CN103651561B - A kind of Fungicidal insecticidal composition containing fenhexamid - Google Patents
A kind of Fungicidal insecticidal composition containing fenhexamid Download PDFInfo
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- CN103651561B CN103651561B CN201310746315.6A CN201310746315A CN103651561B CN 103651561 B CN103651561 B CN 103651561B CN 201310746315 A CN201310746315 A CN 201310746315A CN 103651561 B CN103651561 B CN 103651561B
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- fenhexamid
- insecticidal composition
- imicyafos
- composition containing
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- 229940082509 xanthan gum Drugs 0.000 description 1
Abstract
The present invention relates to a kind of Fungicidal insecticidal composition containing cyflufenamid, its effective ingredient is Imicyafos and two yuan of mixtures of cyflufenamid, and the ratio of weight and number of two kinds of effective ingredient is 1～50: 1～50, and preferred weight portion rate is 3～25: 5～25；The parts by weight content that in insecticidal and bactericidal composition, effective ingredient is total is 1%～80%, preferred weight number content is 5%～35%, remaining is to allow in pesticide to use and acceptable auxiliary element, wettable powder, suspending agent, microemulsion, aqueous emulsion and water dispersible granules can be prepared as by known method, Fungicidal insecticidal composition of the present invention be mainly used in preventing and treating grain, cotton, oil, really, vegetables, the pest and disease damage of crop of flowers.
Description
Technical field
The present invention relates to technical field of pesticide combination, being specifically related to one containing pesticide Imicyafos and fenhexamid is
Two yuan of compounding insecticidal and bactericidal compositions of effective ingredient.
Background technology
Imicyafos (AKD-3088) is a kind of cyanamide heterocyclic Organic substance, and it is by asymmetric organophosphor and nicotinoids
The cyano group Asia imidazolidine of insecticide combines, can be used for Radix Raphani, Radix Dauci Sativae, Fructus Fragariae Ananssae, Fructus Solani melongenae, Fructus Lycopersici esculenti, Fructus Cucumidis sativi, Fructus Melo, Citrullus vulgaris, kind
The crop such as potato and Rhizoma Solani tuber osi, its chemical structural formula is:
。
Fenhexamid is a kind of ergosterol synthetic inhibitor compounds, and sterol is not only the important of nearly all biology
Living matter, and the sterol structure of dissimilar biology and component are the most each otherwise varied, different organism sterol biosynthesis
The difference of approach, provides probability for exploitation selectivity SBI.It is currently known SBI and not only contains different chemical structures type
Derivant, as pyridines, miazines, imidazoles, triazole type, piperazines, piperidines, morpholine class, polyene macrolides and
The compounds such as propylamine, and SBI has different action sites in sterol biosynthesis approach.
Insecticide or antibacterial, insect or pathogenic bacteria that life-time service is single are easy to develop immunity to drugs, and make pesticide dosage increase
Add, cause the adverse consequencess such as high poison, consumption are big, residual is many, drug effect difference, and effect field is more single.The different mechanisms of action
And the insecticide of no interactions resistance and antibacterial rational mixture by a certain percentage, crop disease prevention effect can be improved, reduce dosage,
Residual is few, reduces environmental pollution, effectively reduces the Drug resistance of crop.
Summary of the invention
According to the deficiencies in the prior art, the present invention proposes a kind of Fungicidal insecticidal composition containing fenhexamid, this group
Compound contains two kinds of effective active components of A, B, and component A selects novel pesticide Imicyafos, B be selected from fenhexamid, of the present invention group
It is wide that compound has effect field, can sterilize again by parasite killing, and consumption is few, and preventive effect is high, and residual is few, and the lasting period is long, beneficially ring
Border is protected.
The present invention is a kind of to carry out the killing of two yuan mixtures with fenhexamid for effective ingredient with novel pesticide Imicyafos
Worm bactericidal composition preparation, wherein effective ingredient novel pesticide Imicyafos and ring in the insecticidal and bactericidal composition of the present invention
The ratio of weight and number of acyl bacterium amine is 1～50: 50～1, on the basis of test recipe targetedly screens, and can be new by effective ingredient
Type insecticide Imicyafos is preferably 3～25: 25～5 with the ratio of weight and number of fenhexamid.
The formulations of pesticide that the preparation method of the agricultural insecticide bactericidal composition field of pesticide preparation of the present invention can be prepared as
For wettable powder, suspending agent, microemulsion, aqueous emulsion and water dispersible granules, in preparation, effective ingredient gross weight accounts in preparation total
The portion rate of weight is 1%～80%, and on the basis of test recipe targetedly screens, in preparation, effective ingredient gross weight accounts for
In preparation, the portion rate of gross weight is 3%～35%, and remaining is usual auxiliaries in pesticide.
