CN103651562A - Sterilization insecticidal combination containing prothioconazole - Google Patents
Sterilization insecticidal combination containing prothioconazole Download PDFInfo
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- CN103651562A CN103651562A CN201310746484.XA CN201310746484A CN103651562A CN 103651562 A CN103651562 A CN 103651562A CN 201310746484 A CN201310746484 A CN 201310746484A CN 103651562 A CN103651562 A CN 103651562A
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- insecticidal composition
- prothioconazoles
- fungicidal insecticidal
- insecticidal combination
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a sterilization insecticidal combination containing prothioconazole. The effective ingredients of the sterilization insecticidal combination are obtained through blending Imicyafos and the prothioconazole, the weight part ratio of the two effective ingredients is (1-50):(1-50) and is preferably (3-25):(5-25), the weight part content of the effective ingredients in the sterilization insecticidal combination is 1 percent to 80 percent and is preferably 5 percent to 35 percent, the rest is acceptable auxiliary ingredients permitted to be used in pesticides, and the sterilization insecticidal combination can be prepared into wettable powder, suspending agents, microemulsion, aqueous emulsion and water dispersible granules by the existing method. The sterilization insecticidal combination is mainly used for preventing and treating crop diseases and insect pests of grain, cotton, oil, fruit, vegetables and flowers.
Description
Technical field
The present invention relates to agriculture chemical compounding technical field, be specifically related to a kind ofly contain agricultural chemicals Imicyafos and prothioconazoles is two yuan of composite insecticidal and bactericidal compositions of active ingredient.
Background technology
Imicyafos (AKD-3088) is a kind of cyanamide heterocyclic organic matter, it is combined by the sub-imidazolidine of cyano group of asymmetric organic phosphor and nicotinic insecticide, can be used for the crops such as radish, carrot, strawberry, eggplant, tomato, cucumber, muskmelon, watermelon, sweet potato and potato, its chemical structural formula is:
Prothioconazoles is a kind of ergosterol synthetic inhibitor compounds, sterol is not only the important living matter of nearly all biology, and the sterol structure of dissimilar biology and also each difference to some extent of component, the difference of different organism sterol biosynthesis approach, for exploitation selectivity, SBI provides possibility.Current known SBI has not only comprised the derivative of different chemical structures type, as compounds such as pyridines, miazines, imidazoles, triazole type, piperazines, piperidines, morpholine class, polyene macrolides and propylamines, and SBI has different action sites in sterol biosynthesis approach.
Long-term use single insecticide or bactericide, insect or germ are easy to develop immunity to drugs, and pesticide dosage is increased, and cause large, residual many, the adverse consequences such as drug effect is poor of high poison, consumption, and effect field are more single.The different mechanisms of action and without the insecticide of cross resistance and bactericide rational mixture by a certain percentage, can improve crop disease prevention effect, reduce dosage, residual few, minimizing environmental pollution, effectively reduces the pesticide resistance of crop.
Summary of the invention
According to the deficiencies in the prior art; the present invention proposes a kind of Fungicidal insecticidal composition that contains prothioconazoles, said composition contains A, two kinds of effective active components of B, and component A selects novel pesticide Imicyafos; B is selected from prothioconazoles; it is wide that the present composition has effect field, can desinsection again can sterilization, and consumption is few; preventive effect is high; residual few, the lasting period is long, is conducive to environmental protection.
The present invention a kind ofly be take novel pesticide Imicyafos and prothioconazoles and is carried out two yuan of insecticidal and bactericidal composition preparations that are mixed as active ingredient, wherein in insecticidal and bactericidal composition of the present invention, the ratio of weight and number of active ingredient novel pesticide Imicyafos and prothioconazoles is 1～50: 50～1, on the basis of test recipe screening targetedly, the ratio of weight and number of active ingredient novel pesticide Imicyafos and prothioconazoles can be preferably to 3～25: 25～5.
