CN103749531B - A kind of Pesticidal combination containing matrine - Google Patents
A kind of Pesticidal combination containing matrine Download PDFInfo
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- CN103749531B CN103749531B CN201310752703.5A CN201310752703A CN103749531B CN 103749531 B CN103749531 B CN 103749531B CN 201310752703 A CN201310752703 A CN 201310752703A CN 103749531 B CN103749531 B CN 103749531B
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- matrine
- pesticidal combination
- imicyafos
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- 229920001285 xanthan gum Polymers 0.000 description 1
Abstract
The present invention relates to a kind of Pesticidal combination containing matrine, its active ingredient is Imicyafos and matrine two yuan of mixtures, and the ratio of weight and number of two kinds of active ingredients is 1 ~ 50: 50 ~ 1, and preferred weight portion rate is 5 ~ 25: 30 ~ 3; The parts by weight content that in Pesticidal combination, active ingredient is total is 1% ~ 80%; preferred weight number content is 5% ~ 40%; all the other are allow in agricultural chemicals to use and acceptable auxiliary element, and can be prepared into wetting powder, suspending agent, microemulsion, aqueous emulsion and water dispersible granules by known method, it is wide that the present composition has effect field; insecticide efficiency is high; and consumption is few, preventive effect is high, residual few; lasting period is long, is conducive to environmental protection.
Description
Technical field
The present invention relates to technical field of pesticide combination, be specifically related to a kind of Pesticidal combination containing matrine.
Background technology
Imicyafos (AKD-3088) is a kind of cyanamide heterocyclic organic matter, it is combined by the sub-imidazolidine of cyano group of asymmetric organic phosphor and nicotinic insecticide, can be used for the crops such as radish, carrot, strawberry, eggplant, tomato, cucumber, muskmelon, watermelon, sweet potato and potato, its chemical structural formula is:
Matrine is made up through Solvent Extract methods such as ethanol of the root of Chinese herbal medicine kuh-seng, stem, leaf, fruit, it is alkaloid, be generally Banlangen, its composition mainly contains the multiple alkaloids such as matrine, oxymatrine, sophocarpine, N-Oxysophocarpine, Sophoridine, the highest with the content of matrine, oxymatrine.Matrine is agricultural chemical of natural plant, there is stomach toxicity and action of contace poison, matrine is to people and animals' low toxicity, it is broad spectrum pesticide, can be used to prevent and treat rice hoppers, striped rice borer, paddy stem borer, brassicaceous vegetable aphid, cabbage caterpillar, diamond-back moth, leek fragrant-flowered garlic maggot, tea tree tea caterpillar, tea chi Qu, the pests such as tobacco oriental tobacco budworm, cigarette aphid.
Matrine is after Long-Time Service, and the resistance of insect to it strengthens year by year, and pesticide dosage is constantly increased, and causes the adverse consequencess such as high poison, consumption are large, residual many, drug effect is poor.And use the insecticide of one-component, easily causing insect to develop immunity to drugs is the problem demanding prompt solution faced in current Pesticide use process, and formulate that new and effective Pesticidal compound has high input, the cycle is long, research strength requirement is higher, does not meet the present situation of agricultural chemicals enterprise of current China.And between agricultural chemicals between compositely can solve that agricultural chemicals single dose toxicity is large, the problem of weak effect, less investment again, R&D cycle short applicable domestic agricultural chemicals enterprise present situation, and the mutual use between different agricultural chemicals can the drug-fast generation of retarding action thing, have ideal result of use, therefore between the different mechanism of action, agricultural chemicals composite is the study hotspot of current pesticide field.
Summary of the invention
According to the deficiencies in the prior art; the present invention proposes a kind of Pesticidal combination containing matrine, said composition contains A, B two kinds of effective active components, and component A is selected from imicyafos; B is selected from matrine; it is wide that the present composition has effect field, and insecticide efficiency is high, and consumption is few; preventive effect is high; residual few, the lasting period is long, is conducive to environmental protection.
