worms generated to the drug resistance of the complex preparation significantly lower than fosthiazate and betacyfluthrin single dose
Drug resistance.This experiments have shown that, fosthiazate and betacyfluthrin compounding can effectively delay root-knot nematode, pratylenchus production
Raw drug resistance.
The measurement test result of table 5, fosthiazate and betacyfluthrin compounding to root-knot nematode drug resistance
Note：Above table medium multiple indicates drug resistance of the corresponding algebraically root-knot nematode to each medicament.
The measurement test result of table 6, fosthiazate and betacyfluthrin compounding to pratylenchus drug resistance
Note：Above table medium multiple indicates drug resistance of the corresponding algebraically pratylenchus to each medicament.
In conclusion the present invention uses two kinds of active components for the complex composition of fosthiazate and betacyfluthrin,
Compared with existing single formulation, not only there is apparent synergistic effect, also there is good nematicidal effect, the lasting period is long,
To Crop securify, the generation of pest resistance to insecticide can be slowed down, be worth promoting and applying in agricultural production.
Claims (1)
1. a kind of composition pesticide containing fosthiazate and betacyfluthrin, it is characterised in that weight ratio is：Fosthiazate with
Betacyfluthrin 1-50%, wetting agent 0.5-2.5%, dispersant 2-5%, antifreezing agent 3-4%, thickener 1-4%, antifoaming agent
0.1-1%, pH adjusting agent 0.1-0.5%, water surplus；Fosthiazate is 1 with betacyfluthrin weight ratio:25~25:1；First
Other auxiliary agents are mixed, shear-mixed is uniform in cutter, and active ingredient is then added, and 2-3h is ground in ball crusher, makes
Grain diameter is below 5mm, and obtains nematicidal composition aqueous suspension formulations.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510214658.7A CN104824017B (en) | 2015-04-29 | 2015-04-29 | A kind of composition pesticide containing fosthiazate and betacyfluthrin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510214658.7A CN104824017B (en) | 2015-04-29 | 2015-04-29 | A kind of composition pesticide containing fosthiazate and betacyfluthrin |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104824017A CN104824017A (en) | 2015-08-12 |
| CN104824017B true CN104824017B (en) | 2018-09-28 |
Family
ID=53802549
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510214658.7A Active CN104824017B (en) | 2015-04-29 | 2015-04-29 | A kind of composition pesticide containing fosthiazate and betacyfluthrin |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104824017B (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL2012409B1 (en) * | 2014-03-12 | 2015-11-26 | Saba Dinxperlo B V | Improved low pressure 2-K handheld spray gun. |
| CN105076202A (en) * | 2015-08-27 | 2015-11-25 | 广东中迅农科股份有限公司 | Microcapsule suspension containing fosthiazate and beta-cyfluthrin |
| CN106495930A (en) * | 2016-09-13 | 2017-03-15 | 佛山市盈辉作物科学有限公司 | A kind of medicine fertilizer composition containing fosthiazate and betacyfluthrin |
| CN107467016A (en) * | 2017-08-21 | 2017-12-15 | 山东华阳农药化工集团有限公司 | A kind of preparation method of ultra-low volume fosthiazate finish and its compound chrysanthemum ester type compound finish |
| CN114982776A (en) * | 2022-05-17 | 2022-09-02 | 中研瑞科科技(北京)有限公司 | Fullerene functional liquid for preventing and treating root knot nematode disease of crops and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101444210A (en) * | 2008-12-27 | 2009-06-03 | 深圳诺普信农化股份有限公司 | Desinsection composite with synergy and application thereof |
| CN102326579A (en) * | 2011-07-19 | 2012-01-25 | 陕西上格之路生物科学有限公司 | Insecticidal composition containing cycloxaprid and synthetic pyrethroid insecticides |
| CN103416426A (en) * | 2012-05-23 | 2013-12-04 | 陕西韦尔奇作物保护有限公司 | Insecticide composition containing fosthiazate and pyrethroids |
-
2015
- 2015-04-29 CN CN201510214658.7A patent/CN104824017B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101444210A (en) * | 2008-12-27 | 2009-06-03 | 深圳诺普信农化股份有限公司 | Desinsection composite with synergy and application thereof |
| CN102326579A (en) * | 2011-07-19 | 2012-01-25 | 陕西上格之路生物科学有限公司 | Insecticidal composition containing cycloxaprid and synthetic pyrethroid insecticides |
| CN103416426A (en) * | 2012-05-23 | 2013-12-04 | 陕西韦尔奇作物保护有限公司 | Insecticide composition containing fosthiazate and pyrethroids |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104824017A (en) | 2015-08-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104824017B (en) | A kind of composition pesticide containing fosthiazate and betacyfluthrin | |
| CN104126602A (en) | Dispersible oil suspending agent containing pymetrozine and dinotefuran | |
| CN104663693B (en) | A kind of composition of containing pyriminostrobin and its application | |
| CN104365606B (en) | Dihalo pyrazole amide and Tolfenpyrad complex insecticidal composition | |
| CN104106593B (en) | A kind of insecticide acaricide composition that contains sulfur-phosphor and second mite azoles | |
| CN105707118B (en) | A kind of composition pesticide containing phosmet and Bifenazate | |
| CN104585224A (en) | Pesticide composition containing fluensulfone and pyrethroid insecticide | |
| CN101617676B (en) | Pesticide compound | |
| CN104814031B (en) | A kind of Pesticidal combination containing butene-fipronil and clothianidin | |
| CN102428922A (en) | Diacylhydrazine pesticide compounded pesticidal composition | |
| CN102210320A (en) | Sulfoxaflor-containing insecticidal composition | |
| CN104855399B (en) | A kind of Pesticidal combination containing butene-fipronil and fluorobenzene insect amide | |
| CN104222124A (en) | Spinetoram and bistrifluron compounded composition | |
| CN104920391B (en) | A kind of miticide composition containing cycloxaprid and chlorine fluorine cyanogen insect amide | |
| CN103271081B (en) | Etoxazole-triazophospesticide pesticide composition | |
| CN102440260A (en) | Insecticidal composition comprising sulfoxaflor and cyhalothrin | |
| CN104255751A (en) | Mite-killing composition containing etoxazole and vermectin | |
| CN105941423B (en) | A kind of Pesticidal combination containing capillary and cyromazine | |
| CN104855404B (en) | A kind of Pesticidal combination containing four chlorantraniliproles and diafenthiuron | |
| CN103271078A (en) | Etoxazole-profenofos pesticide composition | |
| CN104255735A (en) | Pyridalyl and tetra-chlorantraniliprole compounded insecticidal composition | |
| CN104255759B (en) | Containing the Pesticidal combination of matrine and metaflumizone | |
| CN104082322B (en) | A kind of containing Nylar with the insecticide acaricide composition of Bifenazate | |
| CN103749530B (en) | A kind of Pesticidal combination containing Avermectin | |
| CN103053573B (en) | Pesticide composition of metaflumizone and chromafenozide |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20230807 Address after: 414000 No. 16 Yangfan Avenue, Green Chemical High tech Industrial Development Zone, Yueyang City, Hunan Province Patentee after: HUNAN AGRICULTURAL UNIVERSITY HEARTALE CHEMURGY CO.,LTD. Address before: 516000 Zhongkai hi tech Development Zone 24, Huizhou, Guangdong Patentee before: GUANGDONG ZHONGXUN AGRICULTURAL TECHNOLOGY Co.,Ltd. |