CN102992913A - Insecticide-fertilizer composition containing chlorantraniliprole or flubendiamide - Google Patents
Insecticide-fertilizer composition containing chlorantraniliprole or flubendiamide Download PDFInfo
- Publication number
- CN102992913A CN102992913A CN2012104997138A CN201210499713A CN102992913A CN 102992913 A CN102992913 A CN 102992913A CN 2012104997138 A CN2012104997138 A CN 2012104997138A CN 201210499713 A CN201210499713 A CN 201210499713A CN 102992913 A CN102992913 A CN 102992913A
- Authority
- CN
- China
- Prior art keywords
- solution
- fertilizer composition
- medicine fertilizer
- acetone
- rice
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003337 fertilizer Substances 0.000 title claims abstract description 47
- 239000000203 mixture Substances 0.000 title claims abstract description 41
- PSOVNZZNOMJUBI-UHFFFAOYSA-N chlorantraniliprole Chemical compound CNC(=O)C1=CC(Cl)=CC(C)=C1NC(=O)C1=CC(Br)=NN1C1=NC=CC=C1Cl PSOVNZZNOMJUBI-UHFFFAOYSA-N 0.000 title claims abstract description 12
- 239000005886 Chlorantraniliprole Substances 0.000 title abstract 3
- 239000005901 Flubendiamide Substances 0.000 title abstract 3
- ZGNITFSDLCMLGI-UHFFFAOYSA-N flubendiamide Chemical compound CC1=CC(C(F)(C(F)(F)F)C(F)(F)F)=CC=C1NC(=O)C1=CC=CC(I)=C1C(=O)NC(C)(C)CS(C)(=O)=O ZGNITFSDLCMLGI-UHFFFAOYSA-N 0.000 title abstract 3
- 230000002195 synergetic effect Effects 0.000 claims abstract description 12
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 7
- 241000607479 Yersinia pestis Species 0.000 claims abstract description 7
- 239000004202 carbamide Substances 0.000 claims abstract description 7
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims abstract description 4
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims abstract description 3
- 235000012538 ammonium bicarbonate Nutrition 0.000 claims abstract description 3
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims abstract description 3
- 235000011130 ammonium sulphate Nutrition 0.000 claims abstract description 3
- 230000003405 preventing effect Effects 0.000 claims abstract description 3
- 239000000243 solution Substances 0.000 claims description 52
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 42
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 36
- 239000003814 drug Substances 0.000 claims description 34
- 239000002253 acid Substances 0.000 claims description 20
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 18
- 240000007594 Oryza sativa Species 0.000 claims description 15
- 235000007164 Oryza sativa Nutrition 0.000 claims description 15
- 235000009566 rice Nutrition 0.000 claims description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 13
- 238000010438 heat treatment Methods 0.000 claims description 12
- 241000238631 Hexapoda Species 0.000 claims description 10
- ZOCSXAVNDGMNBV-UHFFFAOYSA-N 5-amino-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-4-[(trifluoromethyl)sulfinyl]-1H-pyrazole-3-carbonitrile Chemical compound NC1=C(S(=O)C(F)(F)F)C(C#N)=NN1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl ZOCSXAVNDGMNBV-UHFFFAOYSA-N 0.000 claims description 9
- 241000098289 Cnaphalocrocis medinalis Species 0.000 claims description 9
- 241000008892 Cnaphalocrocis patnalis Species 0.000 claims description 9
- 239000005899 Fipronil Substances 0.000 claims description 9
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 9
- 238000003483 aging Methods 0.000 claims description 9
- 230000032683 aging Effects 0.000 claims description 9
- 229940013764 fipronil Drugs 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 9
- FTQWRYSLUYAIRQ-UHFFFAOYSA-N n-[(octadecanoylamino)methyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCNC(=O)CCCCCCCCCCCCCCCCC FTQWRYSLUYAIRQ-UHFFFAOYSA-N 0.000 claims description 9
- 229910052710 silicon Inorganic materials 0.000 claims description 9
- 239000010703 silicon Substances 0.000 claims description 9
- 229910019142 PO4 Inorganic materials 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 8
- 239000010452 phosphate Substances 0.000 claims description 8
- 240000000111 Saccharum officinarum Species 0.000 claims description 7
- 235000007201 Saccharum officinarum Nutrition 0.000 claims description 7
- 230000006837 decompression Effects 0.000 claims description 7
- 238000012545 processing Methods 0.000 claims description 7
- 208000006558 Dental Calculus Diseases 0.000 claims description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 6
- ZFXVRMSLJDYJCH-UHFFFAOYSA-N calcium magnesium Chemical compound [Mg].[Ca] ZFXVRMSLJDYJCH-UHFFFAOYSA-N 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 6
- 239000002244 precipitate Substances 0.000 claims description 6
- 238000001556 precipitation Methods 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 239000007921 spray Substances 0.000 claims description 5
