CN102992913B - Insecticide-fertilizer composition containing chlorantraniliprole or flubendiamide - Google Patents
Insecticide-fertilizer composition containing chlorantraniliprole or flubendiamide Download PDFInfo
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- CN102992913B CN102992913B CN201210499713.8A CN201210499713A CN102992913B CN 102992913 B CN102992913 B CN 102992913B CN 201210499713 A CN201210499713 A CN 201210499713A CN 102992913 B CN102992913 B CN 102992913B
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Abstract
The invention relates to an insecticide-fertilizer composition containing chlorantraniliprole or flubendiamide. The composition comprises an active ingredient, synergistic ingredients and fertilizing ingredients, wherein the active ingredient is chlorantraniliprole or flubendiamide; the synergistic ingredients consist of fulvic acid and chloromethylsilatrane; the fertilizing ingredients contain any one or more of ammonium sulfate, potassium sulfate, urea, ammonium nitrate, ammonium bicarbonate, potassium chloride, potassium dihydrogen phosphate, superphosphate and calcium magnesia phosphate fertilizer. The insecticide-fertilizer composition has beneficial effects that with fulvic acid and chloromethylsilatrane as the synergistic auxiliary agents of an insecticide, and at the same time in cooperation with the use of a compound fertilizer, the insecticide-fertilizer composition can increase the crop yield, and at the same time can also improve the pest preventing effect.
Description
Technical field
The invention belongs to agrochemical field, relate to the medicine fertilizer composition being formed by sterilant, synergistic component and plant nutrient substance, relate to particularly a kind of medicine fertilizer composition that comprises Rynaxypyr or fipronil bisamide and uses thereof.
Background technology
Rynaxypyr is high-efficiency broad spectrum, lepidopterous Noctuidae, Pyralidae, Carposinidae, tortricid, miller section, diamond-back moth section, Gelechidae, Gracilariidae etc. is all had to the sterilant of good control effect, can also control Coleoptera Culculionidae, Chrysomelidae; Diptera Agromyzidae; The multiple non-lepidoptera pest such as Bemisia tabaci.Effective to lepidopterous insect, the period is very long.
Fipronil bisamide belongs to Novel ortho benzenedicarboxamide insecticides, activates ryanodine receptor calcium release passage, causes the property out of control of storing calcium ion to discharge.It is current few in number compound that acts on insect cell ryanodine receptor.Lepidoptera pest is had to spectrum preventive effect, produce without cross resistance with existing sterilant, be suitable for very much the control that existing sterilant produces the insect of resistance.Larva is had to very outstanding preventive effect, limited to adult preventive effect, there is no ovicidal action.After in infiltration plant body, by xylem, slightly conduct.Resistance of rainwater washing against.
Also not for the medicine fertilizer composition of these two kinds of agricultural chemicals, the present invention, for solving the blank of the medicine fertilizer composition of these two kinds of sterilants, has proposed the technical scheme of new medicine fertilizer composition at present.
Summary of the invention
For solving the problems of the technologies described above, the invention provides a kind of medicine fertilizer composition that comprises Rynaxypyr or fipronil bisamide, said composition comprises activeconstituents, synergistic component and fertilizer component, activeconstituents is Rynaxypyr or fipronil bisamide, synergistic component is comprised of xanthohumic acid and silicon Feng Huan, fertilizer component comprises ammonium sulfate, potassium sulfate, urea, ammonium nitrate, bicarbonate of ammonia, any one in Repone K, potassium primary phosphate, calcium superphosphate and fused(calcium magnesium)phosphate or multiple.
In above-mentioned medicine fertilizer composition, the weight ratio of xanthohumic acid and silicon Feng Huan is 1: 0.01-5, preferred, weight ratio is 1: 0.1-1.
In above-mentioned medicine fertilizer composition, the weight ratio of activeconstituents, synergistic component and fertilizer component is 0.01-0.1: 1-20: 80-99, and preferred, weight ratio is 0.01-0.05: 5-15: 85-95.
