JP5185547B2 - Insecticide / nematicide composition and pest control method - Google Patents
Insecticide / nematicide composition and pest control method Download PDFInfo
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- JP5185547B2 JP5185547B2 JP2007056907A JP2007056907A JP5185547B2 JP 5185547 B2 JP5185547 B2 JP 5185547B2 JP 2007056907 A JP2007056907 A JP 2007056907A JP 2007056907 A JP2007056907 A JP 2007056907A JP 5185547 B2 JP5185547 B2 JP 5185547B2
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- organophosphorus
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- insecticide
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Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
本発明は、各種線虫と、土壌害虫等の昆虫の同時防除に有効な殺虫・殺線虫剤組成物及び害虫の防除方法に関する。 The present invention relates to an insecticide / nematicide composition effective for simultaneous control of various nematodes and insects such as soil pests, and a method for controlling pests.
S−sec−ブチル O−エチル 2−オキソ−1,3−チアゾリジン−3−イルホスホノチオアートは米国特許第4590182号に開示された化合物である。O−エチル−S−n−プロピル(2−シアノイミノ−3−エチル−イミダゾリジン−1−イル)ホスホノチオレートは米国特許第5405961号に開示された化合物である。S,S−ジ−sec−ブチル O−エチル ホスホロジチオアートは米国特許第4535077号に開示された化合物である。それらは、公知の有機リン系殺線虫剤の有効成分である。また、これまで、有機リン系殺虫剤が知られている。しかしながら、特定の有機リン系殺線虫剤と特定の有機リン系殺虫剤とを組み合わせたとき、害虫の防除に関し相乗的な効果を発揮することはあまり知られていない。特開平1−238505号には、上記S−sec−ブチル O−エチル 2−オキソ−1,3−チアゾリジン−3−イルホスホノチオアートを含む有機リン系殺線虫剤と有機リン系殺虫剤との組み合わせについて開示がある。 S-sec-butyl O-ethyl 2-oxo-1,3-thiazolidin-3-ylphosphonothioate is a compound disclosed in US Pat. No. 4,590,182. O-ethyl-Sn-propyl (2-cyanoimino-3-ethyl-imidazolidin-1-yl) phosphonothiolate is a compound disclosed in US Pat. No. 5,405,961. S, S-di-sec-butyl O-ethyl phosphorodithioate is a compound disclosed in US Pat. No. 4,535,077. They are active ingredients of known organophosphorus nematicides. Until now, organophosphorus insecticides are known. However, it is not well known that when a specific organophosphorus nematicide and a specific organophosphorus pesticide are combined, they exhibit a synergistic effect on pest control. JP-A-1-238505 discloses an organophosphorus nematicide containing the above S-sec-butyl O-ethyl 2-oxo-1,3-thiazolidin-3-ylphosphonothioate and an organophosphorus insecticide. There is a disclosure about the combination.
公知の殺線虫剤及び殺虫剤の各々を単独で防除するよりも、双方の防除効果が相乗的に強化された殺虫・殺線虫剤が希求されている。 Rather than controlling each of the known nematicides and insecticides alone, there is a need for insecticides and nematicides in which the control effects of both are synergistically enhanced.
本発明者らは、これら課題を解決すべく検討を重ねた結果、特定の有機リン系殺線虫剤と、特定の殺虫剤とを組合せることにより、予期される以上の効果が得られるとの知見を得、本発明を完成した。 As a result of repeated investigations to solve these problems, the present inventors have obtained an effect more than expected by combining a specific organophosphorus nematicide and a specific insecticide. As a result, the present invention was completed.
即ち、本発明は、S−sec−ブチル O−エチル 2−オキソ−1,3−チアゾリジン−3−イルホスホノチオアート、O−エチル−S−n−プロピル(2−シアノイミノ−3−エチル−イミダゾリジン−1−イル)ホスホノチオレート及びS,S−ジ−sec−ブチル O─エチル ホスホロジチオアートから成る群から選ばれる少なくとも1種の有機リン系殺線虫剤と、有機リン系殺虫剤とを有効成分として含有することを特徴とする殺虫・殺線虫剤組成物に関する。また、本発明は、それらの有効成分を害虫又は害虫の生息場所に処理することを特徴とする害虫の防除方法に関する。 That is, the present invention relates to S-sec-butyl O-ethyl 2-oxo-1,3-thiazolidin-3-ylphosphonothioate, O-ethyl-Sn-propyl (2-cyanoimino-3-ethyl-imidazo At least one organophosphorus nematicide selected from the group consisting of lysine-1-yl) phosphonothiolate and S, S-di-sec-butyl O-ethyl phosphorodithioate, and an organophosphorus insecticide The present invention relates to an insecticidal / nematicide composition characterized by containing The present invention also relates to a method for controlling pests, characterized by treating those active ingredients in pests or pest habitats.
S−sec−ブチル O−エチル 2−オキソ−1,3−チアゾリジン−3−イルホスホノチオアートには、光学異性体が存在し、ラセミ体の他に(−)体及び(+)体が含まれる。ラセミ体である(R,S)−S−sec−ブチル O−エチル 2−オキソ−1,3−チアゾリジン−3−イルホスホノチオアートは、一般名ホスチアゼート(Fosthiazate)として知られている化合物である。 S-sec-butyl O-ethyl 2-oxo-1,3-thiazolidin-3-ylphosphonothioate has optical isomers and includes (−) and (+) isomers in addition to racemates. It is. The racemic (R, S) -S-sec-butyl O-ethyl 2-oxo-1,3-thiazolidin-3-ylphosphonothioate is a compound known by the generic name Fosthiazate. .
O−エチル−S−n−プロピル(2−シアノイミノ−3−エチル−イミダゾリジン−1−イル)ホスホノチオレートにも、光学異性体が存在し、ラセミ体の他に(−)体及び(+)体が含まれる。ラセミ体は、一般名イミシアホス(Imicyafos)として知られている化合物である。 O-ethyl-Sn-propyl (2-cyanoimino-3-ethyl-imidazolidin-1-yl) phosphonothiolate also has an optical isomer, and in addition to the racemate, the (−) and (+ ) The body is included. Racemate is a compound known by the general name Imicyafos.
S,S−ジ−sec−ブチル O−エチル ホスホロジチオアートは、一般名カズサホス(cadusafos)として知られている化合物である。 S, S-di-sec-butyl O-ethyl phosphorodithioate is a compound known by the general name cadusafos.