The present invention be a kind of with novel dose of imicyafos and matrine for active ingredient carries out the Pesticidal combination preparation of two yuan of mixtures, wherein in Pesticidal combination of the present invention, the ratio of weight and number of active ingredient novel pesticide imicyafos and matrine is 1 ~ 50: 1 ~ 50, on the basis of test recipe screening targetedly, the ratio of weight and number of novel for active ingredient dose imicyafos and matrine can be preferably 5 ~ 25: 3 ~ 30.
The formulations of pesticide that the preparation method of agricultural insecticide composition field of pesticide preparation of the present invention can be prepared into are wetting powder, suspending agent, microemulsion, aqueous emulsion and water dispersible granules, in preparation, active ingredient gross weight accounts for the portion rate of gross weight in preparation is 1% ~ 80%, on the basis of test recipe screening targetedly, in preparation, active ingredient gross weight accounts for the portion rate of gross weight in preparation and is preferably 5% ~ 40%, and all the other are usual auxiliaries in agricultural chemicals.
When above-described Pesticidal combination is microemulsion, in preparation, the ratio of weight and number of each component is:
The concrete production stage of this microemulsion is: former medicine imicyafos, matrine cosolvent are dissolved completely, then adds other compositions such as emulsifier, antifreezing agent stabilizing agent, and Homogeneous phase mixing, finally adds water, can be made into microemulsion after fully stirring.
When above-described Pesticidal combination is wetting powder, in preparation, the ratio of weight and number of each component is:
The concrete procedure of processing of this Pesticidal combination wetting powder is: by above-mentioned formula by active principle A and active principle B and the mixing of dispersant, wetting agent and filler, uniform stirring in stirred tank, mixing after airslide disintegrating mill, namely can be made into the wetting powder of the present composition.
When above-described Pesticidal combination is suspending agent, in preparation, the ratio of weight and number of each component is:
The concrete production stage of this suspending agent is for first to mix other auxiliary agents, mix through high speed shear, add active principle A and active principle B, abrading-ball 2 ~ 3 hours in ball crusher, make a diameter all at below 5mm, the aqueous suspension formulations of obtained Pesticidal combination of the present invention.
When above-described Pesticidal combination is aqueous emulsion, in preparation, the ratio of weight and number of each component is:
The concrete production stage of this aqueous emulsion is: first former medicine active principle A and active principle B, solvent and emulsifier, cosolvent are added together, and makes to be dissolved into uniform oil phase; By part water, antifreeze, other the insecticides adjuvant such as antimicrobial mixes uniformly aqueous phase; While high-speed stirred, oil phase is added aqueous phase in a kettle., slowly add water until reach phase inversion point, open clipper and carry out high speed shear, and add remaining water, shear about half an hour, form the aqueous emulsion of oil-in-water type.The i.e. aqueous emulsion of obtained Pesticidal combination of the present invention.
When above-described Pesticidal combination is water dispersible granules, in preparation, the ratio of weight and number of each component is:
The concrete procedure of processing of this Pesticidal combination water dispersible granules is: active principle A, active principle B and dispersant, wetting agent, disintegrant and filler are mixed by above-mentioned formula, pulverize with micro jet, through mediating, then add in fluidized-bed granulation dryer and carry out through sample analysis after granulation, drying, screening, be i.e. the water dispersible granules of obtained Pesticidal combination of the present invention.
Described emulsifier is selected from least one in calcium dodecyl benzene sulfonate and aliphatic acid polyethenoxy ether, alkylphenol polyoxyethylene sulfosuccinate, styrylphenol polyoxyethylene ether, polyoxyethylene nonylphenol ether, castor oil polyoxyethylene ether, aliphatic acid polyethenoxy base ester, polyoxyethylene aliphatic alcohol ether.
Described solvent is at least one in dimethylbenzene or biodiesel, toluene, diesel oil, methyl alcohol, ethanol, n-butanol, isopropyl alcohol, turpentine oil, solvent naphtha, dimethyl formamide, dimethyl sulfoxide (DMSO), water equal solvent.
