CN103749530B - A kind of Pesticidal combination containing Avermectin - Google Patents
A kind of Pesticidal combination containing Avermectin Download PDFInfo
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- CN103749530B CN103749530B CN201310746293.3A CN201310746293A CN103749530B CN 103749530 B CN103749530 B CN 103749530B CN 201310746293 A CN201310746293 A CN 201310746293A CN 103749530 B CN103749530 B CN 103749530B
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- avermectin
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- imicyafos
- pesticidal combination
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Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a kind of Pesticidal combination containing Avermectin, in composition, the ratio of weight and number of active ingredient imicyafos and Avermectin is 1 ~ 50: 10 ~ 0.1, on the basis of test recipe screening targetedly, can by the ratio of weight and number of active ingredient imicyafos and Avermectin more preferably 5 ~ 30: 3 ~ 0.1, the formulations of pesticide that the preparation method of agricultural insecticide composition field of pesticide preparation of the present invention can be prepared into are wetting powder, suspending agent, microemulsion, aqueous emulsion and water dispersible granules, in preparation, active ingredient gross weight accounts for the portion rate of gross weight in preparation is 1% ~ 50%, on the basis of test recipe screening targetedly, can by the ratio of weight and number of active ingredient imicyafos in preparation and Avermectin more preferably 1% ~ 25%, all the other components are usual auxiliaries in agricultural chemicals.Said composition two kinds of compositions are composite has notable synergistic effect, and insecticidal spectrum is wide, and consumption is few, and preventive effect is high, and residual few, the lasting period is long, is conducive to environmental protection.
Description
Technical field
The present invention relates to technical field of pesticide combination, be specifically related to a kind of Pesticidal combination containing Avermectin.
Background technology
Imicyafos (AKD-3088) is a kind of cyanamide heterocyclic organic matter, it is combined by the sub-imidazolidine of cyano group of asymmetric organic phosphor and nicotinic insecticide, can be used for the crops such as radish, carrot, strawberry, eggplant, tomato, cucumber, muskmelon, watermelon, sweet potato and potato, its chemical structural formula is:
Avermectin, English common name Abamectin is a kind of macrolide disaccharide compounds, is isolated biopesticide from edaphon.It has tags and stomach poison function have faint fumigation action, without systemic action, has very strong osmosis to plant leaf blade, can kill insect under epidermis, and the lasting period is long.Its mechanism of action is different from chemical insecticide, and its interference neurophysiology is movable, stimulates release γ-aminobutyric acid.Thus Avermectin is widely used in chemical insecticide composite, to expand insecticidal spectrum, improve drug effect and reduce costs.It can be used for preventing and treating the various pests such as various insects, pear sucker, cabbage caterpillar, diamond-back moth, beet armyworm, apple leaf miner, leaf miner, Liriomyza, Americal rice leaf miner and vegetables trialeurodes vaporariorum, and especially have special efficacy to root-knot nematode, its chemical structural formula is as follows:
Avermectin is after Long-Time Service, and the resistance of insect to it strengthens year by year, and pesticide dosage is constantly increased, and causes the adverse consequencess such as high poison, consumption are large, residual many, drug effect is poor.And use the insecticide of one-component, easily causing insect to develop immunity to drugs is the problem demanding prompt solution faced in current Pesticide use process, and formulate that new and effective Pesticidal compound has high input, the cycle is long, research strength requirement is higher, does not meet the present situation of agricultural chemicals enterprise of current China.And between agricultural chemicals between compositely can solve that agricultural chemicals single dose toxicity is large, the problem of weak effect, less investment again, R&D cycle short applicable domestic agricultural chemicals enterprise present situation, and the mutual use between different agricultural chemicals can the drug-fast generation of retarding action thing, have ideal result of use, therefore between the different mechanism of action, agricultural chemicals composite is the study hotspot of current pesticide field.
