CN105360133A - Insecticide composition containing o-phenylenediamine insecticide and chlorantraniliprole - Google Patents
Insecticide composition containing o-phenylenediamine insecticide and chlorantraniliprole Download PDFInfo
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- CN105360133A CN105360133A CN201510942314.8A CN201510942314A CN105360133A CN 105360133 A CN105360133 A CN 105360133A CN 201510942314 A CN201510942314 A CN 201510942314A CN 105360133 A CN105360133 A CN 105360133A
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- Prior art keywords
- rynaxypyr
- insecticide
- pesticidal combination
- phenylenediamine
- phenylenediamine insecticides
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
- A01N37/30—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the groups —CO—N< and, both being directly attached by their carbon atoms to the same carbon skeleton, e.g. H2N—NH—CO—C6H4—COOCH3; Thio-analogues thereof
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to an insecticide composition containing o-phenylenediamine insecticide and chlorantraniliprole. The insecticide composition is characterized in that active components in the insecticide composition are the o-phenylenediamine insecticide A and the chlorantraniliprole, and the remaining components are auxiliary constituents for preparing the insecticide formulation, wherein the weight ratio of the active components, namely the o-phenylenediamine insecticide A to the chlorantraniliprole, is 1-30 to 30-1, the insecticide composition can be prepared into such insecticide formulation as wettable powder, a suspending agent, soluble liquid, emulsion in water and water dispersible granules, and the total weight parts of the active components, , namely the o-phenylenediamine insecticide A and the chlorantraniliprole, in the insecticide formulation accounts for 5-40% the total weight parts of the formulation. The insecticide composition has obvious synergism, the insecticidal spectrum is broadened, the insecticide using amount is reduced, the prevention effect is improved, few residues are left, the effect preserving period is long, and it is helpful to delay generation of insecticide resistance of insects and protect the environment.
Description
Technical field
The present invention relates to technical field of pesticide combination, be specifically related to a kind of Pesticidal combination containing o-phenylenediamine insecticides and Rynaxypyr.
Background technology
The chemical structural formula of o-phenylenediamine insecticides A is as follows:
，
This insecticide is the new type disinsection immunomodulator compounds that Syngenta Co., Ltd announces, and disclosing its mechanism of action is at present ryanodine receptor agent, without more Experimental report or open, does not also have the site test in composite field open.
Rynaxypyr (chlorantraniliprole), molecular formula is C
18h
14n
5o
2brC
l2, belong to O-formammidotiazol-benzamide insecticide.Mainly activate blue Buddhist nun's alkali acceptor, the calcium ion of release smooth muscle and the interior storage of striated muscle cell, causes muscle to regulate weak, paralysis, until last insect death.This active ingredient shows mammal and the extremely significant selective difference of insect blue Buddhist nun's alkali acceptor, substantially increases mammal and other vertebrate safeties.Rynaxypyr high-efficiency broad spectrum, all has good control effects to lepidopterous Noctuidae, Pyralidae, Carposinidae, tortricid, miller section, diamond-back moth section, Gelechidae, Gracilariidae etc., can also control coleoptera Culculionidae, Chrysomelidae; Diptera Agromyzidae; The multiple non-lepidoptera pest such as Bemisia tabaci.
The insecticide that Long-Time Service is single, insect is easy to develop immunity to drugs, and pesticide dosage is increased, and cause the adverse consequencess such as high poison, consumption are large, residual many, drug effect is poor, and effect field is more single.And research and develop the agricultural chemical compound that seems, then the R&D cycle is long, and screening compounds arrangement works is very numerous and diverse, and non-general research and development institution can bear.But the different mechanism of action and without the insecticide rational mixture by a certain percentage of cross resistance, crop disease prevention effect can be improved, reduce dosage, residual few, reduce environmental pollution, effectively reducing the pesticide resistance of crop, is the study hotspot of current medium and small research and development institution.
Summary of the invention
According to the deficiencies in the prior art; the present invention proposes a kind of Pesticidal combination containing o-phenylenediamine insecticides and Rynaxypyr; said composition contains o-phenylenediamine insecticides A and Rynaxypyr two kinds of effective active components, and can be prepared into the preparation being suitable for agricultural application, and this Pesticidal combination has notable synergistic effect; expand insecticidal spectrum; decrease pesticide volume, improve preventive effect, residual few; lasting period is long, and the pesticide resistance being conducive to delaying insect produces and environmental protection.