Agricultural insecticide bactericidal composition of the present invention is wetting powder, suspending agent, microemulsion, aqueous emulsion and water dispersible granules by the formulations of pesticide that the preparation method in pesticidal preparations field can be prepared into, in preparation, to account for the portion rate of gross weight in preparation be 1%～80% to active ingredient gross weight, on the basis of test recipe screening targetedly, in preparation, to account for the portion rate of gross weight in preparation be 3%～35% to active ingredient gross weight, and all the other are usual auxiliaries in agricultural chemicals.
When above-described Pesticidal combination is microemulsion, in preparation, the ratio of weight and number of each component is:
The concrete production stage of this microemulsion is: former medicine imicyafos, prothioconazoles are dissolved completely with cosolvent, then add other compositions such as emulsifier, antifreezing agent stabilizing agent, evenly mix, finally add water, after fully stirring, can be made into microemulsion.
When above-described Pesticidal combination is wetting powder, in preparation, the ratio of weight and number of each component is:
The concrete procedure of processing of this Pesticidal combination wetting powder is: by above-mentioned formula, active principle A and active principle B and dispersant, wetting agent and filler are mixed, uniform stirring in stirred tank, after airslide disintegrating mill, mixing, can be made into the wetting powder of the present composition.
When above-described Pesticidal combination is suspending agent, in preparation, the ratio of weight and number of each component is:
The concrete production stage of this suspending agent is for first mixing other auxiliary agents, through high speed shear, mix, add active principle A and active principle B, in ball crusher, abrading-ball is 2～3 hours, make a diameter all below 5mm, make the suspending agent preparation of Pesticidal combination of the present invention.
When above-described Pesticidal combination is aqueous emulsion, in preparation, the ratio of weight and number of each component is:
The concrete production stage of this aqueous emulsion is: first former medicine active principle A and active principle B, solvent and emulsifier, cosolvent are added together, make to be dissolved into uniform oil phase; By part water, antifreeze, other the insecticides adjuvant such as antimicrobial mixes into uniform water; When reactor high speed stirs, oil phase is added to water, slowly add water until reach phase inversion point, open clipper and carry out high speed shear, and add remaining water, shear about half an hour, form the aqueous emulsion of oil-in-water type.Make the aqueous emulsion of Pesticidal combination of the present invention.
When above-described Pesticidal combination is water dispersible granules, in preparation, the ratio of weight and number of each component is:
The concrete procedure of processing of this Pesticidal combination water dispersible granules is: by above-mentioned formula, active principle A, active principle B and dispersant, wetting agent, disintegrant and filler are mixed, with micro jet, pulverize, through mediating, then add and in fluidized bed prilling dryer, carry out granulation, dry, screening by sample analysis, make the water dispersible granules of Pesticidal combination of the present invention.
Described emulsifier is selected from least one in calcium dodecyl benzene sulfonate and aliphatic acid polyethenoxy ether, alkylphenol polyoxyethylene sulfosuccinate, styrylphenol polyoxyethylene ether, polyoxyethylene nonylphenol ether, castor oil polyoxyethylene ether, aliphatic acid polyethenoxy base ester, polyoxyethylene aliphatic alcohol ether.
Described solvent is at least one in dimethylbenzene or biodiesel, toluene, diesel oil, methyl alcohol, ethanol, n-butanol, isopropyl alcohol, turpentine oil, solvent naphtha, dimethyl formamide, dimethyl sulfoxide (DMSO), water equal solvent.
Described dispersant is selected from least one in polycarboxylate, lignosulfonates, alkylphenol polyoxyethylene formaldehyde condensation products sulphate, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol polyoxyethylene, aliphatic amine polyoxyethylene ether, polyoxyethylene carboxylate, fatty acid glyceride APEO.
Described wetting agent is selected from lauryl sodium sulfate, calcium dodecyl benzene sulfonate, pulls open powder copper rosinate X., wetting and penetrating agent F, at least one in alkylnaphthalene sulfonate, polyoxyethylene triphenylethylene phosphenylic acid salt, spaonin powder, silkworm excrement, soapberry powder.