- 235000010469 Glycine max Nutrition 0.000 claims description 4
- 244000068988 Glycine max Species 0.000 claims description 4
- 241000966204 Lissorhoptrus oryzophilus Species 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- 206010013786 Dry skin Diseases 0.000 claims description 3
- 238000010790 dilution Methods 0.000 claims description 3
- 239000012895 dilution Substances 0.000 claims description 3
- 238000001704 evaporation Methods 0.000 claims description 3
- 230000008020 evaporation Effects 0.000 claims description 3
- 239000003921 oil Substances 0.000 claims description 3
- 239000007790 solid phase Substances 0.000 claims description 3
- 238000009834 vaporization Methods 0.000 claims description 3
- 230000008016 vaporization Effects 0.000 claims description 3
- 235000009436 Actinidia deliciosa Nutrition 0.000 claims description 2
- 244000298697 Actinidia deliciosa Species 0.000 claims description 2
- 244000144730 Amygdalus persica Species 0.000 claims description 2
- 244000099147 Ananas comosus Species 0.000 claims description 2
- 235000007119 Ananas comosus Nutrition 0.000 claims description 2
- 235000017060 Arachis glabrata Nutrition 0.000 claims description 2
- 244000105624 Arachis hypogaea Species 0.000 claims description 2
- 235000010777 Arachis hypogaea Nutrition 0.000 claims description 2
- 235000018262 Arachis monticola Nutrition 0.000 claims description 2
- 244000189799 Asimina triloba Species 0.000 claims description 2
- 235000006264 Asimina triloba Nutrition 0.000 claims description 2
- 235000011274 Benincasa cerifera Nutrition 0.000 claims description 2
- 244000036905 Benincasa cerifera Species 0.000 claims description 2
- 241000167854 Bourreria succulenta Species 0.000 claims description 2
- 235000004936 Bromus mango Nutrition 0.000 claims description 2
- 235000002566 Capsicum Nutrition 0.000 claims description 2
- 240000008574 Capsicum frutescens Species 0.000 claims description 2
- 235000009467 Carica papaya Nutrition 0.000 claims description 2
- 235000009024 Ceanothus sanguineus Nutrition 0.000 claims description 2
- 241000426497 Chilo suppressalis Species 0.000 claims description 2
- 244000241235 Citrullus lanatus Species 0.000 claims description 2
- 235000012828 Citrullus lanatus var citroides Nutrition 0.000 claims description 2
- 241000675108 Citrus tangerina Species 0.000 claims description 2
- 235000013162 Cocos nucifera Nutrition 0.000 claims description 2
- 244000060011 Cocos nucifera Species 0.000 claims description 2
- 229920000742 Cotton Polymers 0.000 claims description 2
- 240000008067 Cucumis sativus Species 0.000 claims description 2
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 claims description 2
- 235000011511 Diospyros Nutrition 0.000 claims description 2
- 244000236655 Diospyros kaki Species 0.000 claims description 2
- 235000016623 Fragaria vesca Nutrition 0.000 claims description 2
- 240000009088 Fragaria x ananassa Species 0.000 claims description 2
- 235000011363 Fragaria x ananassa Nutrition 0.000 claims description 2
- 244000017020 Ipomoea batatas Species 0.000 claims description 2
- 235000002678 Ipomoea batatas Nutrition 0.000 claims description 2
- 240000003553 Leptospermum scoparium Species 0.000 claims description 2
- 235000015459 Lycium barbarum Nutrition 0.000 claims description 2
- 235000007688 Lycopersicon esculentum Nutrition 0.000 claims description 2
- 241000220225 Malus Species 0.000 claims description 2
- 235000011430 Malus pumila Nutrition 0.000 claims description 2
- 235000015103 Malus silvestris Nutrition 0.000 claims description 2
- 235000014826 Mangifera indica Nutrition 0.000 claims description 2
- 240000007228 Mangifera indica Species 0.000 claims description 2
- 235000009811 Momordica charantia Nutrition 0.000 claims description 2
- 235000009812 Momordica cochinchinensis Nutrition 0.000 claims description 2
- 240000001740 Momordica dioica Species 0.000 claims description 2
- 235000018365 Momordica dioica Nutrition 0.000 claims description 2
- 240000005561 Musa balbisiana Species 0.000 claims description 2
- 235000018290 Musa x paradisiaca Nutrition 0.000 claims description 2
- 235000002637 Nicotiana tabacum Nutrition 0.000 claims description 2
- 244000061176 Nicotiana tabacum Species 0.000 claims description 2
- 241001465818 Orseolia oryzae Species 0.000 claims description 2
- 240000004713 Pisum sativum Species 0.000 claims description 2
- 235000010582 Pisum sativum Nutrition 0.000 claims description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- 235000006040 Prunus persica var persica Nutrition 0.000 claims description 2
- 241000220324 Pyrus Species 0.000 claims description 2
- 244000088415 Raphanus sativus Species 0.000 claims description 2
- 235000006140 Raphanus sativus var sativus Nutrition 0.000 claims description 2