Described dispersant is selected from least one in polycarboxylate, lignosulfonates, alkylphenol polyoxyethylene formaldehyde condensation products sulphate, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol polyoxyethylene, aliphatic amine polyoxyethylene ether, polyoxyethylene carboxylate, fatty acid glyceride APEO.
Described wetting agent is selected from lauryl sodium sulfate, calcium dodecyl benzene sulfonate, at least one pulled open in powder copper rosinate X., wetting and penetrating agent F, alkylnaphthalene sulfonate, polyoxyethylene tri-styryl phosphenylic acid salt, spaonin powder, silkworm excrement, soapberry powder.
Described disintegrant is selected from least one in bentonite, urea, ammonium sulfate, aluminium chloride, citric acid, succinic acid, sodium bicarbonate.
Described thickener is selected from least one in xanthans, CMC, hydroxyethylcellulose, methylcellulose, Magnesiumaluminumsilicate, polyvinyl alcohol.
Described stabilizing agent is selected from least one in sodium citrate, resorcinol.
Described antifreezing agent is selected from least one in ethylene glycol, propane diols, glycerine.
Described defoamer is selected from silicone oil, silicone compound, C
10-20saturated fat acid compounds, C
8-10at least one in aliphatic alcohols compound.
Described filler is selected from least one in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, precipitated calcium carbonate.
Pesticidal combination of the present invention can prevent and treat nematoda, etc. the various insects such as sufficient class, coleoptera class pest, Lepidoptera class pest, gastropod, orthoptera pest, plant parasitic acarid class, Thysanoptera, Diptera pest, Hymenoptera insect, hidden wing order insect, Anoplura insect, Isoptera insect, Hemipteran pest, damp insects, centipede insects, thousand-legger class.Especially to destroying the insect of agriculture horticultural crop and trees etc. in soil, destroying the insect of the seed of agriculture horticultural crop and trees, such as nematoda, etc. sufficient class, coleoptera class pest, Lepidoptera class pest, gastropod, orthoptera pest, plant parasitic acarid class, Hemipteran pest preventive effect remarkable.
The above nematode pests comprises the pratylenchus classes such as pratylenchus, pseudo-Pratylenchidae, Lu Si Pratylenchidae, disability Pratylenchidae, the Cyst nematode such as soybean cyst nematode Heterodera glycines, globodera rostochiensis class, the root-knot nematode such as peanut root-knot nematode, Meloidogyne incognita class, the Aphelenchoidea classes such as aphelenchoides besseyi, leaf bud nematode, species of Tylenchorhynchus Nematodes class, loop wire insects, needlework insects, long capsule nematoda, burr nematoda, nematode on strawberry, pine wood nematode.All favorable effect is had in addition to insects such as aphid, leafhopper, plant hopper, chrysomelid, wireworm, cutworm, diamond-back moth, imported cabbageworm, rice thripses.
Agricultural insecticide composition of the present invention is especially to anti-eliminate aphis section, Aleyrodidae, Cicadellidae and Delphacidae insect, and the various pests such as especially various insects, pear sucker, cabbage caterpillar, diamond-back moth, beet armyworm, apple leaf miner, leaf miner, Liriomyza, Americal rice leaf miner and vegetables trialeurodes vaporariorum have efficient effect.
Pesticidal combination of the present invention compares similar medicament other advantages a lot, first, by matrine and novel pesticide imicyafos composite, improve the insecticide efficiency of matrine, delay the resistance of insect to novel pesticide imicyafos, compare respective single dose sphere of action wider, improve disinsection efficiency; The second, delay the generation of pest resistance to insecticide, decreased agricultural chemicals Reusability number of times, reduce Pesticide use amount, reduce agricultural cost; 3rd, the residual quantity of this Pesticidal combination is lower, more friendly to environment, is significant to the safe edible of agricultural products.
Embodiment:
In order to make object of the present invention, technical scheme and advantage clearly understand, the following specific embodiment of the present invention is described, but the present invention is only limitted to absolutely not these examples.The method that the present invention adopts indoor bioassay and field trial to combine, if no special instructions, the ratio (comprising percentage) below mentioned is all ratio of weight and number.