有機リン系殺虫剤としては、例えば、ピリダフェンチオン(Pyridaphenthion)、イソキサチオン(Isoxathion)、ダイアジノン(Diazinon)、クロルピリホス(Chlorpyrifos)、フェニトロチオン(Fenitrohion)、シアノホス(Cyanophos)、プロフェノホス(Profenofos)、アセフェート(Acephate)、ジクロルボス(Dichlorvos)、フェナミホス(Fenamiphos)、EPN、クロルピリホスメチル(Chlorpyrifos-methyl)、プロチオホス(Prothiofos)、ホスホカルブ(Phosphocarb)、ジスルホトン(Dislufoton)、デメトン-S-メチル(Demeton-S-methyl)、ジメトエート(Dimethoate)、メタミドホス(Methamidophos)、イソフェンホス(Isofenphos)、エチオン(Ethion)、エトリムホス(Etrimfos)、キナルホス(Quinalphos)、ジメチルビンホス(Dimethylvinphos)、スルプロホス(Sulprofos)、チオメトン(Thiometon)、バミドチオン(Vamidothion)、ピラクロホス(Pyraclofos)、ピリミホスメチル(Pirimiphos-methyl)、プロパホス(Propaphos)、ホサロン(Phosalone)、ホルモチオン(Formothion)、マラチオン(Malathion)、テトラクロルビンホス(Tetrachlovinphos)、クロルフェンビンホス(Chlorfenvinphos)、トリクロルホン(Trichlorfon)、メチダチオン(Methidathion)、フェントエート(Phenthoate)、ESP、アジンホスメチル(Azinphos-methyl)、フェンチオン(Fenthion)、ヘプテノホス(Heptenophos)、メトキシクロル(Methoxychlor)、パラチオン(Paration)、モノクロトホス(Monocrotophos)、パラチオン-メチル(Parathion-methyl)、テルブホス(Terbufos)、ホスファミドン(Phospamidon)、ホスメット(Phosmet)、ホレート(Phorate)などが挙げられる。これらは、The Pesticide Manual(第13版;BRITISH CROP PROTECTION COUNCIL)等に記載の化合物である。これらの中でも、ピリダフェンチオン(Pyridaphenthion)、イソキサチオン(Isoxathion)、ダイアジノン(Diazinon)、クロルピリホス(Chlorpyrifos)、フェニトロチオン(Fenitrohion)、シアノホス(Cyanophos)、プロフェノホス(Profenofos)、アセフェート(Acephate)などの土壌害虫の防除に優れた殺虫剤が望ましい。S−sec−ブチル O−エチル 2−オキソ−1,3−チアゾリジン−3−イルホスホノチオアートとの組合せにおいては、ピリダフェンチオン(Pyridaphenthion)を用いるのが、特に望ましい。また、O−エチル−S−n−プロピル(2−シアノイミノ−3−エチル−イミダゾリジン−1−イル)ホスホノチオレート及びS,S−ジ−sec−ブチル O─エチル ホスホロジチオアートから成る群から選ばれる少なくとも1種の有機リン系殺線虫剤との組合せにおいては、これら有機リン系殺虫剤のうち、ピリダフェンチオン(Pyridaphenthion)、イソキサチオン(Isoxathion)、ダイアジノン(Diazinon)及びクロルピリホス(Chlorpyrifos)から成る群から選ばれる少なくとも1種を用いるのが、特に望ましい。 Examples of organophosphorus insecticides include pyridaphenthion, isoxathion, diazinon, chlorpyrifos, fenitrohion, cyanophos, profenofos, acephete, and acephate. Dichlorvos, Fenamiphos, EPN, Chlorpyrifos-methyl, Prothiofos, Phosphocarb, Dislufoton, Demeton-S-methyl, Dimethoate ( Dimethoate, Methamidophos, Isofenphos, Ethion, Etrimfos, Quinalphos, Dimethylvinphos, Sulprofos, Thiometon, Vamidothion, Vamidothion Pila Chlophos (Pyraclofos), Pirimiphos-methyl, Propaphos, Phosalone, Formothion, Malathion, Tetrachlovinphos, Chlorfenvinphos, Trichlorfone (Chlorfenvinphos) Trichlorfon, Methidathion, Phenthoate, ESP, Azinphos-methyl, Fenthion, Heptenophos, Methoxychlor, Paration, Monocrotophos, Parathion Examples thereof include methyl (Parathion-methyl), terbufos (Terbufos), phosphamidon (Phospamidon), phosmet (Phosmet), and holate (Phorate). These are compounds described in The Pesticide Manual (13th edition; BRITISH CROP PROTECTION COUNCIL) and the like. Among these, soil damage such as pyridafenthion (Pyridaphenthion), isoxathion (Isoxathion), diazinon (Diazinon), chlorpyrifos (Chlorpyrifos), fenitrothion (Fenitrohion), cyanophos (Cyanophos), profenofos (Acfenate) and insect pest control A good insecticide is desirable. In combination with S-sec-butyl O-ethyl 2-oxo-1,3-thiazolidin-3-ylphosphonothioate, it is particularly desirable to use pyridaphenthion. The group consisting of O-ethyl-Sn-propyl (2-cyanoimino-3-ethyl-imidazolidin-1-yl) phosphonothiolate and S, S-di-sec-butyl O-ethyl phosphorodithioate In combination with at least one organophosphorus nematicide selected from the group consisting of Pyridaphenthion, Isoxathion, Diazinon and Chlorpyrifos among these organophosphorus insecticides It is particularly desirable to use at least one selected from the group.
本発明組成物は、昆虫、線虫等の各種害虫に対して優れた防除効力を有する。 The composition of the present invention has an excellent control effect against various pests such as insects and nematodes.
本発明組成物において、特定の有機リン系殺線虫剤と有機リン系殺虫剤との混合割合は、重量比で通常10:1〜1:50の割合、望ましくは5:1〜1:30の割合、さらに望ましくは2:1〜1:20の割合である。 In the composition of the present invention, the mixing ratio of the specific organophosphorus nematicide and organophosphorus insecticide is usually a ratio of 10: 1 to 1:50, preferably 5: 1 to 1:30 by weight. The ratio is more preferably 2: 1 to 1:20.