- 241001249129 Scirpophaga incertulas Species 0.000 claims description 2
- 240000003768 Solanum lycopersicum Species 0.000 claims description 2
- 235000002597 Solanum melongena Nutrition 0.000 claims description 2
- 244000061458 Solanum melongena Species 0.000 claims description 2
- 235000002595 Solanum tuberosum Nutrition 0.000 claims description 2
- 244000061456 Solanum tuberosum Species 0.000 claims description 2
- 235000009184 Spondias indica Nutrition 0.000 claims description 2
- 235000021307 Triticum Nutrition 0.000 claims description 2
- 244000098338 Triticum aestivum Species 0.000 claims description 2
- 235000009754 Vitis X bourquina Nutrition 0.000 claims description 2
- 235000012333 Vitis X labruscana Nutrition 0.000 claims description 2
- 240000006365 Vitis vinifera Species 0.000 claims description 2
- 235000014787 Vitis vinifera Nutrition 0.000 claims description 2
- 240000008042 Zea mays Species 0.000 claims description 2
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims description 2
- 240000008866 Ziziphus nummularia Species 0.000 claims description 2
- YYRMJZQKEFZXMX-UHFFFAOYSA-L calcium bis(dihydrogenphosphate) Chemical compound [Ca+2].OP(O)([O-])=O.OP(O)([O-])=O YYRMJZQKEFZXMX-UHFFFAOYSA-L 0.000 claims description 2
- 229910000389 calcium phosphate Inorganic materials 0.000 claims description 2
- 239000001390 capsicum minimum Substances 0.000 claims description 2
- 235000019693 cherries Nutrition 0.000 claims description 2
- 235000005822 corn Nutrition 0.000 claims description 2
- 239000000284 extract Substances 0.000 claims description 2
- 235000019691 monocalcium phosphate Nutrition 0.000 claims description 2
- 235000020232 peanut Nutrition 0.000 claims description 2
- 235000021017 pears Nutrition 0.000 claims description 2
- 239000011591 potassium Substances 0.000 claims description 2
- 229910052700 potassium Inorganic materials 0.000 claims description 2
- 229940126589 solid medicine Drugs 0.000 claims description 2
- 238000005507 spraying Methods 0.000 claims description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract description 2
- 239000011575 calcium Substances 0.000 abstract description 2
- 229910052791 calcium Inorganic materials 0.000 abstract description 2
- 150000001875 compounds Chemical class 0.000 abstract description 2
- 239000002917 insecticide Substances 0.000 abstract description 2
- 239000004615 ingredient Substances 0.000 abstract 4
- PUKLDDOGISCFCP-JSQCKWNTSA-N 21-Deoxycortisone Chemical compound C1CC2=CC(=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@@](C(=O)C)(O)[C@@]1(C)CC2=O PUKLDDOGISCFCP-JSQCKWNTSA-N 0.000 abstract 2
- METVSRFIOHSNJX-UHFFFAOYSA-N 5-(chloromethyl)-4,6,11-trioxa-1-aza-5-silabicyclo[3.3.3]undecane Chemical compound O1CCN2CCO[Si]1(CCl)OCC2 METVSRFIOHSNJX-UHFFFAOYSA-N 0.000 abstract 2
- FCYKAQOGGFGCMD-UHFFFAOYSA-N Fulvic acid Natural products O1C2=CC(O)=C(O)C(C(O)=O)=C2C(=O)C2=C1CC(C)(O)OC2 FCYKAQOGGFGCMD-UHFFFAOYSA-N 0.000 abstract 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 abstract 2
- 239000004480 active ingredient Substances 0.000 abstract 2
- 229940095100 fulvic acid Drugs 0.000 abstract 2
- 239000002509 fulvic acid Substances 0.000 abstract 2
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 abstract 1
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 abstract 1
- 239000001099 ammonium carbonate Substances 0.000 abstract 1
- 239000012752 auxiliary agent Substances 0.000 abstract 1
- 230000009286 beneficial effect Effects 0.000 abstract 1
- YYRMJZQKEFZXMX-UHFFFAOYSA-N calcium;phosphoric acid Chemical compound [Ca+2].OP(O)(O)=O.OP(O)(O)=O YYRMJZQKEFZXMX-UHFFFAOYSA-N 0.000 abstract 1
- 235000013877 carbamide Nutrition 0.000 abstract 1
- 239000000395 magnesium oxide Substances 0.000 abstract 1
- 229910000402 monopotassium phosphate Inorganic materials 0.000 abstract 1
- 235000019796 monopotassium phosphate Nutrition 0.000 abstract 1
- 239000002686 phosphate fertilizer Substances 0.000 abstract 1
- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 abstract 1
- 239000001103 potassium chloride Substances 0.000 abstract 1
- 235000011164 potassium chloride Nutrition 0.000 abstract 1
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 abstract 1
- 229910052939 potassium sulfate Inorganic materials 0.000 abstract 1
- 235000011151 potassium sulphates Nutrition 0.000 abstract 1
- 239000002426 superphosphate Substances 0.000 abstract 1
- 230000003449 preventive effect Effects 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 230000000361 pesticidal effect Effects 0.000 description 4
- 239000003905 agrochemical Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 2
- 241000255777 Lepidoptera Species 0.000 description 2