The application is a kind of Pesticidal combination containing o-phenylenediamine insecticides and Rynaxypyr, its feature is that in this Pesticidal combination, active component is o-phenylenediamine insecticides A and Rynaxypyr, all the other are the auxiliary element of the preparation formulations of pesticide, and the chemical structural formula of o-phenylenediamine insecticides A is as follows:
,wherein the ratio of weight and number of active component o-phenylenediamine insecticides A and Rynaxypyr is 1 ~ 30: 30 ~ 1.
In above-described Pesticidal combination, the ratio of weight and number of active component o-phenylenediamine insecticides A and Rynaxypyr is 1 ~ 20: 25 ~ 1.
The formulations of pesticide that above-described Pesticidal combination can be prepared into are wetting powder, suspending agent, soluble liquid, aqueous emulsion and water dispersible granules.
In the application's formulations of pesticide, active component o-phenylenediamine insecticides A and Rynaxypyr total weight parts account for 5% ~ 40% of formulation total weight parts.
In the application's formulations of pesticide, active component o-phenylenediamine insecticides A and Rynaxypyr total weight parts account for 5% ~ 25% of formulation total weight parts.
The application's Pesticidal combination may be used for preventing and treating paddy rice, cotton, wheat, fruit tree, insect on vegetables, may be used for preventing and treating Noctuidae, Pyralidae, Carposinidae, tortricid, miller section, diamond-back moth section, Gracilariidae, aphid section, Aleyrodidae, Cicadellidae, Delphacidae, Culculionidae, Chrysomelidae, Agromyzidae, Bemisia tabaci insect and nematode, acarid.All there is good control effects to lepidopterous Noctuidae, Pyralidae, Carposinidae, tortricid, miller section, diamond-back moth section, Gelechidae, Gracilariidae etc., coleoptera Culculionidae can also be controlled, Chrysomelidae; Diptera Agromyzidae; The multiple non-lepidoptera pest such as Bemisia tabaci.
When the application's Pesticidal combination is prepared as wetting powder, the parts by weight of each component are:
O-phenylenediamine insecticides A1 ~ 30 part
Rynaxypyr 1 ~ 25 part
Dispersant 5 ~ 15 parts
Wetting agent 3 ~ 10 parts
Filler 40 ~ 70 parts.
The concrete procedure of processing of this Pesticidal combination wetting powder is: by above-mentioned formula by o-phenylenediamine insecticides and Rynaxypyr and the mixing of dispersant, wetting agent and filler, uniform stirring in stirred tank, mixing after airslide disintegrating mill, namely can be made into the wetting powder of the present composition.
When the application's Pesticidal combination is prepared as suspending agent, the parts by weight of each component are:
O-phenylenediamine insecticides A1 ~ 30 part
Rynaxypyr 1 ~ 25 part
Dispersant 4 ~ 12 parts
Antifreezing agent 1 ~ 4 part
Thickener 0.1 ~ 4 part
Defoamer 0.1 ~ 1 part
Water surplus.
The concrete production stage of this suspending agent is for first to mix other auxiliary agents, mix through high speed shear, add o-phenylenediamine insecticides and Rynaxypyr, abrading-ball 2 ~ 3 hours in ball crusher, make a diameter all at below 5mm, the aqueous suspension formulations of obtained Pesticidal combination described in the application.
When the application's Pesticidal combination is prepared as aqueous emulsion, the parts by weight of each component are:
O-phenylenediamine insecticides A1 ~ 30 part
Rynaxypyr 1 ~ 25 part
Emulsifier 3 ~ 8 parts
Solvent 5 ~ 15 parts
Stabilizing agent 2 ~ 7 parts
Antifreezing agent 1 ~ 4 part
Defoamer 0.1 ~ 8 part
Thickener 0.2 ~ 2 part
Water surplus.
