CN103734181B - A kind of Fungicidal insecticidal composition containing cyflufenamid - Google Patents
A kind of Fungicidal insecticidal composition containing cyflufenamid Download PDFInfo
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- CN103734181B CN103734181B CN201310746428.6A CN201310746428A CN103734181B CN 103734181 B CN103734181 B CN 103734181B CN 201310746428 A CN201310746428 A CN 201310746428A CN 103734181 B CN103734181 B CN 103734181B
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- cyflufenamid
- insecticidal composition
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- 239000000203 mixture Substances 0.000 title claims abstract description 40
- 239000005755 Cyflufenamid Substances 0.000 title claims abstract description 35
- ACMXQHFNODYQAT-UHFFFAOYSA-N cyflufenamid Chemical compound FC1=CC=C(C(F)(F)F)C(C(NOCC2CC2)=NC(=O)CC=2C=CC=CC=2)=C1F ACMXQHFNODYQAT-UHFFFAOYSA-N 0.000 title claims abstract description 35
- 230000000749 insecticidal effect Effects 0.000 title claims abstract description 17
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Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a kind of Fungicidal insecticidal composition containing cyflufenamid, its active ingredient is Imicyafos and cyflufenamid two yuan of mixtures, and the ratio of weight and number of two kinds of active ingredients is 1 ~ 50: 1 ~ 50, and preferred weight portion rate is 3 ~ 25: 5 ~ 25; The parts by weight content that in insecticidal and bactericidal composition, active ingredient is total is 1% ~ 80%, preferred weight number content is 5% ~ 35%, all the other are allow in agricultural chemicals to use and acceptable auxiliary element, wetting powder, suspending agent, microemulsion, aqueous emulsion and water dispersible granules can be prepared into by known method, Fungicidal insecticidal composition of the present invention be mainly used in preventing and treating grain, cotton, oil, really, vegetables, flowers the damage by disease and insect of crop.
Description
Technical field
The present invention relates to technical field of pesticide combination, being specifically related to a kind of is the composite insecticidal and bactericidal composition of active ingredient two yuan containing agricultural chemicals Imicyafos and cyflufenamid.
Background technology
Imicyafos (AKD-3088) is a kind of cyanamide heterocyclic organic matter, it is combined by the sub-imidazolidine of cyano group of asymmetric organic phosphor and nicotinic insecticide, can be used for the crops such as radish, carrot, strawberry, eggplant, tomato, cucumber, muskmelon, watermelon, sweet potato and potato, its chemical structural formula is:
Cyflufenamid is the bactericide with novel precursor structure of Japanese Cao Da company exploitation, and its chemical structural formula is as follows:
It has excellent effect and characteristic to the powdery mildew of various vegetables and wheat class, peach grey scab bacterium, has same isoreactivity to benzimidazole, imidazoles, methoxy acrylate class resistance bacterium and sensitive bacteria simultaneously.Cyflufenamid is extremely low to the toxicity of people and animals, does not exist follow-on impact, teratogenesis, and mutagenicity test is all negative, also not to stimulation and the allergy of eye, skin in production.In addition, this agent also can not affect environment and beneficial organism, affects also minimum on honeybee and silkworm.
The insecticide that Long-Time Service is single or bactericide, insect or germ are easy to develop immunity to drugs, and pesticide dosage is increased, and cause the adverse consequencess such as high poison, consumption are large, residual many, drug effect is poor, and effect field are more single.The different mechanism of action and without the insecticide of cross resistance and bactericide rational mixture by a certain percentage, crop disease prevention effect can be improved, reduce dosage, residual few, reduce environmental pollution, effectively the pesticide resistance of reduction crop.
Summary of the invention
According to the deficiencies in the prior art; the present invention proposes a kind of Fungicidal insecticidal composition containing cyflufenamid, said composition contains A, B two kinds of effective active components, and component A selects novel pesticide Imicyafos; B is selected from cyflufenamid; it is wide that the present composition has effect field, can desinsection again can sterilization, and consumption is few; preventive effect is high; residual few, the lasting period is long, is conducive to environmental protection.
The present invention be a kind of with novel pesticide Imicyafos and cyflufenamid for active ingredient carries out the insecticidal and bactericidal composition preparation of two yuan of mixtures, wherein in insecticidal and bactericidal composition of the present invention, the ratio of weight and number of active ingredient novel pesticide Imicyafos and cyflufenamid is 1 ~ 50: 50 ~ 1, on the basis of test recipe screening targetedly, the ratio of weight and number of active ingredient novel pesticide Imicyafos and cyflufenamid can be preferably 3 ~ 25: 25 ~ 5.