Summary of the invention
In order to solve above technical problem; the present invention proposes a kind of Pesticidal combination containing Avermectin, said composition contains A, B two kinds of effective active components, and component A is selected from imicyafos; B is selected from Avermectin; the present composition two kinds of compositions are composite has notable synergistic effect, and insecticidal spectrum is wide, and consumption is few; preventive effect is high; residual few, the lasting period is long, is conducive to environmental protection.
The present invention is a kind of Pesticidal combination preparation containing Avermectin, wherein in Pesticidal combination of the present invention, the ratio of weight and number of active ingredient imicyafos and Avermectin is 1 ~ 50: 10 ~ 0.1, on the basis of the screening of test recipe targetedly, can by the ratio of weight and number of active ingredient imicyafos and Avermectin more preferably 5 ~ 30: 3 ~ 0.1.
The formulations of pesticide that the preparation method of agricultural insecticide composition field of pesticide preparation of the present invention can be prepared into are wetting powder, suspending agent, microemulsion, aqueous emulsion and water dispersible granules, in preparation, active ingredient gross weight accounts for the portion rate of gross weight in preparation is 1% ~ 50%, on the basis of test recipe screening targetedly, can by the ratio of weight and number of active ingredient imicyafos in preparation and Avermectin more preferably 1% ~ 25%, all the other components are usual auxiliaries in agricultural chemicals.
When above-described Pesticidal combination is microemulsion, in preparation, the ratio of weight and number of each component is:
The concrete production stage of this microemulsion is: former medicine imicyafos, Avermectin cosolvent are dissolved completely, then adds other compositions such as emulsifier, antifreezing agent stabilizing agent, and Homogeneous phase mixing, finally adds water, can be made into microemulsion after fully stirring.
When above-described Pesticidal combination is wetting powder, in preparation, the ratio of weight and number of each component is:
The concrete procedure of processing of this Pesticidal combination wetting powder is: by above-mentioned formula by active principle A and active principle B and the mixing of dispersant, wetting agent and filler, uniform stirring in stirred tank, mixing after airslide disintegrating mill, namely can be made into the wetting powder of the present composition.
When above-described Pesticidal combination is suspending agent, in preparation, the ratio of weight and number of each component is:
The concrete production stage of this suspending agent is for first to mix other auxiliary agents, mix through high speed shear, add active principle A and active principle B, abrading-ball 2 ~ 3 hours in ball crusher, make a diameter all at below 5mm, the aqueous suspension formulations of obtained Pesticidal combination of the present invention.
When above-described Pesticidal combination is aqueous emulsion, in preparation, the ratio of weight and number of each component is:
The concrete production stage of this aqueous emulsion is: first former medicine active principle A and active principle B, solvent and emulsifier, cosolvent are added together, and makes to be dissolved into uniform oil phase; By part water, antifreeze, other the insecticides adjuvant such as antimicrobial mixes uniformly aqueous phase; While high-speed stirred, oil phase is added aqueous phase in a kettle., slowly add water until reach phase inversion point, open clipper and carry out high speed shear, and add remaining water, shear about half an hour, form the aqueous emulsion of oil-in-water type.The i.e. aqueous emulsion of obtained Pesticidal combination of the present invention.
When above-described Pesticidal combination is water dispersible granules, in preparation, the ratio of weight and number of each component is:
The concrete procedure of processing of this Pesticidal combination water dispersible granules is: active principle A, active principle B and dispersant, wetting agent, disintegrant and filler are mixed by above-mentioned formula, pulverize with micro jet, through mediating, then add in fluidized-bed granulation dryer and carry out through sample analysis after granulation, drying, screening, be i.e. the water dispersible granules of obtained Pesticidal combination of the present invention.
Described emulsifier is selected from least one in calcium dodecyl benzene sulfonate and aliphatic acid polyethenoxy ether, alkylphenol polyoxyethylene sulfosuccinate, styrylphenol polyoxyethylene ether, polyoxyethylene nonylphenol ether, castor oil polyoxyethylene ether, aliphatic acid polyethenoxy base ester, polyoxyethylene aliphatic alcohol ether.