本発明組成物は、有効成分の他に補助剤を含有する。有効成分の配合割合は0.05〜75重量%であればよい。補助剤としては担体、乳化剤、懸濁剤、分散剤、展着剤、浸透剤、湿潤剤、増粘剤、安定剤などが挙げられ、必要により適宜添加すればよい。担体としては、固体担体と液体担体に分けられ、固体担体としては、澱粉、活性炭、大豆粉、小麦粉、木粉、魚粉、粉乳などの動植物性粉末;タルク、カオリン、ベントナイト、炭酸カルシウム、ゼオライト、珪藻土、ホワイトカーボン、クレー、アルミナ、硫黄粉末などの鉱物性粉末などが挙げられ、液体担体としては、水、メチルアルコール、エチレングリコールなどのアルコール類;アセトン、メチルエチルケトンなどのケトン類;ジオキサン、テトラヒドロフランなどのエーテル類;ケロシン、灯油などの脂肪族炭化水素類;キシレン、トリメチルベンゼン、テトラメチルベンゼン、シクロヘキサン、ソルベントナフサなどの芳香族炭化水素類;クロロホルム、クロロベンゼンなどのハロゲン化炭化水素類;ジメチルホルムアミドなどの酸アミド類;酢酸エチルエステル、脂肪酸のグリセリンエステルなどのエステル類;アセトニトリルなどのニトリル類;ジメチルスルホキシドなどの含硫化化合物類などが挙げられる。乳化剤、懸濁剤、分散剤、展着剤、浸透剤、湿潤剤などとしては、各種の界面活性剤が使用される。また、必要に応じて他の農薬、例えば殺虫剤、殺ダニ剤、殺線虫剤、殺菌剤、抗ウイルス剤、誘引剤、除草剤、植物成長調整剤などと混用、併用することができ、この場合に一層優れた効果を示すこともある。 The composition of the present invention contains an auxiliary agent in addition to the active ingredient. The blending ratio of the active ingredient may be 0.05 to 75% by weight. Examples of the auxiliary agent include a carrier, an emulsifier, a suspending agent, a dispersing agent, a spreading agent, a penetrating agent, a wetting agent, a thickening agent, a stabilizer, and the like. The carrier is divided into a solid carrier and a liquid carrier, and the solid carrier includes starch, activated carbon, soybean flour, wheat flour, wood flour, fish flour, powdered milk and other animal and vegetable powders; talc, kaolin, bentonite, calcium carbonate, zeolite, Examples include mineral powders such as diatomaceous earth, white carbon, clay, alumina, and sulfur powder. Examples of liquid carriers include water, alcohols such as methyl alcohol and ethylene glycol; ketones such as acetone and methyl ethyl ketone; dioxane, tetrahydrofuran, and the like. Ethers; aliphatic hydrocarbons such as kerosene and kerosene; aromatic hydrocarbons such as xylene, trimethylbenzene, tetramethylbenzene, cyclohexane and solvent naphtha; halogenated hydrocarbons such as chloroform and chlorobenzene; dimethylformamide Acid amides; nitriles such as acetonitrile; ethyl acetate, esters such as glycerin esters of fatty acids such as sulfur-containing compounds such as dimethyl sulfoxide. Various surfactants are used as the emulsifier, suspending agent, dispersing agent, spreading agent, penetrating agent, wetting agent and the like. Also, if necessary, it can be mixed with other agricultural chemicals such as insecticides, acaricides, nematicides, fungicides, antiviral agents, attractants, herbicides, plant growth regulators, etc. In this case, a more excellent effect may be exhibited.
本発明組成物は、乳剤、粉剤、微粒剤F、微粒剤、粒剤、錠剤、水和剤、液剤、エアゾール剤、ペースト剤、フロアブル剤、ドライフロアブル剤、マイクロカプセル剤などの種々の形態に製剤することができる。なかでも乳剤、微粒剤、水和剤、液剤、粉剤、粒剤、錠剤などの形態がより望ましく、乳剤、微粒剤、粒剤、水和剤、液剤などの形態が最も望ましい。乳剤における好ましい配合割合は、有効成分5〜75重量部、担体90〜10重量部及び界面活性剤5〜15重量部である。また粉剤、粒剤及び錠剤における好ましい配合割合は、有効成分0.1〜10重量部、担体85〜99重量部及び界面活性剤0.5〜5重量部である。これら製剤の実際の使用に際しては、そのまま使用するか、または水等の希釈剤で所定濃度に希釈して使用することができる。 The composition of the present invention can be used in various forms such as emulsions, powders, fine granules F, fine granules, granules, tablets, wettable powders, liquids, aerosols, pastes, flowables, dry flowables, and microcapsules. Can be formulated. Of these, forms such as emulsions, fine granules, wettable powders, liquids, powders, granules, tablets and the like are more desirable, and forms such as emulsions, fine granules, granules, wettable powders and liquids are most desirable. A preferable blending ratio in the emulsion is 5 to 75 parts by weight of the active ingredient, 90 to 10 parts by weight of the carrier, and 5 to 15 parts by weight of the surfactant. Moreover, the preferable mixture ratio in a powder agent, a granule, and a tablet is 0.1-10 weight part of active ingredients, 85-99 weight part of support | carriers, and 0.5-5 weight part of surfactant. In actual use of these preparations, they can be used as they are or diluted to a predetermined concentration with a diluent such as water.
本発明組成物は一般に0.1〜10000ppm望ましくは1〜1000ppmの有効成分濃度で施用する。これらの有効成分濃度は、製剤の形態及び施用する方法、目的、時期、場所及び害虫の発生状況等によって適当に変更できる。単位面積あたりの施用量は10a当たり、有効成分化合物として約1〜5000g、好ましくは10〜1000gが使用される。しかし、特別の場合には、これらの範囲を逸脱することも可能である。本発明組成物の施用方法としては、土壌混和処理、植穴処理、植溝処理、潅注処理、また種子などに対して浸漬処理、粉衣処理などが挙げられる。 The composition of the present invention is generally applied at an active ingredient concentration of 0.1 to 10,000 ppm, preferably 1-1000 ppm. The concentration of these active ingredients can be appropriately changed depending on the form of the preparation and the method of application, purpose, time, place and occurrence of pests. The application amount per unit area is about 1 to 5000 g, preferably 10 to 1000 g as an active ingredient compound per 10a. However, in special cases, it is possible to deviate from these ranges. Examples of the application method of the composition of the present invention include soil admixing treatment, planting hole treatment, grooving treatment, irrigation treatment, and soaking treatment and dressing treatment for seeds.
本発明には、本発明組成物を有害生物に処理する方法の他、前記有機リン系殺線虫剤及び有機リン系殺虫剤を同時に害虫または害虫の生息場所に処理する方法、前記有機リン系殺線虫剤及び有機リン系殺虫剤のどちらか一方の薬剤を害虫または害虫の生息場所に処理した後、他方の薬剤を害虫または害虫の生息場所に処理する方法が含まれる。 In addition to the method of treating the composition of the present invention with pests, the present invention includes a method of treating the organophosphorus nematicide and organophosphorus insecticide at the same time in a pest or a pest habitat, and the organophosphorus A method of treating one of a nematicide and an organophosphorus insecticide in a pest or a pest habitat and then treating the other pest in the pest or pest habitat is included.
本発明が適用できる害虫としては、線虫類、等脚類、鞘翅目害虫、鱗翅目害虫、腹足類、直翅目害虫、植物寄生性ダニ類、アザミウマ目害虫、双翅目害虫、膜翅目害虫、隠翅目害虫、シラミ目害虫、等翅目害虫、半翅目害虫、ワラジムシ類、ムカデ類、ヤスデ類などの各種害虫が挙げられる。特に本発明は農園芸作物および樹木などを土壌中で加害する害虫や、農園芸作物や樹木の種子を加害する害虫、例えば、前記線虫類、等脚類、鞘翅目害虫、鱗翅目害虫、腹足類、直翅目害虫、植物寄生性ダニ類などに有効である。本発明が適用できる各種害虫の具体例を以下に示す。 Examples of the pests to which the present invention can be applied include nematodes, isopods, Coleoptera pests, lepidopterous pests, gastropods, orthoptera pests, plant parasitic mites, thrips pests, diptera pests, hymenoptera Various insect pests such as insect pests, octopus insects, lice insects, and the like are lepidopterous insects, semilepidopterous insects, rotifers, centipedes and millipedes. In particular, the present invention is a pest that harms agricultural and horticultural crops and trees in the soil, and a pest that harms agricultural and horticultural crops and tree seeds, such as the above nematodes, isopods, Coleoptera, Lepidoptera pests, It is effective for gastropods, straight-nosed insect pests, and plant parasitic mites. Specific examples of various pests to which the present invention can be applied are shown below.