The formulations of pesticide that the preparation method of agricultural insecticide bactericidal composition field of pesticide preparation of the present invention can be prepared into are wetting powder, suspending agent, microemulsion, aqueous emulsion and water dispersible granules, in preparation, active ingredient gross weight accounts for the portion rate of gross weight in preparation is 1% ~ 80%, on the basis of test recipe screening targetedly, in preparation, active ingredient gross weight accounts for the portion rate of gross weight in preparation is 3% ~ 35%, and all the other are usual auxiliaries in agricultural chemicals.
When above-described Pesticidal combination is microemulsion, in preparation, the ratio of weight and number of each component is:
The concrete production stage of this microemulsion is: former medicine imicyafos, cyflufenamid cosolvent are dissolved completely, then adds other compositions such as emulsifier, antifreezing agent stabilizing agent, and Homogeneous phase mixing, finally adds water, can be made into microemulsion after fully stirring.
When above-described Pesticidal combination is wetting powder, in preparation, the ratio of weight and number of each component is:
The concrete procedure of processing of this Pesticidal combination wetting powder is: by above-mentioned formula by active principle A and active principle B and the mixing of dispersant, wetting agent and filler, uniform stirring in stirred tank, mixing after airslide disintegrating mill, namely can be made into the wetting powder of the present composition.
When above-described Pesticidal combination is suspending agent, in preparation, the ratio of weight and number of each component is:
The concrete production stage of this suspending agent is for first to mix other auxiliary agents, mix through high speed shear, add active principle A and active principle B, abrading-ball 2 ~ 3 hours in ball crusher, make a diameter all at below 5mm, the aqueous suspension formulations of obtained Pesticidal combination of the present invention.
When above-described Pesticidal combination is aqueous emulsion, in preparation, the ratio of weight and number of each component is:
The concrete production stage of this aqueous emulsion is: first former medicine active principle A and active principle B, solvent and emulsifier, cosolvent are added together, and makes to be dissolved into uniform oil phase; By part water, antifreeze, other the insecticides adjuvant such as antimicrobial mixes uniformly aqueous phase; While high-speed stirred, oil phase is added aqueous phase in a kettle., slowly add water until reach phase inversion point, open clipper and carry out high speed shear, and add remaining water, shear about half an hour, form the aqueous emulsion of oil-in-water type.The i.e. aqueous emulsion of obtained Pesticidal combination of the present invention.
When above-described Pesticidal combination is water dispersible granules, in preparation, the ratio of weight and number of each component is:
The concrete procedure of processing of this Pesticidal combination water dispersible granules is: active principle A, active principle B and dispersant, wetting agent, disintegrant and filler are mixed by above-mentioned formula, pulverize with micro jet, through mediating, then add in fluidized-bed granulation dryer and carry out through sample analysis after granulation, drying, screening, be i.e. the water dispersible granules of obtained Pesticidal combination of the present invention.
Described emulsifier is selected from least one in calcium dodecyl benzene sulfonate and aliphatic acid polyethenoxy ether, alkylphenol polyoxyethylene sulfosuccinate, styrylphenol polyoxyethylene ether, polyoxyethylene nonylphenol ether, castor oil polyoxyethylene ether, aliphatic acid polyethenoxy base ester, polyoxyethylene aliphatic alcohol ether.
Described solvent is at least one in dimethylbenzene or biodiesel, toluene, diesel oil, methyl alcohol, ethanol, n-butanol, isopropyl alcohol, turpentine oil, solvent naphtha, dimethyl formamide, dimethyl sulfoxide (DMSO), water equal solvent.
Described dispersant is selected from least one in polycarboxylate, lignosulfonates, alkylphenol polyoxyethylene formaldehyde condensation products sulphate, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol polyoxyethylene, aliphatic amine polyoxyethylene ether, polyoxyethylene carboxylate, fatty acid glyceride APEO.
Described wetting agent is selected from lauryl sodium sulfate, calcium dodecyl benzene sulfonate, at least one pulled open in powder copper rosinate X., wetting and penetrating agent F, alkylnaphthalene sulfonate, polyoxyethylene tri-styryl phosphenylic acid salt, spaonin powder, silkworm excrement, soapberry powder.
Described disintegrant is selected from least one in bentonite, urea, ammonium sulfate, aluminium chloride, citric acid, succinic acid, sodium bicarbonate.
Described thickener is selected from least one in xanthans, CMC, hydroxyethylcellulose, methylcellulose, Magnesiumaluminumsilicate, polyvinyl alcohol.
Described stabilizing agent is selected from least one in sodium citrate, resorcinol.