Described solvent is at least one in dimethylbenzene or biodiesel, toluene, diesel oil, methyl alcohol, ethanol, n-butanol, isopropyl alcohol, turpentine oil, solvent naphtha, dimethyl formamide, dimethyl sulfoxide (DMSO), water equal solvent.
Described dispersant is selected from least one in polycarboxylate, lignosulfonates, alkylphenol polyoxyethylene formaldehyde condensation products sulphate, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol polyoxyethylene, aliphatic amine polyoxyethylene ether, polyoxyethylene carboxylate, fatty acid glyceride APEO.
Described wetting agent is selected from lauryl sodium sulfate, calcium dodecyl benzene sulfonate, at least one pulled open in powder copper rosinate X., wetting and penetrating agent F, alkylnaphthalene sulfonate, polyoxyethylene tri-styryl phosphenylic acid salt, spaonin powder, silkworm excrement, soapberry powder.
Described disintegrant is selected from least one in bentonite, urea, ammonium sulfate, aluminium chloride, citric acid, succinic acid, sodium bicarbonate.
Described thickener is selected from least one in xanthans, CMC, hydroxyethylcellulose, methylcellulose, Magnesiumaluminumsilicate, polyvinyl alcohol.
Described stabilizing agent is selected from least one in sodium citrate, resorcinol.
Described antifreezing agent is selected from least one in ethylene glycol, propane diols, glycerine.
Described defoamer is selected from silicone oil, silicone compound, C
10-20saturated fat acid compounds, C
8-10at least one in aliphatic alcohols compound.
Described filler is selected from least one in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, precipitated calcium carbonate.
Pesticidal combination of the present invention can prevent and treat nematoda, etc. the various insects such as sufficient class, coleoptera class pest, Lepidoptera class pest, gastropod, orthoptera pest, plant parasitic acarid class, Thysanoptera, Diptera pest, Hymenoptera insect, hidden wing order insect, Anoplura insect, Isoptera insect, Hemipteran pest, damp insects, centipede insects, thousand-legger class.Especially to destroying the insect of agriculture horticultural crop and trees etc. in soil, destroying the insect of the seed of agriculture horticultural crop and trees, such as nematoda, etc. sufficient class, coleoptera class pest, Lepidoptera class pest, gastropod, orthoptera pest, plant parasitic acarid class, Hemipteran pest preventive effect remarkable.
The above nematode pests comprises the pratylenchus classes such as pratylenchus, pseudo-Pratylenchidae, Lu Si Pratylenchidae, disability Pratylenchidae, the Cyst nematode such as soybean cyst nematode Heterodera glycines, globodera rostochiensis class, the root-knot nematode such as peanut root-knot nematode, Meloidogyne incognita class, the Aphelenchoidea classes such as aphelenchoides besseyi, leaf bud nematode, species of Tylenchorhynchus Nematodes class, loop wire insects, needlework insects, long capsule nematoda, burr nematoda, nematode on strawberry, pine wood nematode.All favorable effect is had in addition to insects such as aphid, leafhopper, plant hopper, chrysomelid, wireworm, cutworm, diamond-back moth, imported cabbageworm, rice thripses.
Agricultural insecticide composition of the present invention is especially to anti-eliminate aphis section, Aleyrodidae, Cicadellidae and Delphacidae insect, and the various pests such as especially various insects, pear sucker, cabbage caterpillar, diamond-back moth, beet armyworm, apple leaf miner, leaf miner, Liriomyza, Americal rice leaf miner and vegetables trialeurodes vaporariorum have efficient effect.
In addition, Pesticidal combination of the present invention compares similar medicament other advantages a lot, first, by Avermectin and novel pesticide imicyafos composite, improve the insecticide efficiency of Avermectin, delay the resistance of insect to novel pesticide imicyafos, compared respective single dose sphere of action wider, improve disinsection efficiency; The second, delay the generation of pest resistance to insecticide, decreased agricultural chemicals Reusability number of times, reduce Pesticide use amount, reduce agricultural cost; 3rd, the residual quantity of this Pesticidal combination is lower, more friendly to environment, is significant to the safe edible of agricultural products.
