CN103719149A - Sterilization insecticide composition with picoxystrobin - Google Patents
Sterilization insecticide composition with picoxystrobin Download PDFInfo
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- CN103719149A CN103719149A CN201310752678.0A CN201310752678A CN103719149A CN 103719149 A CN103719149 A CN 103719149A CN 201310752678 A CN201310752678 A CN 201310752678A CN 103719149 A CN103719149 A CN 103719149A
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- 239000005818 Picoxystrobin Substances 0.000 title abstract 3
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a sterilization insecticide composition with picoxystrobin. The composition comprises effective components, namely, Imicyafos and picoxystrobin, in binary blending, wherein the weight part ratio of the two effective components is (1-50):(1-50), and preferably the weight part ratio is (3-25):(5-25); the total percentage by weight of the effective components in the sterilization insecticide composition is 1-80%, preferably the percentage by weight is 5-35%, the remnants are auxiliary components which are allowable and acceptable in pesticide, and the components are prepared into wettable powder, suspending agents, micro emulsions, water emulsions and water dispersible granules. The sterilization insecticide composition provided by the invention is mainly applied to prevention and treatment on insect pests of crops such as grains, cotton, oil, fruits, vegetables and flowers.
Description
Technical field
The present invention relates to agriculture chemical compounding technical field, be specifically related to a kind ofly contain agricultural chemicals Imicyafos and ZEN 90160 is two yuan of composite insecticidal and bactericidal compositions of active ingredient.
Background technology
Imicyafos (AKD-3088) is a kind of cyanamide heterocyclic organic matter, it is combined by the sub-imidazolidine of cyano group of asymmetric organic phosphor and nicotinic insecticide, can be used for the crops such as radish, carrot, strawberry, eggplant, tomato, cucumber, muskmelon, watermelon, sweet potato and potato, its chemical structural formula is:
ZEN 90160 is a class low toxicity, efficient, wide spectrum, systemic fungicide, has the bactericide of protection, treatment and eradicant action.Its mechanism of action is to act on cytochrome compound, and the electron transfer process of blocking-up germ mitochondrial respiratory chain, suppresses the supply of germ cellular energy, makes germ cell lack energy death.The germs such as Ascomycetes, Basidiomycetes, deuteromycetes and Oomycete are had to excellent activity, can prevent and treat the diseases such as powdery mildew, rust, downy mildew, epidemic disease, anthracnose and the rice blast of various crop.
Long-term use single insecticide or bactericide, insect or germ are easy to develop immunity to drugs, and pesticide dosage is increased, and cause large, residual many, the adverse consequences such as drug effect is poor of high poison, consumption, and effect field are more single.The different mechanisms of action and without insecticide and the bactericide rational mixture by a certain percentage of cross resistance, can improve crop disease prevention effect, reduce dosage, residual few, minimizing environmental pollution, effectively reduces the pesticide resistance of crop.
Summary of the invention
According to the deficiencies in the prior art; the present invention proposes a kind of Fungicidal insecticidal composition that contains ZEN 90160, said composition contains A, two kinds of effective active components of B, and component A selects novel pesticide Imicyafos; B is selected from ZEN 90160; it is wide that the present composition has effect field, can desinsection again can sterilization, and consumption is few; preventive effect is high; residual few, the lasting period is long, is conducive to environmental protection.
The present invention is a kind of insecticidal and bactericidal composition preparation that carries out two yuan of mixtures take novel pesticide Imicyafos and ZEN 90160 as active ingredient, wherein in insecticidal and bactericidal composition of the present invention, the ratio of weight and number of active ingredient novel pesticide Imicyafos and ZEN 90160 is 1～50: 50～1, on the basis of test recipe screening targetedly, the ratio of weight and number of active ingredient novel pesticide Imicyafos and ZEN 90160 can be preferably to 3～25: 25～5.
Agricultural insecticide bactericidal composition of the present invention is wetting powder, suspending agent, microemulsion, aqueous emulsion and water dispersible granules by the formulations of pesticide that the preparation method in pesticidal preparations field can be prepared into, in preparation, to account for the portion rate of gross weight in preparation be 1%～80% to active ingredient gross weight, on the basis of test recipe screening targetedly, in preparation, to account for the portion rate of gross weight in preparation be 3%～35% to active ingredient gross weight, and all the other are usual auxiliaries in agricultural chemicals.
