CN103651562B - A kind of Fungicidal insecticidal composition containing prothioconazoles - Google Patents
A kind of Fungicidal insecticidal composition containing prothioconazoles Download PDFInfo
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- CN103651562B CN103651562B CN201310746484.XA CN201310746484A CN103651562B CN 103651562 B CN103651562 B CN 103651562B CN 201310746484 A CN201310746484 A CN 201310746484A CN 103651562 B CN103651562 B CN 103651562B
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- prothioconazoles
- insecticidal composition
- fungicidal insecticidal
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Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a kind of Fungicidal insecticidal composition containing prothioconazoles, its effective ingredient is Imicyafos and two yuan of mixtures of prothioconazoles, and the ratio of weight and number of two kinds of effective ingredient is 1～50: 1～50, and preferred weight portion rate is 3～25: 5～25；The parts by weight content that in insecticidal and bactericidal composition, effective ingredient is total is 1%～80%, preferred weight number content is 5%～35%, remaining is to allow in pesticide to use and acceptable auxiliary element, wettable powder, suspending agent, microemulsion, aqueous emulsion and water dispersible granules can be prepared as by known method, Fungicidal insecticidal composition of the present invention be mainly used in preventing and treating grain, cotton, oil, really, vegetables, the pest and disease damage of crop of flowers.
Description
Technical field
The present invention relates to technical field of pesticide combination, being specifically related to a kind of is two yuan of compounding insecticidal and bactericidal compositions of effective ingredient containing pesticide Imicyafos and prothioconazoles.
Background technology
Imicyafos (AKD-3088) is a kind of cyanamide heterocyclic Organic substance, it is combined by the cyano group Asia imidazolidine of asymmetric organophosphor with nicotinic insecticide, can be used for the crops such as Radix Raphani, Radix Dauci Sativae, Fructus Fragariae Ananssae, Fructus Solani melongenae, Fructus Lycopersici esculenti, Fructus Cucumidis sativi, Fructus Melo, Citrullus vulgaris, Ipomoea batatas Lam. and Rhizoma Solani tuber osi, its chemical structural formula is:
Prothioconazoles is a kind of ergosterol synthetic inhibitor compounds, sterol is not only the important living matter of nearly all biology, and the sterol structure of dissimilar biology and component are the most each otherwise varied, the difference of different organism sterol biosynthesis approach, provides probability for exploitation selectivity SBI.It is currently known SBI and not only contains the derivant of different chemical structures type, such as compounds such as pyridines, miazines, imidazoles, triazole type, piperazines, piperidines, morpholine class, polyene macrolides and propylamines, and SBI has different action sites in sterol biosynthesis approach.
Insecticide or antibacterial, insect or pathogenic bacteria that life-time service is single are easy to develop immunity to drugs, and make pesticide dosage increase, and cause the adverse consequencess such as high poison, consumption are big, residual is many, drug effect difference, and effect field is more single.The different mechanisms of action and the insecticide of no interactions resistance and antibacterial rational mixture by a certain percentage, crop disease prevention effect can be improved, reduce dosage, residual is few, reduces environmental pollution, effectively reduces the Drug resistance of crop.
Summary of the invention
According to the deficiencies in the prior art; the present invention proposes a kind of Fungicidal insecticidal composition containing prothioconazoles, and said composition contains two kinds of effective active components of A, B, and component A selects novel pesticide Imicyafos; B is selected from prothioconazoles; it is wide that the present composition has effect field, can sterilize again by parasite killing, and consumption is few; preventive effect is high; residual is few, and the lasting period is long, beneficially environmental conservation.
The present invention is a kind of insecticidal and bactericidal composition preparation carrying out two yuan of mixtures with novel pesticide Imicyafos and prothioconazoles for effective ingredient, wherein in the insecticidal and bactericidal composition of the present invention, the ratio of weight and number of effective ingredient novel pesticide Imicyafos and prothioconazoles is 1～50: 50～1, on the basis of test recipe targetedly screens, the ratio of weight and number of effective ingredient novel pesticide Imicyafos Yu prothioconazoles can be preferably 3～25: 25～5.