線虫類としては、ミナミネグサレセンチュウ(Pratylenchus coffeae)、キタネグサレセンチュウ(Pratylenchus fallax)、チャネグサレセンチュウ(Pratylenchus loosi)、クルミネグサレセンチュウ(Pratylenchus vulnus)等のネグサレセンチュウ類;ダイズシストセンチュウ(Heterodera glycines)、ジャガイモシストセンチュウ(Globodera rostochiensis)等のシストセンチュウ類;キタネコブセンチュウ(Meloidogyne hapla)、サツマイモネコブセンチュウ(Meloidogyne incognita)等のネコブセンチュウ類;イネシンガレセンチュウ(Aphelenchoides besseyi)、イチゴセンチュウ(Aphelenchoides fragarieae)等のアフェレンコイデス類;イシュクセンチュウ類;ワセンチュウ類;ピンセンチュウ類;ロンギドルス類;トリコドルス類;イチゴメセンチュウ;マツノザイセンチュウなどが挙げられる。また、等脚類としては、ダンゴムシ、ワラジムシなどが挙げられる。 As nematodes, Negrass nematodes (Pratylenchus coffeae), Nepalese nematodes (Pratylenchus fallax), Chanegesu nematodes (Pratylenchus loosi), Negresa nematodes (Pratylenchus vulnus), etc .; soybean Heterodera glycines, cyst nematodes such as potato cyst nematodes (Globodera rostochiensis); root-knot nematodes such as Meloidogyne hapla and Meloidogyne incognita; Aferenchoides such as: Ishku nematodes; Wasenchus; Pin nematodes; Longidorus; Trichodols; Strawberry mesenchus; It is. In addition, examples of isopods include corundum moths and slats.
鞘翅目害虫としては、ウエスタンコーンルームワーム(Diabrotica virgifera virgifera)、サザンコーンルートワーム(Diabrotica undecimpunctata howardi)等のコーンルートワーム類;ドウガネブイブイ(Anomala cuprea)、ヒメコガネ(Anomala rufocuprea)等のコガネムシ類;メイズウィービル(Sitophiluszeamais)、イネゾウムシ(Echinocnemus squameus)、アリモドキゾウムシ(Cylas formicarius)、イネミズゾウムシ(Lissorhoptrus oryzophilus)、アルファルファタコゾウムシ(Hypera pastica)、アズキゾウムシ(Callosobruchuys chienensis)等のゾウムシ類;オキナワカンシャクシコメツキ(Melanotus okinawensis)、トビイロムナボソコメツキ(Agriotes ogurae fusciollis)、クシコメツキ(Melanotus legatus)等のハリガネムシ類;チャイロコメノゴミムシダマシ(Tenebrio molitor)、コクヌストモドキ(Tribolium castaneum)等のゴミムシダマシ類;ウリハムシ(Aulacophora femoralis)、キスジノミハムシ(Phyllotreta striolata)、コロラドハムシ(Leptinotarsa decemlineata)等のハムシ類;ニジュウヤホシテントウ(Epilachna vigintioctopunctata)等のエピラクナ類;ナガシンクイムシ類;アオバアリガタハネカクシ(Paederus fuscipes)等が挙げられる。 Crustacea pests include corn rootworms such as Western corn room worms (Diabrotica virgifera virgifera) and Southern corn root worms (Diabrotica undecimpunctata howardi); Bill (Sitophiluszeamais), Echinocnemus squameus, Cylas formicarius, Lissorhoptrus oryzophilus, Alfalfa weevil (Hypera pastica), Callosobruchuys chiensis; Callosobruchuys chiensis; okinawensis), Agriotes ogurae fusciollis, bark beetles such as Melanotus legatus; Tenebrio molitor, Tribolium castaneum, etc .; leaf beetles (Aulacophora femoralis), horned beetles (Phyllotreta striolata), potato beetles (Leptinotarsa decemlineata), etc .; (Paederus fuscipes).
鱗翅目害虫としては、ニカメイガ(Chilo suppressalis)、コブノメイガ(Cnaphalocrocis medinalis)、ヨーロピアンコーンボーラー(Ostrinia nubilalis)、シバツトガ(Parapediasia teterrella)、ワタノメイガ(Notarcha derogata)、ノシメマダラメイガ(Plodia interpunctella)等のメイガ類;ハスモンヨトウ(Spodoptera litura)、アワヨトウ(Pseudaletia separata)、ヨトウガ(Mamestra brassicae)、タマナヤガ(Agrotis ipsilon)、トリコプルシア属、ヘリオティス属、ヘリコベルパ属等のヤガ類;モンシロチョウ(Pierisrapae)等のシロチョウ類;アドキソフィエス属、ナシヒメシンクイ(Grapholita molesta)、コドリンガ(Cydia pomonella)等のハマキガ類;モモシンクイガ(Carposina niponensis)等のシンクイガ類;リオネティア属等のハモグリガ類;リマントリア属、ユープロクティス属等のドクガ類;コナガ(Plutellaxylostella)等のスガ類;ワタアカミムシ(Pectinophora gossypiella)等のキバガ類;アメリカシロヒトリ(Hyphantria cunea)等のヒトリガ類、イガ(Tinea translucens)、コイガ(Tineola bisselliella)等のヒロズコガ類等が挙げられる。 The lepidopteran pests include Chilo suppressalis, Cnaphalocrocis medinalis, European corn borer (Ostrinia nubilalis), Parapediasia teterrella, Cotton moth (Notarcha derogata), Pelodia Spodoptera litura, Pseudaletia separata, Mamestra brassicae, Agrotis ipsilon, Trichopulcia, Heliotis, Helicoberpa, etc .; Tortoises such as Grapholita molesta, Cydia pomonella; Sinkigas such as Carposina niponensis; Anemones such as Rionetia; Rimantria, Euproctinis, etc. Sugas such as Puga (Plutellaxylostella); Swabs such as Pectinophora gossypiella; Higgriats such as Hyphantria cunea; Hirosukoga such as Tinea translucens and Tineola bisselliella Can be mentioned.
腹足類としてはマイマイ、ナメクジなどが挙げられる。 Examples of gastropods include maimai and slugs.
直翅目害虫としては、ケラ、バッタ、チャバネゴキブリ(Blattella germanica)、クロゴキブリ(Periplaneta fuliginosa)、ワモンゴキブリ(Periplaneta americana)、トビイロゴキブリ(Periplaneta brunnea)、トウヨウゴキブリ(Blatta orientalis)などが挙げられる。 Examples of the direct insect pest include kerat, grasshopper, German cockroach (Blattella germanica), black cockroach (Periplaneta fuliginosa), American cockroach (Periplaneta americana), black cockroach (Periplaneta brunnea), and British cockroach (Blatta orientalis).