In above-mentioned medicine fertilizer composition, the xanthohumic acid of xanthohumic acid for extracting from the alcohol slops of sugarcane deep processing alcohol.The preparation method of the xanthohumic acid preferably, extracting from the alcohol slops of sugarcane deep processing alcohol is as follows:
The alcohol slops heating evaporation that reduces pressure is concentrated, control pressure, vaporization temperature is 40 ℃ ± 3 ℃, the weight percent of measuring dry-matter in concentrated solution stops heating while reaching 60%, obtains concentrated solution; Stirred liq at the uniform velocity in heat-processed.Then in concentrated solution, add the vitriol oil, make the mass concentration of sulfuric acid in concentrated solution reach 30%, at 60 ± 2 ℃, ageing is 20 hours, obtains ageing liquid;
Sodium hydroxide solution alkalization by ageing liquid with 0.5%wt, under stirring, add sodium hydroxide solution, measure the pH of solution, regulate the add-on of sodium hydroxide solution, when being 8, pH stops adding sodium hydroxide solution, in solution, there is precipitation, precipitation part, by removing by filter, is obtained to solution I;
Hydrochloric acid soln acidifying by the solution I of above-mentioned acquisition with 8%wt, stirs and measures pH while adding hydrochloric acid soln, stop adding hydrochloric acid soln when pH value is 1, occurs precipitation in solution, and precipitation part, by removing by filter, is obtained to solution II;
In solution II, add acetone, 10% of the volume that the volume of the acetone adding is solution II.To add the solution of acetone fully to stir, then centrifugal layering, collects acetone soln part;
Acetone soln is partly inputted in still kettle, and decompression heating maintains the temperature at 45 ℃ ± 2 ℃ and concentrates acetone soln, by recover acetone, and remaining material, process decompression heating maintains the temperature at 45 ℃ ± 2 ℃ dry, after being dried, obtains solid phase prod xanthohumic acid.
Above-mentioned medicine fertilizer composition can be prepared into liquid medicine fertilizer composition, also can be prepared into solid medicine fertilizer composition.
The fertilizing method of above-mentioned medicine fertilizer composition, for spraying or irrigating, is preferably and sprays.
The present invention also provides a kind of method of preventing and treating crop pest and improving crop yield, the method comprises and will after above-mentioned medicine fertilizer composition dilution, spray crop, wherein said crop is eggplant, tomato, potato, sweet potato, radish, jowar, tobacco, wheat, paddy rice, corn, cucumber, peanut, coconut, balsam pear, soybean, tea tree, rubber, sugarcane, pea, wax gourd, pears, banana, pawpaw, green soy bean, mango, watermelon, oranges and tangerines, orange, Kiwifruit, strawberry, pineapple, capsicum, apple, jujube, persimmon, grape, cherry, lichee, any in peach and cotton, be preferably paddy rice.
In aforesaid method, described insect is Cnaphalocrocis medinali(rice leaf roller), striped rice borer, yellow rice borer, pink rice borer, to pachydiplosis oryzae, Lissorhoptrus oryzophilus Kuschel, rice water weevil etc., is preferably Cnaphalocrocis medinali(rice leaf roller).
The present invention also provides above-mentioned composition for pest control and has improved the purposes of crop yield, and described insect is Cnaphalocrocis medinali(rice leaf roller), and described crop is paddy rice.
Medicine fertilizer composition of the present invention, through using xanthohumic acid and silicon Feng Huan as the builder of sterilant, coordinates the use of composite fertilizer simultaneously, makes medicine fertilizer composition of the present invention can improve the output of crop, can also improve the preventive effect to insect simultaneously.
Embodiment
In order to understand the present invention, with embodiment, further illustrate the present invention below, but do not limit the present invention.
The material of using in following embodiment is market and buys, and from market, all can buy and obtain.The preparation method of liquid medicine fertilizer mixes activeconstituents, synergistic component and fertilizer component.
The xanthohumic acid of xanthohumic acid for extracting from the alcohol slops of sugarcane deep processing alcohol, preparation method is as follows:
1kg alcohol slops decompression heating evaporation is concentrated, control pressure, vaporization temperature is 40 ℃ ± 3 ℃, when the weight percent of dry-matter reaches 60% in measurement concentrated solution, stops heating, obtains concentrated solution; Stirred liq at the uniform velocity in heat-processed.Then in concentrated solution, add the vitriol oil, make the mass concentration of sulfuric acid in concentrated solution reach 30%, at 60 ± 2 ℃, ageing is 20 hours, obtains ageing liquid;
Sodium hydroxide solution alkalization by ageing liquid with 0.5%wt, under stirring, add sodium hydroxide solution, measure the pH of solution, regulate the add-on of sodium hydroxide solution, when being 8, pH stops adding sodium hydroxide solution, in solution, there is precipitation, precipitation part, by removing by filter, is obtained to solution I;
Hydrochloric acid soln acidifying by the solution I of above-mentioned acquisition with 8%wt, stirs and measures pH while adding hydrochloric acid soln, stop adding hydrochloric acid soln when pH value is 1, occurs precipitation in solution, and precipitation part, by removing by filter, is obtained to solution II;
In solution II, add acetone, 10% of the volume that the volume of the acetone adding is solution II.To add the solution of acetone fully to stir, then centrifugal layering, collects acetone soln part;
Acetone soln is partly inputted in still kettle, decompression heating maintains the temperature at concentrated acetone soln at 45 ℃ ± 2 ℃, by recover acetone, and remaining material, through decompression heating, maintain the temperature at 45 ℃ ± 2 ℃ and be dried, after being dried, obtain solid phase prod xanthohumic acid 21.78g.