Described disintegrant is selected from least one in bentonite, urea, ammonium sulfate, aluminium chloride, citric acid, succinic acid, sodium bicarbonate.
Described thickener is selected from least one in xanthans, CMC, hydroxyethylcellulose, methylcellulose, Magnesiumaluminumsilicate, polyvinyl alcohol.
Described stabilizing agent is selected from least one in sodium citrate, resorcinol.
Described antifreezing agent is selected from least one in ethylene glycol, propane diols, glycerine.
Described defoamer is selected from least one in silicone oil, silicone compound, C10-20 saturated fat acid compounds, C8-10 aliphatic alcohols compound.
Described filler is selected from least one in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, precipitated calcium carbonate.
Agricultural insecticide bactericidal composition of the present invention to grain, cotton, oil, really, the multiple fungal diseases of vegetables, flowers all has favorable effect, especially the powdery mildew on the cereal such as wheat, fruit and vegetables, downy mildew, rust, tikka class disease, scab, rot etc. are caused to ergosterol class synthetic inhibitor class agricultural chemicals, had the control of the disease of certain resistance to have excellent preventive effect by germ.Pesticidal combination of the present invention can prevent and treat nematoda, etc. the various insects such as sufficient class, coleoptera class pest, Lepidoptera class pest, gastropod, orthoptera pest, phytotrophy acarid class, thrips insect, Diptera pest, Hymenoptera insect, hidden wing order insect, Anoplura insect, Isoptera insect, Semiptera insect, damp insects, centipede insects, thousand-legger class.Especially to destroy the insect of agriculture horticultural crop and trees etc., the insect of destroying the seed of agriculture horticultural crop and trees in soil, such as nematoda, etc. sufficient class, coleoptera class pest, Lepidoptera class pest, gastropod, orthoptera pest, phytotrophy acarid class, Semiptera insect preventive effect remarkable.
The above nematode pests comprises the pratylenchus classes such as pratylenchus, pseudo-Pratylenchidae, Lu Si Pratylenchidae, disability Pratylenchidae, the Cyst nematode such as soybean cyst nematode Heterodera glycines, globodera rostochiensis class, the root-knot nematode such as peanut root-knot nematode, Meloidogyne incognita class, the Aphelenchoidea classes such as aphelenchoides besseyi, leaf bud nematode, species of Tylenchorhynchus Nematodes class, loop wire insects, needlework insects, long capsule nematoda, burr nematoda, nematode on strawberry, pine wood nematode.In addition the insects such as aphid, leafhopper, plant hopper, chrysomelid, wireworm, cutworm, diamond-back moth, imported cabbageworm, rice thrips are all had to favorable effect.
In addition, insecticidal and bactericidal composition of the present invention is compared similar medicament also a lot of other obvious advantages, the first, compare single dose sphere of action wider, can desinsection again can diseases prevention; The second, greatly delayed the drug-fast generation of crop, reduced agricultural chemicals Reusability number of times, reduced agricultural chemicals usage amount, reduce agricultural cost; The 3rd, the residual quantity of this insecticidal and bactericidal composition is lower, more friendly to environment; Finally in the application of this insecticidal and bactericidal composition, crops are had to general fresh-keeping production-increasing function, the increasing both production and income of agricultural region is significant.
Embodiment:
In order to make object of the present invention, technical scheme and advantage clearer, the present invention describes with following specific embodiment, but the present invention only limits to absolutely not these examples.The method that the present invention adopts indoor bioassay and field trial to combine, if no special instructions, the ratio of below mentioning (comprising percentage) is all ratio of weight and number.
Embodiment 1: by imicyafos10 part, 10 parts of prothioconazoles, 8 parts of lignosulfonates, 12 parts of lauryl sodium sulfate and 60 parts of mixing of diatomite, uniform stirring in stirred tank, after airslide disintegrating mill, mixing, making the wetting powder of Pesticidal combination of the present invention.