Embodiment 1: by imicyafos20 part, matrine 6 parts, lignosulfonates 12 parts, lauryl sodium sulfate 10 parts and the mixing of 52 parts, diatomite, uniform stirring in stirred tank, mixing after airslide disintegrating mill, i.e. the wetting powder of obtained Pesticidal combination of the present invention.
Embodiment 2: by imicyafos6 part, matrine 26 parts, alkylphenol polyoxyethylene 8 parts, oxygen ethene triphenylethylene phosphenylic acid salt 12 parts and bentonite 48 parts mixing, uniform stirring in stirred tank, mixing after airslide disintegrating mill, i.e. the wetting powder of obtained Pesticidal combination of the present invention.
Embodiment 3: by imicyafos12 part, matrine 25 parts, dispersant 12 parts, wetting agent 10 parts and filler 41 parts mixing, uniform stirring in stirred tank, is mixing after airslide disintegrating mill, the i.e. wetting powder of obtained Pesticidal combination of the present invention.
Embodiment 4: by alkylphenol polyoxyethylene 12 parts, glycerine 1 part, CMC 5 parts, silicone oil 1 part, the mixing of 57 parts, water, mix through high speed shear, add imicyafos18 part, matrine 6 parts successively, abrading-ball 2 ~ 3 hours in ball crusher, make a diameter all at below 5mm, the aqueous suspension formulations of obtained Pesticidal combination of the present invention.
Embodiment 5: by dispersant 12 parts, antifreezing agent 2 parts, thickener 4 parts, defoamer 1 part, the mixing of 53 parts, water, mix through high speed shear, add imicyafos8 part, matrine 20 parts successively, abrading-ball 2 ~ 3 hours in ball crusher, make a diameter all at below 5mm, the aqueous suspension formulations of obtained Pesticidal combination of the present invention.
Embodiment 6: by dispersant 10 parts, antifreezing agent 2 parts, thickener 4 parts, defoamer 2 parts, the mixing of 56 parts, water, mix through high speed shear, add imicyafos18 part, matrine 8 parts successively, abrading-ball 2 ~ 3 hours in ball crusher, make a diameter all at below 5mm, the aqueous suspension formulations of obtained Pesticidal combination of the present invention.
Embodiment 7: imicyafos22 part, matrine 5 parts, 12 parts, turpentine oil, castor oil polyoxyethylene ether 7 parts, resorcinol 9 parts are mixed, is dissolved into uniform oil phase; Part water, propane diols 2 parts, silicone compound 1 part are mixed uniformly aqueous phase; While high-speed stirred, oil phase is added aqueous phase in a kettle., add polyvinyl alcohol 4 parts, slowly add water until reach phase inversion point, open clipper and carry out high speed shear, and add remaining water and supply 100 parts, shear about half an hour, form the aqueous emulsion of oil-in-water type.The i.e. aqueous emulsion of obtained Pesticidal combination of the present invention.
Embodiment 8: imicyafos8 part, matrine 13 parts, solvent 22 parts, emulsifier 8 parts, stabilizing agent 10 parts are mixed, is dissolved into uniform oil phase; Part water, antifreezing agent 1 part, defoamer 2 parts are mixed uniformly aqueous phase; While high-speed stirred, oil phase is added aqueous phase in a kettle., add thickener 3 parts, slowly add water until reach phase inversion point, open clipper and carry out high speed shear, and add remaining water and supply 100 parts, shear about half an hour, form the aqueous emulsion of oil-in-water type.The i.e. aqueous emulsion of obtained Pesticidal combination of the present invention.
Embodiment 9: imicyafos22 part, matrine 3 parts, solvent 20 parts, emulsifier 10 parts, stabilizing agent 8 parts are mixed, is dissolved into uniform oil phase; Part water, antifreezing agent 1 part, defoamer 2 parts are mixed uniformly aqueous phase; While high-speed stirred, oil phase is added aqueous phase in a kettle., add thickener 3 parts, slowly add water until reach phase inversion point, open clipper and carry out high speed shear, and add remaining water and supply 100 parts, shear about half an hour, form the aqueous emulsion of oil-in-water type.The i.e. aqueous emulsion of obtained Pesticidal combination of the present invention.