When above-described Pesticidal combination is microemulsion, in preparation, the ratio of weight and number of each component is:
The concrete production stage of this microemulsion is: former medicine imicyafos, ZEN 90160 cosolvent are dissolved completely, then add other compositions such as emulsifier, antifreezing agent stabilizing agent, evenly mix, finally add water, after fully stirring, can be made into microemulsion.
When above-described Pesticidal combination is wetting powder, in preparation, the ratio of weight and number of each component is:
The concrete procedure of processing of this Pesticidal combination wetting powder is: by above-mentioned formula, active principle A and active principle B and dispersant, wetting agent and filler are mixed, uniform stirring in stirred tank, after airslide disintegrating mill, mixing, can be made into the wetting powder of the present composition.
When above-described Pesticidal combination is suspending agent, in preparation, the ratio of weight and number of each component is:
The concrete production stage of this suspending agent is for first mixing other auxiliary agents, through high speed shear, mix, add active principle A and active principle B, abrading-ball 2～3 hours in ball crusher, make a diameter all below 5mm, make the suspending agent preparation of Pesticidal combination of the present invention.
When above-described Pesticidal combination is aqueous emulsion, in preparation, the ratio of weight and number of each component is:
The concrete production stage of this aqueous emulsion is: first former medicine active principle A and active principle B, solvent and emulsifier, cosolvent are added together, make to be dissolved into uniform oil phase; By part water, antifreeze, other the insecticides adjuvant such as antimicrobial mixes into uniform water; When reactor high speed stirs, oil phase is added to water, slowly add water until reach phase inversion point, open clipper and carry out high speed shear, and add remaining water, shear about half an hour, form the aqueous emulsion of oil-in-water type.Make the aqueous emulsion of Pesticidal combination of the present invention.
When above-described Pesticidal combination is water dispersible granules, in preparation, the ratio of weight and number of each component is:
The concrete procedure of processing of this Pesticidal combination water dispersible granules is: by above-mentioned formula, active principle A, active principle B and dispersant, wetting agent, disintegrant and filler are mixed, pulverize with micro jet, through mediating, then add and in fluidized bed prilling dryer, carry out after granulation, dry, screening, through sample analysis, making the water dispersible granules of Pesticidal combination of the present invention.
Described emulsifier is selected from least one in calcium dodecyl benzene sulfonate and aliphatic acid polyethenoxy ether, alkylphenol polyoxyethylene sulfosuccinate, styrylphenol polyoxyethylene ether, polyoxyethylene nonylphenol ether, castor oil polyoxyethylene ether, aliphatic acid polyethenoxy base ester, polyoxyethylene aliphatic alcohol ether.
Described solvent is at least one in dimethylbenzene or biodiesel, toluene, diesel oil, methyl alcohol, ethanol, n-butanol, isopropyl alcohol, turpentine oil, solvent naphtha, dimethyl formamide, dimethyl sulfoxide (DMSO), water equal solvent.
Described dispersant is selected from least one in polycarboxylate, lignosulfonates, alkylphenol polyoxyethylene formaldehyde condensation products sulphate, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol polyoxyethylene, aliphatic amine polyoxyethylene ether, polyoxyethylene carboxylate, fatty acid glyceride APEO.
Described wetting agent is selected from lauryl sodium sulfate, calcium dodecyl benzene sulfonate, pulls open powder copper rosinate X., wetting and penetrating agent F, at least one in alkylnaphthalene sulfonate, polyoxyethylene triphenylethylene phosphenylic acid salt, spaonin powder, silkworm excrement, soapberry powder.
Described disintegrant is selected from least one in bentonite, urea, ammonium sulfate, aluminium chloride, citric acid, succinic acid, sodium bicarbonate.
Described thickener is selected from least one in xanthans, CMC, hydroxyethylcellulose, methylcellulose, Magnesiumaluminumsilicate, polyvinyl alcohol.
Described stabilizing agent is selected from least one in sodium citrate, resorcinol.
Described antifreezing agent is selected from least one in ethylene glycol, propane diols, glycerine.
Described defoamer is selected from silicone oil, silicone compound, C
10-20saturated fat acid compounds, C
8-10at least one in aliphatic alcohols compound.
Described filler is selected from least one in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, precipitated calcium carbonate.