植物寄生性ダニ類としては、ナミハダニ、ニセナミハダニ、ミカンハダニ、ネダニなどが挙げられる。 Examples of plant parasitic mites include nymph mites, moss mites, citrus mites, and mites.
アザミウマ目害虫としては、ミナミキイロアザミウマ(Thrips palmi)、ネギアザミウマ(Thrips tabaci)、ハナアザミウマ(Thrips hawaiiensis)、チャノキイロアザミウマ(Scirtothrips dorsalis)、ヒラズハナアザミウマ(Frankliniella intonsa)、ミカンキイロアザミウマ(Frankliniella occidentalis)、カキクダアザミウマ(Ponticulothrips diospyrosi)等が挙げられる。 The thrips of the order Thrips palmi, Thrips tabaci, Thrips hawaiiensis, Scirtothrips dorsalis, Frank ella An example of this species is Ponticulothrips diospyrosi.
双翅目害虫としては、アカイエカ(Culex pipiens pallens)、コガタアカイエカ(Culex tritaeniorhynchus)等のイエカ類;Aedes aegypti、Aedes albopictus等のエーデス属;Anopheles sinensis等のアノフェレス属;ユスリカ類;イエバエ(Musca domestica)、オオイエバエ(Muscina stabulans)等のイエバエ類;クロバエ類;ニクバエ類;ヒメイエバエ類;タネバエ(Deliaplatura)、タマネギバエ(Delia antiqua)等のハナバエ類;マメハモグリバエ(Liriomyza trifolii)等のハモグリバエ類;ミバエ類;ショウジョウバエ類;チョウバエ類;ブユ類;アブ類;サシバエ類等が挙げられる。 Diptera: Culex pipiens pallens, Culex tritaeniorhynchus, etc .; Aedes genus, such as Aedes aegypti, Aedes albopictus; Anopheles genus, such as Anopheles sinensis; House flies such as Muscina stabulans; black flies; powder fly; Butterfly species; flyfish; abu species;
膜翅目害虫としては、アリ類;アシナガバチ類;スズメバチ類;アリガタバチ類;カブラハバチ(Athalia rosae)等のハバチ類;チュウレンジハバチ(Arge pagana)等のミフシハバチ類等が挙げられる。 Examples of the Hymenoptera pest include ants; wasps; hornets; scallops;
隠翅目害虫としては、ネコノミ(Ctenocephalides felis)、イヌノミ(Ctenocephalides canis)、ヒトノミ(Pulex irritans)等が挙げられる。 Examples of the pests include cat fleas (Ctenocephalides felis), dog fleas (Ctenocephalides canis), human fleas (Pulex irritans) and the like.
シラミ目害虫としては、コロモジラミ(Pediculus humanus corporis)、ケジラミ(Phthirus pubis)、ヒトジラミ等が挙げられる。 Examples of the lice insects include pediculus humanus corporis, white lice (Phthirus pubis), and human lice.
等翅目害虫としては、ヤマトシロアリ、イエシロアリなどが挙げられる。 Examples of isopods include Yamato termites and termites.
半翅目害虫としては、ヒメトビウンカ(Laodelphax striatellus)、トビイロウンカ(Nilaparvata lugens)、セジロウンカ(Sogatella furcifera)等のウンカ類;ツマグロヨコバイ(Nephotettix cincticeps)、タイワンツマグロヨコバイ(Nephotettix virescens)等のヨコバイ類;ワタアブラムシ(Aphis gossypii)、モモアカアブラムシ(Myzus persicae)、ミカンミドリアブラムシ(Aphis citricola)、ニセダイコンアブラムシ(Lipaphis pserudobrassicae)、ナシミドリオオアブラムシ(Nippolachnus piri)、コミカンアブラムシ(Toxoptera aurantii)、ミカンクロアブラムシ(Toxoptera ciidius)等のアブラムシ類;アオクサカメムシ(Nezara antennata)、ホソハリカメムシ(Cletus punctiger)、ホソヘリカメムシ(Riptortus clavetus)、チャバネアオカメムシ(Plautia stali)等のカメムシ類;オンシツコナジラミ(Trialeurodes vaporariorum)、タバココナジラミ(Bemisia tabaci)、シルバーリーフコナジラミ(Bemisia argentifolii)等のコナジラミ類;アカマルカイガラムシ(Aonidiella aurantii)、サンホーゼカイガラムシ(Comstockaspis perniciosa)、シトラススノースケール(Unaspis citri)、クワシロカイガラムシ(Pseudaulacaspis pentagona)、オリーブカタカイガラムシ(Saissetia oleae)、ミカンノカキカイガラムシ(Lepidosaphes beckii)、ルビーロウムシ(Ceroplastes rubens)、イセリヤカイガラムシ(Icerya purchasi)等のカイガラムシ類;グンバイムシ類;キジラミ類等が挙げられる。
Hemiptera pests include Japanese brown planthoppers (Laodelphax striatellus), brown planthoppers (Nilaparvata lugens), white planthoppers (Sogatella furcifera), etc .; Nephotettix cincticeps; gossypii), peach aphid (Myzus persicae), citrus aphid (Aphis citricola), black-headed aphid (Lipaphis pserudobrassicae), nippolachnus piri, citrus aphid (Toxoptera aurantiera), citrus Aphids such as Nezara antennata, Cletus punctiger, Riptortus clavetus, Platya stali, etc .; Whiteflies such as Trialeurodes vaporariorum, Tobacco whitefly (Bemisia tabaci), Silverleaf whitefly (Bemisia argentifolii); Aonidiella aurantii; Pseudaulacaspis pentagona), Saissetia oleae, Lepidosaphes beckii, Ceroplastes rubens, Icerya purchasi, and other insects;
ワラジムシ類としては、ワラジムシ(Porcellio scaber)、ホソワラジムシ(Porcellionides pruinosus)、オカダンゴムシ(Armadillidium vulgare)等が挙げられる。 Examples of the barley beetles include Porcellio scaber, Porcellionides pruinosus, Armadillidium vulgare, and the like.
ムカデ類としては、トビズムカデ(Scolopendra subspinipes mutilans)、アオズムカデ(Scolopendra subspinipes japonica)、アカズムカデ(Scolopendra subspinipes multidens)、ゲジ(Thereuopoda hilgendorfi)等が挙げられる。 Examples of centipedes include Tobism cadets (Scolopendra subspinipes mutilans), Aosude cadets (Scolopendra subspinipes japonica), Akasumi cadets (Scolopendra subspinipes multidens), Geji (Thereuopoda hilgendorfi), and the like.
ヤスデ類としては、ヤケヤスデ(Oxidus gracilis)、オビババヤスデ(Parafontarialaminata laminata)等が挙げられる。 Millipedes include oyster millipede (Oxidus gracilis), obibaya millipede (Parafontarialaminata laminata) and the like.
