CN103734181A - Cyflufenamid-contained bactericidal and insecticidal composition - Google Patents
Cyflufenamid-contained bactericidal and insecticidal composition Download PDFInfo
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- CN103734181A CN103734181A CN201310746428.6A CN201310746428A CN103734181A CN 103734181 A CN103734181 A CN 103734181A CN 201310746428 A CN201310746428 A CN 201310746428A CN 103734181 A CN103734181 A CN 103734181A
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- insecticidal composition
- cyflufenamid
- bactericidal
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- 239000000203 mixture Substances 0.000 title claims abstract description 46
- 230000000749 insecticidal effect Effects 0.000 title claims abstract description 24
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 17
- 239000005755 Cyflufenamid Substances 0.000 claims abstract description 24
- ACMXQHFNODYQAT-UHFFFAOYSA-N cyflufenamid Chemical compound FC1=CC=C(C(F)(F)F)C(C(NOCC2CC2)=NC(=O)CC=2C=CC=CC=2)=C1F ACMXQHFNODYQAT-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000000839 emulsion Substances 0.000 claims abstract description 13
- PPCUNNLZTNMXFO-ACCUITESSA-N Imicyafos Chemical compound CCCSP(=O)(OCC)N1CCN(CC)\C1=N/C#N PPCUNNLZTNMXFO-ACCUITESSA-N 0.000 claims abstract description 12
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- 229910000278 bentonite Inorganic materials 0.000 description 3
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 3
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- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 description 1
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Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a cyflufenamid-contained bactericidal and insecticidal composition containing the effective components: imicyafos and cyflufenamid which are blended, wherein the weight part ratio of the two effective components is (1-50):(1-50), preferably (3-25):(5-25); the bactericidal and insecticidal composition totally contains 1-80% of the effective components, preferably 5-35%; rest auxiliary components are allowed to be used and can be accepted in a pesticide; the cyflufenamid-contained bactericidal and insecticidal composition can be prepared into wettable powder, a suspending agent, a microemulsion, an emulsion in water and water dispersible granules by using a known method. The bactericidal and insecticidal composition provided by the invention is mainly used for preventing and controlling pest and disease damages to corps of grains, cotton, oil, fruits, vegetables and flowers.
Description
Technical field
The present invention relates to agriculture chemical compounding technical field, be specifically related to a kind ofly contain agricultural chemicals Imicyafos and cyflufenamid is two yuan of composite insecticidal and bactericidal compositions of active ingredient.
Background technology
Imicyafos (AKD-3088) is a kind of cyanamide heterocyclic organic matter, it is combined by the sub-imidazolidine of cyano group of asymmetric organic phosphor and nicotinic insecticide, can be used for the crops such as radish, carrot, strawberry, eggplant, tomato, cucumber, muskmelon, watermelon, sweet potato and potato, its chemical structural formula is:
Cyflufenamid is the bactericide with novel precursor structure of Japanese Cao Da company exploitation, and its chemical structural formula is as follows:
Its powdery mildew, peach grey scab bacterium to various vegetables and wheat class has good effect and characteristic, benzimidazole, imidazoles, methoxy acrylate class resistance bacterium and sensitive bacteria is had to same isoreactivity simultaneously.Cyflufenamid is extremely low to people and animals' toxicity, do not exist follow-on impact, and teratogenesis, mutagenicity test is all negative, the also not stimulation to eye, skin and allergy on producing.In addition, this agent can not affect environment and beneficial organism yet, minimum on honeybee and silkworm impact yet.
Long-term use single insecticide or bactericide, insect or germ are easy to develop immunity to drugs, and pesticide dosage is increased, and cause large, residual many, the adverse consequences such as drug effect is poor of high poison, consumption, and effect field are more single.The different mechanisms of action and without insecticide and the bactericide rational mixture by a certain percentage of cross resistance, can improve crop disease prevention effect, reduce dosage, residual few, minimizing environmental pollution, effectively reduces the pesticide resistance of crop.