Agricultural insecticide bactericidal composition of the present invention to grain, cotton, oil, really, the multiple fungal diseases of vegetables, flowers all has favorable effect, especially the powdery mildew on the cereal such as wheat, fruit and vegetables, downy mildew, rust, tikka class disease, scab, rot etc. are caused to ergosterol class synthetic inhibitor class agricultural chemicals, had the control of the disease of certain resistance to have excellent preventive effect by germ.Pesticidal combination of the present invention can prevent and treat nematoda, etc. the various insects such as sufficient class, coleoptera class pest, Lepidoptera class pest, gastropod, orthoptera pest, phytotrophy acarid class, thrips insect, Diptera pest, Hymenoptera insect, hidden wing order insect, Anoplura insect, Isoptera insect, Semiptera insect, damp insects, centipede insects, thousand-legger class.Especially to destroy the insect of agriculture horticultural crop and trees etc., the insect of destroying the seed of agriculture horticultural crop and trees in soil, such as nematoda, etc. sufficient class, coleoptera class pest, Lepidoptera class pest, gastropod, orthoptera pest, phytotrophy acarid class, Semiptera insect preventive effect remarkable.
The above nematode pests comprises the pratylenchus classes such as pratylenchus, pseudo-Pratylenchidae, Lu Si Pratylenchidae, disability Pratylenchidae, the Cyst nematode such as soybean cyst nematode Heterodera glycines, globodera rostochiensis class, the root-knot nematode such as peanut root-knot nematode, Meloidogyne incognita class, the Aphelenchoidea classes such as aphelenchoides besseyi, leaf bud nematode, species of Tylenchorhynchus Nematodes class, loop wire insects, needlework insects, long capsule nematoda, burr nematoda, nematode on strawberry, pine wood nematode.In addition the insects such as aphid, leafhopper, plant hopper, chrysomelid, wireworm, cutworm, diamond-back moth, imported cabbageworm, rice thrips are all had to favorable effect.
In addition, insecticidal and bactericidal composition of the present invention is compared similar medicament also a lot of other obvious advantages, the first, compare single dose sphere of action wider, can desinsection again can diseases prevention; The second, greatly delayed the drug-fast generation of crop, reduced agricultural chemicals Reusability number of times, reduced agricultural chemicals usage amount, reduce agricultural cost; The 3rd, the residual quantity of this insecticidal and bactericidal composition is lower, more friendly to environment; Finally in the application of this insecticidal and bactericidal composition, crops are had to general fresh-keeping production-increasing function, the increasing both production and income of agricultural region is significant.
Embodiment:
In order to make object of the present invention, technical scheme and advantage clearer, the present invention describes with following specific embodiment, but the present invention only limits to absolutely not these examples.The method that the present invention adopts indoor bioassay and field trial to combine, if no special instructions, the ratio (comprising percentage) of below mentioning is all ratio of weight and number.
Embodiment 1: by imicyafos12 part, 17 parts of ZEN 90160,9 parts of lignosulfonates, 11 parts of lauryl sodium sulfate and 61 parts of mixing of diatomite, uniform stirring in stirred tank, after airslide disintegrating mill, mixing, making the wetting powder of Pesticidal combination of the present invention.
Embodiment 2: by imicyafos6 part, 21 parts of ZEN 90160,9 parts of alkylphenol polyoxyethylene, 13 parts of oxygen ethene triphenylethylene phosphenylic acid salt and 51 parts of mixing of bentonite, uniform stirring in stirred tank, after airslide disintegrating mill, mixing, making the wetting powder of Pesticidal combination of the present invention.
Embodiment 3: by imicyafos5 part, 20 parts of ZEN 90160,11 parts of dispersants, 11 parts of wetting agents and 53 parts of mixing of filler, uniform stirring in stirred tank is mixing after airslide disintegrating mill, makes the wetting powder of Pesticidal combination of the present invention.
Embodiment 4: by 8 parts of alkylphenol polyoxyethylene, 2 parts of glycerine, 4 parts of CMCs, 1 part of silicone oil, 60 parts of mixing of water, through high speed shear, mix, add successively 10 parts of imicyafos15 part, ZEN 90160, abrading-ball 2～3 hours in ball crusher, make a diameter all below 5mm, make the suspending agent preparation of Pesticidal combination of the present invention.
Embodiment 5: by 10 parts of dispersants, 2 parts of antifreezing agents, 3 parts of thickeners, 1 part of defoamer, 64 parts of mixing of water, through high speed shear, mix, add successively 20 parts of imicyafos10 part, ZEN 90160, abrading-ball 2～3 hours in ball crusher, make a diameter all below 5mm, make the suspending agent preparation of Pesticidal combination of the present invention.
Embodiment 6: by 8 parts of dispersants, 2 parts of antifreezing agents, 4 parts of thickeners, 1 part of defoamer, 58 parts of mixing of water, through high speed shear, mix, add successively 12 parts of imicyafos15 part, ZEN 90160, abrading-ball 2～3 hours in ball crusher, make a diameter all below 5mm, make the suspending agent preparation of Pesticidal combination of the present invention.