本発明組成物及び方法は、有害生物防除に関して共力的作用を有する。この共力的作用は、各薬剤の有する各種病害虫防除特性からは予測し得ない相乗効果に基づくものであり、本発明の有用性は、各薬剤を単独で使用するよりも、有害生物防除効果、特に土壌中の有害生物防除力が明らかに増強されるとともに、即効的な効果が付与される点にあるといえる。 The compositions and methods of the present invention have a synergistic effect on pest control. This synergistic action is based on a synergistic effect that cannot be predicted from various pest control properties of each drug, and the usefulness of the present invention is more than the pest control effect than using each drug alone. In particular, it can be said that the pest control power in the soil is clearly enhanced and an immediate effect is imparted.
本発明の望ましい態様を以下に記載するが、本発明はこれらに限定されるものではない。
(1)有機リン系殺線虫剤がS−sec−ブチル O−エチル 2−オキソ−1,3−チアゾリジン−3−イルホスホノチオアートであり、有機リン系殺虫剤がピリダフェンチオンである前記殺虫・殺線虫剤組成物。
(2)O−エチル−S−n−プロピル(2−シアノイミノ−3−エチル−イミダゾリジン−1−イル)ホスホノチオレート及びS,S−ジ−sec−ブチル O─エチル ホスホロジチオアートから成る群から選ばれる少なくとも1種の有機リン系殺線虫剤と、有機リン系殺虫剤とを有効成分として含有する前記殺虫・殺線虫剤組成物。
(3)有機リン系殺虫剤がピリダフェンチオン、イソキサチオン、ダイアジノン、クロルピリホス、フェニトロチオン、シアノホス、プロフェノホス及びアセフェートから成る群から選ばれる少なくとも1種である(2)の殺虫・殺線虫剤組成物。
(4)有機リン系殺虫剤がピリダフェンチオン、イソキサチオン、ダイアジノン及びクロルピリホスから成る群から選ばれる少なくとも1種である(2)の殺虫・殺線虫剤組成物。
(5)S−sec−ブチル O−エチル 2−オキソ−1,3−チアゾリジン−3−イルホスホノチオアート、O−エチル−S−n−プロピル(2−シアノイミノ−3−エチル−イミダゾリジン−1−イル)ホスホノチオレート及びS,S−ジ−sec−ブチル O─エチル ホスホロジチオアートから成る群から選ばれる少なくとも1種の有機リン系殺線虫剤と、有機リン系殺虫剤とを害虫又は害虫の生息場所に処理することを特徴とする害虫の防除方法。
(6)有機リン系殺線虫剤がS−sec−ブチル O−エチル 2−オキソ−1,3−チアゾリジン−3−イルホスホノチオアートであり、有機リン系殺虫剤がピリダフェンチオンである(5)に記載の方法。
(7)有機リン系殺線虫剤がO−エチル−S−n−プロピル(2−シアノイミノ−3−エチル−イミダゾリジン−1−イル)ホスホノチオレート及びS,S−ジ−sec−ブチル O─エチル ホスホロジチオアートから成る群から選ばれる少なくとも1種であり、有機リン系殺虫剤がピリダフェンチオン、イソキサチオン、ダイアジノン及びクロルピリホスから成る群から選ばれる少なくとも1種である(5)に記載の方法。
Desirable embodiments of the present invention will be described below, but the present invention is not limited thereto.
(1) The above insecticide, wherein the organophosphorus nematicide is S-sec-butyl O-ethyl 2-oxo-1,3-thiazolidin-3-ylphosphonothioate, and the organophosphorus insecticide is pyridafenthion. Nematicide composition.
(2) Consists of O-ethyl-Sn-propyl (2-cyanoimino-3-ethyl-imidazolidin-1-yl) phosphonothiolate and S, S-di-sec-butyl O-ethyl phosphorodithioate The insecticidal / nematicidal composition comprising at least one organophosphorus nematicide selected from the group and an organophosphorus insecticide as active ingredients.
(3) The insecticidal / nematicidal composition according to (2), wherein the organophosphorus insecticide is at least one selected from the group consisting of pyridafenthion, isoxathione, diazinon, chlorpyrifos, fenitrothion, cyanophos, propenofos and acephate.
(4) The insecticidal / nematicidal composition according to (2), wherein the organophosphorus insecticide is at least one selected from the group consisting of pyridafenthion, isoxathione, diazinon and chlorpyrifos.
(5) S-sec-butyl O-ethyl 2-oxo-1,3-thiazolidin-3-ylphosphonothioate, O-ethyl-Sn-propyl (2-cyanoimino-3-ethyl-imidazolidine-1 -Yl) phosphonothiolate and S, S-di-sec-butyl O-ethyl phosphorodithioate selected from the group consisting of at least one organophosphorus nematicide and an organophosphorus insecticide Alternatively, a method for controlling pests characterized by treating the pests in a habitat.
(6) The organophosphorus nematicide is S-sec-butyl O-ethyl 2-oxo-1,3-thiazolidin-3-ylphosphonothioate, and the organophosphorus insecticide is pyridafenthione (5) The method described in 1.
(7) Organophosphorus nematicides are O-ethyl-Sn-propyl (2-cyanoimino-3-ethyl-imidazolidin-1-yl) phosphonothiolate and S, S-di-sec-butyl O -The method according to (5), wherein the organophosphorus insecticide is at least one selected from the group consisting of pyridafenthion, isoxathione, diazinon and chlorpyrifos, wherein the organophosphorus insecticide is at least one selected from the group consisting of ethyl phosphorodithioate.
次に本発明の実施例を記載する。 Next, examples of the present invention will be described.
試験例1
オニオンパウダーに水を1:10の割合で加えて十分に攪拌する。8cmろ紙をパウダー懸濁液に浸して風乾燥後、8cmシャーレに3枚重ねて詰め、所定濃度の有機リン系殺線虫剤及び/又は有機リン系殺虫剤の薬液2mlを加える。シャーレ当りネダニ雌成虫を50頭接種して蓋をし、25℃恒温室で静置する。48〜72時間後に実体顕微鏡下で観察し、生死判定を行って死虫率を求める。
死虫率(%)={1-(生存頭数/放虫頭数)}×100
また、コルビーの式により死虫率の理論値(%)を計算できる。死虫率の実験値(%)が理論値(%)よりも高い場合に、本発明の組成物は、ネダニの防除に関し相乗効果を有する。
有機リン系殺線虫剤:有機リン系殺虫剤=10:1〜1:50の範囲内で、死虫率の実験値が理論値よりも高い値を示す。
Test example 1
Add water to the onion powder at a ratio of 1:10 and stir well. 8cm filter paper is dipped in a powder suspension, air-dried, packed in 3 pieces on an 8cm petri dish, and 2ml of a predetermined concentration of organophosphorus nematicide and / or organophosphorus insecticide is added. Inoculate 50 female mite mites per petri dish, cover and place in a constant temperature room at 25 ° C. Observe under a stereomicroscope 48 to 72 hours later, make a life / death determination and determine the death rate.
Mortality (%) = {1- (number of surviving animals / number of insects)} × 100
Also, the theoretical value (%) of the death rate can be calculated by the Colby equation. When the experimental value (%) of mortality is higher than the theoretical value (%), the composition of the present invention has a synergistic effect on the control of mites.