The formulations of pesticide that the preparation method of the agricultural insecticide bactericidal composition field of pesticide preparation of the present invention can be prepared as are wettable powder, suspending agent, microemulsion, aqueous emulsion and water dispersible granules, in preparation, effective ingredient gross weight accounts for the portion rate of gross weight in preparation is 1%～80%, on the basis of test recipe targetedly screens, in preparation, effective ingredient gross weight accounts for the portion rate of gross weight in preparation is 3%～35%, and remaining is usual auxiliaries in pesticide.
When above-described Pesticidal combination is microemulsion, in preparation, the ratio of weight and number of each component is:
The concrete production stage of this microemulsion is: former medicine imicyafos, prothioconazoles cosolvent are completely dissolved, and adds other compositions such as emulsifying agent, antifreezing agent stabilizer, uniformly mixes, be eventually adding water, can be made into microemulsion after being sufficiently stirred for.
When above-described Pesticidal combination is wettable powder, in preparation, the ratio of weight and number of each component is:
This concrete procedure of processing of Pesticidal combination wettable powder is: by above-mentioned formula by active component A and active component B and dispersant, wetting agent and filler mixing, uniform stirring in stirred tank, at mix homogeneously after jet mill, i.e. can be made into the wettable powder of the present composition.
When above-described Pesticidal combination is suspending agent, in preparation, the ratio of weight and number of each component is:
The concrete production stage of this suspending agent is for first to mix other auxiliary agents, through high speed shear mix homogeneously, add active component A and active component B, abrading-ball 2～3 hours in ball crusher, make a diameter all at below 5mm, prepare the aqueous suspension formulations of Pesticidal combination of the present invention.
When above-described Pesticidal combination is aqueous emulsion, in preparation, the ratio of weight and number of each component is:
The concrete production stage of this aqueous emulsion is: first former medicine active component A and active component B, solvent and emulsifying agent, cosolvent is added together, makes to be dissolved into uniform oil phase；By part water, antifreeze, other the insecticides adjuvant such as antimicrobial mixes uniformly aqueous phase；While high-speed stirred, oil phase being added aqueous phase in a kettle., slowly adding water until reaching phase inversion point, open cutter and carry out high speed shear, and add remaining water, shear about half an hour, form the aqueous emulsion of oil-in-water type.I.e. prepare the aqueous emulsion of Pesticidal combination of the present invention.
When above-described Pesticidal combination is water dispersible granules, in preparation, the ratio of weight and number of each component is:
This concrete procedure of processing of Pesticidal combination water dispersible granules is: by above-mentioned formula by active component A, active component B and dispersant, wetting agent, disintegrating agent and filler mix homogeneously, pulverize with micro jet, through mediating, be subsequently adding in fluidized-bed granulation dryer carry out pelletize, be dried, screening after through sample analysis, i.e. prepare the water dispersible granules of Pesticidal combination of the present invention.
At least one in calcium dodecyl benzene sulfonate with aliphatic acid polyethenoxy ether, alkylphenol polyoxyethylene sulfosuccinate, styrylphenol polyoxyethylene ether, NPE, castor oil polyoxyethylene ether, aliphatic acid polyethenoxy base ester, polyoxyethylene aliphatic alcohol ether of described emulsifying agent.
Described solvent is at least one in dimethylbenzene or biodiesel, toluene, diesel oil, methanol, ethanol, n-butyl alcohol, isopropanol, Oleum Terebinthinae, solvent naphtha, dimethylformamide, dimethyl sulfoxide, water equal solvent.
At least one in polycarboxylate, lignosulfonates, alkylphenol polyoxyethylene formaldehyde condensation products sulfate, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol polyoxyethylene, aliphatic amine polyoxyethylene ether, polyoxyethylene carboxylate, fatty acid glyceride polyoxyethylene ether of described dispersant.
Described wetting agent selected from sodium lauryl sulphate, calcium dodecyl benzene sulfonate, pull open in powder copper rosinate X., wetting and penetrating agent F, alkylnaphthalene sulfonate, polyoxyethylene tri-styryl phosphenylic acid salt, spaonin powder, Bombyx mori L., Fructus Sapindi Mukouossi powder at least one.