Embodiment 10: imicyafos19 part, matrine 6 parts, aliphatic amine polyoxyethylene ether 9 parts, alkylnaphthalene sulfonate 10 parts, 5 parts, aluminium chloride and bentonite 51 parts are mixed, pulverize with micro jet, through mediating, then add in fluidized-bed granulation dryer and carry out through sample analysis after granulation, drying, screening, be i.e. the water dispersible granules of obtained Pesticidal combination of the present invention.
Embodiment 11: imicyafos12 part, matrine 18 parts, dispersant 8 parts, wetting agent 10 parts, disintegrant 4 parts and filler 48 parts are mixed, pulverize with micro jet, through mediating, then add in fluidized-bed granulation dryer and carry out through sample analysis after granulation, drying, screening, be i.e. the water dispersible granules of obtained Pesticidal combination of the present invention.
Embodiment 12: imicyafos8 part, matrine 17 parts, dispersant 9 parts, wetting agent 12 parts, disintegrant 4 parts and filler 50 parts are mixed, pulverize with micro jet, through mediating, then add in fluidized-bed granulation dryer and carry out through sample analysis after granulation, drying, screening, be i.e. the water dispersible granules of obtained Pesticidal combination of the present invention.
Embodiment 13: former medicine imicyafos17 part, matrine 10 parts are dissolved completely with cosolvent, add other compositions such as aliphatic acid polyethenoxy base ester 10 parts, ethylene glycol 2 parts, sodium citrate 4 parts, resorcinol 4 parts again, Homogeneous phase mixing, finally add water, after fully stirring, can microemulsion be made into.
Embodiment 14: former medicine imicyafos22 part, matrine 8 parts are dissolved completely with cosolvent, then add other compositions such as emulsifier 11 parts, antifreezing agent 2 parts, stabilizing agent 7 parts, Homogeneous phase mixing, finally adds water, can be made into microemulsion after fully stirring.
Embodiment 15: former medicine imicyafos10 part, matrine 20 parts are dissolved completely with cosolvent, then add other compositions such as emulsifier 7 parts, antifreezing agent 2 parts, stabilizing agent 8 parts, Homogeneous phase mixing, finally adds water, can be made into microemulsion after fully stirring.
Indoor biometrics screening and field experiment:
The method that the present invention adopts indoor bioassay and field trial to combine.If no special instructions, the ratio (comprising percentage) below mentioned is all mass ratio.
Determination of activity example:
(1) reagent agent
The former medicine of 95%imicyafos, the former medicine of 93% matrine.
(2) for examination worm source
Indoor diamondback moth larvae of for many generations raising, indoor conditions: temperature (26 ± 2) DEG C, relative moisture 68% ± 5%, periodicity of illumination 16/8h (L/D).
(3) single dose assay method
Adopt dip method respectively two groups of former medicines all to be used a small amount of acetone solution, then be diluted to into the dense solution of 5 of equal difference with the Tween solution of 0.1%, be diluted in for subsequent use in beaker, and with clear water in contrast.
Diamondback moth larvae of the same size is flooded 5S in the liquid of leaching worm cage, and being placed on diameter after sucking unnecessary liquid is in the culture dish of 9cm, is placed with fresh vegetable leaf and adds a cover in ware.Every concentration process 10, repeats 4 times, if blank.Check lethality keep 24h in (27 ± 1) DEG C illumination box after, it is dead for touching polypide nonresponder by pulling needle.Lethality Abbott formula correction, then according to log concentration---lethality probit value analyzes (Bliss) method, obtains virulence regression equation and puts dead middle amount LC
50value.
(4) the joint toxicity measuring method of different ratio
According to the toxicity test result of single dose, by active ingredient 22% ratio of weight and number imicyafos: matrine is respectively 5:17,7:15,9:13,11:11,13:9.