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 102000042094 ryanodine receptor (TC 1.A.3.1) family Human genes 0.000 description 2
- 108091052345 ryanodine receptor (TC 1.A.3.1) family Proteins 0.000 description 2
- 239000000375 suspending agent Substances 0.000 description 2
- 239000012747 synergistic agent Substances 0.000 description 2
- 239000004562 water dispersible granule Substances 0.000 description 2
- 241000590412 Agromyzidae Species 0.000 description 1
- 238000012935 Averaging Methods 0.000 description 1
- 241000254127 Bemisia tabaci Species 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- 241001347514 Carposinidae Species 0.000 description 1
- 241001124134 Chrysomelidae Species 0.000 description 1
- 241000254173 Coleoptera Species 0.000 description 1
- 241000256259 Noctuidae Species 0.000 description 1
- 206010034133 Pathogen resistance Diseases 0.000 description 1
- 241000500437 Plutella xylostella Species 0.000 description 1
- 241000255893 Pyralidae Species 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 239000000306 component Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 230000003151 ovacidal effect Effects 0.000 description 1
- NAYYNDKKHOIIOD-UHFFFAOYSA-N phthalamide Chemical compound NC(=O)C1=CC=CC=C1C(N)=O NAYYNDKKHOIIOD-UHFFFAOYSA-N 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Fertilizers (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to an insecticide-fertilizer composition containing chlorantraniliprole or flubendiamide. The composition comprises an active ingredient, synergistic ingredients and fertilizing ingredients, wherein the active ingredient is chlorantraniliprole or flubendiamide; the synergistic ingredients consist of fulvic acid and chloromethylsilatrane; the fertilizing ingredients contain any one or more of ammonium sulfate, potassium sulfate, urea, ammonium nitrate, ammonium bicarbonate, potassium chloride, potassium dihydrogen phosphate, superphosphate and calcium magnesia phosphate fertilizer. The insecticide-fertilizer composition has beneficial effects that with fulvic acid and chloromethylsilatrane as the synergistic auxiliary agents of an insecticide, and at the same time in cooperation with the use of a compound fertilizer, the insecticide-fertilizer composition can increase the crop yield, and at the same time can also improve the pest preventing effect.
Description
Technical field
The invention belongs to agrochemical field, relate to the medicine fertilizer composition that is formed by sterilant, synergistic component and plant nutrient substance, relate to particularly a kind of medicine fertilizer composition that comprises Rynaxypyr or fipronil bisamide and uses thereof.
Background technology
Rynaxypyr is high-efficiency broad spectrum, and lepidopterous Noctuidae, Pyralidae, Carposinidae, tortricid, miller section, diamond-back moth section, Gelechidae, Gracilariidae etc. are all had the sterilant of good control effect, can also control the Coleoptera Culculionidae, Chrysomelidae; The Diptera Agromyzidae; The multiple non-lepidoptera pest such as Bemisia tabaci.Effective to lepidopterous insect, the period is very long.
Fipronil bisamide belongs to Novel ortho benzenedicarboxamide insecticides, activates ryanodine receptor calcium release passage, the property out of control release that causes storing calcium ion.It is the present compound that acts on the insect cell ryanodine receptor few in number.Lepidoptera pest there is the spectrum preventive effect, produces without cross resistance with existing sterilant, be suitable for very much the control that existing sterilant produces the insect of resistance.Larva there is very outstanding preventive effect, limited to the adult preventive effect, there is not ovicidal action.Slightly conduct by xylem after in the infiltration plant body.Resistance of rainwater washing against.
Also not for the medicine fertilizer composition of these two kinds of agricultural chemicals, the present invention is the blank of the medicine fertilizer composition of these two kinds of sterilants of solution, has proposed the technical scheme of new medicine fertilizer composition at present.
Summary of the invention
For solving the problems of the technologies described above, the invention provides a kind of medicine fertilizer composition that comprises Rynaxypyr or fipronil bisamide, said composition comprises activeconstituents, synergistic component and fertilizer component, activeconstituents is Rynaxypyr or fipronil bisamide, synergistic component is comprised of xanthohumic acid and silicon Feng Huan, fertilizer component comprises ammonium sulfate, vitriolate of tartar, urea, ammonium nitrate, bicarbonate of ammonia, any one in Repone K, potassium primary phosphate, calcium superphosphate and the fused(calcium magnesium)phosphate or multiple.