At least one in bentonite, carbamide, ammonium sulfate, aluminum chloride, citric acid, succinic acid, sodium bicarbonate of described disintegrating agent.
At least one in xanthan gum, hydroxymethyl cellulose, hydroxyethyl cellulose, methylcellulose, Magnesiumaluminumsilicate, polyvinyl alcohol of described thickening agent.
At least one in sodium citrate, resorcinol of described stabilizer.
At least one in ethylene glycol, propylene glycol, glycerol of described antifreezing agent.
At least one in silicone oil, silicone compound, C10 20 saturated fat acid compounds, C8 10 aliphatic alcohols compound of described defoamer.
At least one in Kaolin, kieselguhr, bentonite, attapulgite, white carbon, starch, precipitated calcium carbonate of described filler.
The agricultural insecticide bactericidal composition of the present invention to grain, cotton, oil, really, vegetables, the multiple fungal disease of flowers be respectively provided with favorable effect, especially the powdery mildew on the corn such as Semen Tritici aestivi, fruit and vegetables, downy mildew, rust, tikka class disease, scab, canker etc. are caused by pathogenic bacteria, had ergosterol class synthetic inhibitor class pesticide the preventing and treating of the disease of certain resistance to have excellent preventive effect.The Pesticidal combination of the present invention can prevent and treat nematode, etc. foot class, coleoptera class pest, Lepidoptera class pest, gastropod, orthoptera pest, plant parasitic acarid class, Thysanoptera, Diptera pest, Hymenoptera insect, hidden wing mesh insect, Anoplura insect, Isoptera insect, Hemipteran pest, the tide various insects such as insects, centipede insects, thousand-legger class.Especially to destroying the insect of agriculture garden crop and trees etc. in soil, destroying the insect of the seed of agriculture garden crop and trees, such as nematode, etc. foot class, coleoptera class pest, Lepidoptera class pest, gastropod, orthoptera pest, plant parasitic acarid class, Hemipteran pest preventive effect notable.
The above nematode pests includes the pratylenchus class such as pratylenchus, pseudo-Pratylenchidae, Lu Si Pratylenchidae, disability Pratylenchidae, the Cyst nematode class such as soybean cyst nematode Heterodera glycines, globodera rostochiensis, the root-knot nematode class such as peanut root-knot nematode, Meloidogyne incognita, the Aphelenchoidea class such as aphelenchoides besseyi, leaf bud nematicide, species of Tylenchorhynchus Nematodes class, loop wire insects, needlework insects, long capsule nematode, burr nematode, nematicide on Fructus Fragariae Ananssae, Bursaphelenchus xylophilus.Additionally the insects such as aphid, leafhopper, plant hopper, chrysomelid, wireworm, cutworm, diamondback moth, cabbage butterfly, rice thrips all there is favorable effect.
In addition, the insecticidal and bactericidal composition of the present invention compares similar medicament also a lot of other obvious advantage, first, compare single dose sphere of action wider, can parasite killing again can diseases prevention；Second, significantly delay the drug-fast generation of crop, decreased pesticide Reusability number of times, reduce Pesticide use amount, reduce agricultural cost；3rd, the residual quantity of this insecticidal and bactericidal composition is lower, to more environment-friendly；Finally have universal fresh-keeping production-increasing function in the application of this insecticidal and bactericidal composition to crops, the increasing both production and income to farming region is significant.
Detailed description of the invention:
In order to make the purpose of the present invention, technical scheme and advantage clearer, present invention specific examples below illustrates, but the present invention is only limitted to absolutely not these examples.The present invention uses the method that indoor bioassay and field test combine, and if no special instructions, ratio (including percentage ratio) mentioned below is all ratio of weight and number.
Embodiment 1: by imicyafos10 part, prothioconazoles 10 parts, lignosulfonates 8 parts, sodium lauryl sulphate 12 parts and the mixing of 60 parts of kieselguhr, uniform stirring in stirred tank, at mix homogeneously after jet mill, i.e. prepare the wettable powder of Pesticidal combination of the present invention.