Described antifreezing agent is selected from least one in ethylene glycol, propane diols, glycerine.
Described defoamer is selected from silicone oil, silicone compound, C
10-20saturated fat acid compounds, C
8-10at least one in aliphatic alcohols compound.
Described filler is selected from least one in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, precipitated calcium carbonate.
Agricultural insecticide bactericidal composition of the present invention to grain, cotton, oil, really, vegetables, flowers multiple fungal disease all there is favorable effect, especially the powdery mildew on the cereal such as wheat, fruit and vegetables, downy mildew, rust, tikka class disease, scab, rot etc. are caused by germ, had the control of the disease of certain resistance to have excellent preventive effect to ergosterol class synthetic inhibitor class agricultural chemicals.Pesticidal combination of the present invention can prevent and treat nematoda, etc. the various insects such as sufficient class, coleoptera class pest, Lepidoptera class pest, gastropod, orthoptera pest, plant parasitic acarid class, Thysanoptera, Diptera pest, Hymenoptera insect, hidden wing order insect, Anoplura insect, Isoptera insect, Hemipteran pest, damp insects, centipede insects, thousand-legger class.Especially to destroying the insect of agriculture horticultural crop and trees etc. in soil, destroying the insect of the seed of agriculture horticultural crop and trees, such as nematoda, etc. sufficient class, coleoptera class pest, Lepidoptera class pest, gastropod, orthoptera pest, plant parasitic acarid class, Hemipteran pest preventive effect remarkable.
The above nematode pests comprises the pratylenchus classes such as pratylenchus, pseudo-Pratylenchidae, Lu Si Pratylenchidae, disability Pratylenchidae, the Cyst nematode such as soybean cyst nematode Heterodera glycines, globodera rostochiensis class, the root-knot nematode such as peanut root-knot nematode, Meloidogyne incognita class, the Aphelenchoidea classes such as aphelenchoides besseyi, leaf bud nematode, species of Tylenchorhynchus Nematodes class, loop wire insects, needlework insects, long capsule nematoda, burr nematoda, nematode on strawberry, pine wood nematode.All favorable effect is had in addition to insects such as aphid, leafhopper, plant hopper, chrysomelid, wireworm, cutworm, diamond-back moth, imported cabbageworm, rice thripses.
In addition, insecticidal and bactericidal composition of the present invention compares similar medicament also other obvious advantages a lot, the first, compare single dose sphere of action wider, can desinsection again can diseases prevention; The second, greatly delay the drug-fast generation of crop, decreased agricultural chemicals Reusability number of times, reduce Pesticide use amount, reduce agricultural cost; 3rd, the residual quantity of this insecticidal and bactericidal composition is lower, more friendly to environment; There is general fresh-keeping production-increasing function to crops in the application of last this insecticidal and bactericidal composition, the increasing both production and income of agricultural region is significant.
Embodiment:
In order to make object of the present invention, technical scheme and advantage clearly understand, the following specific embodiment of the present invention is described, but the present invention is only limitted to absolutely not these examples.The method that the present invention adopts indoor bioassay and field trial to combine, if no special instructions, the ratio (comprising percentage) below mentioned is all ratio of weight and number.
Embodiment 1: by imicyafos15 part, cyflufenamid 15 parts, lignosulfonates 10 parts, lauryl sodium sulfate 12 parts and the mixing of 48 parts, diatomite, uniform stirring in stirred tank, mixing after airslide disintegrating mill, i.e. the wetting powder of obtained Pesticidal combination of the present invention.
Embodiment 2: by imicyafos8 part, cyflufenamid 22 parts, alkylphenol polyoxyethylene 12 parts, oxygen ethene triphenylethylene phosphenylic acid salt 13 parts and bentonite 35 parts mixing, uniform stirring in stirred tank, mixing after airslide disintegrating mill, i.e. the wetting powder of obtained Pesticidal combination of the present invention.
Embodiment 3: by imicyafos20 part, cyflufenamid 10 parts, dispersant 12 parts, wetting agent 12 parts and filler 46 parts mixing, uniform stirring in stirred tank, is mixing after airslide disintegrating mill, the i.e. wetting powder of obtained Pesticidal combination of the present invention.
Embodiment 4: by alkylphenol polyoxyethylene 8 parts, glycerine 2 parts, CMC 3 parts, silicone oil 2 parts, the mixing of 55 parts, water, mix through high speed shear, add imicyafos18 part, cyflufenamid 12 parts successively, abrading-ball 2 ~ 3 hours in ball crusher, make a diameter all at below 5mm, the aqueous suspension formulations of obtained Pesticidal combination of the present invention.