Summary of the invention
According to the deficiencies in the prior art; the present invention proposes a kind of Fungicidal insecticidal composition that contains cyflufenamid, said composition contains A, two kinds of effective active components of B, and component A selects novel pesticide Imicyafos; B is selected from cyflufenamid; it is wide that the present composition has effect field, can desinsection again can sterilization, and consumption is few; preventive effect is high; residual few, the lasting period is long, is conducive to environmental protection.
The present invention is a kind of insecticidal and bactericidal composition preparation that carries out two yuan of mixtures take novel pesticide Imicyafos and cyflufenamid as active ingredient, wherein in insecticidal and bactericidal composition of the present invention, the ratio of weight and number of active ingredient novel pesticide Imicyafos and cyflufenamid is 1～50: 50～1, on the basis of test recipe screening targetedly, the ratio of weight and number of active ingredient novel pesticide Imicyafos and cyflufenamid can be preferably to 3～25: 25～5.
Agricultural insecticide bactericidal composition of the present invention is wetting powder, suspending agent, microemulsion, aqueous emulsion and water dispersible granules by the formulations of pesticide that the preparation method in pesticidal preparations field can be prepared into, in preparation, to account for the portion rate of gross weight in preparation be 1%～80% to active ingredient gross weight, on the basis of test recipe screening targetedly, in preparation, to account for the portion rate of gross weight in preparation be 3%～35% to active ingredient gross weight, and all the other are usual auxiliaries in agricultural chemicals.
When above-described Pesticidal combination is microemulsion, in preparation, the ratio of weight and number of each component is:
The concrete production stage of this microemulsion is: former medicine imicyafos, cyflufenamid cosolvent are dissolved completely, then add other compositions such as emulsifier, antifreezing agent stabilizing agent, evenly mix, finally add water, after fully stirring, can be made into microemulsion.
When above-described Pesticidal combination is wetting powder, in preparation, the ratio of weight and number of each component is:
The concrete procedure of processing of this Pesticidal combination wetting powder is: by above-mentioned formula, active principle A and active principle B and dispersant, wetting agent and filler are mixed, uniform stirring in stirred tank, after airslide disintegrating mill, mixing, can be made into the wetting powder of the present composition.
When above-described Pesticidal combination is suspending agent, in preparation, the ratio of weight and number of each component is:
The concrete production stage of this suspending agent is for first mixing other auxiliary agents, through high speed shear, mix, add active principle A and active principle B, abrading-ball 2～3 hours in ball crusher, make a diameter all below 5mm, make the suspending agent preparation of Pesticidal combination of the present invention.
When above-described Pesticidal combination is aqueous emulsion, in preparation, the ratio of weight and number of each component is:
The concrete production stage of this aqueous emulsion is: first former medicine active principle A and active principle B, solvent and emulsifier, cosolvent are added together, make to be dissolved into uniform oil phase; By part water, antifreeze, other the insecticides adjuvant such as antimicrobial mixes into uniform water; When reactor high speed stirs, oil phase is added to water, slowly add water until reach phase inversion point, open clipper and carry out high speed shear, and add remaining water, shear about half an hour, form the aqueous emulsion of oil-in-water type.Make the aqueous emulsion of Pesticidal combination of the present invention.
When above-described Pesticidal combination is water dispersible granules, in preparation, the ratio of weight and number of each component is:
The concrete procedure of processing of this Pesticidal combination water dispersible granules is: by above-mentioned formula, active principle A, active principle B and dispersant, wetting agent, disintegrant and filler are mixed, pulverize with micro jet, through mediating, then add and in fluidized bed prilling dryer, carry out after granulation, dry, screening, through sample analysis, making the water dispersible granules of Pesticidal combination of the present invention.
Described emulsifier is selected from least one in calcium dodecyl benzene sulfonate and aliphatic acid polyethenoxy ether, alkylphenol polyoxyethylene sulfosuccinate, styrylphenol polyoxyethylene ether, polyoxyethylene nonylphenol ether, castor oil polyoxyethylene ether, aliphatic acid polyethenoxy base ester, polyoxyethylene aliphatic alcohol ether.