The concrete production stage of this aqueous emulsion is: first former medicine o-phenylenediamine insecticides and Rynaxypyr, solvent and emulsifier, cosolvent are added together, and makes to be dissolved into uniform oil phase; By part water, antifreeze, other the insecticides adjuvant such as antimicrobial mixes uniformly aqueous phase; While high-speed stirred, oil phase is added aqueous phase in a kettle., slowly add water until reach phase inversion point, open clipper and carry out high speed shear, and add remaining water, shear about half an hour, form the aqueous emulsion of oil-in-water type.
When the application's Pesticidal combination is prepared as water dispersible granules, the parts by weight of each component are:
O-phenylenediamine insecticides A1 ~ 30 part
Rynaxypyr 1 ~ 25 part
Dispersant 4 ~ 12 parts
Wetting agent 3 ~ 8 parts
Disintegrant 2 ~ 8 parts
Filler 40 ~ 70 parts.
The concrete procedure of processing of this Pesticidal combination water dispersible granules is: o-phenylenediamine insecticides, Rynaxypyr and dispersant, wetting agent, disintegrant and filler are mixed by above-mentioned formula, pulverize with micro jet, through mediating, then add in fluidized-bed granulation dryer and carry out through sample analysis after granulation, drying, screening, be i.e. the water dispersible granules of obtained Pesticidal combination.
Described emulsifier is selected from the mixture that calcium dodecyl benzene sulfonate and aliphatic acid polyethenoxy ether form.
Described solvent is methyl alcohol.
Described dispersant is selected from lignosulfonates.
Described wetting agent is selected from the one in lauryl sodium sulfate, spaonin powder.
Described disintegrant is selected from the one in bentonite, aluminium chloride.
Described thickener is selected from the one in xanthans, CMC, hydroxyethylcellulose, methylcellulose.
Described stabilizing agent is selected from the one in sodium citrate, resorcinol.
Described antifreezing agent is selected from the one in ethylene glycol, propane diols, glycerine.
Described defoamer is selected from silicone oil, silicone compound, C
10-20saturated fat acid compounds, C
8-10one in aliphatic alcohols compound.
Described filler is selected from the one in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, precipitated calcium carbonate.
In addition, the Pesticidal combination of the application compares similar medicament also has other obvious advantages a lot, the first, compares single dose sphere of action wider, can expand insecticidal spectrum; The second, greatly delay the generation of pest resistance to insecticide, decreased agricultural chemicals Reusability number of times, reduce Pesticide use amount, reduce agricultural cost; 3rd, the residual quantity of this Pesticidal combination is lower, more friendly to environment, is significant to the increasing both production and income of agricultural region.
embodiment:
Clearly understand to make object of the present invention, technical scheme and advantage; the following specific embodiment of the present invention is described; following examples are the preferred embodiment of the application, do not represent only test example, and the application's protection domain is as the criterion with claims.
indoor biometrics screening and field experiment:
The method that the present invention adopts indoor bioassay and field trial to combine.If no special instructions, the ratio (comprising percentage) below mentioned is all ratio of weight and number.
determination of activity example:
(1) reagent agent
The former medicine of o-phenylenediamine insecticides A, Syngenta Co., Ltd, the former medicine of 96% Rynaxypyr.
(2) for examination worm source
Indoor diamondback moth larvae of for many generations raising, indoor conditions
:temperature (26 ± 2)
oc, relative moisture 68% ± 5%, periodicity of illumination 16/8h (L/D).
(3) single dose assay method
Adopt dip method respectively two groups of former medicines all to be used a small amount of acetone solution, then use 0
.the Tween solution of 1% is diluted to into the dense solution of 5 of equal difference, is diluted in for subsequent use in beaker, and with clear water in contrast.
Diamondback moth larvae of the same size is flooded 5S in the liquid of leaching worm cage, and being placed on diameter after sucking unnecessary liquid is in the culture dish of 9cm, is placed with fresh vegetable leaf and adds a cover in ware.Every concentration process 10, repeats 4 times, if blank.Check lethality keep 24h in (27 ± 1) DEG C illumination box after, it is dead for touching polypide nonresponder by pulling needle.Lethality Abbott formula correction, then according to log concentration---lethality probit value analyzes (Bliss) method, obtains virulence regression equation and puts dead middle amount LC
50value.