Embodiment 2: by imicyafos5 part, 15 parts of prothioconazoles, 8 parts of alkylphenol polyoxyethylene, 15 parts of oxygen ethene triphenylethylene phosphenylic acid salt and 67 parts of mixing of bentonite, uniform stirring in stirred tank, after airslide disintegrating mill, mixing, making the wetting powder of Pesticidal combination of the present invention.
Embodiment 3: by imicyafos6 part, 20 parts of prothioconazoles, 10 parts of dispersants, 12 parts of wetting agents and 52 parts of mixing of filler, uniform stirring in stirred tank is mixing after airslide disintegrating mill, makes the wetting powder of Pesticidal combination of the present invention.
Embodiment 4: by 8 parts of alkylphenol polyoxyethylene, 1 part of glycerine, 4 parts of CMCs, 1 part of silicone oil, 66 parts of mixing of water, through high speed shear, mix, add successively 5 parts of imicyafos15 part, prothioconazoles, in ball crusher, abrading-ball is 2～3 hours, make a diameter all below 5mm, make the suspending agent preparation of Pesticidal combination of the present invention.
Embodiment 5: by 12 parts of dispersants, 2 parts of antifreezing agents, 3 parts of thickeners, 1 part of defoamer, 57 parts of mixing of water, through high speed shear, mix, add successively 5 parts of imicyafos20 part, prothioconazoles, in ball crusher, abrading-ball is 2～3 hours, make a diameter all below 5mm, make the suspending agent preparation of Pesticidal combination of the present invention.
Embodiment 6: by 10 parts of dispersants, 2 parts of antifreezing agents, 4 parts of thickeners, 1 part of defoamer, 55 parts of mixing of water, through high speed shear, mix, add successively 20 parts of imicyafos8 part, prothioconazoles, in ball crusher, abrading-ball is 2～3 hours, make a diameter all below 5mm, make the suspending agent preparation of Pesticidal combination of the present invention.
Embodiment 7: 8 parts of imicyafos10 parts, 15 parts of prothioconazoles, 12 parts, turpentine oil, 5 parts of castor oil polyoxyethylene ethers, resorcinol are mixed, be dissolved into uniform oil phase; 2 parts, part water, 2 parts of propane diols, silicone compound is mixed into uniform water; When reactor high speed stirs, oil phase is added to water, add 4 parts of polyvinyl alcohol, slowly add water until reach phase inversion point, open clipper and carry out high speed shear, and add remaining water to supply 100 parts, and shear about half an hour, form the aqueous emulsion of oil-in-water type.Make the aqueous emulsion of Pesticidal combination of the present invention.
Embodiment 8: 10 parts of imicyafos25 parts, 5 parts of prothioconazoles, 20 parts of solvents, 8 parts of emulsifier, stabilizing agent are mixed, be dissolved into uniform oil phase; 2 parts, part water, 1 part of antifreezing agent, defoamer is mixed into uniform water; When reactor high speed stirs, oil phase is added to water, add 3 parts of thickeners, slowly add water until reach phase inversion point, open clipper and carry out high speed shear, and add remaining water to supply 100 parts, shear about half an hour, form the aqueous emulsion of oil-in-water type.Make the aqueous emulsion of Pesticidal combination of the present invention.
Embodiment 9: 8 parts of imicyafos12 parts, 15 parts of prothioconazoles, 18 parts of solvents, 11 parts of emulsifier, stabilizing agent are mixed, be dissolved into uniform oil phase; 2 parts, part water, 1 part of antifreezing agent, defoamer is mixed into uniform water; When reactor high speed stirs, oil phase is added to water, add 3 parts of thickeners, slowly add water until reach phase inversion point, open clipper and carry out high speed shear, and add remaining water to supply 100 parts, shear about half an hour, form the aqueous emulsion of oil-in-water type.Make the aqueous emulsion of Pesticidal combination of the present invention.