Described solvent is at least one in dimethylbenzene or biodiesel, toluene, diesel oil, methyl alcohol, ethanol, n-butanol, isopropyl alcohol, turpentine oil, solvent naphtha, dimethyl formamide, dimethyl sulfoxide (DMSO), water equal solvent.
Described dispersant is selected from least one in polycarboxylate, lignosulfonates, alkylphenol polyoxyethylene formaldehyde condensation products sulphate, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol polyoxyethylene, aliphatic amine polyoxyethylene ether, polyoxyethylene carboxylate, fatty acid glyceride APEO.
Described wetting agent is selected from lauryl sodium sulfate, calcium dodecyl benzene sulfonate, pulls open powder copper rosinate X., wetting and penetrating agent F, at least one in alkylnaphthalene sulfonate, polyoxyethylene triphenylethylene phosphenylic acid salt, spaonin powder, silkworm excrement, soapberry powder.
Described disintegrant is selected from least one in bentonite, urea, ammonium sulfate, aluminium chloride, citric acid, succinic acid, sodium bicarbonate.
Described thickener is selected from least one in xanthans, CMC, hydroxyethylcellulose, methylcellulose, Magnesiumaluminumsilicate, polyvinyl alcohol.
Described stabilizing agent is selected from least one in sodium citrate, resorcinol.
Described antifreezing agent is selected from least one in ethylene glycol, propane diols, glycerine.
Described defoamer is selected from silicone oil, silicone compound, C
10-20saturated fat acid compounds, C
8-10at least one in aliphatic alcohols compound.
Described filler is selected from least one in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, precipitated calcium carbonate.
Agricultural insecticide bactericidal composition of the present invention to grain, cotton, oil, really, the multiple fungal diseases of vegetables, flowers all has favorable effect, especially the powdery mildew on the cereal such as wheat, fruit and vegetables, downy mildew, rust, tikka class disease, scab, rot etc. are caused to ergosterol class synthetic inhibitor class agricultural chemicals, had the control of the disease of certain resistance to have excellent preventive effect by germ.Pesticidal combination of the present invention can prevent and treat nematoda, etc. the various insects such as sufficient class, coleoptera class pest, Lepidoptera class pest, gastropod, orthoptera pest, phytotrophy acarid class, thrips insect, Diptera pest, Hymenoptera insect, hidden wing order insect, Anoplura insect, Isoptera insect, Semiptera insect, damp insects, centipede insects, thousand-legger class.Especially to destroy the insect of agriculture horticultural crop and trees etc., the insect of destroying the seed of agriculture horticultural crop and trees in soil, such as nematoda, etc. sufficient class, coleoptera class pest, Lepidoptera class pest, gastropod, orthoptera pest, phytotrophy acarid class, Semiptera insect preventive effect remarkable.
The above nematode pests comprises the pratylenchus classes such as pratylenchus, pseudo-Pratylenchidae, Lu Si Pratylenchidae, disability Pratylenchidae, the Cyst nematode such as soybean cyst nematode Heterodera glycines, globodera rostochiensis class, the root-knot nematode such as peanut root-knot nematode, Meloidogyne incognita class, the Aphelenchoidea classes such as aphelenchoides besseyi, leaf bud nematode, species of Tylenchorhynchus Nematodes class, loop wire insects, needlework insects, long capsule nematoda, burr nematoda, nematode on strawberry, pine wood nematode.In addition the insects such as aphid, leafhopper, plant hopper, chrysomelid, wireworm, cutworm, diamond-back moth, imported cabbageworm, rice thrips are all had to favorable effect.
In addition, insecticidal and bactericidal composition of the present invention is compared similar medicament also a lot of other obvious advantages, the first, compare single dose sphere of action wider, can desinsection again can diseases prevention; The second, greatly delayed the drug-fast generation of crop, reduced agricultural chemicals Reusability number of times, reduced agricultural chemicals usage amount, reduce agricultural cost; The 3rd, the residual quantity of this insecticidal and bactericidal composition is lower, more friendly to environment; Finally in the application of this insecticidal and bactericidal composition, crops are had to general fresh-keeping production-increasing function, the increasing both production and income of agricultural region is significant.