The organophosphorus nematicide: organophosphorus pesticide = within the range of 10: 1 to 1:50, the experimental value of mortality is higher than the theoretical value.
試験例2
壌土3:砂1:腐食土1を混合した試験土壌を作成し、300mlプラスチック製容器に土壌を200gずつ入れ、有機リン系殺線虫剤及び/又は有機リン系殺虫剤を所定濃度で添加混合する。コガネムシ孵化直後幼虫を10頭ずつ放し、暗黒下25℃恒温室にて5〜10日静置した後、土壌を解体し生存する幼虫数を計数し死虫率を求める。
死虫率(%)={1-(生存頭数/放虫頭数)}×100
また、コルビーの式により死虫率の理論値(%)を計算できる。死虫率(%)が理論値(%)よりも高い場合に、本発明の組成物は、コガネムシの防除に関し相乗効果を有する。
有機リン系殺線虫剤:有機リン系殺虫剤=10:1〜1:50の範囲内で、死虫率の実験値が理論値よりも高い値を示す。
Test example 2
Create test soil mixed with loam soil 3: sand 1: corrosive soil 1, put 200g of soil into a 300ml plastic container, add organophosphorus nematicide and / or organophosphorus pesticide at a predetermined concentration and mix To do. 10 larvae immediately after hatching of the beetle are released and allowed to stand in the dark at 25 ° C in a constant temperature room for 5 to 10 days. Then, the soil is demolished and the number of surviving larvae is counted to determine the mortality rate.
Mortality (%) = {1- (number of surviving animals / number of insects)} × 100
Also, the theoretical value (%) of the death rate can be calculated by the Colby equation. When the death rate (%) is higher than the theoretical value (%), the composition of the present invention has a synergistic effect on the control of scarab beetles.
The organophosphorus nematicide: organophosphorus pesticide = within the range of 10: 1 to 1:50, the experimental value of mortality is higher than the theoretical value.
試験例3
水田土4:砂1を混合した砂壌土3リットルを1/5000aポットに入れ、有機リン系殺線虫剤及び/又は有機リン系殺虫剤を所定濃度で添加混合した。薬剤添加直後に、線虫(サツマイモネコブセンチュウ(Meloidogyne incognita))汚染土壌500ccを各々のポットに接種し、充分混和後トマト(品種:強力米寿)苗を移植した。移植44日後に線虫のネコブ着生程度(0〜100%着生)を調査した。結果を第1表に示す。また、コルビーの式によりネコブ着生程度の理論値(%)を計算した。ネコブ着生程度(%)が理論値(%)よりも低い場合に、本発明の組成物は、線虫の防除に関し相乗効果を有する。こういった場合における理論値(%)を第1表の( )内に併せて示した。試験は2連制で行った。
Test example 3
Paddy soil 4: 3 liters of sand loam mixed with sand 1 was placed in a 1 / 5000a pot, and an organophosphorus nematicide and / or organophosphorus insecticide was added and mixed at a predetermined concentration. Immediately after the addition of the drug, 500 cc of nematode (Meloidogyne incognita) -contaminated soil was inoculated into each pot, and after mixing well, a tomato (cultivar: strong rice life) seedling was transplanted. 44 days after transplantation, the degree of nematode formation (0-100%) of nematodes was investigated. The results are shown in Table 1. Further, the theoretical value (%) of the degree of cat root formation was calculated by the Colby equation. The composition of the present invention has a synergistic effect on the control of nematodes when the degree of root formation (%) is lower than the theoretical value (%). The theoretical values (%) in these cases are also shown in parentheses in Table 1. The test was conducted in two consecutive systems.
試験例4
移植49日後に線虫のネコブ着生程度を調査したことと、試験を3連制で行ったこと以外は、試験例3と同様にして、試験を行った。結果を第2表に示す。
Test example 4
The test was conducted in the same manner as in Test Example 3 except that the degree of nematode formation on the nematode was investigated 49 days after the transplantation, and that the test was conducted in triplicate. The results are shown in Table 2.
試験例5
水田土4:砂1を混合した砂壌土3リットルを1/5000aポットに入れ、有機リン系殺線虫剤及び/又は有機リン系殺虫剤を所定濃度で添加混合した。薬剤添加直後に、線虫(キタネグサレセンチュウ(Pratylenchus fallax)汚染土壌500ccを各々のポットに接種し、充分混和後ゴボウ(品種:滝野川牛蒡)苗を移植した。移植49日後又は55日後に線虫のネグサレ被害程度(0〜100%被害)を調査した。結果を第3表及び第4表に示す。また、コルビーの式によりネグサレ指数程度の理論値(%)を計算した。ネグサレ被害程度(%)が理論値(%)よりも低い場合に、本発明の組成物は、線虫の防除に関し相乗効果を有する。こういった場合における理論値(%)を第3表及び第4表の( )内に併せて示した。
Test Example 5
Paddy soil 4: 3 liters of sand loam mixed with sand 1 was placed in a 1 / 5000a pot, and an organophosphorus nematicide and / or organophosphorus insecticide was added and mixed at a predetermined concentration. Immediately after the addition of the drug, 500cc of nematode (Pratylenchus fallax) contaminated soil was inoculated into each pot, and after mixing well, transplanted burdock (variety: Takinogawa Gyudon) seedling. The degree of damage (0 to 100% damage) was investigated, and the results are shown in Tables 3 and 4. The theoretical value (%) of the negre index was calculated using the Colby equation. %) Is lower than the theoretical value (%), the composition of the present invention has a synergistic effect on the control of nematodes.The theoretical value (%) in these cases is shown in Tables 3 and 4. Also shown in parentheses.
試験例6
蒸留水にて所定濃度に希釈した薬液中にサツマイモネコブセンチュウ2期幼虫40〜50頭を浸漬処理して25℃の恒温室に48時間保った。顕微鏡下にて薬液中のサツマイモネコブセンチュウ総個体数(A)、及び薬液中で15秒間動かなかった個体数(B)を調査した。また、薬液に代えて蒸留水を用いた対照区についても、総個体数(A')、及び15秒間動かなかった個体数(B')を調査した。これらの値から、以下の式により運動阻害率を求めた。結果を第5表〜第7表に示す。
運動阻害率(%)=[1−{(1−B/A)/(1−B'/A')}]×100
また、コルビーの式により運動阻害率の理論値(%)を計算した。運動阻害率(%)が理論値(%)よりも高い場合に、本発明の組成物は、線虫の防除に関し相乗効果を有する。こういった場合における理論値(%)を第5表〜第7表の( )内に併せて示した。
Test Example 6
Forty-eight sweet potato root nematode second stage larvae were immersed in a chemical solution diluted to a predetermined concentration with distilled water and kept in a thermostatic chamber at 25 ° C. for 48 hours. Under the microscope, the total number of sweet potato root nematodes in the drug solution (A) and the number of individuals that did not move in the drug solution for 15 seconds (B) were examined. In addition, the total number of individuals (A ′) and the number of individuals that did not move for 15 seconds (B ′) were also investigated in the control group using distilled water instead of the chemical solution. From these values, the motor inhibition rate was determined by the following equation. The results are shown in Tables 5-7.