Embodiment 1:
Get pesticide activity component 20% Rynaxypyr suspension agent 0.10kg, xanthohumic acid 8kg, the former medicine 2kg of silicon Feng Huan, urea 31kg, fused(calcium magnesium)phosphate 30kg, potassium sulfate 28.9kg, fully mixes each component according to weight.
Embodiment 2:
Get pesticide activity component 20% fipronil bisamide water dispersible granules 0.10kg, xanthohumic acid 5kg, the former medicine 5kg of silicon Feng Huan, urea 31kg, fused(calcium magnesium)phosphate 30kg, potassium sulfate 28.9kg, fully mixes each component according to weight.
Comparative example 1:
Get xanthohumic acid 8kg, the former medicine 2kg of silicon Feng Huan, urea 31kg, fused(calcium magnesium)phosphate 30kg, potassium sulfate 28.9kg, fully mixes each component according to weight.
Comparative example 2:
Get xanthohumic acid 5kg, the former medicine 5kg of silicon Feng Huan, urea 31kg, fused(calcium magnesium)phosphate 30kg, potassium sulfate 28.9kg, fully mixes each component according to weight.
Effect embodiment:
Application Example 1-2 and comparative example 1-2 spray paddy rice, control Cnaphalocrocis medinali(rice leaf roller).The experiment of carrying out for the essentially identical rice terrace of upgrowth situation, the experiment number of each processing is 3 times, the calculating output of averaging, the preventive effect of Cnaphalocrocis medinali(rice leaf roller).Various samples are watered to dilution to be sprayed.
The concentration of embodiment 1 and effective agricultural chemicals of embodiment 2 processing paddy rice is identical with the effective level that 20% Rynaxypyr suspension agent and fipronil bisamide water dispersible granules are processed paddy rice, in medicine fertilizer, owing to containing synergistic agent and fertilizer, institute is so that increasing production of rice, not only can reach the object of increasing production of rice, also realized the raising of paddy rice Cnaphalocrocis medinali(rice leaf roller) preventive effect, this raising is to realize by the synergistic blend of pesticide activity component and synergistic agent, fertilizer, and this synergy has exceeded inventor's expectation.Because use separately comparative example 1 and comparative example's 2 composition, also can reach the object of volume increase, but add after pesticide activity component, output further improves.Medicine fertilizer composition has demonstrated the dual purpose of good volume increase and insect protected, and is the effect that increases insect protected.
Claims (3)
1. the method for preventing and treating crop pest and improving crop yield, the method comprises and will after the medicine fertilizer composition dilution that comprise Rynaxypyr or fipronil bisamide, spray crop, wherein said crop is paddy rice, wherein said insect is Cnaphalocrocis medinali(rice leaf roller), and wherein said medicine fertilizer composition is prepared from by the following method:
Get pesticide activity component 20% Rynaxypyr suspension agent 0.10kg, xanthohumic acid 8kg, the former medicine 2kg of silicon Feng Huan, urea 31kg, fused(calcium magnesium)phosphate 30kg, potassium sulfate 28.9kg, fully mixes each component according to weight; Or,
Get pesticide activity component 20% fipronil bisamide water dispersible granules 0.10kg, xanthohumic acid 5kg, the former medicine 5kg of silicon Feng Huan, urea 31kg, fused(calcium magnesium)phosphate 30kg, potassium sulfate 28.9kg, fully mixes each component according to weight.
2. method according to claim 1, the wherein xanthohumic acid of xanthohumic acid for extracting from the alcohol slops of sugarcane deep processing alcohol.