Embodiment 2: by imicyafos5 part, prothioconazoles 15 parts, alkylphenol polyoxyethylene 8 parts, oxygen ethylene triphenylethylene phosphenylic acid salt 15 parts and bentonite 67 parts mixing, uniform stirring in stirred tank, at mix homogeneously after jet mill, i.e. prepare the wettable powder of Pesticidal combination of the present invention.
Embodiment 3: by imicyafos6 part, prothioconazoles 20 parts, dispersant 10 parts, wetting agent 12 parts and filler 52 parts mixing, uniform stirring in stirred tank, at mix homogeneously after jet mill, i.e. prepare the wettable powder of Pesticidal combination of the present invention.
Embodiment 4: by alkylphenol polyoxyethylene 8 parts, glycerol 1 part, hydroxymethyl cellulose 4 parts, silicone oil 1 part, the mixing of 66 parts of water, through high speed shear mix homogeneously, it is sequentially added into imicyafos15 part, prothioconazoles 5 parts, abrading-ball 2～3 hours in ball crusher, make a diameter all at below 5mm, prepare the aqueous suspension formulations of Pesticidal combination of the present invention.
Embodiment 5: by dispersant 12 parts, antifreezing agent 2 parts, thickening agent 3 parts, defoamer 1 part, the mixing of 57 parts of water, through high speed shear mix homogeneously, it is sequentially added into imicyafos20 part, prothioconazoles 5 parts, abrading-ball 2～3 hours in ball crusher, make a diameter all at below 5mm, prepare the aqueous suspension formulations of Pesticidal combination of the present invention.
Embodiment 6: by dispersant 10 parts, antifreezing agent 2 parts, thickening agent 4 parts, defoamer 1 part, the mixing of 55 parts of water, through high speed shear mix homogeneously, it is sequentially added into imicyafos8 part, prothioconazoles 20 parts, abrading-ball 2～3 hours in ball crusher, make a diameter all at below 5mm, prepare the aqueous suspension formulations of Pesticidal combination of the present invention.
Embodiment 7: imicyafos10 part, prothioconazoles 15 parts, Oleum Terebinthinae 12 parts, castor oil polyoxyethylene ether 5 parts, resorcinol 8 parts are mixed, is dissolved into uniform oil phase；Part water, propylene glycol 2 parts, silicone compound 2 parts are mixed uniformly aqueous phase；While high-speed stirred, oil phase is added aqueous phase in a kettle., adding polyvinyl alcohol 4 parts, slowly adding water until reaching phase inversion point, open cutter and carry out high speed shear, and add remaining water and supply 100 parts, shear about half an hour, form the aqueous emulsion of oil-in-water type.I.e. prepare the aqueous emulsion of Pesticidal combination of the present invention.
Embodiment 8: imicyafos25 part, prothioconazoles 5 parts, solvent 20 parts, emulsifying agent 8 parts, stabilizer 10 parts are mixed, is dissolved into uniform oil phase；Part water, antifreezing agent 1 part, defoamer 2 parts are mixed uniformly aqueous phase；While high-speed stirred, oil phase is added aqueous phase in a kettle., adding thickening agent 3 parts, slowly adding water until reaching phase inversion point, open cutter and carry out high speed shear, and add remaining water and supply 100 parts, shear about half an hour, form the aqueous emulsion of oil-in-water type.I.e. prepare the aqueous emulsion of Pesticidal combination of the present invention.
Embodiment 9: imicyafos12 part, prothioconazoles 15 parts, solvent 18 parts, emulsifying agent 11 parts, stabilizer 8 parts are mixed, is dissolved into uniform oil phase；Part water, antifreezing agent 1 part, defoamer 2 parts are mixed uniformly aqueous phase；While high-speed stirred, oil phase is added aqueous phase in a kettle., adding thickening agent 3 parts, slowly adding water until reaching phase inversion point, open cutter and carry out high speed shear, and add remaining water and supply 100 parts, shear about half an hour, form the aqueous emulsion of oil-in-water type.I.e. prepare the aqueous emulsion of Pesticidal combination of the present invention.