Movement inhibition rate (%) = [1-{(1-B / A) / (1-B ′ / A ′)}] × 100
In addition, the theoretical value (%) of the movement inhibition rate was calculated by the Colby equation. When the movement inhibition rate (%) is higher than the theoretical value (%), the composition of the present invention has a synergistic effect on nematode control. The theoretical values (%) in these cases are also shown in parentheses in Tables 5-7.
製剤例1
(1)ホスチアゼート原体 1.7重量部
(2)クロルピリホス原体 1.2重量部
(3)ニューカルゲンEX-70(ジオクチルスルホサクシネート;竹本油脂(株)製)
1.0重量部
(3)シルバーW(微粉炭酸カルシウム;白石カルシウム(株)製) 10.0重量部
(4)炭酸カルシウム 86.1重量部
上記(1)〜(4)の混合物に、1%セロゲン703A(カルボキシメチルセルロースソーダ塩;第一工業製薬(株)製)水溶液を加えて混練した後、0.8mmφのスクリーンを装着したドーム型造粒機(DG-L1;不二パウダル(株)製)で押出し造粒し、70℃の気流化で乾燥した後、0.3mm〜1.00mmの大きさに整粒し、粒剤とする。
Formulation Example 1
(1) Phosthiazet active substance 1.7 parts by weight (2) Chlorpyrifos active substance 1.2 parts by weight (3) Newkalgen EX-70 (Dioctylsulfosuccinate; Takemoto Yushi Co., Ltd.)
1.0 parts by weight (3) Silver W (fine powdered calcium carbonate; manufactured by Shiraishi Calcium Co., Ltd.) 10.0 parts by weight (4) 86.1 parts by weight of calcium carbonate To the mixture of (1) to (4) above, 1% serogen 703A (carboxymethylcellulose) Soda salt (Daiichi Kogyo Seiyaku Co., Ltd.)) Aqueous solution was added and kneaded, then extruded and granulated with a dome type granulator equipped with a 0.8mmφ screen (DG-L1; manufactured by Fuji Powder Co., Ltd.). After drying with air flow at 70 ° C., the particles are sized to a size of 0.3 mm to 1.00 mm to obtain granules.
製剤例2
(1)ホスチアゼート原体 11重量部
(2)クロルピリホス原体 22重量部
(3)ソルポール4296A
(ノニオン系およびアニオン系配合界面活性剤;東邦化学(株)製) 12重量部
(4)ソルベッソ150(芳香族系溶媒;エクソンモービル社製) 55重量部
上記(1)〜(4)を混合、溶解し、乳剤とする。
Formulation Example 2
(1) 11 parts by weight of phostiazate base (2) 22 parts by weight of chlorpyrifos base (3) Solpol 4296A
(Nonionic and anionic compound surfactant: manufactured by Toho Chemical Co., Ltd.) 12 parts by weight (4) Solvesso 150 (aromatic solvent; manufactured by ExxonMobil) 55 parts by weight The above (1) to (4) are mixed Dissolve to make an emulsion.
製剤例3
ホスチアゼート原体50重量部とダイアジノン原体50重量部の混合液3.4重量部を、16〜50メッシュの珪石粒(東海工業(株)製)96.6重量部に吸油、混合し、粒剤とする。
Formulation Example 3
3.4 parts by weight of a mixed solution of 50 parts by weight of a phostiazate base and 50 parts by weight of a diazinon base is oil-absorbed and mixed with 96.6 parts by weight of 16-50 mesh silica stone (manufactured by Tokai Kogyo Co., Ltd.) to obtain a granule.
製剤例4
(1)ホスチアゼート原体 16重量部
(2)ダイアジノン原体 27重量部
(3)ソルポールT-15(ノニオン系界面活性剤;東邦化学(株)製) 12重量部
(4)Rhodacal 70(アニオン系界面活性剤;ローディア日華(株)製) 2重量部
(5)ソルベッソ150 43重量部
上記(1)〜(5)を混合、溶解し、乳剤とする。
Formulation Example 4
(1) Phosthiazate base 16 parts by weight (2) Diazinon base 27 parts by weight (3) Solpol T-15 (nonionic surfactant; manufactured by Toho Chemical Co., Ltd.) 12 parts by weight (4) Rhodacal 70 (anionic) Surfactant; Rhodia Nikka Co., Ltd.) 2 parts by weight (5) Solvesso 150 43 parts by weight The above (1) to (5) are mixed and dissolved to obtain an emulsion.
製剤例5
ホスチアゼート原体60重量部とイソキサチオン原体40重量部の混合液2.9重量部を、180〜710μmの粒度の珪石粒(東海工業(株)製)97.1重量部に吸油、混合し、微粒剤Fとする。
Formulation Example 5
2.9 parts by weight of a mixture of 60 parts by weight of phosthiazate base and 40 parts by weight of isoxathion base is oil-absorbed and mixed with 97.1 parts by weight of silica stone particles (manufactured by Tokai Kogyo Co., Ltd.) with a particle size of 180-710 μm. To do.
製剤例6
(1)カズサホス原体 3.5重量部
(2)クロルピリホス原体 1.2重量部
(3)トプコパーライト#54(東興パーライト工業(株)製) 7重量部
(4)ベントナイト 10重量部
(5)クレー 78.3重量部
上記(1)〜(5)の混合物に、20%に稀釈したサンエキスC(リグニンスルホネート;日本国策パルプ(株)製)水溶液を加えて混練し、0.8mmφのスクリーンを装着したドーム型造粒機(DG-L1)で押出し造粒し、更に70℃の気流化で乾燥した後、0.3mm〜1.00mmの大きさに整粒し、粒剤とする。
Formulation Example 6
(1) Kazusafos bulk 3.5 parts (2) Chlorpyrifos bulk 1.2 parts (3) Topcoperlite # 54 (manufactured by Toko Perlite Industry) 7 parts (4) Bentonite 10 parts (5) Clay 78.3 parts Part To the mixture of (1) to (5) above, an aqueous solution of sun extract C (lignin sulfonate; manufactured by Nippon Kokusaku Pulp Co., Ltd.) diluted to 20% is added and kneaded, and a dome-shaped structure equipped with a 0.8 mmφ screen. Extruded and granulated with a granulator (DG-L1), further dried by air flow at 70 ° C, and then sized to a size of 0.3 mm to 1.00 mm to obtain granules.
製剤例7
カズサホス原体75重量部とイソキサチオン原体25重量部の混合液4.7重量部を、軽石(石川ライトNo.3;石川ライト工業(株))95.3重量部に吸油、混合し、カズサホスとイソキサチオンを含む粒剤とする。
Formulation Example 7
A mixture of 75 parts by weight of kazusafos and 25 parts by weight of isoxathione is absorbed and mixed in 95.3 parts by weight of pumice (Ishikawa Light No.3; Ishikawa Light Industry Co., Ltd.), and contains kazusafos and isoxathione. Use granules.
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