Embodiment:
In order to make object of the present invention, technical scheme and advantage clearer, the present invention describes with following specific embodiment, but the present invention only limits to absolutely not these examples.The method that the present invention adopts indoor bioassay and field trial to combine, if no special instructions, the ratio (comprising percentage) of below mentioning is all ratio of weight and number.
Embodiment 1: by imicyafos15 part, 15 parts of cyflufenamids, 10 parts of lignosulfonates, 12 parts of lauryl sodium sulfate and 48 parts of mixing of diatomite, uniform stirring in stirred tank, after airslide disintegrating mill, mixing, making the wetting powder of Pesticidal combination of the present invention.
Embodiment 2: by imicyafos8 part, 22 parts of cyflufenamids, 12 parts of alkylphenol polyoxyethylene, 13 parts of oxygen ethene triphenylethylene phosphenylic acid salt and 35 parts of mixing of bentonite, uniform stirring in stirred tank, after airslide disintegrating mill, mixing, making the wetting powder of Pesticidal combination of the present invention.
Embodiment 3: by imicyafos20 part, 10 parts of cyflufenamids, 12 parts of dispersants, 12 parts of wetting agents and 46 parts of mixing of filler, uniform stirring in stirred tank is mixing after airslide disintegrating mill, makes the wetting powder of Pesticidal combination of the present invention.
Embodiment 4: by 8 parts of alkylphenol polyoxyethylene, 2 parts of glycerine, 3 parts of CMCs, 2 parts of silicone oil, 55 parts of mixing of water, through high speed shear, mix, add successively 12 parts of imicyafos18 part, cyflufenamids, abrading-ball 2～3 hours in ball crusher, make a diameter all below 5mm, make the suspending agent preparation of Pesticidal combination of the present invention.
Embodiment 5: by 12 parts of dispersants, 2 parts of antifreezing agents, 4 parts of thickeners, 1 part of defoamer, 46 parts of mixing of water, through high speed shear, mix, add successively 10 parts of imicyafos25 part, cyflufenamids, abrading-ball 2～3 hours in ball crusher, make a diameter all below 5mm, make the suspending agent preparation of Pesticidal combination of the present invention.
Embodiment 6: by 10 parts of dispersants, 2 parts of antifreezing agents, 4 parts of thickeners, 1 part of defoamer, 53 parts of mixing of water, through high speed shear, mix, add successively 15 parts of imicyafos15 part, cyflufenamids, abrading-ball 2～3 hours in ball crusher, make a diameter all below 5mm, make the suspending agent preparation of Pesticidal combination of the present invention.
Embodiment 7: 6 parts of imicyafos5 parts, 25 parts of cyflufenamids, 12 parts, turpentine oil, 5 parts of castor oil polyoxyethylene ethers, resorcinol are mixed, be dissolved into uniform oil phase; 1 part, part water, 2 parts of propane diols, silicone compound is mixed into uniform water; When reactor high speed stirs, oil phase is added to water, add 4 parts of polyvinyl alcohol, slowly add water until reach phase inversion point, open clipper and carry out high speed shear, and add remaining water to supply 100 parts, and shear about half an hour, form the aqueous emulsion of oil-in-water type.Make the aqueous emulsion of Pesticidal combination of the present invention.
Embodiment 8: 12 parts of imicyafos30 parts, 5 parts of cyflufenamids, 22 parts of solvents, 8 parts of emulsifier, stabilizing agent are mixed, be dissolved into uniform oil phase; 2 parts, part water, 1 part of antifreezing agent, defoamer is mixed into uniform water; When reactor high speed stirs, oil phase is added to water, add 3 parts of thickeners, slowly add water until reach phase inversion point, open clipper and carry out high speed shear, and add remaining water to supply 100 parts, shear about half an hour, form the aqueous emulsion of oil-in-water type.Make the aqueous emulsion of Pesticidal combination of the present invention.