When above-described Pesticidal combination is microemulsion, in preparation, the ratio of weight and number of each component is:
Imicyafos 1～50 parts
Fenhexamid 1～50 parts
Emulsifying agent 5～20 parts
Antifreezing agent 1～8 parts
Stabilizer 1～15 parts
Conventional solvents cosolvent 15～50 parts.
The concrete production stage of this microemulsion is: former medicine imicyafos, fenhexamid cosolvent are completely dissolved, then
Add other compositions such as emulsifying agent, antifreezing agent stabilizer, uniformly mix, be eventually adding water, microemulsion after being sufficiently stirred for, can be made into
Agent.
When above-described Pesticidal combination is wettable powder, in preparation, the ratio of weight and number of each component is:
Active component A 1 ~ 50 part
Active component B 1 ~ 50 part
Dispersant 3 ~ 15 parts
Wetting agent 3 ~ 15 parts
Filler 30 ~ 70 parts.
This concrete procedure of processing of Pesticidal combination wettable powder is: by above-mentioned formula by active component A and active component B
And dispersant, wetting agent and filler mixing, uniform stirring in stirred tank, at mix homogeneously after jet mill,
Make the wettable powder of the present composition.
When above-described Pesticidal combination is suspending agent, in preparation, the ratio of weight and number of each component is:
Active component A 1 ~ 50 part
Active component B 1 ~ 50 part
Dispersant 1～20 parts
Antifreezing agent 1～5 parts
Thickening agent 0.1～10 parts
Defoamer 0.1～5 parts
Water supplies 100 parts.
The concrete production stage of this suspending agent is for first to mix other auxiliary agents, through high speed shear mix homogeneously, adds effectively
Component A and active component B, abrading-ball 2 ~ 3 hours in ball crusher, make a diameter all at below 5mm, prepare of the present invention
The aqueous suspension formulations of Pesticidal combination.
When above-described Pesticidal combination is aqueous emulsion, in preparation, the ratio of weight and number of each component is:
Active component A 1 ~ 50 part
Active component B 1 ~ 50 part
Emulsifying agent 3～15 parts
Solvent 1～20 parts
Stabilizer 2～6 parts
Antifreezing agent 1～4 parts
Defoamer 0.1～4 parts
Thickening agent 1～5 parts
Water supplies 100 parts.
The concrete production stage of this aqueous emulsion is: first by former medicine active component A and active component B, solvent and emulsifying agent,
Cosolvent is added together, and makes to be dissolved into uniform oil phase；By part water, antifreeze, other the insecticides adjuvant such as antimicrobial
Mix uniformly aqueous phase；While high-speed stirred, oil phase being added aqueous phase in a kettle., slowly adding water until reaching
To phase inversion point, open cutter and carry out high speed shear, and add remaining water, shear about half an hour, form the water of oil-in-water type
Emulsion.I.e. prepare the aqueous emulsion of Pesticidal combination of the present invention.
When above-described Pesticidal combination is water dispersible granules, in preparation, the ratio of weight and number of each component is:
Active component A 1 ~ 50 part
Active component B 1 ~ 50 part
Dispersant 3 ~ 15 parts
Wetting agent 3 ~ 15 parts
Disintegrating agent 1 ~ 5 part
Filler 30 ~ 70 parts.
This concrete procedure of processing of Pesticidal combination water dispersible granules is: by above-mentioned formula by active component A, active component B
With dispersant, wetting agent, disintegrating agent and filler mix homogeneously, pulverize with micro jet, through mediating, be subsequently adding stream
Change in bed granulating and drying machine carry out pelletize, be dried, after screening through sample analysis, i.e. prepare Pesticidal combination of the present invention
Water dispersible granules.
Described emulsifying agent is selected from calcium dodecyl benzene sulfonate and aliphatic acid polyethenoxy ether, alkylphenol polyoxyethylene sulphur
Base succinate, styrylphenol polyoxyethylene ether, NPE, castor oil polyoxyethylene ether, fatty acid polyglycol
At least one in oxyethylene group ester, polyoxyethylene aliphatic alcohol ether.
Described solvent be dimethylbenzene or biodiesel, toluene, diesel oil, methanol, ethanol, n-butyl alcohol, isopropanol, Oleum Terebinthinae,
At least one in solvent naphtha, dimethylformamide, dimethyl sulfoxide, water equal solvent.