Embodiment:
In order to make object of the present invention, technical scheme and advantage clearly understand, the following specific embodiment of the present invention is described, but the present invention is only limitted to absolutely not these examples.The method that the present invention adopts indoor bioassay and field trial to combine, if no special instructions, the ratio (comprising percentage) below mentioned is all ratio of weight and number.
Embodiment 1: by imicyafos10 part, Avermectin 0.5 part, lignosulfonates 5 parts, lauryl sodium sulfate 12 parts and the mixing of 72 parts, diatomite, uniform stirring in stirred tank, mixing after airslide disintegrating mill, i.e. the wetting powder of obtained Pesticidal combination of the present invention.
Embodiment 2: by imicyafos15 part, Avermectin 0.1 part, alkylphenol polyoxyethylene 8 parts, oxygen ethene triphenylethylene phosphenylic acid salt 15 parts and bentonite 68 parts mixing, uniform stirring in stirred tank, mixing after airslide disintegrating mill, i.e. the wetting powder of obtained Pesticidal combination of the present invention.
Embodiment 3: by imicyafos20 part, Avermectin 0.2 part, dispersant 10 parts, wetting agent 17 parts and filler 53 parts mixing, uniform stirring in stirred tank, is mixing after airslide disintegrating mill, the i.e. wetting powder of obtained Pesticidal combination of the present invention.
Embodiment 4: by alkylphenol polyoxyethylene 8 parts, glycerine 1 part, CMC 4 parts, silicone oil 1 part, the mixing of 62 parts, water, mix through high speed shear, add imicyafos14 part, Avermectin 0.1 part successively, abrading-ball 2 ~ 3 hours in ball crusher, make a diameter all at below 5mm, the aqueous suspension formulations of obtained Pesticidal combination of the present invention.
Embodiment 5: by dispersant 10 parts, antifreezing agent 2 parts, thickener 3 parts, defoamer 1 part, the mixing of 72 parts, water, mix through high speed shear, add imicyafos10 part, Avermectin 2 parts successively, abrading-ball 2 ~ 3 hours in ball crusher, make a diameter all at below 5mm, the aqueous suspension formulations of obtained Pesticidal combination of the present invention.
Embodiment 6: by dispersant 8 parts, antifreezing agent 2 parts, thickener 4 parts, defoamer 0.5 part, the mixing of 67 parts, water, mix through high speed shear, add imicyafos17 part, Avermectin 2 parts successively, abrading-ball 2 ~ 3 hours in ball crusher, make a diameter all at below 5mm, the aqueous suspension formulations of obtained Pesticidal combination of the present invention.
Embodiment 7: imicyafos20 part, Avermectin 0.5 part, 15 parts, turpentine oil, castor oil polyoxyethylene ether 5 parts, resorcinol 8 parts are mixed, is dissolved into uniform oil phase; Part water, propane diols 2 parts, silicone compound 1 part are mixed uniformly aqueous phase; While high-speed stirred, oil phase is added aqueous phase in a kettle., add polyvinyl alcohol 4 parts, slowly add water until reach phase inversion point, open clipper and carry out high speed shear, and add remaining water and supply 100 parts, shear about half an hour, form the aqueous emulsion of oil-in-water type.The i.e. aqueous emulsion of obtained Pesticidal combination of the present invention.
Embodiment 8: imicyafos25 part, Avermectin 0.1 part, solvent 20 parts, emulsifier 8 parts, stabilizing agent 10 parts are mixed, is dissolved into uniform oil phase; Part water, antifreezing agent 1 part, defoamer 2 parts are mixed uniformly aqueous phase; While high-speed stirred, oil phase is added aqueous phase in a kettle., add thickener 3 parts, slowly add water until reach phase inversion point, open clipper and carry out high speed shear, and add remaining water and supply 100 parts, shear about half an hour, form the aqueous emulsion of oil-in-water type.The i.e. aqueous emulsion of obtained Pesticidal combination of the present invention.