(4) the joint toxicity measuring method of different ratio
According to the toxicity test result of single dose, by active ingredient ratio of weight and number o-phenylenediamine insecticides A
:rynaxypyr is respectively 6
: 16,8
:14,10
:12,12
:10,14
:8.
Adopt above-mentioned 1
.3 methods carry out toxicity test, calculate LC
50, and press abundant method calculating co-toxicity coefficient (CTC) of Sun Yun.
(5) toxicity test result and analysis
Table 1 o-phenylenediamine insecticides A, Rynaxypyr are to the indoor measurement result of diamond-back moth
As can be seen from the table, in the mixture of different proportion, its co-toxicity coefficient is all greater than 120, shows certain synergistic effect, wherein o-phenylenediamine insecticides A: synergistic effect when Rynaxypyr is 8: 14 is the most obvious, and co-toxicity coefficient is 198.12.Result of the test shows, Rynaxypyr, o-phenylenediamine insecticides A two kinds of medicaments all have higher activity to diamond-back moth in room conditions, and the result of the test of different proportion proportioning shows, by active ingredient o-phenylenediamine insecticides A: Rynaxypyr is 6
: 16,8
:14,10
:12,12
:10,14
:when 8, all show stronger synergistic effect, wherein with o-phenylenediamine insecticides A: when Rynaxypyr is 8: 14, synergistic effect is best.Suggestion carries out further field control effectiveness test to the mixture preparation of suitable proportion about 8:14 scope, to evaluate its field practical application effect.
field experiment: field trial control rice pest
(1) test method
Test is carried out at the double-ridged horn in Luo Wan village, journey market town, Jianli County, Jingzhou City of Hubei Province, and experimental field soil is loam, middle fertility, and irrigation and drainage are convenient, and surrounding all plants double cropping rice.For before the medication of examination paddy rice, the rice is doing well.The Zhu little Ni ridge, minizone is in case string is filled with, and during dispenser, there is 3 ~ 4cm shoaling layer in field, water conservation 7d after medicine, tests four (2) for rice fulgorid low instar nymphs occurrence in peak period medication in afternoon 1 time, to water 50kg/hm
2, evenly slightly spray with workers and peasants 16 type knapsack hand sprayer, time paddy rice be in grouting mid-term, secondly field is mainly white-backed planthopper, is small brown rice planthopper, and 1 ~ 3 age nymph account for 90%.Dispenser same day is fine day, mean temperature of air 29.5 DEG C; After medicine, 7d is all without rain, weather on this test substantially without impact.
(2) investigation method
Investigate 4 times altogether, investigation insect population radix before medicine, 2d after medicine, 7d after medicine, after medicine, 14d investigates 1 time respectively.Take the parallel great-jump-forward random sampling 15 in every community point, 2 clumps often, totally 30 clumps of rice, clap with basin the borer population alive that method records white-backed planthopper, small brown rice planthopper respectively, then calculate its Rectifying efficacies (hereinafter referred to as preventive effect).
(3) drug effect computational methods
Preventive effect (%)=
× 100;
(4) poisoning investigation method
After medicine, 2,7,14d observe paddy growth situation, estimate medicament to paddy rice all without poisoning.
(5) field control effectiveness test result of the test
Table 2 treatment agent prevents and treats rice hoppers field control effectiveness test result
As can be seen from Table 2, the mixture of 8% o-phenylenediamine insecticides A+14% Rynaxypyr combines the successful preventing and treating rice hoppers and is better than 20% Rynaxypyr SC contrast single dose, 8% o-phenylenediamine insecticides A+14% Rynaxypyr insecticidal effect of 14 days after medicine is respectively 93.15%, 95.27% and 96.50%, insecticidal effect increases progressively along with the increase of consumption, estimate according to field, substantially disease is not had with the paddy rice of 8% o-phenylenediamine insecticides A+14% Rynaxypyr, and growth fraction is more vigorous, and the paddy rice of 20% Rynaxypyr SC single dose occurs that disease is more, the disease plant much about about 7% of ratio complex preparation.
In addition within the scope of test dose, plant growth is normal, and the poisoning phenomenon to paddy rice does not all appear in each treatment agent, illustrates that it is safe to paddy rice.