Embodiment 7: 6 parts of imicyafos12 parts, 25 parts of ZEN 90160,12 parts, turpentine oil, 5 parts of castor oil polyoxyethylene ethers, resorcinol are mixed, be dissolved into uniform oil phase; 1 part, part water, 2 parts of propane diols, silicone compound is mixed into uniform water; When reactor high speed stirs, oil phase is added to water, add 4 parts of polyvinyl alcohol, slowly add water until reach phase inversion point, open clipper and carry out high speed shear, and add remaining water to supply 100 parts, and shear about half an hour, form the aqueous emulsion of oil-in-water type.Make the aqueous emulsion of Pesticidal combination of the present invention.
Embodiment 8: 12 parts of imicyafos25 parts, 13 parts of ZEN 90160,20 parts of solvents, 8 parts of emulsifier, stabilizing agent are mixed, be dissolved into uniform oil phase; 2 parts, part water, 1 part of antifreezing agent, defoamer is mixed into uniform water; When reactor high speed stirs, oil phase is added to water, add 3 parts of thickeners, slowly add water until reach phase inversion point, open clipper and carry out high speed shear, and add remaining water to supply 100 parts, shear about half an hour, form the aqueous emulsion of oil-in-water type.Make the aqueous emulsion of Pesticidal combination of the present invention.
Embodiment 9: 8 parts of imicyafos15 parts, 10 parts of ZEN 90160,18 parts of solvents, 10 parts of emulsifier, stabilizing agent are mixed, be dissolved into uniform oil phase; 2 parts, part water, 1 part of antifreezing agent, defoamer is mixed into uniform water; When reactor high speed stirs, oil phase is added to water, add 3 parts of thickeners, slowly add water until reach phase inversion point, open clipper and carry out high speed shear, and add remaining water to supply 100 parts, shear about half an hour, form the aqueous emulsion of oil-in-water type.Make the aqueous emulsion of Pesticidal combination of the present invention.
Embodiment 10: 45 parts of imicyafos25 part, 5 parts of ZEN 90160,10 parts of aliphatic amine polyoxyethylene ethers, 10 parts of alkylnaphthalene sulfonates, 5 parts, aluminium chloride and bentonites are mixed, pulverize with micro jet, through mediating, then add and in fluidized bed prilling dryer, carry out after granulation, dry, screening, through sample analysis, making the water dispersible granules of Pesticidal combination of the present invention.
Embodiment 11: 38 parts of imicyafos5 part, 25 parts of ZEN 90160,12 parts of dispersants, 10 parts of wetting agents, 5 parts of disintegrants and fillers are mixed, pulverize with micro jet, through mediating, then add and in fluidized bed prilling dryer, carry out after granulation, dry, screening, through sample analysis, making the water dispersible granules of Pesticidal combination of the present invention.
Embodiment 12: 45 parts of imicyafos12 part, 18 parts of ZEN 90160,10 parts of dispersants, 12 parts of wetting agents, 3 parts of disintegrants and fillers are mixed, pulverize with micro jet, through mediating, then add and in fluidized bed prilling dryer, carry out after granulation, dry, screening, through sample analysis, making the water dispersible granules of Pesticidal combination of the present invention.
Embodiment 13: 20 parts of former medicine imicyafos15 parts, ZEN 90160 are dissolved completely with cosolvent, add again other compositions such as 10 parts of aliphatic acid polyethenoxy base esters, 2 parts of ethylene glycol, 4 parts of sodium citrates, 4 parts of resorcinols, evenly mix, finally add water, after fully stirring, can be made into microemulsion.
Embodiment 14: 18 parts of former medicine imicyafos12 parts, ZEN 90160 are dissolved completely with cosolvent, then add other compositions such as 11 parts of emulsifier, 2 parts of antifreezing agents, 7 parts of stabilizing agents, evenly mix, finally add water, can be made into microemulsion after fully stirring.
Embodiment 15: 25 parts of former medicine imicyafos8 parts, ZEN 90160 are dissolved completely with cosolvent, then add other compositions such as 9 parts of emulsifier, 2 parts of antifreezing agents, 11 parts of stabilizing agents, evenly mix, finally add water, can be made into microemulsion after fully stirring.
Field experiment: to the control of Wheat Diseases And Insect Pests
(1) investigation method
Experimental field be located at Henan, select the medium rice field of occurring degree for experimental field, soil fertility is medium, and irrigation and drainage are convenient.Adopt bilinear sampling method, 5 points are got in every community, look into 5 caves at every, and during investigation, 2 blades in the fixing middle part of every strain fix a point to check.