In the above-mentioned medicine fertilizer composition, the weight ratio of xanthohumic acid and silicon Feng Huan is 1: 0.01-5, preferred, weight ratio is 1: 0.1-1.
In the above-mentioned medicine fertilizer composition, the weight ratio of activeconstituents, synergistic component and fertilizer component is 0.01-0.1: 1-20: 80-99, and preferred, weight ratio is 0.01-0.05: 5-15: 85-95.
In the above-mentioned medicine fertilizer composition, the xanthohumic acid of xanthohumic acid for from the alcohol slops of sugarcane deep processing alcohol, extracting.The preparation method of the xanthohumic acid that preferably, extracts from the alcohol slops of sugarcane deep processing alcohol is as follows:
The alcohol slops heating evaporation that reduces pressure is concentrated, control pressure, vaporization temperature is 40 ℃ ± 3 ℃, the stopped heating when weight percent of measuring dry-matter in the concentrated solution reaches 60% obtains concentrated solution; Stirred liq at the uniform velocity in the heat-processed.Then in concentrated solution, add the vitriol oil, make that the mass concentration of sulfuric acid reaches 30% in the concentrated solution, 60 ± 2 ℃ of lower ageings 20 hours, get ageing liquid;
With the sodium hydroxide solution alkalization of ageing liquid with 0.5%wt, stir the lower sodium hydroxide solution that adds, measure the pH of solution, regulate the add-on of sodium hydroxide solution, when being 8, pH stops to add sodium hydroxide solution, occur precipitation in the solution, will precipitate part by removing by filter, obtain solution I;
With the hydrochloric acid soln acidifying with 8%wt of the solution I of above-mentioned acquisition, stir when adding hydrochloric acid soln and measure pH, when being 1, pH value stops to add hydrochloric acid soln, and precipitation appears in the solution, will precipitate partly by removing by filter the acquisition solution II;
In solution II, add acetone, the volume of the acetone of adding be solution II volume 10%.The solution that has added acetone is fully stirred, and the acetone soln part is collected in then centrifugal layering;
Acetone soln is partly inputted in the still kettle, concentrated acetone solns under the decompression heating maintains the temperature at 45 ℃ ± 2 ℃, with recover acetone, remaining material maintains the temperature at 45 ℃ ± 2 ℃ lower dryings through the decompression heating, obtains the solid phase prod xanthohumic acid after the drying.
Above-mentioned medicine fertilizer composition can be prepared into the liquid medicine fertilizer composition, also can be prepared into the solid medicine fertilizer composition.
The fertilizing method of above-mentioned medicine fertilizer composition sprays for spraying or irrigate, being preferably.
The present invention also provides a kind of method of preventing and treating crop pest and improving crop yield, the method comprises and will spray crop after the above-mentioned medicine fertilizer composition dilution, wherein said crop is eggplant, tomato, potato, sweet potato, radish, jowar, tobacco, wheat, paddy rice, corn, cucumber, peanut, coconut, balsam pear, soybean, tea tree, rubber, sugarcane, pea, wax gourd, pears, banana, pawpaw, green soy bean, mango, watermelon, oranges and tangerines, orange, Kiwifruit, strawberry, pineapple, capsicum, apple, jujube, persimmon, grape, cherry, lichee, in peach and the cotton any is preferably paddy rice.
In the aforesaid method, described insect is Cnaphalocrocis medinali(rice leaf roller), striped rice borer, yellow rice borer, pink rice borer, to pachydiplosis oryzae, Lissorhoptrus oryzophilus Kuschel, rice water weevil etc., is preferably Cnaphalocrocis medinali(rice leaf roller).
The present invention also provides above-mentioned composition to be used for pest control and has improved the purposes of crop yield, and described insect is Cnaphalocrocis medinali(rice leaf roller), and described crop is paddy rice.
Medicine fertilizer composition of the present invention through with xanthohumic acid and silicon Feng Huan as the builder of sterilant, cooperate simultaneously the use of composite fertilizer so that medicine fertilizer composition of the present invention can improve the output of crop, can also improve the preventive effect to insect simultaneously.
Embodiment
In order to understand the present invention, the below further specifies the present invention with embodiment, but does not limit the present invention.
The material of using among the following embodiment is market and buys, and all can buy from market to obtain.The preparation method of liquid medicine fertilizer mixes activeconstituents, synergistic component and fertilizer component.