Described dispersant is selected from polycarboxylate, lignosulfonates, alkylphenol polyoxyethylene formaldehyde condensation products sulphuric acid
Salt, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol polyoxyethylene, aliphatic amine polyoxyethylene ether, fat
At least one in acid polyoxyethylene ester, fatty acid glyceride polyoxyethylene ether.
Described wetting agent is selected from sodium lauryl sulphate, calcium dodecyl benzene sulfonate, pulls open powder copper rosinate X., moistening
In penetrating agent F, alkylnaphthalene sulfonate, polyoxyethylene tri-styryl phosphenylic acid salt, spaonin powder, Bombyx mori L., Fructus Sapindi Mukouossi powder at least
A kind of.
Described disintegrating agent is in bentonite, carbamide, ammonium sulfate, aluminum chloride, citric acid, succinic acid, sodium bicarbonate
At least one.
Described thickening agent selected from xanthan gum, hydroxymethyl cellulose, hydroxyethyl cellulose, methylcellulose, Magnesiumaluminumsilicate,
At least one in polyvinyl alcohol.
At least one in sodium citrate, resorcinol of described stabilizer.
At least one in ethylene glycol, propylene glycol, glycerol of described antifreezing agent.
Described defoamer is selected from silicone oil, silicone compound, C10—20Saturated fat acid compounds, C8—10Fatty alcohol
At least one in compounds.
Described filler is in Kaolin, kieselguhr, bentonite, attapulgite, white carbon, starch, precipitated calcium carbonate
At least one.
The agricultural insecticide bactericidal composition of the present invention to grain, cotton, oil, really, vegetables, the multiple fungal disease of flowers be respectively provided with
Favorable effect, especially to the powdery mildew on the corn such as Semen Tritici aestivi, fruit and vegetables, downy mildew, rust, tikka class disease, scab,
Cankers etc. are caused by pathogenic bacteria, have had the preventing and treating of the disease of certain resistance to have excellent to ergosterol class synthetic inhibitor class pesticide
Different preventive effect.The Pesticidal combination of the present invention can prevent and treat nematode, etc. foot class, coleoptera class pest, Lepidoptera class pest, abdominal foot
Class, orthoptera pest, plant parasitic acarid class, Thysanoptera, Diptera pest, Hymenoptera insect, hidden wing mesh insect, louse
The various insects such as mesh insect, Isoptera insect, Hemipteran pest, tide insects, centipede insects, thousand-legger class.Especially at soil
The insect of the seed of the insect of middle destruction agriculture garden crop and trees etc., destruction agriculture garden crop and trees, such as nematicide
Class, etc. foot class, coleoptera class pest, Lepidoptera class pest, gastropod, orthoptera pest, plant parasitic acarid class, Semiptera
Insect preventive effect is notable.
The above nematode pests includes pratylenchus, pseudo-Pratylenchidae, Lu Si Pratylenchidae, disability Pratylenchidae etc.
Pratylenchus class, the Cyst nematode class such as soybean cyst nematode Heterodera glycines, globodera rostochiensis, peanut root-knot nematode, Meloidogyne incognita etc.
Root-knot nematode class, the Aphelenchoidea class such as aphelenchoides besseyi, leaf bud nematicide, species of Tylenchorhynchus Nematodes class, loop wire insects, needlework insects, long
Capsule nematode, burr nematode, nematicide on Fructus Fragariae Ananssae, Bursaphelenchus xylophilus.Additionally to aphid, leafhopper, plant hopper, chrysomelid, wireworm, old
The insects such as tiger, diamondback moth, cabbage butterfly, rice thrips all have favorable effect.
In addition, the insecticidal and bactericidal composition of the present invention compares similar medicament also a lot of other obvious advantage, and first,
Compare single dose sphere of action wider, can parasite killing again can diseases prevention；Second, significantly delay the drug-fast generation of crop, decreased
Pesticide Reusability number of times, reduces Pesticide use amount, reduces agricultural cost；3rd, the residual quantity of this insecticidal and bactericidal composition
Lower, to more environment-friendly；Crops are finally had universal fresh-keeping production-increasing function by the application of this insecticidal and bactericidal composition,
Increasing both production and income to farming region is significant.
Detailed description of the invention:
In order to make the purpose of the present invention, technical scheme and advantage clearer, present invention specific examples below
Illustrate, but the present invention is only limitted to absolutely not these examples.The present invention uses indoor bioassay and field test to combine
Method, if no special instructions, ratio (including percentage ratio) mentioned below is all ratio of weight and number.