Embodiment 9: 8 parts of imicyafos16 parts, 10 parts of cyflufenamids, 18 parts of solvents, 10 parts of emulsifier, stabilizing agent are mixed, be dissolved into uniform oil phase; 2 parts, part water, 1 part of antifreezing agent, defoamer is mixed into uniform water; When reactor high speed stirs, oil phase is added to water, add 3 parts of thickeners, slowly add water until reach phase inversion point, open clipper and carry out high speed shear, and add remaining water to supply 100 parts, shear about half an hour, form the aqueous emulsion of oil-in-water type.Make the aqueous emulsion of Pesticidal combination of the present invention.
Embodiment 10: 49 parts of imicyafos20 part, 8 parts of cyflufenamids, 8 parts of aliphatic amine polyoxyethylene ethers, 10 parts of alkylnaphthalene sulfonates, 5 parts, aluminium chloride and bentonites are mixed, pulverize with micro jet, through mediating, then add and in fluidized bed prilling dryer, carry out after granulation, dry, screening, through sample analysis, making the water dispersible granules of Pesticidal combination of the present invention.
Embodiment 11: 51 parts of imicyafos10 part, 15 parts of cyflufenamids, 10 parts of dispersants, 12 parts of wetting agents, 5 parts of disintegrants and fillers are mixed, pulverize with micro jet, through mediating, then add and in fluidized bed prilling dryer, carry out after granulation, dry, screening, through sample analysis, making the water dispersible granules of Pesticidal combination of the present invention.
Embodiment 12: 45 parts of imicyafos18 part, 12 parts of cyflufenamids, 10 parts of dispersants, 12 parts of wetting agents, 3 parts of disintegrants and fillers are mixed, pulverize with micro jet, through mediating, then add and in fluidized bed prilling dryer, carry out after granulation, dry, screening, through sample analysis, making the water dispersible granules of Pesticidal combination of the present invention.
Embodiment 13: 20 parts of former medicine imicyafos15 parts, cyflufenamid are dissolved completely with cosolvent, add again other compositions such as 13 parts of aliphatic acid polyethenoxy base esters, 2 parts of ethylene glycol, 4 parts of sodium citrates, 4 parts of resorcinols, evenly mix, finally add water, after fully stirring, can be made into microemulsion.
Embodiment 14: 20 parts of former medicine imicyafos10 parts, cyflufenamid are dissolved completely with cosolvent, then add other compositions such as 11 parts of emulsifier, 2 parts of antifreezing agents, 7 parts of stabilizing agents, evenly mix, finally add water, can be made into microemulsion after fully stirring.
Embodiment 15: 25 parts of former medicine imicyafos8 parts, cyflufenamid are dissolved completely with cosolvent, then add other compositions such as 9 parts of emulsifier, 2 parts of antifreezing agents, 11 parts of stabilizing agents, evenly mix, finally add water, can be made into microemulsion after fully stirring.
Field experiment: to the control of oranges and tangerines damage by disease and insect
(1) investigation method
Experimental field be located at the 15 years raw Satsuma Orchards in wingceltis village, wingceltis villages and small towns, Jiande City and carry out, 4 repetitions are established in every processing, every repetition 10 strains, and randomized arrangement, protection row is established in centre.Every fixing investigation 4 strains, 10, every strain investigation spring tip, 60 blades, 30 of young fruits of repeating.April 20, average daily employing knapsack sprayer sprinkling in May 10 tree crown, respectively spray medicine once, and liquid consumption is 1201/667m
2.
According to citrus scab grade scale, carry out classification, grade scale is:
0 grade: without scab;
1 grade: lesion area accounts for below 10% of whole leaf area;
3 grades: lesion area accounts for 11%-25% of whole leaf area;
5 grades: lesion area accounts for 26%-40% of whole leaf area;
7 grades: lesion area accounts for 41%-65% of whole leaf area;
9 grades: lesion area accounts for the more than 65% of whole leaf area.
(2) control time and number of times
Test is investigated 3 times altogether, i.e. disease index investigation before medicine, preventive effect investigation in 10 days after the 1st medicine, 10 days and preventive effect investigation in 20 days after 2 medicines.