Embodiment 9: imicyafos15 part, Avermectin 1 part, solvent 18 parts, emulsifier 11 parts, stabilizing agent 8 parts are mixed, is dissolved into uniform oil phase; Part water, antifreezing agent 1 part, defoamer 2 parts are mixed uniformly aqueous phase; While high-speed stirred, oil phase is added aqueous phase in a kettle., add thickener 3 parts, slowly add water until reach phase inversion point, open clipper and carry out high speed shear, and add remaining water and supply 100 parts, shear about half an hour, form the aqueous emulsion of oil-in-water type.The i.e. aqueous emulsion of obtained Pesticidal combination of the present invention.
Embodiment 10: imicyafos18 part, Avermectin 0.5 part, aliphatic amine polyoxyethylene ether 12 parts, alkylnaphthalene sulfonate 12 parts, 5 parts, aluminium chloride and bentonite 53 parts are mixed, pulverize with micro jet, through mediating, then add in fluidized-bed granulation dryer and carry out through sample analysis after granulation, drying, screening, be i.e. the water dispersible granules of obtained Pesticidal combination of the present invention.
Embodiment 11: imicyafos20 part, Avermectin 0.1 part, dispersant 10 parts, wetting agent 10 parts, disintegrant 5 parts and filler 55 parts are mixed, pulverize with micro jet, through mediating, then add in fluidized-bed granulation dryer and carry out through sample analysis after granulation, drying, screening, be i.e. the water dispersible granules of obtained Pesticidal combination of the present invention.
Embodiment 12: imicyafos10 part, Avermectin 5 parts, dispersant 8 parts, wetting agent 12 parts, disintegrant 3 parts and filler 62 parts are mixed, pulverize with micro jet, through mediating, then add in fluidized-bed granulation dryer and carry out through sample analysis after granulation, drying, screening, be i.e. the water dispersible granules of obtained Pesticidal combination of the present invention.
Embodiment 13: former medicine imicyafos15 part, Avermectin 2 parts are dissolved completely with cosolvent, add other compositions such as aliphatic acid polyethenoxy base ester 10 parts, ethylene glycol 2 parts, sodium citrate 4 parts, resorcinol 4 parts again, Homogeneous phase mixing, finally add water, after fully stirring, can microemulsion be made into.
Embodiment 14: former medicine imicyafos20 part, Avermectin 0.3 part are dissolved completely with cosolvent, then add other compositions such as emulsifier 11 parts, antifreezing agent 2 parts, stabilizing agent 7 parts, Homogeneous phase mixing, finally adds water, can be made into microemulsion after fully stirring.
Embodiment 15: former medicine imicyafos10 part, Avermectin 1 part are dissolved completely with cosolvent, then add other compositions such as emulsifier 8 parts, antifreezing agent 2 parts, stabilizing agent 10 parts, Homogeneous phase mixing, finally adds water, can be made into microemulsion after fully stirring.
Indoor biometrics screening and field experiment:
The method that the present invention adopts indoor bioassay and field trial to combine.If no special instructions, the ratio (comprising percentage) below mentioned is all mass ratio.
Determination of activity example 1:
(1) reagent agent
The former medicine of 95%imicyafos, Japanese agricultural chemicals company Agro-Kanesho, the former medicine of 95% Avermectin, Qingdao KYX Chemical Co., Ltd. provides.
(2) for examination worm source
Indoor diamondback moth larvae of for many generations raising, indoor conditions: temperature (26 ± 2) DEG C, relative moisture 68% ± 5%, periodicity of illumination 16/8h (L/D).
(3) single dose assay method
Adopt dip method respectively two groups of former medicines all to be used a small amount of acetone solution, then be diluted to into the dense solution of 5 of equal difference with the Tween solution of 0.1%, be diluted in for subsequent use in beaker, and with clear water in contrast.