Embodiment 5: by dispersant 12 parts, antifreezing agent 2 parts, thickener 4 parts, defoamer 1 part, the mixing of 46 parts, water, mix through high speed shear, add imicyafos25 part, cyflufenamid 10 parts successively, abrading-ball 2 ~ 3 hours in ball crusher, make a diameter all at below 5mm, the aqueous suspension formulations of obtained Pesticidal combination of the present invention.
Embodiment 6: by dispersant 10 parts, antifreezing agent 2 parts, thickener 4 parts, defoamer 1 part, the mixing of 53 parts, water, mix through high speed shear, add imicyafos15 part, cyflufenamid 15 parts successively, abrading-ball 2 ~ 3 hours in ball crusher, make a diameter all at below 5mm, the aqueous suspension formulations of obtained Pesticidal combination of the present invention.
Embodiment 7: imicyafos5 part, cyflufenamid 25 parts, 12 parts, turpentine oil, castor oil polyoxyethylene ether 5 parts, resorcinol 6 parts are mixed, is dissolved into uniform oil phase; Part water, propane diols 2 parts, silicone compound 1 part are mixed uniformly aqueous phase; While high-speed stirred, oil phase is added aqueous phase in a kettle., add polyvinyl alcohol 4 parts, slowly add water until reach phase inversion point, open clipper and carry out high speed shear, and add remaining water and supply 100 parts, shear about half an hour, form the aqueous emulsion of oil-in-water type.The i.e. aqueous emulsion of obtained Pesticidal combination of the present invention.
Embodiment 8: imicyafos30 part, cyflufenamid 5 parts, solvent 22 parts, emulsifier 8 parts, stabilizing agent 12 parts are mixed, is dissolved into uniform oil phase; Part water, antifreezing agent 1 part, defoamer 2 parts are mixed uniformly aqueous phase; While high-speed stirred, oil phase is added aqueous phase in a kettle., add thickener 3 parts, slowly add water until reach phase inversion point, open clipper and carry out high speed shear, and add remaining water and supply 100 parts, shear about half an hour, form the aqueous emulsion of oil-in-water type.The i.e. aqueous emulsion of obtained Pesticidal combination of the present invention.
Embodiment 9: imicyafos16 part, cyflufenamid 10 parts, solvent 18 parts, emulsifier 10 parts, stabilizing agent 8 parts are mixed, is dissolved into uniform oil phase; Part water, antifreezing agent 1 part, defoamer 2 parts are mixed uniformly aqueous phase; While high-speed stirred, oil phase is added aqueous phase in a kettle., add thickener 3 parts, slowly add water until reach phase inversion point, open clipper and carry out high speed shear, and add remaining water and supply 100 parts, shear about half an hour, form the aqueous emulsion of oil-in-water type.The i.e. aqueous emulsion of obtained Pesticidal combination of the present invention.
Embodiment 10: imicyafos20 part, cyflufenamid 8 parts, aliphatic amine polyoxyethylene ether 8 parts, alkylnaphthalene sulfonate 10 parts, 5 parts, aluminium chloride and bentonite 49 parts are mixed, pulverize with micro jet, through mediating, then add in fluidized-bed granulation dryer and carry out through sample analysis after granulation, drying, screening, be i.e. the water dispersible granules of obtained Pesticidal combination of the present invention.
Embodiment 11: imicyafos10 part, cyflufenamid 15 parts, dispersant 10 parts, wetting agent 12 parts, disintegrant 5 parts and filler 51 parts are mixed, pulverize with micro jet, through mediating, then add in fluidized-bed granulation dryer and carry out through sample analysis after granulation, drying, screening, be i.e. the water dispersible granules of obtained Pesticidal combination of the present invention.
Embodiment 12: imicyafos18 part, cyflufenamid 12 parts, dispersant 10 parts, wetting agent 12 parts, disintegrant 3 parts and filler 45 parts are mixed, pulverize with micro jet, through mediating, then add in fluidized-bed granulation dryer and carry out through sample analysis after granulation, drying, screening, be i.e. the water dispersible granules of obtained Pesticidal combination of the present invention.
Embodiment 13: former medicine imicyafos15 part, cyflufenamid 20 parts are dissolved completely with cosolvent, add other compositions such as aliphatic acid polyethenoxy base ester 13 parts, ethylene glycol 2 parts, sodium citrate 4 parts, resorcinol 4 parts again, Homogeneous phase mixing, finally add water, after fully stirring, can microemulsion be made into.