Embodiment 10: 42 parts of imicyafos25 part, 5 parts of prothioconazoles, 11 parts of aliphatic amine polyoxyethylene ethers, 12 parts of alkylnaphthalene sulfonates, 5 parts, aluminium chloride and bentonites are mixed, with micro jet, pulverize, through mediating, then add and in fluidized bed prilling dryer, carry out granulation, dry, screening by sample analysis, make the water dispersible granules of Pesticidal combination of the present invention.
Embodiment 11: 43 parts of imicyafos20 part, 10 parts of prothioconazoles, 12 parts of dispersants, 10 parts of wetting agents, 5 parts of disintegrants and fillers are mixed, with micro jet, pulverize, through mediating, then add and in fluidized bed prilling dryer, carry out granulation, dry, screening by sample analysis, make the water dispersible granules of Pesticidal combination of the present invention.
Embodiment 12: 51 parts of imicyafos10 part, 16 parts of prothioconazoles, 8 parts of dispersants, 12 parts of wetting agents, 3 parts of disintegrants and fillers are mixed, with micro jet, pulverize, through mediating, then add and in fluidized bed prilling dryer, carry out granulation, dry, screening by sample analysis, make the water dispersible granules of Pesticidal combination of the present invention.
Embodiment 13: 5 parts of former medicine imicyafos15 parts, prothioconazoles are dissolved completely with cosolvent, add again other compositions such as 10 parts of aliphatic acid polyethenoxy base esters, 2 parts of ethylene glycol, 4 parts of sodium citrates, 4 parts of resorcinols, evenly mix, finally add water, after fully stirring, can be made into microemulsion.
Embodiment 14: 15 parts of former medicine imicyafos10 parts, prothioconazoles are dissolved completely with cosolvent, then add other compositions such as 11 parts of emulsifier, 2 parts of antifreezing agents, 7 parts of stabilizing agents, evenly mix, finally add water, after fully stirring, can be made into microemulsion.
Embodiment 15: 22 parts of former medicine imicyafos8 parts, prothioconazoles are dissolved completely with cosolvent, then add other compositions such as 8 parts of emulsifier, 2 parts of antifreezing agents, 10 parts of stabilizing agents, evenly mix, finally add water, after fully stirring, can be made into microemulsion.
Field experiment: the control to Cucumber Pests And Diseases.
(1) investigation method
Field trial is all located at the cucumber ground in Li Tai township, Yangling district of Shaanxi Province, and in custard squash booth, 5 points are investigated in every community, and every some investigation 2 strains, record occurring degree by staging, and grade scale is as follows:
0 grade: without scab;
1 grade: lesion area accounts for below 5% of whole leaf area;
3 grades: lesion area accounts for whole leaf area 6%～10%;
5 grades: lesion area accounts for 11%～25% of whole leaf area;
7 grades: lesion area accounts for 26%～50% of whole leaf area;
9 grades: lesion area accounts for the more than 50% of whole leaf area.
(2) control time and number of times
Test is investigated 3 times altogether, i.e. disease index investigation before medicine, preventive effect investigation in 7 days after the 1st medicine, 7 days and preventive effect investigation in 15 days after 2 medicines.
(3) drug effect computational methods
The total number of sheets * 100 of sick leaf rate (%)=sick number of sheets/investigate
Disease index=∑ (the sick number of sheets * relative level numerical value at different levels)/(investigating the total number of sheets * 9) * 100
Control efficiency (%)=(disease index after the front disease index * treatment region medicine of 1-(blank district medicine)/(the front disease index of disease index * treatment region medicine after blank district medicine)) * 100
(4) poisoning investigation method
After dispenser, whether 7d range estimation medicament has poisoning to crop continuously.