Diamondback moth larvae of the same size is flooded 5S in the liquid of leaching worm cage, and being placed on diameter after sucking unnecessary liquid is in the culture dish of 9cm, is placed with fresh vegetable leaf and adds a cover in ware.Every concentration process 10, repeats 4 times, if blank.Check lethality keep 24h in (27 ± 1) DEG C illumination box after, it is dead for touching polypide nonresponder by pulling needle.Lethality Abbott formula correction, then according to log concentration---lethality probit value analyzes (Bliss) method, obtains virulence regression equation and puts dead middle amount LC
50value.
(4) the joint toxicity measuring method of different ratio
According to the toxicity test result of single dose, by active ingredient 20% ratio of weight and number imicyafos: Avermectin is respectively 19.9:0.1,19.5:0.5,19:1,18:2,17:3.
Adopt above-mentioned 1.3 methods to carry out toxicity test, calculate LC
50, and press abundant method calculating co-toxicity coefficient (CTC) of Sun Yun.Co-toxicity coefficient CTC, computing formula is as follows: (take imicyafos as standard agent, its toxicity index is 100):
The LC of toxicity index (the TI)=imicyafos of Avermectin
50the LC of/Avermectin
50× 100
The LC of actual toxicity index (the ATI)=imicyafos of M
50the LC of/M
50× 100
TI × P Avermectin of TI × P imicyafos+ Avermectin of theoretical toxicity index (the TTI)=imicyafos of M
TTI × 100 of the ATI/M of co-toxicity coefficient (the CTC)=M of M
In formula:
M is the mixture of Avermectin and imicyafos different ratio
P Avermectin is the ratio of Avermectin shared by mixture
P imicyafos is the ratio of imicyafos shared by mixture
(5) toxicity test result and analysis
The indoor measurement result of table 1imicyafos, Abamectin on Plutella
As can be seen from the table, in the mixture of different proportion, its co-toxicity coefficient is all greater than 120, shows certain synergistic effect, wherein imicyafos: Avermectin be 19.5: 0.5 synergistic effect the most obvious, co-toxicity coefficient is 189.00.Result of the test shows, Avermectin, imicyafos two kinds of medicaments all have higher activity to diamond-back moth in room conditions, the result of the test of different proportion proportioning shows, by active ingredient imicyafos: when Avermectin is 19.9:0.1,19.5:0.5,19:1,18:2,17:3, all show stronger synergistic effect, wherein with imicyafos: when Avermectin is 19.5: 0.5, synergistic effect is best.Suggestion carries out further field control effectiveness test to the mixture preparation of suitable proportion about 19.5:0.5 scope, to evaluate its field practical application effect.
Field experiment: field experiment control wild cabbage damage by disease and insect
(1) test method
Test sprays medicine 1 time altogether, and the dispenser date is on June 18th, 2012.Now wild cabbage not yet balling, diamondback moth larvae major part was in for 2 ~ 3 length of times, and during spray medicine, weather is cloudy calm, and with sharp agriculture board level pressure knapsack hand sprayer to each process even spraying, leave dual sides all requires to be sprayed with effect liquid, every community liquid 2L.
(2) investigation method
Investigate each community and fix 15 strain wild cabbages as investigation strain, record the larva quantity on whole blade, before spraying medicine, investigate insect population radix, respectively 3,7 days and investigation in 10 days borer population alive after spray medicine.This test investigates 3 times altogether.
(3) drug effect computational methods
Live before Revision insect recluced rate (%)=(borer population of living after borer population one dispenser of living before dispenser)/dispenser borer population * l00.
Preventive effect (%)=(treatment region Revision insect recluced rate-check plot Revision insect recluced rate)/(100-check plot Revision insect recluced rate) * 100.
(4) poisoning investigation method
After dispenser, continuous 10d estimates medicament does not have poisoning to produce to crop, wild cabbage well-grown.