(3) drug effect computational methods
The total number of sheets × 100 of sick leaf rate (%)=sick number of sheets/investigate
Disease index=∑ (the sick number of sheets × relative level numerical value at different levels)/(investigating the total number of sheets × 9) × 100
Control efficiency (%)=(disease index after the front disease index × treatment region medicine of 1-(blank district medicine)/(the front disease index of disease index × treatment region medicine after blank district medicine)) × 100
(4) poisoning investigation method
After dispenser, whether 7d range estimation medicament has poisoning to crop continuously.
(5) experimental result and analysis
The each group of table 1 test medicine is processed the test effect of control citrus anthracnose
As can be seen from Table 1, the effect of the mixture combination control citrus anthracnose that the ratio of weight and number of 30%imicyafos cyflufenamid is 12: 18 is very remarkable, and effect is significantly better than single dose, and its quick-acting and lasting effect are all relatively good, especially outstanding with lasting effect.Complex preparation control efficiency under the consumption of high concentration is significantly better than the effect under low concentration consumption.After the 1st, 2 medicines the best control efficiency of 10 days reach respectively 89.71% and 90.53%, the 2 medicine after 20 days best preventive effects reach 92.41%.And 20 days best preventive effects are 83.37% after the 2nd medicine of single dose 25% cyflufenamid SC, the effect of complex preparation is significantly better than single dose.According to field range estimation, substantially there is no insect pest with the oranges and tangerines of 30%imicyafos cyflufenamid, and growth fraction is more vigorous, and the oranges and tangerines of 25% cyflufenamid single dose occur that insect pest is more, than much approximately 15% left and right of insect pest plant of use complex preparation.
Within the scope of test dose, plant growth is normal in addition, and the poisoning phenomenon to oranges and tangerines does not all appear in each treatment agent, illustrates that it is safe to oranges and tangerines.
Claims (5)
1. a Fungicidal insecticidal composition that contains cyflufenamid, it is characterized in that: this Fungicidal insecticidal composition is take A novel agrochemical Imicyafos and B cyflufenamid as two yuan of composite composite preparations of active ingredient, all the other components are usual auxiliaries in agricultural chemicals, and A novel agrochemical Imicyafos structural formula is as follows:
, in this Fungicidal insecticidal composition, the ratio of weight and number of effective constituents A and B is 1～50: 50～1.
2. a kind of Fungicidal insecticidal composition that contains cyflufenamid according to claim 1, is characterized in that: in this Fungicidal insecticidal composition, the ratio of weight and number of effective constituents A and B is 3～25: 25～5.
3. a kind of Fungicidal insecticidal composition that contains cyflufenamid according to claim 1, is characterized in that: in this Fungicidal insecticidal composition, to account for the portion rate of gross weight in preparation be 1%～80% for effective constituents A and B gross weight.
4. a kind of Fungicidal insecticidal composition that contains cyflufenamid according to claim 1, is characterized in that: in this Fungicidal insecticidal composition, effective constituents A and B gross weight account for the portion rate of gross weight in preparation and be preferably 5%～35%.
5. a kind of Fungicidal insecticidal composition that contains cyflufenamid according to claim 1, is characterized in that: the preparation formulation that insecticidal and bactericidal composition of the present invention can be mixed with is wetting powder, suspending agent, microemulsion, aqueous emulsion and water dispersible granules.
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| CN103190421A (en) * | 2013-04-07 | 2013-07-10 | 海南正业中农高科股份有限公司 | Cyflufenamid-containing sterilizing composite |
| CN103429086A (en) * | 2012-07-03 | 2013-12-04 | 石原产业株式会社 | Insect-killing composition and insect prevention method |
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| CN103429086A (en) * | 2012-07-03 | 2013-12-04 | 石原产业株式会社 | Insect-killing composition and insect prevention method |
| CN103190421A (en) * | 2013-04-07 | 2013-07-10 | 海南正业中农高科股份有限公司 | Cyflufenamid-containing sterilizing composite |
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| CN103651561A (en) * | 2013-12-30 | 2014-03-26 | 孙蒙蒙 | Sterilization insecticidal combination containing fenhexamid |
| CN103651561B (en) * | 2013-12-30 | 2016-08-17 | 青岛青知企业管理咨询有限公司 | A kind of Fungicidal insecticidal composition containing fenhexamid |
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