Embodiment 1: by imicyafos 15 parts, fenhexamid 15 parts, lignosulfonates 10 parts, sodium lauryl sulphate
12 parts and the mixing of 48 parts of kieselguhr, uniform stirring in stirred tank, at mix homogeneously after jet mill, i.e. prepare the present invention
The wettable powder of Pesticidal combination.
Embodiment 2: by imicyafos 8 parts, fenhexamid 22 parts, alkylphenol polyoxyethylene 12 parts, oxygen ethylene triphen
Vinyl phenyl phosphate 13 parts and bentonite 35 parts mixing, uniform stirring in stirred tank, after jet mill in mixing all
Even, i.e. prepare the wettable powder of Pesticidal combination of the present invention.
Embodiment 3: by imicyafos 20 parts, fenhexamid 10 parts, dispersant 12 parts, wetting agent 12 parts and filler 46 parts
Mixing, uniform stirring in stirred tank, at mix homogeneously after jet mill, i.e. prepare the wettable of Pesticidal combination of the present invention
Property powder.
Embodiment 4: by alkylphenol polyoxyethylene 8 parts, glycerol 2 parts, hydroxymethyl cellulose 3 parts, silicone oil 2 parts, water 55
Part mixing, through high speed shear mix homogeneously, is sequentially added into imicyafos 18 parts, fenhexamid 12 parts, abrading-ball 2 in ball crusher
~ 3 hours, make a diameter all at below 5mm, prepare the aqueous suspension formulations of Pesticidal combination of the present invention.
Embodiment 5: by dispersant 12 parts, antifreezing agent 2 parts, thickening agent 4 parts, defoamer 1 part, the mixing of 46 parts of water, through at a high speed
Shear-mixed is uniform, is sequentially added into imicyafos 25 parts, fenhexamid 10 parts, abrading-ball 2 ~ 3 hours in ball crusher, makes grain straight
Footpath all at below 5mm, prepares the aqueous suspension formulations of Pesticidal combination of the present invention.
Embodiment 6: by dispersant 10 parts, antifreezing agent 2 parts, thickening agent 4 parts, defoamer 1 part, the mixing of 53 parts of water, through at a high speed
Shear-mixed is uniform, is sequentially added into imicyafos 15 parts, fenhexamid 15 parts, abrading-ball 2 ~ 3 hours in ball crusher, makes grain straight
Footpath all at below 5mm, prepares the aqueous suspension formulations of Pesticidal combination of the present invention.
Embodiment 7: by imicyafos5 part, fenhexamid 25 parts, Oleum Terebinthinae 12 parts, castor oil polyoxyethylene ether 5 part,
Benzodiazepines 6 parts mixes, and is dissolved into uniform oil phase；Part water, propylene glycol 2 parts, silicone compound 1 part are blended in
The most uniformly aqueous phase；While high-speed stirred, oil phase is added aqueous phase in a kettle., adds polyvinyl alcohol 4 parts, slowly
Adding water until reaching phase inversion point, opening cutter and carrying out high speed shear, and add remaining water and supply 100 parts, shear about half little
Time, form the aqueous emulsion of oil-in-water type.I.e. prepare the aqueous emulsion of Pesticidal combination of the present invention.
Embodiment 8: imicyafos 30 parts, fenhexamid 5 parts, solvent 22 parts, emulsifying agent 8 parts, stabilizer 12 parts are mixed
It is combined, is dissolved into uniform oil phase；Part water, antifreezing agent 1 part, defoamer 2 parts are mixed uniformly aqueous phase；
While high-speed stirred, oil phase is added aqueous phase in a kettle., adding thickening agent 3 parts, slowly adding water until reaching phase inversion point,
Open cutter and carry out high speed shear, and add remaining water and supply 100 parts, shear about half an hour, form the water of oil-in-water type
Emulsion.I.e. prepare the aqueous emulsion of Pesticidal combination of the present invention.
Embodiment 9: imicyafos16 part, fenhexamid 10 parts, solvent 18 parts, emulsifying agent 10 parts, stabilizer 8 parts are mixed
It is combined, is dissolved into uniform oil phase；Part water, antifreezing agent 1 part, defoamer 2 parts are mixed uniformly aqueous phase；
While high-speed stirred, oil phase is added aqueous phase in a kettle., adding thickening agent 3 parts, slowly adding water until reaching phase inversion point,
Open cutter and carry out high speed shear, and add remaining water and supply 100 parts, shear about half an hour, form the water of oil-in-water type
Emulsion.I.e. prepare the aqueous emulsion of Pesticidal combination of the present invention.