Embodiment 10: by imicyafos25 part, prothioconazoles 5 parts, aliphatic amine polyoxyethylene ether 11 parts, alkylnaphthalene sulfonate 12 parts, 5 parts of aluminum chloride and 42 parts of mix homogeneously of bentonite, pulverize with micro jet, through mediating, be subsequently adding in fluidized-bed granulation dryer carry out pelletize, be dried, screening after through sample analysis, i.e. prepare the water dispersible granules of Pesticidal combination of the present invention.
Embodiment 11: by imicyafos20 part, prothioconazoles 10 parts, dispersant 12 parts, wetting agent 10 parts, disintegrating agent 5 parts and 43 parts of mix homogeneously of filler, pulverize with micro jet, through mediating, be subsequently adding in fluidized-bed granulation dryer carry out pelletize, be dried, screening after through sample analysis, i.e. prepare the water dispersible granules of Pesticidal combination of the present invention.
Embodiment 12: by imicyafos10 part, prothioconazoles 16 parts, dispersant 8 parts, wetting agent 12 parts, disintegrating agent 3 parts and 51 parts of mix homogeneously of filler, pulverize with micro jet, through mediating, be subsequently adding in fluidized-bed granulation dryer carry out pelletize, be dried, screening after through sample analysis, i.e. prepare the water dispersible granules of Pesticidal combination of the present invention.
Embodiment 13: former medicine imicyafos15 part, prothioconazoles 5 parts are completely dissolved with cosolvent, add other compositions such as aliphatic acid polyethenoxy base ester 10 parts, ethylene glycol 2 parts, sodium citrate 4 parts, resorcinol 4 parts, uniformly mixing, is eventually adding water, can be made into microemulsion after being sufficiently stirred for.
Embodiment 14: former medicine imicyafos10 part, prothioconazoles 15 parts are completely dissolved with cosolvent, adds other compositions such as emulsifying agent 11 parts, antifreezing agent 2 parts, stabilizer 7 parts, uniformly mixes, be eventually adding water, can be made into microemulsion after being sufficiently stirred for.
Embodiment 15: former medicine imicyafos8 part, prothioconazoles 22 parts are completely dissolved with cosolvent, adds other compositions such as emulsifying agent 8 parts, antifreezing agent 2 parts, stabilizer 10 parts, uniformly mixes, be eventually adding water, can be made into microemulsion after being sufficiently stirred for.
Field experiment: the preventing and treating to Cucumber Pests And Diseases.
(1) investigation method
Field test is each provided at the Fructus Cucumidis sativi ground in Li Tai township, Yangling district of Shaanxi Province, and in Cucurbita pepo L. booth, 5 points, every some investigation 2 strains are investigated in every community, record occurring degree by staging, and grade scale is as follows:
0 grade: without scab；
1 grade: lesion area accounts for less than the 5% of whole leaf area；
3 grades: lesion area accounts for whole leaf area 6%～10%；
5 grades: lesion area accounts for the 11%～25% of whole leaf area；
7 grades: lesion area accounts for the 26%～50% of whole leaf area；
9 grades: lesion area accounts for more than the 50% of whole leaf area.
(2) control time and number of times
Test investigation 3 times altogether, i.e. disease index investigation before medicine, preventive effect investigation in 7 days after the 1st medicine, 7 days and preventive effect investigation in 15 days after 2 medicines.
(3) drug effect computational methods
Sick leaf rate (%)=sick number of sheets/investigate the total number of sheets × 100
Disease index=∑ (the sick number of sheets × relative level numerical value at different levels)/(investigating the total number of sheets × 9) × 100
Prevention effect (%)=(disease index after disease index × treatment region medicine before 1-(blank district medicine)/(disease index before disease index × treatment region medicine after blank district medicine)) × 100
(4) poisoning investigation method
After dispenser, whether continuous 7d range estimation medicament has poisoning to crop.