The xanthohumic acid of xanthohumic acid for from the alcohol slops of sugarcane deep processing alcohol, extracting, the preparation method is as follows:
1kg alcohol slops decompression heating evaporation is concentrated, control pressure, vaporization temperature is 40 ℃ ± 3 ℃, the stopped heating when weight percent of dry-matter reaches 60% in the measurement concentrated solution obtains concentrated solution; Stirred liq at the uniform velocity in the heat-processed.Then in concentrated solution, add the vitriol oil, make that the mass concentration of sulfuric acid reaches 30% in the concentrated solution, 60 ± 2 ℃ of lower ageings 20 hours, get ageing liquid;
With the sodium hydroxide solution alkalization of ageing liquid with 0.5%wt, stir the lower sodium hydroxide solution that adds, measure the pH of solution, regulate the add-on of sodium hydroxide solution, when being 8, pH stops to add sodium hydroxide solution, occur precipitation in the solution, will precipitate part by removing by filter, obtain solution I;
With the hydrochloric acid soln acidifying with 8%wt of the solution I of above-mentioned acquisition, stir when adding hydrochloric acid soln and measure pH, when being 1, pH value stops to add hydrochloric acid soln, and precipitation appears in the solution, will precipitate partly by removing by filter the acquisition solution II;
In solution II, add acetone, the volume of the acetone of adding be solution II volume 10%.The solution that has added acetone is fully stirred, and the acetone soln part is collected in then centrifugal layering;
Partly input acetone soln in the still kettle, the decompression heating maintains the temperature at 45 ℃ ± 2 ℃ lower concentrated acetone solns, with recover acetone, and remaining material, maintain the temperature at 45 ℃ ± 2 ℃ lower dryings through the decompression heating, obtain solid phase prod xanthohumic acid 21.78g after the drying.
Embodiment 1:
Get pesticide activity component 20% Rynaxypyr suspension agent 0.10kg, xanthohumic acid 8kg, the former medicine 2kg of silicon Feng Huan, urea 31kg, fused(calcium magnesium)phosphate 30kg, vitriolate of tartar 28.9kg fully mixes each component according to weight.
Embodiment 2:
Get pesticide activity component 20% fipronil bisamide water dispersible granules 0.10kg, xanthohumic acid 5kg, the former medicine 5kg of silicon Feng Huan, urea 31kg, fused(calcium magnesium)phosphate 30kg, vitriolate of tartar 28.9kg fully mixes each component according to weight.
The comparative example 1:
Get xanthohumic acid 8kg, the former medicine 2kg of silicon Feng Huan, urea 31kg, fused(calcium magnesium)phosphate 30kg, vitriolate of tartar 28.9kg fully mixes each component according to weight.
The comparative example 2:
Get xanthohumic acid 5kg, the former medicine 5kg of silicon Feng Huan, urea 31kg, fused(calcium magnesium)phosphate 30kg, vitriolate of tartar 28.9kg fully mixes each component according to weight.
Effect embodiment:
Application Example 1-2 and comparative example 1-2 spray paddy rice, the control Cnaphalocrocis medinali(rice leaf roller).For the experiment that the essentially identical rice terrace of upgrowth situation carries out, the experiment number of each processing is 3 times, the calculating output of averaging, the preventive effect of Cnaphalocrocis medinali(rice leaf roller).Various samples are watered dilution to be sprayed.
The concentration of embodiment 1 and effective agricultural chemicals of embodiment 2 processing paddy rice is identical with the effective level that 20% Rynaxypyr suspension agent and fipronil bisamide water dispersible granules are processed paddy rice, in medicine fertilizer, owing to contain synergistic agent and fertilizer, institute is so that increasing production of rice, not only can reach the purpose of increasing production of rice, also realized the raising of paddy rice Cnaphalocrocis medinali(rice leaf roller) preventive effect, this raising is to realize that by the synergistic blend of pesticide activity component and synergistic agent, fertilizer this synergy has exceeded inventor's expectation.Because the composition of using separately comparative example 1 and comparative example 2 also can reach the purpose of volume increase, but after adding pesticide activity component, output further improves.The medicine fertilizer composition has demonstrated the dual purpose of good volume increase and insect protected, and is the effect that increases insect protected.
Claims (10)
1. medicine fertilizer composition that comprises Rynaxypyr or fipronil bisamide, said composition comprises activeconstituents, synergistic component and fertilizer component, activeconstituents is Rynaxypyr or fipronil bisamide, synergistic component is comprised of xanthohumic acid and silicon Feng Huan, fertilizer component comprises ammonium sulfate, vitriolate of tartar, urea, ammonium nitrate, bicarbonate of ammonia, any one in Repone K, potassium primary phosphate, calcium superphosphate and the fused(calcium magnesium)phosphate or multiple.
2. medicine fertilizer composition according to claim 1, wherein the weight ratio of xanthohumic acid and silicon Feng Huan is 1: 0.01-5, preferred, weight ratio is 1: 0.1-1.
3. medicine fertilizer composition according to claim 1 and 2, wherein the weight ratio of activeconstituents, synergistic component and fertilizer component is 0.01-0.1: 1-20: 80-99, preferred, weight ratio is 0.01-0.05: 5-15: 85-95.
4. each described medicine fertilizer composition according to claim 1-3, the wherein xanthohumic acid of xanthohumic acid for from the alcohol slops of sugarcane deep processing alcohol, extracting.