According to Rice Leaf rot grade scale, carry out classification, record total strain number, diseased plant number, severity, calculate diseased plant rate, disease index and preventive effect.Rice Leaf rot grade scale is
0 grade: complete stool is anosis;
1 grade: the 4th blade and following leaf sheath thereof, blade morbidity (take sword-like leave as the 1st leaf);
3 grades: the 3rd blade and following leaf sheath thereof, blade morbidity;
5 grades: the 2nd blade and following leaf sheath thereof, blade morbidity;
7 grades: sword-like leave blade and following leaf sheath thereof, blade morbidity;
9 grades: complete stool morbidity, withered ahead of time.
(2) control time and number of times
Test is investigated 3 times altogether, i.e. disease index investigation before medicine, preventive effect investigation in 10 days after the 1st medicine, 10 days and preventive effect investigation in 20 days after 2 medicines.
(3) drug effect computational methods
The total number of sheets × 100 of sick leaf rate (%)=sick number of sheets/investigate
Disease index=∑ (the sick number of sheets × relative level numerical value at different levels)/(investigating the total number of sheets × 9) × 100
Control efficiency (%)=(disease index after the front disease index × treatment region medicine of 1-(blank district medicine)/(the front disease index of disease index × treatment region medicine after blank district medicine)) × 100
(4) poisoning investigation method
After dispenser, whether 7d range estimation medicament has poisoning to crop continuously.
(5) experimental result and analysis
The each group of table 1 test medicine is processed the test effect of control wheat leaf blight
As can be seen from Table 1, the effect of the mixture combination control wheat leaf blight that the ratio of weight and number of 26%imicyafos ZEN 90160 is 10: 16 is very remarkable, and effect is significantly better than single dose, and its quick-acting and lasting effect are all relatively good, especially outstanding with lasting effect.Complex preparation control efficiency under the consumption of high concentration is significantly better than the effect under low concentration consumption.After the 1st, 2 medicines the best control efficiency of 10 days reach respectively 88.89% and 91.49%, the 2 medicine after 20 days best preventive effects reach 91.80%.And 20 days best preventive effects are 85.55% after the 2nd medicine of single dose 25% ZEN 90160 SC, the effect of complex preparation is significantly better than single dose.According to field range estimation, substantially there is no insect pest with the wheat of 26%imicyafos ZEN 90160, and growth fraction is more vigorous, and the wheat of 25% ZEN 90160 single dose occurs that insect pest is more, than much approximately 15% left and right of insect pest plant of use complex preparation.
Within the scope of test dose, plant growth is normal in addition, and the poisoning phenomenon to wheat does not all appear in each treatment agent, illustrates that it is safe to wheat.
Claims (5)
1. a Fungicidal insecticidal composition that contains ZEN 90160, it is characterized in that: this Fungicidal insecticidal composition is take A novel agrochemical Imicyafos and B ZEN 90160 as two yuan of composite composite preparations of active ingredient, all the other components are usual auxiliaries in agricultural chemicals, and the structural formula of A novel agrochemical Imicyafos is as follows:
In this Fungicidal insecticidal composition, the ratio of weight and number of effective constituents A and B is 1～50: 50～1.
2. a kind of Fungicidal insecticidal composition that contains ZEN 90160 according to claim 1, is characterized in that: in this Fungicidal insecticidal composition, the ratio of weight and number of effective constituents A and B is 3～25: 25～5.
3. a kind of Fungicidal insecticidal composition that contains ZEN 90160 according to claim 1, is characterized in that: in this Fungicidal insecticidal composition, to account for the portion rate of gross weight in preparation be 1%～80% for effective constituents A and B gross weight.
4. a kind of Fungicidal insecticidal composition that contains ZEN 90160 according to claim 1, is characterized in that: in this Fungicidal insecticidal composition, effective constituents A and B gross weight account for the portion rate of gross weight in preparation and be preferably 5%～35%.
5. a kind of Fungicidal insecticidal composition that contains ZEN 90160 according to claim 1, is characterized in that: the preparation formulation that insecticidal and bactericidal composition of the present invention can be mixed with is wetting powder, suspending agent, microemulsion, aqueous emulsion and water dispersible granules.
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| CN108029749A (en) * | 2017-12-06 | 2018-05-15 | 宁波市农业科学研究院 | A kind of honey peach method for storing and refreshing |
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