Embodiment 10: by imicyafos 20 parts, fenhexamid 8 parts, aliphatic amine polyoxyethylene ether 8 parts, alkyl naphthalene sulfonic acid
Salt 10 parts, 5 parts of aluminum chloride and 49 parts of mix homogeneously of bentonite, pulverize with micro jet, through mediating, is subsequently adding stream
Change in bed granulating and drying machine carry out pelletize, be dried, after screening through sample analysis, i.e. prepare Pesticidal combination of the present invention
Water dispersible granules.
Embodiment 11: by imicyafos 10 parts, fenhexamid 15 parts, dispersant 10 parts, wetting agent 12 parts, disintegrating agent 5
Part and 51 parts of mix homogeneously of filler, pulverize with micro jet, through mediating, is subsequently adding in fluidized-bed granulation dryer
Carry out pelletize, be dried, screening after through sample analysis, i.e. prepare the water dispersible granules of Pesticidal combination of the present invention.
Embodiment 12: by imicyafos 18 parts, fenhexamid 12 parts, dispersant 10 parts, wetting agent 12 parts, disintegrating agent 3
Part and 45 parts of mix homogeneously of filler, pulverize with micro jet, through mediating, is subsequently adding in fluidized-bed granulation dryer
Carry out pelletize, be dried, screening after through sample analysis, i.e. prepare the water dispersible granules of Pesticidal combination of the present invention.
Embodiment 13: former medicine imicyafos 15 parts, fenhexamid 20 parts are completely dissolved with cosolvent, add fat
Other compositions such as acid polyoxyethylene groups ester 13 parts, ethylene glycol 2 parts, sodium citrate 4 parts, resorcinol 4 parts, uniformly mix, finally
Add water, microemulsion after being sufficiently stirred for, can be made into.
Embodiment 14: former medicine imicyafos 10 parts, fenhexamid 20 parts are completely dissolved with cosolvent, add emulsifying
Other compositions such as agent 11 parts, antifreezing agent 2 parts, stabilizer 7 parts, uniformly mix, are eventually adding water, can be made into micro-after being sufficiently stirred for
Emulsion.
Embodiment 15: former medicine imicyafos 8 parts, fenhexamid 25 parts are completely dissolved with cosolvent, add emulsifying
Other compositions such as agent 9 parts, antifreezing agent 2 parts, stabilizer 11 parts, uniformly mix, are eventually adding water, can be made into micro-after being sufficiently stirred for
Emulsion.
Field experiment: the preventing and treating to Citrus pest and disease damage
(1) investigation method
Experimental field it is located at the 15 years raw Satsuma Orchards in wingceltis village, wingceltis villages and small towns, Jiande City to carry out, often processes and set 4 repetitions, often repeat
10 strains, random alignment, centre sets protection row.Often repeat fixing investigation 4 strains, every strain 10, spring tip of investigation, 60 blades, young fruit 30
Only.Daily using knapsack sprayer to spray tree crown in April 20, May 10, once, medicinal liquid consumption is 120L/667m to each spray medicine2。
Carrying out classification according to citrus anthracnose grade scale, grade scale is:
0 grade: without scab；
1 grade: lesion area accounts for less than the 10% of whole leaf area；
3 grades: lesion area accounts for 11% the 25% of whole leaf area；
5 grades: lesion area accounts for 26% the 40% of whole leaf area；
7 grades: lesion area accounts for 41% the 65% of whole leaf area；
9 grades: lesion area accounts for more than the 65% of whole leaf area.
(2) control time and number of times
Test investigation 3 times altogether, i.e. disease index investigation before medicine, 7 days, the investigation of 10 days preventive effects after the 1st medicine, after 2 medicines 20
It preventive effect is investigated.
(3) drug effect computational methods
Sick leaf rate (%)=sick number of sheets/investigate the total number of sheets × 100
Disease index=∑ (the sick number of sheets × relative level numerical value at different levels)/(investigating the total number of sheets × 9) × 100
Prevention effect (%)=(disease index after disease index × treatment region medicine before 1-(blank district medicine)/(blank
Disease index before disease index × treatment region medicine after district's medicine)) × 100
(4) poisoning investigation method
After dispenser, whether continuous 7d range estimation medicament has poisoning to crop.