Adopt above-mentioned 1.3 methods to carry out toxicity test, calculate LC
50, and press abundant method calculating co-toxicity coefficient (CTC) of Sun Yun.Co-toxicity coefficient CTC, computing formula is as follows: (take imicyafos as standard agent, its toxicity index is 100):
The LC of toxicity index (the TI)=imicyafos of matrine
50the LC of/matrine
50× 100
The LC of actual toxicity index (the ATI)=imicyafos of M
50the LC of/M
50× 100
TI × P matrine of TI × P imicyafos+ matrine of theoretical toxicity index (the TTI)=imicyafos of M
TTI × 100 of the ATI/M of co-toxicity coefficient (the CTC)=M of M
In formula:
M is the mixture of matrine and imicyafos different ratio
P matrine is the ratio of matrine shared by mixture
P imicyafos is the ratio of imicyafos shared by mixture
(5) toxicity test result and analysis
Table 1imicyafos, matrine are to the indoor measurement result of diamond-back moth
As can be seen from the table, in the mixture of different proportion, its co-toxicity coefficient is all greater than 120, shows certain synergistic effect, wherein imicyafos: matrine be 7: 15 synergistic effect the most obvious, co-toxicity coefficient is 188.98.Result of the test shows, matrine, imicyafos two kinds of medicaments all have higher activity to diamond-back moth in room conditions, the result of the test of different proportion proportioning shows, by active ingredient imicyafos: when matrine is 5:17,7:15,9:13,11:11,13:9, all show stronger synergistic effect, wherein with imicyafos: when matrine is 7: 15, synergistic effect is best.Suggestion carries out further field control effectiveness test to the mixture preparation of suitable proportion about 7:15 scope, to evaluate its field practical application effect.
Field experiment: field trial control rice pest
(1) test method
Test is carried out at the double-ridged horn in Luo Wan village, journey market town, Jianli County, Jingzhou City of Hubei Province, and experimental field soil is loam, middle fertility, and irrigation and drainage are convenient, and surrounding all plants double cropping rice.For before the medication of examination paddy rice, the rice is doing well.The Zhu little Ni ridge, minizone is in case string is filled with, and during dispenser, there is 3 ~ 4cm shoaling layer in field, water conservation 7d after medicine, tests four (2) for rice fulgorid low instar nymphs occurrence in peak period (September 4) medication in afternoon 1 time, to water 50kg/hm
2, evenly slightly spray with workers and peasants 16 type knapsack hand sprayer, time paddy rice be in grouting mid-term, secondly field is mainly white-backed planthopper, is small brown rice planthopper, and 1 ~ 3 age nymph account for 90%.Dispenser same day is fine day, mean temperature of air 29.5 DEG C; After medicine, 7d is all without rain, weather on this test substantially without impact.
(2) investigation method
Investigate 5 times altogether, (September 4) investigation insect population radix before medicine, 2d (September 6) after medicine, 7d (September 11) after medicine, after medicine, 14d (September 18) investigates 1 time respectively.Take the parallel great-jump-forward random sampling 15 in every community point, 2 clumps often, totally 30 clumps of rice, clap with basin the borer population alive that method records white-backed planthopper, small brown rice planthopper respectively, then calculate its Rectifying efficacies (hereinafter referred to as preventive effect).
(3) drug effect computational methods
Live before Revision insect recluced rate (%)=(borer population of living after borer population one dispenser of living before dispenser)/dispenser borer population * l00;
(4) poisoning investigation method
After medicine, 2,7,14d observe paddy growth situation, estimate medicament to paddy rice all without poisoning.
(5) field control effectiveness test result of the test
Table 2 treatment agent prevents and treats rice hoppers field control effectiveness test result
As can be seen from Table 2,22%imicyafos matrine is better than 10% matrine SL, 20%imicyafos SC contrasts single dose by the weight portion mixture combination successful of preventing and treating rice hoppers of 7: 15,22%imicyafos matrine insecticidal effect of 7 days after medicine is respectively 92.55%, 92.62% and 94.40%, and insecticidal effect increases progressively along with the increase of consumption.In addition within the scope of test dose, plant growth is normal, and the poisoning phenomenon to paddy rice does not all appear in each treatment agent, illustrates that it is safe to paddy rice.