(5) result of the test and analysis
Table 1 respectively processes the effect preventing and treating powdery mildew of cucumber
As it can be seen from table 1 the effect that the mixture combination that the ratio of weight and number of 26%imicyafos prothioconazoles is 10: 16 prevents and treats powdery mildew of cucumber is very notable, effect is significantly better than single dose, and its quick-acting and lasting effect are relatively good, especially the most prominent with lasting effect.Complex preparation effect under prevention effect is significantly better than low concentration consumption under the consumption of high concentration.After the 1st medicine 7 days, the optimal prevention effect of 7 days respectively reaches 89.52% and 91.44% after the 2nd medicine, after the 2nd medicine, 15 days optimal preventive effects reach 90.53%.And 15 days optimal preventive effects are 81.21% after the 2nd medicine of single dose 25% prothioconazoles SC, the effect of complex preparation is significantly better than single dose.Estimating according to field, substantially do not have insect pest with the Fructus Cucumidis sativi of 26%imicyafos prothioconazoles, and growth fraction is more vigorous, and the Fructus Cucumidis sativi of 25% prothioconazoles single dose occurs that insect pest is more, ratio is with the insect pest plant of complex preparation many about about 15%.
Additionally in the range of test dose, plant growth is normal, and the poisoning phenomenon to Fructus Cucumidis sativi does not all occur in each treatment agent, illustrates that it is safe to Fructus Cucumidis sativi.
Claims (4)
1. the Fungicidal insecticidal composition containing prothioconazoles, it is characterized in that: this Fungicidal insecticidal composition is with A pesticide Imicyafos and B prothioconazoles for two yuan of compounding composite preparations of effective ingredient, remaining component is usual auxiliaries in pesticide, and the structural formula of A pesticide Imicyafos is as follows:, in this Fungicidal insecticidal composition, effective constituents A is 10: 16 with the ratio of weight and number of B.
A kind of Fungicidal insecticidal composition containing prothioconazoles the most according to claim 1, it is characterised in that: in this Fungicidal insecticidal composition, effective constituents A and B gross weight account for the portion rate of gross weight in preparation is 1%～80%.
A kind of Fungicidal insecticidal composition containing prothioconazoles the most according to claim 1, it is characterised in that: in this Fungicidal insecticidal composition, effective constituents A and B gross weight account for the portion rate of gross weight in preparation is 5%～35%.
A kind of Fungicidal insecticidal composition containing prothioconazoles the most according to claim 1, it is characterised in that: the preparation formulation that this insecticidal and bactericidal composition can be configured to is wettable powder, suspending agent, microemulsion, aqueous emulsion and water dispersible granules.
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Citations (4)
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| CN1027670C (en) * | 1990-07-06 | 1995-02-22 | 安哥洛商株式会社 | Organophosphorus compounds, method for preparing same and insecticide, acricides and nematocides |
| CN101209052A (en) * | 2006-12-27 | 2008-07-02 | 石原产业株式会社 | Composition for preventing and controlling tree parasitic pest for tree |
| CN102258043A (en) * | 2011-08-18 | 2011-11-30 | 陕西美邦农药有限公司 | Germicide composition containing protioconazole |
| CN103429086A (en) * | 2012-07-03 | 2013-12-04 | 石原产业株式会社 | Insect-killing composition and insect prevention method |
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| JP2003081987A (en) * | 2001-09-06 | 2003-03-19 | Agro Kanesho Co Ltd | Imidazolidine derivative containing optically active organophosphorus group, method for producing the same and noxious animal controller containing the same as active ingredient |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1027670C (en) * | 1990-07-06 | 1995-02-22 | 安哥洛商株式会社 | Organophosphorus compounds, method for preparing same and insecticide, acricides and nematocides |
| CN101209052A (en) * | 2006-12-27 | 2008-07-02 | 石原产业株式会社 | Composition for preventing and controlling tree parasitic pest for tree |
| CN102258043A (en) * | 2011-08-18 | 2011-11-30 | 陕西美邦农药有限公司 | Germicide composition containing protioconazole |
| CN103429086A (en) * | 2012-07-03 | 2013-12-04 | 石原产业株式会社 | Insect-killing composition and insect prevention method |
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