5. medicine fertilizer composition according to claim 4, the preparation method of the xanthohumic acid that wherein extracts from the alcohol slops of sugarcane deep processing alcohol is as follows:
The alcohol slops heating evaporation that reduces pressure is concentrated, control pressure, vaporization temperature is 40 ℃ ± 3 ℃, the stopped heating when weight percent of measuring dry-matter in the concentrated solution reaches 60% obtains concentrated solution; Stirred liq at the uniform velocity in the heat-processed.Then in concentrated solution, add the vitriol oil, make that the mass concentration of sulfuric acid reaches 30% in the concentrated solution, 60 ± 2 ℃ of lower ageings 20 hours, get ageing liquid;
With the sodium hydroxide solution alkalization of ageing liquid with 0.5%wt, stir the lower sodium hydroxide solution that adds, measure the pH of solution, regulate the add-on of sodium hydroxide solution, when being 8, pH stops to add sodium hydroxide solution, occur precipitation in the solution, will precipitate part by removing by filter, obtain solution I;
With the hydrochloric acid soln acidifying with 8%wt of the solution I of above-mentioned acquisition, stir when adding hydrochloric acid soln and measure pH, when being 1, pH value stops to add hydrochloric acid soln, and precipitation appears in the solution, will precipitate partly by removing by filter the acquisition solution II;
In solution II, add acetone, the volume of the acetone of adding be solution II volume 10%.The solution that has added acetone is fully stirred, and the acetone soln part is collected in then centrifugal layering;
Acetone soln is partly inputted in the still kettle, concentrated acetone solns under the decompression heating maintains the temperature at 45 ℃ ± 2 ℃, with recover acetone, remaining material maintains the temperature at 45 ℃ ± 2 ℃ lower dryings through the decompression heating, obtains the solid phase prod xanthohumic acid after the drying.
6. each described medicine fertilizer composition according to claim 1-5, its Chinese medicine fertilizer composition is prepared into liquid medicine fertilizer composition or solid medicine fertilizer composition.
7. each described medicine fertilizer composition according to claim 1-6, the application process of its Chinese medicine fertilizer composition sprays for spraying or irrigate, being preferably.
8. method of preventing and treating crop pest and improving crop yield, the method comprises and will spray crop after each described medicine fertilizer composition dilution of claim 1-7, wherein said crop is eggplant, tomato, potato, sweet potato, radish, jowar, tobacco, wheat, paddy rice, corn, cucumber, peanut, coconut, balsam pear, soybean, tea tree, rubber, sugarcane, pea, wax gourd, pears, banana, pawpaw, green soy bean, mango, watermelon, oranges and tangerines, orange, Kiwifruit, strawberry, pineapple, capsicum, apple, jujube, persimmon, grape, cherry, lichee, in peach and the cotton any is preferably paddy rice.
9. method according to claim 8, wherein said insect is Cnaphalocrocis medinali(rice leaf roller), striped rice borer, yellow rice borer, pink rice borer, to pachydiplosis oryzae, Lissorhoptrus oryzophilus Kuschel, rice water weevil etc., is preferably Cnaphalocrocis medinali(rice leaf roller).
10. each described composition of claim 1-7 is used for pest control and improves the purposes of crop yield, and described insect is Cnaphalocrocis medinali(rice leaf roller), and described crop is paddy rice.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210499713.8A CN102992913B (en) | 2012-11-29 | 2012-11-29 | Insecticide-fertilizer composition containing chlorantraniliprole or flubendiamide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210499713.8A CN102992913B (en) | 2012-11-29 | 2012-11-29 | Insecticide-fertilizer composition containing chlorantraniliprole or flubendiamide |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102992913A true CN102992913A (en) | 2013-03-27 |
| CN102992913B CN102992913B (en) | 2014-11-26 |
Family
ID=47922100
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210499713.8A Active CN102992913B (en) | 2012-11-29 | 2012-11-29 | Insecticide-fertilizer composition containing chlorantraniliprole or flubendiamide |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102992913B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105325416A (en) * | 2015-12-16 | 2016-02-17 | 济南昊泽环保科技有限公司 | Insecticidal combination containing o-phenylenediamine insecticide and flubendiamide |
| CN105360133A (en) * | 2015-12-16 | 2016-03-02 | 济南昊泽环保科技有限公司 | Insecticide composition containing o-phenylenediamine insecticide and chlorantraniliprole |
| CN106831137A (en) * | 2017-02-21 | 2017-06-13 | 山东康德源农业科技有限公司 | A kind of full-service fluid medicine fertilizer and preparation method and application |