Embodiment 14: former medicine imicyafos10 part, cyflufenamid 20 parts are dissolved completely with cosolvent, then add other compositions such as emulsifier 11 parts, antifreezing agent 2 parts, stabilizing agent 7 parts, Homogeneous phase mixing, finally adds water, can be made into microemulsion after fully stirring.
Embodiment 15: former medicine imicyafos8 part, cyflufenamid 25 parts are dissolved completely with cosolvent, then add other compositions such as emulsifier 9 parts, antifreezing agent 2 parts, stabilizing agent 11 parts, Homogeneous phase mixing, finally adds water, can be made into microemulsion after fully stirring.
Field experiment: to the control of oranges and tangerines damage by disease and insect
(1) investigation method
Experimental field be located at the 15 years raw Satsuma Orchards in wingceltis village, wingceltis villages and small towns, Jiande City to carry out, often 4 repetitions are established in process, often repeat 10 strains, randomized arrangement, and protection row is established in centre.Often repeat fixing investigation 4 strain, every strain investigation 10, spring tip, 60 blades, young fruit 30.Daily adopt knapsack sprayer to spray tree crown in April 20, May 10, once, liquid consumption is 1201/667m to each spray medicine
2.
Carry out classification according to citrus scab grade scale, grade scale is:
0 grade: without scab;
1 grade: lesion area accounts for less than 10% of whole leaf area;
3 grades: lesion area accounts for 11%-25% of whole leaf area;
5 grades: lesion area accounts for 26%-40% of whole leaf area;
7 grades: lesion area accounts for 41%-65% of whole leaf area;
9 grades: lesion area accounts for more than 65% of whole leaf area.
(2) control time and number of times
Test is investigated 3 times altogether, i.e. disease index investigation before medicine, preventive effect investigation in 10 days after the 1st medicine, 10 days and preventive effect investigation in 20 days after 2 medicines.
(3) drug effect computational methods
Sick leaf rate (%)=sick number of sheets/investigate the total number of sheets × 100
Disease index=∑ (the sick number of sheets × relative level numerical value at different levels)/(investigating the total number of sheets × 9) × 100
Control efficiency (%)=(before 1-(blank district medicine after disease index × treatment region medicine disease index)/(after blank district medicine before disease index × treatment region medicine disease index)) × 100
(4) poisoning investigation method
Whether after dispenser, continuous 7d estimates medicament has poisoning to crop.
(5) experimental result and analysis
The test effect of citrus anthracnose prevented and treated by table 1 respectively group test medicine process
As can be seen from Table 1, the ratio of weight and number of 30%imicyafos cyflufenamid is that the effect of the mixture combination control citrus anthracnose of 12: 18 is very remarkable, and Be very effective is better than single dose, and its quick-acting and lasting effect are all relatively good, especially outstanding with lasting effect.Complex preparation control efficiency under the consumption of high concentration is significantly better than the effect under low concentration consumption.After the 1st, 2 medicine, the best control efficiency of 10 days reaches 89.71% and 90.53% respectively, and after the 2nd medicine, 20 days best preventive effects reach 92.41%.And 20 days best preventive effects are 83.37% after single dose 25% cyflufenamid SC the 2nd medicine, the Be very effective of complex preparation is better than single dose.According to field range estimation, substantially there is no insect pest with the oranges and tangerines of 30%imicyafos cyflufenamid, and growth fraction is more vigorous, and the oranges and tangerines of 25% cyflufenamid single dose occur that insect pest is more, than with the insect pest plant of complex preparation much about about 15%.
In addition within the scope of test dose, plant growth is normal, and the poisoning phenomenon to oranges and tangerines does not all appear in each treatment agent, illustrates that it is safe to oranges and tangerines.
Claims (2)
1. containing the Fungicidal insecticidal composition of cyflufenamid, it is characterized in that: this Fungicidal insecticidal composition is that all the other components are usual auxiliaries in agricultural chemicals with A agricultural chemicals Imicyafos and B cyflufenamid for the composite composite preparation of active ingredient two yuan,
A agricultural chemicals Imicyafos,
In this Fungicidal insecticidal composition, the ratio of weight and number of effective constituents A and B is 12: 18.
2. a kind of Fungicidal insecticidal composition containing cyflufenamid according to claim 1, is characterized in that: the preparation formulation that insecticidal and bactericidal composition can be mixed with is wetting powder, suspending agent, microemulsion, aqueous emulsion and water dispersible granules.
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| CN103429086A (en) * | 2012-07-03 | 2013-12-04 | 石原产业株式会社 | Insect-killing composition and insect prevention method |
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| CN103190421A (en) * | 2013-04-07 | 2013-07-10 | 海南正业中农高科股份有限公司 | Cyflufenamid-containing sterilizing composite |
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