(5) field control effectiveness test result of the test
Table 2 treatment agent control diamond-back moth field control effectiveness test result
As can be seen from Table 2,19.5%imicyafos+0.5% Avermectin is that the successful of the mixture combination control diamond-back moth of 19.5: 0.5 is better than 1.8% Avermectin EC, 20%imicyafos SC and contrasts single dose, 19.5%imicyafos+0.5% Avermectin insecticidal effect of 7 days after medicine is respectively 92.33%, 93.84% and 94.52%, and insecticidal effect increases progressively along with the increase of consumption.In addition within the scope of test dose, plant growth is normal, and the poisoning phenomenon to wild cabbage does not all appear in each treatment agent, illustrates that it is safe to wild cabbage.
Claims (1)
1. the Pesticidal combination containing Avermectin, it is characterized in that: containing A in Pesticidal combination of the present invention, B two kinds of effective active components, component A is selected from imicyafos, B is selected from Avermectin, the ratio of weight and number of active ingredient imicyafos and Avermectin is 5 ~ 30: 3 ~ 0.1, the formulations of pesticide that the preparation method of this Pesticidal combination field of pesticide preparation can be prepared into are wetting powder, suspending agent, microemulsion, aqueous emulsion and water dispersible granules, in preparation, active ingredient gross weight accounts for the portion rate of gross weight in preparation is 1% ~ 25%, all the other are usual auxiliaries in agricultural chemicals.
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| CN1909781A (en) * | 2004-01-23 | 2007-02-07 | 石原产业株式会社 | Noxious organism controlling composition and method for controlling the noxious organism |
| CN101617688A (en) * | 2009-08-12 | 2010-01-06 | 深圳诺普信农化股份有限公司 | Pesticide composition containing thiacloprid |
| CN101642131A (en) * | 2009-09-08 | 2010-02-10 | 深圳诺普信农化股份有限公司 | Pesticide composition |
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| CN101617688A (en) * | 2009-08-12 | 2010-01-06 | 深圳诺普信农化股份有限公司 | Pesticide composition containing thiacloprid |
| CN101642131A (en) * | 2009-09-08 | 2010-02-10 | 深圳诺普信农化股份有限公司 | Pesticide composition |
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Address after: Fuchuan Yao Autonomous County of Fuyang New Town Road 542700 the Guangxi Zhuang Autonomous Region Hezhou City No. 34 Patentee after: Gu Xiangmao Address before: 266000 Licang, Qingdao, No. nine East water road, No. 320, No. Patentee before: Gu Xiangmao |
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Address after: 266000 Licang, Qingdao, No. nine East water road, No. 320, No. Patentee after: Gu Xiangmao Address before: Fuchuan Yao Autonomous County of Fuyang New Town Road 542700 the Guangxi Zhuang Autonomous Region Hezhou City No. 34 Patentee before: Gu Xiangmao |
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Address after: 266700 Qingnian Road 5, Cui Jia town, Pingdu City, Shandong Province, No. 5 Patentee after: Gu Xiangmao Address before: 266000 Licang, Qingdao, No. nine East water road, No. 320, No. Patentee before: Gu Xiangmao |
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Effective date of registration: 20181101 Address after: 530000 14 14 Anji Road, Nanning, the Guangxi Zhuang Autonomous Region, 14 Patentee after: Guangxi Jing Lida Construction Engineering Co., Ltd. Address before: 266700 Qingnian Road 5, Cui Jia Ji Town, Pingdu City, Qingdao, Shandong Patentee before: Gu Xiangmao |
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Address after: 530000 No. 14-4, 14 blocks, Yihe Garden District, 13 Anji Avenue, Nanning City, Guangxi Zhuang Autonomous Region Patentee after: Guangxi Jing Lida Construction Engineering Co., Ltd. Address before: 530000 14 14 Anji Road, Nanning, the Guangxi Zhuang Autonomous Region, 14 Patentee before: Guangxi Jing Lida Construction Engineering Co., Ltd. |