| CN112314620A (en) * | 2020-11-16 | 2021-02-05 | 辽宁山水益农科技有限公司 | Multi-effect insecticidal composition containing organic silicon plant growth regulator |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102276356A (en) * | 2011-07-11 | 2011-12-14 | 广西田园生化股份有限公司 | Stable controlled release particle pesticide-containing fertilizer |
| CN102515936A (en) * | 2011-11-20 | 2012-06-27 | 广东中迅农科股份有限公司 | Granular formulation for paddy pesticide fertilizer and preparation method thereof |
| CN102643133A (en) * | 2012-03-26 | 2012-08-22 | 张仕耀 | Formula mixing fertilizer with multiple pesticides and preparation method thereof |
| CN102775245A (en) * | 2012-08-16 | 2012-11-14 | 叶长东 | Pesticide-fertilizer composition containing Fipronil and pyrethroid pesticides |
-
2012
- 2012-11-29 CN CN201210499713.8A patent/CN102992913B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102276356A (en) * | 2011-07-11 | 2011-12-14 | 广西田园生化股份有限公司 | Stable controlled release particle pesticide-containing fertilizer |
| CN102515936A (en) * | 2011-11-20 | 2012-06-27 | 广东中迅农科股份有限公司 | Granular formulation for paddy pesticide fertilizer and preparation method thereof |
| CN102643133A (en) * | 2012-03-26 | 2012-08-22 | 张仕耀 | Formula mixing fertilizer with multiple pesticides and preparation method thereof |
| CN102775245A (en) * | 2012-08-16 | 2012-11-14 | 叶长东 | Pesticide-fertilizer composition containing Fipronil and pyrethroid pesticides |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105325416A (en) * | 2015-12-16 | 2016-02-17 | 济南昊泽环保科技有限公司 | Insecticidal combination containing o-phenylenediamine insecticide and flubendiamide |
| CN105360133A (en) * | 2015-12-16 | 2016-03-02 | 济南昊泽环保科技有限公司 | Insecticide composition containing o-phenylenediamine insecticide and chlorantraniliprole |
| CN106831137A (en) * | 2017-02-21 | 2017-06-13 | 山东康德源农业科技有限公司 | A kind of full-service fluid medicine fertilizer and preparation method and application |
| CN112314620A (en) * | 2020-11-16 | 2021-02-05 | 辽宁山水益农科技有限公司 | Multi-effect insecticidal composition containing organic silicon plant growth regulator |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102992913B (en) | 2014-11-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102992899B (en) | Insecticide-fertilizer composition containing bisultap and humic acid | |
| WO2002087330A2 (en) | Plant growth regulating composition for drought-resistance | |
| CN106305770B (en) | Glyphosate class Herbicidal combinations containing brassin lactones class compound | |
| CN102775245B (en) | Pesticide-fertilizer composition containing Fipronil and pyrethroid pesticides | |
| CN103102224B (en) | Insecticide-fertilizer composition containing benfuracarb | |
| CN102907424B (en) | Micro-capsule suspending agent containing pendimethalin | |
| CN102775246B (en) | Fipronil-containing pesticide fertilizer composition | |
| CN102992901A (en) | Insecticide-fertilizer composition containing organic heterocyclic insecticides | |
| CN106748248A (en) | A kind of efficiently volume increase water soluble fertilizer | |
| CN102992913A (en) | Insecticide-fertilizer composition containing chlorantraniliprole or flubendiamide | |
| CN102763682B (en) | Pesticide composite containing fipronil and pyrethroid pesticide | |
| CN104855397A (en) | Weeding composition and application thereof | |
| CN102626106B (en) | Fulvic acid-containing pesticide synergistic composition and use thereof | |
| CN103783044B (en) | The using method of chitin oligosaccharide in arviculture | |
| CN106359447B (en) | Glyphosate class Herbicidal combinations containing methyl α-naphthyl acetate class compound | |
| CN106305768B (en) | Glyphosate class Herbicidal combinations containing cycocel | |
| CN104211482A (en) | Multifunctional high calcium fertilizer | |
| CN104304263A (en) | Weeding composition | |
| CN106973916A (en) | The Herbicidal combinations of Han You metamifops and its application | |
| CN110463718A (en) | A kind of corn field Synergistic herbicide compositions and its application | |
| CN102415396A (en) | Compound insecticidal composition containing dinotefuran and carbosulfan and purpose thereof | |
| CN105325443A (en) | Pyrazosulfuron and bensulfuron methyl paddy field pesticide fertilizer particle, and preparation method thereof | |
| CN106518269A (en) | Plant root and stem growth promotion accessory ingredient | |
| CN104186580B (en) | A kind of Cotton Fields herbicides special | |
| CN107793250A (en) | Liquid organic boron fertilizer and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: The invention relates to a pharmaceutical fertilizer composition containing chlorantraniliprole or Flubendiamide Effective date of registration: 20200923 Granted publication date: 20141126 Pledgee: Bank of Communications Ltd. the Guangxi Zhuang Autonomous Region branch Pledgor: Ye Changdong Registration number: Y2020450000039 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Granted publication date: 20141126 Pledgee: Bank of Communications Ltd. the Guangxi Zhuang Autonomous Region branch Pledgor: Ye Changdong Registration number: Y2020450000039 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right |