(5) experimental result and analysis
Table 1 is respectively organized test medicine and is processed the test effect of preventing and treating citrus anthracnose
As it can be seen from table 1 the mixture that ratio of weight and number is 12: 13 combination of 25% imicyafos fenhexamid is anti-
The effect controlling citrus anthracnose is very notable, and effect is significantly better than single dose, and its quick-acting and lasting effect are relatively good, especially with holding effect
Property is the most prominent.Complex preparation effect under prevention effect is significantly better than low concentration consumption under the consumption of high concentration.At the 1st medicine
Latter 7 days, the optimal prevention effect of 10 days respectively reach 83.51% and 90.51%, after the 2nd medicine, 20 days optimal preventive effects reach
91.16%.And 20 days optimal preventive effects are 81.83% after the 2nd medicine of single dose 25% fenhexamid SC, the effect of complex preparation is the most excellent
In single dose.Estimate according to field, substantially there is no insect pest with the Citrus of 25% imicyafos fenhexamid, and growth fraction is more prosperous
Containing, and the Citrus of 25% fenhexamid single dose occur that insect pest is more, and ratio is with the insect pest plant of complex preparation many about about 15%.
Additionally in the range of test dose, plant growth is normal, and the poisoning phenomenon to Citrus does not all occur in each treatment agent,
Illustrate that it is safe to Citrus.
Claims (4)
1. the Fungicidal insecticidal composition containing fenhexamid, it is characterised in that: this Fungicidal insecticidal composition is with A pesticide
Imicyafos Yu B fenhexamid is two yuan of compounding composite preparations of effective ingredient, and remaining component is usual auxiliaries in pesticide, A
The structural formula of pesticide Imicyafos is as follows:
In this Fungicidal insecticidal composition, effective constituents A is 12: 13 with the ratio of weight and number of B.
A kind of Fungicidal insecticidal composition containing fenhexamid the most according to claim 1, it is characterised in that: this sterilization is killed
In worm compositions, effective constituents A and B gross weight account for the portion rate of gross weight in preparation is 1%～80%.
A kind of Fungicidal insecticidal composition containing fenhexamid the most according to claim 1, it is characterised in that: this sterilization is killed
In worm compositions, effective constituents A and B gross weight account for the portion rate of gross weight in preparation is 5%～35%.
A kind of Fungicidal insecticidal composition containing fenhexamid the most according to claim 1, it is characterised in that: the present invention kills
The preparation formulation that worm bactericidal composition can be configured to is wettable powder, suspending agent, microemulsion, aqueous emulsion and water-dispersible grain
Agent.
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1027670C (en) * | 1990-07-06 | 1995-02-22 | 安哥洛商株式会社 | Organophosphorus compounds, method for preparing same and insecticide, acricides and nematocides |
| CN101209052A (en) * | 2006-12-27 | 2008-07-02 | 石原产业株式会社 | Composition for preventing and controlling tree parasitic pest for tree |
| CN103125485A (en) * | 2011-12-03 | 2013-06-05 | 深圳诺普信农化股份有限公司 | Sterilization composition containing fenhexamid |
| CN103429086A (en) * | 2012-07-03 | 2013-12-04 | 石原产业株式会社 | Insect-killing composition and insect prevention method |
| CN103734181A (en) * | 2013-12-30 | 2014-04-23 | 孙蒙蒙 | Cyflufenamid-contained bactericidal and insecticidal composition |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003081987A (en) * | 2001-09-06 | 2003-03-19 | Agro Kanesho Co Ltd | Imidazolidine derivative containing optically active organophosphorus group, method for producing the same and noxious animal controller containing the same as active ingredient |
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2013
- 2013-12-30 CN CN201310746315.6A patent/CN103651561B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1027670C (en) * | 1990-07-06 | 1995-02-22 | 安哥洛商株式会社 | Organophosphorus compounds, method for preparing same and insecticide, acricides and nematocides |
| CN101209052A (en) * | 2006-12-27 | 2008-07-02 | 石原产业株式会社 | Composition for preventing and controlling tree parasitic pest for tree |
| CN103125485A (en) * | 2011-12-03 | 2013-06-05 | 深圳诺普信农化股份有限公司 | Sterilization composition containing fenhexamid |
| CN103429086A (en) * | 2012-07-03 | 2013-12-04 | 石原产业株式会社 | Insect-killing composition and insect prevention method |
| CN103734181A (en) * | 2013-12-30 | 2014-04-23 | 孙蒙蒙 | Cyflufenamid-contained bactericidal and insecticidal composition |
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