(5) result of the test and analysis
Each processes the effect of preventing and treating powdery mildew of cucumber table 1
As can be seen from Table 1, the effect that the combination that is mixed that the ratio of weight and number of 26%imicyafos prothioconazoles is 10: 16 prevents and treats powdery mildew of cucumber is very remarkable, and effect is significantly better than single dose, and its quick-acting and lasting effect are all relatively good, especially outstanding with lasting effect.Complex preparation control efficiency under the consumption of high concentration is significantly better than the effect under low concentration consumption.After after the 1st medicine, after 7 days, the 2nd time medicine, the best control efficiency of 7 days reaches respectively 89.52% and 91.44%, the 2 medicine, 15 days best preventive effects reach 90.53%.And 15 days best preventive effects are 81.21% after the 2nd medicine of single dose 25% prothioconazoles SC, the effect of complex preparation is significantly better than single dose.According to field range estimation, with the cucumber of 26%imicyafos prothioconazoles, substantially there is no insect pest, and growth fraction is more vigorous, and the cucumber of 25% prothioconazoles single dose occurs that insect pest is more, than much approximately 15% left and right of insect pest plant with complex preparation.
Within the scope of test dose, plant growth is normal in addition, and the poisoning phenomenon to cucumber does not all appear in each treatment agent, illustrates that it is safe to cucumber.
Claims (5)
1. a Fungicidal insecticidal composition that contains prothioconazoles, it is characterized in that: this Fungicidal insecticidal composition is to take A novel agrochemical Imicyafos and B prothioconazoles as two yuan of composite composite preparations of active ingredient, all the other components are usual auxiliaries in agricultural chemicals, and the structural formula of A novel agrochemical Imicyafos is as follows:
, in this Fungicidal insecticidal composition, the ratio of weight and number of effective constituents A and B is 1～50: 50～1.
2. a kind of Fungicidal insecticidal composition that contains prothioconazoles according to claim 1, is characterized in that: in this Fungicidal insecticidal composition, the ratio of weight and number of effective constituents A and B is 3～25: 25～5.
3. a kind of Fungicidal insecticidal composition that contains prothioconazoles according to claim 1, is characterized in that: in this Fungicidal insecticidal composition, to account for the portion rate of gross weight in preparation be 1%～80% for effective constituents A and B gross weight.
4. a kind of Fungicidal insecticidal composition that contains prothioconazoles according to claim 1, is characterized in that: in this Fungicidal insecticidal composition, effective constituents A and B gross weight account for the portion rate of gross weight in preparation and be preferably 5%～35%.
5. a kind of Fungicidal insecticidal composition that contains prothioconazoles according to claim 1, is characterized in that: the preparation formulation that insecticidal and bactericidal composition of the present invention can be mixed with is wetting powder, suspending agent, microemulsion, aqueous emulsion and water dispersible granules.
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| CN1027670C (en) * | 1990-07-06 | 1995-02-22 | 安哥洛商株式会社 | Organophosphorus compounds, method for preparing same and insecticide, acricides and nematocides |
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| CN101209052A (en) * | 2006-12-27 | 2008-07-02 | 石原产业株式会社 | Composition for preventing and controlling tree parasitic pest for tree |
| CN102258043A (en) * | 2011-08-18 | 2011-11-30 | 陕西美邦农药有限公司 | Germicide composition containing protioconazole |
| CN103429086A (en) * | 2012-07-03 | 2013-12-04 | 石原产业株式会社 | Insect-killing composition and insect prevention method |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1027670C (en) * | 1990-07-06 | 1995-02-22 | 安哥洛商株式会社 | Organophosphorus compounds, method for preparing same and insecticide, acricides and nematocides |
| JP2003081987A (en) * | 2001-09-06 | 2003-03-19 | Agro Kanesho Co Ltd | Imidazolidine derivative containing optically active organophosphorus group, method for producing the same and noxious animal controller containing the same as active ingredient |
| CN101209052A (en) * | 2006-12-27 | 2008-07-02 | 石原产业株式会社 | Composition for preventing and controlling tree parasitic pest for tree |
| CN102258043A (en) * | 2011-08-18 | 2011-11-30 | 陕西美邦农药有限公司 | Germicide composition containing protioconazole |
| CN103429086A (en) * | 2012-07-03 | 2013-12-04 | 石原产业株式会社 | Insect-killing composition and insect prevention method |
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