Claims (7)
1. one kind contains the Pesticidal combination of o-phenylenediamine insecticides and Rynaxypyr, it is characterized in that: in this Pesticidal combination, active component is o-phenylenediamine insecticides A and Rynaxypyr, all the other are the auxiliary element of the preparation formulations of pesticide, and o-phenylenediamine insecticides A structural formula is as follows:
, wherein the ratio of weight and number of active component o-phenylenediamine insecticides A and Rynaxypyr is 1 ~ 30: 30 ~ 1.
2. a kind of Pesticidal combination containing o-phenylenediamine insecticides and Rynaxypyr according to claim 1, is characterized in that: in described Pesticidal combination, the ratio of weight and number of active component o-phenylenediamine insecticides A and Rynaxypyr is 1 ~ 20: 25 ~ 1.
3. a kind of Pesticidal combination containing o-phenylenediamine insecticides and Rynaxypyr according to claim 1 and 2, is characterized in that: the formulations of pesticide that described Pesticidal combination can be prepared into are wetting powder, suspending agent, soluble liquid, aqueous emulsion and water dispersible granules.
4. a kind of Pesticidal combination containing o-phenylenediamine insecticides and Rynaxypyr according to claim 3, is characterized in that: in the formulations of pesticide, active component o-phenylenediamine insecticides A and Rynaxypyr total weight parts account for 5% ~ 40% of formulation total weight parts.
5. a kind of Pesticidal combination containing o-phenylenediamine insecticides and Rynaxypyr according to claim 1 or 2 or 4, is characterized in that: in the formulations of pesticide, active component o-phenylenediamine insecticides A and Rynaxypyr total weight parts account for 5% ~ 25% of formulation total weight parts.
6. a kind of Pesticidal combination containing o-phenylenediamine insecticides and Rynaxypyr according to claim 1 or 2 or 4, is characterized in that: this Pesticidal combination may be used for preventing and treating the insect on paddy rice, cotton, wheat, fruit tree, vegetables.
7. a kind of Pesticidal combination containing o-phenylenediamine insecticides and Rynaxypyr according to claim 6, is characterized in that: this Pesticidal combination may be used for preventing and treating Noctuidae, Pyralidae, Carposinidae, tortricid, miller section, diamond-back moth section, Gracilariidae, aphid section, Aleyrodidae, Cicadellidae, Delphacidae, Culculionidae, Chrysomelidae, Agromyzidae, Bemisia tabaci insect and nematode, acarid.
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|---|---|---|---|
| CN201510942314.8A CN105360133A (en) | 2015-12-16 | 2015-12-16 | Insecticide composition containing o-phenylenediamine insecticide and chlorantraniliprole |
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|---|---|---|---|
| CN201510942314.8A CN105360133A (en) | 2015-12-16 | 2015-12-16 | Insecticide composition containing o-phenylenediamine insecticide and chlorantraniliprole |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2017176945A1 (en) * | 2016-04-06 | 2017-10-12 | Fmc Corporation | Formulations and methods for controlling rootworm larvae |
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| CN102318611A (en) * | 2011-07-28 | 2012-01-18 | 尹小根 | Insecticidal composition containing flubendiamide and chlorantraniliprole |
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2015
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Patent Citations (2)
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| CN102318611A (en) * | 2011-07-28 | 2012-01-18 | 尹小根 | Insecticidal composition containing flubendiamide and chlorantraniliprole |
| CN102992913A (en) * | 2012-11-29 | 2013-03-27 | 叶长东 | Insecticide-fertilizer composition containing chlorantraniliprole or flubendiamide |
Non-Patent Citations (1)
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| 周超等: "氯虫苯甲酰胺和氟虫双酰胺对不同虫态甜菜夜蛾的毒力作用", 《植物保护学报》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2017176945A1 (en) * | 2016-04-06 | 2017-10-12 | Fmc Corporation | Formulations and methods for controlling rootworm larvae |
| US11439149B2 (en) | 2016-04-06 | 2022-09-13 | Fmc Corporation | Formulations and methods for controlling rootworm larvae |
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Application publication date: 20160302 |
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