Claims (1)
1. the Pesticidal combination containing matrine, it is characterized in that: this Pesticidal combination is for the composite composite preparation of active ingredient two yuan with agricultural chemicals A imicyafos and B matrine, all the other components are usual auxiliaries in agricultural chemicals, and the structural formula of agricultural chemicals A imicyafos is:
in this insecticides, the ratio of weight and number of effective constituents A and B is 5 ~ 25: 30 ~ 3, the formulations of pesticide that the preparation method of this Pesticidal combination field of pesticide preparation can be prepared into are wetting powder, suspending agent, microemulsion, aqueous emulsion and water dispersible granules, and in preparation, active ingredient gross weight accounts for the portion rate of gross weight in preparation is 5% ~ 40%.
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| CN1058407A (en) * | 1990-07-06 | 1992-02-05 | 安哥洛商株式会社 | Desinsection, mite and nematode agent that organo phosphorous compounds and preparation method thereof is relevant |
| CN101209052A (en) * | 2006-12-27 | 2008-07-02 | 石原产业株式会社 | Composition for preventing and controlling tree parasitic pest for tree |
| CN101647459A (en) * | 2009-07-21 | 2010-02-17 | 深圳诺普信农化股份有限公司 | Matrine composition |
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| CN1058407A (en) * | 1990-07-06 | 1992-02-05 | 安哥洛商株式会社 | Desinsection, mite and nematode agent that organo phosphorous compounds and preparation method thereof is relevant |
| CN101209052A (en) * | 2006-12-27 | 2008-07-02 | 石原产业株式会社 | Composition for preventing and controlling tree parasitic pest for tree |
| CN101647459A (en) * | 2009-07-21 | 2010-02-17 | 深圳诺普信农化股份有限公司 | Matrine composition |
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| 新烟碱类杀虫剂最新研究进展;杨吉春等;《农药》;20070731;第46卷(第7期);433-438 * |
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Owner name: GU XIANGMAO Free format text: FORMER OWNER: SUN MENGMENG Effective date: 20150826 |
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Effective date of registration: 20150826 Address after: 266000 Licang, Qingdao, No. nine East water road, No. 320, No. Applicant after: Gu Xiangmao Address before: 256660, No. three, 5 village, old town, Binhu District, Shandong, Binzhou Applicant before: Sun Mengmeng |
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Address after: 516879 Guangdong County of Huizhou province Longmen City Yong Han Zhen Hong Xing Cun Heng Long environmental calcium Industry Co. Ltd. Patentee after: Gu Xiangmao Address before: 266000 Licang, Qingdao, No. nine East water road, No. 320, No. Patentee before: Gu Xiangmao |
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Address after: Baisha Street Pingdu City, Shandong province 266700 Qingdao Rong Tai Road No. 5 Patentee after: Gu Xiangmao Address before: 516879 Guangdong County of Huizhou province Longmen City Yong Han Zhen Hong Xing Cun Heng Long environmental calcium Industry Co. Ltd. Patentee before: Gu Xiangmao |
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Address after: 210000 Sujian Building, 31-1 Yunnan Road, Gulou District, Nanjing City, Jiangsu Province Patentee after: Gu Xiangmao Address before: 266700 5 Rong Tai Road, Baisha he street, Pingdu City, Qingdao, Shandong Patentee before: Gu Xiangmao |
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Effective date of registration: 20191025 Address after: 221000 floor 1, Luliang Lake Management Office, Tongshan District, Xuzhou City, Jiangsu Province Patentee after: Jiangsu jiudi Agricultural Ecological Technology Co., Ltd Address before: 210000 Sujian building, 31-1 Yunnan Road, Gulou District, Nanjing City, Jiangsu Province Patentee before: Gu Xiangmao |
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| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20151014 Termination date: 20191230 |