3. method according to claim 2, the preparation method that wherein xanthohumic acid is the xanthohumic acid that extracts from the alcohol slops of sugarcane deep processing alcohol is as follows:
The alcohol slops heating evaporation that reduces pressure is concentrated, control pressure, vaporization temperature is 40 ℃ ± 3 ℃, the weight percent of measuring dry-matter in concentrated solution stops heating while reaching 60%, obtains concentrated solution; Stirred liq at the uniform velocity in heat-processed then adds the vitriol oil in concentrated solution, makes the mass concentration of sulfuric acid in concentrated solution reach 30%, and at 60 ± 2 ℃, ageing is 20 hours, obtains ageing liquid; Sodium hydroxide solution alkalization by ageing liquid with 0.5%wt, under stirring, add sodium hydroxide solution, measure the pH of solution, regulate the add-on of sodium hydroxide solution, when being 8, pH stops adding sodium hydroxide solution, in solution, there is precipitation, precipitation part, by removing by filter, is obtained to solution I;
Hydrochloric acid soln acidifying by the solution I of above-mentioned acquisition with 8%wt, stirs and measures pH while adding hydrochloric acid soln, stop adding hydrochloric acid soln when pH value is 1, occurs precipitation in solution, and precipitation part, by removing by filter, is obtained to solution II;
In solution II, add acetone, 10% of the volume that the volume of the acetone adding is solution II, will add the solution of acetone fully to stir, and acetone soln part is collected in then centrifugal layering;
Acetone soln is partly inputted in still kettle, and decompression heating maintains the temperature at 45 ℃ ± 2 ℃ and concentrates acetone soln, by recover acetone, and remaining material, process decompression heating maintains the temperature at 45 ℃ ± 2 ℃ dry, after being dried, obtains solid phase prod xanthohumic acid.
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| CN201210499713.8A CN102992913B (en) | 2012-11-29 | 2012-11-29 | Insecticide-fertilizer composition containing chlorantraniliprole or flubendiamide |
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| CN201210499713.8A CN102992913B (en) | 2012-11-29 | 2012-11-29 | Insecticide-fertilizer composition containing chlorantraniliprole or flubendiamide |
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| CN102992913B true CN102992913B (en) | 2014-11-26 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105325416A (en) * | 2015-12-16 | 2016-02-17 | 济南昊泽环保科技有限公司 | Insecticidal combination containing o-phenylenediamine insecticide and flubendiamide |
| CN105360133A (en) * | 2015-12-16 | 2016-03-02 | 济南昊泽环保科技有限公司 | Insecticide composition containing o-phenylenediamine insecticide and chlorantraniliprole |
| CN106831137A (en) * | 2017-02-21 | 2017-06-13 | 山东康德源农业科技有限公司 | A kind of full-service fluid medicine fertilizer and preparation method and application |
| CN112314620A (en) * | 2020-11-16 | 2021-02-05 | 辽宁山水益农科技有限公司 | Multi-effect insecticidal composition containing organic silicon plant growth regulator |
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| CN102276356A (en) * | 2011-07-11 | 2011-12-14 | 广西田园生化股份有限公司 | Stable controlled release particle pesticide-containing fertilizer |
| CN102515936A (en) * | 2011-11-20 | 2012-06-27 | 广东中迅农科股份有限公司 | Granular formulation for paddy pesticide fertilizer and preparation method thereof |
| CN102643133A (en) * | 2012-03-26 | 2012-08-22 | 张仕耀 | Formula mixing fertilizer with multiple pesticides and preparation method thereof |
| CN102775245A (en) * | 2012-08-16 | 2012-11-14 | 叶长东 | Pesticide-fertilizer composition containing Fipronil and pyrethroid pesticides |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102276356A (en) * | 2011-07-11 | 2011-12-14 | 广西田园生化股份有限公司 | Stable controlled release particle pesticide-containing fertilizer |
| CN102515936A (en) * | 2011-11-20 | 2012-06-27 | 广东中迅农科股份有限公司 | Granular formulation for paddy pesticide fertilizer and preparation method thereof |
| CN102643133A (en) * | 2012-03-26 | 2012-08-22 | 张仕耀 | Formula mixing fertilizer with multiple pesticides and preparation method thereof |
| CN102775245A (en) * | 2012-08-16 | 2012-11-14 | 叶长东 | Pesticide-fertilizer composition containing Fipronil and pyrethroid pesticides |
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Denomination of invention: The invention relates to a pharmaceutical fertilizer composition containing chlorantraniliprole or Flubendiamide Effective date of registration: 20200923 Granted publication date: 20141126 Pledgee: Bank of Communications Ltd. the Guangxi Zhuang Autonomous Region branch Pledgor: Ye Changdong Registration number: Y2020450000039 |
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